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CN1038344C - High-efficiency steriliging washing powder - Google Patents

High-efficiency steriliging washing powder Download PDF

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Publication number
CN1038344C
CN1038344C CN93110679A CN93110679A CN1038344C CN 1038344 C CN1038344 C CN 1038344C CN 93110679 A CN93110679 A CN 93110679A CN 93110679 A CN93110679 A CN 93110679A CN 1038344 C CN1038344 C CN 1038344C
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China
Prior art keywords
washing powder
washing
powder
present
sterilization
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Expired - Fee Related
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CN93110679A
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Chinese (zh)
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CN1094442A (en
Inventor
娄熙南
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LOU XI'NAN
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LOU XI'NAN
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Priority to CN93110679A priority Critical patent/CN1038344C/en
Publication of CN1094442A publication Critical patent/CN1094442A/en
Application granted granted Critical
Publication of CN1038344C publication Critical patent/CN1038344C/en
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Abstract

The present invention relates to high efficient sterilization washing powder which comprises an anionic surface active agent, a nonionic surface active agent, and washing powder parent powder using an inorganic auxiliary agent and an organic auxiliary agent as basal bodies. The present invention is characterized in that the present invention contains 15% to 30% of trisodium chlorophosphate and 0.2% to 0.5% of perfume by a weight ratio, and prepared washing powder contains 0.4% to 1% of effective chlorine. The present invention has double functions of high efficient sterilization and soil removal by washing, and has no damage to a fabric or a human body, and is especially suitable for use in a washing machine.

Description

High-efficiency steriliging washing powder
The present invention relates to a kind of high-efficiency steriliging washing powder, particularly relate to a kind of washing powder that is called the sterilization king again.
Washing powder commonly used is by a kind of or several tensio-active agents, and allocates that inorganic assistant agent and organic additive preparation process into.This class washing powder is used for the accompanying dirt of washing clothes and has clean dirt-removing functions, and does not have the function of disinfection.Modern society, washing machine has stepped into huge numbers of families, and it has been general present situation that one family uses a washing machine.In one family, old children irrespective of sex, the whole family's clothing is all washed in a washing machine drum, dark moist washing tub, in fact just become the substratum of bacterium, and washing machine mostly is plastics or comes sealed against leakage with rubber item, apparent, any washing machine all should not be sterilized with high temperature, can not be with strong the using as making cleaning clothes with the liquid state disinfectant that cleans dwelling house, kitchen in washing machine of concentration height, corrodibility.Therefore the washing powder of studying a kind of high-efficiency steriliging becomes important topic.In recent years, disinfectant detergent powder has appearred, but it is very high to contain effective cl content in the washing powder, for example with in the washing powder as sterilization host such as Surchlor GR 60, the available chlorine content of its sterilization host is up to 45-62%, and its flavour of a drug of this disinfectant detergent powder are strong, big to the clothing infringement, it is serious to fade, and human body skin is also had certain stimulation, and the cost height.
The purpose of this invention is to provide a kind of specializing in uses in the washing machine, have rapidly and efficiently sterilization and washing decontamination dual-use function, and harmless to fabric and human body, the available chlorine content of sterilization host is only in 3-5%, easy to use, stable serial washing powder in the storage.
To achieve these goals, solution of the present invention is: be in the washing powder of matrix by anion surfactant and nonionogenic tenside and inorganic assistant agent and organic additive, add the Efficacious Disinfeitant of 15-30% (weight ratio), as sterilization host.In order to improve the smell of washing powder product, add the spices of 0.2-0.5% (weight ratio) again, described spices mainly is vanillin food grade,1000.000000ine mesh (having another name called geranial), or vanirone.Available chlorine content only is 0.4-1% (weight ratio) in Pei Zhi the laundry material like this, the sterilising effect of host and sterilization effect obviously is better than sterilizing merely.
The present invention proposes five kinds of specific high-effective disinfecting washing powder prescriptions, and their common trait all contains the spices of sterilization host 15-30% Efficacious Disinfeitant and 0.2-0.5%.Now be described below respectively:
Prescription 1 is: (weight ratio)
Sodium alkyl benzene sulfonate 20-30%
Fatty alcohol-polyoxyethylene ether 5-10%
Soap 5-10%
Carboxymethyl cellulose (CMC) 2-3%
Tripoly phosphate sodium STPP 10-25%
Water glass 5-10%
Sodium sulfate 30-40%
White dyes 0.2-0.3%
Efficacious Disinfeitant 15-30%
Vanillin food grade,1000.000000ine mesh 0.2-0.5%
Prescription 2 is: (weight ratio)
Sodium alkyl benzene sulfonate 15-20%
Fatty alcohol-polyoxyethylene ether 5-10%
Alkylphenol polyoxyethylene 3-6%
Ether alcohol sulfate 2-3
Polyethers 3-5%
Soap 4-6%
Carboxymethyl cellulose (CMC) 2-3%
Yellow soda ash 5-10%
Tripoly phosphate sodium STPP 30-40%
Water glass 6-10%
Sodium sulfate 25-30%
White dyes 0.2-0.3%
Paratoluenesulfonic acid sodium salt 3-5%
Efficacious Disinfeitant 15-30%
Vanillin food grade,1000.000000ine mesh 0.2-0.5%
Prescription 3 is: (weight ratio)
Sodium alkyl sulfate 10-25%
Fatty alcohol-polyoxyethylene ether 3-5%
Alkylphenol polyoxyethylene 4-10%
Polyethers 3-5%
Dimethyl silicone oil 2-3%
Soap 3-5%
Carboxymethyl cellulose (CMC) 2-3%
Yellow soda ash 5-10%
Tripoly phosphate sodium STPP 30-45%
Water glass 6-10%
Sodium sulfate 25-40%
White dyes 0.2-0.3%
Efficacious Disinfeitant 15-30%
Vanirone 0.2-0.5%
Prescription 4 is: (weight ratio)
Fatty alcohol-polyoxyethylene ether 6-10%
Alkylphenol polyoxyethylene 3-5%
Ether alcohol sulfate 2-5%
Polyethers 3-5%
Soap 3-5%
Carboxymethyl cellulose (CMC) 2-3%
Tripoly phosphate sodium STPP 30-40%
Water glass 10-15%
Sodium sulfate 35-40%
White dyes 0.2-0.3%
Paratoluenesulfonic acid sodium salt 3-5%
Efficacious Disinfeitant 15-30%
Vanillin food grade,1000.000000ine mesh 0.2-0.5%
Prescription 5 is: (weight ratio)
Hardened tallow Fatty acid methyl ester sodium sulfonate 30-35%
Sulphonated oleic acid disodium 15-20%
Zeolite 30-35%
Water glass 25-30%
Yellow soda ash 6-10%
Sodium bisulfite 4-6%
Borate glass 3-5%
Efficacious Disinfeitant 15-30%
Vanirone 0.2-0.5%
The method for making of the prescription 1,2,3,4 that the present invention proposes is: with the matrix material (except that as sterilization host Efficacious Disinfeitant and the spices) of washing powder, be made into slip by the prescription composition, in mixing machine, mix, discharging moves in the moisture eliminator, hot blast, discharging after 60-70 ℃ of warm air drying 18-24 hour are supplied with in the bottom from moisture eliminator.Cross 60 mesh sieves and make the female powder of granular laundry powder, then chloride compound Efficacious Disinfeitant and spices pulvis are mixed with the female powder of the washing powder of making, make the finished product, pack is sealed.
The method for making of the prescription 5 that the present invention proposes is: bead is made in the mixture grinding that the matrix material (except that for sterilization host Efficacious Disinfeitant and the spices) of washing powder is formed, pulverize, get 97 parts, zeolite with mean diameter 3um coats, making density is the female powder of washing powder of 0.6-0.8, then Efficacious Disinfeitant and spices pulvis and the female powder of washing powder are mixed, make the finished product, pack is sealed.
The washing powder that the present invention makes is through Hunan Hygienic ﹠ Epidemic Prevention Station's verification test, and its experiment the results are shown in following table:
1, to the killing effect of bacterial propagule: test strain activity effect different time (min) to kill sterilization rate (%) (individual/ML) (PPM) 5 10 15 30 intestinal bacteria 6.25 99.99 100.00 100.00 100.00
12.5 100.00 100.00 100.00 100.00 4.0 * 10 725 100.00 100.00 100.00 100.00 streptococcus aureuses 6.25 100.00 100.00 100.00 100.00
12.5 100.00 100.00 100.00 100.00 3.3×10 7 25 100.00 100.00 100.00 100.00
2, to the killing effect of bacterial spore and in the presence of 10% calf serum the influence to the Bacillus subtillis killing effect test:
To the killing effect test strain activity effect different time (min) of Bacillus subtillis to kill sterilization rate (%) and bacterial content (PPM) 5 10 15 30 (individual/ML) black 750 100.00 100.00 100.00 100.00 look mutation, 1,000 100.00 100.00 100.00 100.003.0 of Bacillus subtillis * 10 61,500 100.00 100.00 100.00 100.00
2,000 100.00 100.00 100.00 100.00 Bacillus subtillis, 750 100.00 100.00 100.00 100.00 ± 10% calf serum, 1,000 100.00 100.00 100.00 100.003.4 * 10 61,500 100.00 100.00 100.00 100.00
2,000 100.00 100.00 100.00 100.003, to the rupture test of hepatitis B surface antigen(HBsAg):
---enzyme linked immunosorbent assay sterilizing agent activity action time (min) and OD value (PPM) 10 15 30 60 1,000 0.24 0.21 0.19 0.21 1,500 0.18 0.14 0.12 0.09 2,000 0.17 0.09 0.08 0.07
2,500 0.05 0.07 0.06 0.04 positive serums, 2.36 negative serums, 0.10 result judges: sample OD value/negative average OD value 〉=2.1 are positive, otherwise negative.By above-mentioned detection: the present invention joins the washing powder of the phosphorus chloride trisodium that contains 25% (weight ratio), and its washing powder available chlorine content is 0.76%.Under 6.25PPM concentration, 10 minutes all can 100% kill intestinal bacteria and golden yellow bag staphylococcus, effective chlorine density 750PPM, 5 minutes 100% kill Bacillus subtillis; And under 10% calf serum protection, the killing effect of Bacillus subtillis there is not influence.
Rupture test to hepatitis B surface antigen(HBsAg): in the concentration of available chlorine 1000PPM, 15 minutes energy completely destroy hepatitis B surface antigen(HBsAgies.
" fabric infringement test " and " to the irritant test of skin " result that the present invention passes through to be done show that the washing powder of making according to the present invention is harmless to clothing, and is non-stimulated to skin.
Also show by test: simple to adopt sterilization host Efficacious Disinfeitant available chlorine content be 3.10%, under 6.25PPM concentration, 15 minutes can 100.00% kill streptococcus aureus, can kill intestinal bacteria in 30 minutes.At effective chlorine density 750PPM, 30 minutes ability 100.00% kill Bacillus subtillis, under the protection of 10% calf serum, 30 minutes ability 99.999% kill Bacillus subtillis.By last comparative illustration, available chlorine content is in the 0.4-1% scope in the washing powder that the present invention proposes, and not only have sterilization and washing decontamination dirt function, and sterilization effect obviously is better than simple sterilization effect with sterilization host.

Claims (1)

1, a kind of high-efficiency steriliging washing powder is characterized in that it contains the component of following weight ratio:
Hardened tallow Fatty acid methyl ester sodium sulfonate 30-50%
Sulphonated oleic acid disodium 15-20%
Zeolite 30-35%
Water glass 25-30%
Yellow soda ash 6-10%
Sodium bisulfite 4-6%
Borate glass 3-5%
Efficacious Disinfeitant 15-30%
Vanirone 0.2-0.5%.
CN93110679A 1993-04-24 1993-04-24 High-efficiency steriliging washing powder Expired - Fee Related CN1038344C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN93110679A CN1038344C (en) 1993-04-24 1993-04-24 High-efficiency steriliging washing powder

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN93110679A CN1038344C (en) 1993-04-24 1993-04-24 High-efficiency steriliging washing powder

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CN1094442A CN1094442A (en) 1994-11-02
CN1038344C true CN1038344C (en) 1998-05-13

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5780404A (en) * 1996-02-26 1998-07-14 The Procter & Gamble Company Detergent compositions containing enduring perfume
CN103184117A (en) * 2011-12-27 2013-07-03 施一飞 Method for preparing detergent by using drainage oil
CN102876523A (en) * 2012-09-27 2013-01-16 启东市华亚工业配套有限公司 Softening laundry powder
CN103740476A (en) * 2013-11-27 2014-04-23 任保林 Washing powder for washing machines
CN104479899A (en) * 2014-12-31 2015-04-01 威莱(广州)日用品有限公司 Super-concentration fabric cleaning agent formula and preparing method thereof
CN110499613B (en) * 2018-05-17 2022-03-25 无锡小天鹅电器有限公司 Control method and control system of clothes treatment device and clothes treatment device

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1065881A (en) * 1992-05-08 1992-11-04 四川川西磷化工集团公司 Concentrated sterilizing washing powder formula and process

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1065881A (en) * 1992-05-08 1992-11-04 四川川西磷化工集团公司 Concentrated sterilizing washing powder formula and process

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
《化工小商品生产法》第九卷 1991.10.1 韩长日,宋小平湖南科学技术出版社 *
《化工小商品生产法》第九卷 1991.10.1 韩长日,宋小平湖南科学技术出版社;《日用化工原料手册》 1991.12.1 中国轻工业出版社 *
《日用化工原料手册》 1991.12.1 中国轻工业出版社 *

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