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CN103814926A - Herbicide composition containing flazasulfuron and use of herbicide composition - Google Patents

Herbicide composition containing flazasulfuron and use of herbicide composition Download PDF

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CN103814926A
CN103814926A CN201410101849.8A CN201410101849A CN103814926A CN 103814926 A CN103814926 A CN 103814926A CN 201410101849 A CN201410101849 A CN 201410101849A CN 103814926 A CN103814926 A CN 103814926A
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flazasulfuron
herbicidal composition
active component
herbicide composition
composition
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CN103814926B (en
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吴元林
王中德
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Zhejiang Jilun plant science and Technology Co.,Ltd.
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ZHEJIANG LEJI CHEMICAL CO Ltd
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Abstract

The invention discloses a herbicide composition containing flazasulfuron and use of the herbicide composition. The herbicide composition comprises the following components by weight percent: 1-30% of an active component A, 1-30% of an active component B, 1-5% of a dispersant, 1-5% of a wetting agent, 1-5% of an adhesive and the balance being filler or deionized water, wherein the active component A is flazasulfuron. The herbicide composition containing the flazasulfuron disclosed by the invention can be applied to effective prevention and removal of annual grasses and broad leaf weeds of direct-seeding rice fields and seedling slinging fields, such as barnyard grass, leptochloa chinensis, crab grass, paspalum distichum, false loosestrife, sheathed monochoria herbs, pondweeds and the like, so as to play a synergistic effect. The herbicide composition has a good weeding effect, not only is the control effect improved by use in a form of a composition, but also the use cost is reduced, and the utilization rate of effective ingredients is improved.

Description

A kind of herbicidal composition that contains flazasulfuron and uses thereof
Technical field
The present invention relates to pesticide herbicide technical field, be specifically related to a kind of herbicidal composition that contains flazasulfuron and uses thereof.
Background technology
Paddy rice is one of important in the world cereal crops, one of the most important grain of Ye Shi China source.The key factor of hazard rice output has a lot, except damage by disease and insect factor, weeds are also a kind of key factors, weeds are non-target cultivated plant in farmland, and main harm is, weeds can fight for water, fertilizer, illumination and space with crops, also be the vector of diseases and pests of agronomic crop simultaneously, China's paddy rice crop smothering area is high, so will make improving yield of wheat, must prevent and treat weeds.
In recent years, reasonable selection rice herbicide has become the important technical links of guaranteeing that rice safety is produced, but because drug of choice is improper or operation technique is not in place, can make control efficiency undesirable or cause the phenomenons such as key.The weed killer herbicide kind that can simultaneously prevent and kill off at present grassy weed and broadleaved herb weeds is little, and people use certain weed killer herbicide to prevent and kill off after grassy weed under normal circumstances, and broad leaved weed becomes again the dominant population of weeds; Or, to remove after broad leaved weed, grassy weed becomes again the dominant population of weeds, and the unable herbicidal effect of waste of manpower is poor.
Summary of the invention
First object of the present invention is: for the deficiencies in the prior art, the invention provides the herbicidal composition that contains flazasulfuron that a kind of herbicidal effect is good; Second object of the present invention is: the purposes that the invention provides a kind of herbicidal composition that contains flazasulfuron.
A herbicidal composition that contains flazasulfuron, is characterized in that comprising following component, described component by weight percentage:
Figure BDA0000478904670000011
Figure BDA0000478904670000021
Wherein, described active component A is flazasulfuron.
Flazasulfuron is a kind of interior absorption translocated herbicide, can suppress the reaction of the predecessor acetolactate synthestase that produces side chain amino acid, leucine, isoleucine and valine, flazasulfuron can be weeds cauline leaf and root absorption, in plant corpus, conduct subsequently, by suppressing the biosynthesis of side chain amino acid in plant corpus, and cause sensitive plant growth retardation, cauline leaf chlorisis, withered gradually, generally newborn blade chlorisis in 4-5 days, then expand to whole plant, within 20-30 days, weeds are thoroughly dead.Flazasulfuron is safe and harmless simultaneously, can prestige not be detrimental to health.
As preferably, as preferably, described active component B is any one in the third careless amine, butachlor, cyhalofop-butyl, dichloro quinolinic acid, oxadiazon.
The third careless amine is the paddy field herbicides special with high selectivity, to rice safety, broad weed-killing spectrum, is applicable to paddy rice and prevents and kill off 1 year raw grass family such as barnyard grass, bare headed barnyard grass, moleplant seed, eleusine indica, needle spikesedge herb, alisma canaliculatum, water three-coloured amaranth, difformed galingale herb, cyperus iria, false loosestrife, Monochoria vaginalis and broad leaved weed.Be mainly used in preventing and kill off grassy weed.The third careless amine is cell division inhibitor, can prevent and kill off barnyard grass in paddy field, difformed galingale herb, needle spikesedge herb, Monochoria vaginalis, alisma canaliculatum etc. for soil treatment.
Butachlor is in amide-type selectivity, to inhale conduction weed killer herbicide, in soil, can be degraded.To people and animals' low toxicity.The butachlor mainly young shoot by weeds absorbs, and then conducts complete stool and works.Plant absorbs after butachlor, suppresses in vivo and destroys protease, affects the formation of protein, suppresses weeds young shoot and young root normal growth and grows, thereby make weeds death.On clay loam and the higher soil of the content of organic matter, use, medicament can be absorbed by soil colloid, is difficult for being leached, and the special efficacy phase is long.
Cyhalofop-butyl belongs to aryloxy group phenoxy propionic acid class weed killer herbicide, mainly prevent and kill off barnyard grass, cyhalofop-butyl is only kind paddy rice to tight security in fragrant phenoxy phenoxy propionic acid weed killer herbicide, the same with such other kinds, also be interior suction conductivity weed killer herbicide, blade and leaf sheath by plant corpus absorb, phloem conduction, accumulate the meristem zone in plant corpus, resist acetyl-CoA carboxylase, fatty acid is synthesized and stop, the growth division of cell can not normally be carried out, film systems etc., containing fat structural deterioration, finally cause plant death.While acting on paddy rice, paddy rice etc. is had to good selectivity, the accretion rate of selectivity based on different, in paddy rice body, cyhalofop-butyl can be degraded to rapidly the diacid state to acetyl-CoA carboxylase non-activity, thereby paddy rice is had to the safety of height.Because it degrades rapidly in soil and in typical paddy field water either, therefore to succession crop safety.
Residual main by the degraded of photodissociation and Soil Microorganism in soil of dichloro quinolinic acid.Belong to hormone-type quinoline carboxylic acid weed killer herbicide, weeds poisoning symptom is similar to auxins effect, is mainly used in preventing and treating barnyard grass and working life very long,
Oxadiazon is used for preventing and kill off multiple annual unifacial leaf and broadleaf weed, is mainly used in paddy field weed-killer, and peanut to dry land, cotton, sugarcane etc. are also effective; Before tagging property bud, post-emergence herbicide.Do soil treatment, the use of floods and droughts field.Mainly absorb and work by weeds young shoot and cauline leaf, under the condition that has light, can bring into play good removing activity.To particularly sensitivity of budding period weeds, when weeds one germinate, the growth of bud scale is just suppressed, and its tissue rots rapidly, weeds death.
As preferably, the percentage by weight that described active component B is is 8-13%.Adopt after above-mentioned preferred version the active better effects if of active component B.
As preferably, the percentage by weight that described active component A is is 18-23%.Adopt after above-mentioned preferred version the active better effects if of active component A.
As preferably, described dispersant is one or more the mixture in dispersing agent MF, alkyl naphthalene formaldehyde condensate sulfonates, polycarboxylate, calcium lignosulfonate, sodium lignin sulfonate.Adopt after above-mentioned preferred version, free particle is mutually free mutually to make particle, can improve the efficiency of grinding distribution, is conducive to improve the stability of product quality.
As preferably, described wetting agent is any one or more the mixture in lauryl sodium sulfate, neopelex, alkylnaphthalene sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy base ether phosphate, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, alkylphenol polyoxyethylene formaldehyde condensation products succinate sodium sulfonate.Adopt after above-mentioned preferred version, can make material water insoluble or that be not soaked in water for water-moistened solid pesticide.Main Function is surface tension or the interfacial tension that reduces water, and solid surface energy is soaked by water.Can make water-fast agricultural chemicals, after being watered, be made into suspension and use, and can make liquid moistening and expansion on crop, polypide and germ body surface, thereby improve control efficiency, reduce the generation of poisoning.Conventional wetting agent is as withered in tea, washing powder, pull open powder.
As preferably, described adhesive is any one or more the mixture in alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate and polyvinyl alcohol.Adopt after above-mentioned preferred version, the mixed effect between association of soil agent is better.
As preferably, described filler is one or more mixtures in clay, potter's clay, kaolin, diatomite, pyrophyllite.Adopt after above-mentioned preferred version, can make the processing soil treatment agent making there is viscosity, processing soil treatment agent can be made into not homophase.
As preferably, described composition is suspending agent, wetting powder, water dispersible granules.Adopt after above-mentioned preferred version, can, for the soil condition of different conditions, can mix with soil better.
In order to realize above-mentioned second object, the present invention has adopted following technical scheme:
A purposes for the processing soil treatment agent composition of containing fluazinam according to claim 1, for preventing and kill off paddy field annual gramineous weed and broadleaved herb.
The herbicidal composition that contains flazasulfuron of the present invention can effectively be prevented and kill off as barnyard grass, a thousand pieces of gold, lady's-grass, Paspalum distichum, false loosestrife, Monochoria vaginalis, pondweed etc. rice direct seeding field, seedling throwing field annual gramineae and broad leaved weed, play synergistic effect, there is good herbicidal effect, the form of composition is used and has not only improved preventive effect, and reduced use cost, improve utilization rate of active components.
Embodiment
Embodiment 1
By the method for air-flow crushing, former solid medicine flazasulfuron is machined to 1000 orders, accurately take cyhalofop-butyl 5% in flazasulfuron 15%, active constituent B, dispersant alkyl naphthalene formaldehyde condensate sulfonates 6%, wetting agent alkylnaphthalene sulfonate 4%, adhesive alkylaryl polyoxy ethyl ether 5% according to percentage by weight, all the other are filler kaolin, supply and fully mix afterwards, can be packaged as 20% flazasulfuron cyhalofop-butyl wetting powder after qualified finally by quality testing all technical.
Embodiment 2
By the method for air-flow crushing, former solid medicine flazasulfuron is machined to 2000 orders, take flazasulfuron 15%, dichloro quinolinic acid 5% according to percentage by weight, dispersant alkyl naphthalene formaldehyde condensate sulfonates 4%, wetting agent alkylnaphthalene sulfonate 4%, adhesive alkylaryl polyoxy ethyl ether 5%, deionized water adds to 100% and carries out just mixing, shear agitation, dispersion, be mixed with after slurry, grind 2 hours through horizontal sand mill, make particle diameter at 1 micron, can be configured to flowable 20% flazasulfuron dichloro quinolinic acid suspension formulation.
Embodiment 3
By the method for air-flow crushing, former solid medicine oxadiazon, flazasulfuron are machined to 3000 orders, accurately take flazasulfuron 15%, oxadiazon 5% according to percentage by weight, dispersant alkyl naphthalene formaldehyde condensate sulfonates 6%, wetting agent alkylnaphthalene sulfonate 4%, adhesive alkylaryl polyoxy ethyl ether 5%, filler kaolin 12% and excess water are fully mixed into plastic material, through extruder grain, dry, sieve after qualified finally by quality testing all technical and can be packaged into 20% flazasulfuron oxadiazon water dispersion granule.
Embodiment 4
By the method for air-flow crushing, former solid medicine flazasulfuron is machined to 1000 orders, accurately take the third careless amine 9% in flazasulfuron 24%, active constituent B, dispersant dispersing agent MF 5%, wetting agent neopelex 4%, adhesive fatty alcohol polyoxy ethyl ether 5% according to percentage by weight, all the other are filler diatomite, supply and fully mix afterwards, can be packaged as 32% flazasulfuron cyhalofop-butyl wetting powder after qualified finally by quality testing all technical.
Embodiment 5
By the method for air-flow crushing, former solid medicine flazasulfuron is machined to 2000 orders, take flazasulfuron 12%, butachlor 5% according to percentage by weight, dispersant sodium lignin sulfonate 6%, wetting agent alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate 4%, adhesive alkylnaphthalene sulfonate 5%, deionized water adds to 100% and carries out just mixing, shear agitation, dispersion, be mixed with after slurry, grind 2 hours through horizontal sand mill, make particle diameter at 1 micron, can be configured to flowable 20% flazasulfuron dichloro quinolinic acid suspension formulation.
Embodiment 6
By the method for air-flow crushing, former solid medicine oxadiazon, flazasulfuron are machined to 3000 orders, accurately take flazasulfuron 15%, oxadiazon 5% according to percentage by weight, dispersant polycarboxylate 4%, wetting agent lauryl alcohol polyethylene glycol oxide base ether sodium sulfate 4%, adhesive polyethylene alcohol 5%, filler pyrophillite 8% and excess water are fully mixed into plastic material, through extruder grain, dry, sieve after qualified finally by quality testing all technical and can be packaged into 20% flazasulfuron oxadiazon water dispersion granule.
Biological control example 1
Prevent and kill off rice direct-seeding field weed field control effectiveness test
Management of weeds preventive effect computational methods are all carried out the community of State Standard of the People's Republic of China's " pesticide field efficacy medicine test criterion " test medicine, contrast medicament and blank and are processed the group arrangement of the random district of employing, community area 50m 2, repeat for 4 times.
Control rice direct-seeding field weed
Table 1 is 20% flazasulfuron cyhalofop-butyl wetting powder system
To rice direct seeding field, the annual and perennial grass family of seedling throwing field and broad leaved weed preventive effect,
Table 1 is as follows:
Figure BDA0000478904670000061
Table 2 is 20% flazasulfuron dichloro quinolinic acid suspension formulation
To rice direct seeding field, the annual and perennial grass family of seedling throwing field and broad leaved weed preventive effect,
Table 2 is as follows:
Figure BDA0000478904670000071
Table 3 is 20% flazasulfuron oxadiazon water dispersion granule
To rice direct seeding field, the annual and perennial grass family of seedling throwing field and broad leaved weed preventive effect,
Table 3 is as follows:
Figure BDA0000478904670000081
Field is taken temperature bright
This complex composition to rice direct seeding field, seedling throwing field annual gramineae and broad leaved weed as: barnyard grass, a thousand pieces of gold, lady's-grass, Paspalum distichum, false loosestrife, Monochoria vaginalis, pondweed etc. are effectively prevented and kill off.Effect obviously, has obtained unexpected herbicidal effect, and its form by composition is used and not only improved preventive effect, to crop safety and reduced use cost, has improved utilization rate of active components.

Claims (10)

1. contain a herbicidal composition for flazasulfuron, it is characterized in that comprising following component, described component by weight percentage:
Figure FDA0000478904660000011
Wherein, described active component A is flazasulfuron.
2. the herbicidal composition that contains flazasulfuron according to claim 1, is characterized in that: described active component B is any one in the third careless amine, butachlor, cyhalofop-butyl, dichloro quinolinic acid, oxadiazon.
3. the herbicidal composition that contains flazasulfuron according to claim 1, is characterized in that: the percentage by weight that described active component B is is 8-13%.
4. the herbicidal composition that contains flazasulfuron according to claim 1, is characterized in that: the percentage by weight that described active component A is is 18-23%.
5. the herbicidal composition that contains flazasulfuron according to claim 1, is characterized in that: described dispersant is one or more the mixture in dispersing agent MF, alkyl naphthalene formaldehyde condensate sulfonates, polycarboxylate, calcium lignosulfonate, sodium lignin sulfonate.
6. the herbicidal composition that contains flazasulfuron according to claim 1, is characterized in that: described wetting agent is any one or more the mixture in lauryl sodium sulfate, neopelex, alkylnaphthalene sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy base ether phosphate, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, alkylphenol polyoxyethylene formaldehyde condensation products succinate sodium sulfonate.
7. the herbicidal composition that contains flazasulfuron according to claim 1, is characterized in that: described adhesive is any one or more the mixture in alkylaryl polyoxy ethyl ether, fatty alcohol polyoxy ethyl ether, alkylnaphthalene sulfonate and polyvinyl alcohol.
8. the herbicidal composition that contains flazasulfuron according to claim 1, is characterized in that: described filler is one or more mixtures in clay, potter's clay, kaolin, diatomite, pyrophyllite.
9. the herbicidal composition that contains flazasulfuron according to claim 1, is characterized in that: described composition is suspending agent, wetting powder, water dispersible granules.
10. a purposes for the processing soil treatment agent composition of containing fluazinam according to claim 1, is characterized in that: for preventing and kill off paddy field annual gramineous weed and broadleaved herb.
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104396998A (en) * 2014-11-30 2015-03-11 南京华洲药业有限公司 Mixed weedicide containing flazasulfuron, butachlor and fluroxypyr
CN104396997A (en) * 2014-11-30 2015-03-11 南京华洲药业有限公司 Mixed weedicide containing flazasulfuron, butachlor and dithiopyr
CN104396994A (en) * 2014-11-30 2015-03-11 南京华洲药业有限公司 Mixed weedicide containing flazasulfuron, butachlor and trifluralin
CN104396996A (en) * 2014-11-30 2015-03-11 南京华洲药业有限公司 Mixed weedicide containing flazasulfuron, butachlor and pendimethalin
CN104430459A (en) * 2014-11-30 2015-03-25 南京华洲药业有限公司 Mixed herbicide containing flazasulfuron, butachlor and carfentrazone ethyl
CN104430454A (en) * 2014-11-30 2015-03-25 南京华洲药业有限公司 Mixed herbicide containing flazasulfuron, butachlor and flumetsulam
CN104663697A (en) * 2015-03-19 2015-06-03 四川利尔作物科学有限公司 Herbicidal composition and its application
CN106106488A (en) * 2016-06-19 2016-11-16 李祥英 Containing flazasulfuron and the Herbicidal combinations of Oxyfluorfen
CN109479890A (en) * 2018-11-06 2019-03-19 杭州瑞丰生物科技有限公司 Flazasulfuron compound herbicide and its application
CN110833072A (en) * 2018-08-17 2020-02-25 新乡市莱恩坪安园林有限公司 Weed killer for preventing and controlling weeds in warm-season lawn

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WO2005092101A2 (en) * 2004-03-26 2005-10-06 Syngenta Participations Ag A herbicidal combination
CN102960357A (en) * 2012-12-11 2013-03-13 江苏龙灯化学有限公司 Weed control composition containing ametryn, sulfentrazone and flazasulfuron and application thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005092101A2 (en) * 2004-03-26 2005-10-06 Syngenta Participations Ag A herbicidal combination
CN102960357A (en) * 2012-12-11 2013-03-13 江苏龙灯化学有限公司 Weed control composition containing ametryn, sulfentrazone and flazasulfuron and application thereof

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104396997B (en) * 2014-11-30 2016-07-27 南京华洲药业有限公司 A kind of mixed herbicide containing flazasulfuron, butachlor and dithiopyr
CN104396997A (en) * 2014-11-30 2015-03-11 南京华洲药业有限公司 Mixed weedicide containing flazasulfuron, butachlor and dithiopyr
CN104396994A (en) * 2014-11-30 2015-03-11 南京华洲药业有限公司 Mixed weedicide containing flazasulfuron, butachlor and trifluralin
CN104396996A (en) * 2014-11-30 2015-03-11 南京华洲药业有限公司 Mixed weedicide containing flazasulfuron, butachlor and pendimethalin
CN104430459A (en) * 2014-11-30 2015-03-25 南京华洲药业有限公司 Mixed herbicide containing flazasulfuron, butachlor and carfentrazone ethyl
CN104430454A (en) * 2014-11-30 2015-03-25 南京华洲药业有限公司 Mixed herbicide containing flazasulfuron, butachlor and flumetsulam
CN104396998A (en) * 2014-11-30 2015-03-11 南京华洲药业有限公司 Mixed weedicide containing flazasulfuron, butachlor and fluroxypyr
CN104396998B (en) * 2014-11-30 2016-06-29 南京华洲药业有限公司 A kind of mixed herbicide containing flazasulfuron, butachlor and fluroxypyr
CN104663697A (en) * 2015-03-19 2015-06-03 四川利尔作物科学有限公司 Herbicidal composition and its application
CN104663697B (en) * 2015-03-19 2016-10-12 四川利尔作物科学有限公司 Herbicidal composition and its application
CN106106488A (en) * 2016-06-19 2016-11-16 李祥英 Containing flazasulfuron and the Herbicidal combinations of Oxyfluorfen
CN110833072A (en) * 2018-08-17 2020-02-25 新乡市莱恩坪安园林有限公司 Weed killer for preventing and controlling weeds in warm-season lawn
CN109479890A (en) * 2018-11-06 2019-03-19 杭州瑞丰生物科技有限公司 Flazasulfuron compound herbicide and its application

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