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CN116160700A - Pultrusion equipment for fiber reinforced resin profile - Google Patents

Pultrusion equipment for fiber reinforced resin profile Download PDF

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Publication number
CN116160700A
CN116160700A CN202310095758.7A CN202310095758A CN116160700A CN 116160700 A CN116160700 A CN 116160700A CN 202310095758 A CN202310095758 A CN 202310095758A CN 116160700 A CN116160700 A CN 116160700A
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Prior art keywords
reinforced resin
fiber
fiber reinforced
pultrusion
profile
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CN202310095758.7A
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Chinese (zh)
Inventor
刘振
李会涛
蒲紫阳
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Kebosi Luoyang New Material Technology Co
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Kebosi Luoyang New Material Technology Co
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Priority to CN202310095758.7A priority Critical patent/CN116160700A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/525Component parts, details or accessories; Auxiliary operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/525Component parts, details or accessories; Auxiliary operations
    • B29C70/526Pultrusion dies, e.g. dies with moving or rotating parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • B29C70/52Pultrusion, i.e. forming and compressing by continuously pulling through a die
    • B29C70/525Component parts, details or accessories; Auxiliary operations
    • B29C70/528Heating or cooling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

本发明提供了一种纤维增强树脂型材的拉挤成型设备,拉挤成型设备包括:拉挤模具,拉挤模具用于向浸胶纤维施加热量,以将浸胶纤维固化成型为纤维增强树脂型材,拉挤模具包括至少两个加热段;挤压组件,挤压组件位于至少两个加热段之间,挤压组件设有纹路;其中,挤压组件用于向预成型的纤维增强树脂型材施加压力,以将纹路印制于纤维增强树脂型材的至少部分表面。本发明提供的拉挤成型设备在连续拉挤工艺的过程中可以实现对纤维增强树脂型材的表面处理,增加纤维增强树脂型材的表面粗糙度,减少辅助材料的使用,减少处理工序,提高生产效率,并降低生产成本。

Figure 202310095758

The invention provides a pultrusion molding equipment for fiber reinforced resin profiles. The pultrusion molding equipment includes: a pultrusion die, and the pultrusion mold is used to apply heat to the dipped fiber, so as to solidify and shape the dipped fiber into a fiber reinforced resin profile , the pultrusion die includes at least two heating sections; an extrusion assembly, the extrusion assembly is located between the at least two heating sections, and the extrusion assembly is provided with lines; wherein, the extrusion assembly is used to apply to the preformed fiber reinforced resin profile pressure to print the texture on at least part of the surface of the fiber reinforced resin profile. The pultrusion molding equipment provided by the present invention can realize the surface treatment of fiber-reinforced resin profiles during the continuous pultrusion process, increase the surface roughness of fiber-reinforced resin profiles, reduce the use of auxiliary materials, reduce processing procedures, and improve production efficiency , and reduce production costs.

Figure 202310095758

Description

一种纤维增强树脂型材的拉挤成型设备A kind of pultrusion molding equipment of fiber-reinforced resin profiles

技术领域technical field

本发明涉及纤维增强树脂型材加工制造的技术领域,具体而言,涉及一种纤维增强树脂型材的拉挤成型设备。The invention relates to the technical field of processing and manufacturing fiber-reinforced resin profiles, in particular to a pultrusion molding equipment for fiber-reinforced resin profiles.

背景技术Background technique

纤维增强树脂型材在轨道交通、建筑建材、家居家装等多个领域均具有广泛的应用前景。比如,从前铁路线路使用的轨枕主要是预应力钢筋混凝土轨枕和木枕。但制作木枕需要优质的硬质木材,优质木材资源有限,这不利于生态环境的可持续性。同时为了木枕的耐腐蚀性来延长使用寿命,在木枕制作过程中使用化学防腐剂,这也会对环境和工人的健康带来了隐患。针对目前常用预应力钢筋混凝土轨枕和木枕所具有的缺陷,以及复合材料技术的不断发展。纤维增强树脂的复合材料成为了一种很好的取代材料。纤维增强树脂的复合材料具有与天然木材相似的结构,并且不易腐烂,性能优异,可以作为轨道交通设施、建筑装饰材料代替木材。拉挤成型是热固性纤维增强树脂型材的成型方法之一,其具有简单、高效的特点,适用于断面形状固定不变的型材生产。对于纤维增强树脂型材而言,在部分应用场景中,需要纤维增强树脂型材的表面具备一定的粗糙度。相关技术中通常采用例如打磨的后处理,来增加纤维增强树脂型材的表面粗糙度。其存在的技术问题是:工艺繁琐,加工效率较低。Fiber-reinforced resin profiles have broad application prospects in many fields such as rail transit, building materials, and home decoration. For example, the sleepers used in the former railway lines were mainly prestressed reinforced concrete sleepers and wooden sleepers. But high-quality hard wood is needed to make wooden sleepers, and high-quality wood resources are limited, which is not conducive to the sustainability of the ecological environment. Simultaneously, in order to prolong the service life for the corrosion resistance of wooden sleepers, chemical preservatives are used in the production process of wooden sleepers, which will also bring hidden dangers to the environment and the health of workers. In view of the defects of commonly used prestressed reinforced concrete sleepers and wooden sleepers, and the continuous development of composite material technology. Fiber-reinforced resin composites are a good alternative. Fiber-reinforced resin composites have a structure similar to natural wood, are not perishable, and have excellent performance. They can be used as rail transit facilities and building decoration materials to replace wood. Pultrusion molding is one of the molding methods of thermosetting fiber-reinforced resin profiles. It is simple and efficient, and is suitable for the production of profiles with constant cross-sectional shapes. For fiber-reinforced resin profiles, in some application scenarios, the surface of the fiber-reinforced resin profiles needs to have a certain roughness. In the related art, post-processing such as grinding is generally used to increase the surface roughness of the fiber reinforced resin profile. The existing technical problems are: the process is cumbersome and the processing efficiency is low.

发明内容Contents of the invention

本发明解决的问题是如何以简单高效的工艺,提高纤维增强树脂型材的表面粗糙度。The problem solved by the invention is how to improve the surface roughness of the fiber-reinforced resin profile with a simple and efficient process.

为解决上述问题,本发明提供一种纤维增强树脂型材的拉挤成型设备。拉挤成型设备包括:拉挤模具,拉挤模具用于向浸胶纤维施加热量,以将浸胶纤维固化成型为纤维增强树脂型材,拉挤模具包括至少两个加热段;挤压组件,挤压组件位于至少两个加热段之间,挤压组件设有纹路;其中,挤压组件用于向预成型的纤维增强树脂型材施加压力,以将纹路印制于纤维增强树脂型材的至少部分表面。In order to solve the above problems, the present invention provides a pultrusion molding equipment for fiber-reinforced resin profiles. The pultrusion molding equipment includes: a pultrusion die, the pultrusion die is used to apply heat to the dipped fibers to solidify the dipped fibers into a fiber reinforced resin profile, the pultrusion die includes at least two heating sections; The pressing assembly is located between at least two heating sections, and the extrusion assembly is provided with textures; wherein, the extrusion assembly is used to apply pressure to the preformed fiber-reinforced resin profile, so as to print the texture on at least part of the surface of the fiber-reinforced resin profile .

在上述任一技术方案中,至少两个加热段包括依次设置的预热段、固化段和离型段;其中,挤压组件位于预热段和固化段之间。In any of the above technical solutions, the at least two heating sections include a preheating section, a curing section and a release section arranged in sequence; wherein, the extrusion assembly is located between the preheating section and the curing section.

在上述任一技术方案中,至少两个加热段包括依次设置的预热段、固化段和离型段;其中,挤压组件位于固化段和离型段之间。In any of the above technical solutions, at least two heating sections include a preheating section, a curing section, and a release section arranged in sequence; wherein, the extruding assembly is located between the curing section and the release section.

在上述任一技术方案中,挤压组件包括:第一挤压件,第一挤压件设于纤维增强树脂型材的任一侧;第二挤压件,第二挤压件设于纤维增强树脂型材相对于任一侧的另一侧;其中,第一挤压件和第二挤压件中的至少一者设有纹路。In any of the above technical solutions, the extruded assembly includes: a first extruded part, which is arranged on either side of the fiber-reinforced resin profile; a second extruded part, which is arranged on the fiber-reinforced resin profile; The opposite side of either side of the resin profile; wherein at least one of the first extrusion and the second extrusion is textured.

在上述任一技术方案中,挤压组件包括:第一履带,第一履带设于纤维增强树脂型材的上侧;第二履带,第二履带设于纤维增强树脂型材的下侧;其中,第一履带和第二履带中的至少一者设有纹路,第一履带沿逆时针滚动,第二履带沿顺时针滚动。In any of the above technical solutions, the extrusion assembly includes: a first crawler, the first crawler is arranged on the upper side of the fiber-reinforced resin profile; a second crawler, the second crawler is arranged on the lower side of the fiber-reinforced resin profile; wherein, the first At least one of the first track and the second track is provided with textures, the first track rolls counterclockwise, and the second track rolls clockwise.

在上述任一技术方案中,挤压组件包括:第一滚筒,第一滚筒设于纤维增强树脂型材的上侧;第二滚筒,第二滚筒设于纤维增强树脂型材的下侧;其中,第一滚筒和第二滚筒中的至少一者设有纹路,第一滚筒沿逆时针滚动,第二滚筒沿顺时针滚动。In any of the above technical solutions, the extruding assembly includes: a first roller, the first roller is arranged on the upper side of the fiber-reinforced resin profile; a second roller, and the second roller is arranged on the lower side of the fiber-reinforced resin profile; wherein, the first At least one of the first roller and the second roller is provided with textures, the first roller rolls counterclockwise, and the second roller rolls clockwise.

在上述任一技术方案中,挤压组件包括:第一往复移动机构,第一往复移动机构设于纤维增强树脂型材的上侧;其中,第一往复移动机构向下移动,以靠近纤维增强树脂型材,并向纤维增强树脂型材施加压力,第一往复移动机构向上移动,以远离纤维增强树脂型材。In any of the above technical solutions, the extruding assembly includes: a first reciprocating mechanism, the first reciprocating mechanism is arranged on the upper side of the fiber-reinforced resin profile; wherein, the first reciprocating mechanism moves downward to approach the fiber-reinforced resin profile, and applying pressure to the fiber-reinforced resin profile, the first reciprocating mechanism moves upward to move away from the fiber-reinforced resin profile.

在上述任一技术方案中,挤压组件还包括:第二往复移动机构,第二往复移动机构设于纤维增强树脂型材的下侧;其中,第二往复移动机构向上移动,以靠近纤维增强树脂型材,并向纤维增强树脂型材施加压力,二往复移动机构向下移动,以远离纤维增强树脂型材。In any of the above technical solutions, the extrusion assembly further includes: a second reciprocating mechanism, the second reciprocating mechanism is arranged on the lower side of the fiber-reinforced resin profile; wherein, the second reciprocating mechanism moves upwards to approach the fiber-reinforced resin profile, and apply pressure to the fiber-reinforced resin profile, and the two reciprocating mechanisms move downward to keep away from the fiber-reinforced resin profile.

在上述任一技术方案中,纹路为以下至少之一或其组合:条形纹路、圆点形纹路、多边形纹路。In any of the above technical solutions, the texture is at least one of the following or a combination thereof: striped texture, dot-shaped texture, polygonal texture.

在上述任一技术方案中,拉挤成型设备还包括:压力传感器,压力传感器设于挤压组件,并用于检测挤压组件向纤维增强树脂型材施加的压力。In any of the above technical solutions, the pultrusion molding equipment further includes: a pressure sensor, which is arranged on the extrusion component and used to detect the pressure exerted by the extrusion component on the fiber reinforced resin profile.

在上述技术方案中,拉挤成型设备还包括:纤维引导组件,纤维引导组件与拉挤模具相邻设置;其中,纤维引导组件用于将浸胶纤维引导送入拉挤模具。In the above technical solution, the pultrusion molding equipment further includes: a fiber guide assembly arranged adjacent to the pultrusion die; wherein the fiber guide assembly is used to guide and send the dipped fiber into the pultrusion die.

在上述任一技术方案中,拉挤成型设备还包括:型材牵引组件,型材牵引组件设于拉挤模具远离纤维引导组件的一端;其中,型材牵引组件用于牵引纤维增强树脂型材离开拉挤模具。In any of the above technical solutions, the pultrusion molding equipment further includes: a profile pulling assembly, the profile pulling assembly is arranged at the end of the pultrusion die away from the fiber guiding assembly; wherein, the profile pulling assembly is used to pull the fiber-reinforced resin profile away from the pultrusion die .

在上述任一技术方案中,拉挤成型设备还包括:锯切组件,锯切组件设于型材牵引组件远离拉挤模具的一端;其中,锯切组件用于将纤维增强树脂型分段锯切。In any of the above technical solutions, the pultrusion molding equipment further includes: a sawing assembly, which is arranged at the end of the profile traction assembly away from the pultrusion die; wherein, the sawing assembly is used to saw the fiber-reinforced resin type .

有益效果Beneficial effect

本发明提供的拉挤成型设备在连续拉挤工艺的过程中可以实现对纤维增强树脂型材的表面处理,增加纤维增强树脂型材的表面粗糙度,由此可以省略后期的打磨处理。此外,本发明还能够避免因打磨而产生粉尘,改善作业环境。最后,本发明还可以避免脱模布的使用。最终,本发明提供的拉挤成型设备可以在不进行打磨且不采用脱模布的情况下,提高拉挤制品的表面粗糙度,减少辅助材料的使用,减少处理工序,提高生产效率,并降低生产成本。The pultrusion molding equipment provided by the present invention can realize the surface treatment of the fiber-reinforced resin profiles during the continuous pultrusion process, increase the surface roughness of the fiber-reinforced resin profiles, and thus can omit the later grinding treatment. In addition, the present invention can also avoid the generation of dust due to grinding and improve the working environment. Finally, the invention also avoids the use of release cloths. Finally, the pultrusion molding equipment provided by the present invention can improve the surface roughness of pultrusion products without grinding and without using release cloth, reduce the use of auxiliary materials, reduce processing procedures, improve production efficiency, and reduce Cost of production.

附图说明Description of drawings

图1为相关技术中纤维增强树脂型材的拉挤成型设备的结构示意图;Fig. 1 is the structural representation of the pultrusion molding equipment of fiber-reinforced resin profiles in the related art;

图2为本发明的纤维增强树脂型材的拉挤成型设备的结构示意图;Fig. 2 is the structural representation of the pultrusion molding equipment of the fiber-reinforced resin profile of the present invention;

图3为本发明的挤压组件的纹路示意图之一;Fig. 3 is one of the texture schematic diagrams of the extrusion assembly of the present invention;

图4为本发明的挤压组件的纹路示意图之二;Fig. 4 is the second schematic diagram of the texture of the extruded assembly of the present invention;

图5为相关技术中纤维增强树脂型材的表观示意图;Fig. 5 is a schematic diagram of the appearance of a fiber-reinforced resin profile in the related art;

图6为本发明的拉挤成型设备获得的纤维增强树脂型材的表观示意图。Fig. 6 is a schematic view of the appearance of a fiber-reinforced resin profile obtained by the pultrusion molding equipment of the present invention.

图1和图5中附图标记说明:Explanation of reference numerals among Fig. 1 and Fig. 5:

拉挤成型设备:100’;拉挤模具:110’;预热段:111’;固化段:112’;离型段:113’;纤维引导组件:130’;型材牵引组件:140’;锯切组件:150’;纤维增强树脂型材:200’。Pultrusion equipment: 100'; Pultrusion die: 110'; Preheating section: 111'; Curing section: 112'; Release section: 113'; Cut components: 150'; fiber reinforced resin profiles: 200'.

图2-4和图6中附图标记说明:Explanation of reference numerals among Fig. 2-4 and Fig. 6:

拉挤成型设备:100;拉挤模具:110;预热段:111;固化段:112;离型段:113;挤压组件:120;第一挤压件:121;第二挤压件:122;纤维引导组件:130;型材牵引组件:140;锯切组件:150;压力传感器:160;纤维增强树脂型材:200。Pultrusion molding equipment: 100; pultrusion die: 110; preheating section: 111; curing section: 112; release section: 113; extrusion components: 120; first extrusion: 121; second extrusion: 122; fiber guide assembly: 130; profile pulling assembly: 140; sawing assembly: 150; pressure sensor: 160; fiber reinforced resin profile: 200.

具体实施方式Detailed ways

为使本发明的上述目的、特征和优点能够更为明显易懂,下面结合附图对本发明的具体实施例做详细的说明。In order to make the above objects, features and advantages of the present invention more comprehensible, specific embodiments of the present invention will be described in detail below in conjunction with the accompanying drawings.

如图1所示,相关技术中拉挤成型设备100’采用的典型拉挤成型工艺主要由送纱、浸胶、预成型、固化成型、牵引和切割等工序组成,其工艺流程一般为,将纤维(纱束)从放置架上引出,经过集束进入胶槽浸胶,然后由纤维引导组件130’牵伸进入预成型模具,挤出多余的树脂并在压实过程中排除气泡,再进入拉挤模具110’,由此,带有树脂的纤维在拉挤模具110’中固化成型,再由型材牵引组件140’拉出,最后由锯切组件150’切割成所需长度的纤维增强树脂型材200’。As shown in Figure 1, the typical pultrusion process used by the pultrusion equipment 100' in the related art is mainly composed of processes such as yarn feeding, dipping, preforming, curing molding, pulling and cutting, and the process flow is generally as follows: The fibers (yarn bundles) are drawn out from the placing frame, and enter the glue tank for dipping through clustering, and then are drawn into the preforming mold by the fiber guide assembly 130', extrude excess resin and remove air bubbles during the compaction process, and then enter the drawing Extrusion die 110', whereby the fibers with resin are solidified in the pultrusion die 110', then pulled out by the profile pulling assembly 140', and finally cut into fiber-reinforced resin profiles of required length by the sawing assembly 150' 200'.

为使纤维增强树脂型材200’具有优质的表面及所需的理化性能,以达到在一定牵引速率下进行连续性生产的基本要求,基于树脂固化工艺特点,相关技术中的拉挤成型设备100’一般将拉挤模具110’的加热温度分为预热段111’、固化段112’和离型段113’三个区间。In order to make the fiber-reinforced resin profile 200' have a high-quality surface and the required physical and chemical properties, so as to meet the basic requirements for continuous production at a certain pulling rate, based on the characteristics of the resin curing process, the pultrusion molding equipment 100' in the related art Generally, the heating temperature of the pultrusion die 110' is divided into three sections: a preheating section 111', a curing section 112' and a release section 113'.

浸渍树脂的纤维在进入拉挤模具110’的预热段111’后,树脂在温度作用下均匀化,使后续的固化更加完全。同时浸渍树脂的纤维因热胀而产生液压,使之紧贴于拉挤模具110’的型腔表面,使得纤维增强树脂型材200’的表面粗糙度降低。After the resin-impregnated fiber enters the preheating section 111' of the pultrusion die 110', the resin is homogenized under the action of temperature, so that the subsequent curing is more complete. At the same time, the fiber impregnated with resin generates hydraulic pressure due to thermal expansion, making it close to the surface of the cavity of the pultrusion die 110', so that the surface roughness of the fiber reinforced resin profile 200' is reduced.

经过预热段111’并进入固化段112’后,在此加热温度下纤维树脂迅速固化成具有一定力学性能的型材。然后,在进入离型段113’后固化放热出现不同程度的体积收缩,而使纤维增强树脂型材200’与模具表面分开,摩擦力下降,并在型材牵引组件140’的作用下出模。After passing through the preheating section 111' and entering the curing section 112', the fiber resin is rapidly solidified at this heating temperature into a profile with certain mechanical properties. Then, after entering the release section 113', different degrees of volume shrinkage occur during curing exotherm, so that the fiber-reinforced resin profile 200' is separated from the mold surface, the friction force is reduced, and the mold is ejected under the action of the profile traction assembly 140'.

因此,如图5所示,在相关技术中,拉挤成型的纤维增强树脂型材200’其表面平整光滑,无法满足表面粗糙度高、不规整的需求。特别的对于有层间灌注粘接的板材,为提高层间结合性能,在灌注或粘接前还需要表面打磨粗糙或通过成型过程中在纤维增强树脂型材200’表面引入辅助材料。例如,在纤维增强树脂型材200’的板材表面包覆脱模布,该材料揭掉后可以在板材表面形成一定形状的纹路,增加其表面的粗糙度。再例如,对于有防滑需求的板材,一般还需要在其表面刷漆同时铺一些小粒径的石子颗粒等,以增加其表面粗糙度达到防滑的目的。但是,以上方法都额外增加了产品应用工序以及成本。Therefore, as shown in FIG. 5 , in the related art, the surface of the pultruded fiber-reinforced resin profile 200' is flat and smooth, which cannot meet the requirements of high surface roughness and irregularity. Especially for plates with interlayer bonding, in order to improve interlayer bonding performance, it is necessary to roughen the surface or introduce auxiliary materials on the surface of the fiber-reinforced resin profile 200' during the molding process before pouring or bonding. For example, the release cloth is coated on the surface of the fiber-reinforced resin profile 200', and after the material is peeled off, it can form textures of a certain shape on the surface of the plate to increase the roughness of the surface. For another example, for boards with anti-slip requirements, it is generally necessary to paint the surface and spread some small-sized stone particles to increase the surface roughness to achieve the purpose of anti-slip. However, the above methods all additionally increase the product application process and cost.

因此,为提高拉挤成型工艺生产制品的应用空间,降低成本,结合拉挤成型工艺的技术特点以及发明人的技术经验,本发明提供了一种纤维增强树脂型材的拉挤成型设备100。Therefore, in order to increase the application space of products produced by the pultrusion process and reduce costs, combined with the technical characteristics of the pultrusion process and the inventor's technical experience, the present invention provides a pultrusion device 100 for fiber-reinforced resin profiles.

如图2所示,该拉挤成型设备100包括:纤维引导组件130、拉挤模具110、型材牵引组件140和锯切组件150。As shown in FIG. 2 , the pultrusion molding equipment 100 includes: a fiber guide assembly 130 , a pultrusion die 110 , a profile pulling assembly 140 and a sawing assembly 150 .

其中,纤维引导组件130具体可以包括定张力纱架和导纱引纱装置,其作用是用于将浸胶纤维引导送入拉挤模具110。具体而言,以玻纤纱作为增强纤维为例,可以将玻纤纱从定张力纤维纱架上抽出,经过导纱引纱装置将纱束牵引至拉挤模具110的入口处。Wherein, the fiber guide assembly 130 may specifically include a constant tension creel and a yarn guiding device, which are used to guide and send the dipped fiber into the pultrusion die 110 . Specifically, taking glass fiber yarn as a reinforcing fiber as an example, the glass fiber yarn can be pulled out from the constant tension fiber creel, and the yarn bundle can be pulled to the entrance of the pultrusion die 110 through the yarn guiding device.

可以理解,在将纤维引导送入拉挤模具110之前,需要将其浸没于树脂中,进行浸胶处理。本实施例中的纤维可以是玻璃纤维,也可以是纺织纤维,或其他纤维。本实施例中的树脂的种类和配方可由本领域技术人员根据实际需要进行选择和调整。It can be understood that before the fibers are guided into the pultrusion die 110, they need to be immersed in resin for impregnation treatment. The fibers in this embodiment can be glass fibers, textile fibers, or other fibers. The types and formulations of the resins in this embodiment can be selected and adjusted by those skilled in the art according to actual needs.

纤维引导组件130与拉挤模具110相邻设置,拉挤模具110用于向浸胶纤维施加热量,以将浸胶纤维固化成型为纤维增强树脂型材。拉挤模具110可以通过机械连接的方式被固定,也可以单独设置。The fiber guide assembly 130 is disposed adjacent to the pultrusion die 110 for applying heat to the dipped fibers to solidify and shape the dipped fibers into a fiber reinforced resin profile. The pultrusion die 110 can be fixed by means of mechanical connection, or can be set separately.

拉挤模具110为了实现上述的加热成型目的,拉挤模具110包括至少两个加热段。示例性地,至少两个加热段包括依次设置的预热段111、固化段112和离型段113。其中,拉挤模具110可以为分段式结构。比如,预热段111与固化段112、离型段113分开,或离型段113与预热段111、固化段112分开。也可以是单独的预热段111,或单独的预热段111与固化段112。还可以将固化段112设置为单独的热固箱或热固炉。Pultrusion die 110 In order to achieve the above-mentioned purpose of thermoforming, the pultrusion die 110 includes at least two heating sections. Exemplarily, at least two heating sections include a preheating section 111 , a curing section 112 and a release section 113 arranged in sequence. Wherein, the pultrusion die 110 may be a segmented structure. For example, the preheating section 111 is separated from the curing section 112 and the release section 113 , or the release section 113 is separated from the preheating section 111 and the curing section 112 . It can also be a separate preheating section 111 , or a separate preheating section 111 and curing section 112 . It is also possible to configure the curing section 112 as a separate thermosetting box or thermosetting oven.

型材牵引组件140设于拉挤模具120远离纤维引导组件130的一端,型材牵引组件140用于牵引纤维增强树脂型材离开拉挤模具110。型材牵引组件140可以调节拉挤成型的速度。The profile pulling assembly 140 is located at the end of the pultrusion die 120 away from the fiber guiding assembly 130 , and the profile pulling assembly 140 is used to pull the fiber reinforced resin profile away from the pultrusion die 110 . The profile pulling assembly 140 can adjust the speed of pultrusion.

锯切组件150设于型材牵引组件140远离拉挤模具110的一端,锯切组件150用于将纤维增强树脂型分段锯切,最终获得如图2右侧所示的纤维增强树脂型材200的成品。示例性地,锯切组件150可以包括刀头,其通过上下往复移动,带动刀头上下移动,以此完成对纤维增强树脂型材的分段锯切。The sawing assembly 150 is arranged at the end of the profile traction assembly 140 away from the pultrusion die 110, and the sawing assembly 150 is used for sawing the fiber-reinforced resin type into segments, and finally obtains the fiber-reinforced resin profile 200 as shown on the right side of FIG. 2 finished product. Exemplarily, the sawing assembly 150 may include a cutter head, which drives the cutter head to move up and down by reciprocating up and down, so as to complete segmental sawing of the fiber-reinforced resin profiles.

示例性地,本实施例的纤维增强合成轨枕的制备方法具体包括以下步骤:S1、导纱,将纤维导入注胶盒;S2、浸渍,向所述注胶盒中注入树脂基体,使得纤维在树脂基体中进行浸渍;S3、成型处理,对内部和/或表面分布有纤维的树脂基体进行挤压成型、牵引、冷却和切割,获得纤维增强树脂型材。Exemplarily, the preparation method of the fiber-reinforced synthetic sleeper in this embodiment specifically includes the following steps: S1, guide the yarn, introduce the fiber into the injection box; S2, impregnate, inject the resin matrix into the injection box, so that the fiber is Impregnation in the resin matrix; S3, forming treatment, extruding, pulling, cooling and cutting the resin matrix with fibers distributed inside and/or on the surface to obtain fiber-reinforced resin profiles.

其中,步骤S1的导纱是指,将至少一种的纤维通过导纱装置引导至注胶盒1中。纤维可以是1000tex~9000tex的任一种或几种纤维无捻粗纱,也可扩展为合股纱。导纱装置有效提高了纤维在树脂中的分布均匀程度,提高了产品性能的均一性。步骤S2的浸渍是指将树脂基体混合均匀后注入注胶盒,使纤维材料浸渍于树脂基体中。树脂基体可以是包括异氰酸酯和多元醇混合物的双组份发泡聚氨酯。步骤S3的成型处理是指,通过送料装置将带有纤维的树脂基体(组合体)送至拉挤模具110中挤压成型并固化,固化温度范围可以为100℃~220℃,完成固化成型过程后,通过型材牵引组件140将产品拉至拉挤模具110的外部,进行冷却和切割。上述步骤中纤维可以为连续增强纤维和/或纤维织物3的至少一种。连续增强纤维的材料选自玻璃纤维、碳纤维、芳纶纤维、超高分子量聚乙烯纤维中的任意一种或几种的组合。纤维织物为编织布、无纺布、三维织物中的任意一种或几种的组合。Wherein, the yarn guiding in step S1 refers to guiding at least one type of fiber into the injection box 1 through the yarn guiding device. The fiber can be any one or several fiber rovings of 1000tex to 9000tex, and can also be expanded into ply yarn. The yarn guide device effectively improves the uniformity of fiber distribution in the resin and improves the uniformity of product performance. The impregnation in step S2 refers to mixing the resin matrix evenly and pouring it into the injection box, so that the fiber material is impregnated in the resin matrix. The resin matrix may be a two-component foamed polyurethane comprising a mixture of isocyanate and polyol. The molding process in step S3 refers to sending the resin matrix (assembly) with fibers to the pultrusion die 110 for extrusion molding and curing through the feeding device. The curing temperature range can be 100°C to 220°C to complete the curing molding process Finally, the product is pulled to the outside of the pultrusion die 110 by the profile pulling assembly 140 for cooling and cutting. The fibers in the above steps may be at least one of continuous reinforcing fibers and/or fiber fabrics 3 . The material of the continuous reinforcing fiber is selected from any one or combination of glass fiber, carbon fiber, aramid fiber and ultra-high molecular weight polyethylene fiber. The fiber fabric is any one or a combination of woven fabrics, non-woven fabrics, and three-dimensional fabrics.

拉挤模具110中设有挤压组件120,挤压组件120位于至少两个加热段之间。优选地,挤压组件120位于预热段111和固化段112之间。挤压组件120设有纹路,该纹路可以为凹印纹路,也可以为凸印纹路。An extrusion assembly 120 is disposed in the pultrusion die 110, and the extrusion assembly 120 is located between at least two heating sections. Preferably, the extrusion assembly 120 is located between the preheating section 111 and the curing section 112 . The extruded component 120 is provided with textures, which may be intaglio or embossed.

可以理解,在本发明中,挤压组件120用于向预成型的纤维增强树脂型材施加压力,以将纹路印制于纤维增强树脂型材的至少部分表面。It can be understood that, in the present invention, the extrusion component 120 is used to apply pressure to the preformed fiber-reinforced resin profile, so as to print the texture on at least part of the surface of the fiber-reinforced resin profile.

具体而言,挤压组件120可以为液压结构或气压机构,挤压组件120在压力作用下实现向预热后的纤维增强树脂型材的表面的挤压运动,其表面的凹凸结构在压力作用下在纤维增强树脂型材表面形成纹路。挤压组件120的材质可以为金属材料、陶瓷材料、玻璃、高分子材料等。Specifically, the extrusion assembly 120 can be a hydraulic structure or a pneumatic mechanism. The extrusion assembly 120 realizes the extrusion movement to the surface of the preheated fiber-reinforced resin profile under the action of pressure, and the concave-convex structure of the surface is under the action of pressure. Textures are formed on the surface of fiber-reinforced resin profiles. The extrusion component 120 can be made of metal material, ceramic material, glass, polymer material and so on.

示例性地,该纹路可以纹路为以下至少之一或其组合:条形纹路、圆点形纹路、多边形纹路。条形纹路包括直条形纹路,或水波纹形纹路。多条的条形纹路之间可相互平行,也可相互交叉。圆点形纹路包括点状纹路,或圆形纹路,或椭圆形纹路。多边形纹路包括菱形纹路,或三角形纹路,或矩形纹路,或五边形以上的多边形纹路。Exemplarily, the texture may be at least one of the following textures or a combination thereof: striped textures, dot-shaped textures, and polygonal textures. Striped textures include straight striped textures or water rippled textures. The multiple stripes can be parallel to each other or cross each other. The dot-shaped texture includes dot-shaped texture, or circular texture, or elliptical texture. Polygonal textures include rhombus textures, or triangular textures, or rectangular textures, or polygonal textures with more than pentagons.

在一个示例中,如图3所示,该纹路可以为以矩阵形式有序排列的多个凸点或凸包状纹路。在另一个示例中,如图4所示,该纹路可以为多条间隔布置的条形纹路。在再一个示例中,该纹路可以为无序排列的任一不规则形状的纹路。In one example, as shown in FIG. 3 , the texture may be a plurality of raised dots or convex hull-shaped textures arranged in a matrix order. In another example, as shown in FIG. 4 , the texture may be a plurality of striped textures arranged at intervals. In yet another example, the texture may be any irregularly shaped texture that is arranged randomly.

本发明采用的成型方法为将浸渍树脂的纤维(以下简称“组合体”)先经过拉挤模具110的预热段111,此时组合体刚开始固化,其硬度较小,可以便于采用挤压组件120实现对其表面进行处理。挤压组件120的表面印刻一定形状、尺寸规格的纹路。完成纹路印制后的纤维增强树脂型材再经由拉挤模具110的固化段112进一步固化成型,并在型材牵引组件140的作用下拉出,得到表面具有纹路的纤维增强树脂型材。The molding method adopted in the present invention is to pass the fiber impregnated with resin (hereinafter referred to as "combination") first through the preheating section 111 of the pultrusion die 110. Component 120 enables the treatment of its surface. The surface of the extrusion component 120 is imprinted with textures of a certain shape and size. The fiber-reinforced resin profile after the pattern printing is further solidified and formed through the curing section 112 of the pultrusion die 110 , and pulled out under the action of the profile pulling assembly 140 to obtain a fiber-reinforced resin profile with texture on the surface.

挤压组件120包括:第一挤压件121,第一挤压件121设于纤维增强树脂型材的任一侧;第二挤压件122,第二挤压件122设于纤维增强树脂型材相对于任一侧的另一侧;其中,第一挤压件121和第二挤压件122中的至少一者设有纹路,第一挤压件121和第二挤压件122中的任一者沿顺时针滚动,另一者沿逆时针滚动。The extrusion assembly 120 includes: a first extrusion 121, the first extrusion 121 is arranged on either side of the fiber reinforced resin profile; a second extrusion 122, the second extrusion 122 is arranged on the opposite side of the fiber reinforced resin profile On the other side of either side; wherein, at least one of the first extruded part 121 and the second extruded part 122 is provided with lines, and any one of the first extruded part 121 and the second extruded part 122 One scrolls clockwise, and the other scrolls counterclockwise.

在一个示例中,如图2所示,第一挤压件121和第二挤压件122分别为履带。具体而言,挤压组件120包括:第一履带,第一履带设于纤维增强树脂型材的上侧;第二履带,第二履带设于纤维增强树脂型材的下侧;其中,第一履带和第二履带中的至少一者设有纹路,第一履带沿逆时针滚动,第二履带沿顺时针滚动。In one example, as shown in FIG. 2 , the first extruded part 121 and the second extruded part 122 are crawlers respectively. Specifically, the extrusion assembly 120 includes: a first track, the first track is set on the upper side of the fiber reinforced resin profile; a second track, the second track is set on the lower side of the fiber reinforced resin profile; wherein, the first track and At least one of the second crawlers is provided with a pattern, the first crawler rolls counterclockwise, and the second crawler rolls clockwise.

在另一个示例中,第一挤压件121和第二挤压件122分别为滚筒。具体而言,挤压组件120包括:第一滚筒,第一滚筒设于纤维增强树脂型材的上侧;第二滚筒,第二滚筒设于纤维增强树脂型材的下侧;其中,第一滚筒和第二滚筒中的至少一者设有纹路,第一滚筒沿逆时针滚动,第二滚筒沿顺时针滚动。滚筒具体筒状或圆柱状的结构,上下两个滚筒分别滚动,将位于两者之间的预热软化后的纤维增强树脂型材印制出花纹。In another example, the first extruded part 121 and the second extruded part 122 are rollers, respectively. Specifically, the extruding assembly 120 includes: a first roller, the first roller is arranged on the upper side of the fiber reinforced resin profile; a second roller, the second roller is arranged on the lower side of the fiber reinforced resin profile; wherein, the first roller and At least one of the second rollers is provided with textures, the first roller rolls counterclockwise, and the second roller rolls clockwise. The roller has a specific cylindrical or cylindrical structure, and the upper and lower rollers roll separately to print patterns on the preheated and softened fiber-reinforced resin profiles between the two.

第一挤压件121和第二挤压件122与受拉挤的纤维增强树脂型材以相同的速度同步运转,由此在纤维增强树脂型材的表面印制连续或不连续的花纹。The first extruded part 121 and the second extruded part 122 run synchronously with the pultruded fiber-reinforced resin profile at the same speed, thereby printing continuous or discontinuous patterns on the surface of the fiber-reinforced resin profile.

在再一个示例中,挤压组件120包括:往复移动机构。往复移动机构可以在电机或其他动力部件的驱动作用下往复移动。往复移动机构设于纤维增强树脂型材的任一侧,并设有纹路。其中,往复移动机构沿目标方向移动,以靠近纤维增强树脂型材,并向纤维增强树脂型材施加压力,往复移动机构沿目标方向的反向移动,以远离纤维增强树脂型材。In yet another example, the extrusion assembly 120 includes: a reciprocating movement mechanism. The reciprocating mechanism can reciprocate under the driving action of a motor or other power components. The reciprocating mechanism is arranged on either side of the fiber-reinforced resin profile and is provided with textures. Wherein, the reciprocating mechanism moves along the target direction to approach the fiber-reinforced resin profile and apply pressure to the fiber-reinforced resin profile, and the reciprocating mechanism moves in the opposite direction of the target direction to move away from the fiber-reinforced resin profile.

举例而言,往复移动机构的数量可以为1个,其设置在纤维增强树脂型材的上方,并能够沿纵向方向上下移动。往复移动机构的下部设有纹路印制板,往复移动机构下移后,纹路印制板在纤维增强树脂型材的上表面印制纹路,往复移动机构上移,则抬起并离开纤维增强树脂型材。For example, there may be one reciprocating mechanism, which is arranged above the fiber-reinforced resin profile and can move up and down in the longitudinal direction. The lower part of the reciprocating mechanism is provided with a textured printed board. After the reciprocating mechanism moves down, the textured printed board prints patterns on the upper surface of the fiber reinforced resin profile, and when the reciprocating mechanism moves up, it lifts and leaves the fiber reinforced resin profile. .

在一个示例中,挤压组件120包括:第一往复移动机构,第一往复移动机构设于纤维增强树脂型材的上侧;其中,第一往复移动机构向下移动,以靠近纤维增强树脂型材,并向纤维增强树脂型材施加压力,第一往复移动机构向上移动,以远离纤维增强树脂型材。此外,挤压组件120还包括:第二往复移动机构,第二往复移动机构设于纤维增强树脂型材的下侧;其中,第二往复移动机构向上移动,以靠近纤维增强树脂型材,并向纤维增强树脂型材施加压力,二往复移动机构向下移动,以远离纤维增强树脂型材。In one example, the extrusion assembly 120 includes: a first reciprocating mechanism, the first reciprocating mechanism is arranged on the upper side of the fiber-reinforced resin profile; wherein, the first reciprocating mechanism moves downward to approach the fiber-reinforced resin profile, And applying pressure to the fiber-reinforced resin profile, the first reciprocating mechanism moves upward to be away from the fiber-reinforced resin profile. In addition, the extruding assembly 120 also includes: a second reciprocating mechanism, the second reciprocating mechanism is arranged on the lower side of the fiber-reinforced resin profile; wherein, the second reciprocating mechanism moves upwards to approach the fiber-reinforced resin profile, and toward the fiber The reinforced resin profile applies pressure, and the two reciprocating mechanisms move downward, away from the fiber reinforced resin profile.

此外,拉挤成型设备100还包括压力传感器160,压力传感器160设于挤压组件120,并用于检测挤压组件120向纤维增强树脂型材施加的压力。具体而言,压力传感器160的数量可以为一个或多个,压力传感器160与拉挤成型设备100的控制器通信连接,以将检测到的用于反应压力程度的电信号传送给控制器。由此,控制器根据压力程度调节挤压组件120的挤压力度,以调节型材表面的纹路深度。In addition, the pultrusion molding equipment 100 further includes a pressure sensor 160 , the pressure sensor 160 is disposed on the extruding assembly 120 and is used to detect the pressure applied by the extruding assembly 120 to the fiber-reinforced resin profile. Specifically, the number of pressure sensors 160 may be one or more, and the pressure sensors 160 are communicatively connected with the controller of the pultrusion equipment 100, so as to transmit the detected electrical signal for reflecting the degree of pressure to the controller. Thus, the controller adjusts the extrusion force of the extrusion assembly 120 according to the degree of pressure, so as to adjust the texture depth of the profile surface.

虽然本发明披露如上,但本发明并非限定于此。任何本领域技术人员,在不脱离本发明的精神和范围内,均可作各种更动与修改,因此本发明的保护范围应当以权利要求所限定的范围为准。Although the present invention is disclosed above, the present invention is not limited thereto. Any person skilled in the art can make various changes and modifications without departing from the spirit and scope of the present invention, so the protection scope of the present invention should be based on the scope defined in the claims.

Claims (10)

1. A pultrusion apparatus (100) of a fiber reinforced resin profile, characterized in that the pultrusion apparatus (100) comprises:
a pultrusion die (110), the pultrusion die (110) being configured to apply heat to the dip fibers to cure the dip fibers into the fiber reinforced resin profile, the pultrusion die (110) comprising at least two heating sections;
a pressing assembly (120), wherein the pressing assembly (120) is positioned between the at least two heating sections, and the pressing assembly (120) is provided with grains;
wherein the extrusion assembly (120) is configured to apply pressure to the preformed fiber-reinforced resin profile to print the texture onto at least a portion of the surface of the fiber-reinforced resin profile.
2. The pultrusion apparatus (100) according to claim 1, characterized in that the at least two heating sections comprise a preheating section (111), a curing section (112) and a release section (113) arranged in sequence; wherein the extrusion assembly (120) is located between the preheating section (111) and the curing section (112).
3. The pultrusion apparatus (100) according to claim 1, characterized in that the at least two heating sections comprise a preheating section (111), a curing section (112) and a release section (113) arranged in sequence; wherein the extrusion assembly (120) is located between the curing section (112) and the release section (113).
4. A pultrusion apparatus (100) according to any of claims 1-3, characterized in that the extrusion assembly (120) comprises:
a first extrusion (121), the first extrusion (121) being provided on either side of the fiber reinforced resin profile;
a second extrusion (122), the second extrusion (122) being provided on the other side of the fiber-reinforced resin profile with respect to either side;
wherein at least one of the first pressing member (121) and the second pressing member (122) is provided with the grain.
5. A pultrusion apparatus (100) according to any of claims 1-3, characterized in that the extrusion assembly (120) comprises:
the first crawler belt is arranged on the upper side of the fiber reinforced resin section bar;
the second caterpillar band is arranged on the lower side of the fiber reinforced resin profile;
wherein at least one of the first track and the second track is provided with the texture, the first track rolls counterclockwise, and the second track rolls clockwise.
6. A pultrusion apparatus (100) according to any of claims 1-3, characterized in that the extrusion assembly (120) comprises:
the first roller is arranged on the upper side of the fiber reinforced resin section bar;
the second roller is arranged on the lower side of the fiber reinforced resin section bar;
wherein at least one of the first roller and the second roller is provided with the texture, the first roller rolls counterclockwise, and the second roller rolls clockwise.
7. A pultrusion apparatus (100) according to any of claims 1-3, characterized in that the extrusion assembly (120) comprises:
the first reciprocating mechanism is arranged on the upper side of the fiber reinforced resin section bar;
wherein the first reciprocating mechanism moves downward to be close to the fiber reinforced resin profile and applies pressure to the fiber reinforced resin profile, and moves upward to be away from the fiber reinforced resin profile.
8. The pultrusion apparatus (100) of claim 7, wherein the extrusion assembly (120) further comprises:
the second reciprocating mechanism is arranged on the lower side of the fiber reinforced resin section;
wherein the second reciprocating mechanism moves upward to be close to the fiber reinforced resin profile and applies pressure to the fiber reinforced resin profile, and moves downward to be away from the fiber reinforced resin profile.
9. A pultrusion apparatus (100) according to any of claims 1-3, characterized in that the texture is at least one of the following or a combination thereof:
bar-shaped lines, dot-shaped lines, polygonal lines.
10. A pultrusion apparatus (100) according to any of claims 1-3, characterized in that the pultrusion apparatus (100) further comprises:
and the pressure sensor (160) is arranged on the extrusion assembly (120) and is used for detecting the pressure applied by the extrusion assembly (120) to the fiber reinforced resin profile.
CN202310095758.7A 2023-02-10 2023-02-10 Pultrusion equipment for fiber reinforced resin profile Pending CN116160700A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1399677A (en) * 1973-10-22 1975-07-02 Youngstown Sheet And Tube Co Pultrusion apparatus
AT388167B (en) * 1987-01-26 1989-05-10 Mitsui Petrochemical Ind Process for producing a substantially unoriented film with a roughened surface and use of the film
JP2002248693A (en) * 2001-02-26 2002-09-03 Toray Ind Inc Frp long molded object and method for manufacturing the same
CN1919587A (en) * 2005-08-25 2007-02-28 深圳市海川实业股份有限公司 Method for increasing transverse strength of fiber reinforced resin pultrusion section bar and product thereof
CN108859183A (en) * 2018-07-06 2018-11-23 江苏海川新材料科技有限公司 A kind of glass fibre sandblasting pultrusion molding process
CN214419655U (en) * 2020-11-02 2021-10-19 增城华昌塑料五金模具有限公司 Pultrusion compression molding equipment

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1399677A (en) * 1973-10-22 1975-07-02 Youngstown Sheet And Tube Co Pultrusion apparatus
AT388167B (en) * 1987-01-26 1989-05-10 Mitsui Petrochemical Ind Process for producing a substantially unoriented film with a roughened surface and use of the film
JP2002248693A (en) * 2001-02-26 2002-09-03 Toray Ind Inc Frp long molded object and method for manufacturing the same
CN1919587A (en) * 2005-08-25 2007-02-28 深圳市海川实业股份有限公司 Method for increasing transverse strength of fiber reinforced resin pultrusion section bar and product thereof
CN108859183A (en) * 2018-07-06 2018-11-23 江苏海川新材料科技有限公司 A kind of glass fibre sandblasting pultrusion molding process
CN214419655U (en) * 2020-11-02 2021-10-19 增城华昌塑料五金模具有限公司 Pultrusion compression molding equipment

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