CN103911900B - Soybean protein and filler turning property toughener are with the use of the method improving offset paper ash content - Google Patents
Soybean protein and filler turning property toughener are with the use of the method improving offset paper ash content Download PDFInfo
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- CN103911900B CN103911900B CN201410107401.7A CN201410107401A CN103911900B CN 103911900 B CN103911900 B CN 103911900B CN 201410107401 A CN201410107401 A CN 201410107401A CN 103911900 B CN103911900 B CN 103911900B
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- 108010073771 Soybean Proteins Proteins 0.000 title claims abstract description 21
- 235000019710 soybean protein Nutrition 0.000 title claims abstract description 21
- 239000000945 filler Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000012745 toughening agent Substances 0.000 title claims 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 18
- 229920001131 Pulp (paper) Polymers 0.000 claims abstract description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 9
- 239000002002 slurry Substances 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920002472 Starch Polymers 0.000 claims description 6
- 125000002091 cationic group Chemical group 0.000 claims description 6
- 235000019698 starch Nutrition 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 239000012895 dilution Substances 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 229920001187 thermosetting polymer Polymers 0.000 claims description 2
- 235000010469 Glycine max Nutrition 0.000 claims 1
- 244000068988 Glycine max Species 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 238000004537 pulping Methods 0.000 claims 1
- 239000003623 enhancer Substances 0.000 abstract description 12
- 230000001965 increasing effect Effects 0.000 abstract description 11
- 238000006243 chemical reaction Methods 0.000 abstract description 10
- 239000000126 substance Substances 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000004061 bleaching Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000012460 protein solution Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
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Abstract
一种大豆蛋白和填料转性增强剂配合使用提高胶版纸灰分的方法,包括以下步骤:①、将大豆蛋白缓慢加入到50-70℃的水中,充分搅拌20-40min,配成百分比浓度为1%的溶液;②、将①中配得的百分比浓度为1%的大豆蛋白按1-4kg/t浆的用量加入到漂白化学机械浆碎浆机中;③、将②中加入大豆蛋白的漂白化学机械浆按质量分数20%的比例加入到配浆池中;④、将填料转性增强剂按1-4kg/t浆的用量加入到稀释后的研磨碳酸钙中,充分混合;⑤、将④所得经填料转性增强剂改性后的研磨碳酸钙加入到③所得浆料中。本发明提出的大豆蛋白和填料转性增强剂配合使用提高胶版纸灰分的生产工艺与其它方法相比,具有系纸张灰分高、纸张厚度大、纸张挺度、表面强度大等优点。
A method for increasing the ash content of offset paper through the combined use of soybean protein and filler conversion enhancer, comprising the following steps: ①. Slowly add soybean protein into water at 50-70°C, stir thoroughly for 20-40min, and prepare a percentage concentration of 1 % solution; ②, add the soybean protein with a concentration of 1% obtained in ① into the bleached chemical mechanical pulp pulper according to the amount of 1-4kg/t pulp; ③, add soybean protein in ② to the bleaching The chemical mechanical pulp is added to the pulp mixing tank in a proportion of 20% by mass fraction; ④, the filler conversion enhancer is added to the diluted ground calcium carbonate according to the amount of 1-4kg/t pulp, and fully mixed; ⑤, the ④ The obtained ground calcium carbonate modified by the filler-transforming enhancer is added to the slurry obtained in ③. Compared with other methods, the production process of increasing the ash content of offset paper through the combined use of soybean protein and filler conversion enhancer has the advantages of high paper ash content, large paper thickness, paper stiffness, and high surface strength.
Description
技术领域 technical field
本发明涉及造纸技术领域,具体来说是一种大豆蛋白和填料转性增强剂配合使用提高胶版纸灰分的方法。 The invention relates to the technical field of papermaking, in particular to a method for increasing the ash content of offset paper through the combined use of soybean protein and a filler conversion enhancer.
背景技术 Background technique
目前,提高胶版纸灰分的通用方法是阳离子淀粉和干强剂配合使用,由于在提高灰分的情况下,阳离子淀粉和干强剂仅能保证纸张的抗张强度、撕裂强度不变,若灰分提高较大,纸张厚度、表面强度、挺度都会下降,造成纸张质量降低。 At present, the general method to increase the ash content of offset paper is to use cationic starch and dry strength agent in combination. Because in the case of increasing ash content, cationic starch and dry strength agent can only ensure the tensile strength and tear strength of the paper remain unchanged. If the ash content If the increase is large, the thickness, surface strength, and stiffness of the paper will all decrease, resulting in a decrease in the quality of the paper.
发明内容 Contents of the invention
为解决现有工艺灰分提高幅度较低、纸张厚度、表面强度、挺度等下降的缺点,本发明提出了一种大豆蛋白和填料转性增强剂配合使用提高胶版纸灰分的生产工艺。 In order to solve the disadvantages of the existing process, such as low increase in ash content and decrease in paper thickness, surface strength, stiffness, etc., the present invention proposes a production process for increasing the ash content of offset paper through the combined use of soybean protein and filler conversion enhancer.
本发明的技术方案包括以下步骤: Technical scheme of the present invention comprises the following steps:
①、将大豆蛋白粉末缓慢加入到50-70℃的水中,充分搅拌均匀配成质量百分比浓度为1%的溶液; ①. Slowly add soybean protein powder into water at 50-70°C, stir well and evenly to form a solution with a concentration of 1% by mass;
②、将①中配得的百分比浓度为1%的大豆蛋白溶液按1-4kg/t浆的用量加入到漂白化学机械浆碎浆机中; ②. Add the soybean protein solution prepared in ① with a concentration of 1% into the bleached chemical mechanical pulp pulper according to the amount of 1-4kg/t pulp;
③、将②中加入大豆蛋白的漂白化学机械浆按质量分数20%的比例加入到配浆池中,即浆料配比(NBKP+LBKP):BCTMP=80:20; ③. Add the bleached chemical mechanical pulp with soybean protein added in ② to the pulp mixing tank at a mass fraction of 20%, that is, the pulp ratio (NBKP+LBKP):BCTMP=80:20;
④、将填料转性增强剂按1-4kg/t浆的用量加入到稀释后质量浓度为10%-20%的研磨碳酸钙中,充分混合; ④. Add the filler conversion enhancer to the ground calcium carbonate with a mass concentration of 10%-20% after dilution according to the amount of 1-4kg/t slurry, and mix thoroughly;
⑤、将④所得经填料转性增强剂改性后的研磨碳酸钙按100-200kg/t浆的用量加入到③所得浆料中,混合均匀后进入纸机。 ⑤. Add the ground calcium carbonate obtained in ④ to the slurry obtained in ③ according to the amount of 100-200kg/t slurry, mix well and enter the paper machine.
上述方案进一步优选为: The above scheme is further preferably:
所述的填料转性增强剂为阳离子热固性树脂、阳离子高聚物或改性聚合物硅溶液。 The filler transfer enhancer is cationic thermosetting resin, cationic high polymer or modified polymer silicon solution.
本发明提出的大豆蛋白和填料转性增强剂配合使用提高胶版纸灰分的生产工艺与其它方法相比,具有系纸张灰分高、纸张厚度大、纸张挺度、表面强度大等优点。大豆蛋白和填料转性增强剂配合在胶版纸使用,成纸灰分提高3-4个百分点、漂白化学热磨机械浆配比提高3-5个百分点,纸张厚度不变、挺度提高20%、表面强度提高10%。 Compared with other methods, the production process of increasing the ash content of offset paper through the combined use of soybean protein and filler conversion enhancer has the advantages of high paper ash content, large paper thickness, paper stiffness, and high surface strength. Soybean protein and filler conversion enhancer are used together in offset paper, the ash content of the paper is increased by 3-4 percentage points, the ratio of bleached chemical thermomechanical pulp is increased by 3-5 percentage points, the thickness of the paper is unchanged, and the stiffness is increased by 20%. Surface strength increased by 10%.
附图说明 Description of drawings
图1是本发明中的生产工艺流程框图。 Fig. 1 is a production process block diagram among the present invention.
具体实施方式 detailed description
参照图1,一种大豆蛋白和填料转性增强剂配合使用提高胶版纸灰分的方法,包括以下步骤:包括以下步骤: With reference to Fig. 1, a kind of soybean protein and the method for improving the ash content of offset paper by cooperating use of filler transfer enhancing agent comprise the following steps: comprising the following steps:
①、将大豆蛋白粉末缓慢加入到50-70℃的水中,充分搅拌(转速300转/min搅拌20-40min)均匀配成质量百分比浓度为1%的溶液; ①. Slowly add soybean protein powder into water at 50-70°C, fully stir (rotate at 300 rpm and stir for 20-40min), and evenly prepare a solution with a concentration of 1% by mass;
②、将①中配得的百分比浓度为1%的大豆蛋白溶液按1-4kg/t浆的用量加入到漂白化学机械浆碎浆机中; ②. Add the soybean protein solution prepared in ① with a concentration of 1% into the bleached chemical mechanical pulp pulper according to the amount of 1-4kg/t pulp;
③、将②中加入大豆蛋白的漂白化学机械浆按质量分数20%的比例加入到配浆池中,即浆料配比(NBKP+LBKP):BCTMP=80:20; ③. Add the bleached chemical mechanical pulp with soybean protein added in ② to the pulp mixing tank at a mass fraction of 20%, that is, the pulp ratio (NBKP+LBKP):BCTMP=80:20;
④、将填料转性增强剂按1-4kg/t浆的用量加入到稀释后质量浓度为10%-20%的研磨碳酸钙中,充分混合; ④. Add the filler conversion enhancer to the ground calcium carbonate with a mass concentration of 10%-20% after dilution according to the amount of 1-4kg/t slurry, and mix thoroughly;
⑤、将④所得经填料转性增强剂改性后的研磨碳酸钙按100-200kg/t浆的用量加入到③所得浆料中,混合均匀后进入纸机。 ⑤. Add the ground calcium carbonate obtained in ④ to the slurry obtained in ③ according to the amount of 100-200kg/t slurry, mix well and enter the paper machine.
我公司9#机文化纸生产线应用该工艺,将大豆蛋白溶液按照0.8-1.2kg/t浆的用量加入BCT浆碎浆机,填料转性增强剂2-3kg/t加入到研磨碳酸钙上料管,全部物料混合混合均与后进入纸机进行后续操作,所生产的胶版纸与现有工艺得到的胶版纸相比(现有工艺即阳离子淀粉和干强剂配合使用提高灰分的方法),灰分提高3%-5%,成纸厚度不变、挺度提高20%、表面强度提高10%。BCT浆配比提高3-5%,吨纸综合成本降低8.5元。 Our company's 9# machine cultural paper production line applies this process, adding soybean protein solution to the BCT pulp pulper according to the amount of 0.8-1.2kg/t pulp, and adding 2-3kg/t filler conversion enhancer to the ground calcium carbonate feeding material tube, all materials are mixed and mixed and then enter the paper machine for subsequent operations. Compared with the offset paper obtained by the existing process (the existing process is the method of using cationic starch and dry strength agent together to increase the ash content), the offset paper produced is The ash content increases by 3%-5%, the paper thickness remains unchanged, the stiffness increases by 20%, and the surface strength increases by 10%. The ratio of BCT pulp is increased by 3-5%, and the comprehensive cost per ton of paper is reduced by 8.5 yuan.
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| CN201410107401.7A CN103911900B (en) | 2014-03-21 | 2014-03-21 | Soybean protein and filler turning property toughener are with the use of the method improving offset paper ash content |
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| CN201410107401.7A CN103911900B (en) | 2014-03-21 | 2014-03-21 | Soybean protein and filler turning property toughener are with the use of the method improving offset paper ash content |
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| RU2717509C1 (en) * | 2015-09-03 | 2020-03-23 | Соленис Текнолоджиз, Л.П. | Method of producing lignocellulose paper and paper products |
| WO2017054198A1 (en) | 2015-09-30 | 2017-04-06 | Ecolab Usa Inc. | Compositions and methods for treating filler in papermaking |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1419621A (en) * | 2000-03-23 | 2003-05-21 | 赫尔克里士公司 | Pitch and stickies control in pulp and papermaking processes |
| CN102154927A (en) * | 2011-03-16 | 2011-08-17 | 亚太纸业(广东)有限公司 | Side offset paper and preparation method thereof |
| CN102493258A (en) * | 2011-11-30 | 2012-06-13 | 沅江纸业有限责任公司 | Woodfree writing paper and production method thereof |
| CN102677543A (en) * | 2012-06-11 | 2012-09-19 | 岳阳林纸股份有限公司 | Method for fill feeding in papermaking |
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| JP2887205B2 (en) * | 1988-05-31 | 1999-04-26 | 王子製紙株式会社 | Coated paper for printing |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1419621A (en) * | 2000-03-23 | 2003-05-21 | 赫尔克里士公司 | Pitch and stickies control in pulp and papermaking processes |
| CN102154927A (en) * | 2011-03-16 | 2011-08-17 | 亚太纸业(广东)有限公司 | Side offset paper and preparation method thereof |
| CN102493258A (en) * | 2011-11-30 | 2012-06-13 | 沅江纸业有限责任公司 | Woodfree writing paper and production method thereof |
| CN102677543A (en) * | 2012-06-11 | 2012-09-19 | 岳阳林纸股份有限公司 | Method for fill feeding in papermaking |
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