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CN103943816A - Magnesium storage primary battery - Google Patents

Magnesium storage primary battery Download PDF

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Publication number
CN103943816A
CN103943816A CN201410189872.7A CN201410189872A CN103943816A CN 103943816 A CN103943816 A CN 103943816A CN 201410189872 A CN201410189872 A CN 201410189872A CN 103943816 A CN103943816 A CN 103943816A
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CN
China
Prior art keywords
magnesium
current collector
tube
battery
positive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410189872.7A
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Chinese (zh)
Inventor
张纪贵
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Individual
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Individual
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Priority to CN201410189872.7A priority Critical patent/CN103943816A/en
Publication of CN103943816A publication Critical patent/CN103943816A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/06Electrodes for primary cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/70Carriers or collectors characterised by shape or form
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

本发明公开了一种镁储备一次电池,它包括一个正极集流体和一个相对的负极底,在一个圆筒形正极集流体的空腔内从顶壁到负极之间同圆心安装有一个镁负极管,在镁负极管侧面均布有6-12个直径为2.5mm的渗滴孔,在镁负极管外壁上包裹有一个隔膜纸筒,在镁负极管内装有储液纤维,在负极底与正极集流体之间安装有一个绝缘圈,在绝缘圈上面的正极集流体与镁负极管之间填充有吸水纤维,在吸水纤维上面的正极集流体与镁负极管之间依次填充有三个长度相同的正极环。本发明在电池内部设置储液型腔及其渗透通道,增大了正极密度,使电池的短路电流和电容量成倍增加,也增加了电池的适用范围,而且无重金属污染。

The invention discloses a magnesium reserve primary battery, which comprises a positive electrode current collector and a relative negative electrode bottom, and a magnesium negative electrode is installed concentrically between the top wall and the negative electrode in the cavity of a cylindrical positive electrode current collector There are 6-12 seepage holes with a diameter of 2.5mm evenly distributed on the side of the magnesium negative tube, a diaphragm paper tube is wrapped on the outer wall of the magnesium negative tube, and liquid storage fibers are installed in the magnesium negative tube. An insulating ring is installed between the positive current collectors, water-absorbing fibers are filled between the positive current collectors on the insulating ring and the magnesium negative tubes, and three of the same length are filled sequentially between the positive current collectors on the water-absorbing fibers and the magnesium negative tubes. positive ring. The invention arranges liquid storage cavity and permeation channel inside the battery, increases the positive electrode density, doubles the short-circuit current and electric capacity of the battery, increases the application range of the battery, and has no heavy metal pollution.

Description

一种镁储备一次电池A magnesium reserve primary battery

  the

技术领域: Technical field:

    本发明涉及蓄电池,特别是一种短路电流大,电容量高、结构合理、储存性能好的镁储备一次电池。 The present invention relates to storage batteries, in particular to a magnesium reserve primary battery with large short-circuit current, high capacitance, reasonable structure and good storage performance.

背景技术: Background technique:

目前的各种储备型电池,虽然选用材料各不相同,但都是采用普通勒克朗谢锌锰电池结构。因为电池内部不具备储液型腔,没有液体渗透通道,且正极密度松散,所以存在短路电流小、电容量低、适用范围小、效率低的缺点。 The current various storage batteries, although the materials used are different, all adopt the ordinary Leclanchet zinc-manganese battery structure. Because the battery does not have a liquid storage cavity inside, there is no liquid permeation channel, and the density of the positive electrode is loose, it has the disadvantages of small short-circuit current, low capacitance, small application range, and low efficiency.

发明内容: Invention content:

本发明的目的是提供一种结构合理、短路电流和电容大、适用范围广的镁储备一次电池。 The purpose of the present invention is to provide a magnesium storage primary battery with reasonable structure, large short-circuit current and capacitance, and wide application range.

本发明的技术方案是以如下方式完成的,一种镁储备一次电池,它包括一个正极集流体和一个相对的负极底, 其特征在于:在一个圆筒形正极集流体的空腔内从顶壁到负极之间同圆心安装有一个镁负极管,在镁负极管侧面均布有6-12个直径为2.5mm的渗滴孔,在镁负极管外壁上包裹有一个隔膜纸筒,在镁负极管内装有储液纤维,在负极底与正极集流体之间安装有一个绝缘圈,在绝缘圈上面的正极集流体与镁负极管之间填充有吸水纤维,在吸水纤维上面的正极集流体与镁负极管之间依次填充有三个长度相同的正极环。 The technical solution of the present invention is accomplished in the following manner, a magnesium storage primary battery, which includes a positive electrode current collector and a relative negative electrode bottom, characterized in that: in the cavity of a cylindrical positive electrode current collector, from the top A magnesium negative tube is installed concentrically between the wall and the negative electrode. On the side of the magnesium negative tube, there are 6-12 seepage holes with a diameter of 2.5mm. A diaphragm paper tube is wrapped on the outer wall of the magnesium negative tube. The liquid storage fiber is installed in the negative electrode tube, and an insulating ring is installed between the negative electrode bottom and the positive electrode current collector. The water-absorbing fiber is filled between the positive electrode current collector and the magnesium negative electrode tube on the insulating ring, and the positive electrode collector on the water-absorbing fiber is Three positive electrode rings of the same length are sequentially filled with the magnesium negative electrode tube.

本发明在电池内部设置储液型腔及其渗透通道,增大了正极密度,使电池的短路电流和电容量成倍增加,也增加了电池的适用范围,而且无重金属污染。 The invention arranges liquid storage cavity and permeation channel inside the battery, increases the positive electrode density, doubles the short-circuit current and electric capacity of the battery, increases the application range of the battery, and has no heavy metal pollution.

附图说明: Description of drawings:

    图1是本发明的结构示意图;图2是储液纤维的结构示意图;图3是吸水纤维的结构示意图;图4是绝缘圈的结构示意图;图5是负极底的结构示意图。 Fig. 1 is a schematic structural diagram of the present invention; Fig. 2 is a schematic structural diagram of a liquid storage fiber; Fig. 3 is a schematic structural diagram of a water-absorbing fiber; Fig. 4 is a schematic structural diagram of an insulating ring; Fig. 5 is a schematic structural diagram of a negative electrode bottom.

具体实施方式: Detailed ways:

结合以上附图详细描述实施例,它包括一个正极集流体1和一个相对的负极底8,其改进之处是在一个圆筒形正极集流体的空腔内从顶壁到负极之间同圆心安装有一个镁负极管4,在镁负极管侧面均布有6-12个直径为2.5mm的渗滴孔,在镁负极管外壁上包裹有一个隔膜纸筒3,在镁负极管内装有储液纤维5,在负极底与正极集流体之间安装有一个绝缘圈7,在绝缘圈上面的正极集流体与镁负极管之间填充有吸水纤维6,在吸水纤维上面的正极集流体与镁负极管之间依次填充有三个长度相同的正极环2。该电池的正极集流体采用普通碱性电池钢壳,正极环由锰、碳、电解质粉与粘结剂用压环机压制而成,然后将其紧贴筒壁压入正极集流体中,镁负极管由镁合金挤压而成,用隔膜纸包裹后插入正极环中形成储液空腔,再在储液空腔内填入储液纤维,然后在下部装入吸水纤维、绝缘圈,最后将负极底与正极集流体封闭即可。 The embodiment is described in detail in conjunction with the above drawings, which includes a positive electrode current collector 1 and a relative negative electrode bottom 8, and the improvement is that the center of the circle from the top wall to the negative electrode is concentric in the cavity of a cylindrical positive electrode current collector. A magnesium negative tube 4 is installed, and 6-12 seepage holes with a diameter of 2.5 mm are evenly distributed on the side of the magnesium negative tube, and a diaphragm paper tube 3 is wrapped on the outer wall of the magnesium negative tube, and a storage tank is housed in the magnesium negative tube. Liquid fiber 5, an insulating ring 7 is installed between the bottom of the negative electrode and the positive electrode current collector, water-absorbing fiber 6 is filled between the positive electrode current collector on the insulating ring and the magnesium negative tube, the positive electrode current collector on the water-absorbing fiber and the magnesium Three positive electrode rings 2 with the same length are sequentially filled between the negative electrode tubes. The positive electrode current collector of the battery is made of ordinary alkaline battery steel shell, and the positive electrode ring is pressed by manganese, carbon, electrolyte powder and binder with a ring pressing machine, and then pressed into the positive electrode current collector close to the wall of the cylinder, magnesium The negative electrode tube is extruded from magnesium alloy, wrapped with diaphragm paper and inserted into the positive electrode ring to form a liquid storage cavity, and then filled with liquid storage fibers in the liquid storage cavity, and then filled with water-absorbing fibers and insulating rings in the lower part, and finally It is sufficient to seal the bottom of the negative electrode and the current collector of the positive electrode.

Claims (1)

1. A magnesium reserve primary battery, comprising a positive current collector and an opposite negative electrode substrate, characterized in that: a magnesium cathode tube is concentrically arranged in a cavity of a cylindrical anode current collector from a top wall to a cathode, 6-12 seepage holes with the diameter of 2.5mm are evenly distributed in the side face of the magnesium cathode tube, a diaphragm paper tube is wrapped on the outer wall of the magnesium cathode tube, liquid storage fibers are arranged in the magnesium cathode tube, an insulating ring is arranged between the bottom of the cathode and the anode current collector, water absorption fibers are filled between the anode current collector above the insulating ring and the magnesium cathode tube, and three anode rings with the same length are sequentially filled between the anode current collector above the water absorption fibers and the magnesium cathode tube.
CN201410189872.7A 2014-05-07 2014-05-07 Magnesium storage primary battery Pending CN103943816A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410189872.7A CN103943816A (en) 2014-05-07 2014-05-07 Magnesium storage primary battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410189872.7A CN103943816A (en) 2014-05-07 2014-05-07 Magnesium storage primary battery

Publications (1)

Publication Number Publication Date
CN103943816A true CN103943816A (en) 2014-07-23

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410189872.7A Pending CN103943816A (en) 2014-05-07 2014-05-07 Magnesium storage primary battery

Country Status (1)

Country Link
CN (1) CN103943816A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1387073A (en) * 1971-08-05 1975-03-12 Lequipement Electr Des Vehicul Dry cell
JP2003197206A (en) * 2001-12-27 2003-07-11 Toshiba Battery Co Ltd Sealed alkaline zinc primary battery
CN2896537Y (en) * 2006-05-24 2007-05-02 张纪贵 Magnesium manganese cardboard primary battery
CN101167212A (en) * 2004-08-06 2008-04-23 吉莱特公司 Primary alkaline battery comprising bismuth metal oxide
CN203553281U (en) * 2013-11-01 2014-04-16 江门金刚电源制品有限公司 Alkaline battery capable of prolonging release time of electrolyte
CN203826477U (en) * 2014-05-07 2014-09-10 张纪贵 Magnesium storage primary battery

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1387073A (en) * 1971-08-05 1975-03-12 Lequipement Electr Des Vehicul Dry cell
JP2003197206A (en) * 2001-12-27 2003-07-11 Toshiba Battery Co Ltd Sealed alkaline zinc primary battery
CN101167212A (en) * 2004-08-06 2008-04-23 吉莱特公司 Primary alkaline battery comprising bismuth metal oxide
CN2896537Y (en) * 2006-05-24 2007-05-02 张纪贵 Magnesium manganese cardboard primary battery
CN203553281U (en) * 2013-11-01 2014-04-16 江门金刚电源制品有限公司 Alkaline battery capable of prolonging release time of electrolyte
CN203826477U (en) * 2014-05-07 2014-09-10 张纪贵 Magnesium storage primary battery

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C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20140723