CN115265773A - Mid- and far-infrared broadband detection system based on whispering gallery mode microcavity - Google Patents
Mid- and far-infrared broadband detection system based on whispering gallery mode microcavity Download PDFInfo
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Abstract
本发明提供了一种基于回音壁模式微腔的中远红外光宽谱探测系统,涉及红外探测技术领域,包括:回音壁模式微腔部,回音壁微腔结构的表面涂覆有中远红外光吸收材料;激光光源部,用于发射探测光;光电探测部,用于检测回音壁模式微腔中的光信号;信号发生部,用于支持混频器向电压计提供电压信号。本发明通过涂覆在片上回音壁微腔表面的中远红外光吸收材料,将光能转换为热能,接着,热量由吸收层传导到微腔波导中,引起波导温度的变化,在热光效应的作用下,微腔模式的等效折射率发生变化,谐振频率发生漂移使得微腔的透射光功率发生变化并由光电探测器将光功率转换为电信号,实现了对中远红外光强度常温下的高灵敏探测。
The invention provides a mid- and far-infrared light wide-spectrum detection system based on a whispering gallery mode microcavity, and relates to the technical field of infrared detection. Material; laser light source part, used for emitting detection light; photoelectric detection part, used to detect the optical signal in the whispering gallery mode microcavity; signal generation part, used to support the mixer to provide voltage signal to the voltmeter. The invention converts light energy into heat energy by coating the mid- and far-infrared light absorbing material on the surface of the on-chip whispering gallery micro-cavity, and then the heat is conducted into the micro-cavity waveguide by the absorption layer, causing the temperature of the waveguide to change. Under the action, the equivalent refractive index of the microcavity mode changes, and the resonant frequency shifts, so that the transmitted optical power of the microcavity changes, and the optical power is converted into an electrical signal by the photodetector, which realizes the measurement of the mid- and far-infrared light intensity at room temperature. Highly sensitive detection.
Description
技术领域technical field
本发明涉及红外探测技术领域,具体而言,涉及一种基于回音壁模式微腔的中远红外光宽谱探测系统。The invention relates to the technical field of infrared detection, in particular to a mid-to-far infrared wide-spectrum detection system based on a whispering gallery mode microcavity.
背景技术Background technique
中远红外波段,尤其是太赫兹波段的电磁波,长期以来由于缺乏高性能的辐射源与高灵敏度的有效探测手段,与微波和可见、近红外波段的光波相比,仍未得到充分的研究和开发利用。然而,中远红外波段在公共安全、无线通信、生物效应、生物医学成像、信息技术等领域具有十分重要的应用前景。如人体的自发辐射光就处于中远红外波段,除了可以用来测量人体温度外,其光谱中包含的丰富信息有望反映出人体的健康和心理状态。此外,大分子振动、转动的跃迁频率,处于凝聚态物质的声子频率以及某些半导体材料中载流子的响应频率,都处于中远红外波段之中。Compared with microwaves, visible and near-infrared light waves, electromagnetic waves in the mid-to-far infrared band, especially the terahertz band, have not been fully researched and developed for a long time due to the lack of high-performance radiation sources and high-sensitivity effective detection methods. use. However, the mid-to-far infrared band has very important application prospects in the fields of public security, wireless communication, biological effects, biomedical imaging, and information technology. For example, the spontaneous radiation of the human body is in the mid-to-far infrared band. In addition to being used to measure the temperature of the human body, the rich information contained in its spectrum is expected to reflect the health and psychological state of the human body. In addition, the transition frequency of vibration and rotation of macromolecules, the phonon frequency of condensed matter, and the response frequency of carriers in some semiconductor materials are all in the mid-to-far infrared band.
中远红外波段位于传统研究中微波电子学向可见、近红外光子学的过渡阶段,这个波段具有一些特殊的性质,不能直接采用现有的微波或可见、近红外光的高灵敏度探测技术。目前,中远红外波的探测主要通过热敏元件,如辐射热计、热释电探测器,或对应波段的半导体光敏元件实现,如PbS、HgCdTe、InAsSb、InAs等。然而,这两种中远红外波段的直接探测器件都存在着一些难以避免的问题。对于热敏元件而言,虽然其本身价格便宜,但其较低的灵敏度严格限制了它的应用范围。而半导体探测器虽然可以做到较高的灵敏度,但其在常温下具有很高的噪声等级而必须采取多级的热电冷却器将温度降至超低温度下工作,导致中远红外半导体探测系统往往十分笨重,包含复杂的制冷系统,无法做到开机即用,成本也被极大的提高。The mid-to-far infrared band is located in the transition stage from microwave electronics to visible and near-infrared photonics in traditional research. This band has some special properties and cannot directly use the existing high-sensitivity detection technology of microwave or visible and near-infrared light. At present, the detection of mid- and far-infrared waves is mainly realized by thermal sensitive elements, such as bolometers, pyroelectric detectors, or semiconductor photosensitive elements of corresponding wavelength bands, such as PbS, HgCdTe, InAsSb, InAs, etc. However, there are some unavoidable problems in these two kinds of direct detection devices in the middle and far infrared bands. For the thermal element, although its own price is cheap, its lower sensitivity strictly limits its application range. Although semiconductor detectors can achieve high sensitivity, they have a high noise level at room temperature and must use multi-stage thermoelectric coolers to lower the temperature to work at ultra-low temperatures, resulting in mid-to-far infrared semiconductor detection systems. It is bulky and contains a complex refrigeration system, which cannot be used immediately after startup, and the cost is also greatly increased.
因此,如何设计一种常温下具有较高灵敏度的中远红外探测器件成为需要解决的技术问题。Therefore, how to design a mid-to-far infrared detection device with high sensitivity at room temperature has become a technical problem to be solved.
发明内容Contents of the invention
本发明旨在至少解决上述现有技术或相关技术中存在的技术问题之一,提供了一种基于回音壁模式微腔的中远红外光宽谱探测系统,不但实现了对中远红外光强度常温下的高灵敏探测,还具有集成度高,体积小等优点。The present invention aims to solve at least one of the technical problems in the above-mentioned prior art or related technologies, and provides a mid-far infrared light broadband detection system based on a whispering gallery mode microcavity, which not only realizes the detection of mid-far infrared light intensity at room temperature High sensitivity detection, also has the advantages of high integration, small size and so on.
本发明是通过以下技术方案予以实现:一种基于回音壁模式微腔的中远红外光宽谱探测系统,包括:回音壁模式微腔部,设有回音壁微腔结构,用于接收待测的中远红外光,回音壁微腔结构的表面涂覆有中远红外光吸收材料;激光光源部,设有激光器和电光相位调制器,通过光纤连接回音壁模式微腔部,用于发射探测光;光电探测部,设有光电探测器和混频器,光电探测器的输入侧通过光纤与回音壁模式微腔部连接,光电探测器的输出侧与混频器电连接,用于检测回音壁模式微腔中的光信号;信号发生部,设有信号发生器,分别连接激光光源部和光电探测部,用于产生调制电信号,一路调制电信号驱动电光相位调制器,另一路调制电信号发送至混频器,以便于混频器向电压计提供电压信号。The present invention is realized through the following technical solutions: a mid-to-far infrared wide-spectrum detection system based on a whispering gallery mode microcavity, comprising: a whispering gallery mode microcavity part, which is provided with a whispering gallery microcavity structure for receiving In the mid-to-far infrared light, the surface of the whispering gallery microcavity structure is coated with mid-to-far infrared light absorbing materials; the laser light source part is equipped with a laser and an electro-optical phase modulator, which is connected to the whispering gallery mode microcavity part through an optical fiber to emit detection light; The detection part is provided with a photodetector and a mixer. The input side of the photodetector is connected to the microcavity of the whispering gallery mode through an optical fiber, and the output side of the photodetector is electrically connected to the mixer for detecting the microcavity of the whispering gallery mode. The optical signal in the cavity; the signal generating part is equipped with a signal generator, which is respectively connected to the laser light source part and the photoelectric detection part, and is used to generate a modulated electrical signal. One modulated electrical signal drives the electro-optic phase modulator, and the other modulated electrical signal is sent to mixer so that the mixer provides a voltage signal to the voltmeter.
在该技术方案中,激光光源部发射的激光经过回音壁模式微腔部后传输至光电探测部,其中,该激光由透镜光纤耦合进出回音壁微腔模式微腔部中的波导,片上波导与环形微腔通过倏逝场的方式进行耦合。信号发生部产生的正弦调制信号分为两路,一路驱动电光相位调制器,另一路与光电探测部的电信号在混频器中进行混频,混频后产生的电信号便于通过电压计进行测量。其中,回音壁微腔是一种微型的光学谐振器,它利用全内反射将光场限制在一个很小的模式体积内。光波与回音壁微腔的谐振,必须满足腔内模式光程长为光波长的整数倍这一关系。由于光的波长极短,光程长的极小变化就会影响到微腔谐振状态的明显变化。得益于腔光谐振条件对光频的超高灵敏性和光波的超高频率,从而实现对中远红外光强度常温下的高灵敏探测。本质上是外界环境的变化引起微腔模式的光程长或是品质因子(Quality Factor,Q值)发生变化,从而通过光与微腔的谐振状态来解读出探测量。In this technical solution, the laser light emitted by the laser light source part passes through the microcavity part of the whispering gallery mode and then is transmitted to the photodetection part, wherein the laser light is coupled into and out of the waveguide in the microcavity part of the microcavity part of the whispering gallery mode by a lens fiber, and the on-chip waveguide and The ring microcavities are coupled through the evanescent field. The sinusoidal modulation signal generated by the signal generation part is divided into two routes, one route drives the electro-optic phase modulator, and the other route is mixed with the electrical signal of the photodetector part in the mixer, and the electrical signal generated after mixing is convenient to be measured by a voltmeter. Measurement. Among them, the whispering gallery microcavity is a miniature optical resonator, which uses total internal reflection to confine the light field in a small mode volume. The resonance between the light wave and the whispering gallery microcavity must satisfy the relationship that the optical path length of the intracavity mode is an integer multiple of the light wavelength. Due to the extremely short wavelength of light, a very small change in the optical path length will affect a significant change in the resonant state of the microcavity. Thanks to the ultra-high sensitivity of the cavity optical resonance condition to the optical frequency and the ultra-high frequency of the light wave, the highly sensitive detection of the mid-to-far infrared light intensity at room temperature is realized. Essentially, changes in the external environment cause changes in the optical path length or quality factor (Q value) of the microcavity mode, so that the detection amount can be interpreted through the resonance state of the light and the microcavity.
根据本发明提供的基于回音壁模式微腔的中远红外光宽谱探测系统,优选地,回音壁微腔结构的波导材料为硅,中远红外吸收材料为聚二甲基硅氧烷(Polydimethylsiloxane,PDMS)。According to the mid-to-far infrared wide-spectrum detection system based on the whispering gallery mode microcavity provided by the present invention, preferably, the waveguide material of the whispering gallery microcavity structure is silicon, and the mid-to-far infrared absorption material is polydimethylsiloxane (Polydimethylsiloxane, PDMS ).
在该技术方案中,回音壁微腔结构采用刻蚀工艺制作,优选的刻蚀材料为绝缘衬底上的硅(Silicon-On-Insulator,SOI)片,回音壁微腔结构以SOI片作为基底,刻蚀工艺成熟,易于以现有技术手段制备;片上集成的波导耦合,极大提升了腔光耦合的稳定性,鲁棒性好,探测结果不易受外界环境的振动等影响。PDMS对宽谱范围的中远红外光都具有较强的吸收作用,可实现宽谱探测;PDMS可采用旋涂法进行涂敷,涂敷的厚度可以通过调节旋转器的转速、运行时间来实现较为精准的控制。本发明优选采用片上涂覆了PDMS的回音壁模式硅环腔作为热敏元件,相较于传统的中远红外热敏元件探测方案具有更高的灵敏度,并可在室温下工作。In this technical scheme, the microcavity structure of the whispering gallery is manufactured by etching process, and the preferred etching material is silicon (Silicon-On-Insulator, SOI) sheet on the insulating substrate, and the microcavity structure of the whispering gallery uses the SOI sheet as the substrate , the etching process is mature, and it is easy to prepare with the existing technical means; the integrated waveguide coupling on the chip greatly improves the stability of the cavity optical coupling, has good robustness, and the detection results are not easily affected by the vibration of the external environment. PDMS has a strong absorption effect on mid- and far-infrared light in a wide spectrum range, and can realize wide-spectrum detection; PDMS can be coated by spin coating, and the thickness of the coating can be achieved by adjusting the rotation speed and running time of the spinner. Precise control. The present invention preferably adopts the whispering gallery mode silicon ring cavity coated with PDMS on the chip as the thermal sensor, which has higher sensitivity than the traditional mid-far infrared thermal sensor detection scheme and can work at room temperature.
PDMS材料在中远红外波段具有很高的吸收率,可将中远红外波的光能转换为热能。然而其本身的热光系数为负值,涂覆在热光系数为正值的常见的二氧化硅微球腔上时,不仅涂层厚度不易控制,难以实现片上集成,两种材料相近的折射率会使得腔内光模式能量同时分布在两种材料内,此时腔模对温度的敏感性由两种材料的热光系数共同决定。两种材料相反符号的热光系数会使得热敏性下降,PDMS的高吸收系数也会显著影响到腔模的Q值,从而使得对中远红外光探测的灵敏度降低。此外,传统微腔探测系统中,往往需要对泵浦激光器的输出频率进行扫描,以透射谱的变化来检测腔光谐振态的变化从而获取出待测量,这无疑增大了系统的复杂度,需要对直接获取的数据进行算法上的处理,因此很难离开计算系统的辅助。本发明利用了激光器稳频中使用的PDH(Pound-Drever-Hall)技术,实现了对待测中远红外光功率的直接读出。PDMS material has a high absorption rate in the mid-to-far infrared band, which can convert the light energy of the mid-to-far infrared wave into heat energy. However, its own thermo-optic coefficient is negative. When it is coated on the common silica microsphere cavity with positive thermo-optic coefficient, not only the thickness of the coating is not easy to control, but also it is difficult to achieve on-chip integration. The refraction of the two materials is similar. The efficiency will make the energy of the optical mode in the cavity be distributed in the two materials at the same time, and the sensitivity of the cavity mode to temperature is determined by the thermo-optic coefficient of the two materials. The thermo-optic coefficients of the two materials with opposite signs will reduce the thermal sensitivity, and the high absorption coefficient of PDMS will also significantly affect the Q value of the cavity mode, thereby reducing the sensitivity to mid- and far-infrared light detection. In addition, in the traditional microcavity detection system, it is often necessary to scan the output frequency of the pump laser, and use the change of the transmission spectrum to detect the change of the optical resonance state of the cavity to obtain the measurement, which undoubtedly increases the complexity of the system. Algorithmic processing of directly acquired data is required, so it is difficult to do without the assistance of computing systems. The invention utilizes the PDH (Pound-Drever-Hall) technology used in laser frequency stabilization, and realizes the direct readout of the middle and far infrared light power to be measured.
根据本发明提供的基于回音壁模式微腔的中远红外光宽谱探测系统,优选地,回音壁模式微腔部还包括:光学滤波片,对应待测的中远红外光设置;聚焦透镜,设于光学滤波片下侧,将待测的中远红外光聚焦于回音壁微腔结构中。According to the mid-to-far infrared wide-spectrum detection system based on the whispering gallery mode microcavity provided by the present invention, preferably, the whispering gallery mode microcavity part further includes: an optical filter, which is set corresponding to the mid-to-far infrared light to be measured; a focusing lens, which is located at The lower side of the optical filter focuses the mid-to-far infrared light to be measured in the microcavity structure of the whispering gallery.
根据本发明提供的基于回音壁模式微腔的中远红外光宽谱探测系统,优选地,激光光源部还包括:光偏振控制器,设置在激光器与电光相位调制器之间。According to the mid-to-far infrared broadband detection system based on the whispering gallery mode microcavity provided by the present invention, preferably, the laser light source part further includes: a light polarization controller disposed between the laser and the electro-optical phase modulator.
根据本发明提供的基于回音壁模式微腔的中远红外光宽谱探测系统,优选地,信号发生部还包括:移相器,设置在信号发生器和混频器之间。According to the mid-to-far infrared broad-spectrum detection system based on the whispering gallery mode microcavity provided by the present invention, preferably, the signal generating part further includes: a phase shifter arranged between the signal generator and the mixer.
根据本发明提供的基于回音壁模式微腔的中远红外光宽谱探测系统,优选地,光电探测部还包括:带通滤波器,设置在光电探测器与混频器之间;低通滤波器,设置在混频器和电压计之间。According to the mid-to-far infrared wide-spectrum detection system based on the whispering gallery mode microcavity provided by the present invention, preferably, the photodetection part further includes: a band-pass filter arranged between the photodetector and the mixer; a low-pass filter , set between the mixer and the voltmeter.
根据本发明提供的基于回音壁模式微腔的中远红外光宽谱探测系统,优选地,回音壁微腔结构设计为方形的硅波导,截面尺寸为1×1μm,环腔直径30到100μm;聚二甲基硅氧烷的涂覆厚度为2.5μm。According to the mid-to-far infrared broadband detection system based on the whispering gallery mode microcavity provided by the present invention, preferably, the structure of the whispering gallery microcavity is designed as a square silicon waveguide with a cross-sectional size of 1×1 μm and a ring cavity diameter of 30 to 100 μm; The coating thickness of dimethylsiloxane was 2.5 μm.
根据本发明提供的基于回音壁模式微腔的中远红外光宽谱探测系统,优选地,激光器为窄线宽激光器,输出光为近红外光,输出波长包括1550nm波段,单频输出,激光的线宽小于10MHz。According to the mid-to-far infrared wide-spectrum detection system based on the whispering gallery mode microcavity provided by the present invention, preferably, the laser is a narrow linewidth laser, the output light is near-infrared light, the output wavelength includes a 1550nm band, single-frequency output, and the line of the laser The width is less than 10MHz.
在该技术方案中,以光波长为12.5μm为例,硅的折射率3.47左右,PDMS为1.68,两者折射率的差值(差值越大愈易满足光的全反射条件)保证了腔模式能量很少能分布在PDMS中,经过有限元法仿真分析,当泵浦光为1550nm时,1×1μm的涂覆有PDMS的硅波导,PDMS中基模能量的占比约为千分之二。因此,可以认为PDMS对腔模的Q值以及谐振条件的影响几乎可以忽略不计,PDMS的负热光系数不会降低探测系统的灵敏度。光波的极短波长与腔光谐振条件的极高敏感性,使得本发明对中远红外光的探测灵敏度高于传统的热敏探测器件,硅材料本身的高热光系数,可实现远强于传统二氧化硅微腔的热探测灵敏度。In this technical solution, taking the light wavelength of 12.5 μm as an example, the refractive index of silicon is about 3.47, and that of PDMS is 1.68. Mode energy can rarely be distributed in PDMS. After finite element method simulation analysis, when the pump light is 1550nm, the 1×1μm silicon waveguide coated with PDMS, the proportion of fundamental mode energy in PDMS is about one thousandth. two. Therefore, it can be considered that the influence of PDMS on the Q value of the cavity mode and the resonance conditions is almost negligible, and the negative thermo-optic coefficient of PDMS will not reduce the sensitivity of the detection system. The extremely short wavelength of the light wave and the extremely high sensitivity of the cavity optical resonance condition make the detection sensitivity of the present invention to the middle and far infrared light higher than that of the traditional heat-sensitive detection device, and the high thermo-optic coefficient of the silicon material itself can realize far stronger Thermal detection sensitivity of silicon oxide microcavities.
根据本发明提供的基于回音壁模式微腔的中远红外光宽谱探测系统,优选地,光电探测器为铟镓砷(InGaAs)光电探测器,工作波段为近红外光波段。According to the mid-to-far infrared wide-spectrum detection system based on the whispering gallery mode microcavity provided by the present invention, preferably, the photodetector is an indium gallium arsenide (InGaAs) photodetector, and the working band is the near-infrared light band.
根据本发明提供的基于回音壁模式微腔的中远红外光宽谱探测系统,优选地,信号发生器输出的调制电信号为正弦波调制信号,调制频率大于微腔模式的线宽。According to the mid-to-far infrared broadband detection system based on the whispering gallery mode microcavity provided by the present invention, preferably, the modulated electrical signal output by the signal generator is a sine wave modulation signal, and the modulation frequency is greater than the linewidth of the microcavity mode.
在该技术方案中,本发明采用激光器稳频中的PDH技术,借助电光相位调制和电路信号处理,将腔光谐振透射率对失谐量的洛伦兹响应转换为近似线性响应,从而可以通过电压计的示数直接读出红外光强度。In this technical solution, the present invention adopts PDH technology in laser frequency stabilization, and by means of electro-optical phase modulation and circuit signal processing, the Lorentz response of the cavity optical resonance transmittance to the detuning amount is converted into an approximate linear response, so that it can pass The indication of the voltmeter directly reads the infrared light intensity.
本发明取得的有益效果至少包括:传统的回音壁微腔传感方案中,测量谐振条件的变化往往需要扫描泵浦波长获取微腔模式的透射谱,无法直接获得待测值,本发明采用激光器稳频中的PDH(Pound-Drever-Hall)技术,借助电光相位调制和电路信号处理,将腔光谐振透射率对失谐量的洛伦兹响应转换为近似线性响应,从而可以通过电压计的示数直接读出红外光强度,不依赖于额外的计算机系统对获取的数据进行算法处理。采用涂覆了PDMS(聚二甲基硅氧烷,Polydimethylsiloxane,PDMS)的回音壁微腔(硅环腔)作为热敏元件,相较于传统的中远红外热敏元件探测方案具有更高的灵敏度,并可在室温下工作。PDMS材料在中远红外波段具有很高的吸收率,大大提升了检测精度。The beneficial effects obtained by the present invention include at least: in the traditional whispering gallery microcavity sensing scheme, the measurement of the change of the resonance condition often needs to scan the pump wavelength to obtain the transmission spectrum of the microcavity mode, and the value to be measured cannot be obtained directly. The present invention uses a laser The PDH (Pound-Drever-Hall) technology in frequency stabilization, with the help of electro-optic phase modulation and circuit signal processing, converts the Lorentz response of the cavity optical resonance transmittance to the detuning amount into an approximate linear response, so that the voltmeter can The display reads out the infrared light intensity directly, and does not rely on an additional computer system to perform algorithmic processing on the acquired data. The whispering gallery microcavity (silicon ring cavity) coated with PDMS (Polydimethylsiloxane, PDMS) is used as the thermal element, which has higher sensitivity than the traditional mid-far infrared thermal element detection scheme , and can work at room temperature. PDMS material has a high absorption rate in the mid-to-far infrared band, which greatly improves the detection accuracy.
附图说明Description of drawings
图1示出了根据本发明实施例的基于回音壁模式微腔的中远红外光宽谱探测系统的结构示意图。Fig. 1 shows a schematic structural diagram of a mid-far infrared light broadband detection system based on a whispering gallery mode microcavity according to an embodiment of the present invention.
图2示出了根据本发明实施例的基于回音壁模式微腔的中远红外光宽谱探测系统的回音壁微腔结构的横截面示意图。Fig. 2 shows a schematic cross-sectional view of a whispering gallery microcavity structure of a mid-far infrared light broadband detection system based on a whispering gallery mode microcavity according to an embodiment of the present invention.
图3示出了根据本发明实施例的探测结果图。Fig. 3 shows a graph of detection results according to an embodiment of the present invention.
具体实施方式Detailed ways
为了能够更清楚地理解本发明的上述目的、特征和优点,下面结合附图和具体实施方式对本发明进行进一步的详细描述。In order to understand the above-mentioned purpose, features and advantages of the present invention more clearly, the present invention will be further described in detail below in conjunction with the accompanying drawings and specific embodiments.
在本发明的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。对于本领域的普通技术人员而言,可以通过具体情况理解上述术语在本发明中的具体含义。In describing the present invention, it should be understood that the terms "center", "longitudinal", "transverse", "upper", "lower", "front", "rear", "left", "right", " The orientations or positional relationships indicated by "vertical", "horizontal", "top", "bottom", "inner" and "outer" are based on the orientations or positional relationships shown in the drawings, and are only for the convenience of describing the present invention and Simplified descriptions, rather than indicating or implying that the device or element referred to must have a particular orientation, be constructed and operate in a particular orientation, and thus should not be construed as limiting the invention. Those of ordinary skill in the art can understand the specific meanings of the above terms in the present invention based on specific situations.
如图1、图2和图3所示,本发明提供了一种基于回音壁模式微腔的中远红外光宽谱探测系统,包括:窄线宽激光器(1),光偏振控制器(2),电光相位调制器(3),回音壁模式微腔芯片(4),光电探测器(5),待测中远红外光辐射源(6),光学滤波片(7),聚焦透镜(8),信号发生器(9),移相器(10),电压计(11),低通滤波器(12),混频器(13),带通滤波器(14)。窄线宽激光器(1),光偏振控制器(2),电光相位调制器(3),回音壁模式微腔芯片(4),光电探测器(5)通过光纤依次连接在一起,其中,激光经由透镜光纤耦合进出微腔芯片。信号发生器(9)产生的正弦调制信号分为两路,一路驱动电光相位调制器(3),一路经由移相器(10)后与通过带通滤波器(14)的光电探测器(5)电信号在混频器(13)中进行混频,混频后产生的电信号通过低通滤波器(12)后最终由电压计(11)测量。待测中远红外光辐射源(6)所发出的红外光通过光学滤波片(7)获取出想要测量波段范围的红外光,光学微腔置于聚焦透镜(8)的焦点处。As shown in Figure 1, Figure 2 and Figure 3, the present invention provides a mid-to-far infrared light broadband detection system based on a whispering gallery mode microcavity, including: a narrow linewidth laser (1), an optical polarization controller (2) , an electro-optic phase modulator (3), a whispering gallery mode microcavity chip (4), a photodetector (5), a medium-to-far infrared radiation source to be measured (6), an optical filter (7), a focusing lens (8), Signal generator (9), phase shifter (10), voltmeter (11), low-pass filter (12), mixer (13), band-pass filter (14). A narrow linewidth laser (1), an optical polarization controller (2), an electro-optic phase modulator (3), a whispering gallery mode microcavity chip (4), and a photodetector (5) are sequentially connected together through an optical fiber, wherein the laser Coupled into and out of the microcavity chip via a lens fiber. The sinusoidal modulation signal generated by the signal generator (9) is divided into two paths, one path drives the electro-optic phase modulator (3), and the other path passes through the phase shifter (10) and passes through the photodetector (5) of the band-pass filter (14). ) electrical signals are mixed in the mixer (13), and the electrical signals generated after the mixing are passed through the low-pass filter (12) and finally measured by the voltmeter (11). The infrared light emitted by the middle and far infrared light radiation source (6) to be measured passes through the optical filter (7) to obtain the infrared light in the desired measurement band range, and the optical microcavity is placed at the focal point of the focusing lens (8).
对于回音壁微腔而言,它的谐振波长与微腔材料的折射率有关,有如下方程:For a whispering gallery microcavity, its resonant wavelength is related to the refractive index of the microcavity material, as follows:
mλ=2πRnmλ=2πRn
上式中,m为非零整数,λ为谐振波长,R为微腔半径,n为微腔模式的等效折射率。当腔体的温度发生变化时,由于热光效应的影响,微腔模式的等效折射率也会发生变化,从而引起谐振波长,即谐振光波的频率发生变化。如图3中(a)部分所示(微腔谐振的透射谱,腔光为临界耦合状态,当腔光完全谐振时,透过率为零),当微腔与光波长完全满足上式的数学关系时,微腔的透射光能量最低,保持泵浦波长不变,温度引发的谐振波长偏移会使得透过光强度发生变化,从而可以测量出红外光的强度。方案中,待测中远红外光辐射源发出的光经由滤波片后获取感兴趣的测量波段,通过聚焦透镜将待测红外光聚集在微腔上。微腔上涂覆的PDMS层对中远红外光具有很强的吸收,因此产生热量,从而引起谐振波长变化,最终导致透射光功率的变化。In the above formula, m is a non-zero integer, λ is the resonance wavelength, R is the radius of the microcavity, and n is the equivalent refractive index of the microcavity mode. When the temperature of the cavity changes, due to the thermo-optic effect, the equivalent refractive index of the microcavity mode will also change, thereby causing the resonant wavelength, that is, the frequency of the resonant light wave to change. As shown in part (a) of Figure 3 (the transmission spectrum of the microcavity resonance, the cavity light is in a critical coupling state, when the cavity light is fully resonant, the transmittance is zero), when the microcavity and light wavelength fully satisfy the above formula In the mathematical relationship, the transmitted light energy of the microcavity is the lowest, keeping the pump wavelength unchanged, the temperature-induced resonant wavelength shift will change the transmitted light intensity, so that the intensity of infrared light can be measured. In the scheme, the light emitted by the medium-to-far infrared radiation source to be measured passes through a filter to obtain the measurement band of interest, and the infrared light to be measured is concentrated on the microcavity through a focusing lens. The PDMS layer coated on the microcavity has a strong absorption of mid- and far-infrared light, so heat is generated, which causes the resonance wavelength to change, and finally leads to the change of the transmitted light power.
系统中,窄线宽激光器、光偏振控制器、电光相位调制器、回音壁模式微腔芯片、光电探测器通过光纤相连接。光偏振控制器用于控制泵浦光的偏振状态,实现对应微腔模式的高效率谐振,电光相位调制器则是用于为PDH技术提供边带。激光通过光纤透镜耦合进出芯片上的波导,光纤透镜与波导端口在实现高效耦合后,两者的位置被精确固定。In the system, a narrow-linewidth laser, an optical polarization controller, an electro-optic phase modulator, a whispering gallery mode microcavity chip, and a photodetector are connected through optical fibers. The optical polarization controller is used to control the polarization state of the pump light to achieve high-efficiency resonance corresponding to the microcavity mode, and the electro-optical phase modulator is used to provide sidebands for PDH technology. The laser light is coupled into and out of the waveguide on the chip through the fiber lens. After the fiber lens and the waveguide port are coupled efficiently, the positions of the two are precisely fixed.
微腔的透射谱随光频的响应是洛伦兹线型的,同一透射光强可对应两种不同的红外光强度,无法直接读出。因此采用PDH技术实现待测红外光强度的直接读出。具体过程是,光电探测器将接收到的微腔透射光信号转换为电信号,通过带通滤波器过滤掉噪声后与信号发生器产生的正弦信号进行混频。其中,移相器用于调整两路混频电信号的相位差,实现选择性获取PDH误差信号的实部或是虚部。混频后的电信号通过低通滤波器后由电压计接受,这样就实现了电信号随待测红外光强度的近似线性响应关系,可直接根据电压值读出中远红外光的强度,如图3中(b)部分所示:电路处理后获取的对应电压计的测量结果,每个点对应于不同的入射红外光功率,相邻两个点的功率差值为10μW。该探测结果的仿真参数设定为PDMS层厚度为2.5μm,环腔波导为1×1μm,直径为50μm,微腔的内禀Q值为1×105,注入微腔的泵浦激光波长为1550nm。The response of the transmission spectrum of the microcavity to the light frequency is Lorentzian, and the same transmitted light intensity can correspond to two different infrared light intensities, which cannot be read directly. Therefore, the PDH technology is used to realize the direct readout of the infrared light intensity to be measured. The specific process is that the photodetector converts the received microcavity transmitted light signal into an electrical signal, filters out the noise through a band-pass filter, and mixes it with the sinusoidal signal generated by the signal generator. Wherein, the phase shifter is used to adjust the phase difference of the two mixed frequency electrical signals, so as to selectively obtain the real part or the imaginary part of the PDH error signal. The electrical signal after frequency mixing is accepted by the voltmeter after passing through the low-pass filter, so that the approximate linear response relationship between the electrical signal and the intensity of the infrared light to be measured is realized, and the intensity of the mid-to-far infrared light can be read directly according to the voltage value, as shown in the figure Part (b) of 3 shows: the measurement results of the corresponding voltmeter obtained after circuit processing, each point corresponds to a different incident infrared light power, and the power difference between two adjacent points is 10 μW. The simulation parameters of the detection results are set as the thickness of the PDMS layer is 2.5 μm, the ring cavity waveguide is 1×1 μm, the diameter is 50 μm, the intrinsic Q value of the microcavity is 1×10 5 , and the wavelength of the pump laser injected into the microcavity is 1550nm.
根据上述实施例,优选地,回音壁模式微环腔优选设计为方形的硅波导,截面尺寸为1×1μm,环腔直径30到100μm,通过旋涂法在芯片表面覆盖中远红外吸收材料,微腔优选材料为PDMS,涂覆厚度为2.5μm。According to the above embodiment, preferably, the whispering gallery mode micro-ring cavity is preferably designed as a square silicon waveguide with a cross-sectional size of 1×1 μm and a ring cavity diameter of 30 to 100 μm. The preferred material of the cavity is PDMS, and the coating thickness is 2.5 μm.
根据上述实施例,优选地,微腔芯片采用电子束曝光与刻蚀工艺制作,芯片制作材料优选为SOI片,氧化层的厚度为2μm。通过电子束曝光将掩膜版的结构写入涂覆在SOI片上的光刻胶,经由干法刻蚀制作出片上的硅波导环腔。According to the above-mentioned embodiment, preferably, the microcavity chip is manufactured by electron beam exposure and etching process, the chip manufacturing material is preferably SOI sheet, and the thickness of the oxide layer is 2 μm. The structure of the mask plate is written into the photoresist coated on the SOI chip by electron beam exposure, and the silicon waveguide ring cavity on the chip is produced by dry etching.
根据上述实施例,优选地,窄线宽激光器(1)的输出光为近红外光,输出波长为1550nm波段,单频输出,激光的线宽小于10MHz。According to the above embodiment, preferably, the output light of the narrow-linewidth laser (1) is near-infrared light, the output wavelength is 1550nm band, single-frequency output, and the linewidth of the laser is less than 10MHz.
根据上述实施例,光电探测器(5)的工作波段为近红外光波段,优选为铟镓砷(InGaAs)探测器。According to the above embodiment, the working band of the photodetector (5) is the near-infrared light band, preferably an indium gallium arsenide (InGaAs) detector.
根据上述实施例,优选地,信号发生器(9)输出的调制信号为正弦波,调制频率大于微腔模式的线宽。According to the above embodiment, preferably, the modulation signal output by the signal generator (9) is a sine wave, and the modulation frequency is greater than the line width of the microcavity mode.
根据本发明的又一个实施例,还提供了一种涂覆有PDMS红外光吸收层的回音壁硅环腔的制备方法,采用标准的SOI片作为基底,以电子束曝光和反应离子刻蚀工艺制备片上集成的回音壁微腔,主要步骤包括:According to another embodiment of the present invention, there is also provided a method for preparing a whispering gallery silicon ring cavity coated with a PDMS infrared light absorbing layer, using a standard SOI sheet as a substrate, and using electron beam exposure and reactive ion etching processes Prepare the whispering gallery microcavity integrated on the chip, the main steps include:
(1)SOI片的清洗。材料表面的污染物会显著降低微腔的Q值,所以需要保证SOI片足够干净。依次将SOI片浸入到丙酮、乙醇、去离子水中,放入到超声波清洗机中,每种溶液清洗20分钟,最后用洁净的氮气枪吹干。(1) Cleaning of SOI sheet. Contaminants on the surface of the material will significantly reduce the Q value of the microcavity, so it is necessary to ensure that the SOI sheet is clean enough. The SOI sheet was immersed in acetone, ethanol, and deionized water in sequence, and placed in an ultrasonic cleaner. Each solution was cleaned for 20 minutes, and finally dried with a clean nitrogen gun.
(2)旋涂光刻胶。光刻胶的型号选用ZEP520A,用吸管将光刻胶滴到SOI片上,利用旋涂法使得光刻胶均匀覆盖在SOI片上。旋转匀胶机的转速设置为4000转/分钟,加速度为4000转/秒,旋涂时间为120秒。匀胶结束后,在加热台上以180℃加热芯片半小时,使光刻胶中的溶剂缓慢、充分地逸出。(2) Spin-coat photoresist. The model of the photoresist is ZEP520A, and the photoresist is dropped onto the SOI sheet with a straw, and the photoresist is evenly covered on the SOI sheet by the spin coating method. The rotational speed of the rotary coater was set at 4000 rpm, the acceleration was 4000 rpm, and the spin coating time was 120 seconds. After homogenization, heat the chip at 180°C on a heating platform for half an hour to allow the solvent in the photoresist to escape slowly and fully.
(3)电子束曝光。将表面有光刻胶的SOI片置于电子束曝光机的底座上,调整焦距和像散,通过电子束曝光的方式将掩膜版上的图形结构写入到光刻胶中。电子束曝光机的参数设置为:加速电压30Kv,光阑15μm,束流55Pa,电子束剂量因子1.2。曝光结束后,将芯片置入显影液中60秒。(3) Electron beam exposure. Put the SOI sheet with photoresist on the surface on the base of the electron beam exposure machine, adjust the focal length and astigmatism, and write the pattern structure on the mask plate into the photoresist by means of electron beam exposure. The parameters of the electron beam exposure machine are set as follows: accelerating voltage 30Kv, aperture 15μm, beam current 55Pa, electron beam dose factor 1.2. After the exposure, the chip was placed in the developer solution for 60 seconds.
(4)离子刻蚀。刻蚀的目的是将光刻胶中的结构转移到芯片上,对于硅的刻蚀,采用六氟化硫(SF6),它可以与硅发生化学反应,产生易挥发的四氟化硅(SiF4),同时对刻蚀室充填三氟甲烷来保护侧壁。刻蚀过程中的具体参数设定为:气体压强15mTorr,射频功率300W,SF6与三氟甲烷的流量分别为5、50sccm,刻蚀时间15分钟。刻蚀完成后,将芯片放入去胶液中,放置在加热台上,温度设定为80℃,加热24小时,最后用丙酮、酒精、去离子水清洗。(4) Ion etching. The purpose of etching is to transfer the structure in the photoresist to the chip. For the etching of silicon, sulfur hexafluoride (SF 6 ) is used, which can chemically react with silicon to produce volatile silicon tetrafluoride ( SiF 4 ), while filling the etching chamber with trifluoromethane to protect the sidewall. The specific parameters in the etching process are set as follows: gas pressure 15mTorr, radio frequency power 300W, flow rates of SF 6 and trifluoromethane respectively 5 and 50 sccm, and
(5)旋涂PDMS与固化。PDMS采用型号为道康宁DC184,将基本组分与固化剂按照7:1的质量比进行充分混合。利用滴管吸取未固化的PDMS胶水,滴在制备的微腔芯片上。通过调整旋转匀胶机的转速来控制最终PDMS层的厚度,转速设定在1000到6000转/分钟,旋涂时间120秒。旋涂完毕后,将芯片密封好放入鼓风干燥箱中,设定温度为120℃,鼓风干燥6小时取出。(5) Spin coating PDMS and curing. The PDMS model is Dow Corning DC184, and the basic components and curing agent are fully mixed according to the mass ratio of 7:1. Use a dropper to draw uncured PDMS glue and drop it on the prepared microcavity chip. The thickness of the final PDMS layer was controlled by adjusting the rotational speed of the rotary coater, the rotational speed was set at 1000 to 6000 rpm, and the spin coating time was 120 seconds. After the spin coating is completed, the chip is sealed and placed in a blast drying oven with a set temperature of 120° C., and is taken out after blast drying for 6 hours.
最终制作完成的具有PDMS层的硅微腔的横截面结构如图2所示。该微腔的谐振状态几乎只由硅材料决定,可具有较高的Q值和红光光探测灵敏度。图2中颜色的深浅表征温度的高低,温度的分布是通过有限元法仿真得出的,具体设定为以波长12.5μm,电场强度约为1500V/m的平面波入射到芯片上,PDMS层厚度为1μm,环腔波导为1×1μm,直径为50μm,材料对电磁波的吸收作为热源,稳态情况下得出温度分布。The cross-sectional structure of the finally fabricated silicon microcavity with PDMS layer is shown in Fig. 2 . The resonance state of the microcavity is almost only determined by the silicon material, which can have a high Q value and red light detection sensitivity. The depth of the color in Figure 2 represents the temperature. The temperature distribution is simulated by the finite element method. The specific setting is that a plane wave with a wavelength of 12.5 μm and an electric field strength of about 1500 V/m is incident on the chip, and the thickness of the PDMS layer is is 1 μm, the ring cavity waveguide is 1×1 μm, and the diameter is 50 μm. The absorption of electromagnetic waves by the material is used as a heat source, and the temperature distribution is obtained in a steady state.
本发明提供的基于回音壁模式微腔的中远红外光宽谱探测系统通过PDMS的吸收作用将中远红外光转换为热能,再以片上集成硅环腔(回音壁微腔结构)将热转换为硅波导折射率的变化从而引起光腔谐振态的改变,使用光电探测器将表征腔光谐振态的光信号转换为电信号,利用腔光谐振条件的极高敏感性,准确探测出红外光的强度,最后借助于电路系统,将腔光谐振透射率对失谐量的洛伦兹响应转换为近似线性响应,从而实现红外光强度的直接读出。The mid-to-far infrared wide-spectrum detection system based on the whispering gallery mode microcavity provided by the present invention converts the mid-to-far infrared light into thermal energy through the absorption of PDMS, and then converts the heat into silicon with an on-chip integrated silicon ring cavity (whispering gallery microcavity structure). Changes in the refractive index of the waveguide lead to changes in the resonant state of the optical cavity. Use a photodetector to convert the optical signal that characterizes the optical resonant state of the cavity into an electrical signal, and use the extremely high sensitivity of the resonant condition of the cavity to accurately detect the intensity of infrared light. , and finally with the help of the circuit system, the Lorentz response of the cavity optical resonance transmittance to the detuning amount is converted into an approximate linear response, thereby realizing the direct readout of the infrared light intensity.
以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included within the protection scope of the present invention.
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