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CN115477812A - High-elasticity crosslinked polypropylene foam material and preparation method thereof - Google Patents

High-elasticity crosslinked polypropylene foam material and preparation method thereof Download PDF

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Publication number
CN115477812A
CN115477812A CN202211239821.1A CN202211239821A CN115477812A CN 115477812 A CN115477812 A CN 115477812A CN 202211239821 A CN202211239821 A CN 202211239821A CN 115477812 A CN115477812 A CN 115477812A
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polypropylene
parts
weight
foam material
elasticity
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陈志光
元吉玉
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Anhui Hongnuo New Materials Co ltd
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Anhui Hongnuo New Materials Co ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102Azo-compounds
    • C08J9/103Azodicarbonamide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0038Use of organic additives containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/04N2 releasing, ex azodicarbonamide or nitroso compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • C08J2323/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2451/00Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2451/06Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond

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  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
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Abstract

The invention provides a high-elasticity cross-linked polypropylene foam material and a preparation method thereof. The method adopts zinc dialkyl thiophosphate as a sensitization and low-temperature foaming inhibitor, and maleic anhydride grafted polypropylene, polypropylene and low-density polyethylene are compounded to obtain the polypropylene foaming material with high heat resistance and mechanical strength. The method of the invention has the following advantages: the product has good heat resistance which can reach more than 120 ℃; (2) The product has high strength and apparent density less than 0.1g/cm 3 When the thickness is 1mm, the elastic modulus is more than 20MPa, and the Shore hardness is more than 60D; (3) Product cohesivenessThe corona surface tension can reach more than 39mN/m, the requirement of a gluing process is met, and the corona surface tension can be maintained for more than 6 months; (4) The obtained material has wide application in the fields of mechanical shock resistance, automotive upholstery, heat preservation pipes, electronic equipment and the like.

Description

High-elasticity crosslinked polypropylene foam material and preparation method thereof
Technical Field
The invention relates to a high-elasticity crosslinked polypropylene foam material and a preparation method thereof, belonging to the technical field of high polymer materials.
Background
The radiation cross-linked polyethylene foam plastic is a novel foam plastic with a closed cell structure between soft (polyurethane) foam plastic and hard (polystyrene) foam plastic, has a series of characteristics of excellent toughness, elasticity, flexibility, wear resistance, chemical corrosion resistance, low temperature resistance, good insulativity and the like, can be used as a good insulating, heat insulating, shockproof and buoyancy material, and is widely applied to various fields of industry, agriculture, buildings, transportation and the like. However, the PE foam plastic has poor mechanical properties, poor heat resistance (the maximum use temperature is only about 80 ℃), difficult degradation and the like, which limit the application of the PE foam material. Polypropylene (PP) foams have many excellent properties, including low cost, good temperature resistance, high melting point, high tensile modulus, low density, and good chemical resistance, and are "new" in the foaming industry. In terms of mechanical properties, PP has higher static bearing capacity than PE and higher impact toughness than PS. Polypropylene (PP) foams have attracted much attention because of their excellent heat resistance, mechanical properties, and environmental friendliness, and thus have become high-performance green foams as alternatives to PU, PE, and PS foams in advanced countries such as europe, america, and the sun.
Despite the superior properties, PP foaming is difficult and heavy, mainly because the molecular chains of ordinary PP are linear, and the biaxial stretching effect to which the cell walls are subjected during foaming causes the entanglement of the linear chains to be rapidly opened, and the molecular chains easily slide relatively, so that the stretching viscosity is low. Even if a small stress action is applied, the PP is greatly deformed, so that the PP is expressed as that the strength of a cell wall is low in the foaming process, the PP is easy to break, and meanwhile, a large amount of gas in the cell escapes and diffuses into the environment, and finally, the defects of the foamed product, such as cell wall thickness, non-uniform cell size, low foaming ratio and the like, are caused. Meanwhile, due to the high melting point of PP, the extrusion processing temperature is above 140 ℃, and the Ac foaming system of the traditional polyethylene can not be adopted in the high-temperature processing process.
Disclosure of Invention
In order to solve the technical problems, the application provides a high-elasticity crosslinked polypropylene foam material and a preparation method thereof, zinc dialkylthiophosphate is used as a sensitization and low-temperature foaming inhibitor, the affinity of long-chain alkyl and polyethylene is utilized to ensure the uniform dispersion of the components, the high complexing capacity of sulfur oxygen atoms to zinc ions is utilized to reduce the low-temperature activation performance of an AC foaming agent, inhibit the low-temperature decomposition of the AC foaming agent, greatly improve the extrusion processing temperature of the material, ensure the polypropylene to be fully melted and plasticized, a specific condensed state structure is formed by blending maleic acid graft copolymerization propylene, low-density polyethylene and polypropylene under a proper extrusion process, the entanglement of molecular chains is promoted, a crosslinking network is formed in an irradiation crosslinking process, the strength of a foaming melt is improved, and the corona durability of the material is improved by utilizing a polar component in a formula.
The foam material comprises 35 to 60 weight parts of polypropylene, 5 to 20 weight parts of maleic anhydride grafted polypropylene, 10 to 60 weight parts of low density polyethylene, 2 to 20 weight parts of azodicarbonamide foaming agent, 1 to 5 weight parts of zinc dialkyl thiophosphate and 0.5 to 4 weight parts of antioxidant. The foam material has high strength, elastic modulus of more than 20MPa, shore hardness of more than 60D, surface tension of more than 39mN/m after corona, and can be maintained for more than 6 months. Meanwhile, the foam material has the apparent density of 0.03-0.10 g/cm 3
In a preferred embodiment, the maleic anhydride grafted polypropylene is mainly prepared by graft copolymerization of polypropylene and maleic anhydride, and the corresponding maleic anhydride grafted polypropylene is obtained by firstly carrying out banburying reaction on 100 parts by mass of polypropylene, 5-30 parts by mass of maleic anhydride, and 0.5-2 parts by mass of a vulcanizing agent in a banbury mixer at 130-160 ℃ for 1-4 h, and then carrying out granulation and extrusion.
In a preferred embodiment, the zinc dialkylthiophosphate is mainly prepared by stirring phosphorus pentasulfide and alkyl alcohol at 60-100 ℃ for reaction for 5-12 h, cooling, slowly adding ammonia water to prepare ammonium salt, dissolving zinc chloride in a certain amount of deionized water, and mixing with an ammonium salt aqueous solution according to a ratio of 1: (2-3), reacting in water bath at 40-60 ℃ for 1-5 h, filtering, washing with ethanol and ethyl acetate, and drying to obtain the corresponding zinc dialkyl thiophosphate.
In a preferred embodiment, the polypropylene for graft copolymerization is a polypropylene copolymer, which comprises any one or a mixture of more of ethylene propylene copolymer, butylene propylene copolymer and other binary copolymers, and ethylene propylene butylene terpolymer, wherein the melt index (MI, 230 ℃/2.16 kg) of the polypropylene copolymer is 0.5-5 g/10min, and the Melting Point (MP) is 125-140 ℃;
in a preferred embodiment, the polypropylene has a density of 0.87 to 0.91g/cm 3 One or more compositions of general isotactic polypropylene with a melt index (MI, 230 ℃/2.16 kg) of 0.5-10 g/10 min.
In a preferred embodiment, the low density polyethylene comprises a polyethylene with a density of 0.901 to 0.922g/cm 3 General low density polyethylene with a melt index (MI, 230 ℃/2.16 kg) of 1-6 g/10min and a density of 0.905-0.930g/cm 3 One or more linear low density polyethylene compositions with melt index (MI, 230 ℃/2.16 kg) of 0.3-5 g/10 min;
the application also provides a preparation method of the high-strength crosslinked polyethylene foam material, which comprises the following steps:
the synthesis stage of maleic anhydride grafted polypropylene: carrying out banburying reaction on 100 parts by mass of polypropylene, 5-30 parts by mass of maleic anhydride and 0.5-2 parts by mass of vulcanizing agent in a banbury mixer at 130-160 ℃ for 1-4 h, and then granulating and extruding to obtain the corresponding maleic anhydride grafted polypropylene.
Zinc dialkylthiophosphate preparation stage: stirring phosphorus pentasulfide and alkyl alcohol at 60-100 ℃ for reaction for 5-12 h, cooling, slowly adding ammonia water to prepare ammonium salt, dissolving zinc chloride in a certain amount of deionized water, and mixing with an ammonium salt aqueous solution according to the weight ratio of 1: (2-3), reacting in water bath at 40-60 ℃ for 1-5 h, filtering, washing with ethanol and ethyl acetate, and drying to obtain the corresponding zinc dialkyl thiophosphate.
The preparation stage of the polypropylene foam comprises the following steps: the foam cotton material is prepared by adding 35-60 parts by weight of polypropylene, 5-20 parts by weight of maleic anhydride grafted polypropylene, 10-60 parts by weight of low-density polyethylene, 2-20 parts by weight of azodicarbonamide foaming agent, 1-5 parts by weight of zinc dialkylthiophosphate and 0.5-4 parts by weight of antioxidant to a screw extruder for plasticizing and extruding a master slice, and then respectively carrying out electronic radiation crosslinking treatment, foaming treatment and calendaring treatment on the master slice.
The application also provides the application of the irradiation crosslinking polypropylene foam material, the foam material can be used in the fields of mechanical shock resistance, automotive upholstery, heat preservation pipes, electronic equipment and the like, the thickness of the foam material is 0.1-4.5 mm, and the thickness deviation is within 10%; at least 2 layers of cells are included in the thickness direction.
Compared with the prior art, the invention has the following advantages:
(1) The product has good heat resistance which can reach more than 120 ℃;
(2) The product has high strength and apparent density less than 0.1g/cm 3 When the thickness is 1mm, the elastic modulus is more than 20MPa, and the Shore hardness is more than 60D;
(3) The product has high cohesiveness, the corona surface tension can reach more than 38mN/m, the requirement of a gluing process is met, and the product can be maintained for more than 6 months;
(4) The obtained material has wide application in the fields of mechanical shock resistance, automotive upholstery, heat preservation pipes, electronic equipment and the like.
The invention adopts zinc dialkyl thiophosphate as a sensitization and low-temperature foaming inhibitor, and maleic anhydride grafted polypropylene, polypropylene and low-density polyethylene are compounded to obtain the polypropylene foaming material with high heat resistance and mechanical strength, which is the most suitable method at present.
Detailed Description
The invention introduces zinc dialkyl thiophosphate as a sensitization and low-temperature foaming inhibitor into a formula of a polyethylene foam material, maleic anhydride grafted polypropylene, polypropylene and low-density polyethylene are compounded, and a three-dimensional cross-linked network is formed through irradiation cross-linking and high-temperature foaming, so that the high-heat-resistance and mechanical strength polypropylene foam material is prepared.
According to the invention, zinc dialkylthiophosphate is used as a sensitization and low-temperature foaming inhibitor, the extrusion processing temperature of the material is greatly increased, the polypropylene is ensured to be fully melted and plasticized, a specific condensed state structure is formed by blending the maleic acid graft copolymerization propylene, the low-density polyethylene and the polypropylene under a proper extrusion process, the molecular chain entanglement is promoted, a cross-linking network is formed by connecting in an irradiation cross-linking process, the strength of a foaming melt is improved, and the corona durability of the material is improved by utilizing a polar component in a formula.
The following detailed description of the preferred embodiments of the present invention is provided to provide a more clear understanding of the objects, features and advantages of the present invention.
All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
Wherein, it is required to be noted that:
(1) The elastic modulus is tested by measuring the bending property of GB/T9341-2008 plastic.
(2) The surface tension is tested by the wetting tension of the GB/T14216-2008 test sample.
(3) The invention adopts GB/T3682-2000 thermoplastic plastic melt mass flow rate and melt volume flow rate to measure and test the melt index
(4) The invention adopts GB/T1033-1986 plastic density and relative density test method to test the material density
(5) The surface hardness (Shore hardness) of the material is measured by using GB/T2411-2008 plastic and hard rubber and using a durometer to measure the indentation hardness
Example 1
Step 1 Zinc dialkylthiophosphate Synthesis
Stirring phosphorus pentasulfide and octanol for reaction for 10 hours at 90 ℃, adding water for dilution, cooling, slowly adding ammonia water to prepare ammonium salt, dissolving zinc chloride in deionized water to prepare 50% solution, and mixing the solution and an ammonium salt aqueous solution according to the ratio of 2: mixing the components according to a molar ratio of 1, reacting for 2 hours in a water bath at 45 ℃, filtering, washing with ethanol and ethyl acetate, and drying to obtain the corresponding zinc dioctylthiophosphate.
Step 2 preparation of maleic anhydride grafted Polypropylene
100 parts by mass of copolymerized polypropylene (PP 5050, taiwan plastic, MI (230 ℃/2.16 kg) 5g/10min, MP 132 ℃) 10 parts by mass of maleic anhydride and 1 part by mass of dicumyl peroxide are subjected to banburying reaction in an internal mixer at 140 ℃ for 2 hours, and then granulation and extrusion are carried out, so as to obtain the corresponding maleic anhydride grafted polypropylene.
Step 3, preparation of polypropylene foam
50 parts by weight of polypropylene (PP PPC 5660, dada France, 0.905 g/cm3, MI 7)) After 15 parts by weight of maleic anhydride grafted polypropylene, 35 parts by weight of low density polyethylene (LDPE, 2426H, zhonghai shell brand, 0.925g/cm < 3 >, MI (230 ℃/2.16 kg) of 1.9 g/10 min), 10 parts by weight of azodicarbonamide foaming agent, 2 parts by weight of zinc dialkyl thiophosphate and 1 part by weight of antioxidant 1010 are uniformly mixed, the mixture is added into a single-screw extruder for extrusion, the extrusion temperature is controlled to be 145-155 ℃, the screw rotation speed is controlled to be 20rpm, and the die head temperature is controlled to be 140 ℃, so that a master slice with the thickness of 0.2mm is obtained; then, carrying out irradiation crosslinking on the master slice by an electron accelerator, and controlling the irradiation dose to be 30kGy to form a crosslinked polymer network; finally, placing the crosslinked master slice in a foaming furnace for foaming, controlling the temperature of the foaming furnace to be 180-260 ℃ and the residence time of the crosslinked master slice to be 0.3min to obtain the high-strength irradiation crosslinked polypropylene foaming material with the apparent density of 0.07g/cm 3 The elastic modulus is 23MPa, the Shore hardness is 63D, the surface tension after corona is 41mN/m, the surface tension after placing for 6 months is 40 mN/m, and the polyethylene foam can be applied to the fields of mechanical shock resistance, automobile interior decoration, heat preservation pipes, electronic equipment and the like.
Examples 2 to 6
The same procedure as in example 1 was repeated except that a different copolymerized propylene was selected.
TABLE 1
Figure 847988DEST_PATH_IMAGE001
Examples 7 to 10
Different low density polyethylenes were chosen as in example 1, except for the following differences.
TABLE 2
Figure 889763DEST_PATH_IMAGE003
Examples 11 to 14
The same procedure as in example 1 was followed, except that different polypropylene was selected.
TABLE 3
Figure 590871DEST_PATH_IMAGE004
Comparative example 1
According to the embodiment 1, 50 parts by weight of polypropylene (PP PPC 5660, france Dadale, 0.905 g/cm3, MI 7), 15 parts by weight of maleic anhydride grafted polypropylene, 35 parts by weight of low density polyethylene (LDPE, 2426H, zhonghai shell brand, 0.925g/cm3, MI (230 ℃/2.16 kg) 1.9 g/10 min), 10 parts by weight of azodicarbonamide foaming agent and 1 part by weight of antioxidant 1010 are uniformly mixed and added into a single screw extruder for extrusion, the extrusion temperature is controlled to be 145-155 ℃, the screw rotation speed is 20rpm, the die head temperature is controlled to be 140 ℃, and after 30min of extrusion, the foaming agent is decomposed seriously, and a master slice cannot be obtained.
Comparative example 2
According to the embodiment 2, zinc dialkylthiophosphate is replaced by traditional zinc stearate, 50 parts by weight of polypropylene (PP PPC 5660, france dadale, 0.905 g/cm3, MI 7), 15 parts by weight of maleic anhydride grafted polypropylene, 35 parts by weight of low density polyethylene (LDPE, 2426H, mediterranean Shell, 0.925g/cm3, MI (230 ℃/2.16 kg) 1.9 g/10 min), 10 parts by weight of azodicarbonamide foaming agent and 1 part by weight of antioxidant 1010 are evenly mixed and then added into a single screw extruder for extrusion, the extrusion temperature is controlled to be 145-155 ℃, the screw rotation speed is 20rpm, the die head temperature is 140 ℃, and after 5min of extrusion, the foaming agent is seriously decomposed, and a master slice cannot be obtained.
Comparative example 3
According to example 3, polypropylene (PP PPC 5660, france Dadale, 0.905 g/cm3, MI 7) was replaced with polypropylene (PP PD702, riandersuckel, 0.9g/cm3, MI (230 ℃/2.16 kg) 35g/10 min), 50 parts by weight of polypropylene (PP PD702, riandersuckel, 0.9g/cm3, MI (230 ℃/2.16 kg) 35g/10 min), 15 parts by weight of maleic anhydride-grafted polypropylene, 35 parts by weight of low-density polyethylene (LDPE, 2426H, michelia (Mediterranean), 0.925g/cm3, MI (230 ℃/2.16 kg) 1.9 g/10 min), 10 parts by weight of azodicarbonamide foaming agent, 2 parts by weight of zinc dialkylthiophosphate, 1 part by weight of 1010 antioxidant were mixed uniformly and then added to a single screw extruder for extrusion, the extrusion temperature was controlled to 145 to 155 ℃, the screw rotation speed was 20rpm, the die temperature was 140 ℃, and a master batch having a thickness of 0.2mm was obtained; then, carrying out irradiation crosslinking on the master slice by an electron accelerator, and controlling the irradiation dose to be 30kGy to form a crosslinked polymer network; and finally, placing the crosslinked master slice in a foaming furnace for foaming, controlling the temperature of the foaming furnace to be 180-260 ℃, and keeping the residence time of the crosslinked master slice for 0.3min to obtain the high-strength irradiation crosslinked polypropylene foaming material, wherein the apparent density is 0.11g/cm & lt 3 & gt, the elastic modulus is 19MPa, the Shore hardness is 54D, the surface tension after corona is 38mN/m, and the surface tension after placing for 6 months is 32 mN/m. The melt-index high polypropylene has low molecular weight, irradiation crosslinking can not be well carried out, more degraded low molecular chains are formed, the melt strength is poor, holes are easy to open, a uniform bubble structure is difficult to form, and the apparent density and the hardness of the formed material are higher and lower.
The product prepared by the preparation method disclosed by the invention has good heat resistance, mechanical strength and long-acting cohesiveness.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and should not be taken as limiting the scope of the present invention, which is intended to cover any modifications, equivalents, improvements, etc. within the spirit and scope of the present invention.

Claims (10)

1. A high-elasticity crosslinked polypropylene foam material is characterized in that: comprises that
35-60 parts by weight of polypropylene
5-20 parts by weight of maleic anhydride grafted polypropylene
10-60 parts by weight of low-density polyethylene
2-20 parts by weight of azodicarbonamide foaming agent
1 to 10 parts by weight of zinc dialkylthiophosphate
0.5 to 4 parts by weight of an antioxidant.
2. The high-elasticity crosslinked polypropylene foam material as claimed in claim 1, wherein: the maleic anhydride grafted polypropylene is mainly prepared by carrying out graft copolymerization on polypropylene and maleic anhydride, and carrying out banburying reaction on 100 parts by mass of polypropylene, 5-30 parts by mass of maleic anhydride and 0.5-2 parts by mass of a vulcanizing agent in a banbury mixer at 130-160 ℃ for 1-4 h, and then carrying out granulation extrusion to obtain the corresponding maleic anhydride grafted polypropylene.
3. The high-elasticity crosslinked polypropylene foam material as claimed in claim 2, wherein: the polypropylene is copolymerized polypropylene, and comprises any one or a mixture of a binary copolymer such as ethylene-propylene copolymer, butylene-propylene copolymer and the like and an ethylene-propylene-butylene terpolymer, wherein the melt index (MI, 230 ℃/2.16 kg) of the copolymerized polypropylene is 0.5-5 g/10min, and the Melting Point (MP) of the copolymerized polypropylene is 125-140 ℃.
4. The high-elasticity crosslinked polypropylene foam material as claimed in claim 2, wherein: the vulcanizing agent is one or a composition of more than one of benzoyl peroxide, dicumyl peroxide, benzoic acid peroxide, methyl ethyl ketone peroxide, neodecanoic peroxide and tert-butyl peroxypivalate.
5. The high elasticity crosslinked polypropylene foam material as claimed in claim 1, wherein: the zinc dialkyl thiophosphate is mainly prepared by stirring phosphorus pentasulfide and alkyl alcohol at the temperature of 60-100 ℃ for reaction for 5-12 h, slowly adding ammonia water after cooling to prepare ammonium salt, then dissolving zinc chloride in a certain amount of deionized water, and mixing with an ammonium salt water solution according to the proportion of 1: (2-3), reacting in water bath at 40-60 ℃ for 1-5 h, filtering, washing with ethanol and ethyl acetate, and drying to obtain the corresponding zinc dialkyl thiophosphate.
6. The high-elasticity crosslinked polypropylene foam material as claimed in claim 5, wherein: the alkyl alcohol is one or more of hexanol, octanol, lauryl alcohol, cetyl alcohol, stearyl alcohol, etc.
7. The high-elasticity crosslinked polypropylene foam material as claimed in claim 1, wherein the low density polyethylene is 0.901 to 0.922g/cm in density 3 General low density polyethylene with melt index (MI, 230 ℃/2.16 kg) of 1-6 g/10min and density of 0.905-0.930 g/cm 3 One or more linear low density polyethylene compositions with a melt index (MI, 230 ℃/2.16 kg) of 0.3-5 g/10 min.
8. The high-elasticity crosslinked polypropylene foam material as claimed in claim 1, wherein: the density of the polypropylene is 0.87 to 0.91g/cm 3 One or more compositions of general isotactic polypropylene with a melt index (MI, 230 ℃/2.16 kg) of 0.5-10 g/10 min.
9. The high-elasticity crosslinked polypropylene foam material as claimed in claim 1, wherein: the antioxidant is one or a composition of more than one of pentaerythritol tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], octadecyl beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate, 1, 3-tris (2-methyl-4-hydroxy-5-tert-butylphenyl) butane, 1,3, 5-trimethyl-2, 4, 6-tris (3, 5-di-tert-butyl-4-hydroxybenzyl) benzene, butyl hydroxyanisole, dibutyl hydroxy toluene, propyl gallate and tert-butyl hydroquinone.
10. A method for preparing a high-elasticity crosslinked polypropylene foam material according to any one of claims 1 to 9, characterized in that: firstly, mixing the following components, adding the mixture into a screw extruder, and mixing and extruding the mixture to obtain a master slice;
35-60 parts by weight of polypropylene
5-20 parts by weight of maleic anhydride grafted polypropylene
10-60 parts by weight of low-density polyethylene
2-20 parts by weight of azodicarbonamide foaming agent
1 to 10 parts by weight of zinc dialkylthiophosphate
0.5 to 4 parts by weight of an antioxidant
Then, carrying out electron irradiation crosslinking on the master slice obtained in the step, and after the electron irradiation crosslinking, carrying out high-temperature foaming treatment on the obtained material, wherein the foaming is carried out in a foaming furnace at the temperature of 180-280 ℃ for 0.1-3 min, so as to obtain the high-heat-resistance and high-foaming polypropylene ethylene foam material;
the extrusion temperature of the screw extruder is 145-160 ℃, the screw rotating speed is 10-20 rpm, and the die head temperature is 140-145 ℃.
CN202211239821.1A 2022-10-11 2022-10-11 High-elasticity crosslinked polypropylene foam material and preparation method thereof Pending CN115477812A (en)

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