CN103254765A - Anti-rust oil employing methyl phenyl silicone oil as base oil and preparation method thereof - Google Patents
Anti-rust oil employing methyl phenyl silicone oil as base oil and preparation method thereof Download PDFInfo
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- CN103254765A CN103254765A CN2013101317067A CN201310131706A CN103254765A CN 103254765 A CN103254765 A CN 103254765A CN 2013101317067 A CN2013101317067 A CN 2013101317067A CN 201310131706 A CN201310131706 A CN 201310131706A CN 103254765 A CN103254765 A CN 103254765A
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- Prior art keywords
- oil
- methyl phenyl
- silicone oil
- phenyl silicone
- preparation
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- 229920003216 poly(methylphenylsiloxane) Polymers 0.000 title claims abstract description 25
- 239000003921 oil Substances 0.000 title claims abstract description 22
- 239000002199 base oil Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title abstract 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 18
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 12
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims abstract description 12
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000919 ceramic Substances 0.000 claims abstract description 6
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims abstract description 6
- 239000004312 hexamethylene tetramine Substances 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 6
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N pentanoic acid group Chemical group C(CCCC)(=O)O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical class CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 abstract description 3
- 239000007921 spray Substances 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical compound O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 abstract 1
- 238000011031 large-scale manufacturing process Methods 0.000 abstract 1
- 229940083037 simethicone Drugs 0.000 abstract 1
- QJJXYPPXXYFBGM-SHYZHZOCSA-N tacrolimus Natural products CO[C@H]1C[C@H](CC[C@@H]1O)C=C(C)[C@H]2OC(=O)[C@H]3CCCCN3C(=O)C(=O)[C@@]4(O)O[C@@H]([C@H](C[C@H]4C)OC)[C@@H](C[C@H](C)CC(=C[C@@H](CC=C)C(=O)C[C@H](O)[C@H]2C)C)OC QJJXYPPXXYFBGM-SHYZHZOCSA-N 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 2
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical class C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses anti-rust oil employing methyl phenyl silicone oil as base oil and a preparation method thereof. The anti-rust oil comprises the components including methyl phenyl silicone oil, hexamethylenetetramine, a film-forming agent, a cross-linking agent TAC, diphenylamine, dimethylbenzene, nano-ceramic powder, ethyl acetate, simethicone, maleic anhydride and dibutyl phthalate. The anti-rust oil prepared by the preparation method is good in adhesive force on metal surface, fast to dry, good in salt spray resistance, environment-friendly and free of pollution. The methyl phenyl silicone oil is adopted as the base oil; and the film-forming agent is added. Thus, the film-forming speed is fast; the surface of the anti-rust oil is not easily oxidized; the appearance of a work-piece is not easily affected; and the overall performance is good. The anti-rust oil is simple in preparation method, low in cost and suitable for large-scale production.
Description
Technical field
The present invention relates to a kind of rush-resisting material, being specifically related to a kind of is the slushing oil and preparation method thereof of base oil with the methyl phenyl silicone oil.
Background technology
Metallic corrosion is to make one of principal mode of fastening piece destruction; can cause very big loss to automobile, motorcycle and various vehicle, machinery; according to statistics; it is annual because the direct economic loss that metallic corrosion causes accounts for the 2-4% of total value of production in national economy; for avoiding corrosion, reducing the loss; people have adopted various methods, protect metal fastenings with antirust grease, are one of present modal means of defences.
Summary of the invention
The object of the present invention is to provide a kind of is the slushing oil and preparation method thereof of base oil with the methyl phenyl silicone oil.
The present invention adopts following technical scheme:
Be the slushing oil of base oil with the methyl phenyl silicone oil, the weight part of its constitutive material is: methyl phenyl silicone oil 80-85, hexamethylenetetramine 1.5-2.0, membrane-forming agent 6.5-7.5, linking agent TAC 3.0-4.5, pentanoic 1.5-2.0, dimethylbenzene 3.0-4.0, nano-ceramic powder 3.5-4.5, ethyl acetate 6.5-7.5, dimethyl silicone oil 6.0-7.0, MALEIC ANHYDRIDE 6.0-8.0 and dibutyl phthalate 10-15.
Be the slushing oil of base oil with the methyl phenyl silicone oil, the weight part of its constitutive material is: methyl phenyl silicone oil 82, hexamethylenetetramine 1.8, membrane-forming agent 7.0, linking agent TAC 3.8, pentanoic 1.8, dimethylbenzene 3.5, nano-ceramic powder 4.0, ethyl acetate 7.0, dimethyl silicone oil 6.5, MALEIC ANHYDRIDE 7.0 and dibutyl phthalate 12.
Be the preparation method of the slushing oil of base oil with the methyl phenyl silicone oil, may further comprise the steps:
(1) measures methyl phenyl silicone oil by the weight part of constitutive material, add heated and stirred in the reactor, add MALEIC ANHYDRIDE during to 110-130 ℃, reaction 30-35min;
(2) in step (1), add membrane-forming agent, linking agent TAC and ethyl acetate, continue to stir, be cooled to 25-30 ℃;
(3) weight part by constitutive material adds other constitutive material in step (2), and continuation gets product after stirring the 3.0-3.5h filtration.
The preparation method of described membrane-forming agent is as follows:
(1) at first 18-22 part ethyl acetate, 3.5-4.5 part dimethylbenzene, 2.0-3.0 part ethylene glycol diglycidylether, 8-12 part E-12 Resins, epoxy are mixed in the adding reactor, reaction is 2-3 hour under 70-110 ℃ of temperature;
(2) in the reactor of step (1), add 15-18 part vinylbenzene, 1.3-1.5 part 2,6 ditertbutylparacresols, 1-2 part vinyltrimethoxy silane, 1.5-1.8 part linking agent TAIC, mix, reaction is 3-5 hour under 50-80 ℃ of temperature condition, namely.
Beneficial effect of the present invention:
Slushing oil, the fast drying good at metallic surface sticking power of the present invention's preparation, salt spray resistance is good, and is environment friendly and pollution-free, and the employing methyl phenyl silicone oil is base oil, and added membrane-forming agent, film forming speed is fast, and the slushing oil surface is difficult for oxidation, is difficult for influencing the outward appearance of workpiece, good combination property, and preparation method of the present invention is simple, and cost is low, is fit to scale operation.
Embodiment
Embodiment 1: be the slushing oil of base oil with the methyl phenyl silicone oil, the weight part of its constitutive material (kg) is: methyl phenyl silicone oil 82, hexamethylenetetramine 1.8, membrane-forming agent 7.0, linking agent TAC 3.8, pentanoic 1.8, dimethylbenzene 3.5, nano-ceramic powder 4.0, ethyl acetate 7.0, dimethyl silicone oil 6.5, MALEIC ANHYDRIDE 7.0 and dibutyl phthalate 12.
Be the preparation method of the slushing oil of base oil with the methyl phenyl silicone oil, may further comprise the steps:
(1) measures methyl phenyl silicone oil by the weight part of constitutive material, add heated and stirred in the reactor, add MALEIC ANHYDRIDE during to 120 ℃, reaction 32min;
(2) in step (1), add membrane-forming agent, linking agent TAC and ethyl acetate, continue to stir, be cooled to 28 ℃;
(3) weight part by constitutive material adds other constitutive material in step (2), and continuation gets product after stirring the 3.2h filtration.
The preparation method of described membrane-forming agent is as follows:
(1) at first 20 parts of ethyl acetate, 4.0 parts of dimethylbenzene, 2.5 parts of ethylene glycol diglycidylethers, 10 parts of E-12 Resins, epoxy are mixed and add in the reactor, reaction is 2.5 hours under 90 ℃ of temperature;
(2) add 17 parts of vinylbenzene, 1.4 part of 2,6 ditertbutylparacresol, 1.5 parts of vinyltrimethoxy silanes, 1.6 parts of linking agent TAIC in the reactor of step (1), mix, reaction is 4 hours under 65 ℃ of temperature condition, namely.
The over-all properties of the slushing oil of above-described embodiment 1 preparation is as follows:
1, sticking power/level≤1 grade; 2, neutral salt spray corrosion test (h) 〉=96; 3, humid heat test (h)＞1150; 4, oil film time of drying (min) 22-25; 5, coating thickness (μ m)＜4.3; 6, ultraviolet (UV) aging test (h)＞420.
Claims (4)
1. one kind is the slushing oil of base oil with the methyl phenyl silicone oil, it is characterized in that the weight part of its constitutive material is: methyl phenyl silicone oil 80-85, hexamethylenetetramine 1.5-2.0, membrane-forming agent 6.5-7.5, linking agent TAC 3.0-4.5, pentanoic 1.5-2.0, dimethylbenzene 3.0-4.0, nano-ceramic powder 3.5-4.5, ethyl acetate 6.5-7.5, dimethyl silicone oil 6.0-7.0, MALEIC ANHYDRIDE 6.0-8.0 and dibutyl phthalate 10-15.
2. according to claim 1 is the slushing oil of base oil with the methyl phenyl silicone oil, it is characterized in that the weight part of its constitutive material is: methyl phenyl silicone oil 82, hexamethylenetetramine 1.8, membrane-forming agent 7.0, linking agent TAC 3.8, pentanoic 1.8, dimethylbenzene 3.5, nano-ceramic powder 4.0, ethyl acetate 7.0, dimethyl silicone oil 6.5, MALEIC ANHYDRIDE 7.0 and dibutyl phthalate 12.
One kind as claimed in claim 1 be the preparation method of the slushing oil of base oil with the methyl phenyl silicone oil, it is characterized in that may further comprise the steps:
(1) measures methyl phenyl silicone oil by the weight part of constitutive material, add heated and stirred in the reactor, add MALEIC ANHYDRIDE during to 110-130 ℃, reaction 30-35min;
(2) in step (1), add membrane-forming agent, linking agent TAC and ethyl acetate, continue to stir, be cooled to 25-30 ℃;
(3) weight part by constitutive material adds other constitutive material in step (2), and continuation gets product after stirring the 3.0-3.5h filtration.
4. according to claim 1 is the slushing oil of base oil with the methyl phenyl silicone oil, and it is characterized in that: the preparation method of described membrane-forming agent is as follows:
(1) at first 18-22 part ethyl acetate, 3.5-4.5 part dimethylbenzene, 2.0-3.0 part ethylene glycol diglycidylether, 8-12 part E-12 Resins, epoxy are mixed in the adding reactor, reaction is 2-3 hour under 70-110 ℃ of temperature;
(2) in the reactor of step (1), add 15-18 part vinylbenzene, 1.3-1.5 part 2,6 ditertbutylparacresols, 1-2 part vinyltrimethoxy silane, 1.5-1.8 part linking agent TAIC, mix, reaction is 3-5 hour under 50-80 ℃ of temperature condition, namely.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101317067A CN103254765A (en) | 2013-04-17 | 2013-04-17 | Anti-rust oil employing methyl phenyl silicone oil as base oil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101317067A CN103254765A (en) | 2013-04-17 | 2013-04-17 | Anti-rust oil employing methyl phenyl silicone oil as base oil and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103254765A true CN103254765A (en) | 2013-08-21 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013101317067A Pending CN103254765A (en) | 2013-04-17 | 2013-04-17 | Anti-rust oil employing methyl phenyl silicone oil as base oil and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103254765A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103757638A (en) * | 2013-12-20 | 2014-04-30 | 吴江邻苏精密机械有限公司 | Solid metal rust-resisting material and preparation method thereof |
| CN104966561A (en) * | 2015-05-11 | 2015-10-07 | 江苏士林电气设备有限公司 | Novel tubular bus with good anti-corrosive property |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1353173A (en) * | 2001-11-21 | 2002-06-12 | 蔡毓英 | Dewatering antirust oil |
| US20070173425A1 (en) * | 2003-11-11 | 2007-07-26 | Nicca Chemical Co., Ltd. | Rust-preventive water-oil separating cleaner composition and a cleaning method using the same |
| CN102634270A (en) * | 2012-03-27 | 2012-08-15 | 马鞍山采石矶涂料有限公司 | Hard film rust preventive oil for train hub rust prevention and preparation method of hard film rust preventive oil |
| CN102876432A (en) * | 2012-09-20 | 2013-01-16 | 吴江市天源塑胶有限公司 | Corrosion-resistant anti-rust oil |
| CN102977981A (en) * | 2012-10-31 | 2013-03-20 | 铜陵瑞莱科技有限公司 | Ferrocene gas-phase slow-release rust preventive oil and preparation method thereof |
-
2013
- 2013-04-17 CN CN2013101317067A patent/CN103254765A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1353173A (en) * | 2001-11-21 | 2002-06-12 | 蔡毓英 | Dewatering antirust oil |
| US20070173425A1 (en) * | 2003-11-11 | 2007-07-26 | Nicca Chemical Co., Ltd. | Rust-preventive water-oil separating cleaner composition and a cleaning method using the same |
| CN102634270A (en) * | 2012-03-27 | 2012-08-15 | 马鞍山采石矶涂料有限公司 | Hard film rust preventive oil for train hub rust prevention and preparation method of hard film rust preventive oil |
| CN102876432A (en) * | 2012-09-20 | 2013-01-16 | 吴江市天源塑胶有限公司 | Corrosion-resistant anti-rust oil |
| CN102977981A (en) * | 2012-10-31 | 2013-03-20 | 铜陵瑞莱科技有限公司 | Ferrocene gas-phase slow-release rust preventive oil and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李东光: "《实用化工产品配方与制备（三）》", 30 September 2011, 中国纺织出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103757638A (en) * | 2013-12-20 | 2014-04-30 | 吴江邻苏精密机械有限公司 | Solid metal rust-resisting material and preparation method thereof |
| CN104966561A (en) * | 2015-05-11 | 2015-10-07 | 江苏士林电气设备有限公司 | Novel tubular bus with good anti-corrosive property |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130821 |
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