CN114156005A - High-temperature sealing adhesive conductor and application thereof in automobile wire harness - Google Patents
High-temperature sealing adhesive conductor and application thereof in automobile wire harness Download PDFInfo
- Publication number
- CN114156005A CN114156005A CN202111334605.0A CN202111334605A CN114156005A CN 114156005 A CN114156005 A CN 114156005A CN 202111334605 A CN202111334605 A CN 202111334605A CN 114156005 A CN114156005 A CN 114156005A
- Authority
- CN
- China
- Prior art keywords
- conductor
- parts
- temperature
- insulating layer
- temperature sealing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004020 conductor Substances 0.000 title claims abstract description 92
- 239000012945 sealing adhesive Substances 0.000 title claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000007789 sealing Methods 0.000 claims abstract description 27
- 239000003292 glue Substances 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 229910052751 metal Inorganic materials 0.000 claims abstract description 19
- 239000002184 metal Substances 0.000 claims abstract description 19
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 14
- 239000007822 coupling agent Substances 0.000 claims abstract description 9
- 239000004593 Epoxy Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000004925 Acrylic resin Substances 0.000 claims description 8
- 229920000178 Acrylic resin Polymers 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 239000003822 epoxy resin Substances 0.000 claims description 8
- 229920000647 polyepoxide Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 229920002379 silicone rubber Polymers 0.000 claims description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 claims description 2
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical compound CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 claims description 2
- CCNDOQHYOIISTA-UHFFFAOYSA-N 1,2-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1C(C)(C)OOC(C)(C)C CCNDOQHYOIISTA-UHFFFAOYSA-N 0.000 claims description 2
- 229920003020 cross-linked polyethylene Polymers 0.000 claims description 2
- 239000004703 cross-linked polyethylene Substances 0.000 claims description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- 239000008393 encapsulating agent Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 239000004945 silicone rubber Substances 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 239000000565 sealant Substances 0.000 abstract description 30
- 229920002050 silicone resin Polymers 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 238000011049 filling Methods 0.000 abstract description 3
- 238000009413 insulation Methods 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- 239000000446 fuel Substances 0.000 abstract 1
- 238000004073 vulcanization Methods 0.000 description 18
- 239000011248 coating agent Substances 0.000 description 14
- 238000000576 coating method Methods 0.000 description 14
- 238000001723 curing Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- 239000006087 Silane Coupling Agent Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- 230000032683 aging Effects 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000003566 sealing material Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/02—Disposition of insulation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
Landscapes
- Sealing Material Composition (AREA)
- Insulated Conductors (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
本发明公开了一种高温封胶导体，包括绞合导体，所述绞合导体外侧设置有绝缘层，所述绝缘层外侧设置有护套层；所述绞合导体与绝缘层之间的空隙中填充有高温密封胶，所述高温密封胶包括按重量份计的如下组分：硅树脂80‑120份、硫化剂5‑20份、导电石墨烯碳管20‑30份、纳米金属粉5‑15份、高温胶70‑120份、偶联剂2‑10份。本发明还公开了所述高温封胶导体在汽车线束中的应用。本发明的高温封胶导体，该高温封胶导体能耐温150℃～200℃、导体内部及导体与绝缘间保持密封，在负压100Hg下不产生漏油现象；电线内部的填充密封物具有导电性，不影响导体原有的导电性；且导体耐各类燃油、耐化学溶剂。
The invention discloses a high-temperature sealant conductor, which comprises a stranded conductor, an insulating layer is arranged on the outer side of the stranded conductor, and a sheath layer is arranged on the outer side of the insulating layer; the gap between the stranded conductor and the insulating layer is Filled with high-temperature sealant, the high-temperature sealant includes the following components by weight: 80-120 parts of silicone resin, 5-20 parts of vulcanizing agent, 20-30 parts of conductive graphene carbon tube, 5 parts of nano metal powder ‑15 parts, high temperature glue 70-120 parts, coupling agent 2-10 parts. The invention also discloses the application of the high temperature sealing glue conductor in the automobile wiring harness. The high-temperature sealant conductor of the present invention can withstand a temperature of 150° C. to 200° C., the inside of the conductor and between the conductor and the insulation are kept sealed, and no oil leakage occurs under a negative pressure of 100Hg; the filling seal inside the wire has conductive properties. It does not affect the original conductivity of the conductor; and the conductor is resistant to various fuels and chemical solvents.
Description
Technical Field
The invention relates to the technical field of wires and cables, in particular to a high-temperature sealing glue conductor and application thereof in an automobile wire harness.
Background
In the existing cable, the full sealing can not be realized among all monofilaments of the stranded conductor and between the conductor and the insulating layer, and gaps are inevitably formed. As a common cable, the usage environment of the automotive wiring harness is mostly a greasy and high-temperature environment, and the automotive wiring harness often needs to bear a certain negative pressure. Under such severe conditions, oil in the oil tank may flow into the cylinder through a gap inside the electric wire, thereby affecting normal use of the engine. Therefore, the common cable cannot meet the requirement of the automobile wire harness, and the automobile wire harness with high temperature resistance and good sealing performance needs to be provided urgently.
Disclosure of Invention
The technical problem to be solved by the invention is to provide a high-temperature sealing glue conductor which can resist the temperature of 150-200 ℃, the interior of the conductor and the space between the conductor and the insulation are kept sealed, and the phenomenon of oil leakage is not generated under the negative pressure of 100 Hg; the filling sealing material in the electric wire has conductivity, and the original conductivity of the conductor is not influenced; and the conductor is resistant to various fuel oils and chemical solvents.
In order to solve the technical problems, the invention provides the following technical scheme:
the invention provides a high-temperature sealing glue conductor which comprises a stranded conductor, wherein an insulating layer is arranged on the outer side of the stranded conductor, and a sheath layer is arranged on the outer side of the insulating layer; the high-temperature sealing adhesive is filled in a gap between the stranded conductor and the insulating layer, and comprises the following components in parts by weight: 80-120 parts of silicon resin, 5-20 parts of vulcanizing agent, 20-30 parts of conductive graphene carbon tubes, 5-15 parts of nano metal powder, 70-120 parts of high-temperature glue and 2-10 parts of coupling agent.
According to the invention, the high-temperature sealant is added into the conventional cable, has good sealing property, is filled among the single wires of the stranded conductor and between the conductor and the insulating layer, realizes the totally-enclosed internal space of the conductor, avoids the oil in the oil tank from flowing into the cylinder through the gap inside the wire, and ensures the normal use of the engine. In addition, the high-temperature sealant also has conductivity, and the original conductivity of the stranded conductor cannot be influenced.
Further, the stranded conductor is formed by stranding a plurality of strands, each strand comprises one or more monofilaments, and each monofilament is a tin-plated monofilament, a silver-plated monofilament or a nickel-plated monofilament. By selecting the single wires as the tin-plated single wires, the silver-plated single wires or the nickel-plated single wires, the temperature resistance of 200 ℃ can be realized, the corrosion resistance of the conductor is improved, and various fuel oil and chemical substances can be resisted. Preferably, the monofilaments are tinned monofilaments.
Further, the insulating layer is a silicon rubber insulating layer or a crosslinked polyethylene insulating layer.
Further, the silicone resin is liquid silicone.
Further, the vulcanizing agent is dicumyl peroxide, 2, 5-dimethyl-2, 5-di (t-butylperoxy) hexane, 2, 4-dichlorobenzoyl peroxide, di-t-butyl peroxide, 2, 5-dimethyl-2, 5-bis (t-butylperoxy) hexane), di (t-butylperoxyisopropyl) benzene, or 1, 1-bis (t-butylperoxy) -3,3, 5-trimethylcyclohexane.
Further, the conductive graphene carbon tube has a diameter of 5 to 50nm and a length of 0.5 to 10 μm.
Further, the thickness of the insulating layer is 1-3 mm.
Further, the nano metal powder is selected from one or more of metal copper powder, metal aluminum powder and metal nickel powder, and the particle size of the nano metal powder is 20-100 nm.
Further, the high-temperature adhesive is composed of epoxy resin, epoxy modified acrylic resin and a curing agent, the mass ratio of the epoxy resin to the epoxy modified acrylic resin is 1-2: 1-2, and the content of the curing agent is 10-20 wt% of the total amount of the resin.
Further, the coupling agent is a silane coupling agent or a titanate coupling agent.
Further, the curing agent is a thermal curing agent, including but not limited to isocyanate curing agents and epoxy curing agents.
Further, the high-temperature sealant comprises the following components in parts by weight: 100 parts of silicon resin, 12 parts of vulcanizing agent, 24 parts of conductive graphene carbon tubes, 10 parts of nano metal powder, 100 parts of high-temperature glue and 8 parts of coupling agent.
The high-temperature sealing glue conductor can be prepared by the following preparation method:
adding a conductive graphene carbon tube, nano metal powder and a coupling agent into a mixer, and mixing at the rotating speed of 300-600 rpm for 30-60 min;
respectively adding silicone resin, a vulcanizing agent and high-temperature glue into the mixer, and mixing at the rotating speed of 300-600 rpm for 30-60 min to obtain a high-temperature sealant coating solution;
providing a stranded conductor, enabling the stranded conductor to pass through high-temperature sealant coating liquid, coating the high-temperature sealant, coating an insulating layer on the outer side of the stranded conductor, and then carrying out vulcanization treatment; after vulcanization, a sheath layer is arranged outside the insulating layer, and the high-temperature sealing glue conductor is obtained.
In the invention, the temperature of the vulcanization treatment is 100-150 ℃, and the time of the vulcanization treatment is 20-60 min. In the process of vulcanization treatment, the high-temperature glue simultaneously carries out curing reaction to firmly bond the conductor monofilament and the insulating layer together.
The invention also provides application of the high-temperature sealing adhesive conductor in an automobile wire harness.
Compared with the prior art, the invention has the beneficial effects that:
1. according to the high-temperature sealing glue conductor, the high-temperature sealing glue is added into a conventional cable, has good sealing performance, is filled among the single wires of the stranded conductor and between the conductor and the insulating layer, realizes the totally-closed internal space of the conductor, avoids oil in an oil tank from flowing into the cylinder through the gap inside the wire, and ensures the normal use of an engine.
2. The high-temperature sealant disclosed by the invention comprises silicon resin, a vulcanizing agent, a conductive graphene carbon tube, nano metal powder, high-temperature glue and a coupling agent, wherein the sealant has good conductivity by adding the conductive graphene carbon tube and the nano metal powder, so that the original conductivity of a conductor cannot be influenced when the sealant is filled among monofilaments of a stranded conductor and between the conductor and an insulating layer; the high-temperature adhesive consists of epoxy resin and epoxy modified acrylic resin with good temperature resistance, so that the bonding performance of the high-temperature adhesive in a high-temperature environment is improved; in addition, by adding the silicone resin and the vulcanizing agent, the mechanical property, the elasticity, the aging resistance and the sealing property of the high-temperature sealant are greatly improved after vulcanization.
Drawings
FIG. 1 is a schematic cross-sectional view of a high temperature molding compound conductor in accordance with embodiment 1 of the present invention;
wherein: 1. a strand; 2. high-temperature sealant; 3. an insulating layer; 4. a sheath layer.
Detailed Description
The present invention is further described below in conjunction with the following figures and specific examples so that those skilled in the art may better understand the present invention and practice it, but the examples are not intended to limit the present invention.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
The experimental methods used in the following examples are conventional methods unless otherwise specified, and materials, reagents and the like used therein are commercially available without otherwise specified.
Example 1
As shown in fig. 1, the embodiment provides a high-temperature sealing compound conductor, which includes a stranded conductor, an insulating layer 3 is disposed outside the stranded conductor, and a sheath layer 4 is disposed outside the insulating layer 3. The cross-sectional area of the stranded conductor is 10mm2The yarn is formed by twisting 16 strands 1, each strand 1 comprises 20 tinned monofilaments, and the diameter of each monofilament is 0.180 mm. The insulating layer 3 is an XLPO insulating layer with a thickness of 1 mm. The sheath layer 4 is a silicon rubber sheath layer with the thickness of 3 mm.
The high-temperature sealant 2 is filled in a gap between the stranded conductor and the insulating layer, and the high-temperature sealant 2 comprises the following components in parts by weight:
wherein the conductive graphene carbon tube has a diameter of 10-20 nm, a length of 5-10 μm, and a particle size of 20-30 nm.
The preparation method of the high-temperature sealing adhesive conductor of the embodiment comprises the following steps: adding the conductive graphene carbon tubes, the nano aluminum powder and the silane coupling agent into a mixer, and mixing at the rotating speed of 500rpm for 60 min; and then respectively adding liquid silica gel, dicumyl peroxide, epoxy resin, epoxy modified acrylic resin and isocyanate curing agent into the mixer, and mixing at the rotating speed of 500rpm for 60min to obtain the high-temperature sealant coating liquid. And finally, the stranded conductor penetrates through the high-temperature sealant coating liquid, the high-temperature sealant is coated, an insulating layer is coated on the outer side of the stranded conductor, and then vulcanization treatment is carried out, wherein the vulcanization treatment temperature is 120 ℃, and the vulcanization treatment time is 60 min. After the vulcanization treatment, a sheath layer is arranged outside the insulating layer, and the high-temperature sealing compound conductor of the embodiment is obtained.
Example 2
The embodiment provides a high temperature seals and glues conductor, including the stranded conductor, the stranded conductor outside is provided with the insulating layer, the insulating layer outside is provided with the restrictive coating. The cross-sectional area of the stranded conductor is 10mm2The yarn is formed by twisting 16 strands, each strand comprises 20 tinned monofilaments, and the diameter of the filament is 0.180 mm. The insulating layer is a silicon rubber insulating layer with the thickness of 1 mm. The restrictive coating is the silicon rubber restrictive coating, and thickness is 3 mm.
And a gap between the stranded conductor and the insulating layer is filled with a high-temperature sealant, and the high-temperature sealant comprises the following components in parts by weight:
wherein the diameter of the conductive graphene carbon tube is 10-20 nm, the length is 5-10 μm, and the particle size of the metallic nickel powder is 30-50 nm.
The preparation method of the high-temperature sealing adhesive conductor of the embodiment comprises the following steps: adding the conductive graphene carbon tube, the nano nickel powder and the silane coupling agent into a mixer, and mixing at the rotating speed of 500rpm for 60 min; and then respectively adding liquid silica gel, dicumyl peroxide, epoxy resin, epoxy modified acrylic resin and epoxy curing agent into the mixer, and mixing at the rotating speed of 500rpm for 60min to obtain the high-temperature sealant. And finally, the stranded conductor penetrates through the high-temperature sealant coating liquid, the high-temperature sealant is coated, an insulating layer is coated on the outer side of the stranded conductor, and then vulcanization treatment is carried out, wherein the vulcanization treatment temperature is 120 ℃, and the vulcanization treatment time is 60 min. After the vulcanization treatment, a sheath layer is arranged outside the insulating layer, and the high-temperature sealing compound conductor of the embodiment is obtained.
Example 3
The embodiment provides a high temperature seals and glues conductor, including the stranded conductor, the stranded conductor outside is provided with the insulating layer, the insulating layer outside is provided with the restrictive coating. The cross-sectional area of the stranded conductor is 10mm2The yarn is formed by twisting 16 strands, each strand comprises 20 tinned monofilaments, and the diameter of the filament is 0.180 mm. The insulating layer is XLPO insulating layer, and the thickness is 2 mm. The restrictive coating is the silicon rubber restrictive coating, and thickness is 3 mm.
And a gap between the stranded conductor and the insulating layer is filled with a high-temperature sealant, and the high-temperature sealant comprises the following components in parts by weight:
wherein the diameter of the conductive graphene carbon tube is 10-20 nm, the length is 5-10 μm, and the particle size of the metal copper powder is 30-50 nm.
The preparation method of the high-temperature sealing adhesive conductor of the embodiment comprises the following steps: adding the conductive graphene carbon tubes, the nano copper powder and the silane coupling agent into a mixer, and mixing at the rotating speed of 500rpm for 60 min; and then respectively adding liquid silica gel, dicumyl peroxide, epoxy resin, epoxy modified acrylic resin and epoxy curing agent into the mixer, and mixing at the rotating speed of 500rpm for 60min to obtain the high-temperature sealant. And finally, the stranded conductor penetrates through the high-temperature sealant coating liquid, the high-temperature sealant is coated, an insulating layer is coated on the outer side of the stranded conductor, and then vulcanization treatment is carried out, wherein the vulcanization treatment temperature is 120 ℃, and the vulcanization treatment time is 60 min. After the vulcanization treatment, a sheath layer is arranged outside the insulating layer, and the high-temperature sealing compound conductor of the embodiment is obtained.
Tests show that the high-temperature sealing glue conductors of the embodiments 1 to 3 have the temperature resistance of 200 ℃, good aging resistance, sealing performance and oil resistance, and can be used as automobile wire harnesses.
In conclusion, the high-temperature sealing glue conductor provided by the invention can resist the temperature of 150-200 ℃, the interior of the conductor and the insulation are sealed, and the oil leakage phenomenon is not generated under the negative pressure of 100 Hg; the filling sealing material in the electric wire has conductivity, and the original conductivity of the conductor is not influenced; and the conductor is resistant to various fuel oils and chemical solvents. The high-temperature sealing glue conductor can be applied to automobile wire harnesses and has wide application prospect.
The above-mentioned embodiments are merely preferred embodiments for fully illustrating the present invention, and the scope of the present invention is not limited thereto. The equivalent substitution or change made by the technical personnel in the technical field on the basis of the invention is all within the protection scope of the invention. The protection scope of the invention is subject to the claims.
Claims (10)
1. A high-temperature glue sealing conductor comprises a stranded conductor, wherein an insulating layer is arranged on the outer side of the stranded conductor, and a sheath layer is arranged on the outer side of the insulating layer; the high-temperature sealing adhesive is characterized in that a high-temperature sealing adhesive is filled in a gap between the stranded conductor and the insulating layer, and the high-temperature sealing adhesive comprises the following components in parts by weight: 80-120 parts of silicon resin, 5-20 parts of vulcanizing agent, 20-30 parts of conductive graphene carbon tubes, 5-15 parts of nano metal powder, 70-120 parts of high-temperature glue and 2-10 parts of coupling agent.
2. The high temperature encapsulated conductor as recited in claim 1, wherein said stranded conductor is formed by stranding a plurality of strands, each strand comprising one or more monofilaments, said monofilaments being tin plated, silver plated or nickel plated.
3. The high temperature sealing compound conductor of claim 1, wherein the insulating layer is a silicone rubber insulating layer or a cross-linked polyethylene insulating layer.
4. A high temperature encapsulated conductor as recited in claim 1, wherein said vulcanizing agent is dicumyl peroxide, 2, 5-dimethyl-2, 5-di (t-butylperoxy) hexane, 2, 4-dichlorobenzoyl peroxide, di-t-butyl peroxide, 2, 5-dimethyl-2, 5-bis (t-butylperoxy) hexane, di (t-butylperoxyisopropyl) benzene, or 1, 1-bis (t-butylperoxy) -3,3, 5-trimethylcyclohexane.
5. The high temperature encapsulant conductor as claimed in claim 1, wherein the conductive graphene carbon tubes have a diameter of 5-50 nm and a length of 0.5-10 μm.
6. The high temperature sealing compound conductor as claimed in claim 1, wherein the thickness of the insulating layer is 1-3 mm.
7. The high-temperature sealing adhesive conductor as claimed in claim 1, wherein the nano metal powder is selected from one or more of metal copper powder, metal aluminum powder and metal nickel powder, and the particle size of the nano metal powder is 20-100 nm.
8. The high-temperature sealing adhesive conductor as claimed in claim 1, wherein the high-temperature adhesive comprises epoxy resin, epoxy modified acrylic resin and a curing agent, the mass ratio of the epoxy resin to the epoxy modified acrylic resin is 1-2: 1-2, and the content of the curing agent is 10 wt% -20 wt% of the total amount of the resin.
9. The high temperature sealing compound conductor as claimed in claim 1, wherein the high temperature sealing compound comprises the following components by weight: 100 parts of silicon resin, 12 parts of vulcanizing agent, 24 parts of conductive graphene carbon tubes, 10 parts of nano metal powder, 100 parts of high-temperature glue and 8 parts of coupling agent.
10. Use of a high temperature sealing compound conductor according to any one of claims 1 to 9 in automotive wiring harnesses.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111334605.0A CN114156005A (en) | 2021-11-11 | 2021-11-11 | High-temperature sealing adhesive conductor and application thereof in automobile wire harness |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111334605.0A CN114156005A (en) | 2021-11-11 | 2021-11-11 | High-temperature sealing adhesive conductor and application thereof in automobile wire harness |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114156005A true CN114156005A (en) | 2022-03-08 |
Family
ID=80459674
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111334605.0A Pending CN114156005A (en) | 2021-11-11 | 2021-11-11 | High-temperature sealing adhesive conductor and application thereof in automobile wire harness |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114156005A (en) |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1656573A (en) * | 2002-05-31 | 2005-08-17 | 大自达电线股份有限公司 | Conductive paste, multilayer board including the conductive paste and process for producing the same |
| CN1661731A (en) * | 2005-01-26 | 2005-08-31 | 上海电缆研究所 | Longitudinal watertight cables/wires |
| CN104021835A (en) * | 2013-02-28 | 2014-09-03 | 比亚迪股份有限公司 | Metal wire for solar cell back electrode and preparation method thereof, back electrode and preparation method thereof, solar cell sheet and cell assembly |
| CN106816202A (en) * | 2017-02-15 | 2017-06-09 | 山东圣泉新材料股份有限公司 | A kind of Graphene denatured conductive silver paste and preparation method thereof |
| CA3162482A1 (en) * | 2016-08-30 | 2018-02-28 | The Boeing Company | Electrically conductive materials |
| WO2019021850A1 (en) * | 2017-07-26 | 2019-01-31 | 株式会社オートネットワーク技術研究所 | Insulated electrical wire |
| CN109585073A (en) * | 2018-11-02 | 2019-04-05 | 江苏亨通电子线缆科技有限公司 | A kind of new-energy automobile high temperature high voltage resistant surpasses flexible cable |
| CN109767866A (en) * | 2018-12-12 | 2019-05-17 | 扬州市凤鸣电缆有限公司 | A kind of ceramic fire-proof high-temperature resistant cable |
| CN110853794A (en) * | 2019-10-30 | 2020-02-28 | 上海润势科技有限公司 | Conductive paste |
| CN111223606A (en) * | 2020-01-09 | 2020-06-02 | 上海电缆研究所有限公司 | A kind of anti-capillary action cable and preparation method thereof |
| CN112908541A (en) * | 2021-01-27 | 2021-06-04 | 上海起帆电线电缆技术有限公司 | High-temperature-resistant vulcanized longitudinal watertight cable for sonar system and twisting mold |
-
2021
- 2021-11-11 CN CN202111334605.0A patent/CN114156005A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1656573A (en) * | 2002-05-31 | 2005-08-17 | 大自达电线股份有限公司 | Conductive paste, multilayer board including the conductive paste and process for producing the same |
| CN1661731A (en) * | 2005-01-26 | 2005-08-31 | 上海电缆研究所 | Longitudinal watertight cables/wires |
| CN104021835A (en) * | 2013-02-28 | 2014-09-03 | 比亚迪股份有限公司 | Metal wire for solar cell back electrode and preparation method thereof, back electrode and preparation method thereof, solar cell sheet and cell assembly |
| CA3162482A1 (en) * | 2016-08-30 | 2018-02-28 | The Boeing Company | Electrically conductive materials |
| CN106816202A (en) * | 2017-02-15 | 2017-06-09 | 山东圣泉新材料股份有限公司 | A kind of Graphene denatured conductive silver paste and preparation method thereof |
| WO2019021850A1 (en) * | 2017-07-26 | 2019-01-31 | 株式会社オートネットワーク技術研究所 | Insulated electrical wire |
| CN109585073A (en) * | 2018-11-02 | 2019-04-05 | 江苏亨通电子线缆科技有限公司 | A kind of new-energy automobile high temperature high voltage resistant surpasses flexible cable |
| CN109767866A (en) * | 2018-12-12 | 2019-05-17 | 扬州市凤鸣电缆有限公司 | A kind of ceramic fire-proof high-temperature resistant cable |
| CN110853794A (en) * | 2019-10-30 | 2020-02-28 | 上海润势科技有限公司 | Conductive paste |
| CN111223606A (en) * | 2020-01-09 | 2020-06-02 | 上海电缆研究所有限公司 | A kind of anti-capillary action cable and preparation method thereof |
| CN112908541A (en) * | 2021-01-27 | 2021-06-04 | 上海起帆电线电缆技术有限公司 | High-temperature-resistant vulcanized longitudinal watertight cable for sonar system and twisting mold |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN201796638U (en) | Polyimide Composite Insulated Cables for Aerospace | |
| CN100530446C (en) | Ethylene propylene rubber insulated non-stick sheath electrical hand cable with 10kV rated voltage | |
| WO2017026391A1 (en) | Dc cable, and method for manufacturing composition and dc cable | |
| CN101887771B (en) | Semiconductive EVA plastic shielded flexible cable and manufacturing method thereof | |
| CN107610825B (en) | A kind of new-energy automobile high temperature resistant flexible cable for connecting and its production technology | |
| CN217933210U (en) | Silica gel insulation new energy automobile shielding cable | |
| CN107039107A (en) | A kind of New-energy electric vehicle charging pile quick charging cable | |
| WO2012073303A1 (en) | Water blocking electric cable | |
| CN111954694A (en) | Resin composition, inorganic filler, direct current cable, and manufacturing method of direct current cable | |
| CN209045225U (en) | The interior high-tension cable of flexible super A class aluminium alloy core new-energy automobile | |
| CN118039262A (en) | Production method for 5G high-frequency anti-interference communication cable | |
| JP2004018652A (en) | Semiconductive watertight composition | |
| CN114156005A (en) | High-temperature sealing adhesive conductor and application thereof in automobile wire harness | |
| JP2003147134A (en) | Semiconductive watertight composition | |
| CN205406117U (en) | Insulating flexible cable line of high temperature resistant flame -retardant | |
| CN109326375A (en) | In-vehicle high-voltage cables for flexible super-A aluminum alloy core new energy vehicles | |
| CN114743722A (en) | Silica gel insulated new energy vehicle shielded cable and preparation method thereof | |
| CN207068489U (en) | New-energy automobile fire resistant special type flexibility aluminium alloy power cable | |
| KR102541344B1 (en) | EPDM high voltage cable for electric vehicle | |
| CN1285074A (en) | Electrically Insulated DC Cables | |
| CN216671238U (en) | Bending-resistant and tearing-resistant single-core cable special for new energy automobile | |
| CN117594282A (en) | Shielded cable, preparation method thereof and vehicle | |
| CN117542568A (en) | Medium voltage cable and method for manufacturing medium voltage cable | |
| CN221378971U (en) | Shielded cable and vehicle | |
| CN218827888U (en) | Corrosion-resistant aluminum wire connecting mechanism |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220308 |