CN116032240A - Thin film bulk acoustic resonator based on phononic crystals to improve quality factor - Google Patents
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Abstract
Description
技术领域technical field
本发明属于射频微机电系统技术领域,具体涉及一种基于声子晶体提升品质因数的薄膜体声波谐振器。The invention belongs to the technical field of radio frequency micro-electromechanical systems, and in particular relates to a thin-film bulk acoustic wave resonator based on a phononic crystal to improve the quality factor.
背景技术Background technique
无线通信技术的迅猛发展,无线信号的频段越来越拥挤,使用的频段越来越高,对射频器件提出了高度集成、低功耗、高性能的要求。射频滤波器在无线通讯中的信号过滤环节起着至关重要的作用。薄膜体声波谐振器具有高谐振频率、CMOS工艺兼容、高品质因子、低损耗、低温度系数和高的功率承载能力等特性,逐渐取代声表面波谐振器成为市场主流。With the rapid development of wireless communication technology, the frequency band of wireless signals is becoming more and more crowded, and the frequency band used is getting higher and higher, which puts forward the requirements of high integration, low power consumption and high performance for radio frequency devices. RF filters play a vital role in signal filtering in wireless communications. Thin film bulk acoustic resonator has the characteristics of high resonance frequency, CMOS process compatibility, high quality factor, low loss, low temperature coefficient and high power carrying capacity, and gradually replaces surface acoustic wave resonator to become the mainstream of the market.
薄膜体声波谐振器工作原理为在上下电极上施加射频电信号,利用压电材料的压电效应,产生纵向模式的振动,从而在上下电极和压电材料构成的三明治结构中产生纵向传播的声信号,声信号在三明治结构中振荡再通过压电效应转化为电信号输出,只有与压电材料谐振频率匹配的射频信号才能通过薄膜体声波谐振器的传输,从而实现滤波的功能。理想状态下谐振器中产生纵向振动,事实上由于制备的压电材料内部可能存在缺陷或者不是完全的C轴取向,谐振器在纵向振动的同时也产生横向振动,而横向振动会造成声波能量的损耗,同时带来杂波的影响,造成薄膜体声波谐振器的品质因子的下降。The working principle of the thin film bulk acoustic resonator is to apply radio frequency electrical signals on the upper and lower electrodes, and use the piezoelectric effect of the piezoelectric material to generate vibration in the longitudinal mode, thereby generating longitudinally transmitted acoustic waves in the sandwich structure composed of the upper and lower electrodes and the piezoelectric material. The signal and the acoustic signal oscillate in the sandwich structure and then convert it into an electrical signal output through the piezoelectric effect. Only the radio frequency signal matching the resonance frequency of the piezoelectric material can be transmitted through the thin film bulk acoustic resonator, thereby realizing the filtering function. Ideally, longitudinal vibrations are generated in the resonator. In fact, due to the possible defects or incomplete C-axis orientation in the prepared piezoelectric material, the resonator also generates lateral vibrations while longitudinal vibrations, and lateral vibrations will cause the sound wave energy to dissipate. At the same time, it brings the influence of clutter, which leads to the decrease of the quality factor of the film bulk acoustic resonator.
发明内容Contents of the invention
本发明提供了一种基于声子晶体提升品质因数的薄膜体声波谐振器,解决背景中薄膜体声波谐振器由于材料制备与工艺中不可避免因素产生的缺陷导致的横向杂波问题,有效抑制伪模态,减少能量损耗,提升谐振器品质因子。The invention provides a thin film bulk acoustic resonator based on phononic crystals to improve the quality factor, which solves the problem of transverse clutter caused by defects in the background thin film bulk acoustic resonator due to unavoidable factors in material preparation and process, and effectively suppresses false mode, reduce energy loss, and improve the quality factor of the resonator.
为实现上述目的,本发明提供一种基于声子晶体提升品质因数的薄膜体声波谐振器,其特征在于:包括衬底、衬底中刻蚀出的空腔、衬底上依次设置的缓冲层、种子层、压电堆叠结构、贯穿压电薄膜的空气柱构成的声子晶体,和环绕压电堆叠结构的电极群;In order to achieve the above object, the present invention provides a thin-film bulk acoustic resonator based on phononic crystals to improve the quality factor, which is characterized in that it includes a substrate, a cavity etched in the substrate, and a buffer layer sequentially arranged on the substrate , a seed layer, a piezoelectric stack structure, a phononic crystal formed by an air column penetrating the piezoelectric film, and an electrode group surrounding the piezoelectric stack structure;
所述空腔位于衬底上且位于种子层与压电堆叠结构下方;The cavity is located on the substrate and below the seed layer and the piezoelectric stack structure;
所述压电堆叠结构从上至下分别为上电极,压电薄膜和下电极,上、下电极的形状均为五边形;The piezoelectric stack structure is respectively an upper electrode, a piezoelectric film and a lower electrode from top to bottom, and the shapes of the upper and lower electrodes are both pentagonal;
所述种子层在缓冲层与压电堆叠结构中间,种子层材料与压电薄膜材料一致;The seed layer is between the buffer layer and the piezoelectric stack structure, and the material of the seed layer is consistent with the piezoelectric film material;
所述环绕压电堆叠结构的电极群在空间上均匀分布在五边形的上、下电极的周围,电极群围成的图案也为五边形、方形或圆形中的任一种。The electrode groups surrounding the piezoelectric stack structure are evenly distributed in space around the pentagonal upper and lower electrodes, and the pattern formed by the electrode groups is any one of pentagonal, square or circular.
作为优选方案,所述空腔形状为圆形或任意多边形;As a preferred solution, the shape of the cavity is circular or any polygon;
所述环绕压电堆叠结构的电极群形状为长方体、三棱柱、圆柱、正六边形柱体中的一种或多种;The shape of the electrode group surrounding the piezoelectric stack structure is one or more of cuboid, triangular prism, cylinder, and regular hexagonal column;
所述贯穿压电薄膜的空气柱形状为长方体,三棱柱,圆柱,正六边形柱体中的一种或多种;由空气柱构成的声子晶体拓扑结构在空间平面上围成的图案为五边形、圆形或方形中任一种。The shape of the air column that runs through the piezoelectric film is one or more of cuboid, triangular prism, cylinder, and regular hexagonal column; the pattern surrounded by the topological structure of the phononic crystal formed by the air column on the space plane is: Either pentagon, circle or square.
进一步地,所述电极群比声子晶体空气柱离压电堆叠结构更近,且电极群,声子晶体空气柱与压电堆叠结构的中心间距相同。Further, the electrode group is closer to the piezoelectric stack structure than the phononic crystal air column, and the distance between the centers of the electrode group, the phononic crystal air column and the piezoelectric stack structure is the same.
更进一步地,所述压电堆叠结构的上、下电极均为金属薄膜,所述金属薄膜材料为金、银、铂、钼或铬中的任一种;Furthermore, the upper and lower electrodes of the piezoelectric stack structure are both metal thin films, and the material of the metal thin films is any one of gold, silver, platinum, molybdenum or chromium;
所述压电薄膜材料为氮化铝、钪掺杂氮化铝、铌酸锂、钽酸锂、PZT或氧化锌中的任一种。The piezoelectric film material is any one of aluminum nitride, scandium-doped aluminum nitride, lithium niobate, lithium tantalate, PZT or zinc oxide.
更进一步地,所述环绕压电堆叠结构的电极群的材料为金、银、铂、钼或铬中的任一种。Furthermore, the material of the electrode group surrounding the piezoelectric stack structure is any one of gold, silver, platinum, molybdenum or chromium.
本发明采用的薄膜体声波谐振器的制备方法,包括步骤如下:The preparation method of the film bulk acoustic resonator that the present invention adopts comprises steps as follows:
S1:在基底上刻蚀空腔;S1: Etching a cavity on the substrate;
S2:在基底上沉积牺牲层;S2: depositing a sacrificial layer on the substrate;
S3:刨除多余的牺牲层,使得保留的牺牲层刚好填满空腔;S3: removing the redundant sacrificial layer, so that the remaining sacrificial layer just fills the cavity;
S4:在基底和牺牲层上面沉积底电极;S4: Depositing a bottom electrode on the substrate and the sacrificial layer;
S5:刻蚀多余的底电极,形成需要的底电极的形状与底部的电极群;S5: Etching the redundant bottom electrode to form the desired shape of the bottom electrode and the bottom electrode group;
S6:通过步骤S5在底电极的上方沉积压电材料;S6: Depositing a piezoelectric material above the bottom electrode through step S5;
S7:在压电材料层上方沉积顶电极;S7: Depositing a top electrode over the piezoelectric material layer;
S8:刻蚀多余的顶电极,形成需要的顶电极的形状与顶部的电极群;S8: Etching the redundant top electrodes to form the desired shape of the top electrodes and the top electrode group;
S9:刻蚀压电堆叠结构不在空气隙的部分,按照一定的拓扑结构,形成贯穿压电材料的声子晶体空气柱;S9: Etch the part of the piezoelectric stack structure that is not in the air gap, and form a phononic crystal air column that runs through the piezoelectric material according to a certain topology;
S10:在压电堆叠结构上刻蚀释放孔;S10: Etching release holes on the piezoelectric stack structure;
S11:通过腐蚀液或者腐蚀气体释放空腔,形成薄膜体声波谐振器。S11: releasing the cavity by corrosive liquid or corrosive gas to form a thin film bulk acoustic resonator.
本发明的优点及有益效果如下:Advantage of the present invention and beneficial effect are as follows:
与现有技术不同的是,本发明使用声子晶体结构的部位不同,现有的技术中有些是在封装上,有些是在衬底上,即分别是从谐振器上方与下方减小声波的散射,减少能量泄露。而本发明是通过优化谐振器的压电三明治结构(上电极,压电材料与下电极),从振动的源头提升Q值。Different from the prior art, the present invention uses different parts of the phononic crystal structure. In the prior art, some are on the package, and some are on the substrate, that is, to reduce the acoustic wave from above and below the resonator. Scattering, reducing energy leakage. However, the present invention improves the Q value from the source of the vibration by optimizing the piezoelectric sandwich structure (upper electrode, piezoelectric material and lower electrode) of the resonator.
本发明通过结构的优化,有效弥补现有技术中工艺导致的性能降低。本发明的技术方案基于FBAR的空气隙结构,在传统的上电极-压电薄膜-下电极的三明治结构中引入声子晶体作为侧边声波抑制结构,使得FBAR中横向传播的伪模态被抑制,减少了杂波,提升器件的品质因数。本发明设计的声子晶体的具体单元结构为:1)环绕传统多边形上下电极的电极群,从而减小电极区域的能量泄露;2)贯穿压电薄膜的图案化孔洞,从而将声波能量约束上下电极覆盖的压电薄膜区域内,即解决横向模态的声波传输,抑制伪模态,从而显著提升品质因数。The invention effectively makes up for the performance reduction caused by the process in the prior art through the optimization of the structure. The technical solution of the present invention is based on the air-gap structure of FBAR, and a phononic crystal is introduced into the sandwich structure of the traditional upper electrode-piezoelectric film-lower electrode as a side acoustic wave suppression structure, so that the false mode of lateral propagation in the FBAR is suppressed , reducing clutter and improving the quality factor of the device. The specific unit structure of the phononic crystal designed in the present invention is: 1) the electrode group surrounding the traditional polygonal upper and lower electrodes, thereby reducing the energy leakage in the electrode area; 2) the patterned holes running through the piezoelectric film, thereby confining the acoustic wave energy In the area of the piezoelectric film covered by the electrode, the acoustic wave transmission of the transverse mode is solved, and the false mode is suppressed, thereby significantly improving the quality factor.
本发明提出的薄膜体声波谐振器,通过刻蚀空腔正上方压电堆叠结构以外的上下电极和压电薄膜,形成环绕式的电极群与声子晶体空气柱。环绕传统多边形上下电极的圆柱形电极能减小电极区域的能量泄露;贯穿压电薄膜的图案化孔洞,能将声波能量约束上下电极覆盖的压电薄膜区域内,谐振时在压电材料有效区域内部横向传播的声波在边缘被空气反射,即解决横向模态的声波传输,抑制伪模态,从而显著提升品质因数。The thin film bulk acoustic resonator proposed by the present invention forms a surrounding electrode group and a phononic crystal air column by etching the upper and lower electrodes and the piezoelectric film other than the piezoelectric stack structure directly above the cavity. The cylindrical electrodes surrounding the traditional polygonal upper and lower electrodes can reduce the energy leakage in the electrode area; the patterned holes running through the piezoelectric film can confine the acoustic wave energy to the piezoelectric film area covered by the upper and lower electrodes, and resonate in the effective area of the piezoelectric material The sound waves propagating laterally in the interior are reflected by the air at the edge, which solves the sound wave transmission of the transverse mode and suppresses the false mode, thereby significantly improving the quality factor.
附图说明Description of drawings
图1为本发明基于声子晶体提升品质因数的薄膜体声波谐振器的剖面图;1 is a cross-sectional view of a thin-film bulk acoustic resonator based on a phononic crystal to improve the quality factor of the present invention;
图2为本发明基于声子晶体提升品质因数的薄膜体声波谐振器的俯视图;Fig. 2 is the top view of the film bulk acoustic resonator based on the phononic crystal to improve the quality factor of the present invention;
图3为本发明基于声子晶体提升品质因数的薄膜体声波谐振器的三种贯穿压电薄膜的声子晶体空气柱的拓扑结构;Fig. 3 is the topological structure of three kinds of phononic crystal air columns penetrating the piezoelectric film of the film bulk acoustic resonator based on the phononic crystal to improve the quality factor of the present invention;
图4为本发明基于声子晶体提升品质因数的薄膜体声波谐振器与传统相同特征几何尺寸的薄膜体声波谐振器的阻抗曲线对比;其中实线代表本发明所述结构的谐振器曲线,虚线代表传统谐振器曲线。Fig. 4 is the impedance curve comparison of the thin film bulk acoustic resonator based on the phononic crystal to improve the quality factor of the present invention and the traditional thin film bulk acoustic resonator of the same characteristic geometric size; wherein the solid line represents the resonator curve of the structure of the present invention, and the dotted line Represents the conventional resonator curve.
图中:In the picture:
110、衬底;120、空腔;130、缓冲层;140、种子层;150、第一压电薄膜;160、下电极;170、上电极;180、贯穿压电薄膜的空气柱构成的声子晶体;190、第一环绕压电堆叠结构的电极群;110. substrate; 120. cavity; 130. buffer layer; 140. seed layer; 150. first piezoelectric film; 160. lower electrode; 170. upper electrode; sub-crystal; 190, the first electrode group surrounding the piezoelectric stack structure;
210、第二压电薄膜;220、第一声子晶体空气柱;230、第二环绕压电堆叠结构的电极群;240、压电堆叠结构;210. The second piezoelectric film; 220. The first phononic crystal air column; 230. The second electrode group surrounding the piezoelectric stack structure; 240. The piezoelectric stack structure;
310、第一声子晶体空气柱拓扑结构;311、第二声子晶体空气柱;312、第一压电薄膜未刻蚀的部分;320、第二声子晶体空气柱拓扑结构;321、第三声子晶体空气柱;322、第二压电薄膜未刻蚀的部分;330、第三声子晶体空气柱拓扑结构;331、第四声子晶体空气柱;332、第三压电薄膜未刻蚀的部分。310. The topological structure of the first phononic crystal air column; 311. The second phononic crystal air column; 312. The unetched part of the first piezoelectric film; 320. The second phononic crystal air column topology; 321. The first Three phononic crystal air columns; 322, the unetched part of the second piezoelectric film; 330, the topological structure of the third phononic crystal air column; 331, the fourth phononic crystal air column; 332, the unetched part of the third piezoelectric film etched part.
具体实施方式Detailed ways
以下结合附图与具体实施例对本发明的技术方案作进一步地详细阐述。The technical solutions of the present invention will be further described in detail below in conjunction with the accompanying drawings and specific embodiments.
实施例1Example 1
本实施例基于声子晶体提升品质因数的薄膜体声波谐振器,通过衬底的制备、衬底中刻蚀出的空腔、衬底上依次沉积缓冲层、种子层、压电堆叠结构(下电极、压电薄膜、上电极)、并在沉积下电极,上电极时进行光刻产生环绕压电堆叠结构的电极群,然后最后光刻产生特定拓扑结构的贯穿压电薄膜的空气柱构成的声子晶体。In this embodiment, a thin-film bulk acoustic resonator based on a phononic crystal to improve the quality factor, through the preparation of the substrate, the cavity etched in the substrate, and the sequential deposition of a buffer layer, a seed layer, and a piezoelectric stack structure on the substrate (below Electrode, piezoelectric film, upper electrode), and when depositing the lower electrode and the upper electrode, photolithography is performed to generate an electrode group surrounding the piezoelectric stack structure, and then finally photolithography produces a specific topology composed of air columns penetrating the piezoelectric film Phononic crystals.
具体实施时,如图1所示,基于声子晶体提升品质因数的薄膜体声波谐振器的结构为:衬底110,该衬底材料为硅、蓝宝石或SOI衬底;包括在衬底上刻蚀出的空腔120;在衬底上沉积的缓冲层130,缓冲层材料为二氧化硅;缓冲层上沉积的种子层140,种子层的材料与第一压电薄膜150相同,材料优选为氮化铝,钪掺杂氮化铝,铌酸锂,钽酸锂,PZT,氧化锌中的一种;种子层上结构为压电振荡堆结构(包括下电极160、压电薄膜层150及上电极170)、贯穿压电薄膜的空气柱构成的声子晶体180和第一环绕压电堆叠结构的电极群190;其中,压电堆叠结构的上电极170和下电极160均为金属薄膜,材料优选为金,银,铂,钼,铬中的一种;第一压电薄膜150材料优选为氮化铝,钪掺杂氮化铝,铌酸锂,钽酸锂,PZT,氧化锌中的一种。围绕压电堆叠结构的电极群190材料优选为金,银,铂,钼,铬中的一种。During specific implementation, as shown in Figure 1, the structure of the thin film bulk acoustic resonator based on phononic crystals to improve the quality factor is: substrate 110, the substrate material is silicon, sapphire or SOI substrate; The cavity 120 etched out; the buffer layer 130 deposited on the substrate, the material of the buffer layer is silicon dioxide; the seed layer 140 deposited on the buffer layer, the material of the seed layer is the same as that of the first piezoelectric film 150, and the material is preferably One of aluminum nitride, scandium-doped aluminum nitride, lithium niobate, lithium tantalate, PZT, and zinc oxide; the upper structure of the seed layer is a piezoelectric oscillator stack structure (including the lower electrode 160, the piezoelectric film layer 150 and The upper electrode 170), the phononic crystal 180 formed by the air column penetrating the piezoelectric film, and the first electrode group 190 surrounding the piezoelectric stack structure; wherein, the upper electrode 170 and the lower electrode 160 of the piezoelectric stack structure are both metal thin films, The material is preferably one of gold, silver, platinum, molybdenum, and chromium; the material of the first piezoelectric film 150 is preferably aluminum nitride, scandium-doped aluminum nitride, lithium niobate, lithium tantalate, PZT, and zinc oxide. kind of. The material of the
图2为图1中实施例的俯视图,包括了压电堆叠结构中的第二压电薄膜210,对应图1中的150;贯穿压电薄膜的空气柱构成的第一声子晶体空气柱220,对应图1中的180;第二环绕压电堆叠结构的电极群230,对应图1中的190;空气隙上方的压电堆叠结构240,对应图1中的下电极160,第一压电薄膜150在空气隙120上方的部分以及上电极170。Fig. 2 is a top view of the embodiment in Fig. 1, including the second
图3为三种光刻条件下形成的三种声子晶体空气柱的拓扑结构,包括第二声子晶体空气柱311形成的五边形,第三声子晶体空气柱321形成的方形,第四声子晶体空气柱331形成的圆形,以及未被贯穿的第一压电薄膜未刻蚀的部分312,第二压电薄膜未刻蚀的部分322,第三压电薄膜未刻蚀的部分332。Figure 3 shows the topological structures of three phononic crystal air columns formed under three photolithographic conditions, including the pentagon formed by the second phononic
图4为有无本发明中电极群与声子晶体空气柱下五边形FBAR的数据曲线,实线代表图1所示的实施例,虚线表示传统FBAR,可以发现本发明所示的实施例能有效的降低横向杂波,减少能量损耗,将振动限制在空气隙上方的压电堆叠结构的纵向方向,有效提升品质因数。即采用了本发明结构的谐振器通过图4中曲线可以明显看出,杂波更少,即实现了抑制伪模态,提升品质因数。Fig. 4 is the data curve of the pentagonal FBAR under the electrode group and the phononic crystal air column with or without the present invention, the solid line represents the embodiment shown in Fig. 1, the dotted line represents the traditional FBAR, and the embodiment shown in the present invention can be found It can effectively reduce transverse clutter, reduce energy loss, limit vibration to the longitudinal direction of the piezoelectric stack structure above the air gap, and effectively improve the quality factor. That is, the resonator adopting the structure of the present invention can be clearly seen from the curve in FIG. 4 , the clutter is less, that is, the pseudo mode is suppressed and the quality factor is improved.
应当理解的是,本说明书未详细阐述的部分均属于现有技术。It should be understood that the parts not described in detail in this specification belong to the prior art.
应当理解的是,上述针对较佳实施例的描述较为详细,并不能因此而认为是对本发明专利保护范围的限制,本领域的普通技术人员在本发明的启示下,在不脱离本发明权利要求所保护的范围情况下,还可以做出替换或变形,均落入本发明的保护范围之内,本发明的请求保护范围应以所附权利要求为准。It should be understood that the above-mentioned descriptions for the preferred embodiments are relatively detailed, and should not therefore be considered as limiting the scope of the patent protection of the present invention. Within the scope of protection, replacements or modifications can also be made, all of which fall within the protection scope of the present invention, and the scope of protection of the present invention should be based on the appended claims.
Claims (5)
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