CN114538813A - Geopolymer artificial aggregate based on disc granulator and preparation method thereof - Google Patents
Geopolymer artificial aggregate based on disc granulator and preparation method thereof Download PDFInfo
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- 229920000876 geopolymer Polymers 0.000 title claims abstract description 69
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000012190 activator Substances 0.000 claims abstract description 83
- 239000003513 alkali Substances 0.000 claims abstract description 77
- 239000000463 material Substances 0.000 claims abstract description 52
- 239000002245 particle Substances 0.000 claims abstract description 45
- 238000000034 method Methods 0.000 claims abstract description 37
- 239000011343 solid material Substances 0.000 claims abstract description 35
- 239000002893 slag Substances 0.000 claims abstract description 22
- 239000006227 byproduct Substances 0.000 claims abstract description 17
- 239000010881 fly ash Substances 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 11
- 238000005507 spraying Methods 0.000 claims abstract description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 17
- 239000004115 Sodium Silicate Substances 0.000 claims description 16
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 16
- 238000005485 electric heating Methods 0.000 claims description 7
- 239000002910 solid waste Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000004568 cement Substances 0.000 abstract description 15
- 239000002699 waste material Substances 0.000 abstract description 12
- 230000008569 process Effects 0.000 abstract description 8
- 238000001354 calcination Methods 0.000 abstract description 7
- 230000007613 environmental effect Effects 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 abstract description 6
- 239000005431 greenhouse gas Substances 0.000 abstract description 6
- 238000009825 accumulation Methods 0.000 abstract description 4
- 238000010304 firing Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 62
- 239000007787 solid Substances 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 230000008859 change Effects 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 7
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 7
- 229910001948 sodium oxide Inorganic materials 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 230000005284 excitation Effects 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 238000004056 waste incineration Methods 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000010813 municipal solid waste Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000011376 self-consolidating concrete Substances 0.000 description 1
- -1 silicon-aluminum-calcium Chemical compound 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/021—Agglomerated materials, e.g. artificial aggregates agglomerated by a mineral binder, e.g. cement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/12—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic in rotating drums
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
本发明公开一种基于圆盘制粒机的地聚合物人工骨料及其制备方法。方法包括:将固体材料添加至圆盘制粒机中,启动圆盘制粒机;往转动的圆盘制粒机中喷洒碱激发剂溶液进行地质聚合反应,得到地聚合物骨料颗粒;将颗粒表面晾干,然后养护,得到地聚合物人工骨料;按质量百分比计,固体材料由主要胶凝材料20%‑100%和次要胶凝材料0%‑80%组成;主要胶凝材料由粉煤灰100%‑80%和粒化高炉矿渣粉0%‑20%组成;次要胶凝材料选自工业副产品或者废弃物。本发明人工骨料为天然骨料的替代提供了新的可能,解决了骨料紧缺以及工业副产品堆积方面的环境问题。烧制过程中也无需添加水泥,避免了水泥煅烧排放大量温室气体的问题。The invention discloses a geopolymer artificial aggregate based on a disc granulator and a preparation method thereof. The method includes: adding solid material into a disc granulator, and starting the disc granulator; spraying an alkali activator solution into the rotating disc granulator to carry out a geopolymerization reaction to obtain geopolymer aggregate particles; The surface of the particles is dried and then cured to obtain a geopolymer artificial aggregate; by mass percentage, the solid material consists of 20%-100% of the main cementitious material and 0%-80% of the secondary cementitious material; the main cementitious material It is composed of 100%-80% of fly ash and 0%-20% of granulated blast furnace slag powder; the secondary cementitious material is selected from industrial by-products or waste. The artificial aggregate of the present invention provides a new possibility for the replacement of natural aggregate, and solves the environmental problems of shortage of aggregate and accumulation of industrial by-products. There is also no need to add cement during the firing process, which avoids the problem of a large amount of greenhouse gases being emitted from cement calcination.
Description
技术领域technical field
本发明涉及建筑材料技术领域,尤其涉及一种基于圆盘制粒机的地聚合物人工骨料及其制备方法。The invention relates to the technical field of building materials, in particular to a geopolymer artificial aggregate based on a disc granulator and a preparation method thereof.
背景技术Background technique
当前利用工业固体副产品或固体废弃物制备人工骨料是解决目前自然骨料资源紧缺以及固废填埋引起环境问题的一种可行方式。已有比较成熟的骨料制备技术有烧结法和冷结法,比如烧结粉煤灰陶粒和水泥冷结骨料。然而烧结法需要提供高于1000摄氏度的高温,且成本高、排放大。冷结法需要用到10%-20%的水泥,但水泥的高温煅烧过程中会排放大量二氧化碳。At present, the use of industrial solid by-products or solid waste to prepare artificial aggregate is a feasible way to solve the current shortage of natural aggregate resources and the environmental problems caused by solid waste landfill. There are relatively mature aggregate preparation technologies including sintering method and cold bonding method, such as sintered fly ash ceramsite and cement cold bonded aggregate. However, the sintering method needs to provide a high temperature higher than 1000 degrees Celsius, and has high cost and large emissions. The cold bonding method needs to use 10%-20% cement, but a large amount of carbon dioxide is emitted during the high temperature calcination of cement.
一种碱激发地聚合物胶凝材料成为了一种合理有效的解决办法,其具体是由碱溶液对硅-铝-钙相材料进行激发,从而该材料可较快硬化形成具备一定强度的胶凝材料。由于该材料具有耗能低,力学性能优异,耐久性突出等优点,是一种非常具有潜力的建筑材料。粉煤灰和粒状高炉矿渣是两种非常常见的地聚合物胶凝材料,所制备的地聚合物性能稳定。另外,大量工业固体副产品或者废弃物对环境造成的压力亟需处理,比如城市垃圾焚烧炉渣与飞灰,城市污泥焚烧灰,赤泥,锂渣,钢渣,废弃玻璃,煤矸石,磷渣等。An alkali-excited geopolymer gelling material has become a reasonable and effective solution. Specifically, the silicon-aluminum-calcium phase material is excited by an alkaline solution, so that the material can harden quickly to form a gel with a certain strength. coagulation material. Due to the advantages of low energy consumption, excellent mechanical properties and outstanding durability, the material is a very potential building material. Fly ash and granular blast furnace slag are two very common geopolymer cementitious materials, and the prepared geopolymers have stable properties. In addition, the pressure on the environment caused by a large number of industrial solid by-products or wastes needs to be dealt with urgently, such as municipal waste incineration slag and fly ash, municipal sludge incineration ash, red mud, lithium slag, steel slag, waste glass, coal gangue, phosphorus slag, etc. .
中国专利文献CN 108424096A公开了一种使用粉煤灰和石灰作为胶凝材料,同时添加了少量水泥,使用轻质有机颗粒作为内核,采用成球工艺并在中温下燃烧制备了一种低密度高比强的地聚合物骨料。但是,本申请发明人发现,使用中温煅烧耗能仍较大,也会产生温室气体排放。Chinese patent document CN 108424096A discloses a kind of low-density, high-density pellets prepared by using fly ash and lime as cementitious materials, adding a small amount of cement, using light organic particles as cores, and adopting a spheroidizing process and burning at medium temperature. Ratio-strength geopolymer aggregates. However, the inventors of the present application found that the use of medium temperature calcination still consumes a large amount of energy and also generates greenhouse gas emissions.
发明内容SUMMARY OF THE INVENTION
鉴于上述现有技术的不足,本发明的目的在于提供一种基于圆盘制粒机的地聚合物人工骨料及其制备方法,旨在解决现有地聚合物骨料的制备方法需要中温煅烧,导致耗能较大,产生温室气体排放的问题。In view of the above-mentioned deficiencies of the prior art, the purpose of the present invention is to provide a kind of geopolymer artificial aggregate based on a disc granulator and a preparation method thereof, aiming at solving the need for medium temperature calcination in the preparation method of the existing geopolymer aggregate , resulting in high energy consumption and greenhouse gas emissions.
本发明的技术方案如下:The technical scheme of the present invention is as follows:
第一方面,本发明提供一种基于圆盘制粒机的地聚合物人工骨料的制备方法,其中,包括步骤:In a first aspect, the present invention provides a method for preparing a geopolymer artificial aggregate based on a disc granulator, comprising the steps of:
将固体材料添加至圆盘制粒机中,启动圆盘制粒机;Add the solid material to the disc granulator and start the disc granulator;
往转动的圆盘制粒机中的固体材料中喷洒碱激发剂溶液进行地质聚合反应,得到地聚合物骨料颗粒;Spray the alkali activator solution into the solid material in the rotating disc granulator to carry out geopolymerization reaction to obtain geopolymer aggregate particles;
将制好的地聚合物骨料颗粒表面的碱激发剂溶液晾干,然后进行养护,得到所述地聚合物人工骨料;drying the alkali activator solution on the surface of the prepared geopolymer aggregate particles, and then curing to obtain the geopolymer artificial aggregate;
其中,按质量百分比计,所述固体材料由主要胶凝材料20%-100%和次要胶凝材料0%-80%组成;其中所述主要胶凝材料由粉煤灰100%-80%和粒化高炉矿渣粉0%-20%组成;所述次要胶凝材料选自工业副产品或者工业固体废弃物。Wherein, in terms of mass percentage, the solid material is composed of 20%-100% of the main cementing material and 0%-80% of the secondary cementing material; wherein the main cementing material is composed of 100%-80% of fly ash It is composed of 0%-20% of granulated blast furnace slag powder; the secondary cementitious material is selected from industrial by-products or industrial solid waste.
可选地,所述将固体材料添加至圆盘制粒机中的步骤之前,还包括步骤:将主要胶凝材料和次要胶凝材料充分混合及搅拌均匀。Optionally, before the step of adding the solid material to the disc granulator, it further includes the step of: fully mixing and stirring the primary gelling material and the secondary gelling material uniformly.
可选地,所述将固体材料添加至圆盘制粒机中的步骤之后,所述启动圆盘制粒机的步骤之前,还包括步骤:对圆盘制粒机中的固体材料均匀喷洒占总质量5%的碱激发剂溶液。Optionally, after the step of adding the solid material to the disc granulator, and before the step of starting the disc granulator, it further includes the step of: uniformly spraying the solid material in the disc granulator Total mass 5% alkali activator solution.
可选地,所述将固体材料添加至圆盘制粒机中的步骤之后,所述启动圆盘制粒机的步骤之前,还包括步骤:将圆盘制粒机的倾斜角度设置为40°-50°,将圆盘制粒机的转动速度设置为25-35r/min。。Optionally, after the step of adding the solid material to the disc granulator, and before the step of starting the disc granulator, the step further includes the step of: setting the inclination angle of the disc granulator to 40° -50°, set the rotation speed of the disc granulator to 25-35r/min. .
可选地,碱激发剂溶液在启动圆盘制粒机后的6分钟之内分四个阶段喷洒,其中0-1.5分钟内匀速喷洒碱激发剂溶液总质量的47.5%,1.5-3分钟内匀速喷洒碱激发剂溶液总质量的23.75%,3-4.5分钟内匀速喷洒碱激发剂溶液总质量的11.875%,4.5-6分钟内匀速喷洒碱激发剂溶液总质量的11.875%。Optionally, the alkali activator solution is sprayed in four stages within 6 minutes after starting the disc granulator, wherein 47.5% of the total mass of the alkali activator solution is sprayed at a uniform speed within 0-1.5 minutes, and within 1.5-3 minutes. 23.75% of the total mass of the alkali activator solution was sprayed at a uniform speed, 11.875% of the total mass of the alkali activator solution was uniformly sprayed within 3-4.5 minutes, and 11.875% of the total mass of the alkali activator solution was uniformly sprayed within 4.5-6 minutes.
可选地,所述碱激发剂溶液通过以下方法制备得到:将工业无水偏硅酸钠溶于水中,并搅拌,冷却,得到所述碱激发剂溶液;Optionally, the alkali activator solution is prepared by the following method: dissolving industrial anhydrous sodium metasilicate in water, stirring and cooling to obtain the alkali activator solution;
或者,将氢氧化钠溶解于硅酸钠溶液中,并搅拌,冷却,得到所述激发剂溶液。Alternatively, sodium hydroxide is dissolved in a sodium silicate solution, stirred, and cooled to obtain the activator solution.
可选地,碱激发剂选自工业无水偏硅酸钠、氢氧化钠、碳酸钠中的至少一种。Optionally, the alkali activator is selected from at least one of industrial anhydrous sodium metasilicate, sodium hydroxide, and sodium carbonate.
可选地,所述将制好的地聚合物骨料颗粒表面的碱激发剂溶液晾干,然后进行养护的步骤,具体包括:将制好的地聚合物骨料颗粒放置在常温空气中晾干至碱激发剂溶液晾干后,放入温度为60℃-105℃的电热烘箱养护24-48小时,再进行常温空气中养护28天或以上。Optionally, the step of drying the alkali activator solution on the surface of the prepared geopolymer aggregate particles, and then performing maintenance, specifically includes: placing the prepared geopolymer aggregate particles in the air at room temperature to dry. After drying until the alkali activator solution is dry, put it into an electric heating oven with a temperature of 60°C-105°C for 24-48 hours, and then perform curing in normal temperature air for 28 days or more.
可选地,所述地聚合物人工骨料的粒径为5-20mm。Optionally, the particle size of the geopolymer artificial aggregate is 5-20 mm.
第二方面,本发明提供一种地聚合物人工骨料,其中,采用本发明所述的基于圆盘制粒机的地聚合物人工骨料的制备方法制备得到。In a second aspect, the present invention provides a geopolymer artificial aggregate, which is prepared by the method for preparing a geopolymer artificial aggregate based on a disc granulator according to the present invention.
有益效果:本发明采用工业固体副产品(粉煤灰和粒化高炉矿渣粉)为主要胶凝材料,或辅以少量其他工业固体副产品或废弃物为次要胶凝材料,在圆盘制粒机转动的同时喷洒碱激发剂溶液,从而使其聚集形成地聚合物骨料颗粒,地聚合物骨料颗粒表面碱激发剂溶液晾干后,经过养护后即可得到具有良好力学性能以及优异的耐久性能的地聚合物人工骨料。本发明人工骨料为天然骨料的替代提供了新的可能,在一定程度上解决了骨料紧缺以及工业固体副产品及废弃物堆积方面的环境问题。另外,本发明转盘操作耗能低,且无需添加水泥,从而避免了水泥煅烧排放大量温室气体的问题。此外,本发明方法,操作便利,无需复杂特殊生产装置,工艺简单,生产成本低。Beneficial effects: The present invention adopts industrial solid by-products (fly ash and granulated blast furnace slag powder) as the main cementing material, or supplemented by a small amount of other industrial solid by-products or wastes as the secondary cementing material, and the pellet mill is processed in a disc granulator. The alkali activator solution is sprayed while rotating, so that it aggregates to form geopolymer aggregate particles. After the surface of the geopolymer aggregate particles is dried, the alkali activator solution can be obtained with good mechanical properties and excellent durability after curing. Performance geopolymer artificial aggregates. The artificial aggregate of the invention provides a new possibility for the replacement of natural aggregates, and to a certain extent solves the environmental problems of shortage of aggregates and accumulation of industrial solid by-products and wastes. In addition, the operation of the turntable of the present invention consumes less energy and does not need to add cement, thereby avoiding the problem that cement calcination emits a large amount of greenhouse gases. In addition, the method of the present invention is convenient to operate, does not need complicated and special production equipment, has simple process and low production cost.
具体实施方式Detailed ways
本发明提供一种基于圆盘制粒机的地聚合物人工骨料及其制备方法,为使本发明的目的、技术方案及效果更加清楚、明确,以下对本发明进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。The present invention provides a geopolymer artificial aggregate based on a disc granulator and a preparation method thereof. In order to make the purpose, technical scheme and effect of the present invention clearer and clearer, the present invention is further described below in detail. It should be understood that the specific embodiments described herein are only used to explain the present invention, but not to limit the present invention.
本发明实施例提供一种基于圆盘制粒机的地聚合物人工骨料的制备方法,其中,包括步骤:The embodiment of the present invention provides a method for preparing a geopolymer artificial aggregate based on a disc granulator, wherein the method includes the steps:
S10、将固体材料添加至圆盘制粒机中,启动圆盘制粒机;S10, adding the solid material to the disc granulator, and starting the disc granulator;
S20、往转动的圆盘制粒机中的固体材料中喷洒碱激发剂溶液进行地质聚合反应,得到地聚合物骨料颗粒;S20, spraying the alkali activator solution into the solid material in the rotating disc granulator to carry out a geopolymerization reaction to obtain geopolymer aggregate particles;
S30、将制好的地聚合物骨料颗粒表面的碱激发剂溶液晾干,然后进行养护,得到所述地聚合物人工骨料;S30, drying the alkali activator solution on the surface of the prepared geopolymer aggregate particles, and then curing to obtain the geopolymer artificial aggregate;
其中,按质量百分比计,所述固体材料由主要胶凝材料20%-100%和次要胶凝材料0%-80%组成;其中所述主要胶凝材料由粉煤灰100%-80%和粒化高炉矿渣粉0%-20%组成;所述次要胶凝材料选自工业副产品或者工业固体废弃物。Wherein, in terms of mass percentage, the solid material is composed of 20%-100% of the main cementing material and 0%-80% of the secondary cementing material; wherein the main cementing material is composed of 100%-80% of fly ash It is composed of 0%-20% of granulated blast furnace slag powder; the secondary cementitious material is selected from industrial by-products or industrial solid waste.
本实施例中,可以只添加主要胶凝材料,也可以用次要胶凝材料替代部分主要胶凝材料,其中主要胶凝材料可以全部采用粉煤灰,也可以采用粒化高炉矿渣粉替代部分粉煤灰,粒化高炉矿渣粉的加入可以有效提高所制备的人工骨料的力学性能。In this embodiment, only the main cementitious material may be added, or a part of the main cementitious material may be replaced by the secondary cementitious material, wherein the main cementitious material may be all fly ash, or granulated blast furnace slag powder may be used to replace part of the main cementitious material The addition of fly ash and granulated blast furnace slag powder can effectively improve the mechanical properties of the prepared artificial aggregate.
本实施例中,次要胶凝材料选自可被碱激发的或者被碱激发性能弱的或者不可被碱激发的工业副产品或者工业固体废弃物。在一种实施方式中,所述次要胶凝材料选自城市垃圾焚烧炉渣与飞灰、城市污泥焚烧灰、赤泥、锂渣、钢渣、废弃玻璃、煤矸石和磷渣等中的至少一种,但不限于此。In this embodiment, the secondary gelling material is selected from industrial by-products or industrial solid wastes that can be excited by alkali or have weak ability to be excited by alkali or cannot be excited by alkali. In one embodiment, the secondary cementitious material is at least selected from municipal waste incineration slag and fly ash, municipal sludge incineration ash, red mud, lithium slag, steel slag, waste glass, coal gangue and phosphorus slag, etc. One, but not limited to this.
本实施例采用工业固体副产品和废弃物为主要原料,在圆盘制粒机转动的同时喷洒碱激发剂溶液,从而使其聚集形成地聚合物骨料颗粒,地聚合物骨料颗粒表面碱激发剂溶液晾干后,经过养护后即可得到具有良好力学性能(包括高强度、强度可持续增长)以及优异的耐久性能的地聚合物人工骨料。In this example, industrial solid by-products and wastes are used as the main raw materials, and the alkali activator solution is sprayed while the disc granulator is rotating, so as to aggregate them to form geopolymer aggregate particles, and the surface of the geopolymer aggregate particles is alkali excited. After the solution of the agent is dried and cured, a geopolymer artificial aggregate with good mechanical properties (including high strength, sustainable strength growth) and excellent durability can be obtained.
本实施例具有以下优势:This embodiment has the following advantages:
1、本实施例以工业固体副产品及废弃物作为制备原料,以碱溶液作为激发剂,生产成本低,反应过程不产生有毒气体,具有绿色环保的优点,且化废为宝,大大解决了工业固体副产品及废弃物堆积方面的环境问题。1, the present embodiment uses industrial solid by-products and wastes as preparation raw materials, and uses alkaline solution as activator, the production cost is low, the reaction process does not produce toxic gas, has the advantages of environmental protection, and turns waste into treasure, greatly solving the problem of industrial Environmental issues with solid by-products and waste accumulation.
2、本实施例人工骨料为天然骨料的替代提供了新的可能,在一定程度上解决了骨料紧缺的问题。2. The artificial aggregate in this embodiment provides a new possibility for the replacement of natural aggregate, and solves the problem of shortage of aggregate to a certain extent.
3、与大多数采用水泥粘结的制备工艺大大不同,本实施例采用碱激发方式制备人工骨料,无需添加水泥,从而避免了水泥煅烧排放大量温室气体的问题。3. It is very different from most of the preparation processes using cement bonding. In this embodiment, the artificial aggregate is prepared by means of alkali excitation, without adding cement, thereby avoiding the problem of calcining cement and emitting a large amount of greenhouse gases.
4、本实施例转盘操作耗能低,操作便利,无需复杂特殊生产装置,工艺简单。4. In this embodiment, the operation of the turntable has low energy consumption, convenient operation, no complicated special production device, and simple process.
5、本实施例人工骨料强度随放置时间的增加而增长,这是由于粉煤灰的火山灰性能随时间发展可以持续被激发。该骨料强度要求可根据产品性能要求而进行调整,调整方法可包括:改变原材料的种类和比例,改变圆盘制粒机的倾斜角度或转动速度,改变用水量,改变喷洒碱激发剂溶液速率,改变激发剂含量或种类,改变养护方式等。另外,骨料的碱度、吸水率等性能也可根据产品性能要求而进行调整,且同样可以采用上述方法进行调整。5. The strength of the artificial aggregate in this embodiment increases with the increase of the placing time, because the pozzolanic properties of the fly ash can be continuously stimulated with the development of time. The aggregate strength requirements can be adjusted according to the product performance requirements. The adjustment methods can include: changing the type and proportion of raw materials, changing the inclination angle or rotation speed of the disc granulator, changing the water consumption, and changing the rate of spraying the alkali activator solution. , change the content or type of activator, change the maintenance method, etc. In addition, the properties such as alkalinity and water absorption of the aggregate can also be adjusted according to the product performance requirements, and can also be adjusted by the above-mentioned methods.
步骤S10中,在一种实施方式中,所述将固体材料添加至圆盘制粒机中的步骤之前,还包括步骤:将主要胶凝材料和次要胶凝材料充分混合及搅拌均匀。In step S10, in one embodiment, before the step of adding the solid material to the disc granulator, it further includes the step of: fully mixing and stirring the primary gelling material and the secondary gelling material evenly.
步骤S10中,在一种实施方式中,所述将固体材料添加至圆盘制粒机中的步骤之后,所述启动圆盘制粒机的步骤之前,还包括步骤:对圆盘制粒机中的固体材料均匀喷洒占总质量5%的碱激发剂溶液。也就是说,按质量百分比计,本步骤中喷洒的量为碱激发剂溶液总用量的5%。本实施例在启动之前对固体材料均匀喷洒碱激发剂溶液,可以防止圆盘制粒机启动后因固体材料粒径过小而弥漫粉尘。In step S10, in one embodiment, after the step of adding the solid material to the disc granulator, and before the step of starting the disc granulator, it further includes the step of: adding the solid material to the disc granulator. The solid material in the medium is evenly sprayed with a solution of alkali activator accounting for 5% of the total mass. That is to say, in terms of mass percentage, the amount sprayed in this step is 5% of the total amount of the alkali activator solution. In this embodiment, the alkali activator solution is uniformly sprayed on the solid material before starting, which can prevent the disk granulator from being filled with dust due to too small particle size of the solid material after the disk granulator is started.
在一种实施方式中,所述将固体材料添加至圆盘制粒机中的步骤之后,所述启动圆盘制粒机的步骤之前,还包括步骤:将圆盘制粒机的倾斜角度设置为40°-50°,将圆盘制粒机的转动速度设置为25-35r/min。倾斜角度和转动速度均是给制粒提供能量,需要根据所用材料设置在一个合理的范围,过大则造成颗粒之间的粘聚,过小则粘聚力不够,均不利于颗粒的造粒效果。In one embodiment, after the step of adding the solid material to the disc granulator, and before the step of starting the disc granulator, it further includes the step of: setting the inclination angle of the disc granulator For 40°-50°, set the rotation speed of the disc granulator to 25-35r/min. Both the inclination angle and the rotation speed provide energy for granulation, and they need to be set within a reasonable range according to the materials used. If too large, it will cause cohesion between particles, and if too small, the cohesion will be insufficient, which is not conducive to the granulation of particles. Effect.
在一种实施方式中,步骤S10具体包括:将固体材料添加至圆盘制粒机的圆盘内,对圆盘制粒机中的固体材料均匀喷洒碱激发剂溶液,将圆盘制粒机调整至合适的倾斜角度和转动速度,启动圆盘制粒机。In one embodiment, step S10 specifically includes: adding the solid material into the disc of the disc granulator, uniformly spraying the alkali activator solution on the solid material in the disc granulator, and adding the solid material to the disc granulator. Adjust to the proper inclination angle and rotation speed, and start the disc granulator.
步骤S20中,在一种实施方式中,所述碱激发剂溶液通过以下方法制备得到:将工业无水偏硅酸钠(作为激发剂)溶于水中,并适度搅拌以加快溶解,冷却至常温,得到所述碱激发剂溶液。或者,将氢氧化钠溶解于硅酸钠溶液(水玻璃)中,并适度搅拌以加快溶解,冷却至常温,得到所述激发剂溶液。需说明的是,本实施例中的常温指的是温度为20-30℃。In step S20, in one embodiment, the alkali activator solution is prepared by the following method: dissolving industrial anhydrous sodium metasilicate (as the activator) in water, stirring moderately to speed up the dissolution, cooling to room temperature , to obtain the alkali activator solution. Alternatively, sodium hydroxide is dissolved in a sodium silicate solution (water glass), moderately stirred to speed up the dissolution, and cooled to room temperature to obtain the activator solution. It should be noted that the normal temperature in this embodiment refers to a temperature of 20-30°C.
在一种实施方式中,所述碱激发剂溶液中碱激发剂可以选自硅酸钠、氢氧化钠、碳酸钠等中的至少一种。在一种实施方式中,所述碱激发剂中的氧化钠含量占固体材料质量的5%-8%,碱激发剂中的二氧化硅和氧化钠的摩尔比在0.9-2之间,水占固体材料质量的21%-27%。最终制备的骨料随着碱激发剂中氧化钠的质量增加而增加,但氧化钠质量过低会造成骨料质量不高,而过高会造成泛碱现象,一定范围内才能保证胶凝材料被充分激发。碱激发剂中的二氧化硅和氧化钠的摩尔比的变化也会使得最终骨料的性能有所变化,水的质量如果过小,一方面会造成碱溶液浓度过高堵塞喷嘴,另一方面胶凝材料的湿度不够。水的质量过大易造成颗粒之间的粘聚,一定范围内可保证颗粒的有效形成。In one embodiment, the alkali activator in the alkali activator solution may be selected from at least one of sodium silicate, sodium hydroxide, sodium carbonate, and the like. In one embodiment, the content of sodium oxide in the alkali activator accounts for 5%-8% of the mass of the solid material, the molar ratio of silica and sodium oxide in the alkali activator is between 0.9-2, the water It accounts for 21%-27% of the solid material mass. The final prepared aggregate increases with the increase of the quality of sodium oxide in the alkali activator, but the quality of sodium oxide is too low, which will cause the quality of the aggregate to be low, while too high will cause the phenomenon of pan-alkali, and the cementitious material can be guaranteed within a certain range. fully motivated. The change of the molar ratio of silica and sodium oxide in the alkali activator will also change the performance of the final aggregate. If the quality of water is too small, on the one hand, the concentration of the alkali solution will be too high to block the nozzle, and on the other hand Insufficient humidity of the cementitious material. If the quality of water is too large, it is easy to cause cohesion between particles, and the effective formation of particles can be ensured within a certain range.
在一种实施方式中,步骤S20具体包括:将备好的碱激发剂溶液装入喷壶中,在启动圆盘制粒机后的6分钟之内分四个阶段喷洒,其中0-1.5分钟内匀速喷洒碱激发剂溶液总质量的47.5%,1.5-3分钟内匀速喷洒碱激发剂溶液总质量的23.75%,3-4.5分钟内匀速喷洒碱激发剂溶液总质量的11.875%,4.5-6分钟内匀速喷洒碱激发剂溶液总质量的11.875%。6分钟以后,不再喷洒碱激发剂溶液,圆盘制粒机继续转动,总时间为10-15分钟后关闭圆盘制粒机。In one embodiment, step S20 specifically includes: loading the prepared alkali activator solution into a watering can, and spraying it in four stages within 6 minutes after starting the disc granulator, wherein within 0-1.5 minutes 47.5% of the total mass of the alkali activator solution is sprayed at a uniform speed, 23.75% of the total mass of the alkali activator solution is sprayed at a uniform speed within 1.5-3 minutes, 11.875% of the total mass of the alkali activator solution is sprayed at a uniform speed within 3-4.5 minutes, 4.5-6 minutes 11.875% of the total mass of the alkali activator solution was sprayed at a uniform speed. After 6 minutes, the alkali activator solution was no longer sprayed, the disc granulator continued to rotate, and the disc granulator was turned off after a total time of 10-15 minutes.
步骤S30中,将制好的地聚合物骨料颗粒表面多余的碱激发剂溶液晾干,可以避免颗粒与颗粒之间由于表面碱激发剂溶液造成的粘接。In step S30, the excess alkali activator solution on the surface of the prepared geopolymer aggregate particles is dried to avoid adhesion between particles due to the surface alkali activator solution.
在一种实施方式中,所述将制好的地聚合物骨料颗粒表面的碱激发剂溶液晾干,然后进行养护的步骤,具体包括:将制好的地聚合物骨料颗粒放置在常温空气中晾干至碱激发剂溶液晾干后,放入电热烘箱养护24-48小时,再进行常温(20-30℃)空气中养护28天或以上。骨料强度随电热养护时间的延长而增加,但超出一定范围增加有限。骨料强度随养护时间的延长强度也会继续增加。在一种实施方式中,所述电热烘箱的温度为60℃-105℃。该温度养护有利于促进地聚合物反应。In one embodiment, the step of drying the alkali activator solution on the surface of the prepared geopolymer aggregate particles, and then performing curing, specifically includes: placing the prepared geopolymer aggregate particles at room temperature After drying in the air until the alkali activator solution is dry, put it into an electric heating oven for curing for 24-48 hours, and then conduct curing in the air at room temperature (20-30°C) for 28 days or more. Aggregate strength increases with the extension of electric heating curing time, but the increase is limited beyond a certain range. Aggregate strength will continue to increase with curing time. In one embodiment, the temperature of the electric heating oven is 60°C-105°C. This temperature curing is beneficial to promote the geopolymer reaction.
在一种实施方式中,所述地聚合物人工骨料的粒径为5-20mm。In one embodiment, the particle size of the geopolymer artificial aggregate is 5-20 mm.
本实施例以工业固体副产品及废弃物作为制备原料,廉价工业碱溶液为激发剂,生产成本低,反应过程不产生有毒气体,具有绿色环保的优点。同时,本实施例人工骨料为天然骨料的替代提供了新的可能,且该人工骨料强度等要求也可根据产品性能要求而进行调整,调整方法可包括:改变原材料的种类和比例,改变圆盘制粒机的倾斜角度或转动速度,改变用水量,改变喷洒碱激发剂溶液速率,改变激发剂含量或种类,改变养护方式等。In this embodiment, industrial solid by-products and wastes are used as preparation raw materials, and inexpensive industrial alkali solution is used as an activator, the production cost is low, and no toxic gas is generated during the reaction process, which has the advantages of environmental protection. At the same time, the artificial aggregate in this embodiment provides a new possibility for the replacement of natural aggregate, and the requirements such as the strength of the artificial aggregate can also be adjusted according to product performance requirements. The adjustment method can include: changing the type and proportion of raw materials, Change the inclination angle or rotation speed of the disc granulator, change the water consumption, change the spraying rate of the alkali activator solution, change the content or type of the activator, change the maintenance method, etc.
本发明实施例提供一种地聚合物人工骨料,其中,采用如上所述的基于圆盘制粒机的地聚合物人工骨料的制备方法制备得到。The embodiment of the present invention provides a geopolymer artificial aggregate, which is prepared by the above-mentioned preparation method of the geopolymer artificial aggregate based on a disc granulator.
本实施例方法制备得到的地聚合物人工骨料为一定粒径范围内的类球形粗骨料,该骨料粒径为5-20mm,适用于自密实混泥土中提供骨架作用。骨料的吸水率约为13%,可提供良好的内养护性能;颗粒密度约1900kg/m3,比自然骨料约轻25%;单个颗粒强度平均值可达6.9Mpa,达到甚至优于水泥冷结骨料的强度水平。The geopolymer artificial aggregate prepared by the method in this example is a spherical coarse aggregate with a certain particle size range, and the aggregate particle size is 5-20 mm, which is suitable for providing skeleton function in self-compacting concrete. The water absorption rate of the aggregate is about 13%, which can provide good internal curing performance; the particle density is about 1900kg/m 3 , which is about 25% lighter than the natural aggregate; the average strength of a single particle can reach 6.9Mpa, which is even better than cement Strength level of chilled aggregates.
下面通过具体的实施例对本发明作进一步地说明。The present invention will be further described below through specific embodiments.
实施例1Example 1
基于圆盘制粒机的地聚合物人工骨料,其组成如下:Geopolymer artificial aggregate based on disc granulator, its composition is as follows:
(1)主要胶凝材料全采用粉煤灰;不添加次要胶凝材料;(1) Fly ash is used as the main cementitious material; no secondary cementitious material is added;
(2)碱激发剂溶液为工业无水偏硅酸钠与水溶解配制,其中工业无水硅酸钠模数(激发剂中二氧化硅与氧化钠的质量比)为0.94,工业无水偏硅酸钠占主要胶凝材料总质量的12%,水占主要胶凝材料总质量的22%;(2) The alkali activator solution is prepared by dissolving industrial anhydrous sodium metasilicate and water, wherein the industrial anhydrous sodium silicate modulus (the mass ratio of silicon dioxide and sodium oxide in the activator) is 0.94, and the industrial anhydrous sodium silicate is 0.94. Sodium silicate accounts for 12% of the total mass of the main cementitious material, and water accounts for 22% of the total mass of the main cementitious material;
制粒步骤如下:The granulation steps are as follows:
(1)将圆盘制粒机参数调整到倾斜角度为45度,转动速度为30r/min;(1) Adjust the parameters of the disc granulator to a tilt angle of 45 degrees and a rotation speed of 30 r/min;
(2)将胶凝材料添加至圆盘制粒机中,均匀喷洒占总质量5%的碱激发剂溶液;(2) adding the gelling material to the disc granulator, and evenly spraying the alkali activator solution accounting for 5% of the total mass;
(3)启动圆盘制粒机,6分钟之内分四个阶段喷洒,其中0-1.5分钟内匀速喷洒碱激发剂溶液总质量的47.5%,1.5-3分钟内匀速喷洒碱激发剂溶液总质量的23.75%,3-4.5分钟内匀速喷洒碱激发剂溶液总质量的11.875%,4.5-6分钟内匀速喷洒碱激发剂溶液总质量的11.875%。6分钟以后,不再喷洒碱激发剂溶液,制粒机继续转动,总时间为10分钟后关闭制粒机。(3) Start the disc granulator and spray in four stages within 6 minutes, wherein 47.5% of the total mass of the alkali activator solution is sprayed at a uniform speed within 0-1.5 minutes, and the total mass of the alkali activator solution is sprayed at a uniform speed within 1.5-3 minutes. 23.75% of the mass, 11.875% of the total mass of the alkali activator solution is uniformly sprayed within 3-4.5 minutes, and 11.875% of the total mass of the alkali activator solution is uniformly sprayed within 4.5-6 minutes. After 6 minutes, the alkali activator solution was no longer sprayed, the granulator continued to rotate, and the granulator was turned off after a total time of 10 minutes.
(4)将制好的地聚合物骨料颗粒放置在常温空气中至碱激发剂溶液晾干后,放入电热烘箱(105℃)养护24小时,再进行常温(25℃)空气中养护28天。(4) The prepared geopolymer aggregate particles are placed in the air at room temperature until the alkali activator solution is dried, then placed in an electric heating oven (105°C) for curing for 24 hours, and then cured in the air at room temperature (25°C) for 28 sky.
按本实施例得到的地聚合物人工骨料指标性能如下:The index performance of the geopolymer artificial aggregate obtained by the present embodiment is as follows:
24h吸水率:13.1%;24h water absorption: 13.1%;
颗粒密度:1900kg/m3;Particle density: 1900kg/m 3 ;
平均单个颗粒压碎值:6.9MPa。Average single particle crush value: 6.9MPa.
实施例2Example 2
基于圆盘制粒机的地聚合物人工骨料,其组成如下:Geopolymer artificial aggregate based on disc granulator, its composition is as follows:
(1)主要胶凝材料采用粉煤灰和粒化高炉矿渣粉,分别占主要胶凝材料总质量的80%和20%;次要胶凝材料采用城市生活垃圾焚烧炉渣。主要胶凝材料和次要胶凝材料分别占所有固体材料总质量的80%和20%。(1) Fly ash and granulated blast furnace slag powder are used as the main cementing materials, accounting for 80% and 20% of the total mass of the main cementing materials respectively; the secondary cementing materials are municipal solid waste incineration slag. The primary and secondary cementitious materials account for 80% and 20% of the total mass of all solid materials, respectively.
(2)碱激发剂溶液为工业无水偏硅酸钠与水溶解配制,其中工业无水硅酸钠模数(激发剂中二氧化硅与氧化钠的质量比)为0.94,工业无水偏硅酸钠占固体材料质量的12%,水占固体材料质量的22%;(2) The alkali activator solution is prepared by dissolving industrial anhydrous sodium metasilicate and water, wherein the industrial anhydrous sodium silicate modulus (the mass ratio of silicon dioxide and sodium oxide in the activator) is 0.94, and the industrial anhydrous sodium silicate is 0.94. Sodium silicate accounts for 12% of the solid material mass, and water accounts for 22% of the solid material mass;
制粒步骤如下:The granulation steps are as follows:
(1)将城市生活垃圾焚烧炉渣烘干后并用球磨机磨成粉末,此步骤是为了增大细度并达到提高炉渣的碱激发活性的效果。(1) The municipal solid waste incineration slag is dried and ground into powder with a ball mill. This step is to increase the fineness and achieve the effect of improving the alkali excitation activity of the slag.
(2)将圆盘制粒机参数调整到倾斜角度为45度,转动速度为30r/min;(2) Adjust the parameters of the disc granulator to a tilt angle of 45 degrees and a rotation speed of 30 r/min;
(3)将固体材料充分搅拌均匀后添加至圆盘制粒机中,均匀喷洒5%碱激发剂溶液;(3) the solid material is fully stirred and added to the disc granulator, and the 5% alkali activator solution is evenly sprayed;
(4)启动圆盘制粒机,6分钟之内分四个阶段喷洒,其中0-1.5分钟内匀速喷洒总碱激发剂溶液质量的47.5%,1.5-3分钟内匀速喷洒总碱激发剂溶液质量的23.75%,3-4.5分钟内匀速喷洒总碱激发剂溶液质量的11.875%,4.5-6分钟内匀速喷洒总碱激发剂溶液质量的11.875%。6分钟以后,不再喷洒碱激发剂溶液,制粒机继续转动,总时间为10分钟后关闭制粒机。(4) Start the disc granulator, spray in four stages within 6 minutes, and spray 47.5% of the mass of the total alkali activator solution at a uniform speed within 0-1.5 minutes, and spray the total alkali activator solution at a uniform speed within 1.5-3 minutes. 23.75% of the mass, 11.875% of the mass of the total alkali activator solution is uniformly sprayed within 3-4.5 minutes, and 11.875% of the mass of the total alkali activator solution is uniformly sprayed within 4.5-6 minutes. After 6 minutes, the alkali activator solution was no longer sprayed, the granulator continued to rotate, and the granulator was turned off after a total time of 10 minutes.
(5)将制好的地聚合物骨料颗粒放置在常温空气中晾干至碱激发剂溶液去除后,放入电热烘箱(105℃)养护24小时,再进行常温(25℃)空气中养护28天。(5) The prepared geopolymer aggregate particles are placed in the air at room temperature to dry until the alkali activator solution is removed, then placed in an electric heating oven (105°C) for curing for 24 hours, and then cured in the air at room temperature (25°C). 28 days.
按本实施方式得到的地聚合物人工骨料指标性能如下:The index performance of the geopolymer artificial aggregate obtained by this embodiment is as follows:
24h吸水率:15.1%;24h water absorption: 15.1%;
颗粒密度:1470kg/m3;Particle density: 1470kg/m 3 ;
单个颗粒平均压碎值:3.1MPa。The average crushing value of a single particle: 3.1MPa.
上述实施例制得的地聚合物人工骨料粒径范围在5-20mm之间;吸水率较普通砂石骨料大,可提供良好的内养护性能;颗粒密度约1470-1900kg/m3,比自然骨料约轻25%-43%,可用于制备轻骨料混凝土;单个颗粒强度平均值可达3.1-6.9Mpa,达到甚至优于水泥冷结骨料的强度水平。添加生活垃圾焚烧炉渣虽然强度下降但制成的骨料更轻质。The particle size range of the geopolymer artificial aggregate prepared in the above embodiment is between 5-20mm; the water absorption rate is larger than that of the ordinary sand-gravel aggregate, which can provide good internal curing performance; the particle density is about 1470-1900kg/m 3 , It is about 25%-43% lighter than natural aggregate, and can be used to prepare lightweight aggregate concrete; the average strength of single particle can reach 3.1-6.9Mpa, which is even better than the strength level of cement cold aggregate. The addition of domestic waste incinerator slag reduces the strength but makes the aggregate lighter.
综上所述,本发明提供的一种基于圆盘制粒机的地聚合物人工骨料及其制备方法,本发明采用工业固体副产品或者工业固体废弃物为原料,以被激发性能优越的粉煤灰和粒化高炉矿渣粉作为主要胶凝材料,以被激发性能弱或者无被激发性能的其他工业废料作为次要胶凝材料。在圆盘制粒机转动的同时喷洒碱激发剂溶液,从而使其聚集形成地聚合物骨料颗粒,地聚合物骨料颗粒表面碱激发剂溶液晾干后,经过养护后即可得到具有良好力学性能以及优异的耐久性能的地聚合物人工骨料。本发明人工骨料为天然骨料的替代提供了新的可能,在一定程度上解决了骨料紧缺以及工业固体副产品和废弃物堆积方面的环境问题。另外,本发明烧制过程中也无需添加水泥,从而避免了水泥煅烧排放大量温室气体的问题。此外,本发明根据工艺过程中各工艺参数的不同,可以制备不同强度、碱度、吸水率等人工骨料,相对传统天然砂石具有更多功能。最后,本发明方法,操作便利,无需复杂特殊生产装置,工艺简单,生产成本低。To sum up, the present invention provides a disc granulator-based geopolymer artificial aggregate and a preparation method thereof. The present invention uses industrial solid by-products or industrial solid wastes as raw materials, and uses powders with superior excitation performance. Coal ash and granulated blast furnace slag powder are used as the main cementing materials, and other industrial wastes with weak or no excitation performance are used as secondary cementing materials. The alkali activator solution is sprayed while the disc granulator is rotating, so as to aggregate to form geopolymer aggregate particles. After the surface of the geopolymer aggregate particles is dried, the alkali activator solution can be obtained after curing. Geopolymer artificial aggregate with mechanical properties and excellent durability properties. The artificial aggregate of the present invention provides a new possibility for the replacement of natural aggregate, and to a certain extent solves the environmental problems of shortage of aggregate and accumulation of industrial solid by-products and waste. In addition, the present invention does not need to add cement during the calcination process, thereby avoiding the problem that cement calcination emits a large amount of greenhouse gases. In addition, the present invention can prepare artificial aggregates with different strengths, alkalinities, water absorption rates, etc., according to different process parameters in the process, and has more functions than traditional natural sand. Finally, the method of the present invention is convenient to operate, does not need complicated and special production equipment, has simple process and low production cost.
应当理解的是,本发明的应用不限于上述的举例,对本领域普通技术人员来说,可以根据上述说明加以改进或变换,所有这些改进和变换都应属于本发明所附权利要求的保护范围。It should be understood that the application of the present invention is not limited to the above examples. For those of ordinary skill in the art, improvements or transformations can be made according to the above descriptions, and all these improvements and transformations should belong to the protection scope of the appended claims of the present invention.
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