CN103232811A - Coating technique of titanium-magnesium alloy foil explosion-proof material - Google Patents
Coating technique of titanium-magnesium alloy foil explosion-proof material Download PDFInfo
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- CN103232811A CN103232811A CN2013101504330A CN201310150433A CN103232811A CN 103232811 A CN103232811 A CN 103232811A CN 2013101504330 A CN2013101504330 A CN 2013101504330A CN 201310150433 A CN201310150433 A CN 201310150433A CN 103232811 A CN103232811 A CN 103232811A
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- explosion
- coating processes
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- proof
- coating
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- 238000000576 coating method Methods 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 25
- 239000011248 coating agent Substances 0.000 title claims abstract description 19
- 239000000463 material Substances 0.000 title claims description 8
- 229910000861 Mg alloy Inorganic materials 0.000 title claims description 7
- SXSVTGQIXJXKJR-UHFFFAOYSA-N [Mg].[Ti] Chemical compound [Mg].[Ti] SXSVTGQIXJXKJR-UHFFFAOYSA-N 0.000 title claims description 7
- 239000011888 foil Substances 0.000 title 1
- 239000000758 substrate Substances 0.000 claims abstract description 13
- 239000002245 particle Substances 0.000 claims abstract description 8
- 230000008021 deposition Effects 0.000 claims abstract description 7
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 6
- 239000004642 Polyimide Substances 0.000 claims abstract description 6
- 239000004917 carbon fiber Substances 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920001721 polyimide Polymers 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000005507 spraying Methods 0.000 claims abstract description 4
- 230000001680 brushing effect Effects 0.000 claims abstract description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 10
- 230000035800 maturation Effects 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 7
- 230000001681 protective effect Effects 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 6
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 5
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 4
- 238000005137 deposition process Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 3
- -1 rare-earth compound Chemical class 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 230000032683 aging Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000007739 conversion coating Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229940125773 compound 10 Drugs 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a coating technique of an anticorrosive paint, which comprises the following steps: mixing siloxane, solvent, silicon dioxide particle, rare-earth compound, deionized water, catalyst, carbon fiber, polyimide and other components, aging, filtering the aged mixture, and applying the mixture on an explosion-proof substrate surface by spraying, brushing or impregnation to form a coating on the explosion-proof substrate surface after deposition, thereby implementing surface anticorrosion treatment.
Description
Technical field
The present invention relates to a kind of protective system coating processes, relate in particular to the tinsel explosion-proof lamp, the coating processes of titanium magnesium alloy paper tinsel explosion-proof lamp particularly, this method is used the environmental protection coating material of aromatic free solvent.
Background technology
In modern industry and daily life; corrosion of metal is seen everywhere; especially crevice corrosion, stress corrosion and the corrosion fatigue, the particularly destruction of the forms such as corrosion of metal explosion-proof lamp that takes place in the fuel oil dangerization product storage vessel causes great potential safety hazard for people's lives.The manufacturing process of described metal explosion-proof lamp generally includes: ingot casting, be rolled into paper tinsel, grooving machine joint-cutting, drawing and forming Web materials.
The metal protection method that adopts can roughly be divided three classes at present: a class is to carry out anodic oxidation treatment, namely form the anode oxide film of one deck tens micron thickness in the metallic surface, but because the anode oxidation process power consumption is big, and electrolyte solution is seriously polluted, be difficult to handle, use its application to be restricted; Second class is chemical conversion film, being about to metal parts is immersed in the solution of definite composition, rely on chemical reaction to form one deck chemical conversion film at a certain temperature, wherein most widely used is the oxidation of chromic salt chemistry, but chromic salt is a kind of carcinogenic toxicant, and the world environments protective tissue has proposed restriction and used chromic salt and other to contain chromate compound; The 3rd class is organic coating, namely applies one deck organic coating in the metallic surface, with outward appearance and the physical and chemical performance that improves metal.People begin rare earth element is used in the aseptic technic of metallic surface in recent years.
The rare-earth conversion coatings film technique develops into today, and people have carried out a large amount of improvement to various film-forming process, and the performance of film also is improved.The rare-earth conversion coatings technology mainly is immersion treatment, and this technological operation is simple, be easy to safeguard; But its drawback is that the long period of soaking process treatment time is oversize, and formed rete is thinner and relatively poor with the sticking power of explosion-proof base material.Discover through long-term exploration, in soaking solution, add strong oxidizer, as H
2O
2, KMnO
4, (NH
4)
2S
2O
8Etc. strong oxide compound, rate of film build is improved greatly, the treatment time shortens dramatically, and simultaneously the treatment soln temperature is not high yet, can at room temperature use, but because the existence of strong oxidizer makes the less stable for the treatment of process.
In order to solve the problem that the rare-earth conversion coatings treatment process exists, the present invention proposes a kind of improved protective system coating processes.This method anticorrosion with low cost, remarkable in economical benefits can be carried out normal temperature and be spread, and coating processes is simple, and solution is environment friendly and pollution-free.
Summary of the invention
The objective of the invention is at the deficiencies in the prior art part, a kind of coating processes of environment friendly corrosion protection coating is provided, in order to solve the tinsel explosion-proof lamp, especially the protection against corrosion difficult problem of titanium magnesium alloy paper tinsel explosion-proof lamp external coating, and coating aromatic free solvent, do not contain strong oxidizer, do not have poisonous pigment, be fit to various constructional methods.Application is not subject to seasonal restrictions, and construction technology is simple and convenient, and technical costs is cheap, good environmental protection.
The present invention is achieved by the following technical solutions:
(1) prepare following component (mass parts):
A methacryloxypropyl trimethoxy silane 1-10;
B propyl alcohol 40-60;
C SiO
2Particle 1-5;
The oxide compound 6-10 of d praseodymium;
E deionized water 5-25;
F acetic acid 4-6;
G carbon fiber 5-7;
H polyimide 1-3;
K. zirconium white 5-10;
(2) with carrying out maturation process after the above component mixing, spray, brush or be immersed in explosion-proof substrate surface then, the deposition back forms coating at explosion-proof substrate surface, realizes the surface anticorrosion processing.
Described SiO
2Particle grain size is the 50-100 nanometer.
Described maturation process is to leave standstill at normal temperatures 50-60 hour.
Described explosion-proof base material is the tinsel explosion-proof lamp, preferred titanium magnesium alloy paper tinsel explosion-proof lamp.
Heat in the deposition process after spraying, brushing or dipping, Heating temperature is to heat 1 minute to 1 hour under 50 ℃ to the 150 ℃ temperature.
The thickness of described coating is 1 micron to 10 microns, preferred 1 micron to 5 microns.The preferred method that adopts spraying or brush forms coating at explosion-proof substrate surface.
Embodiment
The present invention relates to a kind of coating processes of protective system, after being mixed, the various components of protective system carry out maturation process, again the mixture after the slaking is filtered, spray, brush or be immersed in explosion-proof substrate surface then, the deposition back forms coating at explosion-proof substrate surface, realizes the surface anticorrosion processing.
Protective system coating processes disclosed by the invention is simple, convenient, quick, reliable, and raw material is cheap, this method can be simply in conjunction with enter the existing pre-treatment that comprises coating and after in the conventional production line of other postprocessing working procedures of explosion-proof substrate material, substantially need not to carry out other adjustment on the equipment, is the Eco-power production technique of a kind of height.
Elaborate with the present invention of embodiment below, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1
(1) prepare following component (mass parts):
A methacryloxypropyl trimethoxy silane 1;
B propyl alcohol 40;
C SiO
2Particle 1;
The oxide compound 6 of d praseodymium;
E deionized water 5;
F acetic acid 4;
G carbon fiber 5;
H polyimide 1;
K. zirconium white 7;
(2) with carrying out maturation process after the above component mixing, spray, brush or be immersed in explosion-proof substrate surface then, the deposition back forms coating at explosion-proof substrate surface, realizes the surface anticorrosion processing.
Embodiment 2
(1) prepare following component (mass parts):
A methacryloxypropyl trimethoxy silane 10;
B propyl alcohol 60;
C SiO
2Particle 5;
The oxide compound 10 of d praseodymium;
E deionized water 25;
F acetic acid 6;
G carbon fiber 7;
H polyimide 3;
K. zirconium white 10;
(2) with carrying out maturation process after the above component mixing, spray, brush or be immersed in tinsel explosion-proof lamp surface then, the deposition back forms coating on the explosion-proof lamp surface, and the realization surface anticorrosion is handled.
Embodiment 3
(1) prepare following component (mass parts):
A methacryloxypropyl trimethoxy silane 5;
B propyl alcohol 50;
C SiO
2Particle 3;
The oxide compound 8 of d praseodymium;
E deionized water 15;
F acetic acid 5;
G carbon fiber 6;
H polyimide 2;
K. zirconium white 5;
(2) with carrying out maturation process after the above component mixing, spray, brush or be immersed in titanium magnesium alloy paper tinsel explosion-proof lamp surface then, the deposition back forms coating on the explosion-proof lamp surface, and the realization surface anticorrosion is handled.
Claims (9)
1. the coating processes of a protective system comprises:
(1) prepare following component (mass parts):
A methacryloxypropyl trimethoxy silane 1-10;
B propyl alcohol 40-60;
C SiO
2Particle 1-5;
The oxide compound 6-10 of d praseodymium;
E deionized water 5-25;
F acetic acid 4-6;
G carbon fiber 5-7;
H polyimide 1-3;
K. zirconium white 5-10;
(2) with carrying out maturation process after the said components mixing, spray, brush or be immersed in explosion-proof substrate surface then, the deposition back forms coating at explosion-proof substrate surface, realizes the surface anticorrosion processing.
2. coating processes according to claim 1 is characterized in that, described SiO
2Particle grain size is the 50-100 nanometer.
3. coating processes according to claim 1 is characterized in that, described maturation process is to leave standstill at normal temperatures 50-60 hour.
4. coating processes according to claim 1 is characterized in that, described explosion-proof base material is the tinsel explosion-proof lamp.
5. coating processes according to claim 1 is characterized in that, described explosion-proof base material is titanium magnesium alloy paper tinsel explosion-proof lamp.
6. coating processes according to claim 1 is characterized in that, heats in described deposition process, and Heating temperature is 50 ℃ to 150 ℃, 1 minute to 1 hour heat-up time.
7. coating processes according to claim 1 is characterized in that, described coat-thickness is 1 micron to 10 microns.
8. coating processes according to claim 7 is characterized in that, described coat-thickness is 1 micron to 5 microns.
9. coating processes according to claim 1 is characterized in that, adopts the method for spraying or brushing to form coating at explosion-proof substrate surface in the described step (2).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101504330A CN103232811A (en) | 2013-04-27 | 2013-04-27 | Coating technique of titanium-magnesium alloy foil explosion-proof material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013101504330A CN103232811A (en) | 2013-04-27 | 2013-04-27 | Coating technique of titanium-magnesium alloy foil explosion-proof material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103232811A true CN103232811A (en) | 2013-08-07 |
Family
ID=48880884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013101504330A Pending CN103232811A (en) | 2013-04-27 | 2013-04-27 | Coating technique of titanium-magnesium alloy foil explosion-proof material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103232811A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1823143A (en) * | 2003-07-15 | 2006-08-23 | 达克拉尔 | Use of yttrium, zirconium, lanthanum, cerium, praseodymium and/or neodymium as reinforcing agents for anticorrosion coating compositions |
| CN101747835A (en) * | 2008-12-01 | 2010-06-23 | 中国科学院过程工程研究所 | Elastic anti-corrosion coating |
| CN102174289A (en) * | 2011-02-25 | 2011-09-07 | 上海交通大学 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
| CN102604448A (en) * | 2012-01-20 | 2012-07-25 | 北京北矿锌业有限责任公司 | Material used for metal anti-corrosion coating |
| CN102964990A (en) * | 2012-12-10 | 2013-03-13 | 青岛天鹅针织有限公司 | Aromatic-hydrocarbon-free anticorrosion method of metal structure |
-
2013
- 2013-04-27 CN CN2013101504330A patent/CN103232811A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1823143A (en) * | 2003-07-15 | 2006-08-23 | 达克拉尔 | Use of yttrium, zirconium, lanthanum, cerium, praseodymium and/or neodymium as reinforcing agents for anticorrosion coating compositions |
| CN101747835A (en) * | 2008-12-01 | 2010-06-23 | 中国科学院过程工程研究所 | Elastic anti-corrosion coating |
| CN102174289A (en) * | 2011-02-25 | 2011-09-07 | 上海交通大学 | Surface anti-corrosion sol for aeronautic aluminum alloy material and treatment method thereof |
| CN102604448A (en) * | 2012-01-20 | 2012-07-25 | 北京北矿锌业有限责任公司 | Material used for metal anti-corrosion coating |
| CN102964990A (en) * | 2012-12-10 | 2013-03-13 | 青岛天鹅针织有限公司 | Aromatic-hydrocarbon-free anticorrosion method of metal structure |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130807 |