CN103748263B - Deposition system with access gate and related method - Google Patents
Deposition system with access gate and related method Download PDFInfo
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- CN103748263B CN103748263B CN201280040887.6A CN201280040887A CN103748263B CN 103748263 B CN103748263 B CN 103748263B CN 201280040887 A CN201280040887 A CN 201280040887A CN 103748263 B CN103748263 B CN 103748263B
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- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
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- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
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- C30B25/00—Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
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Abstract
Description
技术领域technical field
本发明的实施方式总体涉及用于在基板上沉积材料的系统,并且涉及制造及使用这种系统的方法。更具体地说,本发明的实施方式涉及用于在基板上沉积III-V半导体材料的原子层沉积(ALD)法,并且涉及制造及使用这种系统的方法。Embodiments of the invention generally relate to systems for depositing materials on substrates, and to methods of making and using such systems. More specifically, embodiments of the invention relate to atomic layer deposition (ALD) methods for depositing III-V semiconductor materials on substrates, and to methods of making and using such systems.
背景技术Background technique
化学气相沉积(CVD)是一种用于在基板上沉积固体材料的化学工艺,并且通常被应用于半导体装置的制造过程中。在化学气相沉积过程中,基板暴露于一种或多种反应气体,该反应气体以使固体材料在基板的表面上沉积的方式反应、分解,或者既反应又分解。Chemical vapor deposition (CVD) is a chemical process for depositing solid materials on substrates and is commonly used in the fabrication of semiconductor devices. During chemical vapor deposition, a substrate is exposed to one or more reactive gases that react, decompose, or both react and decompose in such a way that solid materials are deposited on the surface of the substrate.
CVD工艺的一种具体类型在本技术领域中被称作气相外延(VPE)。在VPE工艺中,基板在反应室中暴露于一种或多种反应蒸气,该反应蒸气以使固体材料在基板的表面上外延性沉积的方式反应、分解,或者既反应又分解。VPE工艺常用于使III-V半导体材料沉积。当VPE工艺中的一种反应蒸气包括氢化物蒸气时,该工艺可被称作氢化物气相外延(HVPE)工艺。One specific type of CVD process is known in the art as vapor phase epitaxy (VPE). In a VPE process, a substrate is exposed in a reaction chamber to one or more reactive vapors that react, decompose, or both react and decompose in such a manner as to epitaxially deposit solid material on the surface of the substrate. VPE processes are commonly used to deposit III-V semiconductor materials. When one of the reactive vapors in a VPE process includes hydride vapor, the process may be referred to as a hydride vapor phase epitaxy (HVPE) process.
HVPE工艺用于形成诸如例如氮化镓(GaN)之类的III-V半导体材料。在这些工艺中,GaN在基板上的外延性生长是由氯化镓(GaCl)与氨(NH3)之间形成的蒸气相反应引起的,该蒸气相反应在反应室内以大约500℃与大约1000℃之间的高温进行。NH3可由标准NH3气体源供给。The HVPE process is used to form III-V semiconductor materials such as gallium nitride (GaN), for example. In these processes, the epitaxial growth of GaN on the substrate is caused by the vapor phase reaction formed between gallium chloride (GaCl) and ammonia (NH 3 ) in the reaction chamber at about 500°C and about High temperature between 1000°C. NH 3 can be supplied by a standard NH 3 gas source.
在一些方法中,通过使氯化氢(HCl)气体(可由标准HCl气体源供给)经过加热的液体镓(Ga)以在反应室内就地形成GaCl而提供GaCl蒸气。可将液体镓加热至大约750℃与大约850℃之间的温度。GaCl与NH3可被送往加热的基板表面(例如,位于其上方),所述基板诸如半导体材料的晶片。2001年1月30日公布的Solomon等人的美国专利6,179,913号公报公开了一种用于这种系统与方法的气体注入系统,该专利的全部公开内容通过援引结合于此。In some methods, GaCl vapor is provided by passing hydrogen chloride (HCl) gas (which may be supplied by a standard HCl gas source) over heated liquid gallium (Ga) to form GaCl in situ within the reaction chamber. The liquid gallium may be heated to a temperature between about 750°C and about 850°C. The GaCl and NH 3 may be delivered to (eg, over) a heated substrate surface, such as a wafer of semiconductor material. A gas injection system for such systems and methods is disclosed in US Patent No. 6,179,913 to Solomon et al., issued January 30, 2001, the entire disclosure of which is incorporated herein by reference.
在这样的系统中,可能需要向使反应室通向大气以补充液体镓的来源。而且,在这些系统中不可能就地清扫反应室。In such systems, it may be necessary to vent the reaction chamber to atmosphere to replenish the source of liquid gallium. Furthermore, it is not possible to clean the reaction chamber in situ in these systems.
为了解决这些问题,已经开发了利用被直接注入到反应室内的GaCl3前体的外部来源的方法与系统。这种方法与系统的示例被公开在例如以Arena等人的名义于2009年9月10日公布的公开号为US2009/0223442A1的美国专利申请中,该公告的全部公开内容通过援引结合于此。To address these issues, methods and systems have been developed that utilize an external source of GaCl3 precursor that is injected directly into the reaction chamber. Examples of such methods and systems are disclosed, for example, in US Patent Application Publication No. US2009/0223442A1 published September 10, 2009 in the name of Arena et al., the entire disclosure of which publication is hereby incorporated by reference.
先前公知的沉积系统通常包括存取闸,工件基板可穿过该存取闸被装载到反应室内并且加工后被卸载出反应室。这种存取闸通常定位在沉积系统的前部气体注入歧管中,该气体注入歧管用于将前驱气体注入到反应室内。Previously known deposition systems typically include access gates through which workpiece substrates can be loaded into the reaction chamber and unloaded out of the reaction chamber after processing. Such access gates are typically located in the deposition system's frontal gas injection manifold, which is used to inject precursor gases into the reaction chamber.
发明内容Contents of the invention
提供发明内容部分是为了以简化形式介绍精选的发明思想,在本发明的示例性实施方式的以下详细描述中会进一步描述这些思想。该发明内容部分并非要限定所要保护的主旨的主要特征或必要特征,也不是要用来限定所要保护的主旨的范围。This Summary section is provided to introduce a selection of inventive concepts in a simplified form that are further described below in the following detailed description of the exemplary embodiments of the invention. This summary of the invention is not intended to limit the main or essential features of the subject matter to be protected, nor is it intended to limit the scope of the subject matter to be protected.
在一些实施方式中,本公开包括沉积系统,其包括反应室以及至少局部布置在反应室内并且构造成支撑反应室内的工件基板的基板支撑结构。反应室可由顶壁、底壁以及至少一个侧壁限定。所述系统还包括:用于将包括至少一种前驱气体的一种或多种工艺气体在第一位置注入到反应室内的至少一个气体注入装置;以及真空装置,该真空装置用于将穿过反应室的所述一种或多种工艺气体从第一位置抽至第二位置,并且用于在第二位置将所述一种或多种工艺气体从反应室排出。该系统还包括至少一个存取闸,工件基板可穿过该存取闸被装载到反应室内并装载到基板支撑结构上,以及从基板支撑结构被卸载出反应室。所述至少一个存取闸远离所述至少一个气体注入装置将一种或多种工艺气体注入到反应室内的第一位置定位。In some embodiments, the present disclosure includes a deposition system that includes a reaction chamber and a substrate support structure at least partially disposed within the reaction chamber and configured to support a workpiece substrate within the reaction chamber. The reaction chamber may be defined by a top wall, a bottom wall and at least one side wall. The system also includes: at least one gas injection device for injecting one or more process gases including at least one precursor gas into the reaction chamber at a first location; and a vacuum device for injecting The one or more process gases of the reaction chamber are pumped from the first location to the second location and used to exhaust the one or more process gases from the reaction chamber at the second location. The system also includes at least one access gate through which the workpiece substrate can be loaded into the reaction chamber and onto the substrate support structure, and unloaded from the substrate support structure out of the reaction chamber. The at least one access gate is located remote from a first location where the at least one gas injection device injects one or more process gases into the reaction chamber.
在另外的实施方式中,本公开包括利用沉积系统在工件基板上沉积半导体材料的方法。根据这些方法,可穿过至少一个存取闸将工件基板装载至反应室内并装载到基板支撑结构上。可使一种或多种工艺气体通过远离所述至少一个存取闸定位的至少一个气体注入装置流至所述反应室内。所述一种或多种工艺气体可包括至少一种前驱气体。可将所述一种或多种工艺气体通过至少一个真空装置从所述反应室排出,所述真空装置定位在所述基板支撑结构的与所述至少一个气体注入装置相反的一侧上。当所述一种或多种工艺气体从所述至少一个气体注入装置流向所述至少一个真空装置时,可使所述工件基板的表面暴露于所述一种或多种工艺气体,从而可在所述工件基板的该表面上沉积半导体材料。可穿过所述至少一个存取闸将所述工件基板从所述反应室卸载出。In additional embodiments, the present disclosure includes methods of depositing semiconductor material on a workpiece substrate using a deposition system. According to these methods, a workpiece substrate may be loaded into the reaction chamber through at least one access gate and onto the substrate support structure. One or more process gases may be flowed into the reaction chamber through at least one gas injection device located remotely from the at least one access gate. The one or more process gases may include at least one precursor gas. The one or more process gases may be exhausted from the reaction chamber by at least one vacuum device positioned on an opposite side of the substrate support structure from the at least one gas injection device. When the one or more process gases flow from the at least one gas injection device to the at least one vacuum device, the surface of the workpiece substrate can be exposed to the one or more process gases, so that the A semiconductor material is deposited on the surface of the workpiece substrate. The workpiece substrate can be unloaded from the reaction chamber through the at least one access gate.
在再一实施方式中,本公开包括制造沉积系统的方法。例如,可形成包括顶壁、底壁及至少一个侧壁的反应室。可将用于支撑至少一个工件基板的基板支撑结构至少局部设置在反应室内。可将至少一个气体注入装置在第一位置联接至反应室。该至少一个气体注入装置可被构造成用于将包括至少一种前驱气体的一种或多种工艺气体在第一位置注入到反应室内。可将至少一个真空装置在第二位置联接至反应室。该至少一个真空装置可构造成用于将穿过反应室的该一种或多种工艺气体从第一位置抽到第二位置,并且用于在第二位置将该一种或多种工艺气体从反应室排出。可将至少一个存取闸在远离第一位置的位置联接至反应室。该至少一个存取闸可构造成能够使工件基板穿过该至少一个存取闸被装载到反应室内并装载到基板支撑结构上,以及从基板支撑结构被卸载出反应室。In yet another embodiment, the present disclosure includes a method of making a deposition system. For example, a reaction chamber can be formed that includes a top wall, a bottom wall, and at least one side wall. A substrate support structure for supporting at least one workpiece substrate may be disposed at least partially within the reaction chamber. At least one gas injection device may be coupled to the reaction chamber at a first location. The at least one gas injection device may be configured to inject one or more process gases including at least one precursor gas into the reaction chamber at a first location. At least one vacuum device can be coupled to the reaction chamber at a second location. The at least one vacuum device may be configured for pumping the one or more process gases through the reaction chamber from a first location to a second location, and for pumping the one or more process gases at the second location. Exhausted from the reaction chamber. At least one access gate may be coupled to the reaction chamber at a location remote from the first location. The at least one access gate may be configured to enable the workpiece substrate to be loaded into the reaction chamber and onto the substrate support structure through the at least one access gate, and to be unloaded from the substrate support structure out of the reaction chamber.
附图说明Description of drawings
参照附图中示出的示例性实施方式的以下详细说明会充分理解本公开,在附图中:The present disclosure will be best understood by reference to the following detailed description of exemplary embodiments illustrated in the accompanying drawings, in which:
图1是示意性示出沉积系统的一个示例性实施方式的剖切立体图,该沉积系统包括存取闸,穿过该存取闸可将工件基板插入反应室内并且可从反应室移出,该存取闸定位在远离工艺气体被注入反应室内的位置;1 is a cut-away perspective view schematically illustrating an exemplary embodiment of a deposition system including an access gate through which a workpiece substrate can be inserted into and removed from a reaction chamber, the access gate The gate is positioned away from where the process gas is injected into the reaction chamber;
图2是图1的沉积系统的气体注入装置的前外表面的立体图;2 is a perspective view of the front exterior surface of the gas injection device of the deposition system of FIG. 1;
图3是图1的沉积系统的内置前驱气体炉的剖面侧视图;3 is a cross-sectional side view of a built-in precursor gas furnace of the deposition system of FIG. 1;
图4是图1与图2的前驱气体炉的大致平板形结构之一的俯视图;4 is a top view of one of the generally planar structures of the precursor gas furnaces of FIGS. 1 and 2;
图5是图1的沉积系统的内置前驱气体炉的立体图;5 is a perspective view of a built-in precursor gas furnace of the deposition system of FIG. 1;
图6是示意性示出沉积系统的另一示例性实施方式的剖切立体图,该沉积系统包括在远离工艺气体被注入反应室内的位置定位的存取闸,但包括替代内置前驱气体炉的外置前驱气体注入器;6 is a cut-away perspective view schematically illustrating another exemplary embodiment of a deposition system including an access gate located away from the location where process gases are injected into the reaction chamber, but including an external furnace instead of a built-in precursor gas furnace. Precursor gas injector;
图7是示意性示出本公开的沉积系统的另一示例性实施方式的俯视图,该沉积系统包括在远离工艺气体被注入反应室内的位置定位的存取闸;以及7 is a top view schematically illustrating another exemplary embodiment of a deposition system of the present disclosure including an access gate positioned away from where process gases are injected into the reaction chamber; and
图8是示意性示出沉积系统的另一示例性实施方式的剖切立体图,该沉积系统包括在远离工艺气体被注入反应室内的位置定位的存取闸,其中,所述反应室中包括不止一个气流通道。8 is a cut-away perspective view schematically illustrating another exemplary embodiment of a deposition system including an access gate positioned away from where process gases are injected into a reaction chamber comprising more than an airflow channel.
具体实施方式detailed description
在此呈现的图示并非任一具体系统、元件或者装置的实际视图,而仅仅是用于说明本发明的实施方式的理想化的代表。The diagrams presented here are not actual views of any particular system, element, or device, but are merely idealized representations used to illustrate embodiments of the invention.
本文所用的术语“III-V半导体材料”意指并且包括至少主要由来自元素周期表IIIA族(B、Al、In及Ti)的一个或多个元素及来自元素周期表VA族(N、P、As、Sb及Bi)的一个或多个元素组成的任一半导体材料。例如,III-V半导体材料包括GaN、GaP、GaAs、InN、InP、InAs、AIN、AIP、AlAs、InGaN、InGaP、InGaNP等,但不限于此。The term "III-V semiconductor material" as used herein means and includes at least one or more elements from Group IIIA (B, Al, In, and Ti) of the Periodic Table of the Elements and Group VA (N, P) of the Periodic Table of the Elements. , As, Sb and Bi) any semiconductor material composed of one or more elements. For example, III-V semiconductor materials include GaN, GaP, GaAs, InN, InP, InAs, AlN, AlP, AlAs, InGaN, InGaP, InGaNP, etc., but are not limited thereto.
如上述美国专利申请US2009/0223442Al号公报公开的那些气体注入器一样,近来改进的气体注入器已被开发用于利用注入到反应室内的GaCl3前体的外部源的方法及系统。这种气体注入器的示例被公开在例如以Arena等人的名义于2009年3月3日提交的申请号为61/157,112的美国专利申请中,该专利申请的全部公开内容通过援引结合于此。本文所用的术语“气体”包括气体(无独立形状与体积的流体)与蒸气(包括弥散的液体或悬浮于其中的固体物质的气体),术语“气体”与“蒸气”在此作同义词用。Recently improved gas injectors, like those disclosed in the aforementioned US Patent Application Publication No. US2009/0223442A1, have been developed for methods and systems utilizing an external source of GaCl3 precursor injected into the reaction chamber. Examples of such gas injectors are disclosed, for example, in U.S. Patent Application No. 61/157,112, filed March 3, 2009, in the name of Arena et al., the entire disclosure of which is hereby incorporated by reference. . The term "gas" as used herein includes gases (fluids without separate shape and volume) and vapors (gases including liquids dispersed or solid substances suspended therein), and the terms "gas" and "vapor" are used synonymously herein.
本发明的实施方式包括沉积系统以及沉积系统的利用,该沉积系统包括存取闸,该存取闸用于将工件基板装载到反应室内,并且/或者从反应室卸载工件基板。存取闸布置在远离一种或多种工艺气体被注入到反应室内的位置,该工艺气体可包括一种或多种前驱气体。Embodiments of the invention include deposition systems and the use of deposition systems that include access gates for loading workpiece substrates into and/or unloading workpiece substrates from a reaction chamber. The access gate is positioned remotely from where one or more process gases, which may include one or more precursor gases, are injected into the reaction chamber.
图1示出了沉积系统100,该沉积系统包括至少基本封闭的反应室102。在若干实施方式中,沉积系统100可包括CVD系统,并且可包括VPE沉积系统(例如HVPE沉积系统)。FIG. 1 shows a deposition system 100 comprising an at least substantially closed reaction chamber 102 . In several implementations, the deposition system 100 may include a CVD system, and may include a VPE deposition system (eg, a HVPE deposition system).
反应室102可由顶壁104、底壁106以及一个或多个侧壁限定。一个或多个侧壁可由沉积系统的子组件的一个部件或者多个部件限定。例如,第一侧壁108A可包括用于将一种或多种工艺气体注入到反应室102内的气体注入装置110的部件,并且第二侧壁108B可包括不但用于将工艺气体从反应室102排出而且用于将基板装载到反应室102内并将基板从反应室102卸载的排放及装载子组件112的部件。换言之,气体注入装置110可构造成穿过反应室102的侧壁108A注入一种或多种工艺气体。The reaction chamber 102 may be defined by a top wall 104, a bottom wall 106, and one or more side walls. One or more sidewalls may be defined by a component or components of a subassembly of the deposition system. For example, first sidewall 108A may include components of gas injection device 110 for injecting one or more process gases into reaction chamber 102, and second sidewall 108B may include components for injecting process gases from the reaction chamber 102 discharge and components of a discharge and loading subassembly 112 for loading substrates into and unloading substrates from the reaction chamber 102 . In other words, the gas injection device 110 may be configured to inject one or more process gases through the sidewall 108A of the reaction chamber 102 .
在若干实施方式中,如图1中所示,反应室102可呈细长的长方柱的几何形状。在若干这样的实施方式中,气体注入装置110可位于反应室102的第一端,并且排放及装载子组件可位于反应室102的相反的第二端。在其它实施方式中,反应室102可呈另一几何形状。In several embodiments, as shown in FIG. 1 , reaction chamber 102 may have the geometry of an elongated rectangular column. In several such embodiments, the gas injection device 110 may be located at a first end of the reaction chamber 102 and the discharge and loading subassembly may be located at an opposite second end of the reaction chamber 102 . In other embodiments, reaction chamber 102 may have another geometry.
沉积系统100包括构造成支撑一个或多个工件基板116的基板支撑结构114(例如承载器),期望在沉积系统100内在工件基板116上沉积或者以其它方式提供半导体材料。例如,工件基板116可包括模具或晶片。沉积系统100还包括加热元件118,该加热元件可用于选择性地加热沉积系统100,使得在沉积过程中反应室102内的平均温度可被控制在期望的高温内。加热元件118可包括例如电阻加热元件或者辐射加热元件(例如加热灯)。Deposition system 100 includes a substrate support structure 114 (eg, a carrier) configured to support one or more workpiece substrates 116 on which semiconductor material is desired to be deposited or otherwise provided within deposition system 100 . For example, workpiece substrate 116 may include a mold or a wafer. The deposition system 100 also includes a heating element 118 that can be used to selectively heat the deposition system 100 such that the average temperature within the reaction chamber 102 can be controlled within a desired elevated temperature during the deposition process. Heating element 118 may include, for example, a resistive heating element or a radiant heating element such as a heat lamp.
如图1中所示,基板支撑结构114可联接至心轴119,该心轴可联接(例如:直接结构联接、磁性联接等)至诸如电动马达之类的驱动装置(未示出),该驱动装置构造成驱动心轴119旋转,从而基板支撑结构114在反应室102内旋转。As shown in FIG. 1 , the substrate support structure 114 may be coupled to a spindle 119 which may be coupled (eg, direct structural coupling, magnetic coupling, etc.) to a drive device (not shown), such as an electric motor, which The drive arrangement is configured to drive the spindle 119 in rotation so that the substrate support structure 114 rotates within the reaction chamber 102 .
在若干实施方式中,顶壁104、底壁106、基板支撑结构114、心轴119以及反应室102内的任何其它部件中的一者或多者可至少基本由耐火陶瓷材料构成,诸如陶瓷氧化物(例如二氧化硅(石英)、氧化铝、氧化锆等)、碳化物(例如碳化硅、碳化硼等)、氮化物(例如氮化硅、氮化硼等)或者覆有碳化硅的石墨。就非限制性的实施例而言,顶壁104、底壁106、基板支撑结构114以及心轴119可包括透明石英,以便使加热元件18辐射的热能够从其穿过而加热反应室102内的工艺气体。In several embodiments, one or more of the top wall 104, bottom wall 106, substrate support structure 114, mandrel 119, and any other components within the reaction chamber 102 may be at least substantially composed of a refractory ceramic material, such as a ceramic oxide Substances (such as silicon dioxide (quartz), alumina, zirconia, etc.), carbides (such as silicon carbide, boron carbide, etc.), nitrides (such as silicon nitride, boron nitride, etc.) or graphite coated with silicon carbide . By way of non-limiting example, the top wall 104, bottom wall 106, substrate support structure 114, and mandrel 119 may comprise clear quartz to allow heat radiated by the heating element 18 to pass therethrough to heat the interior of the reaction chamber 102. of process gases.
沉积系统100还包括用于使工艺气体流动穿过反应室102的气体流动系统。例如,沉积系统100可包括:用于将一种或多种工艺气体在第一位置103A注入到反应室102内的至少一个气体注入装置110;以及真空装置113,该真空装置用于将穿过反应室102的该一种或多种工艺气体从第一位置103A抽至第二位置103B,并且用于在第二位置103B将该一种或多种工艺气体从反应室102排出。气体注入装置110可包括例如包括连接器的气体注入歧管,该气体注入歧管构造成与从工艺气体源装载一种或多种工艺气体的导管联接。The deposition system 100 also includes a gas flow system for flowing process gases through the reaction chamber 102 . For example, the deposition system 100 may include: at least one gas injection device 110 for injecting one or more process gases into the reaction chamber 102 at the first location 103A; The one or more process gases of the reaction chamber 102 are pumped from the first location 103A to the second location 103B and used to exhaust the one or more process gases from the reaction chamber 102 at the second location 103B. The gas injection device 110 may include, for example, a gas injection manifold including a connector configured to couple with a conduit charged with one or more process gases from a process gas source.
继续参照图1,沉积系统100可包括从相应的工艺气体源122A至122E装载气体至气体注入装置110的五个气体流入导管120A至120E。可选的是,气体阀(121A至121E)可用于选择性地分别控制通过气体流入导管120A至120E的气体流。With continued reference to FIG. 1 , the deposition system 100 may include five gas inflow conduits 120A to 120E loaded with gas from respective process gas sources 122A to 122E to the gas injection device 110 . Optionally, gas valves (121A-121E) may be used to selectively control gas flow through gas inflow conduits 120A-120E, respectively.
在若干实施方式中,如美国专利申请US2009/0223442Al号公报中所描述的,气体源122A至122E中至少其一可包括GaCl3、InCl3或者AlCl3中至少其一的外部源。GaCl3、InCl3与AlCl3可以分别以例如Ga2Cl6、In2Cl6与Al2Cl6之类的二聚物的形式存在。这样,气体源122A至122F中至少其一可包括诸如Ga2Cl6、In2Cl6或者Al2Cl6之类的二聚物。In several embodiments, at least one of the gas sources 122A-122E may include an external source of at least one of GaCl 3 , InCl 3 , or AlCl 3 , as described in US Patent Application Publication No. US2009/0223442A1. GaCl 3 , InCl 3 and AlCl 3 may exist in the form of dimers such as Ga 2 Cl 6 , In 2 Cl 6 and Al 2 Cl 6 , respectively. As such, at least one of the gas sources 122A-122F may include a dimer such as Ga 2 Cl 6 , In 2 Cl 6 , or Al 2 Cl 6 .
在气体源122A至122E中的一个或多个是或者包括GaCl3源的实施方式中,GaCl3源可包括维持在至少100℃(例如大约130℃)的温度下的液体GaCl3容器,并且可包括用于提高液体GaCl3的蒸发率的物理机构。这些物理机构可例如包括:构造成搅动液体GaCl3的装置;构造成喷洒液体GaCl3的装置;构造成使载料气体快速流经液体GaCl3的装置;构造成使载料气体穿过液体GaCl3而沸腾的装置;构造成使液体GaCl3超声散开的诸如压电装置之类的装置等。作为非限制性实施例,在液体GaCl3维持在至少100℃的温度下时,诸如He、N2、H2或者Ar之类的载料气体可穿过液体GaCl3而沸腾,使得源气体可包括一种或多种运送有前驱气体的载料气体。In embodiments where one or more of the gas sources 122A - 122E is or includes a GaCl source, the GaCl source may comprise a liquid GaCl container maintained at a temperature of at least 100°C (eg, about 130°C ) , and may A physical mechanism for increasing the evaporation rate of liquid GaCl3 is included. These physical mechanisms may include, for example: a device configured to agitate the liquid GaCl ; a device configured to spray the liquid GaCl ; a device configured to rapidly flow a carrier gas through the liquid GaCl ; a device configured to pass a carrier gas through the liquid GaCl 3 and boiling devices; devices such as piezoelectric devices configured to ultrasonically disperse liquid GaCl 3 , etc. As a non-limiting example, while the liquid GaCl is maintained at a temperature of at least 100°C, a carrier gas such as He, N2 , H2 , or Ar can be boiled through the liquid GaCl so that the source gas can Include one or more carrier gases delivered with a precursor gas.
在本发明的若干实施方式中,可控制通过气体流入导管120A至120E的一个或多个前驱气体(例如GaCl3)蒸气的流量。例如,在载料气体穿过液体GaCl3而沸腾的实施方式中,来自气体源122A至122E的GaCl3的流量取决于一种或多种因素,这些因素包括例如GaCl3的温度、GaCl3的压力以及穿过GaCl3而沸腾的载料气体的流动。尽管可主要借助任一这些参数控制GaCl3的质量流量,但是在若干实施方式中,可通过利用质量流控制器变更载料气体的流动而控制GaCl3的质量流量。In several embodiments of the invention, the flow rate of one or more precursor gas (eg, GaCl 3 ) vapors through gas inflow conduits 120A-120E may be controlled. For example, in embodiments where the carrier gas is boiled through liquid GaCl 3 , the flow rate of GaCl 3 from gas sources 122A-122E depends on one or more factors including, for example, the temperature of GaCl 3 , the temperature of GaCl 3 Pressure and flow of carrier gas boiling through GaCl3 . Although the mass flow of GaCl3 can be controlled primarily by means of any of these parameters, in several embodiments, the mass flow of GaCl3 can be controlled by altering the flow of the carrier gas using a mass flow controller.
在若干实施方式中,气体源122A至122E中的所述一个或多个能够保持大约25kg或更多的GaCl3、大约35kg或更多的GaCl3、或者甚至大约50kg或更多的GaCl3。例如,GaCl3源能够保持大约50kg与100kg之间(例如大约60kg与70kg之间)的GaCl3。而且,多个GaCl3源可利用歧管连接在一起以形成气体源122A至122E中的单个气体源,以允许在不干扰沉积系统100的运行以及/或者使用的情况下从一个气体源切换到另一气体源。可在沉积系统100保持运行的同时移除腾空的气体源并由新充满的气体源替代。In several embodiments, the one or more of gas sources 122A-122E is capable of holding about 25 kg or more GaCl 3 , about 35 kg or more GaCl 3 , or even about 50 kg or more GaCl 3 . For example, the GaCl 3 source can hold between about 50 kg and 100 kg (eg, between about 60 kg and 70 kg) of GaCl 3 . Also, multiple GaCl sources may be manifolded together to form a single gas source in gas sources 122A-122E, allowing switching from one gas source to another without interfering with the operation and/or use of deposition system 100. Another gas source. The emptied gas source may be removed and replaced with a freshly filled gas source while the deposition system 100 remains in operation.
在若干实施方式中,可控制气体源122A至122E与反应室102之间气体流入导管120A至120E的温度。气体流入导管120A至120E以及相关联的质量流传感器、控制器等的温度可从相应气体源122A至122E的出口的第一温度(例如大约100℃或更高)逐渐增加至刚进入反应室102之处的第二温度(例如大约150℃或更低),以便防止气体流入导管120A至120E中的气体(例如GaCl3蒸气)冷凝。可选的是,相应的气体源122A至122E与反应室102之间的气体流入导管120A至120E的长度可约为三英尺以下,两英尺以下,甚至一英尺以下。可使用一个或多个压力控制系统控制源气体的压力。In several embodiments, the temperature of the gas inflow conduits 120A- 120E between the gas sources 122A- 122E and the reaction chamber 102 can be controlled. The temperature of the gas inflow conduits 120A-120E and associated mass flow sensors, controllers, etc. may be gradually increased from a first temperature (eg, about 100° C. or higher) at the outlet of the respective gas source 122A-122E to just entering the reaction chamber 102 The second temperature (for example, about 150° C. or lower) in order to prevent condensation of the gas (for example, GaCl 3 vapor) flowing into the gas conduits 120A to 120E. Optionally, the gas inflow conduits 120A to 120E between the corresponding gas sources 122A to 122E and the reaction chamber 102 may have a length of less than three feet, less than two feet, or even less than one foot. The pressure of the source gas can be controlled using one or more pressure control systems.
在另外的实施方式中,沉积系统100可包括少于五个(例如一至四个)气体流入导管及各自的气体源,或者沉积系统100可包括多于五个(例如六个、七个等)气体流入导管及各自的气体源。In other embodiments, the deposition system 100 may include fewer than five (eg, one to four) gas inflow conduits and respective gas sources, or the deposition system 100 may include more than five (eg, six, seven, etc.) Gas flows into the conduits and respective gas sources.
气体流入导管120A至120E中的一个或多个延伸至气体注入装置110。气体注入装置110可包括一个或多个材料块,工艺气体通过该材料块被装载到反应室102内。一个或多个冷却导管111可延伸穿过材料块。可使冷却流体流经一个或多个冷却导管111,以便使经由气体流入导管120A至120E而流经气体注入装置110的气体在沉积系统100运行期间维持在期望的温度范围内。例如,可取的是使经由气体流入导管120A至120E而流经气体注入装置110的气体在沉积系统100运行期间维持在小于大约200℃的温度(例如大约150℃)。One or more of the gas inflow conduits 120A to 120E extend to the gas injection device 110 . The gas injection device 110 may include one or more blocks of material through which process gases are loaded into the reaction chamber 102 . One or more cooling conduits 111 may extend through the block of material. A cooling fluid may be flowed through one or more cooling conduits 111 in order to maintain the gas flowing through gas injection device 110 via gas inflow conduits 120A-120E within a desired temperature range during operation of deposition system 100 . For example, it may be desirable to maintain the gas flowing through gas injection device 110 via gas inflow conduits 120A-120E at a temperature of less than about 200° C. (eg, about 150° C.) during operation of deposition system 100 .
图2是示出气体注入装置110的外表面的立体图。如图2中所示,气体注入装置110可包括多个连接器117,这些连接器被构造成用于连接至气体流入导管120A至120E。在若干实施方式中,气体注入装置110可包括连接器117的多个行115A至115E。每行115A至115E可构造成将相应的工艺气体注入到反应室102内。例如,第一底端行115A中的连接器117可用于将吹扫气体注入到反应室102内,第二行115B中的连接器117可用于将前驱气体(例如GaCl3)注入到反应室102内,第三行115C中的连接器117可用于将另一种前驱气体(例如NH3)注入到反应室102内,第四行115D中的连接器117可用于将另一种工艺气体(例如SiH4)注入到反应室102内,并且顶端第五行115E中的连接器117可用于将吹扫气体或载料气体(例如N2)注入到反应室102内。连接器117可被分组成连接器117的分离的区119A至119C,每个区119A至119C包括来自每行115A至115E的连接器117。每个区119A至119C中的连接器117FIG. 2 is a perspective view showing the outer surface of the gas injection device 110 . As shown in FIG. 2 , the gas injection device 110 may include a plurality of connectors 117 configured for connection to the gas inflow conduits 120A to 120E. In several embodiments, the gas injection device 110 may include multiple rows 115A- 115E of connectors 117 . Each row 115A- 115E may be configured to inject a corresponding process gas into the reaction chamber 102 . For example, the connectors 117 in the first bottom row 115A can be used to inject a purge gas into the reaction chamber 102 and the connectors 117 in the second row 115B can be used to inject a precursor gas (eg, GaCl 3 ) into the reaction chamber 102 Inside, the connectors 117 in the third row 115C can be used to inject another precursor gas (such as NH 3 ) into the reaction chamber 102, and the connectors 117 in the fourth row 115D can be used to inject another process gas (such as SiH 4 ) is injected into the reaction chamber 102 , and the connectors 117 in the top fifth row 115E can be used to inject a purge gas or a carrier gas (eg, N 2 ) into the reaction chamber 102 . Connectors 117 may be grouped into separate zones 119A-119C of connectors 117, each zone 119A-119C including connectors 117 from each row 115A-115E. Connector 117 in each zone 119A to 119C
可用于将工艺气体运送至反应室102内不同的区,从而使得不同的工艺气体成分和/或浓缩物被引入到反应室102内工件基板116上方的不同区域中。Can be used to deliver process gases to different regions within the reaction chamber 102 such that different process gas compositions and/or concentrates are introduced into different regions within the reaction chamber 102 above the workpiece substrate 116 .
再次参照图1,排放及装载子组件112可包括真空室184,流经反应室102的气体被真空抽到该真空室内,从反应室102排出。真空室184内的真空由真空装置113造成。如图1中所示,真空室184可位于反应室102之下。Referring again to FIG. 1 , the exhaust and load subassembly 112 may include a vacuum chamber 184 into which gases flowing through the reaction chamber 102 are vacuumed and exhausted from the reaction chamber 102 . The vacuum in the vacuum chamber 184 is created by the vacuum device 113 . As shown in FIG. 1 , a vacuum chamber 184 may be located below the reaction chamber 102 .
排放及装载子组件112还可包括吹扫气体帘装置186,该吹扫气体帘装置构造并取向成提供大体平坦的流动吹扫气体帘,该吹扫气体从吹扫气体帘装置186流出,流到真空室184内。排放及装载子组件112还可包括存取闸188,该存取闸可选择性地打开以用于装载工件基板116并且/或者从基板支撑结构114卸载工件基板116,并且可选择性地闭合以利用沉积系统100处理工件基板116。在若干实施方式中,存取闸188可包括构造成在闭合的第一位置与开放的第二位置之间移动的至少一个板。存取闸188可延伸穿过反应室102的侧壁,该侧壁远离注入一种或多种工艺气体所穿过的侧壁。The discharge and loading subassembly 112 may also include a purge gas curtain arrangement 186 configured and oriented to provide a generally flat curtain of flow purge gas from which the purge gas exits the purge gas curtain arrangement 186 to flow into the vacuum chamber 184. The discharge and loading subassembly 112 may also include an access gate 188 that is selectively openable for loading the workpiece substrate 116 and/or unloading the workpiece substrate 116 from the substrate support structure 114 and is selectively closed for A workpiece substrate 116 is processed using the deposition system 100 . In several embodiments, the access gate 188 can include at least one plate configured to move between a closed first position and an open second position. The access gate 188 may extend through a sidewall of the reaction chamber 102 away from the sidewall through which the one or more process gases are injected.
当存取闸188的板在闭合的第一位置时,反应室102可是至少基本闭合的,会禁止穿过存取闸188接近基板支撑结构114。当存取闸188的板在开放的第二位置时,能够穿过存取闸188接近基板支撑结构114。When the plates of the access gate 188 are in the closed first position, the reaction chamber 102 may be at least substantially closed, and access to the substrate support structure 114 through the access gate 188 may be prohibited. The substrate support structure 114 is accessible through the access gate 188 when the plate of the access gate 188 is in the open second position.
由吹扫气体帘装置186发出的吹扫气体帘可在装载及/或卸载工件基板116期间减少或阻止气体流出反应室102。The purge gas curtain emitted by the purge gas curtain device 186 may reduce or prevent gas flow out of the reaction chamber 102 during loading and/or unloading of the workpiece substrate 116 .
气态副产物、载料气体及任何过量的前驱气体可通过排放及装载子组件112从反应室102排出。Gaseous byproducts, carrier gas, and any excess precursor gas may be exhausted from reaction chamber 102 through exhaust and loading subassembly 112 .
存取闸188可远离一种或多种工艺气体被注入到反应室102内的第一位置103A定位。在若干实施方式中,如图1中所示,第一位置103A可布置在基板支撑结构114的第一侧上,并且工艺气体被从反应室102排出的第二位置103B可布置在基板支撑结构114的相反的第二侧上。此外,工艺气体被从反应室102排出的第二位置103B可布置在基板支撑结构114与存取闸188之间。如前所述,吹扫气体帘装置186可构造成形成在吹扫气体注入装置与真空装置113之间流动的流动吹扫气体帘。流动吹扫气体帘可布置在基板支撑结构114与存取闸188之间,以便形成使工件基板116与存取闸188分开的流动吹扫气体屏障。当存取闸188开放时,这种流动吹扫气体屏障可减少或防止工艺气体从反应室102逃逸。The access gate 188 may be located remotely from the first location 103A where one or more process gases are injected into the reaction chamber 102 . In several embodiments, as shown in FIG. 1 , a first location 103A may be arranged on a first side of the substrate support structure 114 and a second location 103B where process gases are exhausted from the reaction chamber 102 may be arranged on the substrate support structure. 114 on the second opposite side. Furthermore, a second location 103B where process gases are exhausted from the reaction chamber 102 may be disposed between the substrate support structure 114 and the access gate 188 . As previously mentioned, the purge gas curtain device 186 may be configured to form a curtain of flowing purge gas flowing between the purge gas injection device and the vacuum device 113 . A curtain of flowing purge gas may be disposed between the substrate support structure 114 and the access gate 188 to form a barrier of flowing purge gas separating the workpiece substrate 116 from the access gate 188 . This flow purge gas barrier can reduce or prevent process gases from escaping from the reaction chamber 102 when the access gate 188 is open.
在若干实施方式中,气体注入系统100可包括布置在反应室102内的至少一个内置前驱气体炉130。内置前驱气体炉130可构造成用于加热至少一种前驱气体,并且将反应室102内的该至少一种前驱气体从气体注入装置110运送到最接近基板支撑结构114的位置。In several embodiments, the gas injection system 100 may include at least one built-in precursor gas furnace 130 disposed within the reaction chamber 102 . The built-in precursor gas furnace 130 may be configured to heat and transport at least one precursor gas within the reaction chamber 102 from the gas injection device 110 to a location proximate to the substrate support structure 114 .
图3是图1的前驱气体炉130的剖面侧视图。图1与图2的实施方式的炉130包括附接在一起的五(5)个大致板形结构132A至132E,这些大致板形结构的尺寸和构造设定成在大致板形结构132A至132E之间限定的室中限定延伸穿过炉130的一个或多个前驱气体流动路径。大致板形结构132A至132E可包括例如透明的石英,以便使得由加热元件118发出的辐射能能够穿过结构132A至132E,从而加热炉130中的前驱气体。FIG. 3 is a cross-sectional side view of the precursor furnace 130 of FIG. 1 . The furnace 130 of the embodiment of FIGS. 1 and 2 includes five (5) generally plate-shaped structures 132A- 132E attached together that are sized and configured to operate within the generally plate-shaped structures 132A- 132E One or more precursor gas flow paths extending through the furnace 130 are defined in the chambers defined therebetween. The generally plate-shaped structures 132A-132E may comprise, for example, transparent quartz to allow radiant energy emitted by the heating element 118 to pass through the structures 132A-132E to heat the precursor gases in the furnace 130 .
如图3中所示,第一板形结构132A与第二板形结构132B可联接在一起以在二者之间限定室134。第一板形结构132A上的多个一体的脊形突起136可将室134再分成从室134的入口138延伸至室134的出口140的一个或多个流动路径。As shown in FIG. 3 , the first plate-shaped structure 132A and the second plate-shaped structure 132B may be coupled together to define a chamber 134 therebetween. A plurality of integral ridges 136 on the first plate structure 132A may subdivide the chamber 134 into one or more flow paths extending from the inlet 138 of the chamber 134 to the outlet 140 of the chamber 134 .
图4是第一板形结构132的俯视图,并且示出了其上的脊形突起136及由此限定在室134中的流动路径。如图4中所示,突起136限定延伸穿过炉130(图3)的呈蜿蜒构型的流动路径区段。如图4中所示,突起136可包括交替壁,这些交替壁具有在突起136的侧向端及突起136的中央贯穿突起136的孔138。因此,在此构造中,如图4中所示,气体可接近室134的中央区域进入室134,朝炉130的横向侧横向向外流动,穿过一个突起136的侧端处的孔138返回室134的中央区域,穿过另一个突起136的中央处的另一个孔138。一直重复这种流动形式直到气体从入口138以蜿蜒方式往复流经室134后到达板132A的相反侧。FIG. 4 is a top view of the first plate-like structure 132 and shows the ridges 136 thereon and the flow path defined thereby in the chamber 134 . As shown in FIG. 4 , protrusions 136 define flow path segments that extend through furnace 130 ( FIG. 3 ) in a serpentine configuration. As shown in FIG. 4 , the protrusion 136 may include alternating walls with holes 138 extending through the protrusion 136 at the lateral ends of the protrusion 136 and at the center of the protrusion 136 . Therefore, in this configuration, as shown in FIG. The central area of the chamber 134 passes through another hole 138 in the center of another protrusion 136 . This flow pattern is repeated until the gas reaches the opposite side of plate 132A after reciprocating from inlet 138 through chamber 134 in a serpentine fashion.
借助使一种或多种前驱气体流经延伸穿过炉130的该流动路径区段,可选择性地增长该一种或多种前驱气体在炉130内的停留时间。By flowing the one or more precursor gases through the flow path segment extending through the furnace 130 , the residence time of the one or more precursor gases within the furnace 130 may be selectively increased.
再次参照图1,通往室134的入口138可由例如管状构件142限定。如图1中所示,气体流入导管120A至120E之一,例如气体流入导管120B可延伸至管状构件142并与其联接。可使用诸如聚合物O形环之类的密封构件144形成气体流入导管120B与管状构件142之间的气密密封。管状构件142可包括例如不透明的石英材料,以便防止从加热元件118散发出的热能将密封构件144加热到可能使密封构件144受损的高温。此外,利用通过冷却导管111的冷却流体流使气体注入装置110冷却,这可防止过热导致密封构件144受损。当气体流入导管包括金属或金属合金(例如钢)并且管状构件142包括诸如石英之类的耐高温材料时,通过使密封构件144的温度维持在大约200℃以下,可利用密封构件144维持气体流入导管120A至120E之一与管状构件142之间的充分密封。管状构件142与第一板形结构132A可结合在一起以形成一体的单元式石英体。Referring again to FIG. 1 , the inlet 138 to the chamber 134 may be defined by, for example, a tubular member 142 . As shown in FIG. 1 , one of gas inflow conduits 120A to 120E, such as gas inflow conduit 120B, may extend to and couple to tubular member 142 . A sealing member 144 such as a polymer O-ring may be used to form an airtight seal between the gas inflow conduit 120B and the tubular member 142 . Tubular member 142 may comprise, for example, an opaque quartz material in order to prevent thermal energy emanating from heating element 118 from heating sealing member 144 to high temperatures that could damage sealing member 144 . In addition, cooling the gas injection device 110 with the flow of cooling fluid through the cooling conduit 111 prevents damage to the sealing member 144 due to overheating. When the gas inflow conduit comprises a metal or metal alloy such as steel and the tubular member 142 comprises a high temperature resistant material such as quartz, the sealing member 144 can be utilized to maintain gas inflow by maintaining the temperature of the sealing member 144 below about 200°C A sufficient seal between one of the conduits 120A-120E and the tubular member 142. The tubular member 142 and the first plate-shaped structure 132A may be joined together to form an integrated unitary quartz body.
如图2与图3中所示,板形结构132A、132B可包括互补的密封特征147A、147B(例如脊与相应的凹口),该互补的密封特征绕板形结构132A、132B的周边延伸,并且至少基本不透气地密封板形结构132A、132B之间的室134。因此,室134内的气体被防止侧向流出室134,并被迫使从室134流经出口140(图3)。As shown in FIGS. 2 and 3 , the plate-shaped structures 132A, 132B may include complementary sealing features 147A, 147B (eg, ridges and corresponding notches) that extend around the perimeter of the plate-shaped structures 132A, 132B. , and at least substantially hermetically seal the chamber 134 between the plate-shaped structures 132A, 132B. Accordingly, gas within chamber 134 is prevented from flowing laterally out of chamber 134 and is forced to flow from chamber 134 through outlet 140 ( FIG. 3 ).
可选的是,突起136可构造成高度稍小于第一板形结构132A的突起136开始延伸的表面152与第二板形结构132B的对置表面154的分开距离。因而,可在突起136与第二板形结构132B的表面154之间设置一个小间隙。尽管微量的气体会通过这些间隙泄漏,但是该微量泄漏不会对室134内的前驱气体分子的平均停留时间造成不利影响。通过以此方式构造突起136,可对因形成板形结构132A、132B的制造过程中所用的容差而产生的突起136的高度变化负责,使得不故意而制成高度过高的突起136不会妨碍借助互补的密封特征147A、147B在板形结构132A、132B之间形成充分的密封。Optionally, the protrusion 136 can be configured to have a height slightly smaller than the separation distance between the surface 152 where the protrusion 136 starts to extend of the first plate-shaped structure 132A and the opposite surface 154 of the second plate-shaped structure 132B. Thus, a small gap may be provided between the protrusion 136 and the surface 154 of the second plate-shaped structure 132B. Although small amounts of gas may leak through these gaps, this small amount of leakage does not adversely affect the mean residence time of the precursor gas molecules within chamber 134 . By configuring the protrusions 136 in this manner, variations in the height of the protrusions 136 due to the tolerances used in the manufacturing process used to form the plate-shaped structures 132A, 132B can be accounted for so that inadvertently making the protrusions 136 too high will not Formation of an adequate seal between the plate-shaped structures 132A, 132B by means of the complementary sealing features 147A, 147B is prevented.
如图3中所示,板形结构132A、132B之间的室134的出口140通往第三板形结构132C与第四板形结构132D之间的室150的入口148。室150可构造成其中的气体从入口148朝室150的出口156以大体线性方式流动。例如,室150可在入口148与出口156之间具有大体矩形且尺寸均匀的剖面形状。因而,室150可构造成使气流越加为层流,与湍流相反。As shown in Figure 3, the outlet 140 of the chamber 134 between the plate structures 132A, 132B leads to the inlet 148 of the chamber 150 between the third plate structure 132C and the fourth plate structure 132D. Chamber 150 may be configured such that gas therein flows in a generally linear fashion from inlet 148 toward outlet 156 of chamber 150 . For example, chamber 150 may have a generally rectangular and uniformly sized cross-sectional shape between inlet 148 and outlet 156 . Thus, chamber 150 may be configured such that the airflow is more laminar, as opposed to turbulent.
板形结构132C、132D可包括互补的密封特征158A、158B(例如脊与相应的凹口),该互补的密封特征绕板形结构132C、132D的周边延伸,并且至少基本不透气地密封板形结构132C、132D之间的室150。因此,室150内的气体被防止侧向流出室150,并被迫使从室150流经出口156。The plate-shaped structures 132C, 132D may include complementary sealing features 158A, 158B (eg, ridges and corresponding indentations) that extend around the perimeter of the plate-shaped structures 132C, 132D and at least substantially hermetically seal the plate-shaped structures 132C, 132D. Chamber 150 between structures 132C, 132D. Thus, gas within chamber 150 is prevented from flowing laterally out of chamber 150 and is forced to flow from chamber 150 through outlet 156 .
出口156可包括例如细长的孔(例如狭缝),其邻近与入口148的邻近端相反的一端延伸通过板形结构132D。Outlet 156 may include, for example, an elongated hole (eg, a slit) extending through plate-shaped structure 132D adjacent an end opposite the proximal end of inlet 148 .
继续参照图3,板形结构132C、132D之间的室150的出口156通往第四板形结构132D与第五板形结构132E之间的室162的入口160。室162可构造成其中的气体从入口160朝室162的出口164以大体线性方式流动。例如,室162可在入口160与出口164之间具有大体矩形并且尺寸均匀的剖面形状。因而,以与先前参照室150所述类似的方式,室162可构造成使气流越加为层流,与湍流相反。With continued reference to FIG. 3 , the outlet 156 of the chamber 150 between the plate structures 132C, 132D leads to the inlet 160 of the chamber 162 between the fourth plate structure 132D and the fifth plate structure 132E. Chamber 162 may be configured such that gas therein flows in a generally linear fashion from inlet 160 toward outlet 164 of chamber 162 . For example, chamber 162 may have a generally rectangular and uniformly sized cross-sectional shape between inlet 160 and outlet 164 . Thus, in a manner similar to that previously described with reference to chamber 150, chamber 162 may be configured to make the air flow more laminar, as opposed to turbulent.
板形结构132D、132E可包括互补的密封特征166A、166B(例如,脊与相应的凹口),该互补的密封特征绕板形结构132D、132E的周边的一部分延伸,从而在除板形结构132D、132E一侧以外所有侧上密封板形结构132D、132E之间的室162。在板形结构132D、板形结构132E的与入口160相反的一侧在二者之间设有间隙,该间隙限定室162的出口164。因此,气体通过入口160进入室162,向着出口164流经室162(同时借助互补的密封特征166A、166B防止从室162横向流出),并通过出口164从室162流出。由室150与室162限定的气体流动路径在炉130内的区段构造成将层流赋予被致使流过炉130内的流动路径的所述一种或多种前驱气体,从而减小了其中的任何湍流。The plate-shaped structures 132D, 132E may include complementary sealing features 166A, 166B (e.g., ridges and corresponding notches) that extend around a portion of the perimeter of the plate-shaped structures 132D, 132E such The chamber 162 between the plate-shaped structures 132D, 132E is sealed on all but one side 132D, 132E. On the opposite side of the plate-shaped structure 132D, 132E from the inlet 160 there is a gap between them, which gap defines an outlet 164 of the chamber 162 . Thus, gas enters chamber 162 through inlet 160 , flows through chamber 162 toward outlet 164 (while preventing lateral outflow from chamber 162 by complementary sealing features 166A, 166B ), and exits chamber 162 through outlet 164 . The section of the gas flow path defined by chamber 150 and chamber 162 within furnace 130 is configured to impart laminar flow to the one or more precursor gases caused to flow through the flow path within furnace 130, thereby reducing any turbulent flow.
出口164构造成将一种或多种前驱气体从炉130输出到反应室102内的内部区域中。图5是炉130的立体图,并且示出了出口164。如图5中所示,出口164可具有矩形的剖面形状,该形状可帮助保持从炉130喷出并注入到反应室102内的内部区域中的前驱气体的层流。出口164的尺寸和构造可设定成在横向方向上输出一片流动的前驱气体,越过基板支撑结构114的上表面168。如图5中所示,如先前所述,第四大致板形结构132D与第五大致板形结构132E之间的间隙限定室162的出口164,该第四大致板形结构132D的端面180与该第五大致板形结构132E的端面182可具有与工件基板116的形状大致匹配的形状,该工件基板被支撑在基板支撑结构114上,并且要利用从炉130流出的前驱气体将材料沉积在该工件基板上。例如,在工件基板116包括具有大致圆形边缘的模具或晶片的实施方式中,端面180、182可具有弧形形状,大致匹配处于工艺过程中的工件基板116的外周轮廓。在这种构造中,出口164与工件基板116的外缘之间的距离横过出口164大致恒定。在此构造中,防止从出口164流出的前驱气体与反应室102内的其它前驱气体混合,直到位于工件基板116的待由前驱气体在其上沉积材料的表面附近,从而避免在沉积系统100的部件上不期望的沉积材料。Outlet 164 is configured to output one or more precursor gases from furnace 130 into an interior region within reaction chamber 102 . FIG. 5 is a perspective view of furnace 130 and shows outlet 164 . As shown in FIG. 5 , the outlet 164 may have a rectangular cross-sectional shape, which may help maintain a laminar flow of precursor gases ejected from the furnace 130 and injected into the interior region within the reaction chamber 102 . The outlet 164 may be sized and configured to output a sheet of flowing precursor gas in a lateral direction, across the upper surface 168 of the substrate support structure 114 . As shown in FIG. 5 , the gap between the fourth generally plate-shaped structure 132D and the fifth generally plate-shaped structure 132E defines the outlet 164 of the chamber 162 as previously described, the end surface 180 of the fourth generally plate-shaped structure 132D is in contact with The end face 182 of the fifth substantially plate-shaped structure 132E may have a shape that substantially matches the shape of the workpiece substrate 116 that is supported on the substrate support structure 114 and on which material is to be deposited using precursor gases flowing from the furnace 130. the workpiece substrate. For example, in embodiments where the workpiece substrate 116 includes a mold or wafer with generally rounded edges, the end faces 180, 182 may have an arcuate shape that generally matches the peripheral contour of the workpiece substrate 116 during processing. In this configuration, the distance between the outlet 164 and the outer edge of the workpiece substrate 116 is substantially constant across the outlet 164 . In this configuration, the precursor gas flowing out of outlet 164 is prevented from mixing with other precursor gases within reaction chamber 102 until near the surface of workpiece substrate 116 on which material is to be deposited by the precursor gas, thereby avoiding the Undesired deposited material on the part.
再次参照图1,沉积系统100可包括加热元件118。加热元件118可包括电阻加热器、电感加热器或辐射加热器。在某一实施方式中,加热元件118包括构造成辐射红外能的辐射加热灯。例如,加热元件118可包括加热元件118的第一组加热元件170与第二组加热元件172。加热元件118的第一组加热元件170的位置和构造设定成用于向炉130传递辐射能,从而加热其中的前驱气体。如图1所示,例如加热元件118的第一组加热元件170可位于炉130下方的反应室102之下。在另外的实施方式中,加热元件118的第一组加热元件170可位于炉130上方的反应室102之上,或者可既包括位于炉130下方的反应室102之下的加热元件118又包括位于炉130上方的反应室102之上的加热元件。加热元件118的第二组加热元件172的位置和构造可设定成用于向基板支撑结构114及任何支撑于其上的工件基板传递热能。例如,如图1所示,加热元件118的第二组加热元件172可位于反应室102下方在基板支撑结构114之下。在另外是实施方式中,加热元件118的第二组加热元件172可位于反应室102上方在基板支撑结构114之上,或者可既包括位于反应室102下方在基板支撑结构114之下的加热元件118又包括位于反应室102上方在基板支撑结构114之上的加热元件。Referring again to FIG. 1 , the deposition system 100 may include a heating element 118 . Heating element 118 may comprise a resistive heater, an inductive heater, or a radiant heater. In one embodiment, heating element 118 comprises a radiant heat lamp configured to radiate infrared energy. For example, the heating elements 118 may include a first set of heating elements 170 and a second set of heating elements 172 of the heating elements 118 . A first set of heating elements 170 of heating elements 118 are positioned and configured to deliver radiant energy to furnace 130 to heat the precursor gas therein. As shown in FIG. 1 , a first set of heating elements 170 , such as heating elements 118 , may be located below reaction chamber 102 below furnace 130 . In other embodiments, the first set of heating elements 170 of heating elements 118 may be located above the reaction chamber 102 above the furnace 130, or may include both heating elements 118 located below the reaction chamber 102 below the furnace 130 and the Heating elements above the reaction chamber 102 above the furnace 130 . A second set of heating elements 172 of heating elements 118 may be positioned and configured to deliver thermal energy to substrate support structure 114 and any workpiece substrate supported thereon. For example, as shown in FIG. 1 , a second set of heating elements 172 of heating elements 118 may be positioned below reaction chamber 102 below substrate support structure 114 . In other embodiments, the second set of heating elements 172 of heating elements 118 may be located above the reaction chamber 102 above the substrate support structure 114, or may include both heating elements located below the reaction chamber 102 below the substrate support structure 114. 118 in turn includes a heating element located above the reaction chamber 102 above the substrate support structure 114 .
加热元件118的第一组加热元件170可借助热反射或热绝缘挡板174与加热元件118的第二组加热元件172隔开。以实施例而非限制的方式,这种挡板174可包括位于加热元件118的第一组加热元件170与加热元件118的第二组加热元件172之间的镀金金属板。金属板可定向成使得能够独立控制炉130的加热(借助加热元件118的第一组加热元件170)与基板支撑结构114的加热(借助加热元件118的第二组加热元件172)。换言之,挡板174可定位并定向成减少或防止基板支撑结构114由加热元件118的第一组的加热元件170加热,以及减少或防止炉130由加热元件118的第二组加热元件172加热。A first set of heating elements 170 of heating elements 118 may be separated from a second set of heating elements 172 of heating elements 118 by a heat reflective or thermally insulating barrier 174 . By way of example and not limitation, such baffles 174 may comprise a gold-plated metal plate positioned between a first set of heating elements 170 of heating elements 118 and a second set of heating elements 172 of heating elements 118 . The metal plates may be oriented such that heating of the furnace 130 (by the first set of heating elements 170 of heating elements 118 ) and heating of the substrate support structure 114 (by the second set of heating elements 172 of the heating elements 118 ) can be independently controlled. In other words, baffles 174 may be positioned and oriented to reduce or prevent heating of substrate support structure 114 by first set of heating elements 170 of heating elements 118 and to reduce or prevent heating of furnace 130 by second set of heating elements 172 of heating elements 118 .
加热元件118的第一组的加热元件170可包括多行加热元件118,这些行被相互独立地控制。换言之,由各行加热元件118发出的热量可以是独立可控的。这些行可横向于纯净气流通过反应室102的方向取向,反应室102的方向是从图1的立体图从左向右延伸的方向。因而,如果需要的话,独立控制加热元件118的行可用于提供横过炉130的所选热梯度。类似地,加热元件118的第二组加热元件172也可包括多行加热元件118,这些行可被相互独立地控制。因而,如果需要的话,也可提供横过基板支撑结构114的所选热梯度。The heating elements 170 of the first set of heating elements 118 may include multiple rows of heating elements 118 that are controlled independently of each other. In other words, the heat emitted by each row of heating elements 118 may be independently controllable. The rows may be oriented transverse to the direction of the pure gas flow through the reaction chamber 102 , which is the direction extending from left to right in the perspective view of FIG. 1 . Thus, independently controlled rows of heating elements 118 may be used to provide a selected thermal gradient across furnace 130, if desired. Similarly, the second set of heating elements 172 of heating elements 118 may also include multiple rows of heating elements 118 that may be controlled independently of each other. Thus, a selected thermal gradient across the substrate support structure 114 may also be provided, if desired.
可选的是,被动热传递结构(例如,包括作用与黑体类似的材料的结构)可邻近或靠近反应室102内前驱气体炉130的至少一部分定位以增强传至炉130内的前驱气体的热传递。Optionally, a passive heat transfer structure (e.g., a structure comprising a material that acts like a black body) may be positioned adjacent to or near at least a portion of the precursor gas furnace 130 within the reaction chamber 102 to enhance heat transfer to the precursor gas within the furnace 130. transfer.
可选的是,如例如以Arena等人的名义于2009年8月27日公布的公开号为US2009/0214785A1的美国专利申请中所公开的,可在反应室102内设置被动热传递结构(例如,包括作用与黑体类似的材料的结构),该专利申请的全部公开内容通过援引结合于此。Optionally, passive heat transfer structures (e.g., , including structures that function as materials similar to boldfaces), the entire disclosure of this patent application is hereby incorporated by reference.
以实施例而非限制的方式,如图1中所示,沉积系统100可包括在反应室102内的一个或多个被动传热板177。这些被动传热板177可大致平坦,并且可大致平行于顶壁104与底壁106定向。在若干实施方式中,这些被动传热板177可相比底壁106更接近顶壁104定位,使得这些被动传热板定位在工件基板116在反应室102内的布置平面的竖向上方的平面中。被动传热板177可横跨反应室102内的仅部分空间,如图1中所示,或者其可横跨反应室102内的大致整个空间。在若干实施方式中,可使吹扫气体在反应室102的顶壁104与所述一个或多个被动传热板177之间的空间流过反应室102,以便防止不必要的材料在反应室102内的顶壁104的内表面上沉积。这种吹扫气体可由例如气体流入导管120A供应。当然,在另外的实施方式中,具有除图1的被动传热板177的构造以外的构造的被动传热板也可结合在反应室102内,并且这种被动传热板可定位在除图1的被动传热板177所在的位置以外的位置。By way of example and not limitation, as shown in FIG. 1 , deposition system 100 may include one or more passive heat transfer plates 177 within reaction chamber 102 . The passive heat transfer plates 177 may be generally flat and may be oriented generally parallel to the top wall 104 and the bottom wall 106 . In several embodiments, the passive heat transfer plates 177 may be positioned closer to the top wall 104 than the bottom wall 106 such that the passive heat transfer plates are positioned in a plane vertically above the plane of arrangement of the workpiece substrate 116 within the reaction chamber 102 middle. Passive heat transfer plate 177 may span only a portion of the space within reaction chamber 102 , as shown in FIG. 1 , or it may span substantially the entire space within reaction chamber 102 . In several embodiments, a purge gas may be made to flow through the reaction chamber 102 in the space between the top wall 104 of the reaction chamber 102 and the one or more passive heat transfer plates 177, so as to prevent unwanted material from being trapped in the reaction chamber. Deposited on the inner surface of the top wall 104 inside the 102. Such purge gas may be supplied, for example, by gas inflow conduit 120A. Of course, in other embodiments, a passive heat transfer plate having a configuration other than the configuration of the passive heat transfer plate 177 of FIG. A position other than the position where the passive heat transfer plate 177 of 1 is located.
作为另一个非限制性实施例,如图3中所示,前驱气体炉130可包括被动传热板178,该被动传热板可定位在第二板形结构132B与第三板形结构132C之间。此被动传热板178可增强由加热元件118提供的热至炉130内的前驱气体的热传递,并且可增强炉130内温度的均匀一致性。被动传热板178可包括具有高辐射系数值的材料(接近一致)(黑体材料),该材料也能够耐受在反应室102内可能遭遇的高温、腐蚀性环境。这种材料可包括例如氮化铝(AlN)、碳化硅(SiC)及碳化硼(B4C),其分别具有0.98、0.92及0.92的辐射系数值。因而,被动传热板178可吸收由加热元件118发出的热能,并将该热能重发射到炉130内及其中的前驱气体。As another non-limiting example, as shown in FIG. 3, the precursor gas furnace 130 can include a passive heat transfer plate 178 that can be positioned between the second plate-shaped structure 132B and the third plate-shaped structure 132C. between. This passive heat transfer plate 178 may enhance the heat transfer of the heat provided by the heating element 118 to the precursor gases within the furnace 130 and may enhance the uniformity of temperature within the furnace 130 . The passive heat transfer plate 178 may comprise a material with a high emissivity value (near uniform) (a blackbody material) that is also able to withstand the high temperature, corrosive environment that may be encountered within the reaction chamber 102 . Such materials may include, for example, aluminum nitride (AlN), silicon carbide (SiC), and boron carbide (B 4 C), which have emissivity values of 0.98, 0.92, and 0.92, respectively. Thus, the passive heat transfer plate 178 can absorb thermal energy emitted by the heating element 118 and re-emit that thermal energy into the furnace 130 and the precursor gases therein.
图6是示出类似图1的沉积系统100的沉积系统200的另一实施方式的平面图的示意图,但是该沉积系统包括定位在反应室102的内部区域内的三个前驱气体炉130A、130B、130C。因而,每个前驱气体炉130A、130B、130C可用于将不同的前驱气体注入到反应室102内。以实施例但非限制的方式,前驱气体炉130B可用于将GaCl3注入到反应室102内,前驱气体炉130A可用于将InCl3注入到反应室102内,并且前驱气体炉130B可用于将AlCl3注入到反应室102内。可选的是,可利用前驱气体炉130B将III族元素前驱气体注入到反应室102内以用于沉积III-V半导体材料,并且前驱气体炉130A、130C可用于注入用于使一种或多种掺杂元素沉积到III-V半导体材料内的一种或多种前驱气体。6 is a schematic diagram showing a plan view of another embodiment of a deposition system 200 similar to the deposition system 100 of FIG. 130C. Thus, each precursor gas furnace 130A, 130B, 130C may be used to inject a different precursor gas into the reaction chamber 102 . By way of example and not limitation, precursor gas furnace 130B may be used to inject GaCl into reaction chamber 102, precursor gas furnace 130A may be used to inject InCl into reaction chamber 102, and precursor gas furnace 130B may be used to inject AlCl 3 into the reaction chamber 102. Optionally, Group III element precursor gases may be injected into reaction chamber 102 for deposition of III-V semiconductor materials using precursor gas furnace 130B, and precursor gas furnaces 130A, 130C may be used for injection to make one or more One or more precursor gases that deposit a dopant element into a III-V semiconductor material.
如在此描述的沉积系统的实施方式,例如图1的沉积系统100与图6的沉积系统200,可将相当大量的高温前驱气体引至反应室102内,同时保持前驱气体彼此空间分离,直到气体紧邻材料待沉积的工件基板116定位,这可提高前驱气体的利用效率。Embodiments of deposition systems as described herein, such as deposition system 100 of FIG. 1 and deposition system 200 of FIG. Positioning the gas in close proximity to the workpiece substrate 116 on which the material is to be deposited increases the efficiency of the utilization of the precursor gas.
以前公知的沉积系统(例如HVPE沉积系统)普遍会致使反应产物形成在反应室102内的表面上,而不是在材料待沉积的工件基板116上。久而久之,这种不期望的材料沉积可导致反应室102内的颗粒水平增大,从而连带地降低沉积在工件基板116上的材料的质量并且使借助加热元件118加热反应室102的效率低下。例如,GaCl3在低于500℃的温度下从蒸气相冷凝,并且可在与GaCl3蒸气接触而未保持在高于气化温度的温度下的表面上从GaCl3沉积镓。此外,GaCl3通常在反应室中转化成GaCl,并且Ga从GaCl蒸气沉积。在高于大约730℃的温度下GaCl种比GaCl3种更有利。因而,前驱气体炉130可用于在将前驱气体注入到工件基板116的待被沉积材料的表面上之前,使流经该炉的前驱气体被加热到大约730℃以上的温度。Previously known deposition systems, such as HVPE deposition systems, generally result in reaction products being formed on surfaces within the reaction chamber 102 rather than on the workpiece substrate 116 on which the material is to be deposited. Over time, this undesired deposition of material may lead to increased particle levels within the reaction chamber 102 , thereby concomitantly reducing the quality of material deposited on the workpiece substrate 116 and making heating of the reaction chamber 102 via the heating element 118 inefficient. For example, GaCl3 condenses from the vapor phase at temperatures below 500°C, and gallium can be deposited from GaCl3 on surfaces that are in contact with GaCl3 vapor but not maintained at temperatures above the vaporization temperature. Furthermore, GaCl3 is usually converted to GaCl in the reaction chamber, and Ga is deposited from GaCl vapor. GaCl species are more favorable than GaCl3 species at temperatures above about 730°C. Thus, the precursor gas furnace 130 may be used to heat the precursor gas flowing through the furnace to a temperature above about 730° C. prior to injecting the precursor gas onto the surface of the workpiece substrate 116 of the material to be deposited.
图6是示意性示出沉积系统200的另一示例性实施方式的剖切立体图。沉积系统200类似图1的沉积系统100,并且包括存取闸188(在图6中示出为开放位置),该存取闸远离工艺气体被注入到反应室102内的位置定位。但是,沉积系统200不包括内置前驱气体炉130,而是包括定位在反应室102外部的外置前驱气体注入器230。外置前驱气体注入器230可构造成用于加热至少一种前驱气体,并且将该至少一种前驱气体从前驱气体源运送至气体注入装置210,该气体注入装置可基本与图1的气体注入装置110相同。FIG. 6 is a cutaway perspective view schematically illustrating another exemplary embodiment of a deposition system 200 . Deposition system 200 is similar to deposition system 100 of FIG. 1 and includes access gate 188 (shown in an open position in FIG. 6 ) positioned away from where process gases are injected into reaction chamber 102 . However, instead of a built-in precursor furnace 130 , the deposition system 200 includes an external precursor injector 230 positioned outside the reaction chamber 102 . The external precursor gas injector 230 can be configured to heat at least one precursor gas and deliver the at least one precursor gas from the precursor gas source to the gas injection device 210, which can be substantially the same as the gas injection device of FIG. Device 110 is the same.
以实施例而非限制方式,外置前驱气体注入器230可包括如下任一文献中所述的前驱气体注入器:2010年11月23日递交的名称为“Methods of Forming Bulk III-NitrideMaterials on Metal-Nitride Growth Template Layers,and Structures formed by SuchMethods”,申请号为61/416,525的美国临时专利申请;以Arena等人的名义于2009年9月10日公布的公开号为US2009/0223442A1的美国专利申请;2010年9月10日公布的名称为“Gas Injectors for CVD Systems with the Same”国际公开号为WO2010/101715Al的国际申请;以Bertran的名义于2010年9月30日递交的申请号为12/894,724的美国专利申请;以及以Werkhoven的名义于2010年9月30日递交的申请号为12/895,311的美国专利申请,这些申请的公开内容通过援引完整结合于此。By way of example and not limitation, the external precursor gas injector 230 may include a precursor gas injector described in any of the following documents: "Methods of Forming Bulk III-NitrideMaterials on Metal" filed on November 23, 2010 -Nitride Growth Template Layers, and Structures formed by SuchMethods", U.S. Provisional Patent Application No. 61/416,525; U.S. Patent Application Publication No. US2009/0223442A1 published September 10, 2009 in the name of Arena et al. ; published on September 10, 2010, the international application with the international publication number WO2010/101715Al titled "Gas Injectors for CVD Systems with the Same"; the application number submitted on September 30, 2010 in the name of Bertran is 12/ 894,724; and US Patent Application No. 12/895,311 filed September 30, 2010 in the name of Werkhoven, the disclosures of which are hereby incorporated by reference in their entirety.
气体注入器230可包括热化气体注入器,该热化气体注入器包括细长的导管,该导管可具有螺旋构型、蛇形构型等,在该气体注入器中,流经的所述一种或多种工艺气体(例如前驱气体)在流经细长的导管时被加热。可使用外部加热元件在工艺气体流经细长的导管时加热工艺气体。可选的是,一个或多个被动加热结构(与本文先前所述类似)可结合到气体注入器230内,以增强对流经气体注入器230的工艺气体的加热。The gas injector 230 may comprise a thermalizing gas injector comprising an elongated conduit, which may have a helical configuration, a serpentine configuration, etc., through which the One or more process gases (eg, precursor gases) are heated as they flow through the elongated conduit. An external heating element may be used to heat the process gas as it flows through the elongated conduit. Optionally, one or more passive heating structures (similar to those previously described herein) may be incorporated into the gas injector 230 to enhance heating of the process gas flowing through the gas injector 230 .
可选的是,气体注入器230还可包括构造成保持用于与工艺气体(或者工艺气体的分解物或反应产物)反应的液体试剂的容器。例如,该容器可构造成保持诸如液体镓(Ga)、液体铝(Al)或者液体铟(In)之类的液体金属或其它元素。在本发明的另外实施方式中,该容器可构造成保持用于与工艺气体(或者工艺气体的分解物或反应产物)反应的固体试剂。例如,该容器可构造成保持诸如固体硅(Si)或者固体镁(Mg)之类的一种或多种材料的固态体。Optionally, the gas injector 230 may also include a container configured to hold a liquid reagent for reacting with the process gas (or decomposition or reaction products of the process gas). For example, the vessel may be configured to hold a liquid metal or other element such as liquid gallium (Ga), liquid aluminum (Al), or liquid indium (In). In a further embodiment of the invention, the container may be configured to hold a solid reagent for reaction with the process gas (or decomposition or reaction products of the process gas). For example, the container may be configured to hold a solid body of one or more materials such as solid silicon (Si) or solid magnesium (Mg).
继续参照图6,从外置气体注入器230注入到反应室102内的工艺气体可在罩140内被运送通过反应室102内的内部区域,到达靠近基板支撑结构114的位置,为的是在工艺气体位于支撑在基板支撑结构114上的工件基板116附近之前,避免这种工艺气体与其它工艺气体混合。Continuing to refer to FIG. 6 , the process gas injected from the external gas injector 230 into the reaction chamber 102 may be transported within the hood 140 through the interior region of the reaction chamber 102 to a position near the substrate support structure 114 in order to The process gases are located in the vicinity of the workpiece substrate 116 supported on the substrate support structure 114, preventing such process gases from mixing with other process gases.
在另外的实施方式中,沉积系统既可包括如参照图1所描述的内置前驱气体炉130,又可包括如参照图6所描述的外置气体注入器230。例如,图6中所示的罩240可由图1的内置前驱气体炉130代替。In another embodiment, the deposition system may include both a built-in precursor gas furnace 130 as described with reference to FIG. 1 and an external gas injector 230 as described with reference to FIG. 6 . For example, the hood 240 shown in FIG. 6 may be replaced by the built-in precursor furnace 130 of FIG. 1 .
如图6中所示,反应室102还可包括结构性支撑肋240,该结构性支撑肋可用于向反应室102提供结构性刚度。这种支撑肋240可包括与反应室102的顶壁104与底壁106类似的耐火材料。在另外的实施方式中,图1的反应室102也可包括这种结构性支撑肋240。As shown in FIG. 6 , the reaction chamber 102 may also include structural support ribs 240 that may be used to provide structural rigidity to the reaction chamber 102 . Such support ribs 240 may comprise a refractory material similar to the top wall 104 and bottom wall 106 of the reaction chamber 102 . In other embodiments, the reaction chamber 102 of FIG. 1 may also include such structural support ribs 240 .
图7示意性示出了本公开的附加示例性实施方式的沉积系统300的俯视图。沉积系统300可与图1的沉积系统100或图6的沉积系统200基本相同,只不过存取闸188位于反应室102的横向侧,在纵向上位于反应室102的接近一种或多种工艺气体被注入到反应室102内的位置103A的第一纵向端与反应室102的接近该工艺气体从反应室102被排出的位置103B的第二纵向端之间。换言之,在图7的沉积系统300中,工件基板116可沿与气体流经反应室102的总体方向横交的方向被装载及卸载。因而,如图1与图6的实施方式中的存取闸188一样,存取闸188远离工艺气体被注入到反应室102内的位置103A定位。FIG. 7 schematically illustrates a top view of a deposition system 300 of an additional exemplary embodiment of the present disclosure. The deposition system 300 can be substantially the same as the deposition system 100 of FIG. 1 or the deposition system 200 of FIG. Gas is injected into the reaction chamber 102 between a first longitudinal end at a location 103A and a second longitudinal end of the reaction chamber 102 near a location 103B where the process gas is exhausted from the reaction chamber 102 . In other words, in the deposition system 300 of FIG. 7 , the workpiece substrate 116 may be loaded and unloaded in a direction transverse to the general direction of gas flow through the reaction chamber 102 . Thus, like access gate 188 in the embodiment of FIGS. 1 and 6 , access gate 188 is located away from location 103A where process gas is injected into reaction chamber 102 .
如图7所示,沉积系统300还包括至少一个机器臂装置310,该机器臂装置构造成自动地穿过存取闸188将工件基板116装载到反应室102内,并穿过存取闸188将工件基板116从反应室102卸载出。本领域公知这种机器臂装置。尽管未在图1与图6中示出,图1的沉积系统100与图6的沉积系统200也可包括至少一个这种机器臂装置310,该机器臂装置构造成自动地穿过存取闸188将工件基板116装载到反应室102内,并穿过存取闸188将工件基板116从反应室102卸载出。As shown in FIG. 7 , the deposition system 300 also includes at least one robotic arm assembly 310 configured to automatically load the workpiece substrate 116 into the reaction chamber 102 through the access gate 188 and through the access gate 188 The workpiece substrate 116 is unloaded from the reaction chamber 102 . Such robotic arm arrangements are well known in the art. Although not shown in FIGS. 1 and 6, the deposition system 100 of FIG. 1 and the deposition system 200 of FIG. 6 may also include at least one such robotic arm device 310 configured to automatically pass through the access gate 188 loads workpiece substrate 116 into reaction chamber 102 and unloads workpiece substrate 116 from reaction chamber 102 through access gate 188 .
图8示意性示出了本公开的另一示例性实施方式的沉积系统400的视图。沉积系统400可与图1的沉积系统100或图6的沉积系统200基本相同,只不过反应室102可被分成两个或更多个通道。在若干实施方式中,这两个或更多个通道可竖向叠置。例如,这两个或更多个通道可包括装载/卸载通道402及注入/排出通道404。装载/卸载通道402可定位在反应室102内在后中间架406与底壁106之间,并且注入/排出通道404可定位在反应室102内在后中间架406与顶壁104之间。FIG. 8 schematically shows a view of a deposition system 400 according to another exemplary embodiment of the present disclosure. The deposition system 400 may be substantially the same as the deposition system 100 of FIG. 1 or the deposition system 200 of FIG. 6 except that the reaction chamber 102 may be divided into two or more channels. In several embodiments, the two or more channels may be vertically stacked. For example, the two or more channels may include a load/unload channel 402 and an inject/exhaust channel 404 . Load/unload channel 402 may be positioned within reaction chamber 102 between rear intermediate frame 406 and bottom wall 106 , and injection/exhaust channel 404 may be positioned within reaction chamber 102 between rear intermediate frame 406 and top wall 104 .
注入/排出通道404通过真空室184与真空装置113流体连通以用于从反应室102排出气态副产物、载料气体及所有过量的前驱气体。Injection/exhaust channel 404 is in fluid communication with vacuum device 113 through vacuum chamber 184 for exhausting gaseous by-products, carrier gas and any excess precursor gas from reaction chamber 102 .
加载/卸载通道402可延伸至存取闸188,该存取闸188可选择性地打开以用于穿过加载/卸载通道402将工件基板116装载至基板支撑结构114以及/或者从基板支撑结构114卸载工件基板116并且/或者装载/卸载基板支撑结构114。存取闸188可选择性地关闭以用于利用沉积系统400处理工件基板116。此外,加载/卸载通道402可与连接器117的第一底行115A流体连通以用于注入工艺气体。在此构造中,可将吹扫气体注入到加载/卸载通道402以防止气态副产物、载料气体及所有过量的前驱气体进入加载/卸载通道402,从而减少(例如阻止)材料在存取闸188上的寄生沉积。The load/unload lane 402 can extend to an access gate 188 that can be selectively opened for loading workpiece substrates 116 to and/or from the substrate support structure 114 through the load/unload lane 402. 114 unloads workpiece substrate 116 and/or loads/unloads substrate support structure 114 . Access gate 188 may be selectively closed for processing workpiece substrate 116 with deposition system 400 . Additionally, the load/unload channels 402 may be in fluid communication with the first bottom row 115A of connectors 117 for injecting process gases. In this configuration, a purge gas may be injected into the load/unload channel 402 to prevent gaseous by-products, carrier gas, and any excess precursor gas from entering the load/unload channel 402, thereby reducing (e.g., preventing) material from entering the load/unload channel 402. Parasitic deposition on 188.
就装载/卸载过程而言,至少一个机器臂装置(图8中未示出)可构造成来回横动经过加载/卸载通道402以能够穿过存取闸188将工件基板116(以及/或者基板支撑结构114)以机器人自动方式加载到反应室102内,并且能够穿过存取闸188将工件基板116(以及/或者基板支撑结构114)以机器人自动方式从反应室102卸载出。本领域公知这种机器臂装置。For the loading/unloading process, at least one robotic arm arrangement (not shown in FIG. 8 ) may be configured to traverse back and forth across the loading/unloading lane 402 to enable loading of the workpiece substrate 116 (and/or the substrate 116) through the access gate 188. The support structure 114 ) is robotically loaded into the reaction chamber 102 and the workpiece substrate 116 (and/or the substrate support structure 114 ) can be robotically unloaded from the reaction chamber 102 through the access gate 188 . Such robotic arm arrangements are well known in the art.
可沿基板支撑结构114的旋转轴线408使基板支撑结构114及位于其上的工件基板116升降。驱动器(未示出)可联接至心轴119以使基板支撑结构114及位于其上的工件基板116能沿旋转轴线408移动(除了基板支撑结构114与工件基板116绕旋转轴线408旋转外)。The substrate support structure 114 and the workpiece substrate 116 thereon may be raised and lowered along a rotational axis 408 of the substrate support structure 114 . A drive (not shown) may be coupled to spindle 119 to enable movement of substrate support structure 114 and workpiece substrate 116 thereon along axis of rotation 408 (in addition to rotation of substrate support structure 114 and workpiece substrate 116 about axis of rotation 408 ).
基板支撑结构114及位于其上的工件基板116可在反应室102内被提升至沉积位置并且可在反应室102内被降低至装载/卸载位置,以分别能进行沉积过程及装载/卸载过程。就沉积过程而言,基板支撑结构114可被提升至基板支撑结构114可定位在注入/排出通道404内或至少邻近注入/排出通道404的沉积位置,更具体地说与后中间架406大致共面。就装载/卸载过程而言,基板支撑结构114可被降低至基板支撑结构114可定位在注入/排出通道404内的装载/卸载位置,更具体地说可靠近底壁106定位。The substrate support structure 114 and the workpiece substrate 116 thereon may be raised to a deposition position and lowered to a loading/unloading position within the reaction chamber 102 to enable a deposition process and a loading/unloading process, respectively. For the deposition process, the substrate support structure 114 may be lifted to a deposition position where the substrate support structure 114 may be positioned within or at least adjacent to the injection/exhaust channel 404, more specifically approximately co-located with the rear intermediate frame 406. noodle. For the loading/unloading process, the substrate support structure 114 may be lowered to a loading/unloading position where the substrate support structure 114 may be positioned within the fill/exhaust channel 404 , and more specifically may be positioned near the bottom wall 106 .
如在此所描述的沉积系统的实施方式,诸如图1的沉积系统100、图6的沉积系统200、图7的沉积系统300以及图8的沉积系统400可根据本公开的其它实施方式用于使半导体材料沉积在工件基板116上。Embodiments of deposition systems as described herein, such as deposition system 100 of FIG. 1 , deposition system 200 of FIG. 6 , deposition system 300 of FIG. 7 , and deposition system 400 of FIG. A semiconductor material is deposited on the workpiece substrate 116 .
参照图1,工件基板116可穿过至少一个存取闸188定位在反应室102内并且定位在基板支撑结构114上。可通过远离该至少一个存取闸188定位的至少一个气体注入装置110使可包括一种或多种前驱气体的一种或多种工艺气体流到反应室102内。可通过可定位在基板支撑结构114的与该至少一个气体注入装置110相反的一侧上的至少一个真空装置113使一种或多种工艺气体从反应室102排出。当该一种或多种工艺气体从该至少一个气体注入装置110流至该至少一个真空装置113时,工件基板116的表面可暴露于该一种或多种工艺气体,从而半导体材料可沉积在工件基板116的该表面上。Referring to FIG. 1 , a workpiece substrate 116 may be positioned within reaction chamber 102 and on substrate support structure 114 through at least one access gate 188 . One or more process gases, which may include one or more precursor gases, may be flowed into the reaction chamber 102 through at least one gas injection device 110 located remotely from the at least one access gate 188 . One or more process gases may be exhausted from the reaction chamber 102 by at least one vacuum device 113 , which may be positioned on a side of the substrate support structure 114 opposite the at least one gas injection device 110 . When the one or more process gases flow from the at least one gas injection device 110 to the at least one vacuum device 113, the surface of the workpiece substrate 116 can be exposed to the one or more process gases, so that semiconductor material can be deposited on the on this surface of the workpiece substrate 116 .
在若干实施方式中,如前所述,工件基板116被装载及卸载所穿过的存取闸188可定位在真空装置113的与所述至少一个气体注入装置110相反的一侧上。In several embodiments, the access gate 188 through which the workpiece substrate 116 is loaded and unloaded may be positioned on the opposite side of the vacuum device 113 from the at least one gas injection device 110 as previously described.
此外,如前所述,可利用吹扫气体帘装置186形成流动吹扫气体帘。流动吹扫气体帘可布置在基板支撑结构114与存取闸188之间。Additionally, as previously described, a flowing purge gas curtain may be formed using purge gas curtain assembly 186 . A curtain of flowing purge gas may be disposed between the substrate support structure 114 and the access gate 188 .
在若干实施方式中,工艺气体可至少包括选择为包括III族元素前驱气体及V族元素前驱气体的前驱气体。在这种实施方式中,待沉积在工件基板116上的半导体材料可包括III-V半导体材料。可选地能够使III族元素前驱气体流经延伸穿过布置在反应室102内的前驱气体炉130的至少一个前驱气体流动路径以加热III族元素前驱气体。In some embodiments, the process gas may include at least a precursor gas selected to include a Group III element precursor gas and a Group V element precursor gas. In such an embodiment, the semiconductor material to be deposited on the workpiece substrate 116 may include a III-V semiconductor material. The Group III precursor gas can optionally be flowed through at least one precursor gas flow path extending through a precursor gas furnace 130 disposed within the reaction chamber 102 to heat the Group III precursor gas.
III族元素前驱气体可包括GaCl3、InCl3及AlCl3中的一种或多种。在这种实施方式中,加热III族元素前驱气体可导致GaCl3、InCl3及AlCl3中至少其一裂解以形成GaCl、InCl及AlCl至少其一及氯化物质(例如HCl)。The Group III element precursor gas may include one or more of GaCl 3 , InCl 3 and AlCl 3 . In such an embodiment, heating the Group III precursor gas may cause at least one of GaCl 3 , InCl 3 , and AlCl 3 to crack to form at least one of GaCl, InCl, and AlCl and a chloride species (eg, HCl).
加热炉130内的III族元素前驱气体后,V族元素前驱气体与III族元素前驱气体可在反应室102内在工件基板116上方混合在一起。工件基板116的表面可暴露至V族元素前驱气体与III族元素前驱气体的混合物,以在工件基板116的表面上形成III-V半导体材料。After heating the Group III precursor gas in the furnace 130 , the Group V precursor gas and the Group III precursor gas may be mixed together in the reaction chamber 102 above the workpiece substrate 116 . The surface of the workpiece substrate 116 may be exposed to a mixture of the group V precursor gas and the group III precursor gas to form a III-V semiconductor material on the surface of the workpiece substrate 116 .
可利用图6的沉积系统200执行根据本公开的类似方法。A similar method according to the present disclosure may be performed using the deposition system 200 of FIG. 6 .
本公开的方法也包括制造在此描述的诸如图1的沉积系统100与图6的沉积系统200的沉积系统的方法。反应室102可形成为包括顶壁104、底壁106及至少一个侧壁108A、108B。用于支撑至少一个工件基板116的基板支撑结构114可至少局部设置在反应室102内。至少一个气体注入装置110可在第一位置103A联接至反应室。气体注入装置可构造成用于在第一位置103A处将一种或多种工艺气体注入到反应室102内。该一种或多种工艺气体可包括至少一种前驱气体。至少一个真空装置113也可在第二位置联接至反应室102。真空装置113可构造成用于将穿过反应室102的工艺气体从第一位置103A抽至第二位置103B,并用于在第二位置103B将工艺气体从反应室102排出。Methods of the present disclosure also include methods of manufacturing deposition systems described herein, such as deposition system 100 of FIG. 1 and deposition system 200 of FIG. 6 . The reaction chamber 102 may be formed to include a top wall 104, a bottom wall 106, and at least one side wall 108A, 108B. A substrate support structure 114 for supporting at least one workpiece substrate 116 may be at least partially disposed within the reaction chamber 102 . At least one gas injection device 110 may be coupled to the reaction chamber at a first location 103A. The gas injection device may be configured for injecting one or more process gases into the reaction chamber 102 at the first location 103A. The one or more process gases may include at least one precursor gas. At least one vacuum device 113 may also be coupled to reaction chamber 102 at a second location. The vacuum device 113 may be configured for evacuating process gases through the reaction chamber 102 from the first location 103A to the second location 103B, and for exhausting the process gases from the reaction chamber 102 at the second location 103B.
至少一个存取闸188可在远离第一位置103A的位置联接至反应室102,在该第一位置,气体注入装置110联接至反应室102。该至少一个存取闸188可构造成能够使工件基板116通过该至少一个存取闸188被装载到反应室102内并被装载到基板支撑结构114上,以及从基板支撑结构114被卸载出反应室102。At least one access gate 188 may be coupled to reaction chamber 102 at a location remote from first location 103A where gas injection device 110 is coupled to reaction chamber 102 . The at least one access gate 188 can be configured to enable the workpiece substrate 116 to be loaded into the reaction chamber 102 and onto the substrate support structure 114 through the at least one access gate 188, and to be unloaded from the substrate support structure 114 for reaction. Room 102.
以下描述本发明另外的非限制性的示例性实施方式。Additional non-limiting exemplary embodiments of the present invention are described below.
实施方式1:一种沉积系统,该沉积系统包括:由顶壁、底壁及至少一个侧壁限定的反应室;基板支撑结构,该基板支撑结构至少局部布置在反应室内并且构造成支撑反应室内的工件基板;用于将包括至少一种前驱气体的一种或多种工艺气体在第一位置注入到反应室内的至少一个气体注入装置;真空装置,该真空装置用于将穿过反应室的该一种或多种工艺气体从第一位置抽至第二位置,并且用于在第二位置将该一种或多种工艺气体从反应室排出;以及至少一个存取闸,工件基板可穿过该存取闸被装载到反应室内并装载到基板支撑结构上,以及从基板支撑结构被卸载出反应室,所述至少一个存取闸远离第一位置定位。Embodiment 1: A deposition system comprising: a reaction chamber defined by a top wall, a bottom wall, and at least one side wall; a substrate support structure at least partially disposed within the reaction chamber and configured to support the reaction chamber a workpiece substrate; at least one gas injection device for injecting one or more process gases comprising at least one precursor gas into the reaction chamber at a first location; a vacuum device for injecting The one or more process gases are pumped from the first location to the second location and used to exhaust the one or more process gases from the reaction chamber at the second location; and at least one access gate through which the workpiece substrate can pass The at least one access gate is positioned remotely from the first position by which the access gate is loaded into the reaction chamber and onto the substrate support structure, and unloaded from the substrate support structure out of the reaction chamber.
实施方式2:实施方式1的沉积系统,其中第一位置布置在基板支撑结构的第一侧,并且第二位置布置在基板支撑结构的相反的第二侧上。Embodiment 2: The deposition system of Embodiment 1, wherein the first location is arranged on a first side of the substrate support structure and the second location is arranged on an opposite second side of the substrate support structure.
实施方式3:实施方式2的沉积系统,其中第二位置布置在基板支撑结构与所述至少一个存取闸之间。Embodiment 3: The deposition system of Embodiment 2, wherein the second location is disposed between the substrate support structure and the at least one access gate.
实施方式4:实施方式1至3中任一实施方式的沉积系统,还包括至少一个吹扫气体注入装置,该吹扫气体注入装置构造成形成在至少一个吹扫气体注入装置与真空装置之间流动的流动吹扫气体帘,该流动吹扫气体帘布置在工件支撑结构与该至少一个存取闸之间。Embodiment 4: The deposition system of any one of Embodiments 1 to 3, further comprising at least one purge gas injection device configured to be formed between the at least one purge gas injection device and the vacuum device A flowing curtain of flow purge gas is disposed between the workpiece support structure and the at least one access gate.
实施方式5:实施方式1的沉积系统,其中,第二位置布置在基板支撑结构与该至少一个存取闸之间。Embodiment 5: The deposition system of Embodiment 1, wherein the second location is disposed between the substrate support structure and the at least one access gate.
实施方式6:实施方式1至4中任一实施方式的沉积系统,其中,至少一个气体注入装置定位在反应室的第一端,并且该至少一个存取闸定位在反应室的相反的第二端。Embodiment 6: The deposition system of any one of Embodiments 1 to 4, wherein at least one gas injection device is positioned at a first end of the reaction chamber, and the at least one access gate is positioned at an opposite second end of the reaction chamber end.
实施方式7:实施方式1至4中任一实施方式的沉积系统,其中,至少一个气体注入装置定位在反应室的第一端,并且该至少一个存取闸定位在反应室的横向侧。Embodiment 7: The deposition system of any of Embodiments 1 to 4, wherein at least one gas injection device is positioned at the first end of the reaction chamber and the at least one access gate is positioned at a lateral side of the reaction chamber.
实施方式8:实施方式1至7中任一实施方式的沉积系统,其中该至少一个存取闸包括构造成在闭合的第一位置与开放的第二位置之间移动的至少一个板,其中在该至少一个板在闭合的第一位置时,反应室是至少基本封闭的,禁止穿过该至少一个存取闸访问基板支撑结构,并且其中,在该至少一个板在开放的第二位置时,能够穿过该至少一个存取闸而接近基板支撑结构。Embodiment 8: The deposition system of any of Embodiments 1 to 7, wherein the at least one access gate comprises at least one plate configured to move between a closed first position and an open second position, wherein at When the at least one plate is in the closed first position, the reaction chamber is at least substantially closed from accessing the substrate support structure through the at least one access gate, and wherein, when the at least one plate is in the open second position, The substrate support structure is accessible through the at least one access gate.
实施方式9:实施方式1至8中任一实施方式的沉积系统,其中,该至少一个气体注入装置包括气体注入歧管。Embodiment 9: The deposition system of any of Embodiments 1 to 8, wherein the at least one gas injection device comprises a gas injection manifold.
实施方式10:实施方式1至9中任一实施方式的沉积系统还包括布置在反应室内的至少一个内置前驱气体炉,该至少一个内置前驱气体炉构造成用于加热至少一种前驱气体,并且将反应室内的至少一种前驱气体从该至少一个气体注入装置运送至靠近基板支撑结构的位置。Embodiment 10: The deposition system of any one of Embodiments 1 to 9 further comprising at least one built-in precursor gas furnace disposed within the reaction chamber, the at least one built-in precursor gas furnace configured to heat at least one precursor gas, and At least one precursor gas within the reaction chamber is delivered from the at least one gas injection device to a location proximate to the substrate support structure.
实施方式11:实施方式1至10中任一实施方式的沉积系统还包括至少一个布置在反应室外部的外置前驱气体注入器,该至少一个外置前驱气体注入器构造成用于加热至少一种前驱气体,并且将该至少一种前驱气体从前驱气体源运送至该至少一个气体注入装置。Embodiment 11: The deposition system of any one of Embodiments 1 to 10 further includes at least one external precursor gas injector arranged outside the reaction chamber, and the at least one external precursor gas injector is configured to heat at least one and delivering the at least one precursor gas from the precursor gas source to the at least one gas injection device.
实施方式12:实施方式1至11中任一实施方式的沉积系统还包括至少一个机器臂装置,该机器臂装置构造成穿过该至少一个存取闸将工件基板自动地装载到反应室内,以及将工件基板从反应室自动地卸载出。Embodiment 12: The deposition system of any one of Embodiments 1 to 11 further comprising at least one robotic arm device configured to automatically load the workpiece substrate into the reaction chamber through the at least one access gate, and The workpiece substrate is automatically unloaded from the reaction chamber.
实施方式13:实施方式1至12中任一实施方式的沉积系统,其中,用于注入一种或多种工艺气体的该至少一个气体注入装置构造成穿过反应室的至少一个侧壁注入该一种或多种工艺气体,其中,该至少一个存取闸延伸穿过另一侧壁,该另一侧壁远离该一种或多种工艺气体被注入所穿过的该至少一个侧壁。Embodiment 13: The deposition system of any of Embodiments 1 to 12, wherein the at least one gas injection device for injecting one or more process gases is configured to inject the One or more process gases, wherein the at least one access gate extends through another sidewall remote from the at least one sidewall through which the one or more process gases are injected.
实施方式14:实施方式13的沉积系统,其中,该一种或多种工艺气体被注入所穿过的该至少一个侧壁与所述另一侧壁被定位在反应室的相对两端。Embodiment 14: The deposition system of Embodiment 13, wherein the at least one sidewall and the other sidewall through which the one or more process gases are injected are positioned at opposite ends of the reaction chamber.
实施方式15:一种利用沉积系统将半导体材料沉积在工件基板上的方法,该方法包括:穿过至少一个存取闸将工件基板装载至反应室内并且装载到基板支撑结构上;使一种或多种工艺气体通过远离所述至少一个存取闸定位的至少一个气体注入装置流至反应室内,该一种或多种工艺气体包括至少一种前驱气体;将一种或多种工艺气体通过定位在基板支撑结构的与该至少一个气体注入装置相反的一侧上的至少一个真空装置从反应室排出;当该一种或多种工艺气体从该至少一个气体注入装置流至该至少一个真空装置时,使工件基板的表面暴露于该一种或多种工艺气体,从而在工件基板的该表面上沉积半导体材料;以及穿过该至少一个存取闸将工件基板从反应室卸载出。Embodiment 15: A method of depositing a semiconductor material on a workpiece substrate using a deposition system, the method comprising: loading the workpiece substrate into a reaction chamber through at least one access gate and onto a substrate support structure; A plurality of process gases are flowed into the reaction chamber through at least one gas injection device positioned away from the at least one access gate, the one or more process gases including at least one precursor gas; the one or more process gases are passed through the positioned At least one vacuum device on the opposite side of the substrate support structure from the at least one gas injection device is exhausted from the reaction chamber; when the one or more process gases flow from the at least one gas injection device to the at least one vacuum device When, exposing the surface of the workpiece substrate to the one or more process gases, thereby depositing semiconductor material on the surface of the workpiece substrate; and unloading the workpiece substrate from the reaction chamber through the at least one access gate.
实施方式16:实施方式15的方法还包括选择所述至少一种前驱气体使其包括III族元素前驱气体与V族元素前驱气体。Embodiment 16: The method of Embodiment 15 further includes selecting the at least one precursor gas to include a Group III element precursor gas and a Group V element precursor gas.
实施方式17:实施方式15或实施方式16的方法,其中,所述的在工件基板的表面上沉积半导体材料包括在工件基板的表面上沉积III-V半导体材料。Embodiment 17: the method of Embodiment 15 or Embodiment 16, wherein said depositing a semiconductor material on the surface of the workpiece substrate includes depositing a III-V semiconductor material on the surface of the workpiece substrate.
实施方式18:实施方式15至17中任一实施方式的方法,其中,所述的穿过该至少一个存取闸将工件基板装载到反应室内并装载到基板支撑结构上包括穿过定位在该至少一个真空装置的与该至少一个气体注入装置相反的一侧上的至少一个存取闸将工件基板装载到反应室内。Embodiment 18: The method of any of Embodiments 15 to 17, wherein loading the workpiece substrate into the reaction chamber and onto the substrate support structure through the at least one access gate comprises passing through a At least one access gate on a side of the at least one vacuum device opposite the at least one gas injection device loads the workpiece substrate into the reaction chamber.
实施方式19:实施方式15至18中任一实施方式的方法还包括形成布置在工件支撑结构与至少一个存取闸之间的流动吹扫气体帘。Embodiment 19: The method of any of Embodiments 15 to 18 further comprising forming a curtain of flowing purge gas disposed between the workpiece support structure and the at least one access gate.
实施方式20:一种制造沉积系统的方法,包括:形成包括顶壁、底壁及至少一个侧壁的反应室;设置至少局部在反应室内用于支撑至少一个工件基板的基板支撑结构;将至少一个气体注入装置在第一位置联接至反应室,该至少一个气体注入装置被构造成用于将包括至少一种前驱气体的一种或多种工艺气体在第一位置注入到反应室内;将至少一个真空装置在第二位置联接至反应室,该至少一个真空装置构造成用于将穿过反应室的该一种或多种工艺气体从第一位置抽至第二位置,并且用于在第二位置将该一种或多种工艺气体从反应室排出;以及将至少一个存取闸在远离第一位置的位置联接至反应室,该至少一个存取闸构造成能够使工件基板穿过该至少一个存取闸被装载到反应室内并装载到基板支撑结构上,并且能够穿过该至少一个存取闸从基板支撑结构被卸载出反应室。Embodiment 20: A method of manufacturing a deposition system, comprising: forming a reaction chamber including a top wall, a bottom wall, and at least one side wall; providing a substrate support structure at least partially within the reaction chamber for supporting at least one workpiece substrate; placing at least A gas injection device coupled to the reaction chamber at a first location, the at least one gas injection device configured to inject one or more process gases including at least one precursor gas into the reaction chamber at the first location; A vacuum device is coupled to the reaction chamber at a second location, the at least one vacuum device is configured for pumping the one or more process gases passing through the reaction chamber from the first location to the second location, and for two locations to exhaust the one or more process gases from the reaction chamber; and at least one access gate coupled to the reaction chamber at a location remote from the first location, the at least one access gate configured to allow a workpiece substrate to pass through the reaction chamber At least one access gate is loaded into the reaction chamber and onto the substrate support structure and can be unloaded out of the reaction chamber from the substrate support structure through the at least one access gate.
实施方式21:实施方式20的方法还包括将该至少一个气体注入装置定位在基板支撑结构的第一侧上,并且将该至少一个真空装置定位在基板支撑结构的相反的第二侧上。Embodiment 21: The method of Embodiment 20 further comprising positioning the at least one gas injection device on a first side of the substrate support structure, and positioning the at least one vacuum device on an opposite second side of the substrate support structure.
实施方式22:实施方式20或实施方式21的方法还包括将该至少一个真空装置定位在基板支撑结构与该至少一个存取闸之间。Embodiment 22: The method of Embodiment 20 or Embodiment 21 further comprising positioning the at least one vacuum device between the substrate support structure and the at least one access gate.
实施方式23:实施方式20至22中任一实施方式的方法还包括靠近该至少一个真空装置将至少一个吹扫气体注入装置联接至反应室,该至少一个吹扫气体注入装置构造成形成在基板支撑结构与该至少一个存取闸之间从该至少一个吹扫气体注入装置流向该至少一个真空装置的吹扫气体帘。Embodiment 23: The method of any of Embodiments 20 to 22 further comprising coupling at least one purge gas injection device to the reaction chamber proximate to the at least one vacuum device, the at least one purge gas injection device configured to form on the substrate A curtain of purge gas flowing from the at least one purge gas injection device to the at least one vacuum device between the support structure and the at least one access gate.
实施方式24:实施方式20至23中任一实施方式的方法还包括将该至少一个真空装置定位在基板支撑结构与该至少一个存取闸之间。Embodiment 24: The method of any of Embodiments 20-23, further comprising positioning the at least one vacuum device between the substrate support structure and the at least one access gate.
实施方式25:实施方式20至24中任一实施方式的方法还包括将该至少一个气体注入装置定位在反应室的第一端,并且将该至少一个存取闸定位在反应室的相反的第二端。Embodiment 25: The method of any one of Embodiments 20 to 24 further comprising positioning the at least one gas injection device at a first end of the reaction chamber, and positioning the at least one access gate at an opposite first end of the reaction chamber Two ends.
以上所述的本发明的实施方式不限制本发明的范围,因为这些实施方式仅仅是本发明的示例性实施方式,本发明由所附权利要求的范围及其法定等同物限定。任一等同实施方式理应在本发明的范围内。实际上,根据本描述,对于本技术领域的技术人员来说,除在此所示及所述的变型例以外,本发明的多种变型例,例如所述元素的有益交替组合,将会是显而易见的。这种变型例也理应落入所附权利要求的范围内。The embodiments of the invention described above do not limit the scope of the invention, since these embodiments are merely exemplary embodiments of the invention, which is defined by the scope of the appended claims and their legal equivalents. Any equivalent embodiments are intended to be within the scope of this invention. Indeed, from the present description, numerous variants of the invention, such as beneficial alternate combinations of the elements described, will be apparent to a person skilled in the art, in addition to the variants shown and described here. Obvious. Such modifications are also intended to fall within the scope of the appended claims.
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| FR1157954A FR2979748B1 (en) | 2011-09-07 | 2011-09-07 | DEPOSITION SYSTEMS HAVING ACCESS DOORS TO DESIRABLE LOCATIONS, AND METHODS RELATING THERETO |
| PCT/IB2012/001577 WO2013027102A1 (en) | 2011-08-22 | 2012-08-10 | Deposition system having acces gates and related method |
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| US20090223442A1 (en) * | 2006-11-22 | 2009-09-10 | Chantal Arena | Methods for high volume manufacture of group iii-v semiconductor materials |
| US20100166955A1 (en) * | 2008-11-01 | 2010-07-01 | Cambridge Nanotech Inc. | System and method for thin film deposition |
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| US20090223442A1 (en) * | 2006-11-22 | 2009-09-10 | Chantal Arena | Methods for high volume manufacture of group iii-v semiconductor materials |
| US20100166955A1 (en) * | 2008-11-01 | 2010-07-01 | Cambridge Nanotech Inc. | System and method for thin film deposition |
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