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CN116300147A - VO-based 2 Current modulation terahertz device and system of metamaterial - Google Patents

VO-based 2 Current modulation terahertz device and system of metamaterial Download PDF

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CN116300147A
CN116300147A CN202211511219.9A CN202211511219A CN116300147A CN 116300147 A CN116300147 A CN 116300147A CN 202211511219 A CN202211511219 A CN 202211511219A CN 116300147 A CN116300147 A CN 116300147A
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CN116300147B (en
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周庆莉
梁菀琳
张存林
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Capital Normal University
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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/0121Operation of devices; Circuit arrangements, not otherwise provided for in this subclass
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/0102Constructional details, not otherwise provided for in this subclass
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/0147Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on thermo-optic effects
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F3/00Optical logic elements; Optical bistable devices
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q15/00Devices for reflection, refraction, diffraction or polarisation of waves radiated from an antenna, e.g. quasi-optical devices
    • H01Q15/0006Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices
    • H01Q15/0013Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices said selective devices working as frequency-selective reflecting surfaces, e.g. FSS, dichroic plates, surfaces being partly transmissive and reflective
    • H01Q15/002Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices said selective devices working as frequency-selective reflecting surfaces, e.g. FSS, dichroic plates, surfaces being partly transmissive and reflective said selective devices being reconfigurable or tunable, e.g. using switches or diodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q15/00Devices for reflection, refraction, diffraction or polarisation of waves radiated from an antenna, e.g. quasi-optical devices
    • H01Q15/0006Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices
    • H01Q15/0086Devices acting selectively as reflecting surface, as diffracting or as refracting device, e.g. frequency filtering or angular spatial filtering devices said selective devices having materials with a synthesized negative refractive index, e.g. metamaterials or left-handed materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Optical Modulation, Optical Deflection, Nonlinear Optics, Optical Demodulation, Optical Logic Elements (AREA)
  • Semiconductor Lasers (AREA)

Abstract

The invention provides a VO-based system 2 And a current modulation terahertz device, a terahertz wave modulation system and an information encryption system of the metamaterial. Wherein, current modulation terahertz device includes: a substrate transparent to terahertz waves; VO formed on substrate 2 A layer; formed at VO 2 A microresonator on the layer; the microresonator includes: formed at VO 2 The layer is used for loading bias current, and a current positive terminal and a current negative terminal which are bilaterally symmetrical; formed at VO 2 On the layer, the inner sides of the current positive electrode end and the current negative electrode end are bilaterally symmetrical, N is more than or equal to 2, and M is more than or equal to 2; the resonance units are in a split ring structure with LC resonance modes, M resonance units in each row are sequentially connected in series, and two ends of the N rows of resonance units are respectively connected to a current positive terminal and a current negative terminalAnd extreme ends. Compared with the modes of laser irradiation, voltage regulation, traditional thermal control and the like, the invention has the advantages of simple operation, easier integration with the current integrated circuit technology and the like.

Description

基于VO2和超材料的电流调制太赫兹器件及系统Current-modulated terahertz devices and systems based on VO2 and metamaterials

技术领域technical field

本发明涉及超材料及太赫兹功能器件领域,尤其涉及一种基于VO2和超材料的电流调制太赫兹器件、太赫兹波调制系统、信息加密系统。The invention relates to the field of metamaterials and terahertz functional devices, in particular to a current modulation terahertz device based on VO2 and metamaterials, a terahertz wave modulation system, and an information encryption system.

背景技术Background technique

超材料通过设计周期性单元结构实现对电磁波的特殊响应从而获得了很多不寻常的特性,如负折射,完美透镜,超透镜和隐形隐身等。然而这些超材料是被动的,因为它们的光学响应在制造后不能动态改变。Metamaterials obtain many unusual properties, such as negative refraction, perfect lens, superlens and invisibility, etc., by designing a periodic unit structure to achieve a special response to electromagnetic waves. However, these metamaterials are passive because their optical response cannot be changed dynamically after fabrication.

二氧化钒(VO2)作为一种相变材料,它在近室温下表现出绝缘体-金属过渡(IMT)行为。相变过程中,VO2在高温金属四方相与低温绝缘单斜相之间发生可逆电阻变化。电导率能够达到几个数量级的变化,同时伴有热滞特性。这些优秀的特性使VO2材料适用于许多有前途的应用,如智能窗口、光开关和相变存储器。Vanadium dioxide (VO 2 ), as a phase change material, exhibits insulator-metal transition (IMT) behavior at near room temperature. During the phase transition, VO undergoes a reversible resistance change between the high-temperature metallic tetragonal phase and the low-temperature insulating monoclinic phase. Conductivity can vary by several orders of magnitude, accompanied by thermal hysteresis. These excellent properties make VO materials suitable for many promising applications, such as smart windows, optical switches, and phase-change memories.

但是,对基于VO2和超材料的器件进行热控制时需要通过使用昂贵且笨重的加热设备,这为实验的操作带来了不便,进一步失去了发展成集成器件的机会。However, the thermal control of VO2 and metamaterial-based devices requires the use of expensive and bulky heating equipment, which brings inconvenience to the operation of experiments and further loses the opportunity to develop into integrated devices.

发明内容Contents of the invention

(一)要解决的技术问题(1) Technical problems to be solved

有鉴于此,本发明期望至少部分解决上述技术问题中的其中之一。In view of this, the present invention intends to at least partially solve one of the above technical problems.

(二)技术方案(2) Technical solutions

为了实现如上目的,根据本发明的第一个方面,提供了一种基于VO2和超材料的电流调制太赫兹器件,包括:对太赫兹波透明的基底;形成于基底上的VO2层;形成于VO2层上的微谐振器;微谐振器包括:形成于VO2层上,用于加载偏置电流,左右对称的电流正极端和电流负极端;形成于VO2层上电流正极端和电流负极端内侧,左右对称,阵列布置的N×M个谐振单元,N≥2,M≥2;其中,谐振单元呈具有LC共振模式的裂环结构,每行的M个谐振单元依次串联,N行谐振单元的两端分别连接至电流正极端和电流负极端。In order to achieve the above purpose, according to the first aspect of the present invention, a current modulation terahertz device based on VO2 and metamaterials is provided, including: a substrate transparent to terahertz waves; a VO2 layer formed on the substrate; A microresonator formed on the VO 2 layer; the microresonator includes: formed on the VO 2 layer for loading bias current, left and right symmetrical current positive terminals and current negative terminals; current positive terminals formed on the VO 2 layer The inner side of the negative terminal of the sum current, left and right symmetrical, N×M resonant units arranged in an array, N≥2, M≥2; wherein, the resonant unit has a split ring structure with LC resonance mode, and the M resonant units in each row are sequentially connected in series , the two ends of the resonant units in the N rows are respectively connected to the positive current terminal and the negative current terminal.

在本发明的一些实施例中,在水平方向上,谐振单元上下对称,包括:封闭环;分别穿过封闭环左、右两侧的左延伸臂和右延伸臂;左延伸臂的左侧连接电流正极端或上一谐振单元的右延伸臂;右延伸臂的右侧连接下一谐振单元的左延伸臂或电流负极端;左、右延伸臂之间形成矩形开口区域。In some embodiments of the present invention, in the horizontal direction, the resonant unit is symmetrical up and down, including: a closed ring; a left extension arm and a right extension arm passing through the left and right sides of the closed ring respectively; the left side of the left extension arm is connected The positive current terminal or the right extension arm of the last resonance unit; the right side of the right extension arm is connected to the left extension arm or the current negative terminal of the next resonance unit; a rectangular opening area is formed between the left and right extension arms.

在本发明的一些实施例中,包括:形成于VO2层上,阵列布置的S×T个微谐振器,S≥2,T≥2;对于每一个微谐振器,N×M个谐振单元的结构参数相同,且N=M;谐振单元的周期p介于40μm~60μm之间;封闭环为封闭方环,其边长l介于30μm~40μm之间;线宽w介于3μm~6μm之间;左、右延伸臂的线宽与封闭环的线宽相同;矩形开口区域的高度h介于5μm~15μm之间,宽度g介于2μm~8μm之间。In some embodiments of the present invention, it includes: formed on the VO2 layer, S×T microresonators arranged in an array, S≥2, T≥2; for each microresonator, N×M resonant units The structural parameters are the same, and N=M; the period p of the resonant unit is between 40 μm and 60 μm; the closed ring is a closed square ring, and its side length l is between 30 μm and 40 μm; the line width w is between 3 μm and 6 μm Between; the line width of the left and right extension arms is the same as that of the closed loop; the height h of the rectangular opening area is between 5 μm and 15 μm, and the width g is between 2 μm and 8 μm.

在本发明的一些实施例中,VO2层的厚度介于5nm~100nm之间。In some embodiments of the present invention, the thickness of the VO 2 layer is between 5 nm˜100 nm.

在本发明的一些实施例中,电流正极端和电流负极端为内侧N行谐振单元加载的偏置电流介于0~0.7A之间。In some embodiments of the present invention, the bias current loaded by the positive current terminal and the negative current terminal to the inner N rows of resonant units is between 0-0.7A.

在本发明的一些实施例中,在厚度方向上,谐振单元包括:形成于VO2层上的粘性金属层;形成于粘性金属层上的导电层,粘性金属层的厚度介于5nm~100nm之间,导电金属层的厚度介于100nm~300nm之间,由粘性金属层和导电金属层形成封闭环和左、右延伸臂。In some embodiments of the present invention, in the thickness direction, the resonance unit includes: an adhesive metal layer formed on the VO2 layer; a conductive layer formed on the adhesive metal layer, and the thickness of the adhesive metal layer is between 5nm and 100nm , the thickness of the conductive metal layer is between 100nm and 300nm, and the closed ring and the left and right extension arms are formed by the adhesive metal layer and the conductive metal layer.

在本发明的一些实施例中,在水平方向,谐振单元的周期为50μm;封闭环的边长l为36μm,线宽w为4μm;左、右延伸臂之间矩形开口区域的高度h为10μm。In some embodiments of the present invention, in the horizontal direction, the period of the resonant unit is 50 μm; the side length l of the closed loop is 36 μm, and the line width w is 4 μm; the height h of the rectangular opening area between the left and right extension arms is 10 μm .

在本发明的一些实施例中,在竖直方向,基底为蓝宝石基底;VO2层的厚度为10nm;粘性金属层为铬薄膜,其厚度为20nm;导电金属层为金薄膜,其厚度为200nm。In some embodiments of the present invention, in the vertical direction, the substrate is a sapphire substrate; the VO2 layer has a thickness of 10 nm; the adhesive metal layer is a chromium film with a thickness of 20 nm; the conductive metal layer is a gold film with a thickness of 200 nm .

在本发明的一些实施例中,电流调制太赫兹器件作为太赫兹波主动调制器或信息加密存储器。In some embodiments of the present invention, the current modulated terahertz device is used as a terahertz wave active modulator or an information encryption memory.

为了实现如上目的,根据本发明的第二个方面,提供了一种太赫兹波调制系统,包括:如上的电流调制太赫兹器件,其作为太赫兹波主动调制器;偏置电流源,其两端连接至太赫兹波主动调制器中微谐振器的电流正极端和电流负极端;其中,偏置电流源将承载编码信息的编码电流加载至太赫兹波主动调制器中微谐振器的电流正极端和电流负极端,以调控微谐振器的太赫兹波透过率。In order to achieve the above object, according to the second aspect of the present invention, a terahertz wave modulation system is provided, including: the above current modulation terahertz device, which serves as a terahertz wave active modulator; a bias current source, two of which terminal is connected to the current positive terminal and the current negative terminal of the microresonator in the terahertz wave active modulator; wherein, the bias current source loads the encoded current carrying the encoded information to the current positive terminal of the microresonator in the terahertz wave active modulator extreme and negative current to adjust the terahertz wave transmittance of the microresonator.

在本发明的一些实施例中,太赫兹波透过率中承载的编码信息为2-bit信息编码;太赫兹波调制系统做如下定义:太赫兹波透过率大于等于透过率阈值时,承载二进制编码“1”;小于透过率阈值时,承载二进制编码“0”。In some embodiments of the present invention, the coded information carried in the terahertz wave transmittance is 2-bit information code; the terahertz wave modulation system is defined as follows: when the terahertz wave transmittance is greater than or equal to the transmittance threshold, Carry binary code "1"; when it is less than the transmittance threshold, carry binary code "0".

在本发明的一些实施例中,太赫兹波主动调制器包括:阵列布置的S×T个微谐振器,S≥2,T≥2,对于每一微谐振器,N×M个谐振单元的结构参数相同;对于不同微谐振器,其内部谐振单元的结构参数不同,且偏置电流源可为不同微谐振器提供不同的偏置电流。In some embodiments of the present invention, the terahertz wave active modulator includes: S×T micro-resonators arranged in an array, S≥2, T≥2, for each micro-resonator, N×M resonance units The structural parameters are the same; for different micro-resonators, the structural parameters of the internal resonant units are different, and the bias current source can provide different bias currents for different micro-resonators.

为了实现如上目的,根据本发明的第三个方面,提供了一种信息加密系统,包括:如上的电流调制太赫兹器件,其作为信息加密存储器;微谐振器作为信息加密存储器的像素;其中,信息加密存储器中微谐振器的结构参数承载加密信息,以特定太赫兹波频率以及加载至微谐振器的电流正极端和电流负极端的特定偏置电流作为密钥,其中,作为密钥的特定太赫兹波频率在微谐振器的谐振峰或谐振谷中选择。In order to achieve the above object, according to the third aspect of the present invention, an information encryption system is provided, including: the current modulation terahertz device as above, which is used as an information encryption memory; the microresonator is used as a pixel of the information encryption memory; wherein, The structural parameters of the microresonator in the information encryption memory carry encrypted information, and the specific terahertz wave frequency and the specific bias current loaded to the positive and negative terminals of the current of the microresonator are used as the key, wherein the specific The terahertz wave frequency is selected among the resonant peaks or resonant valleys of the microresonator.

在本发明的一些实施例中,信息加密存储器包括:阵列布置的S×T个微谐振器,S≥2,T≥2,每一个微谐振器作为组成信息加密存储器的一个像素,对于每一个微谐振器,N×M个谐振单元的结构参数相同;对于不同微谐振器,其内部谐振单元的结构参数不同;信息加密系统中,预设太赫兹波透过率与色彩的对应关系;像素承载的加密信息表现为特定太赫兹波频率和特定偏置电流的条件下,由太赫兹波透过率得到的对应色彩;信息加密存储器承载的加密信息表现为由S×T个像素的色块排列组合而成的图形,图形作为字母、数字和/或符号的表现形式;在解密侧,信息加密系统还包括:解密模块,用于对信息加密存储器中的各个微谐振器分别施加特定偏置电流,并用特定频率的太赫兹波照射信息加密存储器;色彩解调模块,设置于信息加密存储器的光路后端,用于按照预设的太赫兹波透过率与色彩的对应关系,将信息加密存储器中每一个像素的太赫兹波透过率解密为对应的色彩,并将S×T个像素的色块排列组合形成图形。In some embodiments of the present invention, the information encryption memory includes: S×T microresonators arranged in an array, S≥2, T≥2, each microresonator serves as a pixel forming the information encryption memory, for each For microresonators, the structural parameters of N×M resonant units are the same; for different microresonators, the structural parameters of the internal resonant units are different; in the information encryption system, the corresponding relationship between terahertz wave transmittance and color is preset; The encrypted information carried is expressed as the corresponding color obtained from the transmittance of the terahertz wave under the condition of a specific terahertz wave frequency and a specific bias current; the encrypted information carried by the information encryption memory is expressed as a color block composed of S×T pixels Arranged and combined graphics, the graphics are expressed as letters, numbers and/or symbols; on the decryption side, the information encryption system also includes: a decryption module, which is used to apply specific biases to each micro-resonator in the information encryption memory current, and irradiate the information encryption memory with a terahertz wave of a specific frequency; the color demodulation module is set at the back end of the optical path of the information encryption memory, and is used to encrypt the information according to the preset corresponding relationship between the terahertz wave transmittance and the color The terahertz wave transmittance of each pixel in the memory is decrypted into the corresponding color, and the color blocks of S×T pixels are arranged and combined to form a graph.

(三)有益效果(3) Beneficial effects

从上述技术方案可知,本发明相对于现有技术至少具有以下有益效果之一:It can be seen from the above technical solutions that the present invention has at least one of the following beneficial effects compared with the prior art:

(1)本发明在微谐振器的两侧对称设置电流正极端和电流负极端,通过偏置电流在通过微谐振器时产生的电场来对下方的VO2材料进行加热。微谐振器的结构导致了VO2的相变高度局域和依附于微谐振器的电流丝(electrical current filaments)的分布,这样设计既可以确保偏置电流在流经每个谐振器时产生较为一致的加热效果,又可以利用间隙的不同实现对太赫兹波的共振光谱响应的操控和透过谱谱线的调节。(1) The present invention symmetrically arranges the current positive terminal and the current negative terminal on both sides of the microresonator, and heats the VO2 material below by the electric field generated when the bias current passes through the microresonator. The structure of the microresonator results in a highly localized phase transition of VO2 and a distribution of electrical current filaments attached to the microresonator, so that the design can ensure that the bias current flows through each resonator to generate relatively The consistent heating effect can be used to control the resonance spectral response of the terahertz wave and adjust the transmission spectral line by using the difference in the gap.

与采用激光照射的调控方式相比,本发明更加有利于和当前集成电路主流技术的融合,同时还避免了激光光源和太赫兹波源之间的干扰。Compared with the control method using laser irradiation, the present invention is more conducive to the integration with the current mainstream technology of integrated circuits, and at the same time avoids the interference between the laser light source and the terahertz wave source.

与采用电压的调控方式相比,本发明采用电流调制方式,实验证明电流调整更为的直接有效,并且电流可以作为额外的调制参数拓展了器件的应用范围。同时更加有利于同当前的集成电路技术相结合。Compared with the voltage regulation method, the present invention adopts the current modulation method, and the experiment proves that the current regulation is more direct and effective, and the current can be used as an additional modulation parameter to expand the application range of the device. At the same time, it is more conducive to the combination with the current integrated circuit technology.

与传统的热控制VO2相变的调制方式相比,本发明抛弃了笨重的外加热器,采用灵活的电调控方式,降低了实际操作的复杂性,为集成器件的发展提供了便利。Compared with the traditional modulation method of thermally controlling the phase transition of VO 2 , the present invention abandons the bulky external heater and adopts a flexible electrical control method, which reduces the complexity of actual operation and provides convenience for the development of integrated devices.

与VO2层和下层材料形成p-n结来对VO2材料进行加热的调制方式相比,本发明利用超材料的金属特性在通电后产生焦耳热,对VO2层进行加热,从而改变VO2材料的电导率,降低太赫兹波透过率,过程更加直接有效,能耗更低,同时降低了对基底材料进行掺杂而对集成电路其他部件所产生的影响。Compared with the modulation method in which the VO2 layer and the lower layer material form a pn junction to heat the VO2 material, the present invention utilizes the metal properties of the metamaterial to generate Joule heat after electrification, and heats the VO2 layer, thereby changing the VO2 material The electrical conductivity is lower, the terahertz wave transmittance is reduced, the process is more direct and effective, the energy consumption is lower, and at the same time, the impact of doping the base material on other components of the integrated circuit is reduced.

与利用VO2粉末仅在裂环开口处形成相变材料区相比,本发明具有如下优势,第一,通过外延生长的方式制作的整片的VO2层,结晶性更高,一致性更好,从而器件的可靠性更高;第二,整体镀膜工艺可控性更好,制作成本较低,更加有利于工业化生产;第三,更加有利于与当前集成电路主流技术相融合。Compared with using VO2 powder to form the phase change material region only at the opening of the split ring, the present invention has the following advantages. First, the whole piece of VO2 layer made by epitaxial growth has higher crystallinity and better consistency Good, so that the reliability of the device is higher; second, the overall coating process is more controllable, the production cost is lower, and it is more conducive to industrial production; third, it is more conducive to the integration with the current mainstream technology of integrated circuits.

(2)相比于现有技术非对称的谐振单元,本发明中无论是微谐振器中电流正极端、电流负极端的对称布置,谐振单元的阵列布置,谐振单元内部构造,均是设置为对称布置。与现有技术中非对称的谐振单元,如此对称设置,使得整个器件的电学、热力学特性更加稳定。(2) Compared with the asymmetric resonant unit in the prior art, no matter in the present invention, the symmetrical arrangement of the positive current terminal and the negative current terminal in the microresonator, the array arrangement of the resonant unit, and the internal structure of the resonant unit are all set as Symmetrical arrangement. Compared with the asymmetric resonant unit in the prior art, such a symmetrical arrangement makes the electrical and thermodynamic characteristics of the whole device more stable.

(3)每个微谐振器都是在同一基板上制造的具有不同亚波长大小的裂环谐振单元结构阵列,并通过施加外部电流进行独立控制。每个微谐振器所需的阈值电流大小和共振响应的不同使得该微谐振器可以根据实际需求作为一个具有空间选择性的太赫兹调制器。(3) Each microresonator is an array of split-ring resonant unit structures with different subwavelength sizes fabricated on the same substrate and independently controlled by applying an external current. The difference in threshold current and resonance response required by each microresonator enables the microresonator to be used as a space-selective terahertz modulator according to actual needs.

(4)采用具有LC共振模式的裂环结构来构造太赫兹超表面层微结构。LC共振模式使频谱谱线展现出尖锐且具有高质量因子的线形,该线形对外场响应灵敏度较高,可以增强太赫兹波对VO2相变过程中电导率变化的响应,提高频谱曲线线形对VO2相变时的调制灵敏度。(4) The split-ring structure with LC resonance mode is used to construct the microstructure of the terahertz metasurface layer. The LC resonance mode makes the spectral line show a sharp line shape with a high quality factor. This line shape has a high sensitivity to the external field response, which can enhance the response of the terahertz wave to the conductivity change during the phase transition of VO2 , and improve the line shape of the spectrum curve. Modulation sensitivity upon phase transition of VO2 .

(5)在太赫兹超表面微结构中,谐振单元结构内部间隙尺寸分别是8、6、4、2μm;其中,间隙最小的微谐振器具有最强响应的LC共振模式,所以在频谱中表现出最尖锐的共振谷谱线线形,在对VO2的相变调制中表现出最大的灵敏程度。完全调制时,间隙的减小使器件的工作电流从0.62A减小到0.38A,有效的降低了器件的工作阈值。(5) In the terahertz metasurface microstructure, the internal gap size of the resonant unit structure is 8, 6, 4, and 2 μm respectively; among them, the microresonator with the smallest gap has the strongest response LC resonance mode, so it shows in the frequency spectrum It shows the sharpest resonance valley line shape, and shows the greatest sensitivity in the phase change modulation of VO2 . When fully modulated, the reduction of the gap reduces the operating current of the device from 0.62A to 0.38A, which effectively reduces the operating threshold of the device.

(6)基于电流调制太赫兹器件展现出的高调制深度和迟滞特性,开发了一种基于透过谱的太赫兹波调制系统。基于可擦写特性和不同电致的非挥发性多能级电导态,多个微谐振器阵列均可实现可重写功能,并且可以对输出的二进制编码进行任意组合输出,为光子存储器和太赫兹通信器件的发展提供了令人兴奋的机会。(6) Based on the high modulation depth and hysteresis characteristics exhibited by current-modulated terahertz devices, a terahertz wave modulation system based on transmission spectrum was developed. Based on the rewritable characteristics and non-volatile multi-level conductance states of different electromagnetisms, multiple microresonator arrays can realize rewritable functions, and can output any combination of output binary codes, which is a promising solution for photonic memory and solar energy. The development of Hertzian communication devices presents exciting opportunities.

(7)利用不同谐振单元结构阵列产生的分离的透射率迟滞回线,进一步在太赫兹频段提供了一种频率可选动态可调彩色图案显示的信息加密系统,通过预设太赫兹波透过率与色彩的对应关系,利用电流和太赫兹波频率作为解密密钥可以实现信息加密和多图像再现。(7) Using the separated transmittance hysteresis loops generated by arrays of different resonant unit structures, an information encryption system with frequency-selectable and dynamically adjustable color pattern display is further provided in the terahertz frequency band. Through the preset terahertz wave transmission The corresponding relationship between frequency and color, using current and terahertz wave frequency as the decryption key can realize information encryption and multi-image reproduction.

附图说明Description of drawings

图1A为本发明实施例电流调制太赫兹器件的立体示意图。FIG. 1A is a three-dimensional schematic diagram of a current-modulated terahertz device according to an embodiment of the present invention.

图1B为图1A所示电流调制太赫兹器件的剖视图。FIG. 1B is a cross-sectional view of the current-modulated terahertz device shown in FIG. 1A .

图2为图1A所示电流调制太赫兹器件中四个谐振器各自其中之一谐振单元的示意图。FIG. 2 is a schematic diagram of a resonance unit of each of the four resonators in the current-modulated terahertz device shown in FIG. 1A .

图3A、图3B、图3C、图3D分别为图1A所示电流调制太赫兹器件的四个谐振器在电流调制下的太赫兹透过谱曲线。FIG. 3A , FIG. 3B , FIG. 3C , and FIG. 3D are respectively the terahertz transmission spectrum curves of the four resonators of the current-modulated terahertz device shown in FIG. 1A under current modulation.

图4为图1A所示电流调制太赫兹器件中的内部间隙g=2的第四谐振器在第一个谐振谷处的表面电流和电场分布图。FIG. 4 is a diagram of the surface current and electric field distribution at the first resonance valley of the fourth resonator with an internal gap g=2 in the current-modulated terahertz device shown in FIG. 1A .

图5为图1A所示电流调制太赫兹器件中的第二、三、四微谐振器在第一个谐振谷处的透过率的调制深度随电流变化的比较图。FIG. 5 is a comparison diagram of the modulation depth of the transmittance at the first resonance valley of the second, third, and fourth microresonators in the current-modulated terahertz device shown in FIG. 1A as a function of current.

图6为本发明中电流调制太赫兹器件中四个微谐振器随电流变化的连续频谱到数字信息的转化与输出示意图。Fig. 6 is a schematic diagram of the conversion and output of the continuous frequency spectrum of the four microresonators varying with the current into digital information in the current-modulated terahertz device of the present invention.

图7为本发明实施例太赫兹波调制系统实现的透过率的多态特性及多态对应的二进制编码示意图。FIG. 7 is a schematic diagram of the multi-state characteristics of the transmittance realized by the terahertz wave modulation system and the binary codes corresponding to the multi-states according to the embodiment of the present invention.

图8A、图8B为图7所示太赫兹波调制系统中第四谐振器实现的利用可编程电流脉冲的灵活任意编码功能的示意图。8A and 8B are schematic diagrams of the flexible arbitrary encoding function realized by the fourth resonator in the terahertz wave modulation system shown in FIG. 7 by using programmable current pulses.

图9A演示了由四个微谐振器组合而成的信息加密存储器示意图。Fig. 9A demonstrates a schematic diagram of an information encryption memory composed of four micro-resonators.

图9B为在错误的解密密钥-0.87和1.01THz下的彩色显示随电流变化的示意图。Fig. 9B is a schematic diagram of color display changing with current at wrong decryption key - 0.87 and 1.01 THz.

图9C为以多种的太赫兹波频率和偏置电流作为解密密钥实现信息解密和图像再现的示意图。FIG. 9C is a schematic diagram of implementing information decryption and image reproduction using various terahertz wave frequencies and bias currents as decryption keys.

具体实施方式Detailed ways

本发明中,提出了一种利用电流产生的焦耳热来调制VO2层,利用VO2相变特性实现相关功能的技术方案,相比于激光照射、电压调控、传统热控等方式,具有操作简单,更易于同当前集成电路技术相融合等优势。In the present invention, a technical solution is proposed that utilizes Joule heat generated by current to modulate the VO2 layer, and utilizes the phase transition characteristics of VO2 to realize related functions. Compared with laser irradiation, voltage regulation, traditional thermal control, etc. Simple, easier to integrate with current integrated circuit technology and other advantages.

为使本发明的目的、技术方案和优点更加清楚明白,下文结合具体实施方式,并参照附图,对本发明进一步详细说明。In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be further described in detail below in conjunction with specific implementation methods and with reference to the accompanying drawings.

一、电流调制太赫兹器件1. Current-modulated terahertz devices

在本发明的第一个示例性实施例中,提供了一种基于VO2和超材料的电流调制太赫兹器件,其通过对调制方式的优化和对超表面层微结构设计获得了对外场敏感的谱线线形,提升了整个器件的一致性和稳定性,增加了与当前集成电路技术的兼容性。In the first exemplary embodiment of the present invention, a current-modulated terahertz device based on VO2 and metamaterials is provided, which is sensitive to external fields by optimizing the modulation method and designing the microstructure of the metasurface layer The spectral line shape improves the consistency and stability of the entire device, and increases the compatibility with current integrated circuit technology.

图1A为本发明实施例电流调制太赫兹器件的立体示意图。图1B为图1A所示电流调制太赫兹器件的剖视图。如图1A和图1B所示,本实施例电流调制太赫兹器件包括:FIG. 1A is a three-dimensional schematic diagram of a current-modulated terahertz device according to an embodiment of the present invention. FIG. 1B is a cross-sectional view of the current-modulated terahertz device shown in FIG. 1A . As shown in Figure 1A and Figure 1B, the current modulation terahertz device of this embodiment includes:

对太赫兹波透明的基底;Substrates transparent to terahertz waves;

形成于所述基底上的VO2层;a VO layer formed on the substrate;

刻蚀形成于所述VO2层上,呈2×2阵列排列的四个微谐振器。Four microresonators arranged in a 2× 2 array were formed on the VO layer by etching.

以下对本实施例电流调制太赫兹器件进行详细说明,尤其是本发明的重点部分VO2层及微谐振器。The current-modulated terahertz device of this embodiment will be described in detail below, especially the VO 2 layer and the microresonator, which are the key parts of the present invention.

本实施例中,基底为430μm厚的蓝宝石基底(Sapphire),其对太赫兹波透明。蓝宝石基底具有工艺成熟,成本低廉,透明度好等优点。除了蓝宝石基底之外,本发明还可以采用与VO2材料晶格参数匹配的其他基底来制作VO2层。In this embodiment, the substrate is a 430 μm thick sapphire substrate (Sapphire), which is transparent to terahertz waves. The sapphire substrate has the advantages of mature technology, low cost and good transparency. In addition to the sapphire substrate, the present invention can also use other substrates that match the lattice parameters of the VO 2 material to make the VO 2 layer.

本实施例中,采用脉冲激光沉积(PLD)方法在衬底上生长了VO2层。VO2层的厚度为10nm,平铺在整个基底之上,而并非仅在谐振器区域。本领域技术人员应当理解,除了PLD之外,还可以采用其他薄膜外延沉积方式。此外,在本发明其他实施例中,VO2层的厚度介于5nm~100nm之间,同样可以实现本发明。In this embodiment, a VO 2 layer is grown on a substrate by a pulsed laser deposition (PLD) method. The VO2 layer has a thickness of 10nm and is tiled over the entire substrate, not just in the resonator region. Those skilled in the art should understand that, in addition to PLD, other thin film epitaxial deposition methods can also be used. In addition, in other embodiments of the present invention, the thickness of the VO 2 layer is between 5nm and 100nm, and the present invention can also be realized.

测试结果表明,本实施例在蓝宝石基底上外延生长的VO2层具有高质量的外延性和较平滑的表面,电阻在转变温度附近出现了三个数量级的突变,为电控调制提供了较大的对比度和更高的稳定性。The test results show that the VO2 layer epitaxially grown on the sapphire substrate in this embodiment has high-quality epitaxy and a relatively smooth surface, and the resistance has a sudden change of three orders of magnitude near the transition temperature, which provides a large contrast and greater stability.

需要特别说明的是,现有技术中已有利用VO2粉末涂敷裂环开口的方式来形成相变材料区的技术方案。与其相比,本发明具有如下优势,第一,通过外延生长的方式制作的整片的VO2层,结晶性更高,一致性更好,从而器件的可靠性更高;第二,整体镀膜工艺可控性更好,制作成本较低,更加有利于工业化生产;第三,更加有利于与当前集成电路主流技术相融合。It should be noted that in the prior art, there is a technical solution for forming the phase-change material region by coating the opening of the split ring with VO2 powder. Compared with it, the present invention has the following advantages. First, the entire VO2 layer made by epitaxial growth has higher crystallinity and better consistency, so that the reliability of the device is higher; second, the overall coating The controllability of the process is better, the production cost is lower, and it is more conducive to industrial production; third, it is more conducive to the integration with the current mainstream technology of integrated circuits.

请继续参照图1,本实施例中,在VO2层上通过刻蚀方法制作了由四个微谐振器组成的超表面层微结构。四个微谐振器2×2均匀分布于VO2层上,每个微谐振器在横、纵向的间距为2mm。为描述方便,左上、右上、左下、右下的为谐振器分别命名为:第一谐振器、第二谐振器、第三谐振器、第四谐振器。Please continue to refer to FIG. 1 , in this embodiment, a metasurface layer microstructure consisting of four microresonators is fabricated on the VO2 layer by etching. Four microresonators 2×2 are evenly distributed on the VO 2 layer, and the distance between each microresonator in the horizontal and vertical directions is 2mm. For the convenience of description, the upper left, upper right, lower left, and lower right resonators are respectively named: the first resonator, the second resonator, the third resonator, and the fourth resonator.

本领域技术人员应当理解,本发明中,每个微谐振器都是在同一基板上制造的具有不同亚波长大小的裂环谐振单元结构阵列,并通过施加外部电流进行独立控制。每个微谐振器所需的阈值电流大小和共振响应的不同使得该微谐振器可以根据实际需求作为一个具有空间选择性的太赫兹波主动调制器。Those skilled in the art should understand that in the present invention, each microresonator is an array of split-ring resonant unit structures with different subwavelength sizes fabricated on the same substrate, and is independently controlled by applying an external current. The difference in threshold current and resonance response required by each microresonator enables the microresonator to be used as a spatially selective terahertz wave active modulator according to actual needs.

在本发明的其他实施例中,电流调制太赫兹器件可以包括S×T个独立的微谐振器,S≥2,T≥2,S和T可以相同,也可以不同。本实施例中,S=T=3。In other embodiments of the present invention, the current-modulated terahertz device may include S×T independent micro-resonators, S≥2, T≥2, and S and T may be the same or different. In this embodiment, S=T=3.

对于每个微谐振器,其包括:形成于VO2层上,用于加载偏置电流,左右对称的电流正极端和电流负极端,连接于偏置电流源(Bias Current);形成于VO2层上,电流正极端和电流负极端内侧,阵列布置的3×3个谐振单元。其中,每个微谐振器的3×3个谐振单元都通过金线相连并连接到左右两侧的电流正极端和电流负极端来形成一个通路,以便实现独立的电流调制。换句话说,每个微谐振器作为一个独立的电流调制单元。For each microresonator, it includes: formed on the VO 2 layer for loading bias current, left and right symmetrical current positive terminals and current negative terminals, connected to the bias current source (Bias Current); formed on VO 2 On the layer, on the inner side of the current positive terminal and the current negative terminal, there are 3×3 resonant units arranged in an array. Among them, the 3×3 resonant units of each microresonator are connected by gold wires and connected to the positive current terminal and negative current terminal on the left and right sides to form a path, so as to realize independent current modulation. In other words, each microresonator acts as an independent current modulation unit.

在本发明的其他实施例中,组成微谐振器的谐振单元阵列可以包括N×M个单元,N≥2,M≥2,N和M可以相同,也可以不同。优选地,为了尽可能降低检测的各向异性,横向和纵向的单元结构数目相同,即N=M。此外,优选地,为了保证检测信号强度,单元结构阵列所覆盖的面积应当等于或大于太赫兹时域光谱系统中太赫兹波的覆盖面积。In other embodiments of the present invention, the resonant unit array constituting the micro-resonator may include N×M units, N≥2, M≥2, and N and M may be the same or different. Preferably, in order to reduce the detected anisotropy as much as possible, the number of unit structures in the transverse and longitudinal directions is the same, ie N=M. In addition, preferably, in order to ensure the detection signal strength, the area covered by the unit structure array should be equal to or larger than the covered area of the terahertz wave in the terahertz time-domain spectroscopy system.

如图1A所示,本实施例中,谐振单元呈具有LC共振模式的裂环结构,每行的3个谐振单元依次串联,3行谐振单元的两端分别连接至所述电流正极端和电流负极端。图2为图1A所示电流调制太赫兹器件中四个谐振器各自其中之一谐振单元的示意图。As shown in Figure 1A, in this embodiment, the resonant unit has a split ring structure with LC resonance mode, and the three resonant units in each row are connected in series in sequence, and the two ends of the resonant units in the three rows are respectively connected to the positive terminal of the current and the current negative extreme. FIG. 2 is a schematic diagram of a resonance unit of each of the four resonators in the current-modulated terahertz device shown in FIG. 1A .

其中,(A)、(B)、(C)、(D)图为图1A中第一、二、三、四微谐振器中的谐振单元。以下结合如图1A、图1B和图2,来介绍本实施例中的谐振单元。Among them, (A), (B), (C), and (D) are the resonant units in the first, second, third, and fourth microresonators in FIG. 1A . The resonant unit in this embodiment will be introduced below with reference to FIG. 1A , FIG. 1B and FIG. 2 .

请参照图1B,在厚度方向上,谐振单元包括:形成于VO2层上的铬层;形成于铬层上的金层。其中,铬层的厚度为20nm,金层的厚度为200nm。其中,铬层的作用主要是保证金层在基底上的附着度。铬层和金层经刻蚀形成谐振单元的平面结构。Referring to FIG. 1B , in the thickness direction, the resonant unit includes: a chromium layer formed on the VO 2 layer; and a gold layer formed on the chromium layer. Wherein, the thickness of the chromium layer is 20nm, and the thickness of the gold layer is 200nm. Among them, the role of the chromium layer is mainly to ensure the adhesion of the gold layer on the substrate. The chromium and gold layers are etched to form the planar structure of the resonant unit.

本领域技术人员应当清楚,铬薄膜也可以用其他能够提供高粘合性的粘合金属材料来代替,例如钛等;金微结构也可以用其他类似的金属材料来代替,例如:银、铜等。此外,铬薄膜和金微结构的厚度也可以根据需要进行调整,优选地,铬薄膜的厚度介于5nm~100nm之间。金薄膜的厚度介于100nm~300nm之间。It should be clear to those skilled in the art that the chromium film can also be replaced by other bonding metal materials that can provide high adhesion, such as titanium, etc.; the gold microstructure can also be replaced by other similar metal materials, such as: silver, copper wait. In addition, the thickness of the chromium thin film and the gold microstructure can also be adjusted according to needs. Preferably, the thickness of the chromium thin film is between 5nm and 100nm. The thickness of the gold thin film is between 100nm and 300nm.

本实施例中,四个微谐振器中谐振单元结构相同,其区别仅在于分裂间隙尺寸g不同。请参照图1A和图2,在水平方向上,所述谐振单元上下对称,包括:封闭方环;分别穿过所述封闭方环左、右两侧的左延伸臂和右延伸臂;所述左延伸臂的左侧连接所述电流正极端或上一谐振单元的右延伸臂;所述右延伸臂的右侧连接下一谐振单元的左延伸臂或所述电流负极端;所述左、右延伸臂之间形成矩形开口区域。In this embodiment, the structures of the resonant units in the four microresonators are the same, and the only difference lies in the size g of the split gap. Please refer to Figure 1A and Figure 2, in the horizontal direction, the resonance unit is symmetrical up and down, including: a closed square ring; a left extension arm and a right extension arm passing through the left and right sides of the closed square ring; The left side of the left extension arm is connected to the positive terminal of the current or the right extension arm of the previous resonance unit; the right side of the right extension arm is connected to the left extension arm of the next resonance unit or the negative terminal of the current; the left, A rectangular open area is formed between the right extension arms.

具体而言,本实施例中,谐振单元的周期p介于40μm~60μm之间;所述封闭方环的边长l介于30μm~40μm之间;线宽w介于3μm~6μm之间;所述左、右延伸臂的线宽与封闭方环的线宽相同;所述矩形开口区域的高度h介于5μm~15μm之间,宽度g介于2μm~8μm之间。谐振单元的周期为50μm;所述封闭方环的边长l为36μm,线宽w为4μm;所述左、右延伸臂之间矩形开口区域的高度h为10μm。Specifically, in this embodiment, the period p of the resonant unit is between 40 μm and 60 μm; the side length l of the closed square ring is between 30 μm and 40 μm; the line width w is between 3 μm and 6 μm; The line width of the left and right extension arms is the same as that of the closed square ring; the height h of the rectangular opening area is between 5 μm and 15 μm, and the width g is between 2 μm and 8 μm. The period of the resonance unit is 50 μm; the side length l of the closed square ring is 36 μm, the line width w is 4 μm; the height h of the rectangular opening area between the left and right extension arms is 10 μm.

本领域技术人员应当理解,虽然本实施例以封闭方环为例进行说明,但在本发明的其他实施方式中,还可以采用封闭圆环、封闭矩形环等封闭环形式。同时,封闭环的结构参数,如边长、线宽、开口尺寸等,也可以根据需要进行调整。Those skilled in the art should understand that although this embodiment is described by taking a closed square ring as an example, in other embodiments of the present invention, closed ring forms such as a closed circular ring and a closed rectangular ring may also be used. At the same time, the structural parameters of the closed loop, such as side length, line width, opening size, etc., can also be adjusted as needed.

需要特别说明的是,为了增强本实施例电流调制太赫兹器件谱线线形对VO2相变的灵敏度,通过调整共振响应后实验中确定的四个谐振器中谐振单元的参数g的值分别为8、6、4、2μm。It should be noted that, in order to enhance the sensitivity of the spectral line shape of the current-modulated terahertz device in this embodiment to the VO2 phase change, the values of the parameter g of the resonance unit in the four resonators determined in the experiment after adjusting the resonance response are respectively: 8, 6, 4, 2 μm.

本实施例电流调制太赫兹器件如此设置,是因为VO2的相变高度局域和依附于微谐振器的电流丝(electrical current filaments)的分布,这样设计既可以确保偏置电流在流经每个微谐振器时产生较为一致的加热效果,又可以利用间隙的不同实现对太赫兹波的共振光谱响应的操控和透过谱谱线的调节。The current modulation terahertz device of this embodiment is set up in this way because the phase transition of VO2 is highly localized and the distribution of the electrical current filaments attached to the microresonator, so that the design can ensure that the bias current flows through each A relatively consistent heating effect can be produced when a microresonator is used, and the difference in the gap can be used to realize the manipulation of the resonant spectral response of the terahertz wave and the adjustment of the transmission spectral line.

进一步地,本发明采用具有LC共振模式的裂环结构来构造太赫兹超表面层微结构。LC共振模式使频谱谱线展现出尖锐且具有高质量因子的线形,该线形对外场响应灵敏度较高,可以增强THz波对VO2相变过程中电导率变化的响应,提高频谱曲线线形对VO2相变时的调制灵敏度。Further, the present invention adopts the split ring structure with LC resonance mode to construct the microstructure of the terahertz metasurface layer. The LC resonance mode makes the spectral line show a sharp line shape with a high quality factor. This line shape has a high sensitivity to the external field response, which can enhance the response of the THz wave to the conductivity change during the phase transition of VO2 , and improve the line shape of the spectrum curve to VO2. Modulation sensitivity at phase transitions.

此外,从上述结构可以看出,相比于现有技术非对称的谐振单元,本发明中无论是微谐振器中电流正极端、电流负极端的对称布置,谐振单元的阵列布置,谐振单元内部构造,均是设置为对称布置。与现有技术中非对称的谐振单元,如此对称设置,使得整个器件的电学、热力学特性更加稳定。In addition, it can be seen from the above structure that, compared with the asymmetric resonant unit in the prior art, no matter the symmetrical arrangement of the positive current terminal and the negative current terminal in the microresonator in the present invention, the array arrangement of the resonant unit, the inside of the resonant unit The structures are all arranged symmetrically. Compared with the asymmetric resonant unit in the prior art, such a symmetrical arrangement makes the electrical and thermodynamic characteristics of the whole device more stable.

图3A、图3B、图3C及图3D分别为图1所示电流调制太赫兹器件中第一、二、三、四微谐振器的透过谱曲线随施加电流的变化。其中,横坐标为频率(Frequency),单位为太赫兹(THz);纵坐标为透过率(Transmission)。如图3A所示,静态(I=0A)下的透过谱没有出现明显的共振吸收。当I逐渐增加时,振幅透过率开始减小并在电流值足够大时整体下降到最低值,随着电流又减小到0A时,透过谱又重新恢复到静态电流的状态,说明VO2的电阻变化是可逆的。同时图3A中在小电流的调制下,谱线的变化并不明显。Fig. 3A, Fig. 3B, Fig. 3C and Fig. 3D are respectively the transmission spectrum curves of the first, second, third and fourth micro-resonators in the current-modulated terahertz device shown in Fig. 1 as a function of the applied current. Wherein, the abscissa is frequency (Frequency), and the unit is terahertz (THz); the ordinate is transmittance (Transmission). As shown in FIG. 3A , there is no obvious resonance absorption in the transmission spectrum under static state (I=0A). When I gradually increases, the amplitude transmittance begins to decrease and drops to the lowest value as a whole when the current value is large enough. As the current decreases to 0A, the transmittance spectrum returns to the state of static current again, indicating that VO 2 The resistance change is reversible. At the same time, in Fig. 3A, under the modulation of small current, the changes of the spectral lines are not obvious.

为了提高微谐振器对电控响应的灵敏度,本发明对表面谐振器单元结构的设计进行了系统的研究。固定谐振单元结构中外部连线结构,仅减小间隙尺寸g值来调谐阻抗和减小损耗,从而得到在频谱中具有高质量因子且窄带宽的共振线形。当谐振单元结构中的g的值分别减小到6、4、2μm,实验测得的相应的电调谐透过谱如图3B、图3C和图3D所示。图中显示,随着g的减小,频谱中谐振频率和幅度均发生了变化,静态时的谐振频率向低频移动同时产生了线形更为尖锐的共振。In order to improve the sensitivity of the micro-resonator to electric control response, the present invention conducts systematic research on the design of the unit structure of the surface resonator. Fix the external wiring structure in the resonance unit structure, and only reduce the gap size g value to tune the impedance and reduce the loss, so as to obtain a resonance line shape with high quality factor and narrow bandwidth in the frequency spectrum. When the value of g in the resonant unit structure is reduced to 6, 4, and 2 μm, the corresponding electrical tuning transmission spectra measured by experiments are shown in Fig. 3B, Fig. 3C and Fig. 3D. The figure shows that with the decrease of g, both the resonant frequency and amplitude in the frequency spectrum have changed, and the resonant frequency in the static state has moved to the low frequency while producing a sharper linear resonance.

图4展示了第四谐振器在第一个谐振谷处的表面电流及电场分布图。电流为环形电流表示该微谐振器具有LC共振模式,电场主要局域在间隙处,强度较强。Fig. 4 shows the surface current and electric field distribution diagram of the fourth resonator at the first resonance valley. The fact that the current is a circular current indicates that the microresonator has an LC resonance mode, and the electric field is mainly localized at the gap with a strong intensity.

值得注意的是,当谐振单元结构中内部间隙尺寸g值减小时,谱线在小电流值下的变化也变得敏感,第四谐振器的太赫兹透过振幅随电流的增大迅速减小。为了更加有力的表明具有尖锐线形共振的微谐振器增大了对调制电流的响应,提取了第二、三及四微谐振器在第一个谐振谷处的共振振幅的调制深度随电流值的变化,如图5所示。结果表明,随着g的减小,LC谐振调制的饱和电流从0.32A下降到0.22A。这说明通过减小谐振单元结构内部间隙尺寸成功增强了太赫兹波对VO2相变过程中电导率变化的响应,提高了频谱曲线线形对小电流调控下的灵敏度,降低了工作电流。It is worth noting that when the value of the internal gap size g in the resonant unit structure decreases, the changes of the spectral lines at small current values also become sensitive, and the terahertz transmission amplitude of the fourth resonator decreases rapidly with the increase of current . In order to show more strongly that the microresonator with sharp linear resonance increases the response to the modulation current, the modulation depth of the resonance amplitude of the second, third and fourth microresonators at the first resonance valley is extracted as a function of the current value changes, as shown in Figure 5. The results show that the saturation current of LC resonance modulation drops from 0.32A to 0.22A with the decrease of g. This shows that by reducing the internal gap size of the resonant unit structure, the response of the terahertz wave to the conductivity change during the phase transition of VO2 has been successfully enhanced, the sensitivity of the spectral curve to the control of small currents has been improved, and the operating current has been reduced.

本发明中,在微谐振器的两侧对称设置电流正极端和电流负极端,通过偏置电流在通过微谐振器时产生的电场来对下方的VO2材料进行加热。微谐振器的结构导致了VO2的相变高度局域和依附于微谐振器的电流丝(electrical current filaments)的分布,这样设计既可以确保偏置电流在流经每个谐振器时产生较为一致的加热效果,又可以利用间隙的不同实现对太赫兹波的共振光谱响应的操控和透过谱谱线的调节。In the present invention, the positive current terminal and the negative current terminal are arranged symmetrically on both sides of the microresonator, and the VO2 material below is heated by the electric field generated when the bias current passes through the microresonator. The structure of the microresonator results in a highly localized phase transition of VO2 and a distribution of electrical current filaments attached to the microresonator, so that the design can ensure that the bias current flows through each resonator to generate relatively The consistent heating effect can be used to control the resonance spectral response of the terahertz wave and adjust the transmission spectral line by using the difference in the gap.

从以上说明可知,本发明在微谐振器的两侧对称设置电流正极端和电流负极端,通过偏置电流在通过微谐振器时产生的电场来对下方的VO2材料进行加热。微谐振器的结构导致了VO2的相变高度局域和依附于微谐振器的电流丝(electrical currentfilaments)的分布,这样设计既可以确保偏置电流在流经每个谐振器时产生较为一致的加热效果,又可以利用间隙的不同实现对太赫兹波的共振光谱响应的操控和透过谱谱线的调节。以下来说明本发明电流调制太赫兹器件相比于现有技术中VO2调控方式的区别和优势:As can be seen from the above description, the present invention symmetrically arranges the current positive terminal and the current negative terminal on both sides of the microresonator, and heats the VO2 material below by the electric field generated when the bias current passes through the microresonator. The structure of the microresonator results in a highly localized phase transition of VO2 and the distribution of electrical current filaments attached to the microresonator. This design can ensure that the bias current is relatively consistent when flowing through each resonator. The heating effect of the terahertz wave can also be realized by using the difference in the gap to control the resonant spectral response of the terahertz wave and adjust the transmission spectral line. The following describes the differences and advantages of the current modulation terahertz device of the present invention compared with the VO2 regulation method in the prior art:

(1)与采用激光照射的调控方式相比,本发明更加有利于和当前集成电路主流技术的融合,同时还避免了激光光源和太赫兹波源之间的干扰。(1) Compared with the control method using laser irradiation, the present invention is more conducive to the integration with the mainstream technology of current integrated circuits, and at the same time avoids the interference between the laser light source and the terahertz wave source.

(2)与采用电压的调控方式相比,本发明采用电流调制方式,实验证明电流调整更为的直接有效,并且电流可以作为额外的调制参数拓展了器件的应用范围。同时更加有利于同当前的集成电路技术相结合。(2) Compared with the voltage regulation method, the present invention adopts the current modulation method, and the experiment proves that the current regulation is more direct and effective, and the current can be used as an additional modulation parameter to expand the application range of the device. At the same time, it is more conducive to the combination with the current integrated circuit technology.

(3)与VO2层和下层材料形成p-n结来对VO2材料进行加热的调制方式相比,本发明利用超材料的金属特性在通电后产生焦耳热,对VO2层进行加热,从而改变VO2材料的电导率,降低太赫兹波透过率,过程更加直接有效,能耗更低,同时降低了对基底材料进行掺杂而对集成电路其他部件所产生的影响。(3) Compared with the modulation method in which the VO 2 layer and the lower layer material form a pn junction to heat the VO 2 material, the present invention uses the metallic properties of the metamaterial to generate Joule heat after electrification, and heats the VO 2 layer, thereby changing The electrical conductivity of the VO 2 material reduces the transmittance of terahertz waves, the process is more direct and effective, and the energy consumption is lower. At the same time, it reduces the impact of doping the base material on other components of the integrated circuit.

(4)与传统的热控制VO2相变的调制方式相比,本发明抛弃了笨重的外加热器,采用灵活的电调控方式,降低了实际操作的复杂性,为集成器件的发展提供了便利。(4) Compared with the traditional modulation method of thermally controlling the phase transition of VO2 , the present invention abandons the bulky external heater and adopts a flexible electric control method, which reduces the complexity of actual operation and provides a great advantage for the development of integrated devices convenient.

(5)与利用VO2粉末仅在裂环开口处形成相变材料区相比,本发明具有如下优势,第一,通过外延生长的方式制作的整片的VO2层,结晶性更高,一致性更好,从而器件的可靠性更高;第二,整体镀膜工艺可控性更好,制作成本较低,更加有利于工业化生产;第三,更加有利于与当前集成电路主流技术相融合。(5) Compared with utilizing VO2 powder to only form the phase change material region at the opening of the split ring, the present invention has the following advantages, first, the whole piece of VO2 layer made by epitaxial growth has higher crystallinity, The consistency is better, so the reliability of the device is higher; second, the overall coating process is more controllable, the production cost is lower, and it is more conducive to industrial production; third, it is more conducive to the integration with the current mainstream integrated circuit technology .

本实施例中四个微谐振器在实验可测的频率范围内(0.25-2.25THz)对应着不同的透过谱线形,基于此开发了将连续的频谱信息转化为数字信息的功能,具体提出了两种应用:太赫兹波主动调制器、信息加密存储器。In this embodiment, the four microresonators correspond to different transmission spectral line shapes in the experimentally measurable frequency range (0.25-2.25THz). Based on this, the function of converting continuous spectral information into digital information is developed. Specifically Two applications are proposed: terahertz wave active modulator, information encryption memory.

二、太赫兹波调制系统2. Terahertz wave modulation system

在本发明的第二个示例性实施例中,提供了一种太赫兹波调制系统。请参照图1A,本实施例太赫兹波调制系统包括:In a second exemplary embodiment of the present invention, a terahertz wave modulation system is provided. Please refer to Figure 1A, the terahertz wave modulation system of this embodiment includes:

如上所述的电流调制太赫兹器件,其作为太赫兹波主动调制器;The current-modulated terahertz device as described above, which acts as an active modulator of terahertz waves;

偏置电流源,其两端连接至所述太赫兹波主动调制器中微谐振器的电流正极端和电流负极端;A bias current source, both ends of which are connected to the current positive terminal and the current negative terminal of the microresonator in the terahertz wave active modulator;

其中,所述偏置电流源向承载编码信息的编码电流加载至所述太赫兹波主动调制器中微谐振器的电流正极端和电流负极端,以调控所述微谐振器的太赫兹波透过率。Wherein, the bias current source loads the coded current carrying coded information to the current positive terminal and the current negative terminal of the micro-resonator in the terahertz wave active modulator, so as to regulate the terahertz wave transmission of the micro-resonator Overrate.

本实施例中,定义(1)当频谱中透过率大于0.3时,输出为数字信号为“1”;(2)当频谱中透过率小于0.3时,输出为数字信号“0”。这样可以将连续频谱以0.25THz为间隔,共用8个二进制编码表示频谱范围内的透过率大小。并参考国际ASCII码,将8个二进制编码组合成相应数字信息。四个微谐振器在不同电流调制状态下的谱线对应的数字信号输出如图6左上角所示。在不加电流时,VO2薄膜处于绝缘状态,此时四个微谐振器的信号转换和输出分别对应从上到下的4条曲线。例如:对于第一微谐振器,透过率在0.5-2.0THz内均超过0.3,所以该频段用6个二进制编码1表示,而其他频段的透过率均小于0.3,所以用0表示,这样整个频段对应的数值信号为“01111110”,参考国际ASCII码输出对应编码信息为符号“~”;图中也分别展示了其他3个微谐振器在静态时的编码信息输出,均实现了从连续频谱信息到数字信息的转化与输出。In this embodiment, it is defined that (1) when the transmittance in the spectrum is greater than 0.3, the output is a digital signal "1"; (2) when the transmittance in the spectrum is less than 0.3, the output is a digital signal "0". In this way, the continuous spectrum can be separated by 0.25THz, and 8 binary codes can be used to represent the transmittance within the spectrum range. And referring to the international ASCII code, 8 binary codes are combined into corresponding digital information. The digital signal outputs corresponding to the spectral lines of the four microresonators under different current modulation states are shown in the upper left corner of Fig. 6 . When no current is applied, the VO2 thin film is in an insulating state, and the signal conversion and output of the four microresonators correspond to the four curves from top to bottom respectively. For example: for the first microresonator, the transmittance exceeds 0.3 within 0.5-2.0THz, so this frequency band is represented by 6 binary codes 1, while the transmittance of other frequency bands is less than 0.3, so it is represented by 0, so The numerical signal corresponding to the entire frequency band is "01111110", and the coded information corresponding to the output of the reference international ASCII code is the symbol "~"; the figure also shows the coded information output of the other three microresonators in static state, all of which realize continuous Conversion and output of spectral information to digital information.

改变施加偏置电流的大小可以改变透过谱线形,从而改变编码输出信息。图6中随着箭头方向的指引,分别展示了升电流至0.34A,以及0.7A致VO2薄膜完全呈金属态,再降低偏置电流至0.34A时四个微谐振器的编码输出信息。可以发现,随着施加电流的变化,同一个微谐振器的输出信息随着透过谱的变化而有所不同。整个电流调制过程中,第一谐振器一共输出两种符号信息,第二谐振器一共输出3种符号信息,而g值较小的第三谐振器和第四谐振器一共输出4种符号信息。在绝缘和金属态下,各微谐振器谱线线形受电流调制影响明显,均输出了不同的编码信息。Changing the magnitude of the applied bias current can change the shape of the transmitted spectrum, thereby changing the coded output information. In Fig. 6, as directed by the direction of the arrow, the encoded output information of the four microresonators when the current is raised to 0.34A and 0.7A until the VO 2 film is completely metallic, and then the bias current is reduced to 0.34A are shown. It can be found that with the change of the applied current, the output information of the same microresonator varies with the change of the transmission spectrum. During the entire current modulation process, the first resonator outputs two types of symbol information, the second resonator outputs three types of symbol information, and the third and fourth resonators with smaller g values output four types of symbol information. In the insulating and metallic states, the spectral line shape of each microresonator is significantly affected by the current modulation, and they all output different coded information.

值得注意的是,电流两次停在0.34A时,微谐振器由于VO2内在迟滞的特性,呈现出不同的编码信息,基于此,开发了电流调制太赫兹器件的任意编码功能。It is worth noting that when the current stops at 0.34A twice, the microresonator presents different encoding information due to the inherent hysteresis of VO 2 . Based on this, the arbitrary encoding function of the current-modulated terahertz device is developed.

本实施例中选择具有单调变化且透过率振幅随电流调制较大的频率处来实现任意编码功能。图7为本发明实施例太赫兹波调制系统实现的透过率的多态特性及多态对应的二进制编码示意图。图7中,首先对四个微谐振器在1.425THz的透过率进行提取,做出其随电流调控的整个过程的变化曲线,对应图中最长的循环曲线。可以看到,不同微谐振器的透过率对施加电流的响应不同,结构设计为谐振器带来了太赫兹电磁响应的差异也使迟滞回线具有可调节性。从上到下,对应着单元结构内部间隙g值的减小,微谐振器的工作电流值向小电流方向移动。同时,找寻了每个微谐振器对应的最大迟滞处的电流值Ih(图7中的垂直虚线),此电流下的透过率差异最大,更利于信号的区分和状态的读取。显然,Ih也随着间隙的减小而降低,间隙减小对应的Ih值分别为0.45、0.34、0.3和0.26A。进一步,为了实现VO2的多态记忆功能,申请人给微谐振器施加具有不同终点电流值的电流循环曲线,实现了对应的3个清晰可见的透过率变化的循环曲线,如图7在每个微谐振器中的3条完整循环曲线表示;在Ih处对应4个不同的透过率大小,将他们定义为VO2的4态,并分别用2-bit编码“00、01、10、11”态以表示。In this embodiment, the arbitrary encoding function is realized by selecting a frequency with a monotonous change and a large transmittance amplitude modulated with the current. FIG. 7 is a schematic diagram of the multi-state characteristics of the transmittance realized by the terahertz wave modulation system and the binary codes corresponding to the multi-states according to the embodiment of the present invention. In Fig. 7, the transmittance of the four microresonators at 1.425THz is first extracted, and the change curve of the whole process of current regulation is drawn, which corresponds to the longest cycle curve in the figure. It can be seen that the transmittance of different microresonators responds differently to the applied current, and the structural design brings the difference in the terahertz electromagnetic response to the resonator and also makes the hysteresis loop adjustable. From top to bottom, corresponding to the decrease of the g value of the internal gap of the unit structure, the working current value of the microresonator moves to the direction of small current. At the same time, the current value I h corresponding to the maximum hysteresis of each microresonator (vertical dotted line in Fig. 7) was found. The transmittance difference under this current is the largest, which is more conducive to signal distinction and state reading. Obviously, I h also decreases with the decrease of the gap, and the I h values corresponding to the decrease of the gap are 0.45, 0.34, 0.3 and 0.26A, respectively. Further, in order to realize the multi-state memory function of VO 2 , the applicant applied current circulation curves with different terminal current values to the microresonator, and realized three corresponding circulation curves with clearly visible transmittance changes, as shown in Figure 7. The three complete circular curves in each microresonator are represented; corresponding to four different transmittances at Ih , they are defined as the four states of VO2 , and are coded with 2-bits "00, 01, 10, 11" states are represented by .

本实施例中,申请人对第四谐振器施加可编程系列脉冲电流以实现对任意编码功能的演示。如图8A所示,Ih值0.26A作为获取透过率状态过程的“读”电流输入,“写”和“擦除”输入是通过施加不同短脉冲电流实现的。“写”输入设置为0.5A,脉冲宽度为4s,“擦除”输入设置为0A,脉冲宽度为10s。首先,若要实现图6中第四谐振器在0A无电流时的二进制编码输出的信息“|”,只需给谐振器施加图8A上图中的可编写脉冲序列,其中“写入”电流编码为0.29-0.5-0.5-0A,就可以得到与图6结果相同的二进制序列“01111100”及其所对应的编码;此外,还可以进行其他序列的任意编码,如图8B,其中写入电流序列为0-0.5-0.35-0A,就可得到图6中的电流降至0.34A时相同的输出信息。值得注意的是,这个器件不仅可以重复图6中自己结构里的全谱固定编码,还可以通过脉冲序列的设计和施加,实现任意2-bit信息编码和传输功能。In this embodiment, the applicant applies a programmable series of pulse currents to the fourth resonator to realize the demonstration of any encoding function. As shown in Figure 8A, the I h value of 0.26A is used as the "read" current input in the process of obtaining the transmittance state, and the "write" and "erase" inputs are realized by applying different short pulse currents. The "write" input is set to 0.5A with a pulse width of 4s, and the "erase" input is set to 0A with a pulse width of 10s. First, to realize the information "|" output by the binary code of the fourth resonator in Figure 6 when there is no current at 0A, it is only necessary to apply the programmable pulse sequence in the upper figure of Figure 8A to the resonator, where the "write" current If the encoding is 0.29-0.5-0.5-0A, the binary sequence "01111100" and its corresponding encoding can be obtained, which is the same as the result in Figure 6; in addition, any encoding of other sequences can be performed, as shown in Figure 8B, where the current The sequence is 0-0.5-0.35-0A, and the same output information can be obtained when the current in Figure 6 drops to 0.34A. It is worth noting that this device can not only repeat the full-spectrum fixed encoding in its own structure in Figure 6, but also realize arbitrary 2-bit information encoding and transmission functions through the design and application of pulse sequences.

本领域技术人员应当理解,对于包含S×T个微谐振器,S≥2,T≥2,的太赫兹波主动调制器而言,对于每一个微谐振器,N×M个谐振单元的结构参数相同;对于不同微谐振器,其内部谐振单元的结构参数不同,且所述偏置电流源可为不同微谐振器提供不同的偏置电流。通过本实施例的方法,就可以提供多种的调制选择。Those skilled in the art should understand that for an active terahertz wave modulator containing S×T microresonators, S≥2, T≥2, for each microresonator, the structure of N×M resonant units The parameters are the same; for different micro-resonators, the structural parameters of the internal resonance units are different, and the bias current source can provide different bias currents for different micro-resonators. Through the method of this embodiment, various modulation options can be provided.

可见,本发明中,基于可擦写特性和不同电致的非挥发性多能级电导态,多个微谐振器阵列均可实现可重写功能,并且可以对输出的二进制编码进行任意组合输出,为光子存储器和太赫兹通信器件的发展提供了令人兴奋的机会。It can be seen that in the present invention, based on the rewritable characteristics and different electro-induced non-volatile multi-level conductance states, multiple microresonator arrays can realize rewritable functions, and can output binary codes in any combination. , providing exciting opportunities for the development of photonic memory and terahertz communication devices.

三、信息加密系统3. Information encryption system

根据本发明的第三个方面,还提供了一种信息加密系统。本发明实施例信息加密系统包括:According to the third aspect of the present invention, an information encryption system is also provided. The information encryption system of the embodiment of the present invention includes:

如上所述的电流调制太赫兹器件,其作为信息加密存储器;所述微谐振器作为信息加密存储器的像素;The current modulation terahertz device as described above is used as an information encryption memory; the micro-resonator is used as a pixel of the information encryption memory;

其中,所述信息加密存储器中微谐振器的结构参数承载加密信息,以特定太赫兹波频率以及加载至所述微谐振器的电流正极端和电流负极端的特定偏置电流作为密钥。优选地,作为密钥的特定太赫兹波频率在所述微谐振器的谐振峰或谐振谷中选择。Wherein, the structural parameters of the micro-resonator in the information encryption memory carry encrypted information, and a specific terahertz wave frequency and a specific bias current loaded to the positive current terminal and the negative current terminal of the micro-resonator are used as keys. Preferably, a specific terahertz wave frequency as a key is selected among resonant peaks or resonant valleys of said microresonator.

对于信息加密存储器而言,其包括:S'×T'个微谐振器,每一微谐振器作为信息加密存储器的一个像素,对于每一个微谐振器,N×M个谐振单元的结构参数相同;对于不同微谐振器,其内部谐振单元的结构参数不同。需要说明的是,此处用S'和T'分别表示信息加密存储器中微谐振器的行数和列数,目的在于与图1A所示电流调制太赫兹器件中,微谐振器的行数S=2和列数T=2,相区别,并无其他含义。For the information encryption memory, it includes: S'×T' micro-resonators, each micro-resonator is used as a pixel of the information encryption memory, and for each micro-resonator, the structural parameters of the N×M resonance units are the same ; For different microresonators, the structural parameters of the internal resonant unit are different. It should be noted that here, S' and T' are used to represent the number of rows and columns of microresonators in the information encryption memory, respectively, in order to compare with the number of rows of microresonators in the current-modulated terahertz device shown in Figure 1A. =2 and the number of columns T=2 are different and have no other meaning.

所述信息加密系统中,预设太赫兹波透过率与色彩的对应关系;所述像素承载的加密信息表现为特定太赫兹波频率和特定偏置电流的条件下,由太赫兹波透过率得到的对应色彩;所述信息加密存储器承载的加密信息表现为由S'×T'个像素的色块排列组合而成的图形,所述图形作为字母、数字和/或符号的表现形式。In the information encryption system, the corresponding relationship between the terahertz wave transmittance and the color is preset; the encrypted information carried by the pixel is represented by the transmission rate of the terahertz wave under the condition of a specific terahertz wave frequency and a specific bias current. The corresponding color obtained at a higher rate; the encrypted information carried by the information encryption memory is presented as a graphic formed by the arrangement and combination of color blocks of S'×T' pixels, and the graphic is a form of expression of letters, numbers and/or symbols.

图9A演示了由四个微谐振器组合而成的信息加密存储器示意图。在图9A所示的中信息加密存储器,利用四个不同间隙尺寸(g)的微谐振器-第一谐振器、第二谐振器、第三谐振器、第四谐振器,的可区分的迟滞特性进行了阵列器件的空间排列设计,拓展了其在太赫兹范围内尚缺乏的动态显示领域的应用。Fig. 9A demonstrates a schematic diagram of an information encryption memory composed of four micro-resonators. In the medium information encryption memory shown in Fig. 9A, using four different gap sizes (g) of the microresonator - the first resonator, the second resonator, the third resonator, the fourth resonator, the distinguishable hysteresis The spatial arrangement design of the array device is carried out, which expands its application in the field of dynamic display that is still lacking in the terahertz range.

在图9A中,每一个方块对应一个像素,即一个微谐振器。数字1、2、3、4分别表示上述第一、二、三、四微谐振器在信息加密存储器中的位置,灰度表示在频率1.425THz处,偏置电流值为从0A上升至0.34A时,各个微谐振器的透过率对应的伪色彩灰度。In FIG. 9A, each square corresponds to a pixel, that is, a microresonator. Numbers 1, 2, 3, and 4 represent the positions of the above-mentioned first, second, third, and fourth microresonators in the information encryption memory respectively, and the gray scale indicates that at a frequency of 1.425THz, the bias current value increases from 0A to 0.34A When , the transmittance of each microresonator corresponds to the pseudo-color grayscale.

本实施例中,色彩表现为伪色彩。加密原理是:利用函数绘图软件Origin中的“Colormap”选项将像素的太赫兹波透过率数值与伪色彩关联,用数值的范围对应颜色的范围,最后用颜色表示出透过率大小,从而将微谐振器在特殊太赫兹频率处的颜色组成字母图形,每个微谐振器作为信息加密存储器的像素单元进行排列,组成的字母图形为加密信息。In this embodiment, the color is displayed as a false color. The encryption principle is: use the "Colormap" option in the function drawing software Origin to associate the terahertz wave transmittance value of the pixel with the pseudo color, use the range of the value to correspond to the range of the color, and finally use the color to express the transmittance, so that The colors of the microresonators at special terahertz frequencies are combined into letter patterns, and each microresonator is arranged as a pixel unit of the information encryption memory, and the composed letter patterns are encrypted information.

在图9A中,S'=16,T'=16。由四个微谐振器组成了16×16个像素的加密信息,即字母“EROI”。值得注意的是,此时的灰度仅为了更清楚地表明加密过程,在真实操作中,该步骤只能看到由16×16个微谐振器组成的器件,并没有灰度显示,但此时字母信息已经完成加密,信息已存在于存储器中。In FIG. 9A, S'=16, T'=16. The encrypted information of 16×16 pixels, the letters “EROI”, is formed by four microresonators. It is worth noting that the grayscale at this time is only to show the encryption process more clearly. In the real operation, only the device composed of 16×16 microresonators can be seen in this step, and there is no grayscale display, but this When the letter information has been encrypted, the information already exists in the memory.

在解密侧,所述信息加密系统还包括:解密模块,用于对信息加密存储器中的各个微谐振器分别施加特定偏置电流,并用太赫兹波照射所述信息加密存储器;色彩解调模块,设置于所述信息加密存储器的光路后端,用于按照预设的太赫兹波在特定频率下的透过率与色彩的对应关系,将信息加密存储器中每一个像素的太赫兹波透过率解密为对应的色彩,并将S'×T',即16×16,个像素的色块排列组合形成图形。On the decryption side, the information encryption system further includes: a decryption module, which is used to respectively apply a specific bias current to each micro-resonator in the information encryption memory, and irradiate the information encryption memory with a terahertz wave; a color demodulation module, It is arranged at the back end of the optical path of the information encryption memory, and is used to convert the terahertz wave transmittance of each pixel in the information encryption memory to Decrypt it into the corresponding color, and arrange and combine the color blocks of S'×T', that is, 16×16 pixels, to form a graphic.

本实施例中,解密模块选择了3个频率,分别是第四谐振器中的LC谐振谷(1.01THz)及其侧两个谐振峰(0.87THz和1.425THz)用于动态显示和解密演示。用伪色彩表示与电流相关的透过率。In this embodiment, the decryption module selects 3 frequencies, which are the LC resonance valley (1.01THz) in the fourth resonator and the two side resonance peaks (0.87THz and 1.425THz) for dynamic display and decryption demonstration. Current-dependent transmittance is represented in pseudo-color.

图9B显示了分别在0.87和1.01THz下的图形显示。当VO2薄膜处于无外加电流的绝缘状态时,四种微谐振器在0.87THz下的透射率近似,色差较小。在1.01THz下,只有第四谐振器由于谐振谷的原因,其透射率非常低,这将导致与其他三个微谐振器相比,在颜色显示上存在巨大的差异。但是,当电流加到0.7A时,可以观察到这两个频率下的图像在深蓝色下几乎相同,因为在金属态下,所有混合微谐振器的透过率都被VO2薄膜显著衰减。由此可见,图9B展示了在不同频率处和不同电流值下的动态成像。但是值得注意的是,因为频率和电流值并非解密的密钥,所以演示的图形均不是加密字母信息“EROI”。可见,只要太赫兹波频率和偏置电流其中一项不符合,就不能解密出加密信息。Figure 9B shows the graphical displays at 0.87 and 1.01 THz, respectively. When the VO2 film is in the insulating state with no applied current, the transmittance of the four microresonators at 0.87THz is similar and the chromatic aberration is small. At 1.01 THz, only the fourth resonator has very low transmittance due to the resonance valley, which will lead to a huge difference in color display compared with the other three microresonators. However, when the current is applied to 0.7 A, it can be observed that the images at these two frequencies are almost the same in dark blue, because in the metallic state, the transmittance of all hybrid microresonators is significantly attenuated by the VO2 film. It can be seen that Fig. 9B shows the dynamic imaging at different frequencies and different current values. But it is worth noting that, because the frequency and current values are not the key to decrypt, the graphics shown are not encrypted letter information "EROI". It can be seen that as long as one of the frequency of the terahertz wave and the bias current does not match, the encrypted information cannot be decrypted.

图9C为以多种的太赫兹波频率和偏置电流作为解密密钥实现信息解密和图像再现的示意图。如图9C所示,演示了该阵列在1.425THz频率下的功能。在0A的初始状态下,四种微谐振器的透过率都是最高的,但相差不大,结果显示为红色(状态Ⅰ),看不到加密的字母图案的信息,无法实现解密。当电流增大到0.34A时,图案与加密的字母信息“EROI”(状态Ⅱ)一致,说明该太赫兹波频率和该偏置电流下,已完成解密过程,成功再现了存储进信息加密存储器中的字母信息,解密成功。为了更加清楚演示偏置电流作为密钥的重要性,施加偏置电流进一步增大到0.7A,发现字母信息隐藏于蓝色背景中(状态Ⅲ),无法完成解密。另外,如果偏置电流作为密钥,施加顺序不对时,也无法完成解密。例如,偏置电流选择从最大电流0.7A开始逐渐减小至0.34A时,虽然电流值相同,但是图形显示与Ⅱ状态下的有很大的不同,显示的是字母信息被转换为红色突出的“FPCL”(状态Ⅳ),解密失败。重要的是,这为利用偏置电流作为解密密钥,利用电流调制太赫兹器件实现信息加密,实现多色动态显示在太赫兹成像中的应用开辟了新的途径。FIG. 9C is a schematic diagram of implementing information decryption and image reproduction using various terahertz wave frequencies and bias currents as decryption keys. As shown in Figure 9C, the functionality of this array at a frequency of 1.425 THz is demonstrated. In the initial state of 0A, the transmittance of the four microresonators is the highest, but the difference is not large, the result is displayed in red (state Ⅰ), and the information of the encrypted letter pattern cannot be seen, and the decryption cannot be realized. When the current increases to 0.34A, the pattern is consistent with the encrypted letter information "EROI" (state II), indicating that under the terahertz wave frequency and the bias current, the decryption process has been completed, and the information stored in the encrypted memory has been successfully reproduced. The letter information in , successfully decrypted. In order to more clearly demonstrate the importance of the bias current as a key, the bias current was further increased to 0.7A, and it was found that the letter information was hidden in the blue background (state III), and the decryption could not be completed. In addition, if the bias current is used as the key, the decryption cannot be completed if the order of application is wrong. For example, when the bias current selection starts from the maximum current of 0.7A and gradually decreases to 0.34A, although the current value is the same, the graphic display is quite different from that in state II, and the displayed information is that the letter information is converted into a red highlighted "FPCL" (state IV), decryption failed. Importantly, this opens up new avenues for using the bias current as a decryption key, using current-modulated terahertz devices to realize information encryption, and realizing multi-color dynamic display in terahertz imaging.

可见,本发明中,利用不同谐振单元结构阵列产生的分离的透射率迟滞回线,进一步在太赫兹频段提供了一种频率可选动态可调彩色图案显示的信息加密系统,利用电流和太赫兹波频率作为解密密钥可以实现信息加密和多图像再现。It can be seen that in the present invention, the separate transmittance hysteresis loops generated by arrays of different resonant unit structures are used to further provide an information encryption system for displaying frequency-selectable and dynamically adjustable color patterns in the terahertz frequency band, using current and terahertz The wave frequency can be used as the decryption key to realize information encryption and multi-image reproduction.

至此,已经结合附图对本发明实施例进行了详细描述。依据以上描述,本领域技术人员应当对本发明有了清楚的认识。So far, the embodiments of the present invention have been described in detail with reference to the accompanying drawings. Based on the above description, those skilled in the art should have a clear understanding of the present invention.

需要说明的是,对于某些实现方式,如果其并非本发明的关键内容,且为所属技术领域中普通技术人员所熟知,则在附图或说明书正文中并未对其进行详细说明,此时可参照相关现有技术进行理解。应当理解的是,提供这些实施例的目的仅是使得本发明满足法律要求,而本发明可以用许多不同形式实现,而不应被解释为限于如上的实施例。It should be noted that, for some implementations, if they are not the key content of the present invention and are well known to those of ordinary skill in the art, they are not described in detail in the accompanying drawings or in the text of the specification. It can be understood with reference to relevant prior art. It should be understood that these examples are provided only to enable the invention to satisfy legal requirements, and the invention can be embodied in many different forms, and should not be construed as being limited to the above examples.

此外,上述对各元件和方法的定义并不仅限于实施例中提到的各种具体结构、形状或方式,本领域普通技术人员可对其进行简单的更改或替换,例如:In addition, the above definitions of each element and method are not limited to the various specific structures, shapes or methods mentioned in the embodiments, and those skilled in the art can easily modify or replace them, for example:

(1)微谐振器中谐振单元结构的尺寸可以做细微调整;(1) The size of the resonant unit structure in the microresonator can be finely adjusted;

(2)谐振单元阵列中各单胞的间距可以根据需要进行设置;(2) The spacing of each unit cell in the resonant unit array can be set as required;

(3)电流调制太赫兹器件中,基底和VO2层的厚度可以细微调整。(3) In current-modulated terahertz devices, the thickness of the substrate and VO2 layer can be finely tuned.

综上所述,本发明提供一种基于VO2和超材料的电流调制太赫兹器件,其通过对谐振单元结构、谐振器的平面布置、调制方式等方面的改进,以增强线形对VO2相变过程中电导率变化的响应,降低电流调制太赫兹器件的工作电流,并开发出太赫兹波调制系统、信息加密系统的应用,为构建具有VO2集成器件的变革平台提供了一种新方法,具有良好的应用前景。In summary, the present invention provides a current-modulated terahertz device based on VO2 and metamaterials, which enhances the linearity of the VO2 phase by improving the structure of the resonant unit, the plane layout of the resonator, and the modulation method. The response to the change of conductivity during the change process, reduce the working current of the current modulation terahertz device, and develop the application of the terahertz wave modulation system and information encryption system, which provides a new method for building a change platform with VO2 integrated devices , has a good application prospect.

还需要说明的是,实施例中提到的方向用语,例如“上”、“下”、“前”、“后”、“左”、“右”、“内”、“外”等,仅是参考附图的方向,并非用来限制本发明的保护范围。贯穿附图,相同的元素由相同或相近的附图标记来表示。并且,图中各部件的形状和尺寸不反映真实大小和比例,而仅示意本发明实施例的内容。另外,在权利要求中,不应将位于括号之间的任何参考符号构造成对权利要求的限制。It should also be noted that the directional terms mentioned in the embodiments, such as "up", "down", "front", "back", "left", "right", "inside", "outside" and so on, only It is the direction of referring to the accompanying drawings, and is not used to limit the protection scope of the present invention. Throughout the drawings, the same elements are indicated by the same or similar reference numerals. Moreover, the shape and size of each component in the figure do not reflect the actual size and proportion, but only illustrate the content of the embodiment of the present invention. Furthermore, in the claims, any reference signs placed between parentheses shall not be construed as limiting the claim.

在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体的连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语的具体含义。In the description of the present invention, it should be noted that unless otherwise specified and limited, the terms "connected" and "connected" should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral It can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediary, and it can be the internal communication of two components. Those of ordinary skill in the art can understand the specific meanings of the above terms according to specific situations.

除非明确指明为相反之意,本发明的说明书及权利要求中的数值参数可以是近似值,能够根据通过本发明的内容改变。具体而言,所有记载于说明书及权利要求中表示组成的含量、反应条件等的数字,应理解为在所有情况中是受到“约”的用语所修饰,其表达的含义是指包含由特定数量在一些实施例中±10%的变化、在一些实施例中±5%的变化、在一些实施例中±1%的变化、在一些实施例中±0.5%的变化。Unless expressly indicated to the contrary, the numerical parameters in the specification and claims of the present invention may be approximations, which can be changed according to the content of the present invention. Specifically, all numbers indicating composition content, reaction conditions, etc. in the specification and claims should be understood as being modified by the word "about" in all cases, and the meaning expressed refers to including In some embodiments a variation of ±10%, in some embodiments a variation of ±5%, in some embodiments a variation of ±1%, in some embodiments a variation of ±0.5%.

再者,单词“包含”不排除存在未列在权利要求中的元件或步骤。位于元件或步骤之前的单词“一”或“一个”不排除存在多个这样的元件或步骤。Furthermore, the word "comprising" does not exclude the presence of elements or steps not listed in a claim. The word "a" or "an" preceding an element or step does not exclude the presence of a plurality of such elements or steps.

说明书与权利要求中所使用的序数例如“第一”、“第二”、“第三”、“主”、“次”,以及阿拉伯数字、字母等,以修饰相应的元件或步骤,其本意仅用来使具有某命名的一个元件(或步骤)得以和另一具有相同命名的元件(或步骤)能做出清楚区分,并不意味着该元件(或步骤)有任何的序数,也不代表某一元件(或步骤)与另一元件(或步骤)的顺序。The ordinal numbers used in the specification and claims, such as "first", "second", "third", "main", "secondary", as well as Arabic numerals, letters, etc., are used to modify corresponding elements or steps. It is only used to clearly distinguish one element (or step) with a certain name from another element (or step) with the same name, it does not mean that the element (or step) has any ordinal number, nor Represents the sequence of an element (or step) with another element (or step).

类似地,应当理解,为了精简本发明并帮助理解各个发明方面中的一个或多个,在上面对本发明的示例性实施例的描述中,本发明的各个特征有时被一起分组到单个实施例、图,或者对其的描述中。然而,并不应将该发明的方法解释成反映如下意图:所要求保护的本发明需要比在每个权利要求中所明确记载的特征更多的特征。更确切地说,如权利要求书所反映的那样,各个发明方面在于少于前面单个实施例的所有特征。因此,遵循具体实施方式的权利要求书由此明确地并入该具体实施方式,其中每个权利要求本身都作为本发明的单独实施例。Similarly, it should be appreciated that in the foregoing description of exemplary embodiments of the invention, in order to streamline the present disclosure and to facilitate an understanding of one or more of the various inventive aspects, various features of the invention are sometimes grouped together in a single embodiment, figure, or in its description. This method of invention, however, is not to be interpreted as reflecting an intention that the claimed invention requires more features than are expressly recited in each claim. Rather, as the following claims reflect, various inventive aspects lie in less than all features of a single foregoing embodiment. Thus, the claims following the Detailed Description are hereby expressly incorporated into this Detailed Description, with each claim standing on its own as a separate embodiment of this invention.

以上所述的具体实施例,对本发明的目的、技术方案和有益效果进行了详细说明,应理解的是,以上所述仅为本发明的具体实施例而已,并不用于限制本发明,凡在本发明的精神和原则之内,所做的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The specific embodiments described above have described the purpose, technical solutions and beneficial effects of the present invention in detail. It should be understood that the above descriptions are only specific embodiments of the present invention, and are not intended to limit the present invention. Within the spirit and principles of the present invention, any modifications, equivalent replacements, improvements, etc., shall be included in the protection scope of the present invention.

Claims (10)

1. VO-based 2 And a metamaterial current-modulated terahertz device, characterized by comprising: a substrate transparent to terahertz waves; VO formed on the substrate 2 A layer; formed at the VO 2 A microresonator on the layer;
the microresonator includes: formed at the VO 2 The layer is used for loading bias current, and a current positive terminal and a current negative terminal which are bilaterally symmetrical; formed at the VO 2 N multiplied by M resonant units are arranged in an array manner, wherein N is more than or equal to 2, and M is more than or equal to 2;
the resonant units are in a split ring structure with LC resonant modes, M resonant units in each row are sequentially connected in series, and two ends of the N rows of resonant units are respectively connected to the current positive terminal and the current negative terminal.
2. The current-modulated terahertz device according to claim 1, characterized in that the resonance unit is symmetrical up and down in a horizontal direction, comprising: a closed loop; a left extension arm and a right extension arm respectively penetrating through the left side and the right side of the closed loop;
The left side of the left extension arm is connected with the current positive end or the right extension arm of the last resonance unit; the right side of the right extension arm is connected with the left extension arm of the next resonance unit or the current negative electrode end; a rectangular opening area is formed between the left extension arm and the right extension arm.
3. The current-modulated terahertz device of claim 2, comprising: formed at the VO 2 S multiplied by T micro resonators arranged in an array manner on the layer, wherein S is more than or equal to 2, and T is more than or equal to 2;
for each microresonator, the structural parameters of n×m resonant cells are the same, and n=m;
the period p of the resonance unit is between 40 and 60 mu m; the closed ring is a closed square ring, and the side length l of the closed square ring is between 30 and 40 mu m; the line width w is between 3 μm and 6 μm; the line width of the left and right extension arms is the same as that of the closed loop; the rectangular opening area has a height h of 5 μm to 15 μm and a width g of 2 μm to 8 μm.
4. The current-modulated terahertz device of claim 3, characterized in that,
the VO is 2 The thickness of the layer is between 5nm and 100 nm; and/or
The bias current loaded by the N rows of resonance units at the inner side is between 0 and 0.7A at the current positive end and the current negative end; and/or
In the thickness direction, the resonance unit includes: formed at VO 2 An adhesive metal layer on the layer; a conductive layer formed on the adhesive metal layer, theThe thickness of the adhesive metal layer is between 5nm and 100nm, the thickness of the conductive metal layer is between 100nm and 300nm, and the adhesive metal layer and the conductive metal layer form the closed ring and the left and right extension arms.
5. The current-modulated terahertz device of claim 4, characterized in that,
in the horizontal direction, the period of the resonance unit is 50 μm; the side length l of the closed ring is 36 mu m, and the line width w is 4 mu m; the height h of the rectangular opening area between the left extension arm and the right extension arm is 10 mu m; and/or
In the vertical direction, the substrate is a sapphire substrate; the VO is 2 The thickness of the layer was 10nm; the viscous metal layer is a chromium film, and the thickness of the viscous metal layer is 20nm; the conductive metal layer is a gold film, and the thickness of the conductive metal layer is 200nm.
6. The current-modulated terahertz device according to claim 1, characterized in that the current-modulated terahertz device functions as a terahertz wave active modulator or an information encryption memory.
7. A terahertz wave modulation system, characterized by comprising:
The current-modulated terahertz device as set forth in any one of claims 1 to 5, which functions as a terahertz-wave active modulator;
a bias current source, two ends of which are connected to a current positive terminal and a current negative terminal of a micro resonator in the terahertz wave active modulator;
the bias current source loads coding current carrying coding information to a current positive end and a current negative end of a micro resonator in the terahertz wave active modulator so as to regulate and control the terahertz wave transmittance of the micro resonator.
8. The terahertz wave modulation system according to claim 7, wherein,
the encoded information carried in the terahertz wave transmittance is 2-bit information encoding; the terahertz wave modulation system is defined as follows: when the transmittance of the terahertz waves is larger than or equal to a transmittance threshold value, carrying a binary code of 1; when the transmittance is smaller than the threshold value, carrying binary code '0'; and/or
The terahertz wave active modulator includes: s multiplied by T micro resonators arranged in an array, wherein S is more than or equal to 2, T is more than or equal to 2, and for each micro resonator, the structural parameters of N multiplied by M resonance units are the same; the structural parameters of the internal resonant cells are different for different microresonators, and the bias current source can provide different bias currents for different microresonators.
9. An information encryption system, comprising:
the current-modulated terahertz device as set forth in any one of claims 1 to 5, which serves as an information encryption memory; the microresonator serves as a pixel of an information encryption memory;
the structural parameters of the micro resonator in the information encryption memory bear encryption information, specific terahertz wave frequency and specific bias currents loaded to the positive end and the negative end of the current of the micro resonator are used as keys, and the specific terahertz wave frequency used as the keys is selected from resonance peaks or resonance valleys of the micro resonator.
10. The information encryption system of claim 9, wherein,
the information encryption memory includes: s multiplied by T micro resonators arranged in an array, wherein S is more than or equal to 2, T is more than or equal to 2, each micro resonator is used as a pixel for forming an information encryption memory, and the structural parameters of N multiplied by M resonance units are the same for each micro resonator; the structural parameters of the internal resonance units of the micro-resonators are different;
in the information encryption system, presetting a corresponding relation between the transmittance of terahertz waves and the color; the encryption information carried by the pixels is represented as corresponding colors obtained by terahertz wave transmittance under the conditions of specific terahertz wave frequency and specific bias current; the encryption information carried by the information encryption memory is represented as a graph formed by arranging and combining color blocks of S multiplied by T pixels, and the graph is taken as a representation form of letters, numbers and/or symbols;
On the decryption side, the information encryption system further includes: a decryption module for applying a specific bias current to each micro resonator in an information encryption memory, respectively, and irradiating the information encryption memory with terahertz waves of a specific frequency; the color demodulation module is arranged at the rear end of the light path of the information encryption memory and is used for decrypting the terahertz wave transmittance of each pixel in the information encryption memory into a corresponding color according to the corresponding relation between the preset terahertz wave transmittance and the color, and arranging and combining color blocks of S multiplied by T pixels to form a graph.
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