CN1038231C - Selective capturing agent for bastnaesite-(La) ore - Google Patents
Selective capturing agent for bastnaesite-(La) ore Download PDFInfo
- Publication number
- CN1038231C CN1038231C CN 93112332 CN93112332A CN1038231C CN 1038231 C CN1038231 C CN 1038231C CN 93112332 CN93112332 CN 93112332 CN 93112332 A CN93112332 A CN 93112332A CN 1038231 C CN1038231 C CN 1038231C
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- China
- Prior art keywords
- collecting agent
- flotation
- existing
- rare
- present
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 238000005188 flotation Methods 0.000 claims abstract description 16
- 239000002253 acid Substances 0.000 claims abstract description 15
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 7
- 240000000203 Salix gracilistyla Species 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 6
- 159000000013 aluminium salts Chemical class 0.000 claims description 6
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims description 6
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 6
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 6
- 238000007127 saponification reaction Methods 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims 3
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 13
- 150000002910 rare earth metals Chemical class 0.000 abstract description 13
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 abstract description 5
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000011707 mineral Substances 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 2
- 229960001047 methyl salicylate Drugs 0.000 abstract description 2
- 238000006146 oximation reaction Methods 0.000 abstract description 2
- 230000020477 pH reduction Effects 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000012141 concentrate Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- -1 diamines acids Chemical class 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- NEAQRZUHTPSBBM-UHFFFAOYSA-N 2-hydroxy-3,3-dimethyl-7-nitro-4h-isoquinolin-1-one Chemical compound C1=C([N+]([O-])=O)C=C2C(=O)N(O)C(C)(C)CC2=C1 NEAQRZUHTPSBBM-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Natural products OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 229960002969 oleic acid Drugs 0.000 description 2
- 235000021313 oleic acid Nutrition 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 229960004889 salicylic acid Drugs 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- VDEUYMSGMPQMIK-UHFFFAOYSA-N benzhydroxamic acid Chemical compound ONC(=O)C1=CC=CC=C1 VDEUYMSGMPQMIK-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000021050 feed intake Nutrition 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- JRZGPWOEHDOVMC-UHFFFAOYSA-N n-hydroxynaphthalene-1-carboxamide Chemical compound C1=CC=C2C(C(=O)NO)=CC=CC2=C1 JRZGPWOEHDOVMC-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The present invention discloses a selective collecting agent for the flotation of bastnaesite, which is a high-efficiency collecting agent for rare-earth minerals. Methyl salicylate reacts with hydroxylamine in a strong basic medium to prepare the high-efficiency collecting agent for rare-earth minerals by the processes of oximation, acidification and sponification. Compared with the existing fat collecting agent, the existing alkane sulfonic salt, the existing phosphoric acid collecting agent, the existing hydroximic acid collecting agent of H205, etc., the present invention has the advantages of good water solubility, stable production and technical indication, good selectivity, high rare earth flotation grade and recovery rate, etc.
Description
The present invention is a kind of selective copper collector of flotation bastnasite, belongs to the flotation of material field.
At present, the collecting agent of FLOTATION SEPARATION bastnasite Rare Earth Mine roughly has three classes: one, fatty acid collecting agent.As Japanese professor Xiang Jingzi with enuatrol with No. 300 medicines, tallow diamines acids flotation rare earth under acid medium and 50-90 ℃ of condition; U.S. molybdenum company produces f_c_ce_la concentrate with lignin ammonium carbonate, waterglass and N-80 oleic acid under 90-100 ℃ of condition.Two, alkane sulphur salt, phosphoric acid class collecting agent.This type of is not used for producing as yet.Three, hydroximic acid collecting agent.Begin (C the sixties as the former Soviet Union with HM-50
7-9Hydroximic acid) flotation rare earth; The eighties, China has successively developed cycloalkanes hydroximic acid 802, H
205(2 hydroxyls-3 naphthalene hydroximic acid), benzene hydroximic acid etc. are as effective collecting agent of flotation Rare Earth Mine.Disclosed hydroxamic acid type collecting agent in " development of hydroxamic acid type collecting agent and the test of flotation rare-earth mineral " delivered as, 1985 the 3rd phases of " rare earth " magazine; Packet header Institute of Metallurgical Technology the 1st phase of nineteen eighty-three also once disclosed " novel rare-earth collecting agent-802 " for another example.In this three classes collecting agent, the oleic-acid separating effect is poor, and alkane sulphur salt, phosphoric acid class collecting agent are not used for producing; The hydroximic acid selectivity is good, and technical indicator height, but also exist on the high sidely be the more important thing is poorly water-soluble, and easy blocking pipe is to making the production and technical indication instability.
The objective of the invention is to: propose that a kind of selectivity is good, soluble in water, technical indicator is high, be convenient to the selective copper collector of the flotation bastnasite operating and manage.
Technical characterictic of the present invention is: collecting agent by structural formula is
Bigcatkin willow hydroxy acid amine and sodium metasilicate and aluminium salt combine.It is characterized in that salicylic acid hydroxyl hydroxamamide: sodium metasilicate: aluminium salt=1.3: 1.5: 0.5 (weight), and be mixed with the aqueous solution of 2-5%,
Salicylic acid hydroxyl hydroxamamide be by gaultherolin in strongly basic medium with azanol reaction, through oximate, acidifying, saponification and to make its reaction as follows:
Reaction condition is:
The oximate acidifying saponification temperature ℃ 25-35 40-50 30-40 reaction time: hour 8-10 4-6 4-5 ph value of reaction 12-13 2-3 8-9
Application process of the present invention is as follows:
With rare earth, grinde ore, size mixing, add PH and adjust agent, add inhibitor, add collecting agent of the present invention then, through flotation, separation, get rare earth ore concentrate (bastnasite), surplus mine tailing (Fe, Si, S, Ca, Ba, Al etc.), collecting agent wherein of the present invention adds and sodium metasilicate, and the proportioning of aluminium salt is 1.3: 1.5: 0.5. (weight)
Flotation temperature: 35-45 ℃
PH value: 7.5-8.5
Flotation time: 16-20 minute
Compare prior art, the present invention has the following advantages:
1. manufacturing process is simple, and is nontoxic, tasteless, and the three wastes are few,
2. good water solubility, selectivity is good, does not need during ore dressing to use under strong basicity and high temperature (90-100 ℃) or acid condition, helps operation and management,
3. adopt collecting agent of the present invention, the grade and the rate of recovery of flotation rare earth obviously improve
4. low-consuming only is 1/2 of at present existing collector dosage,
Below in conjunction with embodiment, the invention will be further described: feed intake by following proportioning preparation:
112 kilograms in caustic soda
15 kilograms of azanols
25 kilograms of methyl salicylates
38 kilograms of hydrochloric acid
20 kilograms of ammoniacal liquor
At first, with methyl salicylate, caustic soda and azanol carried out oximation reaction 8 hours under 30 ℃, and reaction pressure is a normal pressure; And then adding hydrochloric acid 45 ℃ of following acidification reactions 4 hours, pressure is normal pressure; Add ammoniacal liquor again and carry out saponification, 35 ℃ of temperature make bigcatkin willow hydroximic acid ammonium after about 4 hours, and again with bigcatkin willow hydroximic acid ammonium and sodium metasilicate, aluminium salt is mixed with the aqueous solution of 2-5% with 1.3: 1.5: 0.5 ratio, makes this collecting agent,
During use, by one ton of former mining collecting agent 1.0-1.2 kilogram of every processing, and assistant medicament (as adjusting agent, inhibitor and foaming agent) the total consumption of floating agent that adds the 1.0-1.5 kilogram is the 2.0-2.7 kg/ton, during use this collecting agent is added in the good ore pulp of mill successively, at 35 ℃ of following PH is 7.5-8.5, with mechanical agitation type flotation 16-20 minute, through one roughing, 2-4 selected acquisition high-quality f_c_ce_la concentrate.
α % is that head grade β % is a concentrate grade ε % concentrate rate of recovery subordinate list
| The present invention | α％ | 3.62 | 4.52 | 5.47 | 6.06 | 9.52 | 10.39 |
| β％ | 38.65 | 47.02 | 50.80 | 49.55 | 54.86 | 54.65 | |
| ε％ | 85.95 | 73.72 | 82.00 | 83.40 | 86.80 | 88.21 | |
| Prior art H2O5 | α％ | 3.82 | 4.45 | 5.45 | 6.24 | 9.47 | 10.36 |
| β％ | 24.37 | 34.67 | 44.95 | 43.97 | 52.72 | 50.32 | |
| ε％ | 79.61 | 80.52 | 81.24 | 80.89 | 71.57 | 82.88 |
Claims (3)
1. the selective copper collector of a flotation bastnasite comprises the sodium metasilicate of effective dose, and aluminium salt is characterized in that also comprising the bigcatkin willow hydroximic acid amine of effective dose, and its structural formula is as follows:
2. according to the collecting agent of claim 1, it is characterized in that bigcatkin willow hydroximic acid amine: sodium metasilicate: the ratio of aluminium salt is 1.3: 1.5: 0.5 (weight).
3. according to the collecting agent of claim 1, it is characterized in that described bigcatkin willow hydroximic acid amine is made through oximate, acidifying and saponification by gaultherolin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93112332 CN1038231C (en) | 1993-01-30 | 1993-01-30 | Selective capturing agent for bastnaesite-(La) ore |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93112332 CN1038231C (en) | 1993-01-30 | 1993-01-30 | Selective capturing agent for bastnaesite-(La) ore |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1090226A CN1090226A (en) | 1994-08-03 |
| CN1038231C true CN1038231C (en) | 1998-05-06 |
Family
ID=4989952
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93112332 Expired - Fee Related CN1038231C (en) | 1993-01-30 | 1993-01-30 | Selective capturing agent for bastnaesite-(La) ore |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1038231C (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104148189B (en) * | 2014-08-08 | 2016-08-17 | 西北矿冶研究院 | Rare earth mineral collecting agent |
| CN104607320A (en) * | 2014-11-19 | 2015-05-13 | 四川省地质矿产勘查开发局成都综合岩矿测试中心 | Efficient flotation collector for rare earth ore |
| CN106040436B (en) * | 2016-05-27 | 2019-01-04 | 中国地质科学院矿产综合利用研究所 | Low-temperature-resistant rare earth ore flotation collector, preparation method and application thereof |
| CN110449257B (en) * | 2019-07-31 | 2021-12-07 | 中国恩菲工程技术有限公司 | Beneficiation method of bastnaesite |
| CN111298980B (en) * | 2020-02-29 | 2022-04-01 | 武汉理工大学 | Preparation method of mixed long-carbon-chain hydroxamic acid collecting agent |
-
1993
- 1993-01-30 CN CN 93112332 patent/CN1038231C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1090226A (en) | 1994-08-03 |
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