CN116001992A - Marine floating type clean energy production and biological carbon fixing platform - Google Patents
Marine floating type clean energy production and biological carbon fixing platform Download PDFInfo
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- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 12
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Abstract
一种海上浮式清洁能源生产及生物固碳平台,平台由多个三角形基础框架组成,基础框架由三个垂直轴发电机柱及浮体支撑杆形成整体呈三角形的基础框架。其中一个基础框架上铺设有甲板,甲板上设置有吊车、设备间及清洁联产模块,其余基础框架上方架设网箱框架,养殖网箱位于网箱框架内,通过电动绞车上下运动。清洁联产模块固碳后,将形成的氯化铵供给平台周围的浮游生物,达到固碳目的。本发明利用自身绿色能源循环,自给自足,基于绿色能源固碳的同时,提高海水养殖产量。利用海洋温差能发电系统废弃的混合海水,进行海水淡化及后续的清洁能源生产、海产养殖,清洁能源及副产品又可进行固碳,减低运行成本,提高系统本身的经济适用性。
An offshore floating clean energy production and biological carbon sequestration platform, the platform is composed of a plurality of triangular basic frames, and the basic frame is formed by three vertical axis generator columns and floating body support rods to form an overall triangular basic frame. A deck is laid on one of the basic frames, and cranes, equipment rooms and cleaning co-production modules are arranged on the deck, and cage frames are erected above the rest of the basic frames. The breeding cages are located in the cage frames and move up and down through electric winches. After cleaning the cogeneration module for carbon sequestration, the formed ammonium chloride is supplied to the plankton around the platform to achieve the purpose of carbon sequestration. The invention utilizes its own green energy cycle, is self-sufficient, and improves seawater aquaculture production while sequestering carbon based on green energy. Use the mixed seawater discarded by the ocean thermal power generation system for desalination and subsequent clean energy production and mariculture. Clean energy and by-products can also be used for carbon sequestration, reducing operating costs and improving the economic applicability of the system itself.
Description
技术领域technical field
本发明涉及船舶及海洋工程领域,更具体的说,涉及一种基于绿色能源的海上浮式清洁能源生产及生物固碳系统。The invention relates to the field of ships and ocean engineering, and more specifically, to a green energy-based offshore floating clean energy production and biological carbon sequestration system.
背景技术Background technique
目前,海洋碳封存主要是超临界二氧化碳海底盐水层封存和深海直接注入二氧化碳封存。由于海底盐水层空间有限,以及超临界二氧化碳会因高压泄露重新释放到海水中,导致海洋酸化。深海直接注入二氧化碳是在1000米以上的深度中直接注入二氧化碳使之溶于海水,或在3000米以上的海底空间中直接注入高密度二氧化碳以延缓其在海水中的扩散,但这种碳封存方法同样面临海洋酸化对海洋生态系统产生负面影响的问题,同时溶于水中的二氧化碳最终可能会重新释放到大气中,无法永久封存。At present, ocean carbon storage is mainly supercritical carbon dioxide seabed saline layer storage and deep sea direct injection of carbon dioxide storage. Ocean acidification is caused by the limited space in the seafloor saline layer and the re-release of supercritical carbon dioxide into the seawater due to high-pressure leaks. Deep-sea direct injection of carbon dioxide is directly injecting carbon dioxide at a depth of more than 1,000 meters to dissolve it in seawater, or directly injecting high-density carbon dioxide into the seabed space above 3,000 meters to delay its diffusion in seawater, but this carbon sequestration method It also faces the problem of ocean acidification negatively impacting marine ecosystems, while carbon dioxide dissolved in water may eventually be re-released into the atmosphere and cannot be stored permanently.
氢气和氨气作为无碳排放的清洁能源越来越受到市场的重视,各国有意将两种燃料作为今后的替代化石燃料的主流新能源。但目前制约氢气及氨气发展的主要原因之一即生产成本较高,而全球海洋温差能、海上风能、海上太阳能资源丰富,通过利用海上可再生能源生产清洁能源、电能,同时利用生产的清洁能源对二氧化碳进行化学固碳、生物固碳,不但可以充分利用资源,而且实现二氧化碳稳定的封存。Hydrogen and ammonia, as clean energy sources without carbon emissions, are gaining more and more attention in the market, and countries intend to use these two fuels as mainstream new energy sources to replace fossil fuels in the future. However, one of the main reasons restricting the development of hydrogen and ammonia at present is the high production cost, and the global ocean temperature difference energy, offshore wind energy, and offshore solar energy resources are abundant. By using offshore renewable energy to produce clean energy and electricity, while using the clean production The chemical carbon fixation and biological carbon fixation of carbon dioxide by energy can not only make full use of resources, but also realize the stable storage of carbon dioxide.
发明内容Contents of the invention
为解决上述问题,本发明提供一种绿色海上浮式清洁能源生产及生物固碳系统,其所采用的技术方案是:In order to solve the above problems, the present invention provides a green offshore floating clean energy production and biological carbon sequestration system, the technical solution adopted is:
一种海上浮式清洁能源生产及生物固碳平台,平台由多个三角形基础框架组成,所述基础框架带有三个垂直轴发电机柱,三个所述垂直轴发电机柱之间通过上层浮体支撑杆和下层浮体支撑杆固定连接,所述上层浮体支撑杆位于海面上方,所述下层浮体支撑杆位于所述海面下方,所述浮体支撑杆通过连接副与所述垂直轴发电机柱连接,所述下层浮体支撑杆之间固定有多个水下浮体,所述水下浮体带有多个压载舱及空舱。平台以基础框架为单位,由多个基础框架进行组合形成整体的平台结构,垂直轴发电机柱顶部固定有垂直轴发电机,通过垂直轴发电机发电,并将电储存在蓄电池中,蓄电池对平台中各单元、部件进行供电。An offshore floating clean energy production and biological carbon sequestration platform, the platform is composed of a plurality of triangular base frames, the base frame has three vertical axis generator columns, and the upper floating body is passed between the three vertical axis generator columns The support rod is fixedly connected to the lower floating body support rod, the upper floating body support rod is located above the sea surface, the lower floating body support rod is located below the sea surface, and the floating body support rod is connected to the vertical axis generator column through a connection pair, A plurality of underwater floating bodies are fixed between the supporting rods of the lower floating body, and the underwater floating bodies are provided with a plurality of ballast tanks and empty tanks. The platform takes the basic frame as a unit, and is composed of multiple basic frames to form an overall platform structure. A vertical-axis generator is fixed on the top of the vertical-axis generator column. The vertical-axis generator generates electricity and stores the electricity in the battery. All units and components in the platform are powered.
所述连接副带有圆形套环,所述套环套在所述垂直轴发电机柱上,沿所述套环周向等间距设置有多个连接环,所述连接环为开口连接环,所述连接环通过横向连接轴与所述套环连接,所述连接环通过纵向连接轴与所述浮体支撑杆连接。采用开口连接环这种连接结构,可以使浮体支撑杆相对套环可在横向方向、纵向方向上自由转动,进而多个基础框架可以相对活动、基础框架内的浮体支撑杆相对垂直轴发电机柱可以活动,使整个平台既存在整体状态,在外力介入时,也可以是独立单元个体状态存在,采用上述这种结构,可以增加平台在位扩充风机的可操作度和整体抗疲劳能力。The connecting pair has a circular collar, and the collar is set on the vertical axis generator column. A plurality of connecting rings are arranged at equal intervals along the circumferential direction of the collar, and the connecting rings are split connecting rings , the connecting ring is connected to the collar through a transverse connecting shaft, and the connecting ring is connected to the buoy support rod through a longitudinal connecting shaft. The connection structure of the open connection ring can make the support rod of the floating body rotate freely in the horizontal direction and the longitudinal direction relative to the collar, and then multiple basic frames can move relatively, and the support rod of the floating body in the basic frame is relatively vertical to the generator column. It can be movable so that the whole platform exists in an overall state, and when external forces intervene, it can also exist in an individual state of an independent unit. Using the above-mentioned structure can increase the operability and overall anti-fatigue ability of the platform's on-site expansion fan.
一个所述基础框架的上层浮体支撑杆上铺设有甲板,所述甲板上设置有吊车、设备间及清洁联产模块,所述甲板上、靠近所述垂直轴发电机柱处,固定有多个光伏电池板,所述垂直轴发电机、所述光伏电池板与蓄电池连接。垂直轴发电机及光伏电池板将产生的电输送至蓄电池,蓄电池对整个平台进行供电,为平台系统运转提供稳定的动力来源,解决发电系统与耗电装置供需不平的问题。A deck is laid on the support bar of the upper floating body of the foundation frame, and a crane, an equipment room, and a cleaning and co-production module are arranged on the deck, and a plurality of The photovoltaic battery panel, the vertical axis generator, the photovoltaic battery panel are connected to the storage battery. The vertical axis generator and photovoltaic panels transmit the generated electricity to the storage battery, which supplies power to the entire platform, providing a stable source of power for the operation of the platform system, and solving the problem of uneven supply and demand of the power generation system and power consumption devices.
所述清洁联产模块带有OTEC系统,OTEC系统将一部分混合海水通过混合海水管路排放至海中,排放至海中的混合海水富含硝酸盐、磷酸盐、硅酸盐等无机营养物质,可提高养殖区域内营养物质含量;另一部分输送至海水淡化系统,海水淡化系统生成淡水及浓海水,浓海水输送至固碳系统,淡水电解生成氧气和氢气,所述氢气输送给制氨系统,制氮系统将生成的氮气供给所述制氨系统,所述制氨系统将生成的液氨输送至OTEC系统,生成的氨气输送至所述固碳系统,所述固碳系统带有CCS装置,所述CCS装置将捕捉到的CO2与所述氨气、所述浓海水混合,形成的氯化铵供给周围的浮游生物。周围的浮游生物可供养殖生物食用,浮游生物也起到固碳作用。The clean cogeneration module is equipped with an OTEC system. The OTEC system discharges part of the mixed seawater into the sea through the mixed seawater pipeline. The mixed seawater discharged into the sea is rich in inorganic nutrients such as nitrates, phosphates, and silicates, which can improve The content of nutrients in the breeding area; the other part is sent to the seawater desalination system, the seawater desalination system generates fresh water and concentrated seawater, the concentrated seawater is sent to the carbon fixation system, and the fresh water is electrolyzed to generate oxygen and hydrogen, and the hydrogen is sent to the ammonia production system to produce nitrogen The system supplies the generated nitrogen to the ammonia production system, the ammonia production system transports the generated liquid ammonia to the OTEC system, and the generated ammonia gas to the carbon fixation system, the carbon fixation system is equipped with a CCS device, so The CCS device mixes the captured CO 2 with the ammonia gas and the concentrated seawater, and the ammonium chloride formed supplies the surrounding plankton. The surrounding plankton can be eaten by the farmed organisms, and the plankton also play a role in carbon sequestration.
其余所述基础框架上方架设有网箱框架,养殖网箱位于所述网箱框架内,所述网箱框架顶端固定有电动绞车,所述电动绞车通过控制室内的控制系统控制,缆绳绕过所述电动绞车与所述养殖网箱连接,所述网箱框架上设置有竖向的导轨,所述养殖网箱带有与所述导轨相配合的滑轮,所述养殖网箱之间设置有人行通道。其余的基础框架均为养殖区域,三角形养殖区域之间设置有供人通行的通道。A net cage frame is erected above the rest of the basic frame, and the breeding net cage is located in the net cage frame, and an electric winch is fixed on the top of the net cage frame, and the electric winch is controlled by the control system in the control room. The electric winch is connected with the culture net cage, the cage frame is provided with a vertical guide rail, the culture net cage has a pulley matched with the guide rail, and a walkway is arranged between the culture net cages. aisle. The rest of the basic framework is the breeding area, and there are passages for people to pass between the triangle breeding areas.
上述一种海上浮式清洁能源生产及生物固碳平台,更进一步地,所述OTEC系统带有OTEC蒸发器,所述OTEC蒸发器分别与温水泵、液氨泵连接,所述OTEC蒸发器通过管路依次与OTEC涡轮机、OTEC冷凝器、液氨泵连接后回流至所述OTEC蒸发器,形成第一循环网,所述OTEC冷凝器连接有冷水泵,冷水泵通过管路依次与制氨系统、海水淡化系统连接,所述冷水泵连接的冷水管伸入海底,所述温水泵连接的温水管连通海面。工质氨通过液氨泵泵入OTEC蒸发器,与通过温水泵从海洋表层抽取的25~27℃温海水换热,换热后的液氨变为气态,进入OTEC涡轮机,推动涡轮机将内能转换为机械能后产生电能,此处电能通过海底电缆输送上岸并网供电。经过OTEC涡轮机做功后的氨气进入OTEC冷凝器,在冷凝器中与通过冷水泵从海洋1000米深处抽取的冷海水换热,此处海水温度恒定在5℃左右,换热后的氨气变为液氨进入下一次循环。The above-mentioned offshore floating clean energy production and biological carbon sequestration platform, furthermore, the OTEC system has an OTEC evaporator, and the OTEC evaporator is connected to a warm water pump and a liquid ammonia pump respectively, and the OTEC evaporator passes through The pipeline is connected with OTEC turbine, OTEC condenser and liquid ammonia pump in turn, and then returns to the OTEC evaporator to form the first circulation network. The OTEC condenser is connected with a cold water pump, which is connected with the ammonia production system in turn through the pipeline. , Seawater desalination system connection, the cold water pipe connected to the cold water pump extends into the seabed, and the warm water pipe connected to the warm water pump communicates with the sea surface. The working fluid ammonia is pumped into the OTEC evaporator through the liquid ammonia pump, and exchanges heat with the warm seawater at 25-27°C drawn from the ocean surface by the warm water pump. After being converted into mechanical energy, electrical energy is generated, where the electrical energy is transported ashore through submarine cables and connected to the grid for power supply. The ammonia gas after the work done by the OTEC turbine enters the OTEC condenser, where it exchanges heat with the cold seawater drawn from the ocean at a depth of 1,000 meters through the cold water pump. The temperature of the seawater here is constant at about 5°C. Become liquid ammonia and enter the next cycle.
上述一种海上浮式清洁能源生产及生物固碳平台,更进一步地,所述OTEC蒸发器通过管路与海水淡化系统连接。In the aforementioned offshore floating clean energy production and biological carbon sequestration platform, further, the OTEC evaporator is connected to a seawater desalination system through pipelines.
上述一种海上浮式清洁能源生产及生物固碳平台,更进一步地,制氨系统通过管路分别与储氨罐、固碳系统连接,储氨罐通过管路依次与液氨泵、OTEC蒸发器连接。The above-mentioned offshore floating clean energy production and biological carbon fixation platform, further, the ammonia production system is connected to the ammonia storage tank and the carbon fixation system through pipelines, and the ammonia storage tank is sequentially connected to the liquid ammonia pump and OTEC evaporation through the pipeline device connection.
上述一种海上浮式清洁能源生产及生物固碳平台,更进一步地,所述甲板上设置有二氧化碳存储罐,所述CCS装置将捕捉到的二氧化碳存储在所述二氧化碳存储罐内。In the aforementioned offshore floating clean energy production and biological carbon sequestration platform, further, the deck is provided with a carbon dioxide storage tank, and the CCS device stores the captured carbon dioxide in the carbon dioxide storage tank.
上述一种海上浮式清洁能源生产及生物固碳平台,更进一步地,海水淡化系统伸出有支管路与制氨系统连接。In the aforementioned offshore floating clean energy production and biological carbon sequestration platform, further, the seawater desalination system has a branch pipeline connected to the ammonia production system.
上述一种海上浮式清洁能源生产及生物固碳平台,更进一步地,所述基础框架的数量为六个,六个所述基础框架组成整体呈六边形的平台。In the aforementioned offshore floating clean energy production and biological carbon sequestration platform, further, the number of the base frames is six, and the six base frames form a hexagonal platform as a whole.
上述一种海上浮式清洁能源生产及生物固碳平台,更进一步地,所述设备间内设置有压载泵及压载系统,所述压载泵与所述压载舱连接,通过所述压载系统控制所述压载泵调节所述压载舱内的压载水位。The above-mentioned offshore floating clean energy production and biological carbon sequestration platform, furthermore, a ballast pump and a ballast system are arranged in the equipment room, the ballast pump is connected to the ballast tank, and through the The ballast system controls the ballast pump to adjust the ballast water level in the ballast tank.
上述一种海上浮式清洁能源生产及生物固碳平台,更进一步地,所述水下浮体是四个,对称固定在所述下层浮体支撑杆上。In the aforementioned offshore floating clean energy production and biological carbon sequestration platform, further, there are four underwater floating bodies, which are symmetrically fixed on the support rods of the lower floating bodies.
上述一种海上浮式清洁能源生产及生物固碳平台,更进一步地,所述垂直轴发电机柱上固定有系泊系统,所述系泊系统带有系泊缆,所述系泊缆自由端连接有锚,所述系泊缆上还固定有浮子。浮子可以改善系泊缆线型及受力。锚与海床固定,使平台漂浮于指定海域。The above-mentioned offshore floating clean energy production and biological carbon sequestration platform, furthermore, a mooring system is fixed on the vertical axis generator column, and the mooring system has a mooring cable, and the mooring cable is free An anchor is connected to the mooring line, and a buoy is also fixed on the mooring line. Floats can improve mooring line shape and force. The anchor is fixed to the seabed to make the platform float in the designated sea area.
本发明的有益效果是:The beneficial effects of the present invention are:
1、本浮式系统将绿色能源转化为电能为系统提供动力,不但清洁环保而且适用于远岸浮式系统自存。对于作为电能输出单元的海水温差能系统,其内耗50%左右的电力由风光互补发电系统提供,可大大提高并网供电的效率。1. The floating system converts green energy into electric energy to provide power for the system, which is not only clean and environmentally friendly, but also suitable for self-storage of offshore floating systems. For the seawater temperature difference energy system as an electric energy output unit, about 50% of its internal power consumption is provided by a wind-solar hybrid power generation system, which can greatly improve the efficiency of grid-connected power supply.
2、本浮式系统生产的清洁能源既可作为产品输出,也可参与到系统固碳。2. The clean energy produced by the floating system can be used as a product output, and can also participate in the carbon sequestration of the system.
3、本浮式系统的利用海洋温差能发电系统废弃的混合海水,进行海水淡化及后续的清洁能源生产、海产养殖,清洁能源及副产品又可进行固碳,减低运行成本,提高系统本身的经济适用性。3. The floating system utilizes the mixed seawater discarded by the ocean temperature difference power generation system for seawater desalination and subsequent clean energy production and mariculture. Clean energy and by-products can also be used for carbon sequestration, reducing operating costs and improving the economy of the system itself applicability.
4、本浮式系统固碳方式采用化学固碳和生物固碳两种方式。改变以往的超临界二氧化碳海底盐水层封存和深海直接注入二氧化碳封存的海洋固碳方式。本系统采用的固碳方式更为稳定可靠,不会对海洋产生酸化的影响,同时带来可观的经济效益。4. The carbon fixation method of this floating system adopts chemical carbon fixation and biological carbon fixation. Change the previous marine carbon sequestration methods of supercritical carbon dioxide seabed saline layer storage and deep sea direct injection of carbon dioxide storage. The carbon sequestration method adopted by this system is more stable and reliable, will not have an acidification effect on the ocean, and will bring considerable economic benefits at the same time.
附图说明Description of drawings
图1是本发明侧视结构示意图;Fig. 1 is a side view structural representation of the present invention;
图2是本发明立体结构示意图;Fig. 2 is a schematic diagram of the three-dimensional structure of the present invention;
图3是本发明俯视结构示意图;Fig. 3 is a schematic view of the top view structure of the present invention;
图4是连接副的结构示意图;Fig. 4 is the structural representation of connection pair;
图5是本发明的系统示意图;Fig. 5 is a schematic diagram of the system of the present invention;
图6是扩充两台风力发电机后的平台示意图;Fig. 6 is a schematic diagram of the platform after expanding two wind turbines;
图7是扩充四台风力发电机后的平台示意图;Fig. 7 is the platform schematic diagram after expanding four wind turbines;
其中:1-OTEC蒸发器、2-OTEC涡轮机、3-OTEC冷凝器、4-液氨泵、5-冷水泵、6-温水泵、7-储氨罐、8-制氮系统、9-制氨系统、10-蓄电池、11-海水淡化系统、12-垂直轴发电机柱、13-光伏电池板、14-连接副、15-网箱框架、16-养殖网箱、17-设备间、18-吊机、19-生活楼、21-OTEC系统、22-人行通道、23-甲板、24-系泊缆、25-浮子、26-锚、27-水下浮体、28-浮体支撑杆、29-二氧化碳储存罐、30-控制室、33-温水管路、34-冷水管路、1401-套环、1402-连接环、1403-横向连接轴、1404-纵向连接轴。Among them: 1-OTEC evaporator, 2-OTEC turbine, 3-OTEC condenser, 4-liquid ammonia pump, 5-cold water pump, 6-warm water pump, 7-ammonia storage tank, 8-nitrogen system, 9-system Ammonia system, 10-battery, 11-seawater desalination system, 12-vertical axis generator column, 13-photovoltaic battery panel, 14-connection pair, 15-net cage frame, 16-culture cage, 17-equipment room, 18 -crane, 19-living building, 21-OTEC system, 22-walkway, 23-deck, 24-mooring cable, 25-float, 26-anchor, 27-underwater floating body, 28-floating body support rod, 29 -carbon dioxide storage tank, 30-control room, 33-warm water pipeline, 34-cold water pipeline, 1401-collar, 1402-connecting ring, 1403-horizontal connecting shaft, 1404-longitudinal connecting shaft.
具体实施方式Detailed ways
结合附图对本发明做进一步说明。The present invention will be further described in conjunction with the accompanying drawings.
如图1、2所示的一种海上浮式清洁能源生产及生物固碳平台,其适用于低纬度地区水深大于800米的深海区域,平台由六个三角形基础框架组成整体呈六边形的平台,基础框架由三个垂直轴发电机柱组成,三个垂直轴发电机柱之间通过上层浮体支撑杆和下层浮体支撑杆固定连接,上层浮体支撑杆位于海面上方,下层浮体支撑杆位于海面下方,浮体支撑杆通过连接副与垂直轴发电机柱连接,下层浮体支撑杆之间固定有多个水下浮体,水下浮体带有多个压载舱及空舱。As shown in Figures 1 and 2, an offshore floating clean energy production and biological carbon sequestration platform is suitable for deep sea areas with a water depth greater than 800 meters in low latitudes. The platform is composed of six triangular basic frames and is hexagonal in shape The platform and the foundation frame are composed of three vertical axis generator columns. The three vertical axis generator columns are fixedly connected by the upper floating body support rod and the lower floating body support rod. The upper floating body support rod is located above the sea surface, and the lower floating body support rod is located on the sea surface. Below, the support rods of the floating body are connected to the vertical axis generator column through the connecting pair, and a plurality of underwater floating bodies are fixed between the supporting rods of the lower floating body, and the underwater floating bodies have multiple ballast tanks and empty tanks.
连接副带有圆形套环,如图4所示,套环套在垂直轴发电机柱上,沿套环周向等间距设置有六个连接环,连接环为开口连接环,连接环通过横向连接轴与套环连接,连接环通过纵向连接轴与浮体支撑杆连接。甲板上、靠近垂直轴发电机柱处,固定有多个光伏电池板,垂直轴发电机、光伏电池板与蓄电池连接。垂直轴发电机、光伏电池板将生成的电储存在蓄电池内,将风能及太阳能转化为电能,并将两种不稳定能源产生的电能存储于蓄电池中,为平台系统运转提供稳定的动力来源,解决发电系统与耗电装置供需不平的问题。The connecting pair has a circular collar, as shown in Figure 4, the collar is set on the vertical axis generator column, and six connecting rings are arranged at equal intervals along the circumferential direction of the collar, the connecting rings are split connecting rings, and the connecting rings pass through The transverse connecting shaft is connected with the collar, and the connecting ring is connected with the support bar of the floating body through the longitudinal connecting shaft. A plurality of photovoltaic panels are fixed on the deck near the column of the vertical-axis generator, and the vertical-axis generator, the photovoltaic panel and the storage battery are connected. The vertical axis generator and photovoltaic panels store the generated electricity in the battery, convert wind energy and solar energy into electrical energy, and store the electrical energy generated by the two unstable energy sources in the battery to provide a stable power source for the operation of the platform system. Solve the problem of uneven supply and demand of power generation systems and power consumption devices.
如图3所示,一个基础框架的上层浮体支撑杆上铺设有甲板,甲板上设置有吊车、设备间及清洁联产模块,其余五个基础框架上方设置有网箱框架,养殖网箱位于网箱框架内,网箱框架顶端固定有电动绞车,电动绞车通过控制室内的控制系统控制,缆绳绕过电动绞车与养殖网箱连接,网箱框架上设置有竖向的导轨(未在图中显示),养殖网箱带有与导轨相配合的滑轮,养殖网箱之间设置有人行通道。As shown in Figure 3, a deck is laid on the support rods of the upper floating body of a foundation frame. Cranes, equipment rooms and cleaning and co-production modules are arranged on the deck. Cage frames are arranged above the other five foundation frames. Inside the box frame, an electric winch is fixed on the top of the cage frame, and the electric winch is controlled by the control system in the control room. ), the culture net cage has a pulley matched with the guide rail, and a walkway is arranged between the culture net cages.
如图5所示,清洁联产模块带有OTEC系统,OTEC系统将一部分混合海水通过混合海水管路排放至海中,另一部分输送至海水淡化系统,海水淡化系统生成淡水及浓海水,浓海水输送至固碳系统,淡水电解生成氧气和氢气,氢气输送给制氨系统,制氮系统将生成的氮气供给制氨系统,制氨系统将生成的液氨输送至OTEC系统,生成的氨气输送至固碳系统,固碳系统带有CCS装置,CCS装置将捕捉到的CO2与氨气、浓海水混合,形成的氯化铵供给周围的浮游生物。As shown in Figure 5, the clean cogeneration module is equipped with an OTEC system. The OTEC system discharges part of the mixed seawater into the sea through the mixed seawater pipeline, and the other part is sent to the seawater desalination system. The seawater desalination system generates fresh water and concentrated seawater, and the concentrated seawater is transported To the carbon fixation system, fresh water is electrolyzed to generate oxygen and hydrogen, and the hydrogen is sent to the ammonia production system. The nitrogen production system supplies the generated nitrogen to the ammonia production system. Carbon system, the carbon fixation system has a CCS device, and the CCS device mixes the captured CO 2 with ammonia gas and concentrated seawater, and the ammonium chloride formed supplies the surrounding plankton.
OTEC系统是利用海洋中可获得的热梯度转换电能的技术,按过程分为闭式循环、开式循环和混合循环系统。因本系统用于海上浮式结构,整体空间有限,所以采用整体装置更为紧凑的闭式循环系统。OTEC系统的工作流体选用物理性能、价格、系统成熟度更为优益的氨。基于氨工质的OTEC闭式循环系统,由OTEC蒸发器、OTEC涡轮机、OTEC冷凝器、储氨罐、液氨泵、温水泵、冷水泵组成。工质氨通过液氨泵泵入OTEC蒸发器,与通过温水泵从海洋表层抽取的温海水换热,此处海水温度在25~27℃,换热后的液氨变为气态,进入OTEC涡轮机,推动涡轮机将内能转换为机械能后产生电能,此处电能通过海底电缆输送上岸并网供电。经过OTEC涡轮机做功后的氨气进入OTEC冷凝器,在冷凝器中与通过冷水泵从海洋1000米深处抽取的冷海水换热,此处海水温度恒定在5℃左右,换热后的氨气变为液氨进入下一次循环。储氨罐中的液氨作为系统补充工质进入循环系统。将在OTEC蒸发器和OTEC冷凝器换热后的温海水和冷海水混合,此时海水温度在18℃左右,中温海水进入海水淡化系统及后续的固碳系统。海水淡化过程可以采用热过程或膜过程,海水淡化的产品为淡水及浓海水(含有高浓度氯化钠)。产生的淡水一部分可以作为产品输出,为浮式装置提供淡水来源。另一部分通过电解制氢和制氧,其公式如下:The OTEC system is a technology that converts electrical energy using the thermal gradient available in the ocean, and is divided into closed cycle, open cycle and mixed cycle systems according to the process. Because this system is used in offshore floating structures, the overall space is limited, so a closed circulation system with a more compact overall device is adopted. The working fluid of the OTEC system is ammonia, which has better physical performance, price and system maturity. The OTEC closed cycle system based on ammonia working fluid is composed of OTEC evaporator, OTEC turbine, OTEC condenser, ammonia storage tank, liquid ammonia pump, warm water pump and cold water pump. The working fluid ammonia is pumped into the OTEC evaporator through the liquid ammonia pump, and exchanges heat with the warm seawater drawn from the ocean surface through the warm water pump. The temperature of the seawater here is 25-27°C. , to drive the turbine to convert the internal energy into mechanical energy to generate electrical energy, where the electrical energy is transmitted to the shore through submarine cables and connected to the grid for power supply. The ammonia gas after the work done by the OTEC turbine enters the OTEC condenser, where it exchanges heat with the cold seawater drawn from the ocean at a depth of 1,000 meters through the cold water pump. The temperature of the seawater here is constant at about 5°C. Become liquid ammonia and enter the next cycle. The liquid ammonia in the ammonia storage tank enters the circulation system as a supplementary working medium for the system. The warm seawater and cold seawater after heat exchange in the OTEC evaporator and OTEC condenser are mixed. At this time, the seawater temperature is about 18°C, and the medium-temperature seawater enters the seawater desalination system and the subsequent carbon fixation system. The seawater desalination process can adopt thermal process or membrane process, and the products of seawater desalination are fresh water and concentrated seawater (containing high concentration of sodium chloride). A part of the fresh water produced can be exported as a product to provide a source of fresh water for the floating unit. The other part produces hydrogen and oxygen through electrolysis, and its formula is as follows:
2H2O→2H2(g)+O2(g)(通电)2H 2 O→2H 2 (g)+O 2 (g) (energized)
氢气和氧气一部分作为产品输出,另一部分参与到制氮和固碳系统中。同样考虑到浮式装置整体空间有限,制氮系统宜采用变压吸附制氮法(PSA),将空气中的氮气分离出来。产生的氮气一部分作为产品输出,另一部分与系统产生的氢气混合,采用哈伯法合成氨,基本公式如下:Part of the hydrogen and oxygen is output as products, and the other part participates in nitrogen production and carbon fixation systems. Also considering the limited overall space of the floating unit, the nitrogen production system should adopt the pressure swing adsorption nitrogen production method (PSA) to separate the nitrogen in the air. Part of the generated nitrogen is output as a product, and the other part is mixed with the hydrogen generated by the system to synthesize ammonia using the Haber method. The basic formula is as follows:
OTEC系统泵出的冷海水可作为制氨系统的冷却水来源,哈伯制氨法分离出的液氨一部分进入储氨罐作为OTEC系统的补充工质液体和作为产品输出,另一部分气化形成氨气进入固碳系统。气化后的氨气与CCS捕捉并运输到浮式系统的二氧化碳气体相继通入海水淡化系统产生的浓海水中,三者混合发生化学反应产生碳酸氢钠晶体沉淀和氯化铵,其公式如下:The cold sea water pumped out of the OTEC system can be used as the cooling water source of the ammonia production system. Part of the liquid ammonia separated by the Haber ammonia production process enters the ammonia storage tank as a supplementary working fluid for the OTEC system and is output as a product, and the other part is gasified to form Ammonia enters the carbon sequestration system. The gasified ammonia gas and the carbon dioxide gas captured by CCS and transported to the floating system are successively passed into the concentrated seawater produced by the seawater desalination system, and the three are mixed to undergo a chemical reaction to produce sodium bicarbonate crystal precipitation and ammonium chloride. The formula is as follows :
NaCl+NH3+H2O+CO2→NaHCO3↓+NH4ClNaCl+NH 3 +H 2 O+CO 2 →NaHCO 3 ↓+NH 4 Cl
碳酸氢纳晶体从溶液中分离后可以通过管道注入1000米以下的海水中封存或采用容器封存,影响碳酸氢纳在海水中封存的因素有PH值和海水密度(海水温度),深层海水PH值介于7.5到7.8之间,在此区间碳酸氢钠在海水中主要以钠离子和碳酸氢离子存在,是相对稳定的(根据Bjerrum碳酸盐系图)。并且在1000米以下的深水层,水温低(2-5℃)、密度几乎恒定。在周围海水温度和PH值都稳定的条件下,将碳酸氢钠晶体注入1000米以下的深水层,利用其与海水的密度差,溶解后高浓度的碳酸氢钠溶液将受重力影响沉入海底,达到固碳的作用,此为化学固碳。生物固碳为养殖体内无机碳含量较高海洋生物,利用无机碳在自然界中循环周期长的特点,达到固碳的目的。化学固碳的产物氯化铵作为氮肥供给浮式系统周边的浮游生物,可有效增加周边海域浮游生物容量,为养殖的腹足类、双壳类提供充足的食物来源,同时未被捕食的浮游生物死亡后沉入海底也可起到固碳效果。腹足类、双壳类生物可为经济效益高的鲍鱼、海螺、牡蛎、扇贝等,这两类生物壳体内无机成分-碳酸钙含量约占90%,在获取海洋食品的同时剩下的壳体可沉入海底进行碳封存,或用于制作工艺品、饰品、建筑材料等。OTEC系统排出的中低温海水小部分用于海水养殖,从深海泵出的冷水中包含丰富的硝酸盐、磷酸盐、硅酸盐等无机营养物质,其可提高养殖区域内营养物质含量。淡水电解产生的氧气可增加养殖区域内海水的含氧量,提高生物存活率。养殖的海生物为腹足类、双壳类生物,其可为经济效益高的鲍鱼、海螺、牡蛎、扇贝等,这两类生物壳体内无机成分-碳酸钙含量约占90%,在获取海洋食品的同时,剩下的壳体可沉入海底进行碳封存,或运输上岸用于制作工艺品、饰品、建筑材料等,达到了固碳的目的。After the sodium bicarbonate crystals are separated from the solution, they can be injected into seawater below 1000 meters through pipelines for storage or sealed in containers. Factors affecting the storage of sodium bicarbonate in seawater include pH value and seawater density (seawater temperature), deep seawater pH value Between 7.5 and 7.8, sodium bicarbonate mainly exists in seawater as sodium ions and bicarbonate ions, and is relatively stable (according to the Bjerrum carbonate system diagram). And in the deep water layer below 1000 meters, the water temperature is low (2-5 ℃), and the density is almost constant. Under the condition that the temperature and PH value of the surrounding seawater are stable, inject sodium bicarbonate crystals into the deep water layer below 1000 meters. Using the density difference between it and seawater, the dissolved high-concentration sodium bicarbonate solution will sink to the seabed under the influence of gravity. , to achieve the role of carbon fixation, which is chemical carbon fixation. Biological carbon sequestration is the cultivation of marine organisms with high inorganic carbon content in the body. It uses the characteristics of long cycle of inorganic carbon in nature to achieve the purpose of carbon sequestration. Ammonium chloride, the product of chemical carbon fixation, is used as nitrogen fertilizer to supply the plankton around the floating system, which can effectively increase the plankton capacity in the surrounding sea area, and provide sufficient food sources for the cultured gastropods and bivalves. The carbon sequestration effect can also be achieved by the sinking of organisms to the bottom of the sea after death. Gastropods and bivalves can be abalones, conchs, oysters, scallops, etc. with high economic benefits. The inorganic components in the shells of these two types of organisms - calcium carbonate content accounts for about 90%. The body can sink into the seabed for carbon sequestration, or be used to make handicrafts, ornaments, building materials, etc. A small part of the medium and low temperature seawater discharged from the OTEC system is used for mariculture. The cold water pumped from the deep sea contains rich inorganic nutrients such as nitrate, phosphate, and silicate, which can increase the content of nutrients in the farming area. The oxygen produced by freshwater electrolysis can increase the oxygen content of seawater in the culture area and improve the survival rate of organisms. The marine organisms cultured are gastropods and bivalves, which can be abalones, conchs, oysters, scallops, etc. with high economic benefits. At the same time as food, the remaining shells can be sunk into the seabed for carbon sequestration, or transported ashore for making handicrafts, ornaments, building materials, etc., to achieve the purpose of carbon sequestration.
本发明利用自身绿色能源循环,自给自足,基于绿色能源固碳的同时,提高海水养殖产量。将绿色能源转化为电能为系统提供动力,不但清洁环保而且适用于远岸浮式系统自存。对于作为电能输出单元的海水温差能系统,其内耗50%左右的电力由风光互补发电系统提供,可大大提高并网供电的效率。本发明所产生的氨既可作为产品输出,也可参与到系统固碳,从两方面解决碳达峰、碳中和问题。利用海洋温差能发电系统废弃的混合海水,进行海水淡化及后续的清洁能源生产、海产养殖,清洁能源及副产品又可进行固碳,减低运行成本,提高系统本身的经济适用性。本发明采用了化学固碳和生物固碳两种方式,改变以往的超临界二氧化碳海底盐水层封存和深海直接注入二氧化碳封存的海洋固碳方式。本系统采用的固碳方式更为稳定可靠,不会对海洋产生酸化的影响,同时带来可观的经济效益。The invention utilizes its own green energy cycle, is self-sufficient, and improves seawater aquaculture production while sequestering carbon based on green energy. Converting green energy into electric energy to power the system is not only clean and environmentally friendly, but also suitable for self-storage of off-shore floating systems. For the seawater temperature difference energy system as an electric energy output unit, about 50% of its internal power consumption is provided by a wind-solar hybrid power generation system, which can greatly improve the efficiency of grid-connected power supply. The ammonia produced by the invention can be output as a product, and can also participate in the carbon fixation of the system, so as to solve the problems of carbon peaking and carbon neutralization from two aspects. Use the mixed seawater discarded by the ocean thermal power generation system for desalination and subsequent clean energy production and mariculture. Clean energy and by-products can also be used for carbon sequestration, reducing operating costs and improving the economic applicability of the system itself. The present invention adopts two methods of chemical carbon fixation and biological carbon fixation, and changes the previous ocean carbon fixation methods of supercritical carbon dioxide seabed saline layer storage and deep sea direct injection of carbon dioxide for storage. The carbon sequestration method adopted by this system is more stable and reliable, will not have an acidification effect on the ocean, and will bring considerable economic benefits at the same time.
本平台同时利用垂直轴风力发电机的回转半径小,风场紧凑的特点,在位运行后,可根据电网需求,通过扩充垂直轴风机的数量提高并网供电量,如图6、图7所示,分别为扩充两台及四台风力发电机后的俯视示意图,风机扩充方式是通过浮体支撑杆上的公扣与垂直轴发电机柱形浮标上对接环的母扣连接实现。At the same time, this platform takes advantage of the small radius of gyration of the vertical axis wind turbine and the characteristics of compact wind field. After the on-site operation, it can increase the grid-connected power supply by expanding the number of vertical axis wind turbines according to the needs of the grid, as shown in Figure 6 and Figure 7. 2 and 4 are the top view schematic diagrams after the expansion of two and four wind turbines respectively. The expansion of the wind turbines is realized by connecting the male buckle on the support rod of the floating body with the female buckle of the docking ring on the vertical axis generator cylindrical buoy.
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