CN103387803A - Hot melt adhesive - Google Patents
Hot melt adhesive Download PDFInfo
- Publication number
- CN103387803A CN103387803A CN201310269527XA CN201310269527A CN103387803A CN 103387803 A CN103387803 A CN 103387803A CN 201310269527X A CN201310269527X A CN 201310269527XA CN 201310269527 A CN201310269527 A CN 201310269527A CN 103387803 A CN103387803 A CN 103387803A
- Authority
- CN
- China
- Prior art keywords
- hot melt
- melt adhesive
- parts
- adhesive according
- vinyl acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004831 Hot glue Substances 0.000 title claims abstract description 22
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 6
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 3
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 3
- 239000003112 inhibitor Substances 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 9
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 7
- -1 polyethylene Polymers 0.000 claims description 7
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 6
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000003208 petroleum Substances 0.000 claims description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 4
- 239000001993 wax Substances 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 235000019260 propionic acid Nutrition 0.000 claims description 3
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical class C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 claims description 2
- 239000004200 microcrystalline wax Substances 0.000 claims description 2
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- 230000003750 conditioning effect Effects 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000000463 material Substances 0.000 description 3
- 230000003044 adaptive effect Effects 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides a hot melt adhesive, which comprises, based on quality percentage, 50-90 parts of base resin and 10-50 parts of auxiliary agent, wherein the base resin is an ethane-vinyl acetate copolymer, and the auxiliary agent comprises 10-30 parts of adhesion agent, 1-15 parts of viscosity conditioning agent and 1-7 parts of anti-oxidant. The hot melt adhesive provided by the invention is environment-friendly that has a wide temperature scope, convenient usage, strong adhesion stress and stable performance.
Description
Technical field
The present invention relates to jointing material, in particular to a kind of hot melt adhesive.
Background technology
Hot melt adhesive is a kind of plastic tackiness agent, and its physical condition changes along with temperature change in certain temperature range, and chemical property is constant, and is nonpoisonous and tasteless because of it, is a kind of environmental-protecting chemical product, is applied in a lot of industries.But because make the difference of formula, technique, the own characteristics such as the bonding force intensity of hot melt adhesive, adaptive temperature scope, stability are also different, and this will cause the hot melt adhesive quality uneven.
Summary of the invention
The invention solves deficiency of the prior art, provide that a kind of bonding force is strong, the hot melt adhesive of adaptive temperature wide ranges, good stability.
Technical scheme of the present invention is: a kind of hot melt adhesive, by massfraction, its formula is comprised of 50～90 parts of basic resin and 10～50 parts of auxiliary agents, described basic resin is ethylene-vinyl acetate copolymer, and described auxiliary agent is 10～30 parts of tackifier, 1～15 portion of viscosity modifier, 1～7 part of oxidation inhibitor.
Preferably, its formula is comprised of 70 parts of ethylene vinyl acetates, 20 parts of tackifier, 7 portions of viscosity modifiers and 3 parts of oxidation inhibitor.
Preferably, in described ethylene-vinyl acetate copolymer, the massfraction of vinyl acetate is 18～30%.
Preferably, the melting index of described ethylene-vinyl acetate copolymer is 10～600g/10min.
Preferably, described tackifier are a kind of or its mixture in rosin, modified rosin, terpine resin, C5 petroleum resin and C9 petroleum resin.
Preferably, described viscosity modifier is a kind of or its mixture in paraffin, Microcrystalline Wax, polyethylene wax and Poly Propylene Wax.
Preferably, described oxidation inhibitor is hindered phenol type antioxidant.
More preferably, described oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester.
The defect that solves prior art of the present invention has following beneficial effect:
1. in the ethylene-vinyl acetate copolymer resin of the present invention's employing, the massfraction of vinyl acetate is 18～30%, and its elasticity is suitable, when melting index is 10～600g/10min, and its good fluidity, the value range of melt temperature is wider.
2. the present invention adds tackifier, has improved the mobility of colloid and the wettability of adherend, improves adhesive property, has good adhesive property.
3. the present invention adopts four [β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester is as oxidation inhibitor, this oxidation inhibitor is nontoxic, nonflammable, non-explosive, burn into good stability not, meets the hot melt adhesive environmental requirement, and increases stability and the work-ing life of hot melt adhesive.
4. softening temperature of the present invention is 95 ± 5 ℃, easily reaches, and is easy to use, and cohesive force is strong; Second-order transition temperature is-25 ± 5 ℃, and temperature range is wide, and the present invention is a kind of easy to use, and cohesive force is strong, the environment-friendly type hot melt glue that temperature range is wide.
Embodiment
In order to make those skilled in the art person understand better the present invention, and above-mentioned advantage of the present invention can be become apparent more, the present invention is further detailed explanation below in conjunction with specific embodiment.
Embodiment 1
Take each component according to ratio corresponding in table 1; Again each component materials is mixed; Material melting mixing in twin screw extruder with mixing, be controlled at temperature below 160 ℃; Mixing fully rear extrusion moulding; Cut into finally finished product.
Embodiment 2
Take each component according to ratio corresponding in table 1, all the other steps are with embodiment 1.
Embodiment 3
Take each component according to ratio corresponding in table 1, all the other steps are with embodiment 1.
Embodiment 4
Take each component according to ratio corresponding in table 1, all the other steps are with embodiment 1.
Embodiment 5
Take each component according to ratio corresponding in table 1, all the other steps are with embodiment 1.
Embodiment 6
Take each component according to ratio corresponding in table 1, all the other steps are with embodiment 1.
Embodiment 7
Take each component according to ratio corresponding in table 1, all the other steps are with embodiment 1.
Table 1 recipe ingredient list position (%)
Performance test
With the hot melt adhesive for preparing in the embodiment of the present invention, carry out performance test, indices is as shown in table 2:
Table 2 performance index
As above table can be found out, the softening temperature in the embodiment of the present invention 1 is the highest, and viscous force is lasting, and second-order transition temperature is lower, and the temperature use range is wider, and melting viscosity is suitable, produces good mobility under use temperature; Tensile strength is strong, and guarantee hot melt adhesive and bonding object have enough avidities like this, and bond effect is good, so embodiment 1 is most preferred embodiment of the present invention.
The above; be only the specific embodiment of the present invention, protection scope of the present invention is not limited to this, anyly is familiar with those skilled in the art in the technical scope that the present invention discloses; the variation that can expect easily or replacement, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claim was defined.
Claims (8)
1. hot melt adhesive, it is characterized in that, by massfraction, its formula is comprised of 50～90 parts of basic resin and 10～50 parts of auxiliary agents, described basic resin is ethylene-vinyl acetate copolymer, and described auxiliary agent is 10～30 parts of tackifier, 1～15 portion of viscosity modifier, 1～7 part of oxidation inhibitor.
2. a kind of hot melt adhesive according to claim 1, is characterized in that, by massfraction, its formula is comprised of 70 parts of ethylene vinyl acetates, 20 parts of tackifier, 7 portions of viscosity modifiers and 3 parts of oxidation inhibitor.
3. a kind of hot melt adhesive according to claim 1, is characterized in that, in described ethylene-vinyl acetate copolymer, the massfraction of vinyl acetate is 18～30%.
4. a kind of hot melt adhesive according to claim 3, is characterized in that, the melting index of described ethylene-vinyl acetate copolymer is 10～600g/10min.
5. a kind of hot melt adhesive according to claim 1, is characterized in that, described tackifier are a kind of or its mixture in rosin, modified rosin, terpine resin, C5 petroleum resin and C9 petroleum resin.
6. a kind of hot melt adhesive according to claim 1, is characterized in that, described viscosity modifier is a kind of or its mixture in paraffin, Microcrystalline Wax, polyethylene wax and Poly Propylene Wax.
7. a kind of hot melt adhesive according to claim 1, is characterized in that, described oxidation inhibitor is hindered phenol type antioxidant.
8. a kind of hot melt adhesive according to claim 7, is characterized in that, described oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310269527XA CN103387803A (en) | 2013-07-01 | 2013-07-01 | Hot melt adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310269527XA CN103387803A (en) | 2013-07-01 | 2013-07-01 | Hot melt adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103387803A true CN103387803A (en) | 2013-11-13 |
Family
ID=49532227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310269527XA Pending CN103387803A (en) | 2013-07-01 | 2013-07-01 | Hot melt adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103387803A (en) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103756580A (en) * | 2014-01-14 | 2014-04-30 | 谢斌 | Hot-melting adhesive film for bonding shoe soles and preparation method thereof |
| CN104497924A (en) * | 2014-11-25 | 2015-04-08 | 四川大学 | New antistatic hot melt adhesive and preparation method thereof |
| CN104497916A (en) * | 2014-12-15 | 2015-04-08 | 湖州天强绫绢工艺品有限公司 | Ghatpot silk handicraft picture mounting process, EVA (ethylene-vinyl acetate copolymer) hot melt adhesive and modified rosin resin |
| CN105950087A (en) * | 2016-06-14 | 2016-09-21 | 深圳市优力新材料有限公司 | Novel electret hot-melt adhesive composite and preparation method thereof |
| CN106207033A (en) * | 2016-08-15 | 2016-12-07 | 系统电子科技（镇江）有限公司 | A kind of battery core bracket of high safety performance |
| CN106349567A (en) * | 2016-08-31 | 2017-01-25 | 温州鑫泰新材料股份有限公司 | Teaching and scrawling blackboard pasting composite material and preparation method thereof |
| CN106362485A (en) * | 2015-07-24 | 2017-02-01 | 上海名冠净化材料股份有限公司 | Purification composite material |
| CN107384252A (en) * | 2017-07-20 | 2017-11-24 | 毕同召 | A kind of low temperature resistant joint sealing PUR and preparation method thereof |
| CN107400480A (en) * | 2017-08-24 | 2017-11-28 | 蒋磊 | One kind is daily to be made by hand with slow curing type PUR |
| CN108192529A (en) * | 2017-12-13 | 2018-06-22 | 广州艾科洛克建筑材料技术开发有限公司 | A kind of new type hot-melt adhesive that microwave heating can be used and preparation method thereof |
| CN108624257A (en) * | 2018-05-30 | 2018-10-09 | 王召惠 | A kind of modified meerschaum EVA hot-melt adhesive |
| CN109207094A (en) * | 2017-06-30 | 2019-01-15 | 重庆文理学院 | A kind of EVA melt pressure sensitive gluing agent and preparation method thereof |
| CN109401683A (en) * | 2018-10-25 | 2019-03-01 | 北京文盛印刷材料有限公司 | Adhesive bookbinding hot melt adhesive and preparation method thereof |
| CN109679532A (en) * | 2018-11-30 | 2019-04-26 | 江苏和和新材料股份有限公司 | A kind of hot melt adhesive film and its production technology for footwear material star actor |
| CN110055030A (en) * | 2019-04-02 | 2019-07-26 | 佛山精展科技有限公司 | A kind of preparation method of hot melt adhesive |
| CN110305623A (en) * | 2019-06-04 | 2019-10-08 | 广州市豪特粘接材料有限公司 | One kind is ridden helmet hot melt adhesive and preparation method thereof |
| CN110467906A (en) * | 2019-08-28 | 2019-11-19 | 佛山市南海骏驰新材料有限公司 | A kind of heat molten type carpenter overlay film glue and its production technology |
| CN111363417A (en) * | 2020-04-27 | 2020-07-03 | 广州旭川合成材料有限公司 | Degradable coating and preparation method and application thereof |
| CN111590975A (en) * | 2020-04-13 | 2020-08-28 | 广盟（广州）包装有限公司 | Antibacterial composite cover material film and preparation method thereof |
| CN112266756A (en) * | 2020-11-03 | 2021-01-26 | 杭州三联油墨化学有限公司 | Hot melt adhesive for radiographic inspection |
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| CN102653665A (en) * | 2012-04-28 | 2012-09-05 | 成都鑫三洋科技发展有限公司 | Hot melt adhesive |
| CN102925080A (en) * | 2012-11-29 | 2013-02-13 | 无锡市万力粘合材料有限公司 | Book thermoplastic binding hot melt glue used at low temperature and preparation method thereof |
-
2013
- 2013-07-01 CN CN201310269527XA patent/CN103387803A/en active Pending
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| CN102925080A (en) * | 2012-11-29 | 2013-02-13 | 无锡市万力粘合材料有限公司 | Book thermoplastic binding hot melt glue used at low temperature and preparation method thereof |
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Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103756580B (en) * | 2014-01-14 | 2015-12-30 | 谢斌 | A kind of for hot melt adhesive film at the bottom of cement footwear and preparation method thereof |
| CN103756580A (en) * | 2014-01-14 | 2014-04-30 | 谢斌 | Hot-melting adhesive film for bonding shoe soles and preparation method thereof |
| CN104497924A (en) * | 2014-11-25 | 2015-04-08 | 四川大学 | New antistatic hot melt adhesive and preparation method thereof |
| CN104497924B (en) * | 2014-11-25 | 2016-08-24 | 四川大学 | A kind of antistatic PUR and preparation method thereof |
| CN104497916A (en) * | 2014-12-15 | 2015-04-08 | 湖州天强绫绢工艺品有限公司 | Ghatpot silk handicraft picture mounting process, EVA (ethylene-vinyl acetate copolymer) hot melt adhesive and modified rosin resin |
| CN104497916B (en) * | 2014-12-15 | 2016-06-08 | 湖州天强绫绢工艺品有限公司 | Thin silk fabric thin,tough silk handicraft picture mounting process, EVA hot-melt adhesive and modified rosin resin |
| CN106362485A (en) * | 2015-07-24 | 2017-02-01 | 上海名冠净化材料股份有限公司 | Purification composite material |
| CN105950087A (en) * | 2016-06-14 | 2016-09-21 | 深圳市优力新材料有限公司 | Novel electret hot-melt adhesive composite and preparation method thereof |
| CN106207033A (en) * | 2016-08-15 | 2016-12-07 | 系统电子科技（镇江）有限公司 | A kind of battery core bracket of high safety performance |
| CN106207033B (en) * | 2016-08-15 | 2019-05-24 | 系统电子科技（镇江）有限公司 | A kind of battery core bracket of high safety performance |
| CN106349567A (en) * | 2016-08-31 | 2017-01-25 | 温州鑫泰新材料股份有限公司 | Teaching and scrawling blackboard pasting composite material and preparation method thereof |
| CN109207094A (en) * | 2017-06-30 | 2019-01-15 | 重庆文理学院 | A kind of EVA melt pressure sensitive gluing agent and preparation method thereof |
| CN107384252B (en) * | 2017-07-20 | 2019-06-25 | 新乡市华洋粘合剂有限公司 | A kind of low temperature resistant joint sealing hot melt adhesive and preparation method thereof |
| CN107384252A (en) * | 2017-07-20 | 2017-11-24 | 毕同召 | A kind of low temperature resistant joint sealing PUR and preparation method thereof |
| CN107400480A (en) * | 2017-08-24 | 2017-11-28 | 蒋磊 | One kind is daily to be made by hand with slow curing type PUR |
| CN108192529A (en) * | 2017-12-13 | 2018-06-22 | 广州艾科洛克建筑材料技术开发有限公司 | A kind of new type hot-melt adhesive that microwave heating can be used and preparation method thereof |
| CN108624257A (en) * | 2018-05-30 | 2018-10-09 | 王召惠 | A kind of modified meerschaum EVA hot-melt adhesive |
| CN109401683B (en) * | 2018-10-25 | 2020-08-21 | 北京文盛印刷材料有限公司 | Hot melt adhesive for book binding and preparation method thereof |
| CN109401683A (en) * | 2018-10-25 | 2019-03-01 | 北京文盛印刷材料有限公司 | Adhesive bookbinding hot melt adhesive and preparation method thereof |
| CN109679532A (en) * | 2018-11-30 | 2019-04-26 | 江苏和和新材料股份有限公司 | A kind of hot melt adhesive film and its production technology for footwear material star actor |
| CN110055030A (en) * | 2019-04-02 | 2019-07-26 | 佛山精展科技有限公司 | A kind of preparation method of hot melt adhesive |
| CN110305623A (en) * | 2019-06-04 | 2019-10-08 | 广州市豪特粘接材料有限公司 | One kind is ridden helmet hot melt adhesive and preparation method thereof |
| CN110467906A (en) * | 2019-08-28 | 2019-11-19 | 佛山市南海骏驰新材料有限公司 | A kind of heat molten type carpenter overlay film glue and its production technology |
| CN111590975A (en) * | 2020-04-13 | 2020-08-28 | 广盟（广州）包装有限公司 | Antibacterial composite cover material film and preparation method thereof |
| CN111363417A (en) * | 2020-04-27 | 2020-07-03 | 广州旭川合成材料有限公司 | Degradable coating and preparation method and application thereof |
| CN111363417B (en) * | 2020-04-27 | 2021-12-10 | 广州旭川合成材料有限公司 | Degradable coating and preparation method and application thereof |
| CN112266756A (en) * | 2020-11-03 | 2021-01-26 | 杭州三联油墨化学有限公司 | Hot melt adhesive for radiographic inspection |
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Application publication date: 20131113 |