[go: up one dir, main page]

CN1142555A - Prescription and process for intensively bleaching pulp using singlet state oxygen in alkali bleaching stage of multi-stage process - Google Patents

Prescription and process for intensively bleaching pulp using singlet state oxygen in alkali bleaching stage of multi-stage process Download PDF

Info

Publication number
CN1142555A
CN1142555A CN 96116809 CN96116809A CN1142555A CN 1142555 A CN1142555 A CN 1142555A CN 96116809 CN96116809 CN 96116809 CN 96116809 A CN96116809 A CN 96116809A CN 1142555 A CN1142555 A CN 1142555A
Authority
CN
China
Prior art keywords
bleaching
pulp
stage
paper pulp
naclo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 96116809
Other languages
Chinese (zh)
Other versions
CN1055737C (en
Inventor
曹云峰
李忠正
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Forestry University
Original Assignee
Nanjing Forestry University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Forestry University filed Critical Nanjing Forestry University
Priority to CN96116809A priority Critical patent/CN1055737C/en
Publication of CN1142555A publication Critical patent/CN1142555A/en
Application granted granted Critical
Publication of CN1055737C publication Critical patent/CN1055737C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Landscapes

  • Paper (AREA)

Abstract

A bleaching process for paper pulp features use of NaClO and H2O2, which take part in reaction to generate single-linear oxygen that has better selectivity in removing lignin and inereases whiteness and decreases degradation of carbohydrate. The above mentioned two compounds have low corrosion to apparatus.

Description

Intensively bleaching pulp using singlet state oxygen in alkali bleaching stage of multi-stage prescription and technology
The invention belongs to the paper pulp chemical bleaching treatment technology in the pulping chemistry.
The whiteness of paper pulp is the main quality index of paper pulp.The method for bleaching of paper pulp is that the oxygen of handicraft production era floats the earliest.After Sweden chemist K.W.Sheele in 1774 finds chlorine and strong discoloration thereof, just the chlorination bleaching technology is used for textile and paper.Bleaching results when just having brought into use the chlorine bleaching technology is also bad, and the finished product damage is serious.Soon, french chemist Berthollet finds that the bleaching liquor effect that potassium hydroxide (KOH) absorbs behind the chlorine is better, to the damage of finished product seldom.Begin postassium hypochlorite (KClO) in 1789 and be used to bleach textiles.After several years, another one french chemist Labarraque finds to replace potassium hydroxide (KOH) can make similar bleaching liquor with NaOH (NaOH).Scotland chemist C.Tennant in 1798 finds that absorbing chlorine with milk of lime can be made into after calcium hypochlorite is used for bleaching, and paper industry has just obtained bleaching agent with low cost.But the transportation of liquid bleaching liquor is very inconvenient, and 1799, C.Tennant made the bleaching powder of solid state, and one jumps and becomes the unique bleaching agent of textile and paper industry.Calcium hypochlorite is beginning in 1800 as the bleaching agent of paper pulp.U.S. Gilpin paper mill in 1804 is the paper mill of North America first hand with the bleaching powder bleaching, and bleaching slurry in beater carries out for dense 3～4% times.German Bellmer brother had reformed bleaching equipment in 1895, had made the Bel wheat Bellmer of using till today, and the bleached pulp of this equipment is dense brings up to 7%, therefore, has improved bleaching efficiency greatly.1903, Rolm-Haas company proposed to use low sulphite (dithionate) and makes bleaching agent.Germany had proposed with hydrogen peroxide and chlorine multistage bleaching ground wood pulp in 1905.Began in 1919 to prepare the calcium hypochlorite bleaching liquor in the paper mill with liquid chlorine.Nineteen twenty has begun the hypochlorite multistage bleaching.Nineteen twenty-one U.S. Newton Falls papermaking company begins to adopt first high dense (15～25%) Bellmer (the horizontal Bellmer of Wolf).The dense continuous bleaching device of vertical height has appearred in nineteen twenty-five.Nineteen thirty begins to carry out the phase I of continuous chlorination as bleaching with elemental chlorine, obtained for the first time whiteness thus and be 70% float sulfate wood pulp entirely.Nineteen thirty-seven, Sweden used chlorine dioxide ClO for the first time in alkaline medium 2Bleaching agent as prebleaching paper pulp.Sweden in 1938 for the first time in acid medium with using ClO 2Bleaching agent as prebleaching paper pulp.1940, peroxide was used for bleached mechanical pulp and has reached perfect stage.Nineteen forty-six ClO 2Formally be used for the multistage bleaching production system, therefore to nineteen fifty, the whiteness of sulfate wood pulp can be floated to more than 90%.Nineteen fifty-two, Soviet Union wood chemistry expert NiKitin and AKim find that elemental oxygen has discoloration, but seriously fail to be used for production because of carbohydrate degradation.People such as French scientist Robert in 1964 find that magnesium salts has the effect of protection carbohydrate when oxygen floats, and therefore, nineteen sixty-eight the pilot plant that continuous oxygen floats just occurred in the U.S., France and Sweden.Enstra paper mill, South Africa in 1970 has been built up in the world, and the oxygen of 220 tons of paper pulp of first daily output floats the workshop.Muskegon pulp mills of U.S. Scott papermaking company in 1972 build up the ozone bleaching pilot plant of 12 tons of paper pulp of daily output.1975, Scott company applied for the patent of chlorine-free bleaching, and had built up the CEDED displacement bleaching workshop of 500 tons of first daily outputs in the world in 1975.
From the history of association with pulp bleaching technical development, at first be to have developed chlorine bleach, comprise chlorination (technology code name C), hypochlorite bleaching (technology code name H) and ClO 2 bleaching (technology code name D) technology; Then develop oxygen bleach now, comprising oxygen-alkali bleaching (technology code name O), hydrogen peroxide bleaching (technology code name P), ozone bleaching (technology code name Z) and peracetic acid bleaching (technology code name Pa) technology etc.
Sulfate pulping adaptability is big, can utilize various assortments, and technical maturity can be produced high-intensity paper pulp.Therefore, it is the topmost pulping process that adopt countries in the world always.But the pulp brightness that sulfate process is produced is lower, and bleaching process is had relatively high expectations.In order to improve the whiteness of sulfate pulp, adopt the multistage bleaching technology usually, wherein, the most commonly used is chlorination (technology code name C), alkali treatment (technology code name E), hypochlorite bleaching (technology code name H) tri-stage bleaching technology, i.e. CEH tri-stage bleaching technology.In paper pulp multistage bleaching process, chlorination and alkali treatment (also claiming the alkali extracting) are the stages that removes in a large number as residual lignin in the paper pulp, and how many whiteness of paper pulp do not obtain and improve, and therefore, chlorination and alkali treatment can not be used as bleaching process separately.But, chlorination and alkali treatment suitably whether, with the bleaching stage that directly has influence on thereafter.
The objective of the invention is to determine the chemical formulation and the process that in paper pulp CEH multistage bleaching technology alkali treatment section (E section), produce singlet oxygen, thereby reach a part of indissoluble and the coloured chlorlignin that after the alkali treatment section is removed chloridized, exists in the paper pulp, improve the purpose of delignification ability and pulp brightness.
In typical paper pulp multistage bleaching technology---in the CEH tri-stage bleaching technology, the main effect of alkali pretreatment is, removes with chlorlignin a part of indissoluble and the coloured dissolving that alkaline medium exists in the paper pulp after with chloridized.The solubilizing reaction of chlorlignin when alkali treatment seen Fig. 1.In this course of reaction, lignin because positive chlorion parent electricity is attacked the chlorination quinone structure that generates, is subjected to the effect of the hydroxyl ion of nucleophilic when alkali treatment when chlorination, become the quinonyl [seeing Fig. 1 (a)] that hydroxyl replaces, and impels it to dissolve in alkali lye quickly; Hydroxide ion can also be attacked the carbonyl that is present on the o-quinone locations of structures simultaneously, and generates the structure [seeing Fig. 1 (b)] of hydroxyl-carbonyl-penta cyclic ethylene, makes chlorlignin dissolve in the alkali treatment stage equally.In addition, the effect of alkali also makes chlorination process because the dicarboxylic acids dissolving that the fracture of benzene nucleus side chain produces.Alkali treatment is suitable, can not only more lignin of stripping and coloring matter, and during post-bleach, pulp brightness, intensity are improved after making; Go back carbonyl simultaneously, the stability of having promoted pulp brightness owing to some carbohydrate of energy stripping.The unlikely damage paper pulp fiber of alkali treatment generally speaking, but if process conditions are too violent, in the time of similar alkaline cooking also can occurring to the degradation of carbohydrate.
Singlet oxygen (Singlet Oxygen) claim singlet oxygen again, and people such as Wilkinson have proposed it in 1981 and unsaturated compound reacts, the theory that reacts with the two keys of C=C especially, and exist this unsaturated bond in the lignin in a large number.
Technical solution of the present invention is as follows:
1. the intensively bleaching pulp using singlet state oxygen in alkali bleaching stage of multi-stage prescription is characterized in that adding activator hydrogen peroxide H in the common process of alkali treatment section (E section) 2O 2With clorox NaClO.
2. intensively bleaching pulp using singlet state oxygen in alkali bleaching stage of multi-stage technology is characterized in that in the common process of alkali treatment section (E section) activator hydrogen peroxide H 2O 2After mixing, NaClO and slurry add H for adding earlier more in proper order with the interpolation of clorox NaClO 2O 2
Adopt the concrete technology of above technical solution and parameter definite opinion embodiment really.
The common process condition of CEH tri-stage bleaching technology alkali treatment section (E section) is as follows:
NaOH 0.5～5.0% (to oven dry stock), pulp density 6～10%, pH value 9.5～11.5,50～80 ℃ of temperature, 1～2 hour time.
In following each embodiment and result of the test table, all consumptions are all with respect to absolute dried paper pulp; Activator NaClO and H 2O 2Mix in the back adding slurry and use E ABExpression; Add earlier and add H again after NaClO and slurry mix 2O 2Use E A/BExpression; Add H earlier 2O 2Add NaClO E again after mixing with slurry B/AExpression; Represent with subscript I when adding sulfamic acid during processing, as C I, H INot elsewhere specified raw material is betulinic acid salt paper pulp.
Embodiment one, and the addition of activator NaClO is to the influence of delignification effect:
Test combinations and result of the test see Table 1.
Table 1
H 2O 2Consumption be 2.0% o'clock, different N aClO consumption is to the influence of alkali treatment effect
Bleaching process NaClO consumption (%) Viscosity (Cm 3/g) Kappa number Kappa number reduction rate (%)
??C IE B ????0 ????922.2 ????2.01 ????0
??Q IE A/B ????0.20 ????0.50 ????1.00 ????1.50 ????2.00 ????910.6 ????896.1 ????907.6 ????853.7 ????874.8 ????1.75 ????1.69 ????1.71 ????1.82 ????1.84 ????12.9 ????15.9 ????14.9 ????9.5 ????8.5
The result who draws from present embodiment as can be known, when the consumption of activator NaClO surpasses after 1.00%, not only the delignification effect descends, and the viscosity of paper pulp descends morely, illustrate that carbohydrate degradation at this moment is serious, delignification selectivity descends on the contrary.Take all factors into consideration the factor of aspects such as cost and effect, the amount ranges that can make NaClO is comparatively suitable between 0.20～2.00%, and its optimum amount is about 0.50%.
Embodiment two, activator H 2O 2Addition and interpolation order to the influence of delignification effect:
Test combinations and result of the test see Table 2 and accompanying drawing 2～4.
The result who draws from present embodiment as can be known, at activator NaClO and H 2O 2Three kinds of different interpolations order situations under, along with H 2O 2The increase of consumption, the Kappa number and the viscosity of paper pulp all descend, but work as H 2O 2Consumption surpasses after 1%, and the decline of Kappa number all tends towards stability; After Kappa number dropped to a certain degree, the decrease speed of pulp viscosity was accelerated, almost linear decline.This shows that even carry out alkali treatment under stronger condition, those indissoluble lignins also are difficult to remove after the delignification of alkali treatment section arrives to a certain degree, and the degraded of carbohydrate aggravates to some extent at this moment.
The result who draws according to present embodiment also takes all factors into consideration cost and the factor of aspect such as effect, can make H 2O 2Amount ranges comparatively suitable between 0.2～2.0%, its optimum amount is about 1.0%.
The result who draws from present embodiment also knows, at identical H 2O 2Under the situation of consumption, C IE A/BPaper pulp kappa number after the reinforcement is minimum; When identical Kappa number, C IE A/BPulp viscosity after the reinforcement is the highest.This has illustrated with C IE A/BThe delignification effect of schedule of reinforcement is best, and its delignification selectivity is also best.And C IE ABThe effect of schedule of reinforcement is the poorest.Promptly when intensive treatment, should adopt and add H again after allowing NaClO and slurry mix earlier 2O 2Process sequence.
Table 2
The consumption of NaClO is 0.50% o'clock
Different H 2O 2Consumption and NaClO and H 2O 2Interpolation order to the influence of alkali treatment effect
Bleaching process H 2O 2Consumption (%) Viscosity (Cm 3/g) Kappa number
????C IE AB ????0.2 ????0.5 ????1.0 ????1.5 ????2.0 ????1002.1 ????986.2 ????942.2 ????919.2 ????906.1 ????3.27 ????2.80 ????2.20 ????1.98 ????1.89
????C IE A/B ????0.2 ????0.5 ????1.0 ????1.5 ????2.0 ????1010.6 ????978.9 ????946.3 ????916.2 ????899.5 ????2.89 ????2.35 ????2.02 ????1.79 ????1.69
????C IE B/A ????0.2 ????0.5 ????1.0 ????1.5 ????2.0 ????988.2 ????971.0 ????937.0 ????922.0 ????896.1 ????3.05 ????2.70 ????2.05 ????1.90 ????1.8l
Embodiment three, NaClO and H 2O 2Different amounts at C IE BAnd C IE A/BIn the technology to the influence of delignification effect:
Test combinations and result of the test see Table 3 and accompanying drawing 5～7.
In the present embodiment, NaClO and H 2O 2Amount ranges and best point consistent with conclusion among embodiment one and two.In the present embodiment, can clearly be seen that in the alkali treatment section and to add the influence of activator NaClO the delignification effect, promptly when identical Kappa number, C IE A/BThe ratio of viscosities C of paper pulp IE BThe viscosity height of paper pulp, this has illustrated that singlet oxygen has certain selectivity to delignification.
Table 3
NaClO and H 2O 2Different amounts at C IE BAnd C IE A/BIn the technology to the influence of delignification effect
Bleaching process NaClO consumption (%) H 2O 2Consumption (%) Viscosity (Cm 3/g) Kappa number
????C IE B ????0 ????0.2 ????0.5 ????1.0 ????1.5 ????2.0 ????1018.0 ????997.9 ????970.1 ????948.9 ????922.2 ????3.22 ????2.79 ????2.41 ????2.23 ????2.01
????C IE A/B ????0.50 ????0.2 ????0.5 ????1.0 ????1.5 ????2.0 ????1010.6 ????978.9 ????946.3 ????916.2 ????899.5 ????2.89 ????2.30 ????2.02 ????1.79 ????1.69
????C IE A/B ????1.00 ????0.2 ????0.5 ????1.0 ????1.5 ????2.0 ????1014.2 ????988.0 ????941.0 ????913.2 ????895.6 ????2.95 ????2.61 ????2.18 ????1.88 ????1.83
Embodiment four, and betulinic acid salt paper pulp adopts the technology bleaching provided by the present invention back and the bleaching results of other technology to contrast.
C IE BH I, C IE A/BH I, C IEH IB and C IE A/BH IFour kinds of bleaching process of P the results are shown in Table 4 and accompanying drawing 8～11.In the present embodiment, the process conditions of H section are: the consumption of NaClO is 2.8% (effective chlorine meter), and 38 ℃ of temperature, concentration are 8%, and the time is 90 minutes;
The process conditions of P section are: NaSiO 3Consumption be 2%, MgSO 4Consumption is 0.05%, and the consumption of NaOH is 2.0%, and the consumption of NaClO is 1.0%.
Table 4
C IE BH I, C IE A/BH IAnd C IEH IThe bleaching results of three kinds of technologies of B
Technology ??H 2O 2Consumption % Viscosity Cm 3/g Whiteness % (SBD) The PC valency Residual chlorine g/l
Before aging After aging
??C IE BH I ????0.2 ????0.5 ????1.0 ????1.5 ????2.0 ??871.6 ??845.9 ??814.5 ??800.5 ??790.4 ??77.6 ??79.8 ??81.2 ??82.2 ??82.4 ??71.1 ??73.2 ??74.8 ??75.8 ??76.1 ??2.64 ??2.35 ??2.07 ??1.94 ??1.87 ??1.21 ??1.25 ??1.34 ??1.47 ??1.51
?C IE A/BH I ????0.2 ????0.5 ????1.0 ????1.5 ????2.0 ??846.8 ??820.5 ??798.8 ??780.0 ??766.0 ??78.5 ??81.1 ??82.9 ??83.2 ??83.4 ??72.6 ??74.7 ??76.3 ??76.5 ??76.6 ??2.23 ??2.08 ??1.92 ??1.91 ??1.92 ??1.43 ??1.55 ??1.56 ??1.60 ??1.70
??C IEH IB ????0.2 ????0.5 ????1.0 ????1.5 ????2.0 ??792.6 ??773.9 ??765.6 ??753.8 ??755.6 ??80.9 ??82.2 ??83.5 ??83.6 ??83.6 ??76.8 ??77.9 ??78.3 ??78.9 ??79.4 ??1.25 ??1.34 ??1.38 ??1.21 ??1.06 ??0.91 ??0.91 ??0.91 ??0.91 ??0.91
The result who is drawn by present embodiment uses C as can be known IE BH I, C IE A/BH I, C IEH IThe slurry of three kinds of driftage bleachings of B, their final whiteness is along with H 2O 2The increase of consumption and increasing, and the increment rate of whiteness reduces gradually, and the viscosity of paper pulp also descends gradually; In addition, along with the increase of whiteness, the pulp viscosity decrease speed is accelerated.
From C IE BH I, C IE A/BH I, C IEH IThe result of three kinds of driftages of B more as can be known, C IEH IThe whiteness of B is the highest, PC valency minimum, whiteness stable best; And C IE BH IWhiteness minimum, the PC valency is the highest, the stability of whiteness is the poorest.C IE A/BH IBleaching process and C IEH IThe whiteness of B is very approaching, but compares C IEH IB has reduced by a bleaching process.Also can find out C from present embodiment IE A/BH IThe final residual chlorine of H bleaching section higher, therefore, bleaching time that can be by prolonging the H section and reduce H 2O 2Consumption reduces the amount of residual chlorine, to reach the purpose that improves whiteness and reduce brightness reversion.
Embodiment five, the bleaching of softwood sulfate pulp
Kappa number is 28.2 masson pine sulfate pulp, adopts the CEH driftage, and chlorine dosage is 8% o'clock, and floating the back whiteness is 62.0% (SBD).If adopt CE A/BThe H driftage is floated the back whiteness and can be reached 74.4% (SBD), and whiteness is than original 12.4% (SBD) that improve.
Embodiment six, the bleaching of grass as raw material sulfate pulp
Kappa number is 14.8 kraft reed pulp, adopts the CEH driftage, and floating the back whiteness is 80.7% (SBD).If adopt CE A/BThe H driftage is floated the back whiteness and can be reached 84.6% (SBD).
The description of the drawings:
Fig. 1 is the solubilizing reaction of chlorlignin when alkali treatment;
Kappa number and H that Fig. 2 makes for the result according to embodiment two 2O 2Consumption correlation curve;
Viscosity and H that Fig. 3 makes for the result according to embodiment two 2O 2Consumption correlation curve;
Fig. 4 is the viscosity of making according to the result of embodiment two and the correlation curve of Kappa number;
Kappa number and H that Fig. 5 makes for the result according to embodiment three 2O 2Consumption correlation curve;
Viscosity and H that Fig. 6 makes for the result according to embodiment three 2O 2Consumption correlation curve;
Fig. 7 is the viscosity of making according to the result of embodiment three and the correlation curve of Kappa number;
Whiteness and H that Fig. 8 makes for the result according to embodiment four 2O 2The correlation curve of consumption;
PC valency and H that Fig. 9 makes for the result according to embodiment four 2O 2The correlation curve of consumption;
Viscosity and H that Figure 10 makes for the result according to embodiment four 2O 2The correlation curve of consumption;
Figure 11 is the viscosity of making according to the result of embodiment four and the correlation curve of whiteness.
In sum, at panoramic Cl2，NaClO，H 2O 2，O 2，O 3，CH 3COOOH, in the paper pulp bleaching agents such as ClO2, the present invention is actual according to the pulping bleaching of China, has adopted distinguished intensively bleaching pulp using singlet state oxygen in alkali bleaching stage of multi-stage composition and engineering. Because NaClO and H2O 2The singlet oxygens that produce after this two kinds of compounds reaction have good selective when delignification, increase is removed lignin and improves whiteness, the degraded that reduces carbohydrate is very favourable, and these two kinds of compounds are compared with other bleaching agent commonly used, corrosivity to equipment is lower, therefore, more wide in the application prospect of China.
Birch is one of China northeast, North China Hardwood Timber seeds, is important pulping and paper-making material. Adopt technology provided by the present invention, can under the prerequisite that does not increase bleaching process, betulinic acid salt paper pulp be floated to the whiteness of 82.9% (SBD). And the highest paper pulp can only being floated to the whiteness of 73～75% (SBD) of common CEH tri-stage bleaching technique. This technology is also very remarkable to the bleaching effect of the sulfate pulp of softwood sulfate pulp and grass as raw material.

Claims (4)

1. the drug formulation of a paper pulp multistage bleaching technology alkali treatment section (E section) is characterized in that adding 0.20～2.00% clorox NaClO and 0.2～2.0% hydrogen peroxide in the common process of alkali treatment section (E section).
2. a paper pulp multistage bleaching technology is characterized in that hydrogen peroxide H in the common process of alkali treatment section (E section) 2O 2After mixing, NaClO and slurry add hydrogen peroxide for adding earlier more in proper order with the interpolation of hypochlorite.
3. paper pulp multistage bleaching technical recipe as claimed in claim 1, the optimum addition that it is characterized in that clorox NaClO in the common process of alkali treatment section (E section) is 0.50%.
4. paper pulp multistage bleaching technical recipe as claimed in claim 1, the optimum addition that it is characterized in that hydrogen peroxide in the common process of alkali treatment section (E section) is 1.0%.
CN96116809A 1996-01-15 1996-01-15 Prescription and process for intensively bleaching pulp using singlet state oxygen in alkali bleaching stage of multi-stage process Expired - Fee Related CN1055737C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN96116809A CN1055737C (en) 1996-01-15 1996-01-15 Prescription and process for intensively bleaching pulp using singlet state oxygen in alkali bleaching stage of multi-stage process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN96116809A CN1055737C (en) 1996-01-15 1996-01-15 Prescription and process for intensively bleaching pulp using singlet state oxygen in alkali bleaching stage of multi-stage process

Publications (2)

Publication Number Publication Date
CN1142555A true CN1142555A (en) 1997-02-12
CN1055737C CN1055737C (en) 2000-08-23

Family

ID=5123765

Family Applications (1)

Application Number Title Priority Date Filing Date
CN96116809A Expired - Fee Related CN1055737C (en) 1996-01-15 1996-01-15 Prescription and process for intensively bleaching pulp using singlet state oxygen in alkali bleaching stage of multi-stage process

Country Status (1)

Country Link
CN (1) CN1055737C (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005064077A1 (en) * 2003-12-25 2005-07-14 Xiuquan Mei Closed cycle zero discharge bio-oxidizing pulping process
WO2005064076A1 (en) * 2003-12-25 2005-07-14 Xiuquan Mei Closed cycle zero discharge oxidizing pulping process
CN103521081A (en) * 2013-10-31 2014-01-22 哈尔滨工业大学 Method for cleaning membrane pollution with high-activity singlet oxygen
CN103570115A (en) * 2013-10-31 2014-02-12 哈尔滨工业大学 Method of treating reverse osmosis concentrate by using high-activity singlet oxygen
CN105155327A (en) * 2015-07-24 2015-12-16 福建希源纸业有限公司 Production method for hydrophilic transfer printing body paper
CN106012627A (en) * 2016-05-24 2016-10-12 中国林业科学研究院林产化学工业研究所 Method for preparing high-brightness bleached mechanical pulp of bamboo by utilizing alcohol solvent
WO2018106285A1 (en) * 2015-12-07 2018-06-14 Clean Chemistry, Inc. Methods of pulp fiber treatment
US10259729B2 (en) 2014-09-04 2019-04-16 Clean Chemistry, Inc. Systems and method of water treatment utilizing reactive oxygen species and applications thereof
US10472265B2 (en) 2015-03-26 2019-11-12 Clean Chemistry, Inc. Systems and methods of reducing a bacteria population in high hydrogen sulfide water
US10501346B2 (en) 2012-09-07 2019-12-10 Clean Chemistry, Inc. System and method for generation of point of use reactive oxygen species
US10577698B2 (en) 2011-05-31 2020-03-03 Clean Chemistry, Inc. Electrochemical reactor and process
US10883224B2 (en) 2015-12-07 2021-01-05 Clean Chemistry, Inc. Methods of pulp fiber treatment
US11001864B1 (en) 2017-09-07 2021-05-11 Clean Chemistry, Inc. Bacterial control in fermentation systems
US11311012B1 (en) 2017-09-07 2022-04-26 Clean Chemistry, Inc. Bacterial control in fermentation systems

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100404753C (en) * 2002-10-18 2008-07-23 梅秀泉 Oxidation method prepared whole-cotton stalk newspaper pulp and its preparation method
CN100404754C (en) * 2002-10-18 2008-07-23 梅秀泉 Reed pulp prepared from wholly closed pollution-free biological oxidation method and its preparation method

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1072746A (en) * 1991-11-20 1993-06-02 杨广富 A kind of method of efficient bleached pulp
FR2712313B1 (en) * 1993-11-10 1995-12-15 Atochem Elf Sa Process for bleaching a high-yield paper pulp with hydrogen peroxide.

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005064076A1 (en) * 2003-12-25 2005-07-14 Xiuquan Mei Closed cycle zero discharge oxidizing pulping process
CN100420788C (en) * 2003-12-25 2008-09-24 梅秀泉 Totally-enclosed zero-emission biological/oxidation method for cleaning paper pulp and paper pulp obtained thereby
CN100420789C (en) * 2003-12-25 2008-09-24 梅秀泉 Totally-enclosed zero-discharge oxidation clean pulping method
WO2005064077A1 (en) * 2003-12-25 2005-07-14 Xiuquan Mei Closed cycle zero discharge bio-oxidizing pulping process
US10577698B2 (en) 2011-05-31 2020-03-03 Clean Chemistry, Inc. Electrochemical reactor and process
US10501346B2 (en) 2012-09-07 2019-12-10 Clean Chemistry, Inc. System and method for generation of point of use reactive oxygen species
US10875799B2 (en) 2012-09-07 2020-12-29 Clean Chemistry, Inc. System and method for generation of point of use reactive oxygen species
CN103521081A (en) * 2013-10-31 2014-01-22 哈尔滨工业大学 Method for cleaning membrane pollution with high-activity singlet oxygen
CN103570115A (en) * 2013-10-31 2014-02-12 哈尔滨工业大学 Method of treating reverse osmosis concentrate by using high-activity singlet oxygen
US11827543B2 (en) 2014-09-04 2023-11-28 Clean Chemistry, Inc. Method for continuous supply of superoxide-containing peracetate oxidant solution
US10875798B2 (en) 2014-09-04 2020-12-29 Clean Chemistry, Inc. Systems and method for oxidative treatment utilizing reactive oxygen species and applications thereof
US10259729B2 (en) 2014-09-04 2019-04-16 Clean Chemistry, Inc. Systems and method of water treatment utilizing reactive oxygen species and applications thereof
US10941063B2 (en) 2015-03-26 2021-03-09 Clean Chemistry, Inc. Method for down-hole treatment of a production well for sulfur based contaminants
US10472265B2 (en) 2015-03-26 2019-11-12 Clean Chemistry, Inc. Systems and methods of reducing a bacteria population in high hydrogen sulfide water
CN105155327A (en) * 2015-07-24 2015-12-16 福建希源纸业有限公司 Production method for hydrophilic transfer printing body paper
US10611656B2 (en) 2015-12-07 2020-04-07 Clean Chemistry, Inc. Methods of microbial control
WO2018106285A1 (en) * 2015-12-07 2018-06-14 Clean Chemistry, Inc. Methods of pulp fiber treatment
US10883224B2 (en) 2015-12-07 2021-01-05 Clean Chemistry, Inc. Methods of pulp fiber treatment
US11111629B2 (en) 2015-12-07 2021-09-07 Clean Chemistry, Inc. Methods of pulp fiber treatment
US11225755B2 (en) 2015-12-07 2022-01-18 Clean Chemistry, Inc. Methods of paper mill processing using recycled white water with microbial control
US12215460B2 (en) 2015-12-07 2025-02-04 Clean Chemistry, Inc. Methods of microbial control
US11795615B2 (en) 2015-12-07 2023-10-24 Clean Chemistry, Inc. Methods of pulp fiber treatment
CN106012627B (en) * 2016-05-24 2018-05-04 中国林业科学研究院林产化学工业研究所 A kind of method that bamboo wood High brightenss bleach reducing rules are prepared using alcohols solvent
CN106012627A (en) * 2016-05-24 2016-10-12 中国林业科学研究院林产化学工业研究所 Method for preparing high-brightness bleached mechanical pulp of bamboo by utilizing alcohol solvent
US11001864B1 (en) 2017-09-07 2021-05-11 Clean Chemistry, Inc. Bacterial control in fermentation systems
US11311012B1 (en) 2017-09-07 2022-04-26 Clean Chemistry, Inc. Bacterial control in fermentation systems

Also Published As

Publication number Publication date
CN1055737C (en) 2000-08-23

Similar Documents

Publication Publication Date Title
CN1142555A (en) Prescription and process for intensively bleaching pulp using singlet state oxygen in alkali bleaching stage of multi-stage process
US4568420A (en) Multi-stage bleaching process including an enhanced oxidative extraction stage
US5164044A (en) Environmentally improved process for bleaching lignocellulosic materials with ozone
AU638017B2 (en) Environmentally improved process for bleaching lignocellulosic materials
US8864942B2 (en) Process for producing bleached pulp
US5164043A (en) Environmentally improved process for bleaching lignocellulosic materials with ozone
CN114174589A (en) Method for producing bleached pulp
US5211811A (en) Process for high consistency oxygen delignification of alkaline treated pulp followed by ozone delignification
US5188708A (en) Process for high consistency oxygen delignification followed by ozone relignification
FI105213B (en) Method for production of bleached pulp from lignocellulose material
AU2007331538B2 (en) Method for bleaching chemical paper pulps by final ozone treatment at high temperature
WO2005024126A1 (en) Chlorine dioxide delignification of medium consistency pulp
FI62361C (en) BLEKNING AV CELLULOSA MED EN AVSEVAERT REDUCERAD KLORMAENGD
US10006168B2 (en) Method for treating chemical pulps by treatment with ozone in the presence of magnesium ions
CA1080406A (en) Bleach hydrolysis of pulp with substantially reduced use of chlorine
RU2091530C1 (en) Method of groundwood pulp bleaching
Darmawan et al. Effect of oxygen delignification process on the lignin content and wastewater quality from kraft-pulped Eucalyptus pellita
EP0496782A1 (en) HIGH PERFORMANCE METHOD FOR BLEACHING CELLULAR WITH CHLORDIOXYD.
EP0579744A1 (en) Method for reducing colored matter from bleach effluent using a dzd bleach sequence
JP5888151B2 (en) Method for producing bleached pulp
CN112127193A (en) Production process for improving quality index of dissolving pulp by using bleaching process
WO1995006772A1 (en) Improved method for bleaching lignocellulosic pulp
JP2002266271A (en) Bleached pulp with improved fade
JP2005105426A (en) Bleached kraft pulp having improved heat discoloration property
JP4039308B2 (en) Method for producing bleached pulp

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee