CN1037700C - Hot-rolled steel sheet with superior uniform elongation after cold working and production process thereof - Google Patents
Hot-rolled steel sheet with superior uniform elongation after cold working and production process thereof Download PDFInfo
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Abstract
在冷加工后有333.2-607.bN/mm2的拉伸强度和良好延伸率的热轧钢板及其生产工艺,且生产率不降低。该热轧钢板含有0.04%-0.25%的C、0.0050%至0.0150%的N和0.003%至0.050%的Ti,也含有0.0008%至0.015%的有1μm至3μm的平均颗粒尺寸并弥散在其基体中的TiN,还有0.10%至0.45%的碳当量(WES)。工艺包括将上述钢板坯加热至1000至1300℃,轧制,至少在转变点Ar3精轧,从至少500℃空冷或在至少500℃卷取并空冷,所得钢组织有5%至20%的珠光体相。
A hot-rolled steel plate with a tensile strength of 333.2-607.bN/mm2 and a good elongation after cold working and a production process thereof without reducing productivity. The hot-rolled steel sheet contains 0.04%-0.25% C, 0.0050%-0.0150% N, and 0.003%-0.050% Ti, and also contains 0.0008%-0.015% Ti with an average particle size of 1 μm to 3 μm and dispersed in its matrix TiN in TiN, and 0.10% to 0.45% carbon equivalent (WES). The process consists of heating the above steel slab to 1000 to 1300°C, rolling, finish rolling at least at the transformation point Ar 3 , air cooling from at least 500°C or coiling and air cooling at at least 500°C, the resulting steel structure has 5% to 20% pearlite phase.
Description
本发明涉及在冷加工工艺之后有极好的均匀延伸率和高的拉伸强度的普通结构用和焊接结构用热轧钢板和薄板,并涉及生产该种产品的工艺。This invention relates to hot-rolled steel plates and sheets for general structural and welded structures having excellent uniform elongation and high tensile strength after the cold working process, and to a process for producing such products.
近年来随着结构用热轧钢板和薄板的品质改进和生产技术的重大进步,对具有极好的塑性变形能力的钢产品的需求日益增加,特别是在建筑业和土木工程领域从抗震设计的观点出发更是如此,并且要求钢板具有高强度,低屈服比和高的均匀延伸率。In recent years, with the improvement of the quality of hot-rolled steel plates and thin plates for structural use and major advances in production technology, there has been an increasing demand for steel products with excellent plastic deformation capabilities, especially in the fields of construction and civil engineering from seismic design to This is even more so from a point of view, and the steel plate is required to have high strength, low yield ratio and high uniform elongation.
为适应这一要求,例如在Kokai(日本未审查专利公开No.57-16118中就公开了一种生产用于油井的低屈服比电焊管的工艺,其中管子的含碳量增加到0.26%至0.48%,并且Kokai(日本未审查专利公开)No.57-16119公开了一种用于生产含碳量为0.10%至0.20%的高拉伸强度、低屈服比的电焊管工艺。在这两种工艺中,不需要热处理的电焊管的制造需要通过生产一种低屈服比的热轧钢板或薄板来完成,并且在应变量受到限制的同时冷加工上述钢制产品,由此加工硬化量不会变大。另外,Kokai(日本未审查专利公开)No.4-176818中提出了一种用于生产抗震性能良好的圆钢管或方钢管的工艺,该方法是通过对无应变铁素体—珠光体双相结构进行热加工,在热加工后控制其冷却率并进行热处理而实现的。但是,所有上述工艺都大大降低了生产率,并且前一工艺还显著地降低了焊接性。因此,这些工艺在目前必然不能满足工业领域的要求。To meet this requirement, for example, Kokai (Japanese Unexamined Patent Publication No. 57-16118) discloses a process for producing low-yield ratio electric welded pipes for oil wells, wherein the carbon content of the pipes is increased to 0.26% to 0.48%, and Kokai (Japanese Unexamined Patent Publication) No. 57-16119 discloses a process for producing high tensile strength, low yield ratio electric welded pipes with a carbon content of 0.10% to 0.20%. In this process, the manufacture of electric welded pipes that do not require heat treatment needs to be accomplished by producing a hot-rolled steel plate or sheet with a low yield ratio, and cold working the above-mentioned steel product while the amount of strain is limited, whereby the amount of work hardening will not In addition, Kokai (Japanese unexamined patent publication) No.4-176818 proposes a kind of technology that is used to produce the round steel pipe or the square steel pipe of seismic performance good, and this method is by unstrained ferrite-pearlite The bulk duplex structure is thermally processed, and its cooling rate is controlled and heat treated after thermal processing. However, all the above-mentioned processes greatly reduce productivity, and the former process also significantly reduces weldability. Therefore, these processes It is inevitable that the requirements of the industrial field cannot be met at present.
除了上述公开文件,Kokai(日本未审查专利公开)No.4-48048与KoKai(日本未审查专利公开)No.4-99248公开了用以通过在钢基体中弥散氧化物夹杂而改善焊接热影响区韧性的技术。在前一专利公开文本中的氧化物夹杂的颗粒尺寸为0.5μm或更小并且有(Ti,Nb)(Q,N)复合结晶相。在后一专利公开文本中氧化物夹杂的颗粒尺寸为1μm或更小并具有Ti(O,N)复合结晶相。这些专利公开的技术在分散外相与目的方面都与本发明有本质上的不同。In addition to the above publications, Kokai (Japanese Unexamined Patent Publication) No. 4-48048 and KoKai (Japanese Unexamined Patent Publication) No. 4-99248 disclose methods for improving the thermal influence of welding by dispersing oxide inclusions in the steel matrix. technology for regional resilience. The oxide inclusions in the former patent publication have a grain size of 0.5 μm or less and have a (Ti, Nb)(Q, N) composite crystal phase. The particle size of the oxide inclusions in the latter patent publication is 1 μm or less and has a Ti(O,N) composite crystal phase. The techniques disclosed in these patents are essentially different from the present invention in terms of dispersing the external phase and purpose.
一般说来,强度较高的钢都显示出较高的屈服比和较低的延展性,因此使其均匀延伸率降低。尤其在将钢冷加工成圆钢管、方钢管、型钢、板桩等时,由于加工应变引起的加工硬化的影响,其均匀延伸率要显著降低。In general, higher strength steels exhibit higher yield ratios and lower ductility, thereby reducing their uniform elongation. Especially when the steel is cold processed into round steel pipes, square steel pipes, section steel, sheet piles, etc., due to the influence of work hardening caused by processing strain, its uniform elongation will be significantly reduced.
本发明已经成功地解决了上述问题,并且本发明的目的就是提供即使在将其冷加工成圆管、方管、型钢、板桩等到生产率并不降低这样一种普通程度之后仍具有优越的均匀延伸率并具有高拉伸强度(至少333.2N/mm2)的热轧钢板和薄板。The present invention has successfully solved the above-mentioned problems, and it is an object of the present invention to provide excellent uniform elongation even after it is cold-worked into round pipes, square pipes, section steel, sheet piles, etc. to such an ordinary degree that productivity does not decrease. Hot-rolled steel sheets and sheets with high tensile strength (at least 333.2N/mm 2 ).
为了达到上述目的,本发明的发明人已经仔细地研究了钢的化学成份与晶体结构以及由此得到的机械性能之间的关系,经过冷加工的钢的机械性能与轧制状态的钢的机械性能之间的关系,等等。由此,本发明的发明人已经得到以下认识:就普通结构用和焊接结构用钢,特别是最大量用于建筑业和土木工程领域的具有拉伸强度为333.2至607.6N/mm2的热轧钢板或薄板而言,热轧状态产品(其均匀延伸率随拉伸强度的提高而降低)的拉伸强度与均匀延伸率之间的关系与它们在冷加工后的关系大致一致,而且两种情况下的关系可以用同一曲线来近似表示;虽然热轧状态钢与冷加工钢两者都显示出随着钢中N的增加,强度提高而均匀延伸率降低的特性,但通过进一步增加Ti,即使在钢具有高的强度时,也可恢复均匀延伸率,并可得到高的均匀延伸率,上述关系在此时不再保持。In order to achieve the above objects, the inventors of the present invention have carefully studied the relationship between the chemical composition and crystal structure of steel and the mechanical properties obtained therefrom, the mechanical properties of cold-worked steel and the mechanical properties of steel in the rolled state. relationship, and so on. Thus, the inventors of the present invention have obtained the following recognition: with regard to steels for ordinary structures and welded structures, especially steels with a tensile strength of 333.2 to 607.6 N/mm 2 which are most widely used in the field of construction and civil engineering For rolled steel plate or thin plate, the relationship between tensile strength and uniform elongation of hot-rolled products (whose uniform elongation decreases with the increase of tensile strength) is roughly the same as their relationship after cold working, and the two The relationship in this case can be approximated by the same curve; although both the hot-rolled steel and the cold-worked steel show the characteristic that the strength increases and the uniform elongation decreases with the increase of N in the steel, but by further increasing Ti, even When the steel has a high strength, the uniform elongation can also be restored, and a high uniform elongation can be obtained, and the above-mentioned relationship is no longer maintained at this time.
这一认识可以参考图2进一步说明如下。This realization can be further explained with reference to FIG. 2 as follows.
图2是一张曲线图,它表示由热轧状态钢产品和冷加工钢产品(方钢管)所得到的TS(拉伸强度,N/mm2)与Elu(均匀延伸率,%)之间的关系,所用的钢为表1中所列的S-1(比较例)、S-2(比较例)、T-1(举例)和T-2(举例),S-1、T-1和T-2按表2所示的生产工艺B生产,S-2按生产工艺C生产。S-1中的Ti和N的含量都低于本发明的下限。虽然S-2中的N含量在本发明的范围之内,但Ti的含量较低并低于本发明的下限。在生产工艺C中,精轧温度较低并低于转变点Ar3。Fig. 2 is a graph showing the relationship between TS (tensile strength, N/mm 2 ) and Elu (uniform elongation, %) obtained from steel products in the hot-rolled state and cold-worked steel products (square steel pipes). relationship, the steel used is listed in Table 1 as S-1 (comparative example), S-2 (comparative example), T-1 (example) and T-2 (example), S-1, T-1 and T-2 is produced according to production process B shown in Table 2, and S-2 is produced according to production process C. The contents of Ti and N in S-1 were both lower than the lower limit of the present invention. Although the N content in S-2 is within the range of the present invention, the Ti content is low and below the lower limit of the present invention. In production process C, the finish rolling temperature is lower and lower than the transformation point Ar 3 .
在图2中,就TS与Elu之间的关系而言,S-1的热轧状态钢板或薄板显示出高的TS与Elu。但是,随着TS的增加,S-1的方钢管显示出Elu的急剧降低。In FIG. 2 , in terms of the relationship between TS and Elu, the hot-rolled steel sheet or thin plate of S-1 showed high TS and Elu. However, the square steel tubes of S-1 showed a sharp decrease of Elu with the increase of TS.
在S-2的情况下,上述关系更加明显。当TS较高时,热轧状态钢板或薄板显示出10%或更小的Elu,虽然它们可以在TS较低时显示出较高的Elu。用冷加工制成的方管在多数情况下显示出10%或更小的Elu,并随TS增大而使Elu进一步降低。In the case of S-2, the above relationship is even more pronounced. Steel plates or sheets in the hot-rolled state show Elu of 10% or less when TS is high, although they can show high Elu when TS is low. Square tubes made by cold working showed Elu of 10% or less in most cases, and further decreased Elu with increasing TS.
这就是说,在S-1和S-2的情况下,冷加工钢产品显示出Elu随TS的增加而急剧降低的趋势。That is to say, in the case of S-1 and S-2, the cold-worked steel products showed a trend of a sharp decrease of Elu with the increase of TS.
与之相反,在T-1和T-2的情况下,热轧状态钢板或薄板显示出即使在TS增加时Elu也几乎不降低的特性。由此得到的冷加工产品显示出其Elu有很少程度的降低,并且几乎不受TS增加的影响。In contrast, in the cases of T-1 and T-2, the steel sheet or thin plate in the hot-rolled state exhibited a characteristic that Elu hardly decreased even when TS was increased. The resulting cold worked product showed a small decrease in Elu and was hardly affected by the increase in TS.
这就是说,含有适量添加的N和Ti的本发明的钢显示出即使在冷加工后,随着拉伸强度的提高,均匀延伸率也几乎不降低的特性。特别是本发明的一种具有TS至少为460.6N/mm2的钢可显示出本发明的效果。如上所述,作为普通结构用和焊接结构用钢,本发明的钢具有卓越的性能。That is to say, the steel of the present invention containing appropriate amounts of N and Ti added exhibits a characteristic that the uniform elongation hardly decreases as the tensile strength increases even after cold working. In particular, a steel of the present invention having a TS of at least 460.6 N/mm 2 can exhibit the effect of the present invention. As described above, the steel of the present invention has excellent properties as a steel for general structural use and welded structural use.
基于上述事实,本发明已经达到了本发明的目的,并且本发明的主题是在冷成形后具有333.2至607.6/mm2的拉伸强度和优越的均匀延伸率的高强度热轧钢板和薄板,上述钢板和薄板含有0.040%至0.25%的C,0.0050%至0.0150%的N和0.003%至0.050%的Ti,同时含有0.0008%至0.015%、平均尺寸由1μm至30μm并弥散在钢基体中的TiN,并且含有0.10%至0.45%的碳当量(WES),在制备钢板及薄板时,将含有上述成分的板坯加热至1000至1300℃的热轧温度,轧制板坯,在至少为转变点Ar3的温度精轧,然后将轧制产品空冷至至少为500℃的温度或将轧制产品在至少为500℃的温度卷取并将卷取产品空冷从而在钢的组织中形成其总量折算成面积百分率为5%至20%的珠光体相,本发明的主题还在于生产上述产品的生产工艺。Based on the above facts, the present invention has achieved the object of the present invention, and the subject of the present invention is a high-strength hot-rolled steel plate and sheet having a tensile strength of 333.2 to 607.6/ mm2 and a superior uniform elongation after cold forming, The above-mentioned steel plates and thin plates contain 0.040% to 0.25% of C, 0.0050% to 0.0150% of N and 0.003% to 0.050% of Ti, and at the same time contain 0.0008% to 0.015% of the average size of 1 μm to 30 μm and dispersed in the steel matrix TiN, and contains 0.10% to 0.45% carbon equivalent (WES). When preparing steel plates and thin plates, the slabs containing the above components are heated to a hot rolling temperature of 1000 to 1300 ° C, and the slabs are rolled. Finish rolling at a temperature of point Ar 3 , followed by air cooling of the rolled product to a temperature of at least 500°C or coiling of the rolled product at a temperature of at least 500°C and air cooling of the coiled product to form its overall The amount is converted into the pearlite phase with an area percentage of 5% to 20%. The subject of the present invention is also a production process for producing the above-mentioned products.
图1(A)表示一显微照相图片(放大400倍),说明用本发明的钢〔表4中的T-2(中间部分)钢,含有15.2%的珠光体相〕制取的方管的平面部分的金相组织。Figure 1(A) shows a photomicrograph (400X magnification) illustrating a square tube made from the steel of the present invention [T-2 (middle part) steel in Table 4, containing 15.2% pearlite phase] The metallographic structure of the planar part.
图1(B)表示一显微照相图片(放大400倍),说明用比较用钢〔表4中的S-2钢(厚度(t)=3.2mm),含有4%的珠光体相〕制取的方管的平面部分的金相组织。Fig. 1(B) shows a photomicrograph (400 times magnification) illustrating the steel produced by comparative steel [S-2 steel in Table 4 (thickness (t) = 3.2 mm), containing 4% pearlite phase]. Take the metallographic structure of the flat part of the square tube.
图2表示表4中的各种热轧钢板与方管的拉伸强度和均匀延伸率之间的关系。FIG. 2 shows the relationship between the tensile strength and uniform elongation of various hot-rolled steel sheets in Table 4 and square tubes.
下面详细说明本发明。The present invention will be described in detail below.
在本发明中,首先用传统的生产步骤制造一种由0.040%至-0.25%的C、0.0050%至0.0150%的N、0.003%至0.050%的Ti组成,其碳当量(Ceq)的范围为0.10%至0.45%,其余为Fe与不可避免的杂质的低合金钢板坯,它是由诸如转炉或电炉的熔化炉生产的钢水经过连续铸造制成的或是将钢水制成钢锭并将钢锭经过初轧制成的。In the present invention, a kind of by 0.040% to -0.25% of C, 0.0050% to 0.0150% of N, 0.003% to 0.050% of Ti is made by traditional production steps at first, and the range of its carbon equivalent (Ceq) is 0.10% to 0.45%, the rest is Fe and unavoidable impurities low-alloy steel slabs, which are made by continuous casting of molten steel produced in a melting furnace such as a converter or electric furnace or by making molten steel into ingots and passing the ingots through Initially rolled.
在本发明中,将钢中的成份如上所述加以规定,其理由说明如下。In the present invention, the components in the steel are specified as described above, and the reason for this is explained below.
C是决定钢的强度和钢组织中的珠光体相的总量的重要成份。当具有拉伸强度至少为333.2N/mm2的热轧钢板或薄板在钢的组织中含有所占面积率少于5%的珠光体相时,其冷成形之后的均匀延伸率要显著降低。这是因为珠光体可保证钢的强度,防止位错密度增加,并可保持塑性形变能力。C is an important component that determines the strength of steel and the total amount of pearlite phase in the steel structure. When a hot-rolled steel sheet or sheet having a tensile strength of at least 333.2 N/ mm2 contains a pearlite phase occupying an area ratio of less than 5% in the steel structure, its uniform elongation after cold forming is significantly reduced. This is because pearlite secures the strength of steel, prevents an increase in dislocation density, and maintains plastic deformation ability.
另外,当热轧钢板含有所占面积率为20%或更多的珠光体相时,可使钢的硬度增加,塑性形变能力降低。为了得到这种具有其总量占面积百分率为5%至20%的珠光体相的钢组织,就需要钢含有至少0.04%的C。但是,当C的含量超过0.25%时可削弱钢的焊接性能,因此C含量的上限限定为0.25%。In addition, when the hot-rolled steel sheet contains a pearlite phase occupying an area ratio of 20% or more, the hardness of the steel increases and the plastic deformability decreases. In order to obtain such a steel structure having a pearlite phase whose total area percentage is 5% to 20%, it is required that the steel contains at least 0.04% of C. However, when the C content exceeds 0.25%, the weldability of steel may be impaired, so the upper limit of the C content is limited to 0.25%.
添加在钢中的N溶解在铁素体的基体中,它可提高钢的强度并降低塑性形变能力。但是,当N与Ti一起加入时,就形成TiN。这种形成不仅使溶解在钢中的N减少,并使塑性形变能力得以改善,而且其弥散作用使钢得到加强。因此N是一种重要的元素,它赋予钢以高的强度和大的均匀延伸率。The N added to the steel dissolves in the ferrite matrix, which increases the strength of the steel and reduces the plastic deformation capacity. However, when N is added together with Ti, TiN is formed. This formation not only reduces the dissolved N in the steel and improves the plastic deformation ability, but also strengthens the steel due to its dispersion effect. Therefore N is an important element which endows steel with high strength and large uniform elongation.
为了赋予钢以这种性能,就必需使具有1μm至30μm的平均颗粒尺寸的TiN弥散在基体中,其总量按重量折算为0.0008%至0.015%。换句话说,当TiN的平均颗粒尺寸小于1μm时,弥散增强作用就不十分有效。In order to impart such properties to steel, it is necessary to disperse TiN having an average particle size of 1 μm to 30 μm in the matrix in a total amount of 0.0008% to 0.015% by weight. In other words, when the average particle size of TiN is smaller than 1 µm, the dispersion enhancing effect is not very effective.
当然,当TiN的平均颗粒尺寸超过30μm时,在冷加工过程中在粗大的TiN颗粒与基体之间会产生隔离作用。与塑性形变的增加相一致,会出现微裂纹,并由此使钢的塑性形变能力下降。Of course, when the average particle size of TiN exceeds 30 μm, there will be an isolation effect between the coarse TiN particles and the matrix during cold working. Corresponding to the increase in plastic deformation, microcracks appear and thereby reduce the plastic deformation capacity of the steel.
为了获得上述的TiN,Ti的含量最好在0.003%至0.050%的范围内。In order to obtain the above-mentioned TiN, the content of Ti is preferably in the range of 0.003% to 0.050%.
此外,虽然N的必需量至少为0.0050%,最好至少为0.0080%,但是当N的含量超过0.0150%时,增强作用过大,并使均匀延伸率降低。因此N含量的上限限定为0.0150%。另外,为了在钢中有效地形成上述的TiN,最好在加入Ti之前在钢中加入Al,使之脱氧。Furthermore, although the necessary amount of N is at least 0.0050%, preferably at least 0.0080%, when the N content exceeds 0.0150%, the reinforcing effect is too large and the uniform elongation decreases. Therefore, the upper limit of the N content is limited to 0.0150%. In addition, in order to efficiently form the above-mentioned TiN in steel, it is preferable to add Al to the steel to deoxidize it before adding Ti.
在本发明的钢中添加Ti的原因如上所述,并且其含量最好为0.01%至0.03%。The reason for adding Ti to the steel of the present invention is as described above, and its content is preferably 0.01% to 0.03%.
碳当量(Ceq)由下列公式获得(根据WES):Carbon equivalent (Ceq) is obtained by the following formula (according to WES):
Ceq=C+Si/24+Mn/6+Ni/40+Cr/5+Mo/4+V/14。Ceq=C+Si/24+Mn/6+Ni/40+Cr/5+Mo/4+V/14.
Ceq的总量的确定与强度和焊接性有关。当总量少于0.10%时,不能保证有足够的强度。当总量超过0.45%时,虽然能获得高的强度,但焊接性受到削弱。因此将Ceq.限制在0.10%在0.45%的范围内。The determination of the total amount of Ceq is related to strength and weldability. When the total amount is less than 0.10%, sufficient strength cannot be guaranteed. When the total amount exceeds 0.45%, although high strength can be obtained, weldability is impaired. Ceq. is therefore limited to a range of 0.10% to 0.45%.
钢可以含有用于改进强度和韧性的有效成份,至少可以从由0.01%至0.7%的Si、0.1%至2.0%的Mn、0.05%至1.0%的Ni、0.05%至1.0%的Cr、0.02%至0.5%的Mo和0.005%至0.2%的V组成的组分中选取一种元素。Steel can contain effective ingredients for improving strength and toughness, at least from 0.01% to 0.7% of Si, 0.1% to 2.0% of Mn, 0.05% to 1.0% of Ni, 0.05% to 1.0% of Cr, 0.02 % to 0.5% of Mo and 0.005% to 0.2% of V to select one element.
此外,本发明的钢板坯中所含有的P与S是降低钢的韧性和焊接性等的有害杂质。因此,将P的含量和S的含量分别限制在0.025%或更少,而P+S的含量限制在0.04%或更少。In addition, P and S contained in the steel slab of the present invention are harmful impurities that lower the toughness, weldability, and the like of the steel. Therefore, the content of P and the content of S are limited to 0.025% or less, respectively, and the content of P+S is limited to 0.04% or less.
另外,本发明的钢可以含有一种用于改进强度和韧性的有效成份,至少可以从由0.05%至1.0%的Cu、0.005%至0.05%的Nb、0.001%至0.1%的Al、0.0005%至0.0020%的B、0.0005%至0.0070%的Ca和0.001%至0.050%的REM(包括Y的镧系元素中的稀土金属)组成的组分中选取一种。In addition, the steel of the present invention may contain an active ingredient for improving strength and toughness, at least from 0.05% to 1.0% of Cu, 0.005% to 0.05% of Nb, 0.001% to 0.1% of Al, 0.0005% One of the components consisting of B to 0.0020%, Ca from 0.0005% to 0.0070%, and REM (rare earth metals in lanthanides including Y) from 0.001% to 0.050% is selected.
将其成份调整在上述范围内的低合金钢板坯加热至用于热轧的1000至1300℃并进行轧制,然后在钢的温度至少为转变点Ar3时进行精轧。将所得到的钢空冷至至少为500℃的温度,以获得钢板,或将所得到的钢在至少为500℃的卷取温度下卷取并空冷,以获得热轧带材。The low alloy steel slab whose composition is adjusted within the above range is heated to 1000 to 1300° C. for hot rolling and rolled, and then finish rolled when the temperature of the steel is at least the transformation point Ar 3 . The resulting steel is air-cooled to a temperature of at least 500°C to obtain a steel plate, or the resulting steel is coiled at a coiling temperature of at least 500°C and air-cooled to obtain a hot-rolled strip.
将热轧所用的加热温度的下限限定为1000℃,以防止由下述情况引起的强度提高而塑性形变能力降低:根据钢的厚度,钢的精轧温度可以低于转变点Ar3;其结果将迫使其中的铁素体受到加工,于是基体中的位错密度增加。当钢的板坯温度超过1300℃时,产品的生产率将由于产品的氧化而显著下降。因此,将其温度上限限定为1300℃。将精轧温度限定在至少为转变点Ar3,其原因如上所述。此外,为了避免本发明的钢板和薄板强度的不必要提高,将轧制后的空冷起始温度和卷取温度限定在至少为500℃。The lower limit of the heating temperature used for hot rolling is limited to 1000°C in order to prevent the increase in strength and decrease in plastic deformation ability caused by the following: depending on the thickness of the steel, the finish rolling temperature of the steel can be lower than the transformation point Ar 3 ; as a result The ferrite in it will be forced to be processed, so the dislocation density in the matrix will increase. When the slab temperature of the steel exceeds 1300° C., the productivity of the product will drop significantly due to the oxidation of the product. Therefore, the upper limit of the temperature is limited to 1300°C. The finishing temperature is limited to at least the transformation point Ar₃ for the reasons mentioned above. Furthermore, in order to avoid unnecessary increase in the strength of the steel sheet and sheet of the present invention, the air cooling start temperature after rolling and the coiling temperature are limited to at least 500°C.
在根据本发明生产的钢板中,将具有平均颗粒尺寸为1μm至30μm的TiN很好的弥散并沉淀在基体中,其比例为0.0008%至0.015%。其结果是,钢显示出一种细晶粒铁素体一珠光体组织(一部分含有贝氏体组织),其中含有如图1(A)所示的、其含量折算为面积百分率为5%至20%的珠光体相。由于本发明的钢板和薄板具有这种钢的组织,它们在冷加工后具有优越的均匀延伸率,并有333.2至607.6N/mm2的高的强度。In the steel sheet produced according to the present invention, TiN having an average particle size of 1 μm to 30 μm is well dispersed and precipitated in the matrix at a ratio of 0.0008% to 0.015%. As a result, the steel exhibits a fine-grained ferrite-pearlite structure (partially containing a bainite structure) containing a content of 5% to 20% pearlite phase. Since the steel plates and thin plates of the present invention have such a steel structure, they have excellent uniform elongation after cold working and have a high strength of 333.2 to 607.6 N/mm 2 .
下面说明本发明的实施例。Embodiments of the present invention are described below.
具有表1所示化学成份的含TiN的钢板坯和比较用钢均热轧成厚度为3.0至22.2mm的钢板及薄板,并对成品钢板的机械性能进行了研究。其生产工艺表示在表2中。热轧状态或加工至有10%应变的钢产品的性能均表示在表3中。TiN-containing steel slabs and comparative steels having the chemical composition shown in Table 1 were hot-rolled into steel plates and thin plates with a thickness of 3.0 to 22.2 mm, and the mechanical properties of the finished steel plates were studied. Its production process is shown in Table 2. The properties of the steel product as hot rolled or processed to a 10% strain are shown in Table 3.
表4与表5表示轧制状态的钢和用其制成的方管上各个部位的性能研究结果。图1(A)表示了用本发明的钢T-2制造的方管的平面部分(中部)的金相组织的显微照相(放大400倍),图1(B)表示用比较用钢S-2制造的方管的相同部位的金相组织的显微照相。在图1(A)中的本发明的钢中,珠光体相的按面积百分率折算的含量大约为15.2%,而在图1(B)中的比较用钢中,只含有约为4%的极少量的珠光体相。图2表示本发明的钢和用于比较的钢的拉伸强度与均匀延伸率之间的关系,它们主要利用了表4中的结果。Table 4 and Table 5 show the performance research results of various parts on the rolled steel and the square tube made of it. Fig. 1 (A) has shown the micrograph (
根据这些结果,虽然其强度在与各个比较用钢相比时要高一些,但是本发明的钢(C-4,C-6,T-1,T-2,T-3,T-4)保持了高的均匀延伸率,特别是在冷加工之后。这些结果可从图2中得到很好的理解,该图表示本发明的钢和比较用钢的热轧钢板和薄板的均匀延伸率与强度之间的关系,以及在实际生产线中通过冷成形上述钢板所得到的方管的均匀延伸率与强度之间的关系。According to these results, the steels of the present invention (C-4, C-6, T-1, T-2, T-3, T-4) were somewhat higher in strength than the respective comparison steels. High uniform elongation is maintained, especially after cold working. These results can be well understood from Fig. 2, which shows the relationship between uniform elongation and strength of hot-rolled steel plates and sheets of the steels of the present invention and comparative steels, and the above-mentioned The relationship between the uniform elongation and the strength of the square tube obtained from the steel plate.
如上所述,在本发明中,即使在受冷成形到不会降低普通生产率这样一种程度仍具有333.2至607.6/mm2的拉伸强度和极优越的均匀延伸率的高强度热轧钢板和薄板可以通过限定钢中的成份以使之形成具有弥散增强能力的较大的TiN颗粒,并通过在其中形成有效的珠光体相而生产出来。作为普通结构用和焊接结构用钢制产品和作为圆管和方管、型钢、板桩等的材料,高强度热轧钢板和薄板是极其有用的。As described above, in the present invention, a high-strength hot-rolled steel sheet having a tensile strength of 333.2 to 607.6/ mm2 and an extremely superior uniform elongation even when cold-formed to such an extent that ordinary productivity is not lowered and Thin plates can be produced by limiting the composition of the steel to form larger TiN particles with dispersion enhancing capabilities and by forming an effective pearlite phase therein. High-strength hot-rolled steel plates and thin plates are extremely useful as steel products for general structural use and welded structural use and as materials for round and square pipes, section steel, sheet piles, etc.
表1 Table 1
(重量%)钢种 C Si Mn P S Cu Ni Cr Mo V Al Ti N CeqCS C-1 0.16 0.05 0.45 0.009 0.007 - - 0.11 0.02 - 0.025 - 0.0027 0.26CS C-2 0.16 0.05 0.45 0.009 0.017 - - 0.11 0.03 - 0.030 - 0.0034 0.26CS C-3 0.15 0.05 0.44 0.010 0.016 - - 0.07 0.02 - 0.026 - 0.0071 0.24IS C-4 0.15 0.05 0.45 0.010 0.017 - - 0.07 0.02 - 0.027 0.015 0.0071 0.24CS C-5 0.08 0.07 0.31 0.012 0.017 0.20 0.59 0.06 0.10 0.01 0.027 0.001 0.0058 0.19IS C-6 0.08 0.08 0.28 0.010 0.016 0.21 0.60 0.05 0.11 0.01 0.012 0.012 0.0092 0.18CS C-7 0.08 0.07 0.30 0.010 0.017 0.20 0.57 0.05 0.09 0.01 0.023 0.011 0.0167 0.18CS S-1 0.14 0.01 0.46 0.013 0.003 - - - - - 0.032 - 0.0015 0.22CS S-2 0.12 0.09 0.29 0.016 0.022 - - 0.05 - 0.005 0.038 0.001 0.0074 0.18CS S-3 0.15 0.39 1.40 0.012 0.013 - - 0.05 - - 0.033 - 0.0040 0.41CS S-4 0.06 0.04 0.33 0.009 0.010 - - 0.03 - - 0.034 - 0.0110 0.12IS T-1 0.15 0.09 0.27 0.014 0.019 - - 0.05 - 0.006 0.039 0.016 0.0111 0.21IS T-2 0.17 0.09 0.28 0.011 0.015 - - 0.06 - 0.007 0.030 0.021 0.0110 0.23IS T-3 0.15 0.38 1.39 0.013 0.013 - - 0.06 - - 0.031 0.022 0.0100 0.41IS T-4 0.05 0.05 0.39 0.010 0.010 - - 0.06 - - 0.031 0.027 0.0090 0.13(Weight %) Steel C SI MN P S Cu Ni CR Mo V Al Ti N CEQCS CEQCS CEQCS CEQCS CEQCS CEQCS CEQCS CEQCS CEQCS CEQCS CEQCS CEQCS CEQCS CEQCs C-0.05 0.009 0.007-0.11 0.025-0.0027 0.26CS C-2 0.05 0.009 0.017-0.11 0.03 - 0.030 - 0.0034 0.26CS C-3 0.15 0.05 0.44 0.010 0.016 - - 0.07 0.02 - 0.026 - 0.0071 0.24IS C-4 0.15 0.05 0.45 0.010 0.017 - - 0.07 0.02 - 0.027 0.015 0.0071 0.24CS C-5 0.08 0.07 0.31 0.012 0.017 0.20 0.59 0.06 0.10 0.01 0.027 0.001 0.0058 0.19IS C-6 0.08 0.08 0.28 0.010 0.016 0.21 0.60 0.05 0.11 0.01 0.012 0.012 0.0092 0.18CS C-7 0.08 0.07 0.30 0.010 0.017 0.20 0.57 0.05 0.09 0.01 0.023 0.011 0.0167 0.18CS S-1 0.14 0.01 0.46 0.013 0.003 - - - - - 0.032 - 0.0015 0.22CS S-2 0.12 0.09 0.29 0.016 0.022 - - 0.05 - 0.005 0.038 0.001 0.0074 0.18CS S-3 0.15 0.39 1.40 0.012 0.013 - - 0.05 - - 0.033 - 0.0040 0.41CS S-4 0.06 0.04 0.009 0.010-0.03-0.034-0.0110 0.12IS T-0.09 0.27 0.019-0.06 0.039 0.011I 0.0.09 0.015 0.015 0.015 0.015 0.01115 0.01115 0.01115 0.015 0.015 0.015 0.015 0.015 0.015 0.09 0.0 0.09 0.0 0.09 0.0 0.09 0.0 0.09 0.0 0.015 0.09 0.7 0.09 0 0.09 0.0 0. 0.21IS 0.09 0.09 0.0 0. 0.09 0.0 0.09 0.0 0. 0.7 0.0 0.09 0.0-0-. That 0.021 0.0110 0.23is T-3 0.15 0.39 1.39 0.013 0.013-0.06-0.031 0.022 0.0100 0.41IS T-4 0.05 0.39 0.010-0.031 0.027 0.0090 0.13
注:CS=比较用钢;IS=本发明的钢Note: CS = comparative steel; IS = steel of the present invention
Ceq.(WES)=C+Si/24+Mn/6+Ni/40+Cr/5+Mo/4+V/14Ceq.(WES)=C+Si/24+Mn/6+Ni/40+Cr/5+Mo/4+V/14
表2 Table 2
(温度℃)生产工艺 钢板坯加 精轧温度 薄钢板卷 空冷起(Temperature °C) Production process Steel slab processing Finish rolling temperature Thin steel coil Air cooling
热温度 取温度 始温度IB A 1200 950 680 -IB B 1230 980 630 -CB C 1230 790 490 -IB D 1180 900 - 700Thermal temperature takes temperature, start temperature IB A 1200 950 680 -ib B 1230 980 630 -CB C 1230 790 490 -ib D 1180 900-700
注:(1)TS=本发明的钢;CS=比较用钢Note: (1) TS = steel of the present invention; CS = comparative steel
(2)温度低于转变点Ar3 (2) The temperature is lower than the transformation point Ar 3
表3 table 3
折合成 面积钢种 工艺 厚度 YSl* TS* El* ELu* TiN的 TiN的平 百分率的珠光 注Converted into Area Steel Type Process Thickness YSl * TS * El * ELu * TiN Percentage of TiN Pearlescent Note
(mm) (N/mm2)(N/mm2) (%) (%) 重量(%)均颗粒尺寸 体相(mm) (N/mm 2 )(N/mm 2 ) (%) (%) Weight (%) Average particle size Bulk phase
(μm) (%)CS C-1 A 5.7 305.0 421.7 42.0 22.2 0 - 16.9 热轧状态(Μm) ( %) CS C-1 A 5.7 305.0 42.7 42.0 22.2 0-16.9 hot-rolled state state
5.4 475.6 475.6 28.0 7.2 - - - 10%应变CS C-2 A 5.7 286.3 428.5 43.5 21.6 0 - 17.1 热轧状态5.4 475.6 475.6 28.0 7.2--10 % Stocking CS CS C-2 A 5.7 286.3 428.5 43.5 21.6 0-17.1 The hot rolling state
5.4 483.4 488.4 26.0 5.2 - - - 10%应变CS C-3 A 5.7 306.0 439.3 40.5 21.0 0 - 16.6 热轧状态5.4 483.4 488.4 26.0 5.2--10 % Stock CS CS C-3 A 5.7 306.0 40.5 21.0 0-16.6 The hot rolling state
5.4 510.9 517.8 23.0 2.0 - - - 10%应变IS C-4 A 5.7 319.7 451.1 44.0 20.0 0.0051 3.82 16.8 热轧状态510.9 517.8 23.0 2.0-10 % strain IS C-4 A 5.7 319.7 451.1 44.0 20.051 3.82 16.8 hot-rolled state
5.4 515.5 522.7 31.0 9.0 - - - 10%应变CS C-5 A 8.5 240.3 339.3 47.0 22.8 0 - 10.7 热轧状态515.5 522.7 31.0 9.0-10 % Stocking CS CS CS C-5 A 8.5 240.3 339.3 47.0 22.8 0-10.7 hot rolling state
6.9 415.8 424.6 21.0 1.2 - - - 10%应变IS C-6 A 8.7 245.2 347.1 45.5 22.0 0.0041 3.44 10.9 热轧状态6.9 415.8 424.6 21.0 1.2--10 % Stocking IS C-6 A 8.7 247.1 45.5 22.0 0.0041 3.44 10.9 The hot rolling state
6.9 426.6 454.0 26.0 6.4 - - - 10%应变CS C-7 C 8.5 407.0 478.5 34.0 17.5 0.0038 3.20 4.5 热轧状态6.9 426.6 454.0 26.0 6.4--10 % Stock CS CS C-7 C 8.5 478.5 34.0 17.5 0.0038 3.20 4.5 The hot rolling state
6.9 559.0 566.8 20.1 1.4 - - - 10%应变6.9 559.0 566.8 20.1 1.4 - - - 10% strain
注:IS=本发明的钢;CS=比较用钢Note: IS = steel of the present invention; CS = steel for comparison
*YSI=屈服强度;TS=拉伸强度;El=延伸率; * YSI=yield strength; TS=tensile strength; El=elongation;
Elu=均匀延伸率Elu = uniform elongation
拉伸试件根据JIS Z22015的试件规格制备The tensile test piece is prepared according to the test piece specification of JIS Z22015
表4钢种 工艺 厚度 YSl* TS* El* ELu* TiN TiN的平 折合成 面积 注Table 4 Steel Type Process Thickness YSl * TS * El * ELu * TiN Flat converted area of TiN Note
(mm) (N/mm2) (N/mm2) (%) (%) 的重量 均颗粒尺寸 百分率的珠光(mm) (N/mm 2 ) (N/mm 2 ) (%) (%) Weight Average particle size Percentage of pearlescent
(%) 体相(%) (%) Bulk(%)
(μm) (%)CS S-1 B 3.2 306.9 444.2 39.0 19.2 0 - 9.3 热轧状态(Μm) ( %) CS S-B 3.2 306.9 444.2 39.0 19.2 0-9.3 hot-rolled state state
3.3 441.3 468.7 33.2 11.6 - - - sq.tube F3.3 441.3 468.7 33.2 11.6 - - - - sq.tube F
B 3.2 311.8 450.1 39.2 18.8 - - 9.5 热轧状态B 3.2 311.8 450.1 39.2 18.8 - - 9.5 Hot-rolled
3.2 376.6 454.0 36.0 17.3 - - - sq.tube F3.2 376.6 454.0 36.0 17.3 - - - - sq.tube F
B 6.0 312.8 438.3 40.6 19.7 - - 9.7 热轧状态B 6.0 312.8 438.3 40.6 19.7 - - 9.7 Hot-rolled state
6.1 396.2 444.2 37.0 14.5 - - - sq.tube FCS S-2 C 3.2 333.4 437.4 34.8 16.3 0 - 4.4 热轧状态6.1 396.2 444.2 37.0 14.5--SQ.Tube FCS S-2 C 3.2 337.4 34.8 16.3 0-4.4 hot-rolled state state
3.2 471.7 505.0 20.4 4.0 - - - sq.tube F3.2 471.7 505.0 20.4 4.0 - - - - - sq.tube F
C 6.0 390.3 471.7 29.0 9.8 - - 4.2 热轧状态C 6.0 390.3 471.7 29.0 9.8 - - 4.2 Hot-rolled
6.0 454.0 498.2 23.6 4.9 - - - sq.tube F6.0 454.0 498.2 23.6 4.9 - - - - - sq.tube F
C 5.7 310.9 433.4 38.0 18.7 - - 4.3 热轧状态C 5.7 310.9 433.4 38.0 18.7 - - 4.3 Hot-rolled
5.8 423.6 477.6 29.0 5.5 - - - sq.tube F5.8 423.6 477.6 29.0 5.5 - - - - sq.tube F
表4(续)钢种 工艺 厚度 YSl* TS* El* ELu* TiN TiN的平 折合成 面积 注Table 4 (Continued) Steel Type Process Thickness YSl * TS * El * ELu * TiN Flat Converted Area of TiN Note
(mm) (N/mm2) (N/mm2) (%) (%) 的重量 均颗粒尺寸 百分率的珠光(mm) (N/mm 2 ) (N/mm 2 ) (%) (%) Weight Average particle size Percentage of pearlescent
(%) (μm) 体相(%)IS T-1 B 3.0 314.8 444.2 39.5 19.5 0.0055 6.50 14.7 热轧状态(顶部)( %) (Μm) body phase ( %) IS T-1 B 3.0 314.8 444.2 39.5 19.5 0.0055 6.50 14.7 hot-rolled state (top)
3.1 330.5 458.9 36.0 16.6 - - - sq.tube F(顶部)3.1 330.5 458.9 36.0 16.6 - - - - - sq.tube F(Top)
B 3.0 297.1 455.0 40.0 20.0 - - 14.9 热轧状态(中部)
3.1 373.6 461.9 36.5 17.0 - - - sq.tube F(中部)3.1 373.6 461.9 36.5 17.0 - - - - - sq.tube F(middle)
B 3.1 337.3 502.1 34.0 17.5 - - 14.1 热轧状态(底部)B 3.1 337.3 502.1 34.0 17.5 - - - 14.1 Hot rolled state (bottom)
3.1 419.7 508.0 31.0 13.6 - - - sq.tube F(底部)3.1 419.7 508.0 31.0 13.6 - - - - - sq.tube F(bottom)
B 3.1 640.3 705.1 28.0 6.2 - - - sq.tube C(底部)B 3.1 640.3 705.1 28.0 6.2 - - - - - sq.tube C(bottom)
3.1 597.2 642.3 32.0 7.9 - - - sq.tube C(底部)IS T-2 B 3.0 340.7 479.5 40.0 19.8 0.0072 6.21 15.5 热轧状态(顶部)3.1 597.2 642.3 32.0 7.9--SQ.Tube C (bottom) IS T-2 B 3.0 340.7 479.5 40.0 19.8 0.0072 6.21 15.5 hot rolling state (top)
3.1 327.5 472.7 35.0 16.0 - - - sq.tube F(顶部)3.1 327.5 472.7 35.0 16.0 - - - - - sq.tube F(Top)
B 3.0 303.0 463.8 37.0 19.4 - - 15.3 as rolled(中部)B 3.0 303.0 463.8 37.0 19.4 - - - 15.3 as rolled (middle)
3.1 380.5 471.7 35.0 16.2 - - - sq.tube F(中部)3.1 380.5 471.7 35.0 16.2 - - - - - sq.tube F(middle)
B 3.1 326.5 518.7 35.0 17.6 - - 16.0 热轧状态(底部)B 3.1 326.5 518.7 35.0 17.6 - - - 16.0 Hot rolled state (bottom)
3.1 386.4 480.5 35.0 16.0 - - - sq.tube F(底部)3.1 386.4 480.5 35.0 16.0 - - - - - sq.tube F(bottom)
B 3.1 596.2 660.9 33.0 12.0 - - - sq.tube C(底部)B 3.1 596.2 660.9 33.0 12.0 - - - - - sq.tube C (bottom)
3.1 581.5 652.1 35.0 12.3 - - - sq.tube C(底部)3.1 581.5 652.1 35.0 12.3 - - - - - sq.tube C(bottom)
注:(1)IS=本发明的钢;CS=比较用钢Note: (1) IS = steel of the present invention; CS = steel for comparison
(2)*YSl=屈服强度;TS=拉伸强度;El=延伸率;Elu=均匀延伸率(2) * YSl=yield strength; TS=tensile strength; El=elongation; Elu=uniform elongation
(3)Sq.tube F=方管的平面部分;Sq.tube C=方管的角部(3) Sq.tube F = plane part of square tube; Sq.tube C = corner of square tube
(4)拉伸试件根据JIS Z 2201 5的试件规格制备,只有角部试件根(4) Tensile specimens are prepared according to the specimen specifications of JIS Z 2201 5, only the corner specimens are rooted
据JIS Z2201 12B的试件规格制备。Prepared according to the test piece specification of JIS Z2201 12B.
(5)每类钢管的尺寸均为75mm×75mm(5) The size of each type of steel pipe is 75mm×75mm
表5钢种 工艺 厚度 0.2%PS* TS* El* ELu* TiN TiN的平均 折合成 面积 注Table 5 Steel type Process Thickness 0.2%PS * TS * El * ELu * TiN Average converted area of TiN Note
(mm) (N/mm2) (N/mm2) (%) (%) 的重量 颗粒尺寸 百分率的珠光(mm) (N/mm 2 ) (N/mm 2 ) (%) (%) Weight Particle Size Percentage of Pearlescent
(%) (μm) 体相(%)CS S-3 D 22.2 353.0 538.4 28.4 20.0 0 - 5.5 热轧状态( %) (Μm) Body phase ( %) CS S-3 D 22.2 353.0 538.4 28.0 20.0 0-5.5 hot-rolled state
22.0 373.6 549.1 24.7 16.6 - - - sq.tube F22.0 373.6 549.1 24.7 16.6 - - - - - sq.tube F
22.1 559.9 649.2 15.0 5.2 - - - sq.tube CCS S-4 C 9.0 294.2 421.7 40.0 17.5 0 - 3.8 热轧状态22.1 559.9 649.2 15.0 5.2--SQ.Tube CCS S-4 C 9.0 294.2 421.7 40.0 17.5 0-3.8 The hot rolling state
9.1 374.6 449.1 35.0 9.5 - - - sq.tube F9.1 374.6 449.1 35.0 9.5 - - - - - sq.tube F
9.0 479.5 530.5 26.0 4.2 - - - sq.tube CIS T-3 D 22.1 355.0 540.3 29.0 21.3 0.0076 5.77 5.5 热轧状态9.0 479.5 530.5 26.0 4.2--SQ.Tube CIS T-3 D 22.1 355.0 540.3 29.0 21.3 0.0076 5.77 5.5 The hot rolling state
22.0 377.5 551.1 27.1 18.7 - - - sq.tube CIS T-4 B 8.9 287.3 441.3 38.5 20.5 0.0093 4.06 6.2 热轧状态22.0 377.5 551.1 27.1 18.7--SQ.Tube CIS T-4 B 8.9 287.3 441.3 38.5 20.5 0.0093 4.06 6.2 The hot rolling state
9.0 335.4 444.2 38.0 19.6 - - - sq.tube F9.0 335.4 444.2 38.0 19.6 - - - - - sq.tube F
9.0 493.3 554.1 36.0 16.0 - - - sq.tube C注:(1)Prodn=产品9.0 493.3 554.1 36.0 16.0 - - - - - sq.tube C Note: (1) Prodn=Product
(2)IS=本发明的钢;CS=比较用钢(2) IS = steel of the present invention; CS = comparative steel
(3)*0.2%PS=0.2%的屈服点,TS=拉伸强度;El=延伸1率;(3) * 0.2% PS = 0.2% yield point, TS = tensile strength; El = elongation rate;
Elu=均匀延伸率Elu = uniform elongation
(4)gq.tube F=方管的平面部分;Sq.tube C=方管的角部(4) gq.tube F = plane part of square tube; Sq.tube C = corner of square tube
(5)S-3,T-3:每种方管具有350mm×350mm的尺寸,拉伸(5) S-3, T-3: Each square tube has a size of 350mm×350mm, stretched
试件根据JIS Z2201 1B的试件规格制备。The test piece is prepared according to the test piece specification of JIS Z2201 1B.
(6)S-4,T-4:每种方管具有250mm×250mm的尺寸,拉伸(6) S-4, T-4: Each square tube has a size of 250mm×250mm, stretched
试件根据JIS Z2201 5的试件规格制备。The test piece is prepared according to the test piece specification of JIS Z2201 5.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94102515A CN1037700C (en) | 1994-02-25 | 1994-02-25 | Hot-rolled steel sheet with superior uniform elongation after cold working and production process thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94102515A CN1037700C (en) | 1994-02-25 | 1994-02-25 | Hot-rolled steel sheet with superior uniform elongation after cold working and production process thereof |
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| Publication Number | Publication Date |
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| CN1107521A CN1107521A (en) | 1995-08-30 |
| CN1037700C true CN1037700C (en) | 1998-03-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN94102515A Expired - Fee Related CN1037700C (en) | 1994-02-25 | 1994-02-25 | Hot-rolled steel sheet with superior uniform elongation after cold working and production process thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100392131C (en) * | 2003-09-24 | 2008-06-04 | 新日本制铁株式会社 | Hot-rolled steel sheet for processing and manufacturing method thereof |
| CN100400679C (en) * | 2004-02-19 | 2008-07-09 | 住友金属工业株式会社 | High-strength non-quenched and tempered seamless steel pipe and its manufacturing method |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100434560C (en) * | 2006-12-26 | 2008-11-19 | 宋立华 | Following steering axle for air suspension of automobile |
| CN102021493A (en) * | 2009-09-21 | 2011-04-20 | 宝山钢铁股份有限公司 | Hot rolled steel plate for precision stamping and manufacturing method thereof |
| CN105734422B (en) * | 2016-03-24 | 2018-06-05 | 攀钢集团攀枝花钢铁研究院有限公司 | The production method of the effective hot rolled strip of cold rolling thin-walled |
| CN107304458B (en) * | 2016-04-21 | 2019-06-25 | 北大方正集团有限公司 | A kind of hot-rolled steel and its manufacturing method, mooring cable and its manufacturing method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02267222A (en) * | 1989-04-10 | 1990-11-01 | Nippon Steel Corp | Production of thick hot-rolled dual phase-type high tensile steel plate having low yield ratio |
-
1994
- 1994-02-25 CN CN94102515A patent/CN1037700C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02267222A (en) * | 1989-04-10 | 1990-11-01 | Nippon Steel Corp | Production of thick hot-rolled dual phase-type high tensile steel plate having low yield ratio |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100392131C (en) * | 2003-09-24 | 2008-06-04 | 新日本制铁株式会社 | Hot-rolled steel sheet for processing and manufacturing method thereof |
| CN100400679C (en) * | 2004-02-19 | 2008-07-09 | 住友金属工业株式会社 | High-strength non-quenched and tempered seamless steel pipe and its manufacturing method |
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| Publication number | Publication date |
|---|---|
| CN1107521A (en) | 1995-08-30 |
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