CN1039987C - Production process for nutritious photosynthetic liquid fertilizer - Google Patents

Abstract

The present invention relates to a production technology for nutritious photosynthetic liquid fertilizer, which comprises: firstly, humic acid, trace elements and a compounding additive are mixed to carry out a chelation reaction under an agitating condition to prepare a compounding agent; the compounding agent, urea and a nitrogen solution prepared by an adduction reaction of ammonium nitrate are added to the prepared supersaturated phosphorus-potassium solution containing fine particles; finally, a mixed mixture is milled by colloid mill, homogenized by a homogenizer and is emulsified to prepared the nutritious photosynthetic liquid fertilizer. If ultramicro elements are sprayed while the nutritious photosynthetic liquid fertilizer is applied, grains, fruits, vegetables, etc. not only can be used as food but also have the functions of health-care medicines, and the photosynthesis utilization ratio of crops is greatly increased. Thus, the nutritious photosynthetic liquid fertilizer can increase yield and income.

Description

A kind of production method of nutritious photosynthetic liquid fertilizer

The invention belongs to a kind of liquid fertilizer that contains the employing crop foliage-spray of micro element nutritive type.

As everyone knows, chemical fertilizer is the indispensable volume increase means of agricultural crops.Therefore be devoted to the personage of scientific circles of agricultural both at home and abroad, developing the polytype composite fertilizer that promotes the agricultural crops increasing both production and income with great concentration all the time.Be used for agricultural now and go up more advanced chemical fertilizer and contain trace elements such as iron, zinc, manganese, copper, molybdenum, and according to the crop composite fertilizer special of the required different nitrogen of crop itself, phosphorus, potassium content.We know that foods such as grain, vegetables, fruit are that people are necessary, also are to replenish the various micro-important channel that needed by human body is wanted.But a lot of in the world areas are owing to the restriction and the influence of natural condition, and crops such as the grain of being grown, vegetables and fruit lack naturally as ultramicro-elements such as iodine, selenium, germanium, titaniums.

Finland finds that the earliest trace element-selenium is with the relevant country of heart trouble in the human diet.Present Dutch scientist has taken over this research, and Holland is according to the greatest institute's certify by a physician of studying medicine in Lars, and it is considerably less with trace selenium content in the precursor to have a heart attack.Selenium content in the outbreak precursor is done radiotreatment to clean toenail and just can be measured the wherein content of selenium very exactly so do some research on heart diseases emphatically.The Holland scientist is exactly in this way, takes one group of healthy people, with another kind of 84 the heart patient is taken place recently and contrasts, and the result shows that the selenium content in the people's that once suffers from a heart complaint the toenail is on the low side.The Holland researchist utilizes the collection data analysis, and the low heart trouble rate higher than selenium content of selenium content is high four in the human body.China scientist studies confirm that in the generation of Keshan disease and the environment that trace selenium content is low excessively a direct relation.There are 100,000,000 populations in China approximately owing to selenium content deficiency in the diet formula, and multiple disease takes place.

Trace iodine also is a necessary for human body, and iodine deficiency comprises mainly that thyrocele, congenital deformity are deaf and dumb, infantile dementia, cretinism, and wherein endemic cretinism is that iodine deficiency is the most serious.In China Guizhou, the Heilungkiang morbidity is up to 10-15%, the annual newborn infant of China is in advance in respect of 2,400 ten thousand, wherein 9,600,000 will be born in the iodine deficiency district, just have 100-200 ten thousand intelligence low relatively in 1 year, this numeral is quite fearful.Because this disease is to form between embryonic stage, so once finding just to have lost the treatment meaning, prevention work must be done before gestation.The harm of iodine deficiency is big, because at first invade human brain, belongs to congenital irreversible disease, has a strong impact on people's intelligence growth, and consequence is serious.

Prove that through scientific experiment germanium can make human body produce " Interferon, rabbit " and cancer-resisting substances such as " cell interleukins ", strengthens body immunity, and diseases such as cancer of the stomach, lung cancer, carcinoma of the pancreas, multiple marrow cancer are all had preventive effect and curative effect preferably.Germanium also has antiviral, anti-inflammatory, promotes the effect of hemopoietic function.The modern is along with development of high-tech and growth in the living standard, and is urgent all the more to the demand of anti-senility life-prolonging food.Especially valued pandemic abroad in recent years biogenic organic germanium anti-cancer, antisenility cistanche food.Some producers of Japan are added among the food to extract the solubility organic germanium in genseng, glossy ganoderma, matrimony vine, garlic and the marine alga, topic with " life prolonging food ", " oral liquid for preventing cancer " and etc. good name, market is in very great demand.Why organic germanium has magical health-care effect like this, and it has three big characteristics with the other medicines ratio, and nontoxicity has no side effect; Can strengthen body immunity, all effective to internal organs; Promote red blood corpuscle band oxygen function, make inharmonic part normalizing, thereby reach the purpose of curing various diseases.

Theoretically, the photosynthesis interest rate can reach about 10% on the earth.But actual photosynthesis effect utilization ratio only is 0.4-0.6% at present, and the high-yield field can reach 1-2%.And the sea-tangle that under shallow water, grows, the photosynthesis interest rate can reach 2.5%.Therefore utilize ultramicro-elements such as the highly enriched photosynthetic active iodine of energy, titanium to improve the photosynthesis utilization ratio, can significantly increase per unit area yield.As iodine plot experiment south pawl long to 30-40 jin/, capsicum, tomato 2-3/jin; Paddy rice, corn yield increasing 30-50%, long one times of morning glory pistil.Can estimate thus: cereal, fruit, vegetables per unit area yield, will improve 10-15%, 20-30%, 30-50% respectively.

The objective of the invention is to increase on the basis of 88105079.2 patents ultramicro-element iodine, selenium, germanium, titanium compound and make nutritious photosynthetic liquid fertilizer, to increase the human body trace elements necessary, play health care, disease-resistant, anti-aging, and promote photosynthesis, increasing both production and income significantly.

The production method of nutritious photosynthetic liquid fertilizer of the present invention is achieved in that this method is made up of following step:

(1) with humic acids; Ferrous sulfate, copper sulfate, manganous sulfate, boric acid, Zinc Sulphate Heptahydrate and ammonium molybdate trace compound, its weight ratio are 15-25: 5: 7.5-12: 7.5-15: 9-12: 0.15; Potassiumiodide, Sodium Selenite, sodium germanate and sulfurous acid titanium ultramicro-element compound, its weight ratio 12-25: 20-30: 12-25: 30-48; And by tripoly phosphate sodium STPP, trisodium phosphate, Sodium hexametaphosphate 99 and calcium-base bentonite by its weight ratio 1: 1: the composite additive that 1-1.5: 1-1.5 mixes to form is put among the reactor A, add water and be warming up to 60-80 ℃, stirring is carried out chelatropic reaction and is made recombiner, and wherein the trace compound 10-40% (weight), the ultramicro-element compound that account for recombiner accounts for that 0.5-1.0% (weight), humic acids account for 65-75% (weight), composite additive accounts for 5% (weight);

(2) urea and ammonium nitrate are pressed nitrogen amount 1: the 0.4-0.6 proportioning drops among the reactor B, adds water and is warming up to 40-60 ℃ and carries out addition reaction, makes nitrogen solution;

(3) be 1 by weight with diammonium phosphate and Repone K or vitriolate of tartar again: 2.0-3.2 puts among the reactor C, adds water under the normal temperature and stirs, and makes all over-fed solution that contains particulate;

(4) resultant in A, B two reactors is dropped among the reactor C through fully stirring 1-2 hour, make supersaturation work in-process suspension, drop into the colloidal mill circular grinding again three times, after clarifixator will make suspended particles diameter≤100 micron, photosynthetic liquid fertilizer is made in emulsification;

Above-mentioned nitrogenous fertilizer, phosphine fertilizer, potash fertilizer weight proportion are: 12: 4-9: 5-13; Above-mentioned recombiner accounts for the 2-8% that makes the liquid fertilizer gross weight.

Nutritious photosynthetic liquid fertilizer of the present invention is the compound that proposes crop is sprayed ultramicro-element iodine, selenium, titanium on the basis of 88105079.2 patents, make cereal, fruit, vegetables not only cook food, simultaneously play the health care medicine effect again, and increase substantially crop photosynthesis utilization ratio, increasing both production and income.The present invention utilizes the plant biochemistry effect with ultramicro-element, and the iodine of inorganic states, selenium, germanium, salt compounds are converted into organic, and is the same with Chinese medicine, improves the absorption by human body utilization ratio, makes it play antidotal effect.Develop simultaneously iodine, titanium, etc. element promote photosynthetic usefulness, make the crop photosynthesis utilization ratio be increased to 1-2% by average 0.4-0.6%, by agriculture lab scale for many years, estimate that unit per mu yield cereal, fruit, vegetables etc. can increase production 10-5O%.Iron, zinc, copper, manganese, molybdenum that the present invention has also increased relatively except that boron are human nutrition, diseases prevention, anti-ageing trace elements necessary, and through the field lab scale, above-mentioned six kinds of trace elements all can promote photosynthesis in varying degrees, improve its utilization ratio.

Below will the invention will be further described by embodiment.

Embodiment 1

Henan wheat is special-purpose fertile: nitrogen, phosphorus, potassium three fertile proportionings are 16: 10: 9, effective constituent 35.At first add 15 kilograms of refining humic acidss (yellow humic acid) at reactor A, trace element ferrous sulfate 2500 grams, copper sulfate 500 grams, manganous sulfate 1200 grams, boric acid 1000 grams, Zinc Sulphate Heptahydrate 1200 grams, ammonium molybdate 15 grams, add ultramicro-element potassiumiodide 5 gram, Sodium Selenite 5 grams, sodium germanate 3 grams, sulfurous acid titanium 10 grams again and be warmed to 60-80 ℃, add again and contain tripoly phosphate sodium STPP, each 200 gram of trisodium phosphate, composite additives of each 300 gram of Sodium hexametaphosphate 99, calcium-base bentonite fully stir for 1 kilogram, carry out chelatropic reaction half an hour.

Secondly 130 kilograms in urea, 179 kilograms of input reactors of ammonium nitrate B are added certain water gaging, carry out addition reaction when being heated to 40-60 ℃, stir half an hour, make nitrogen solution.

To add 217 kilograms of diammonium phosphate among the reactor C again, 150 kilograms in Repone K and certain water gaging, normal temperature stirs down.

At last the resultant in A, B two reactors is dropped among the reactor C and stirred 1 hour, make saturated work in-process suspension through abundant.Drop into the colloidal mill circular grinding again three times,, thereby make wheat special nutritional photosynthetic liquid fertilizer after clarifixator will make suspended particles diameter≤100 micron.

When wheat booting, spray 1-2 time as ear manuer, each 0.5-1 kilogram, every mu can be increased production the 15-20 kilogram.Should at fine day before early 10 o'clock or after at 4 o'clock in afternoon, with stoste thin up 50-100 doubly, whenever use 1 kilogram and can replace five kilograms of soil topdressings during use.Can increasing both production and income.

Embodiment 2

Changzhou fertilizer special for cole: nitrogen, phosphorus, potassium three fertile proportionings are 14: 10: 11, effective constituent 35.At first add 15 kilograms of refining humic acidss at reactor A, trace element ferrous sulfate 2500 grams, copper sulfate 500 grams, manganous sulfate 750 grams, boric acid 1500 grams, Zinc Sulphate Heptahydrate 900 grams, ammonium molybdate 15 grams, add 1 kilogram of ultramicro-element potassiumiodide 3 gram, Sodium Selenite 5 grams, sodium germanate 3 grams, sulfurous acid titanium 10 grams, composite additive (composition such as example one) again, fully stir, carry out chelatropic reaction half an hour.

Secondly 110 kilograms in urea, 149 kilograms of input reactors of ammonium nitrate B are added certain water gaging, carry out addition reaction when being heated to 40-60 ℃, stir half an hour, make nitrogen solution.

To add 217 kilograms of diammonium phosphate among the reactor C again, 183 kilograms in Repone K and certain water gaging, normal temperature stirs down.

At last the resultant in A, B two reactors is dropped among the reactor C and stir, make work in-process supersaturation suspension through abundant.Again it is dropped into colloidal mill circular grinding three times,, thereby make rape special nutritional photosynthetic liquid fertilizer after clarifixator will make suspended particles diameter≤100 micron.

Before and after rape bears pods, topdress and spray 2 times, each 0.5-0.75 kilogram, every mu can be increased production the 5-10 kilogram.Should at fine day before early 10 o'clock or after at 4 o'clock in afternoon, with stoste thin up 50-100 doubly, whenever use 1 kilogram and can replace five kilograms of soil topdressings during use.Can increasing both production and income.

Implement 3

The Jing Dezhen citrus special fertilizer: nitrogen, phosphorus, potassium three fertile proportionings are 16: 6: 13, effective constituent 35.At first add 15 kilograms of refining humic acidss at reactor A, trace element ferrous sulfate 1500 grams, copper sulfate 500 grams, manganous sulfate 1200 grams, boric acid 1500 grams, Zinc Sulphate Heptahydrate 1200 grams, ammonium molybdate 15 grams, add ultramicro-element potassiumiodide 5 gram, Sodium Selenite 8 grams, sodium germanate 5 grams, sulfurous acid titanium 15 grams again and be warmed to 60-80 ℃, add again and contain tripoly phosphate sodium STPP, each 200 gram of trisodium phosphate, additives of each 300 gram of Sodium hexametaphosphate 99, calcium-base bentonite fully stir for 1 kilogram, carry out chelatropic reaction half an hour.

Secondly with 149 kilograms in urea, 202 kilograms of input reactors of ammonium nitrate B, add certain water gaging, carry out addition reaction when being heated to 40-60 ℃, stir half an hour, make nitrogen solution.

To add 130 kilograms of diammonium phosphate among the reactor C again, 260 kilograms in Repone K and certain water gaging, normal temperature stirs down.

At last the resultant in A, B two reactors is dropped among the reactor C and stirred 1 hour, make supersaturation work in-process suspension through abundant.Drop into the colloidal mill circular grinding again three times,, thereby make citrus special nutritional photosynthetic liquid fertilizer after clarifixator will make suspended particles diameter≤100 micron.

In citrus flower early stage, young fruit period, physiological fruit drop phase, each spray of strong fruit phase once, totally four times, each consumption is big or small with each 0.5-1 kilogram according to tree crown, and every mu can be increased production 15-30%.Should with stoste thin up 50-100 doubly, whenever use 1 kilogram and can replace five kilograms of soil topdressings before fine 10 o'clock or after at 4 o'clock in afternoon during use.Can increasing both production and income.

Embodiment 4

Huoxian county fruit and vegetable are special-purpose fertile: nitrogen, phosphorus, potassium three fertile proportionings are 19: 10: 7, effective constituent 36.At first add 15 kilograms of refining humic acidss at reactor A, trace element ferrous sulfate 2500 grams, copper sulfate 500 grams, manganous sulfate 750 grams, boric acid 750 grams, Zinc Sulphate Heptahydrate 900 grams, ammonium molybdate 15 grams, add 1 kilogram of ultramicro-element potassiumiodide 3 gram, Sodium Selenite 6 grams, sodium germanate 4 grams, sulfurous acid titanium 12 grams, additive (composition such as example three) again, fully stir, carry out chelatropic reaction half an hour.

Secondly 164 kilograms in urea, 222 kilograms of input reactors of ammonium nitrate B are added certain water gaging, carry out addition reaction when being heated to 40-60 ℃, stir half an hour, make nitrogen solution.

To add 217 kilograms of diammonium phosphate among the reactor C again, 117 kilograms in Repone K and certain water gaging, normal temperature stirs down.

At last the resultant in A, B two reactors is dropped among the reactor C and stir, make work in-process supersaturation suspension through abundant.Drop into the colloidal mill circular grinding again three times,, thereby make fruit and vegetable special nutritional photosynthetic liquid fertilizer after clarifixator will make suspended particles diameter≤100 micron.

Sprayed once every 10 days to flowering fruit bearing stage in the first flower bud phase of fruit and vegetable,, totally five times.Each 0.5 kilogram, every mu can be increased production 20-50%.Should at fine day before early 10 o'clock or after at 4 o'clock in afternoon, with stoste thin up 50-100 doubly, whenever use 1 kilogram and can replace five kilograms of soil topdressings during use.Can increasing both production and income.

Claims (1)

1. the production method of a nutritious photosynthetic liquid fertilizer is characterized in that this method is made up of following step:

(1) with humic acids; Ferrous sulfate, copper sulfate, manganous sulfate, boric acid, Zinc Sulphate Heptahydrate and ammonium molybdate trace compound, its weight ratio are 15-25: 5: 7.5-12: 7.5-15: 9-12: 0.15; Potassiumiodide, Sodium Selenite, sodium germanate and sulfurous acid titanium ultramicro-element compound, its weight ratio 12-25: 20-30: 12-25: 30-48; And by tripoly phosphate sodium STPP, trisodium phosphate, Sodium hexametaphosphate 99 and calcium-base bentonite by its weight ratio 1: 1: the composite additive that 1-1.5: 1-1.5 mixes to form is put among the reactor A, add water and be warming up to 60-80 ℃, stirring is carried out chelatropic reaction and is made recombiner, and wherein trace compound accounts for recombiner 10-40% (weight), ultramicro-element compound and accounts for that 0.5-1.0% (weight), humic acids account for 65-75% (weight), composite additive accounts for 5% (weight);

(2) urea and ammonium nitrate are pressed nitrogen amount 1: the 0.4-0.6 proportioning drops among the reactor B, adds water and is warming up to 40-60 ℃ and carries out addition reaction, makes nitrogen solution;

(3) be 1 by weight with diammonium phosphate and Repone K or vitriolate of tartar again: 2.0-3.2 puts among the reactor C, adds water under the normal temperature and stirs, and makes the supersaturated solution that contains particulate;

(4) resultant in A, B two reactors is dropped among the reactor C through fully stirring 1-2 hour, make supersaturation work in-process suspension, drop into the colloidal mill circular grinding again three times, after clarifixator will make suspended particles diameter≤100 micron, photosynthetic liquid fertilizer is made in emulsification;

Above-mentioned nitrogenous fertilizer, phosphate fertilizer, potash fertilizer weight proportion are: 12: 4-9: 5-13; Above-mentioned recombiner accounts for the 2-8% that makes the liquid fertilizer gross weight.