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CN1152568C - Thin Film Field Emission Flat Panel Display - Google Patents

Thin Film Field Emission Flat Panel Display Download PDF

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CN1152568C
CN1152568C CNB001029207A CN00102920A CN1152568C CN 1152568 C CN1152568 C CN 1152568C CN B001029207 A CNB001029207 A CN B001029207A CN 00102920 A CN00102920 A CN 00102920A CN 1152568 C CN1152568 C CN 1152568C
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thin film
panel display
field emission
flat panel
electrode
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CN1264248A (en
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李德杰
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Tsinghua University
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Abstract

The present invention belongs to the technical field of a panel display which is composed of an upper glass board, a lower glass board, ring seal glass and a supporting structure, wherein the upper glass board is coated with fluorescent powder and an anodic aluminium film, the lower glass board is prepared with a cathode grid for emitting electron, and the middle of the present invention is kept in an ultrahigh vacuum state. The present invention is characterized in that the cathode grid in turn comprises an earth metal lower electrode, an alkaline earth sulphide insulating layer, an upper electrode, an electron emission layer and a row/column confluence electrode which is printed on the lower glass board for connecting the upper electrode and the lower electrode. The present invention has the advantages of low capacitance, long service life, cost reduction of drive circuit, etc., and is especially suitable for large-screen high definition televisions.

Description

薄膜场发射平板显示器Thin Film Field Emission Flat Panel Display

技术领域  本发明属于显示器件技术领域,特别涉及一种新型电子发射型平板显示器件的结构。Technical Field The present invention belongs to the technical field of display devices, and in particular relates to the structure of a novel electron-emitting flat panel display device.

背景技术  电子发射型平板显示器件包括金属微尖型场发射显示器件(FED)、表面传导发射显示器件(SED)、真空荧光显示器件(VFD)和各类金属-绝缘体-金属(MIM)或金属-绝缘体-半导体-金属(MISM)结构的场发射平板显示器件。其中,MIM器件结构如图1所示。包括:涂有荧光粉12和阳极铝摸13的上极板11、其上有发射电子阴栅极的下极板18、环封玻璃和支撑结构(图中未画出)。阴栅极的结构依次为金属膜的下电极17、绝缘层(电子传输层)16和金属膜的上电极15。工作时器件处于真空状态。其工作原理是:电子从阴栅下电极17发出穿过绝缘层16后到达阴栅上电极15,部分电子穿过上电极,形成发射电子14。发射电子被阳极电压加速到达阳极13,轰击荧光粉12发光。Background Art Electron emission flat panel display devices include metal microtip field emission display devices (FED), surface conduction emission display devices (SED), vacuum fluorescent display devices (VFD) and various metal-insulator-metal (MIM) or metal - Field emission flat panel display devices of insulator-semiconductor-metal (MISM) structure. Wherein, the MIM device structure is shown in FIG. 1 . It includes: an upper plate 11 coated with phosphor powder 12 and an anode aluminum mold 13, a lower plate 18 with an electron-emitting cathode grid on it, a ring sealing glass and a supporting structure (not shown in the figure). The structure of the cathode grid is successively the lower electrode 17 of the metal film, the insulating layer (electron transport layer) 16 and the upper electrode 15 of the metal film. The device is in a vacuum state during operation. Its working principle is: electrons are emitted from the lower electrode 17 of the cathode grid through the insulating layer 16 and then reach the upper electrode 15 of the cathode grid, and part of the electrons pass through the upper electrode to form emitted electrons 14 . The emitted electrons are accelerated by the anode voltage to reach the anode 13 and bombard the phosphor 12 to emit light.

在已经发表的MIM场发射器件中,金属下电极一般采用铝、钼、金、铂等,上电极采用铝、金、铱、铂等抗氧化的金属薄膜。绝缘层多采用三氧化二铝和氧化硅。例如日立公司研制的场发射显示器件中,下电极用铝膜,上电极用铱-铂-金三层复合薄膜电极,中间绝缘层用阳极氧化形成的氧化铝膜。In the published MIM field emission devices, aluminum, molybdenum, gold, platinum, etc. are generally used for the metal lower electrode, and anti-oxidation metal films such as aluminum, gold, iridium, platinum, etc. are used for the upper electrode. The insulating layer mostly uses aluminum oxide and silicon oxide. For example, in the field emission display device developed by Hitachi, the lower electrode uses an aluminum film, the upper electrode uses an iridium-platinum-gold three-layer composite film electrode, and the middle insulating layer uses an aluminum oxide film formed by anodic oxidation.

上述结构中,无论是氧化铝还是二氧化硅,电子在其中运动时的平均自由程电子一般不超过1.5纳米。为了使得足够数量的电子获得足够的能量克服上电极的功函数从而发射出去,绝缘层中的电场强度要达到每纳米一伏左右(1v/nm)。用铝和金等作下电极,氧化铝或二氧化硅作绝缘层时可以达到上述要求。这种结构存在两个致命的弱点。一是驱动电压和器件电容之间的矛盾,绝缘层薄则驱动电压低,一般绝缘层厚度在20纳米范围之内,因此器件电容比较大,导致显示器件面积不能太大。上述结构只适合于小尺寸显示器。二是由于绝缘层中电场太高,容易形成所谓的“形成”结构,即形成一些金属丝状物,使得器件容易击穿,因此寿命较短,实用化受到限制。In the above structure, whether it is alumina or silicon dioxide, the mean free path of electrons when moving in it is generally not more than 1.5 nanometers. In order for a sufficient number of electrons to obtain enough energy to overcome the work function of the upper electrode and be emitted, the electric field strength in the insulating layer should reach about one volt per nanometer (1v/nm). The above requirements can be met when aluminum and gold are used as the lower electrode, and aluminum oxide or silicon dioxide is used as the insulating layer. There are two fatal weaknesses in this structure. One is the contradiction between the driving voltage and the device capacitance. The thinner the insulating layer, the lower the driving voltage. Generally, the thickness of the insulating layer is within the range of 20 nanometers, so the device capacitance is relatively large, so the area of the display device cannot be too large. The above structure is only suitable for small-sized displays. The second is that because the electric field in the insulating layer is too high, it is easy to form the so-called "formation" structure, that is, some metal filaments are formed, which makes the device easy to break down, so the service life is short and the practical application is limited.

发明内容  本发明的目的是为克服已有技术的不足之处,从材料和结构尺寸入手,提出一种新的薄膜场发射显示器件。具有器件电容低,器件寿命长,可降低驱动电路成本等优点,特别适于大屏幕高清晰度电视。SUMMARY OF THE INVENTION The object of the present invention is to overcome the deficiencies of the prior art and propose a new thin-film field emission display device starting from materials and structural dimensions. It has the advantages of low device capacitance, long device life, and can reduce the cost of the driving circuit, and is especially suitable for large-screen high-definition televisions.

本发明提出一种场发射平板显示器,由涂有荧光粉和阳极金属膜的上玻板、制备有发射电子的阴栅极的下玻板、环封玻璃和支撑结构组成,中间维持超高真空,其特征在于,所说的阴栅极依次包括稀土金属薄膜下电极、碱土金属硫化物绝缘层、上电极和电子发射层,还包括印刷在该下玻板上连接所说的上、下电极的行列汇流电极。The present invention proposes a field emission flat panel display, which consists of an upper glass plate coated with phosphor powder and an anode metal film, a lower glass plate prepared with a cathode grid for emitting electrons, a ring sealing glass and a supporting structure, and an ultra-high vacuum is maintained in the middle , it is characterized in that, said cathode grid comprises rare earth metal thin film lower electrode, alkaline earth metal sulfide insulating layer, upper electrode and electron emission layer in sequence, and also includes printing on said lower glass plate and connecting said upper and lower electrodes The row and column bus electrodes.

所说的绝缘层材料可采用碱土金属硫化物,如硫化锶、硫化钙和硫化镁,厚度在50-500纳米的范围。Said insulating layer material can be made of alkaline earth metal sulfide, such as strontium sulfide, calcium sulfide and magnesium sulfide, with a thickness in the range of 50-500 nanometers.

所说的下电极采用稀土金属薄膜。The said lower electrode adopts rare earth metal film.

所说的电子发射层可采用低电子亲和势的N型半导体材料。Said electron emission layer can adopt N-type semiconductor material with low electron affinity.

所说的行列汇流电极用丝往印刷法印制,其的交叉点上可用丝网印刷法印制绝缘层隔离。Said row-column bus electrodes are printed by silk printing method, and the insulating layer can be printed by silk screen printing method on the intersections thereof for isolation.

所说的上极板上可采用彩色荧光粉,并在彩色荧光粉条之间加石墨黑底,形成黑矩阵。Said upper pole plate can adopt colored fluorescent powder, and add graphite black base between colored fluorescent powder stripes, form black matrix.

所说的支撑结构可放在行汇流电极上。Said support structure may be placed on the row bus electrodes.

本发明的原理结合图2、3、4说明如下:Principle of the present invention is described as follows in conjunction with Fig. 2,3,4:

本发明所述薄膜场发射平板显示器结构包括上极板21、下极板29、中间的抵抗大气压的支撑结构211等。上极板上有阳极铝膜214、黑矩阵213、荧光粉22等。下极板上有阴栅极,阴栅极详细结构依次为下电极24、绝缘层28、上电极23和电子发射层31。为了减小电极电阻,阴栅上下电极分别增加了汇流电极25、26,使得电极电阻小于100欧姆。上下玻板之间支撑结构。由于器件工作在真空状态,为了抵抗大气压,支撑结构是必须的。支撑结构一般称为支撑柱或支撑墙,材料一般为高强度陶瓷或单晶材料,如氧化锆单晶等。The thin film field emission flat panel display structure of the present invention includes an upper plate 21 , a lower plate 29 , a support structure 211 in the middle that resists atmospheric pressure, and the like. There are anodic aluminum film 214, black matrix 213, fluorescent powder 22, etc. on the upper plate. There is a cathode grid on the lower electrode plate, and the detailed structure of the cathode grid is a lower electrode 24, an insulating layer 28, an upper electrode 23 and an electron emission layer 31 in sequence. In order to reduce the electrode resistance, bus electrodes 25 and 26 are respectively added to the upper and lower electrodes of the cathode grid, so that the electrode resistance is less than 100 ohms. The support structure between the upper and lower glass plates. Since the device works in a vacuum, a support structure is necessary to resist atmospheric pressure. The support structure is generally called a support column or a support wall, and the material is generally a high-strength ceramic or a single crystal material, such as a zirconia single crystal.

由稀土金属薄膜下电极和碱土金属硫化物组成的电子发射传输系统,在小于每纳米0.3伏的场强下是就开始形成绝缘层中的传输电子,比通常的MIM系统小三倍以上,因此驱动电压大大降低,寿命大大增加。由于稀土硫化物中电子的平均自由程远大于氧化铝和二氧化硅中的平均自由程,因此电子获得的能量反而更大,有利于电子从上电极发射出去。The electron emission transport system composed of the lower electrode of the rare earth metal film and the alkaline earth metal sulfide starts to form the transport electrons in the insulating layer at a field strength of less than 0.3 volts per nanometer, which is more than three times smaller than the usual MIM system, so the drive The voltage is greatly reduced and the life is greatly increased. Since the mean free path of electrons in rare earth sulfides is much larger than that in alumina and silicon dioxide, the energy obtained by electrons is actually greater, which is conducive to the emission of electrons from the upper electrode.

阴栅上下电极分别是行电极和列电极,成行列矩阵结构。行列电极的交叉点上是一个子像素,三条列电极和一条行电极的交叉点构成一个像素。The upper and lower electrodes of the cathode grid are row electrodes and column electrodes respectively, forming a matrix structure of rows and columns. The intersection of the row and column electrodes is a sub-pixel, and the intersection of three column electrodes and one row electrode constitutes a pixel.

图4表示显示器的行和列电极,交叉点处发射电子。行列数分别为N和3M(一行三列对应一个彩色像素),形成的像素数为M×N。具体器件中,可能行电极在上,也可能列电极在上。计算和实验表明电子在一个方向上有自聚焦效应,可以减小电子的发散作用,有利于提高分辨率。行电极在上则在行方向上有聚焦作用,反之在列方向上有自聚焦作用。具体选用可依器件性能要求为准。Figure 4 shows the row and column electrodes of a display, where electrons are emitted at the intersections. The numbers of rows and columns are N and 3M respectively (one row and three columns correspond to one color pixel), and the number of formed pixels is M×N. In a specific device, the row electrodes may be on top, or the column electrodes may be on top. Calculations and experiments show that electrons have a self-focusing effect in one direction, which can reduce the divergence of electrons and help improve resolution. If the row electrodes are on the top, there is a focusing effect in the row direction, and vice versa, there is a self-focusing effect in the column direction. The specific selection can be based on the performance requirements of the device.

上电极加正电压,下电极加负电压,电子从下电极通过隧道效应发射到绝缘层中,并在其中加速,穿过上电极和发射层后,发射到真空中。经过阳极电压加速后,轰击荧光粉发光。如图4所示,显示某行时,其它行电极接地。依据列电压的高低,交叉处发射不同量的电子。接地行上,列电压不足以引起电子发射。这样一行一行地显示,上电极之上的发射层的作用是降低有效功函数,得到较大的发射电流。Positive voltage is applied to the upper electrode and negative voltage is applied to the lower electrode. Electrons are emitted from the lower electrode into the insulating layer through the tunnel effect and accelerated therein. After passing through the upper electrode and the emission layer, they are emitted into the vacuum. After being accelerated by the anode voltage, the bombardment phosphor emits light. As shown in Figure 4, when a certain row is displayed, the electrodes of other rows are grounded. Depending on how high or low the column voltage is, the intersections emit different amounts of electrons. On grounded rows, the column voltage is insufficient to cause electron emission. It is shown line by line that the function of the emission layer above the upper electrode is to reduce the effective work function and obtain a larger emission current.

本发明具有如下特点:The present invention has following characteristics:

(1)器件电容低,从而实现大面积器件,适用于大尺寸显示器。(1) The capacitance of the device is low, thereby realizing a large-area device, which is suitable for a large-size display.

(2)绝缘层中电场强度低,器件寿命长,达到实用水平。(2) The electric field intensity in the insulating layer is low, and the service life of the device is long, reaching a practical level.

附图说明Description of drawings

图1为已有的直流驱动MIM结构原理图。Figure 1 is a schematic diagram of the structure of the existing DC drive MIM.

图2为本发明结构原理图,其中(a)为结构示意图;(b)为工作原理图。Fig. 2 is a structural principle diagram of the present invention, wherein (a) is a structural schematic diagram; (b) is a working principle diagram.

图3为本发明的阴栅极具体结构图。Fig. 3 is a specific structure diagram of the cathode grid of the present invention.

图4为本发明行列电极排列结构和驱动方式原理图。Fig. 4 is a schematic diagram of the row and column electrode arrangement structure and driving mode of the present invention.

具体实施方式  本发明所述薄膜发射平板显示器件的实施例结合各附图详细说明如下:DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the thin film emitting flat panel display device of the present invention are described in detail as follows in conjunction with the accompanying drawings:

本实施例的结构和原理如图2所示。其结构包括上玻板21、下玻板29、中间的抵抗大气压的支撑结构211等。上玻板上有阳极铝膜214、荧光粉22等。显示器尺寸5英寸,单色,上玻板21和下玻板29厚度均为2毫米,阳极板(上玻板21)上涂有绿色荧光粉22。The structure and principle of this embodiment are shown in FIG. 2 . Its structure includes an upper glass plate 21, a lower glass plate 29, a support structure 211 in the middle that resists atmospheric pressure, and the like. There are anodic aluminum film 214, fluorescent powder 22, etc. on the upper glass plate. Display size 5 inches, monochrome, upper glass plate 21 and lower glass plate 29 thickness are 2 millimeters, be coated with green fluorescent powder 22 on the anode plate (upper glass plate 21).

下玻板上有阴栅极,阴栅极详细结构依次为下电极24、绝缘层28、上电极23和电子发射层31。所说的电子发射层采用低电子亲和势的N型半导体材料,如图3所示。本实施例阴栅极的绝缘层28硫化镁厚度100纳米,下电极24镝薄膜厚度100纳米,上电极23和发射层31复合薄膜厚度8纳米,阳极板和阴栅极板间距3毫米。阴栅上下电极分别是行电极和列电极,成行列矩阵结构。行列汇流电极的交叉点上用丝网印刷法印制绝缘层隔离。支撑结构211用氧化锆单晶,支撑结构一般长数厘米,厚度200微米,高度等于极板之间距离。支撑结构放在行汇流电极上。上下玻板之间用3毫米高的玻璃框215和低熔点玻璃封接,经过排气和烘烤后封离排气台,形成真空工作条件。上玻板上采用彩色荧光粉,并在彩色荧光粉条之间加石墨黑底,形成黑矩阵。测试时,行电极(下电极)电压-30伏,列电极(上电极)最大电压20伏。阳压5000伏,得到稳定均匀可靠的显示。There is a cathode grid on the lower glass plate, and the detailed structure of the cathode grid is a lower electrode 24 , an insulating layer 28 , an upper electrode 23 and an electron emission layer 31 in sequence. Said electron emission layer adopts N-type semiconductor material with low electron affinity, as shown in FIG. 3 . In this embodiment, the insulating layer 28 of the cathode grid has a thickness of 100 nanometers of magnesium sulfide, the thickness of the lower electrode 24 dysprosium film is 100 nanometers, the thickness of the composite film of the upper electrode 23 and the emission layer 31 is 8 nanometers, and the distance between the anode plate and the cathode grid plate is 3 mm. The upper and lower electrodes of the cathode grid are row electrodes and column electrodes respectively, forming a matrix structure of rows and columns. An insulating layer is printed on the intersection of the row and column bus electrodes to isolate them by screen printing. Zirconia single crystal is used for the support structure 211, the support structure is generally several centimeters long, 200 microns thick, and the height is equal to the distance between the plates. The support structure is placed on the row bus electrodes. The upper and lower glass plates are sealed with a 3 mm high glass frame 215 and low-melting point glass, and sealed off the exhaust platform after exhaust and baking to form a vacuum working condition. Colored fluorescent powder is used on the upper glass plate, and graphite black matrix is added between colored fluorescent powder strips to form a black matrix. During the test, the voltage of the row electrodes (lower electrodes) is -30 volts, and the maximum voltage of the column electrodes (upper electrodes) is 20 volts. The positive pressure is 5000 volts, and a stable, uniform and reliable display is obtained.

本实施例的上电极采用铂-金双层薄膜,功函数高的金属在下,功函数低的在上。电子发射比单金属电极提高5倍以上。采用铂上电极,用硫化物或氮化物N型半导体作发射层,发射提高10倍以上。电子束发散很小,在非自聚焦方向,荧光屏发光面积与阴极基本相同。在自聚焦方向,则明显见到发光区域小于电子发射区域。当阳压超过5000伏时,自聚焦效应明显减弱。The upper electrode of this embodiment adopts a platinum-gold double-layer thin film, the metal with a high work function is on the bottom, and the metal with a low work function is on top. Electron emission is more than 5 times higher than that of single metal electrodes. Platinum upper electrode is used, and sulfide or nitride N-type semiconductor is used as the emission layer, and the emission is increased by more than 10 times. The divergence of the electron beam is very small, and in the non-self-focusing direction, the light-emitting area of the fluorescent screen is basically the same as that of the cathode. In the self-focusing direction, it is obvious that the light-emitting area is smaller than the electron-emitting area. When the positive pressure exceeds 5000 volts, the self-focusing effect is obviously weakened.

Claims (7)

1、一种薄膜场发射平板显示器,由涂有荧光粉和阳极铝膜的上玻板、制备有发射电子的阴栅极的下玻板、环封玻璃和支撑结构组成,中间维持超高真空,其特征在于,所说的阴栅极依次包括稀土金属薄膜下电极、碱土金属硫化物绝缘层、上电极和电子发射层,还包括印刷在该下玻板上连接所说的上、下电极的行列汇流电极。1. A thin-film field emission flat-panel display, consisting of an upper glass plate coated with phosphor powder and anodic aluminum film, a lower glass plate prepared with a cathode grid for emitting electrons, a ring sealing glass and a supporting structure, and an ultra-high vacuum is maintained in the middle , it is characterized in that, said cathode grid comprises rare earth metal thin film lower electrode, alkaline earth metal sulfide insulating layer, upper electrode and electron emission layer in sequence, and also includes printing on said lower glass plate and connecting said upper and lower electrodes The row and column bus electrodes. 2、如权利要求1所述的薄膜场发射平板显示器,其特征在于,所说的绝缘层其厚度在50-500纳米的范围。2. The thin film field emission flat panel display according to claim 1, wherein the thickness of said insulating layer is in the range of 50-500 nanometers. 3、如权利要求1所述的薄膜场发射平板显示器,其特征在于,所说的上电极采用双层金属薄膜复合电极,功函数高的金属在下,功函数低的在上。3. The thin film field emission flat panel display according to claim 1, wherein the upper electrode is a double-layer metal thin film composite electrode, the metal with a high work function is on the bottom, and the metal with a low work function is on top. 4、如权利要求1所述的薄膜场发射平板显示器,其特征在于,所说的电子发射层采用低电子亲和势的N型半导体材料。4. The thin film field emission flat panel display according to claim 1, characterized in that said electron emission layer is made of N-type semiconductor material with low electron affinity. 5、如权利要求1所述的薄膜场发射平板显示器,其特征在于,所说的行列汇流电极用丝网印刷法印制,在汇流电极的交叉点上用丝网印刷法印制绝缘层隔离。5. The thin film field emission flat panel display as claimed in claim 1, characterized in that, said row-column bus electrodes are printed by screen printing, and an insulating layer is printed by screen printing on the intersections of the bus electrodes to isolate them. . 6、如权利要求1所述的薄膜场发射平板显示器,其特征在于,所说的上玻板上采用彩色荧光粉,并在彩色荧光粉条之间加石墨黑底,形成黑矩阵。6. The thin film field emission flat panel display as claimed in claim 1, characterized in that said upper glass plate adopts colored fluorescent powder, and a graphite black matrix is added between the colored fluorescent powder stripes to form a black matrix. 7、如权利要求1所述的薄膜场发射平板显示器,其特征在于,所说的支撑结构放在行汇流电极上。7. The thin film field emission flat panel display as claimed in claim 1, wherein said supporting structure is placed on the row bus electrodes.
CNB001029207A 2000-03-10 2000-03-10 Thin Film Field Emission Flat Panel Display Expired - Fee Related CN1152568C (en)

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