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CN114792818A - Cooling open type fuel cell, cooling system and cooling method - Google Patents

Cooling open type fuel cell, cooling system and cooling method Download PDF

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Publication number
CN114792818A
CN114792818A CN202210456770.1A CN202210456770A CN114792818A CN 114792818 A CN114792818 A CN 114792818A CN 202210456770 A CN202210456770 A CN 202210456770A CN 114792818 A CN114792818 A CN 114792818A
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cooling
plate
fuel cell
flow field
anode
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刘军恒
马浩然
嵇乾
梁雯雯
孙平
王攀
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Jiangsu University
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Jiangsu University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0267Collectors; Separators, e.g. bipolar separators; Interconnectors having heating or cooling means, e.g. heaters or coolant flow channels
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014Heat exchange using gaseous fluids; Heat exchange by combustion of reactants

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Fuel Cell (AREA)

Abstract

The invention discloses a cooling open type fuel cell, a cooling system and a cooling method, which comprises a plurality of bipolar plates which are stacked and aligned, wherein the upper side and the lower side of each bipolar plate are respectively provided with a current collecting plate, one side of each current collecting plate, which is far away from the bipolar plates, is fixedly connected with an end plate, and the end plates, the current collecting plates and the bipolar plates are fixedly connected through bolts and nuts; the bipolar plate comprises a cathode plate and an anode plate, the anode plate is positioned above the cathode plate, and the lower surface of the anode plate is fixedly connected with the upper surface of the cathode plate; the invention has the advantages of simple structure, convenient operation, convenient production, difficult leakage of cooling medium and good cooling effect on the fuel cell.

Description

一种冷却开放式燃料电池、冷却系统及冷却方法A kind of cooling open fuel cell, cooling system and cooling method

技术领域technical field

本发明涉及质子交换膜燃料电池技术领域,特别是涉及一种冷却开放式燃料电池、冷却系统及冷却方法。The invention relates to the technical field of proton exchange membrane fuel cells, in particular to a cooling open fuel cell, a cooling system and a cooling method.

背景技术Background technique

现有燃料电池冷却系统多采用单相冷却的方式,对于小功率燃料电池采用空气冷却,对于大功率燃料电池采用液体冷却,通过冷却介质温度变化实现热量传递。现有燃料电池系统单相冷却换热系数低、导热速率低、效率低且换热能力差,此外燃料电池局部热点热量若不能及时通过冷却介质带走也会导致膜电极的反应活性下降、燃料电池工作效率降低、燃料电池寿命减少和故障率增加。Existing fuel cell cooling systems mostly use single-phase cooling. For low-power fuel cells, air cooling is used, and for high-power fuel cells, liquid cooling is used, and heat transfer is achieved through the temperature change of the cooling medium. The single-phase cooling of the existing fuel cell system has low heat transfer coefficient, low thermal conductivity, low efficiency and poor heat transfer capacity. In addition, if the local hot spot heat of the fuel cell cannot be taken away by the cooling medium in time, the reactivity of the membrane electrode will decrease, and the fuel Battery operating efficiency decreases, fuel cell life decreases, and failure rates increase.

现有车用燃料电池冷却系统的特点是燃料电池电堆和其他产热部件共用一个循环,具体表现为燃料电池电堆与其他产热辅助部件共用冷却介质,而燃料电池电堆电活性氛围下对冷却介质的电导率要求较高,故燃料电池电堆冷却液进口常设置去离子器,用以去除冷却介质循环过程中产生的带电粒子,这导致整个冷却系统特别是冷却介质的使用和维护成本较高。The characteristic of the existing vehicle fuel cell cooling system is that the fuel cell stack and other heat-generating components share a cycle. Specifically, the fuel cell stack and other heat-generating auxiliary components share the cooling medium. The requirements for the conductivity of the cooling medium are relatively high, so the fuel cell stack coolant inlet is often equipped with a deionizer to remove the charged particles generated during the circulation of the cooling medium, which leads to the use and maintenance of the entire cooling system, especially the cooling medium. higher cost.

同时现有车用燃料电池冷却流道大多是封闭式流道,而燃料电池产热速率与其有效功率相当,较大的热负荷往往采用较高的冷却介质流速,泵功的大量额外消耗降低了燃料电池效率,同时较大的冷却介质压力、密封不严也会导致冷却介质泄露,此外封闭式冷却流道加工工艺复杂、加工难度大会使加工成本升高。故亟需一种新型冷却开放式燃料电池、冷却系统及冷却方法。At the same time, most of the existing vehicle fuel cell cooling channels are closed channels, and the heat generation rate of the fuel cell is equivalent to its effective power. Larger heat loads often use higher cooling medium flow rates, which reduces a large amount of additional pump power consumption. Fuel cell efficiency, high cooling medium pressure and poor sealing will also lead to cooling medium leakage. In addition, the processing technology of closed cooling channels is complicated and difficult to process, which will increase the processing cost. Therefore, there is an urgent need for a novel cooling open fuel cell, cooling system and cooling method.

发明内容SUMMARY OF THE INVENTION

本发明的目的是提供一种冷却开放式燃料电池、冷却系统及冷却方法,以解决上述现有技术存在的问题。The purpose of the present invention is to provide a cooling open fuel cell, a cooling system and a cooling method, so as to solve the above-mentioned problems in the prior art.

为实现上述目的,本发明提供了如下方案:本发明提供一种冷却开放式燃料电池,包括若干层叠对正设置的双极板,若干所述双极板上下两侧分别设置有集流板,所述集流板远离所述双极板的一侧固定连接有端板,所述端板、集流板以及双极板通过螺栓、螺母固定连接;In order to achieve the above object, the present invention provides the following solutions: the present invention provides a cooling open fuel cell, comprising a plurality of bipolar plates arranged in a stacked alignment, and collector plates are respectively provided on the upper and lower sides of the bipolar plates, An end plate is fixedly connected to the side of the collector plate away from the bipolar plate, and the end plate, the collector plate and the bipolar plate are fixedly connected by bolts and nuts;

所述双极板包括阴极板和阳极板,所述阳极板位于所述阴极板上方且所述阳极板上表面与所述阴极板下表面固定连接。The bipolar plate includes a cathode plate and an anode plate, the anode plate is located above the cathode plate, and the upper surface of the anode plate is fixedly connected with the lower surface of the cathode plate.

优选的,所述阴极板和所述阳极板顶部对应开设有氧化气体入口以及还原气体入口,所述阴极板和所述阳极板底部对应开设有氧化气体出口以及还原气体出口,所述阳极板上表面以及阴极板下表面上均开设有气体流场,所述氧化气体入口以及还原气体入口通过所述气体流场分别对应与所述氧化气体出口、还原气体出口相连通,所述阳极板下表面开设有阳极冷却半流场,所述阴极板上表面与所述阳极冷却半流场对应开设有阴极冷却半流场,所述阳极冷却半流场与所述阴极冷却半流场形成冷却流场,所述冷却流场连通有冷却介质循环器,所述冷却流场内设置有用于连接阴极板与阳极板的若干支撑板以及若干开放式的流通通道。Preferably, an oxidizing gas inlet and a reducing gas inlet are correspondingly opened on the top of the cathode plate and the anode plate, and an oxidizing gas outlet and a reducing gas outlet are correspondingly opened on the bottom of the cathode plate and the anode plate, and the anode plate The surface and the lower surface of the cathode plate are provided with a gas flow field, and the oxidizing gas inlet and the reducing gas inlet are respectively communicated with the oxidizing gas outlet and the reducing gas outlet through the gas flow field, and the lower surface of the anode plate is communicated with the oxidizing gas outlet and the reducing gas outlet respectively. An anode cooling half-flow field is opened, and a cathode cooling half-flow field is opened on the upper surface of the cathode plate corresponding to the anode cooling half-flow field, and the anode cooling half-flow field and the cathode cooling half-flow field form a cooling flow field A cooling medium circulator is communicated with the cooling flow field, and a plurality of support plates and a plurality of open circulation channels are arranged in the cooling flow field for connecting the cathode plate and the anode plate.

优选的,所述气体流场包括流场脊和流场槽,所述气体流场为直通形、蛇形、交指形及仿生形中的一种,所述氧化气体入口、所述氧化气体出口、所述还原气体入口以及所述还原气体出口处分别设置有气流分配区,所述气流分配区均位于所述气体流场内。Preferably, the gas flow field includes a flow field ridge and a flow field groove, the gas flow field is one of a straight-through shape, a serpentine shape, an interdigital shape and a bionic shape, the oxidizing gas inlet, the oxidizing gas The outlet, the reducing gas inlet and the reducing gas outlet are respectively provided with airflow distribution areas, and the airflow distribution areas are all located in the gas flow field.

优选的,同一所述双极板内的所述阳极板与所述阴极板之间固定连接有膜电极。Preferably, a membrane electrode is fixedly connected between the anode plate and the cathode plate in the same bipolar plate.

优选的,所述阳极板和所述阴极板的气体流场周侧、所述氧化气体入口、氧化气体出口、还原气体入口以及还原气体出口周侧均开设有密封槽,所述密封槽内安装有密封垫圈。Preferably, sealing grooves are provided on the peripheral sides of the gas flow field of the anode plate and the cathode plate, the oxidizing gas inlet, the oxidizing gas outlet, the reducing gas inlet, and the peripheral sides of the reducing gas outlet, and the sealing grooves are installed in the sealing grooves. With sealing gasket.

优选的,所述流通通道空间不少于所述冷却流场空间的二分之一。Preferably, the circulation channel space is not less than half of the cooling flow field space.

一种冷却开放式燃料电池冷却系统,包括冷却箱,所述燃料电池位于所述冷却箱内,所述燃料电池顶部固定安装有冷凝管,所述冷却箱内填充有冷却介质,所述冷却箱内固定安装有温度传感器、压力传感器,所述温度传感器与所述压力传感器均电性连接有控制器,所述冷却箱内开设有紧急泄压阀。A cooling open fuel cell cooling system, comprising a cooling box, the fuel cell is located in the cooling box, a condensation pipe is fixedly installed on the top of the fuel cell, the cooling box is filled with a cooling medium, and the cooling box is A temperature sensor and a pressure sensor are fixedly installed inside, the temperature sensor and the pressure sensor are both electrically connected with a controller, and an emergency pressure relief valve is opened in the cooling box.

一种冷却开放式燃料电池的冷却方法,包括如下步骤:A cooling method for cooling an open fuel cell, comprising the steps of:

步骤一、组装燃料电池,于阳极板上表面与阴极板下表面间布置一膜电极并对齐压紧组成双极板,将若干双极板对齐并在上下两侧分别安装集流板,在所述集流板远离所述双极板的一侧分别固定连接有端板,将螺栓贯穿端板、集流板和双极板后利用螺母进行固定;Step 1: Assemble the fuel cell, arrange a membrane electrode between the upper surface of the anode plate and the lower surface of the cathode plate and align and press them to form a bipolar plate, align several bipolar plates and install current collector plates on the upper and lower sides respectively, in the The side of the collector plate away from the bipolar plate is respectively fixed and connected with an end plate, and bolts are inserted through the end plate, the collector plate and the bipolar plate and then fixed with nuts;

步骤二、安装燃料电池,将步骤一组装好的燃料电池固定于冷却箱内,并在冷却箱内部顶部安装冷凝管;Step 2, install the fuel cell, fix the fuel cell assembled in step 1 in the cooling box, and install a condensation pipe on the top of the cooling box;

步骤三、向冷却箱内通入冷却介质,直到冷却介质没过燃料电池且位于冷凝管下方;Step 3: Pass the cooling medium into the cooling box until the cooling medium does not pass the fuel cell and is located below the condensation pipe;

步骤四、利用温度传感器以及压力传感器进行监测。Step 4. Use a temperature sensor and a pressure sensor to monitor.

优选的,步骤四中,当压力传感器监测到冷却箱压力超过预设压力阀值时,开启紧急泄压阀进行泄压。Preferably, in step 4, when the pressure sensor detects that the pressure of the cooling tank exceeds the preset pressure threshold, the emergency pressure relief valve is opened to release the pressure.

优选的,步骤四中,当燃料电池温度低时,冷却介质依靠自然对流向上汽化蒸发,通过冷凝管冷凝后自然落下;当燃料电池功率增大温度较高时,温度传感器接收到的温度信号达到强制冷却的温度阈值时,启动冷却循环器,冷却介质依靠强制对流流动进行换热,通过冷凝管冷凝后自然落下。Preferably, in step 4, when the temperature of the fuel cell is low, the cooling medium is vaporized and evaporated upward by natural convection, and then falls naturally after condensing through the condenser; when the power of the fuel cell increases and the temperature is high, the temperature signal received by the temperature sensor reaches When the temperature threshold of forced cooling is reached, the cooling circulator is activated, and the cooling medium relies on forced convection flow for heat exchange, and falls naturally after condensing through the condenser tube.

本发明公开了以下技术效果:双极板可以用于多种类型和材质的质子交换膜燃料电池,双极板既可以通过硬模冲压制备,也可以通过铸造工艺制备成型,便于生产;双极板为冷却开放式双极板,既可以浸没在相变冷却介质中实现相变散热,或可以浸没在液体冷却介质中实现液体冷却,也可以放置在空气中通过风冷散热,将冷却流道独立出来,避免了循环高压冷却介质所产生的泵功,同时解决了冷却介质在较高压力下容易泄漏的问题;在热负荷较小时可以利用冷却介质的自然对流实现换热,当热负荷较大时,通过冷却流道前设置的冷却循环器实现冷却介质强制对流加快燃料电池散热,可以自主调节冷却能力。The invention discloses the following technical effects: the bipolar plate can be used for proton exchange membrane fuel cells of various types and materials, and the bipolar plate can be prepared by die stamping or casting process, which is convenient for production; The plate is a cooling open bipolar plate, which can be immersed in a phase change cooling medium to achieve phase change heat dissipation, or can be immersed in a liquid cooling medium to achieve liquid cooling, or can be placed in the air to dissipate heat through air cooling, and the cooling channel Independently, it avoids the pump work generated by circulating high-pressure cooling medium, and solves the problem that the cooling medium is easy to leak under high pressure; when the heat load is small, the natural convection of the cooling medium can be used to achieve heat exchange, and when the heat load is relatively high. When it is large, the forced convection of the cooling medium can be realized by the cooling circulator set in front of the cooling channel to accelerate the heat dissipation of the fuel cell, and the cooling capacity can be adjusted independently.

附图说明Description of drawings

为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the accompanying drawings required in the embodiments will be briefly introduced below. Obviously, the drawings in the following description are only some of the present invention. In the embodiments, for those of ordinary skill in the art, other drawings can also be obtained according to these drawings without creative labor.

图1为本发明燃料电池结构示意图;Fig. 1 is the structural schematic diagram of the fuel cell of the present invention;

图2为本发明阳极板上表面结构示意图;Fig. 2 is the schematic diagram of the surface structure of the anode plate of the present invention;

图3为本发明阳极板下表面结构示意图;3 is a schematic diagram of the structure of the lower surface of the anode plate of the present invention;

图4为本发明阴极板下表面结构示意图;4 is a schematic diagram of the structure of the lower surface of the cathode plate of the present invention;

图5为本发明阴极板上表面结构示意图;5 is a schematic diagram of the surface structure of the cathode plate of the present invention;

图6为本发明冷却流场装配示意图;6 is a schematic diagram of the assembly of the cooling flow field of the present invention;

图7为图6中B的结构放大图;Figure 7 is an enlarged view of the structure of B in Figure 6;

图8为本发明冷却系统结构示意图;8 is a schematic structural diagram of the cooling system of the present invention;

图9为实施例二中阴极板上表面结构示意图;9 is a schematic diagram of the surface structure of the cathode plate in the second embodiment;

图10为实施例二中冷却流场装配示意图;10 is a schematic diagram of the assembly of the cooling flow field in the second embodiment;

图11为图10中C的局部放大图;Fig. 11 is a partial enlarged view of C in Fig. 10;

其中:2-冷却介质,3-冷凝管,4-冷却箱,11-双极板,12-阳极板,13-阴极板,14螺栓,15-端板,16-集流板,17-膜电极,18-密封垫圈,19-螺母,111-氧化气体入口,112-还原气体入口,113-气体流场,114-密封槽,115-气流分配区,116-氧化气体出口,117-还原气体出口,119-冷却流场,1191-支撑板,1192-流通通道,121阳极冷却半流场,131-阴极冷却半流场,1131-流场脊,1132-流场槽。Among them: 2-cooling medium, 3-condenser tube, 4-cooling box, 11-bipolar plate, 12-anode plate, 13-cathode plate, 14-bolt, 15-end plate, 16-collector plate, 17-membrane Electrode, 18-sealing gasket, 19-nut, 111-oxidizing gas inlet, 112-reducing gas inlet, 113-gas flow field, 114-seal groove, 115-gas distribution area, 116-oxidizing gas outlet, 117-reducing gas Outlet, 119 - cooling flow field, 1191 - support plate, 1192 - flow channel, 121 anode cooling half flow field, 131 - cathode cooling half flow field, 1131 - flow field ridge, 1132 - flow field groove.

具体实施方式Detailed ways

下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

为使本发明的上述目的、特征和优点能够更加明显易懂,下面结合附图和具体实施方式对本发明作进一步详细的说明。In order to make the above objects, features and advantages of the present invention more clearly understood, the present invention will be described in further detail below with reference to the accompanying drawings and specific embodiments.

实施例一:Example 1:

参照图1-8,本实施例提供一种冷却开放式燃料电池,包括若干层叠对正设置的双极板11,若干双极板11上下两侧分别设置有集流板16,集流板16远离双极板11的一侧固定连接有端板15,端板15、集流板16以及双极板11通过螺栓14、螺母19固定连接;通过在端板15、集流板16和双极板11上对应开设通孔,利用螺栓14和螺母19对其进行固定,使双极板11之间紧密贴合,形成对反应气体的密封,同时增加端板15、集流板16与双极板11之间的稳定性。Referring to FIGS. 1-8 , the present embodiment provides a cooling open fuel cell, which includes a plurality of bipolar plates 11 that are stacked and aligned, and a current collecting plate 16 is respectively provided on the upper and lower sides of the plurality of bipolar plates 11 . The current collecting plate 16 An end plate 15 is fixedly connected to the side away from the bipolar plate 11, and the end plate 15, the current collecting plate 16 and the bipolar plate 11 are fixedly connected by bolts 14 and nuts 19; Corresponding through holes are opened on the plate 11, and the bolts 14 and nuts 19 are used to fix it, so that the bipolar plates 11 are closely attached to form a seal for the reaction gas, and the end plate 15, the collector plate 16 and the bipolar plate are added at the same time. Stability between plates 11.

双极板11包括阴极板13和阳极板12,阳极板12位于阴极板13上方且阳极板12上表面与阴极板13下表面间设置有一膜电极并固定连接。利用阳极板12与阴极板13相配合形成双极板11,通过分别加工阳极板12和阴极板13组成双极板11,使双极板11便于获取。The bipolar plate 11 includes a cathode plate 13 and an anode plate 12. The anode plate 12 is located above the cathode plate 13 and a membrane electrode is disposed between the upper surface of the anode plate 12 and the lower surface of the cathode plate 13 and is fixedly connected. The bipolar plate 11 is formed by cooperating with the anode plate 12 and the cathode plate 13 , and the bipolar plate 11 is formed by processing the anode plate 12 and the cathode plate 13 respectively, so that the bipolar plate 11 is easy to obtain.

进一步优化方案,阴极板13和阳极板12顶部对应开设有氧化气体入口111以及还原气体入口112,阴极板13和阳极板12底部对应开设有氧化气体出口116以及还原气体出口117,阳极板12上表面以及阴极板13下表面上均开设有气体流场113,氧化气体入口111以及还原气体入口112通过气体流场113分别对应与氧化气体出口116、还原气体出口117相连通,阳极板12下表面开设有阳极冷却半流场121,阴极板13上表面上与阳极冷却半流场121对应开设有阴极冷却半流场131,阳极冷却半流场121与阴极冷却半流场131形成冷却流场119,冷却流场119连通有冷却介质循环器,冷却流场119内设置有用于连接阴极板13与阳极板12的若干支撑板1191以及若干开放式的流通通道1192。冷却流场119能够为冷却介质提供空间,使燃料电池便于冷却,支撑板1191能够使阳极板12和阴极板13充分贴合,保证阳极板12与阴极板13的抗压强度。To further optimize the scheme, the top of the cathode plate 13 and the anode plate 12 are correspondingly provided with an oxidizing gas inlet 111 and a reducing gas inlet 112, and the bottom of the cathode plate 13 and the anode plate 12 are correspondingly provided with an oxidizing gas outlet 116 and a reducing gas outlet 117. The surface and the lower surface of the cathode plate 13 are provided with a gas flow field 113. The oxidizing gas inlet 111 and the reducing gas inlet 112 are respectively communicated with the oxidizing gas outlet 116 and the reducing gas outlet 117 through the gas flow field 113, and the lower surface of the anode plate 12 is connected. An anode cooling half-flow field 121 is opened, a cathode cooling half-flow field 131 is opened on the upper surface of the cathode plate 13 corresponding to the anode cooling half-flow field 121, and the anode cooling half-flow field 121 and the cathode cooling half-flow field 131 form a cooling flow field 119 The cooling flow field 119 is communicated with a cooling medium circulator, and a plurality of support plates 1191 and a plurality of open circulation channels 1192 are arranged in the cooling flow field 119 for connecting the cathode plate 13 and the anode plate 12 . The cooling flow field 119 can provide space for the cooling medium to facilitate cooling of the fuel cell, and the support plate 1191 can fully fit the anode plate 12 and the cathode plate 13 to ensure the compressive strength of the anode plate 12 and the cathode plate 13 .

进一步优化方案,气体流场113包括流场脊1131和流场槽1132,气体流场113为直通形、蛇形、交指形及仿生形中的一种,氧化气体入口111、氧化气体出口116、还原气体入口112以及还原气体出口117处分别设置有气流分配区115,气流分配区115均位于气体流场113内。气流分配区115用以分别连通氧化气体入口111和气体流场113与还原气体入口111和气体流场113,使反应气体进入到气体流场113内充分反应。To further optimize the scheme, the gas flow field 113 includes a flow field ridge 1131 and a flow field groove 1132, the gas flow field 113 is one of a straight-through shape, a serpentine shape, an interdigital shape and a bionic shape, an oxidizing gas inlet 111, and an oxidizing gas outlet 116. , the reducing gas inlet 112 and the reducing gas outlet 117 are respectively provided with airflow distribution areas 115 , and the airflow distribution areas 115 are all located in the gas flow field 113 . The gas distribution area 115 is used to connect the oxidizing gas inlet 111 and the gas flow field 113 with the reducing gas inlet 111 and the gas flow field 113 respectively, so that the reactant gas enters the gas flow field 113 and reacts fully.

进一步的,气体流场113的尺寸为110mm×80mm,流场脊1131的长度为100mm,宽度为2mm;流场槽1132的长度为100mm,宽度为2mm,深度为1mm。Further, the size of the gas flow field 113 is 110 mm×80 mm, the length of the flow field ridge 1131 is 100 mm, and the width is 2 mm; the length of the flow field groove 1132 is 100 mm, the width is 2 mm, and the depth is 1 mm.

进一步的,冷却流场119的尺寸为110mm×100mm,支撑部分1191的长度为100mm,宽度为2mm;流通部分1192的长度为100mm,宽度为2mm,深度为1mm。Further, the size of the cooling flow field 119 is 110mm×100mm, the length of the support part 1191 is 100mm, the width is 2mm; the length of the circulation part 1192 is 100mm, the width is 2mm, and the depth is 1mm.

进一步优化方案,同一双极板11内的阳极板12与阴极板13之间固定连接有膜电极17。In a further optimized solution, a membrane electrode 17 is fixedly connected between the anode plate 12 and the cathode plate 13 in the same bipolar plate 11 .

进一步优化方案,所述阳极板12和所述阴极板13的气体流场113周侧、所述氧化气体入口111、氧化气体出口116、还原气体入口112以及还原气体出口117周侧均开设有密封槽114,所述密封槽114内安装有密封垫圈18。在密封槽114内安装密封垫圈18能够增加密封性能,防止跑气,导致气体泄漏反应不充分甚至发生爆炸危险。To further optimize the solution, seals are provided on the periphery of the gas flow field 113 of the anode plate 12 and the cathode plate 13 , the oxidizing gas inlet 111 , the oxidizing gas outlet 116 , the reducing gas inlet 112 and the peripheral side of the reducing gas outlet 117 . The sealing groove 114 has a sealing gasket 18 installed in the sealing groove 114 . Installing the sealing gasket 18 in the sealing groove 114 can increase the sealing performance and prevent outgassing, resulting in insufficient gas leakage reaction and even the danger of explosion.

进一步优化方案,流通通道1192空间不少于冷却流场119空间的二分之一。保证整个燃料电池抗压性和密封性足够的前提下,尽可能扩大所述流通部分面积,加大双极板11与冷却介质2的换热面积,从而获得优异的换热能力。To further optimize the solution, the space of the circulation channel 1192 is not less than half of the space of the cooling flow field 119 . On the premise of ensuring sufficient pressure resistance and sealing performance of the entire fuel cell, the area of the circulation part is enlarged as much as possible, and the heat exchange area between the bipolar plate 11 and the cooling medium 2 is enlarged, so as to obtain excellent heat exchange capacity.

进一步的,氧化气体入口、还原气体入口和氧化气体出口、还原气体出口沿双极板对角线设置,这样的布置方式可以提升气体流场113的使用效率。Further, the oxidizing gas inlet, the reducing gas inlet, the oxidizing gas outlet, and the reducing gas outlet are arranged along the diagonal of the bipolar plate, and such an arrangement can improve the use efficiency of the gas flow field 113 .

进一步的,氧化气体入口通道111面积为所述还原气体入口通道112面积的二分之一,按照化学反应计量比设计可以尽可能减少膜电极17两端气流流道中氧化气体和还原气体的压强差并避免窜气。Further, the area of the oxidizing gas inlet channel 111 is one-half of the area of the reducing gas inlet channel 112. According to the stoichiometric ratio design, the pressure difference between the oxidizing gas and the reducing gas in the gas flow channels at both ends of the membrane electrode 17 can be reduced as much as possible. And avoid blow-by.

进一步优化方案,所述气体流场113内气体流向为所述双极板11长度方向,所述冷却流场119内冷却介质流向为所述双极板11宽度方向。便于对燃料电池进行冷却。In a further optimized solution, the gas flow direction in the gas flow field 113 is the length direction of the bipolar plate 11 , and the cooling medium flow direction in the cooling flow field 119 is the width direction of the bipolar plate 11 . It is convenient to cool the fuel cell.

一种冷却开放式燃料电池冷却系统,包括冷却箱4,燃料电池位于冷却箱4内,燃料电池顶部固定安装有冷凝管3,冷却箱4内填充有冷却介质2,冷却箱4内固定安装有温度传感器、压力传感器,温度传感器与压力传感器均电性连接有控制器,冷却箱4内开设有紧急泄压阀。将燃料电池固定于冷却箱4内,然后利用冷却介质2对燃料电池进行冷却,当燃料电池工作时,产生大量热量将冷却介质2蒸发,然后利用冷凝管使蒸汽凝结,降温后又滴入冷却介质2中。A cooling and open fuel cell cooling system, comprising a cooling box 4, a fuel cell is located in the cooling box 4, a condensation pipe 3 is fixedly installed on the top of the fuel cell, a cooling medium 2 is filled in the cooling box 4, and a cooling medium 2 is fixedly installed in the cooling box 4. The temperature sensor, the pressure sensor, the temperature sensor and the pressure sensor are all electrically connected with a controller, and an emergency pressure relief valve is opened in the cooling box 4 . The fuel cell is fixed in the cooling box 4, and then the fuel cell is cooled by the cooling medium 2. When the fuel cell is working, a large amount of heat is generated to evaporate the cooling medium 2, and then the condensation pipe is used to condense the steam, and then drop into the cooling after cooling. medium 2.

一种冷却开放式燃料电池的冷却方法,包括如下步骤:A cooling method for cooling an open fuel cell, comprising the steps of:

步骤一、组装燃料电池,于阳极板12上表面与阴极板13下表面对齐间布置一膜电极17并压紧组成双极板11,将若干双极板11对齐并在上下两侧分别安装集流板16,在集流板16远离双极板11的一侧分别固定连接有端板15,将螺栓14贯穿端板15、集流板16和双极板11后利用螺母19进行固定;保证各双极板11之间的密封性;增强结构的稳定性。Step 1: Assemble the fuel cell, arrange a membrane electrode 17 between the upper surface of the anode plate 12 and the lower surface of the cathode plate 13 and press them together to form a bipolar plate 11, align a plurality of bipolar plates 11 and install the collectors on the upper and lower sides respectively. The current plate 16 is fixedly connected with the end plate 15 on the side of the current collecting plate 16 away from the bipolar plate 11, and the bolts 14 are inserted through the end plate 15, the current collecting plate 16 and the bipolar plate 11 and are fixed with nuts 19; The tightness between the bipolar plates 11; the stability of the structure is enhanced.

步骤二、安装燃料电池,将步骤一组装好的燃料电池固定于冷却箱4内,并在冷却箱4内部顶部安装冷凝管3;Step 2, install the fuel cell, fix the fuel cell assembled in step 1 in the cooling box 4, and install the condensation pipe 3 on the top of the cooling box 4;

步骤三、向冷却箱4内通入冷却介质2,直到冷却介质2没过燃料电池且位于冷凝管3下方,使冷却介质2吸收燃料电池释放的热量汽化蒸发,蒸汽在冷凝管3附近冷凝回落至冷却介质2中;Step 3: Pass the cooling medium 2 into the cooling box 4 until the cooling medium 2 does not pass the fuel cell and is located under the condensation pipe 3, so that the cooling medium 2 absorbs the heat released by the fuel cell to vaporize and evaporate, and the steam condenses and falls back near the condensation pipe 3. into the cooling medium 2;

步骤四、利用温度传感器以及压力传感器进行监测。Step 4. Use a temperature sensor and a pressure sensor to monitor.

进一步优化方案,步骤四中,当压力传感器监测到冷却箱4压力超过预设压力阀值时,开启紧急泄压阀进行泄压。防止由于冷却介质2不断蒸发导致冷却箱4内压力过大发生意外。To further optimize the solution, in step 4, when the pressure sensor detects that the pressure of the cooling tank 4 exceeds the preset pressure threshold, the emergency pressure relief valve is opened to release the pressure. Prevent accidents caused by excessive pressure in the cooling box 4 due to the continuous evaporation of the cooling medium 2 .

进一步优化方案,步骤四中,当燃料电池功率低产热较少时,冷却介质2依靠自然对流向上汽化蒸发,通过冷凝管3冷凝后自然落下;当燃料电池功率增大温度较高时,温度传感器接收到的温度信号达到强制冷却的温度阈值时,启动冷却循环器,冷却介质2依靠强制对流流动进行换热,通过冷凝管3冷凝后自然落下。To further optimize the scheme, in step 4, when the fuel cell power is low and the heat production is low, the cooling medium 2 vaporizes and evaporates upwards by natural convection, and then falls naturally after condensing through the condenser tube 3; when the fuel cell power increases and the temperature is higher, the temperature sensor When the received temperature signal reaches the temperature threshold of forced cooling, the cooling circulator is started, and the cooling medium 2 relies on forced convection flow for heat exchange, and falls naturally after condensing through the condensing pipe 3 .

当燃料电池温度较低时,冷却介质2依靠自然对流向上汽化蒸发,通过冷凝管3冷凝后自然落下,如此循环冷却;当燃料电池功率增大温度较高时,温度传感器接收到的温度信号达到强制冷却阈值,则启动冷却循环器,冷却介质2依靠的强制对流迅速流动加快换热,通过冷凝管3冷凝后自然落下,如此循环冷却;能够根据特定情况对燃料电池进行冷却,冷却稳定。When the temperature of the fuel cell is low, the cooling medium 2 is vaporized and evaporated upwards by natural convection, condensed through the condenser tube 3 and then falls down naturally, thus circulating cooling; when the power of the fuel cell increases and the temperature is high, the temperature signal received by the temperature sensor reaches When the forced cooling threshold is set, the cooling circulator is activated, and the forced convection that the cooling medium 2 relies on quickly flows to speed up the heat exchange, and after condensing through the condensing pipe 3, it naturally falls down, so as to circulate and cool; the fuel cell can be cooled according to specific conditions, and the cooling is stable.

进一步的,冷凝管3中的冷却循环介质为常见冷却循环介质,冷却箱4中的冷却循环介质需要满足低导电率高导热率且容易发生相变的特点。Further, the cooling circulating medium in the condenser tube 3 is a common cooling circulating medium, and the cooling circulating medium in the cooling box 4 needs to meet the characteristics of low electrical conductivity, high thermal conductivity and easy phase change.

实施例二:Embodiment 2:

参照图9-11,本实施例提供一种冷却开放式燃料电池,本实施例与实施例一的区别仅在于阴极板13上表面和阳极板12下表面所形成的冷却流场119内的支撑板1191为圆形柱凸起,冷却流场119在圆形柱凸起的作用下形成扰流柱式冷却流场,流通通道1192空间更大,且扰流柱可以破坏冷却介质的平行流动,使冷却介质产生紊流,强化双极板11和冷却介质2之间的散热。9-11 , this embodiment provides a cooling open fuel cell. The difference between this embodiment and Embodiment 1 is only the support in the cooling flow field 119 formed by the upper surface of the cathode plate 13 and the lower surface of the anode plate 12 The plate 1191 is a circular column protrusion, the cooling flow field 119 forms a turbulent column cooling flow field under the action of the circular column protrusion, the circulation channel 1192 has a larger space, and the turbulent column can destroy the parallel flow of the cooling medium, The cooling medium is turbulent, and the heat dissipation between the bipolar plate 11 and the cooling medium 2 is enhanced.

在本发明的描述中,需要理解的是,术语“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In the description of the present invention, it should be understood that the terms "portrait", "horizontal", "upper", "lower", "front", "rear", "left", "right", "vertical", The orientation or positional relationship indicated by "horizontal", "top", "bottom", "inner", "outer", etc. is based on the orientation or positional relationship shown in the drawings, and is only for the convenience of describing the present invention, rather than indicating or It is implied that the device or element referred to must have a particular orientation, be constructed and operate in a particular orientation, and therefore should not be construed as limiting the invention.

以上所述的实施例仅是对本发明的优选方式进行描述,并非对本发明的范围进行限定,在不脱离本发明设计精神的前提下,本领域普通技术人员对本发明的技术方案做出的各种变形和改进,均应落入本发明权利要求书确定的保护范围内。The above-mentioned embodiments are only to describe the preferred modes of the present invention, but not to limit the scope of the present invention. Without departing from the design spirit of the present invention, those of ordinary skill in the art can make various modifications to the technical solutions of the present invention. Variations and improvements should fall within the protection scope determined by the claims of the present invention.

Claims (10)

1.一种冷却开放式燃料电池,其特征在于:包括若干层叠对正设置的双极板(11),若干所述双极板(11)上下两侧分别设置有集流板(16),所述集流板(16)远离所述双极板(11)的一侧固定连接有端板(15),所述端板(15)、集流板(16)以及双极板(11)通过螺栓(14)、螺母(19)固定连接;1. A cooling open fuel cell, characterized in that it comprises a number of bipolar plates (11) that are stacked and aligned, and collector plates (16) are respectively provided on the upper and lower sides of the bipolar plates (11), An end plate (15) is fixedly connected to the side of the current collecting plate (16) away from the bipolar plate (11), the end plate (15), the current collecting plate (16) and the bipolar plate (11) The connection is fixed by bolts (14) and nuts (19); 所述双极板(11)包括阴极板(13)和阳极板(12),所述阳极板(12)位于所述阴极板(13)上方且所述阳极板(12)上表面与所述阴极板(13)下表面固定连接。The bipolar plate (11) comprises a cathode plate (13) and an anode plate (12), the anode plate (12) is located above the cathode plate (13) and the upper surface of the anode plate (12) is in contact with the anode plate (12). The lower surface of the cathode plate (13) is fixedly connected. 2.根据权利要求1所述的一种冷却开放式燃料电池,其特征在于:所述阴极板(13)和所述阳极板(12)顶部对应开设有氧化气体入口(111)以及还原气体入口(112),所述阴极板(13)和所述阳极板(12)底部对应开设有氧化气体出口(116)以及还原气体出口(117),所述阳极板(12)上表面以及阴极板(13)下表面上均开设有气体流场(113),所述氧化气体入口(111)以及还原气体入口(112)通过所述气体流场(113)分别对应与所述氧化气体出口(116)、还原气体出口(117)相连通,所述阳极板(12)下表面开设有阳极冷却半流场(121),所述阴极板(13)上表面与所述阳极冷却半流场(121)对应开设有阴极冷却半流场(131),所述阳极冷却半流场(121)与所述阴极冷却半流场(131)形成冷却流场(119),所述冷却流场(119)连通有冷却介质循环器,所述冷却流场(119)内设置有用于连接阴极板(13)与阳极板(12)的若干支撑板(1191)以及若干开放式的流通通道(1192)。2. A cooling open fuel cell according to claim 1, wherein an oxidizing gas inlet (111) and a reducing gas inlet are correspondingly opened at the top of the cathode plate (13) and the anode plate (12). (112), an oxidizing gas outlet (116) and a reducing gas outlet (117) are correspondingly provided at the bottom of the cathode plate (13) and the anode plate (12), and the upper surface of the anode plate (12) and the cathode plate ( 13) A gas flow field (113) is provided on the lower surface, and the oxidizing gas inlet (111) and the reducing gas inlet (112) respectively correspond to the oxidizing gas outlet (116) through the gas flow field (113) , the reducing gas outlet (117) is connected, the anode cooling half-flow field (121) is opened on the lower surface of the anode plate (12), and the anode cooling half-flow field (121) is opened on the upper surface of the cathode plate (13) A cathode cooling half-flow field (131) is correspondingly opened, the anode cooling half-flow field (121) and the cathode cooling half-flow field (131) form a cooling flow field (119), and the cooling flow field (119) communicates with each other There is a cooling medium circulator, and the cooling flow field (119) is provided with several support plates (1191) for connecting the cathode plate (13) and the anode plate (12) and several open circulation channels (1192). 3.根据权利要求2所述的一种冷却开放式燃料电池,其特征在于:所述气体流场(113)包括流场脊(1131)和流场槽(1132),所述气体流场(113)为直通形、蛇形、交指形及仿生形中的一种,所述氧化气体入口(111)、所述氧化气体出口(116)、所述还原气体入口(112)以及所述还原气体出口(117)处分别设置有气流分配区(115),所述气流分配区(115)均位于所述气体流场(113)内。3. A cooling open fuel cell according to claim 2, characterized in that: the gas flow field (113) comprises a flow field ridge (1131) and a flow field groove (1132), and the gas flow field ( 113) is one of a straight-through shape, a serpentine shape, an interdigital shape and a bionic shape, the oxidizing gas inlet (111), the oxidizing gas outlet (116), the reducing gas inlet (112) and the reducing The gas outlets (117) are respectively provided with airflow distribution areas (115), and the airflow distribution areas (115) are all located in the gas flow field (113). 4.根据权利要求1所述的一种冷却开放式燃料电池,其特征在于:同一所述双极板(11)内的所述阳极板(12)与所述阴极板(13)之间固定连接有膜电极(17)。4. A cooling open fuel cell according to claim 1, characterized in that: the anode plate (12) and the cathode plate (13) in the same bipolar plate (11) are fixed between A membrane electrode (17) is connected. 5.根据权利要求2所述的一种冷却开放式燃料电池,其特征在于:所述阳极板(12)和所述阴极板(13)的气体流场(113)周侧、所述氧化气体入口(111)、氧化气体出口(116)、还原气体入口(112)以及还原气体出口(117)周侧均开设有密封槽(114),所述密封槽(114)内安装有密封垫圈(18)。5. A cooling open fuel cell according to claim 2, characterized in that: the gas flow field (113) peripheral side of the anode plate (12) and the cathode plate (13), the oxidizing gas The inlet (111), the oxidizing gas outlet (116), the reducing gas inlet (112) and the reducing gas outlet (117) are provided with sealing grooves (114) on the peripheral sides, and a sealing gasket (18) is installed in the sealing groove (114) ). 6.根据权利要求2所述的一种冷却开放式燃料电池,其特征在于:所述流通通道(1192)空间不少于所述冷却流场(119)空间的二分之一。6 . The cooling open fuel cell according to claim 2 , wherein the space of the circulation channel ( 1192 ) is not less than half of the space of the cooling flow field ( 119 ). 7 . 7.一种冷却开放式燃料电池冷却系统,基于权利要求1-6任一项所述的一种冷却开放式燃料电池,其特征在于:包括冷却箱(4),所述燃料电池位于所述冷却箱(4)内,所述燃料电池顶部固定安装有冷凝管(3),所述冷却箱(4)内填充有冷却介质(2),所述冷却箱(4)内固定安装有温度传感器、压力传感器,所述温度传感器与所述压力传感器均电性连接有控制器,所述冷却箱(4)内开设有紧急泄压阀。7. A cooling system for cooling an open fuel cell, based on the cooling open fuel cell according to any one of claims 1-6, characterized in that it comprises a cooling box (4), the fuel cell is located in the In the cooling box (4), a condensation pipe (3) is fixedly installed on the top of the fuel cell, the cooling medium (2) is filled in the cooling box (4), and a temperature sensor is fixedly installed in the cooling box (4) , a pressure sensor, the temperature sensor and the pressure sensor are both electrically connected with a controller, and an emergency pressure relief valve is opened in the cooling box (4). 8.一种冷却开放式燃料电池的冷却方法,基于权利要求7所述的一种冷却开放式燃料电池冷却系统,其特征在于,包括如下步骤:8. A cooling method for cooling an open fuel cell, based on a cooling system for cooling an open fuel cell according to claim 7, characterized in that, comprising the steps of: 步骤一、组装燃料电池,于阳极板(12)上表面与阴极板(13)下表面间布置一膜电极(17)并对齐压紧组成双极板(11),将若干双极板(11)对齐并在上下两侧分别安装集流板(16),在所述集流板(16)远离所述双极板(11)的一侧分别固定连接有端板(15),将螺栓(14)贯穿端板(15)、集流板(16)和双极板(11)后利用螺母(19)进行固定;Step 1. Assembling the fuel cell, arranging a membrane electrode (17) between the upper surface of the anode plate (12) and the lower surface of the cathode plate (13) and aligning and pressing to form a bipolar plate (11). ) align and install current collector plates (16) on the upper and lower sides respectively, on the side of the current collector plate (16) away from the bipolar plate (11) are fixedly connected with end plates (15) respectively, and bolts ( 14) After passing through the end plate (15), the current collecting plate (16) and the bipolar plate (11), the nut (19) is used for fixing; 步骤二、安装燃料电池,将步骤一组装好的燃料电池固定于冷却箱(4)内,并在冷却箱(4)内部顶部安装冷凝管(3);Step 2, installing the fuel cell, fixing the fuel cell assembled in step 1 in the cooling box (4), and installing a condensation pipe (3) on the inner top of the cooling box (4); 步骤三、向冷却箱(4)内通入冷却介质(2),直到冷却介质(2)没过燃料电池且位于冷凝管(3)下方;Step 3: Pass the cooling medium (2) into the cooling box (4) until the cooling medium (2) does not pass the fuel cell and is located below the condensation pipe (3); 步骤四、利用温度传感器以及压力传感器进行监测。Step 4. Use a temperature sensor and a pressure sensor to monitor. 9.根据权利要求8所述的一种冷却开放式燃料电池的冷却方法,其特征在于:步骤四中,当压力传感器监测到冷却箱(4)压力超过预设压力阀值时,开启紧急泄压阀进行泄压。9. A cooling method for cooling an open fuel cell according to claim 8, characterized in that: in step 4, when the pressure sensor detects that the pressure of the cooling tank (4) exceeds a preset pressure threshold, the emergency vent is turned on. pressure relief valve. 10.根据权利要求8所述的一种冷却开放式燃料电池的冷却方法,其特征在于:步骤四中,当燃料电池温度低时,冷却介质(2)依靠自然对流向上汽化蒸发,通过冷凝管(3)冷凝后自然落下;当燃料电池功率增大温度较高时,温度传感器接收到的温度信号达到强制冷却的温度阈值时,启动冷却循环器,冷却介质(2)依靠强制对流流动进行换热,通过冷凝管(3)冷凝后自然落下。10. A cooling method for cooling an open fuel cell according to claim 8, characterized in that: in step 4, when the temperature of the fuel cell is low, the cooling medium (2) is vaporized and evaporated upward by natural convection, and passes through the condensation pipe. (3) Natural fall after condensation; when the fuel cell power increases and the temperature is higher, when the temperature signal received by the temperature sensor reaches the temperature threshold of forced cooling, the cooling circulator is started, and the cooling medium (2) is replaced by forced convection flow. The heat will fall naturally after being condensed through the condensing pipe (3).
CN202210456770.1A 2022-04-28 2022-04-28 Cooling open type fuel cell, cooling system and cooling method Pending CN114792818A (en)

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