CN103224731B - Pinkish red UV ink-jet ink for high-speed ink-jet printing and preparation method thereof - Google Patents
Pinkish red UV ink-jet ink for high-speed ink-jet printing and preparation method thereof Download PDFInfo
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- CN103224731B CN103224731B CN201210408370.XA CN201210408370A CN103224731B CN 103224731 B CN103224731 B CN 103224731B CN 201210408370 A CN201210408370 A CN 201210408370A CN 103224731 B CN103224731 B CN 103224731B
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- 238000007641 inkjet printing Methods 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 47
- 239000000178 monomer Substances 0.000 claims abstract description 36
- 238000003756 stirring Methods 0.000 claims abstract description 29
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000002270 dispersing agent Substances 0.000 claims abstract description 23
- 239000000049 pigment Substances 0.000 claims abstract description 13
- 238000000227 grinding Methods 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 7
- -1 polysiloxanes Polymers 0.000 claims description 18
- 229920000178 Acrylic resin Polymers 0.000 claims description 17
- 239000004925 Acrylic resin Substances 0.000 claims description 17
- WZXNKIQZEIEZEA-UHFFFAOYSA-N ethyl 2-(2-ethoxyethoxy)prop-2-enoate Chemical compound CCOCCOC(=C)C(=O)OCC WZXNKIQZEIEZEA-UHFFFAOYSA-N 0.000 claims description 13
- KTALPKYXQZGAEG-UHFFFAOYSA-N 2-propan-2-ylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C(C)C)=CC=C3SC2=C1 KTALPKYXQZGAEG-UHFFFAOYSA-N 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 claims description 12
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 9
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 6
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 claims description 6
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 6
- 238000001723 curing Methods 0.000 claims description 6
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 claims description 5
- RZVINYQDSSQUKO-UHFFFAOYSA-N 2-phenoxyethyl prop-2-enoate Chemical group C=CC(=O)OCCOC1=CC=CC=C1 RZVINYQDSSQUKO-UHFFFAOYSA-N 0.000 claims description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 5
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 claims description 4
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 claims description 4
- 229920003180 amino resin Polymers 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 claims description 4
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- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 2
- NNAHKQUHXJHBIV-UHFFFAOYSA-N 2-methyl-1-(4-methylthiophen-2-yl)-2-morpholin-4-ylpropan-1-one Chemical compound CC1=CSC(C(=O)C(C)(C)N2CCOCC2)=C1 NNAHKQUHXJHBIV-UHFFFAOYSA-N 0.000 claims description 2
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 claims description 2
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- NQSMEZJWJJVYOI-UHFFFAOYSA-N Methyl 2-benzoylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 NQSMEZJWJJVYOI-UHFFFAOYSA-N 0.000 claims description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 claims description 2
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 claims description 2
- GUCYFKSBFREPBC-UHFFFAOYSA-N [phenyl-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone Chemical group CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C(=O)C1=C(C)C=C(C)C=C1C GUCYFKSBFREPBC-UHFFFAOYSA-N 0.000 claims description 2
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 2
- 229920000180 alkyd Polymers 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 claims description 2
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 2
- 229940119545 isobornyl methacrylate Drugs 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- LUCXVPAZUDVVBT-UHFFFAOYSA-N methyl-[3-(2-methylphenoxy)-3-phenylpropyl]azanium;chloride Chemical compound Cl.C=1C=CC=CC=1C(CCNC)OC1=CC=CC=C1C LUCXVPAZUDVVBT-UHFFFAOYSA-N 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims 1
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- 238000007639 printing Methods 0.000 abstract description 23
- 239000000463 material Substances 0.000 abstract description 4
- 239000000976 ink Substances 0.000 description 59
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- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 5
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- 239000002253 acid Substances 0.000 description 4
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- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 description 3
- BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 description 3
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- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
本发明涉及一种用于高速喷墨印刷的品红UV喷墨油墨及其制备方法,其承印材料主要为纸张类,属于数字印刷技术领域。油墨的组成和重量配比为:色浆15-30份,单体20-35份,成膜树脂40-50份,光引发剂1-10份;色浆配方中品红颜料10-25份,预聚物15-30份,单体40-60份,分散剂4-10份。本发明的油墨可通过搅拌和高速研磨的方法制备。本发明品红UV喷墨油墨符合喷墨印刷的要求,粒径小于0.5μm,粘度为20~30cP(25℃),表面张力为20~35mN/m(25℃),固化速度为30~50m/min(光源线功率为200W/cm),电导率为<18μs/cm。The invention relates to a magenta UV inkjet ink for high-speed inkjet printing and a preparation method thereof. The printing material is mainly paper, and belongs to the technical field of digital printing. The composition and weight ratio of the ink are: 15-30 parts of color paste, 20-35 parts of monomer, 40-50 parts of film-forming resin, 1-10 parts of photoinitiator; 10-25 parts of magenta pigment in the color paste formula , 15-30 parts of prepolymer, 40-60 parts of monomer, 4-10 parts of dispersant. The ink of the present invention can be prepared by stirring and high-speed grinding. The magenta UV inkjet ink of the present invention meets the requirements of inkjet printing, the particle size is less than 0.5μm, the viscosity is 20~30cP (25°C), the surface tension is 20~35mN/m (25°C), and the curing speed is 30~50m /min (the power of the light source is 200W/cm), and the conductivity is <18μs/cm.
Description
技术领域 technical field
本发明涉及一种用于高速喷墨印刷的品红紫外(UV)喷墨油墨及其制备方法,其承印材料主要为纸张类,属于数字印刷技术领域。The invention relates to a magenta ultraviolet (UV) inkjet ink for high-speed inkjet printing and a preparation method thereof. The printing material is mainly paper, and belongs to the technical field of digital printing.
背景技术 Background technique
UV固化技术的关键优势就是不含溶剂,没有VOC排放、避免了传统溶剂型油墨对环境所带来的影响,被认为是一种“绿色技术”,并且可实现瞬时固化,油墨干燥速度高于水性或溶剂型油墨,但是UV油墨主要应用在传统的印刷方式中,比如胶印、丝印等。喷墨印刷作为数字印刷技术的一种,具有非撞击转印、操作简单、对承印材料要求不高等优点,将UV固化技术与喷墨印刷相结合的印刷设备已经面世,对相应的UV喷墨油墨的需求将会加大。The key advantage of UV curing technology is that it does not contain solvents, has no VOC emissions, and avoids the impact of traditional solvent-based inks on the environment. It is considered a "green technology" and can achieve instant curing. The drying speed of the ink is higher than that of Water-based or solvent-based inks, but UV inks are mainly used in traditional printing methods, such as offset printing, silk screen printing, etc. As a kind of digital printing technology, inkjet printing has the advantages of non-impact transfer printing, simple operation, and low requirements for printing materials. Printing equipment that combines UV curing technology with inkjet printing has been released. For the corresponding UV inkjet printing Ink demand will increase.
目前已有专利提出了多种可辐射固化的喷墨油墨,但是这些油墨的应用仅局限于喷绘、印染,还远远达不到高速喷墨印刷的要求。At present, patents have proposed a variety of radiation-curable inkjet inks, but the application of these inks is limited to inkjet printing, printing and dyeing, and is far from meeting the requirements of high-speed inkjet printing.
发明内容 Contents of the invention
本发明提供了一种新型品红UV喷墨油墨配方及其制备方法。本UV喷墨油墨的研发针对的印刷方式为高速喷墨印刷,其承印材料主要为纸张类,为了满足高速喷墨印刷的要求,油墨的物化性能必须符合相关喷墨印刷设备的需要。由于颜料不溶于体系,颜料颗粒在体系中的分散性及分散稳定性是重要性能之一,否则会导致喷头的堵塞,UV体系不同于水和溶剂,颜料颗粒必须能够均匀分散在体系中并保持稳定才能不会出现团聚的现象才能防止堵塞喷头,普通的水性和溶剂型喷墨油墨或用于喷绘、印染的UV油墨的颗粒粒径一般在1μm以上,而用于高速喷墨印刷的UV油墨需要达到0.5μm以下。市场上两种最主要的按需喷墨技术是热喷墨和压电喷墨,不同工作方式的喷头对油墨粘度的要求不同,根据油墨类型又可分为水性喷头、溶剂型喷头和UV用喷头,SPECTRA和XAAR推出的UV用喷头已在UV喷墨印刷机上有所应用,UV用喷头大部分是压电类型,对油墨粘度要求较高,通常为20-30cP(25℃)。UV喷墨油墨在紫外光的照射下,体系中的各组分发生反应而固化,要求固化速度为30-50m/min(光源线功率为200W/cm)。在喷墨印刷中,墨滴的喷射及成形过程将受到流体物理属性的影响,射流颈缩是墨滴生成的必要前提,而表面张力是射流颈缩的主要推动力,故油墨的表面张力是墨滴喷射的动力源,影响着墨滴的最终形状和飞行轨迹,乃至于影响最终的复制质量,表面张力要求为20-35mN/m(25℃)。The invention provides a novel magenta UV inkjet ink formula and a preparation method thereof. The printing method of this UV inkjet ink research and development is high-speed inkjet printing, and its printing material is mainly paper. In order to meet the requirements of high-speed inkjet printing, the physical and chemical properties of the ink must meet the needs of related inkjet printing equipment. Since the pigment is insoluble in the system, the dispersibility and dispersion stability of the pigment particles in the system are one of the important properties, otherwise it will lead to the clogging of the nozzle. The UV system is different from water and solvents, and the pigment particles must be able to disperse evenly in the system and maintain Stability can prevent the phenomenon of agglomeration to prevent nozzle clogging. The particle size of ordinary water-based and solvent-based inkjet inks or UV inks used for inkjet printing and printing and dyeing is generally above 1 μm, while UV inks used for high-speed inkjet printing It needs to be 0.5 μm or less. The two most important on-demand inkjet technologies in the market are thermal inkjet and piezoelectric inkjet. The nozzles with different working methods have different requirements for ink viscosity. According to the type of ink, they can be divided into water-based nozzles, solvent-based nozzles and UV nozzles. Nozzles, the UV nozzles launched by SPECTRA and XAAR have been used in UV inkjet printers. Most of the UV nozzles are piezoelectric types, which require high ink viscosity, usually 20-30cP (25°C). UV inkjet ink is irradiated by ultraviolet light, each component in the system reacts and cures, and the curing speed is required to be 30-50m/min (the line power of the light source is 200W/cm). In inkjet printing, the ejection and forming process of ink droplets will be affected by the physical properties of the fluid. Jet necking is a necessary prerequisite for the formation of ink droplets, and surface tension is the main driving force for jet necking. Therefore, the surface tension of ink is The power source of ink drop ejection affects the final shape and flight trajectory of ink droplets, and even affects the final reproduction quality. The surface tension requirement is 20-35mN/m (25°C).
为了达到以上目的,本发明采取以下技术方案:In order to achieve the above object, the present invention takes the following technical solutions:
一种品红UV喷墨油墨,,主要用于高速喷墨印刷,由颜料、预聚物、单体和助剂组成,具体包括如下的组成和重量配比:A magenta UV inkjet ink, mainly used for high-speed inkjet printing, consists of pigments, prepolymers, monomers and additives, specifically including the following composition and weight ratio:
油墨配方:Ink formula:
其中,色浆配方(重量配比)为:Among them, the color paste formula (weight ratio) is:
本发明中的品红颜料为不溶性的着色剂,耐水性、耐色牢度较好,选自偶氮红、洋红、喹吖啶酮红、喹吖啶酮和吡咯并吡咯二酮混合红等中的一种。The magenta pigment in the present invention is an insoluble coloring agent with good water resistance and color fastness, and is selected from azo red, magenta, quinacridone red, quinacridone and diketopyrrolopyrrole mixed red, etc. One of.
所述的预聚物和成膜树脂分别为选自环氧丙烯酸树脂、聚氨酯丙烯酸树脂、聚酯丙烯酸树脂、氯醋树脂、氨基丙烯酸树脂、醇酸树脂、脲醛树脂、甲醚化氨基树脂、丁醚化氨基树脂、双酚A环氧丙烯酸酯、UV氟碳树脂和磷酸改性丙烯酸酯中的一种或两种以上的混合物。预聚物和成膜树脂可以相同,也可以不同。The prepolymer and film-forming resin are respectively selected from epoxy acrylic resin, polyurethane acrylic resin, polyester acrylic resin, vinyl acetate resin, aminoacrylic resin, alkyd resin, urea-formaldehyde resin, methyl etherified amino resin, butyl One or more mixtures of etherified amino resin, bisphenol A epoxy acrylate, UV fluorocarbon resin and phosphoric acid modified acrylate. The prepolymer and film-forming resin may be the same or different.
所述的单体为2-苯氧基乙基丙烯酸酯、丙烯酸酯丁酯、氨基甲酸酯单丙烯酸酯、丙烯酸异冰片酯、甲基丙烯酸异冰片酯、丙烯酸双环戊烯基酯、丙烯酸2-乙氧乙氧基乙酯、1,4-丁二醇二丙烯酸酯、丙氧基化新戊二醇二丙烯酸酯、二缩三乙二醇二甲基丙烯酸酯、丙烯酸2—乙基己酯、己二醇二丙烯酸酯、邻苯二甲酸二乙醇二丙烯酸酯、新戊二醇二丙烯酸酯、二缩三乙二醇二丙烯酸酯、二缩三丙二醇二丙烯酸酯、三羟甲基丙烷三丙烯酸酯、乙氧基化的三羟甲基丙烷三丙烯酸酯、三羟甲基丙烷三甲基丙烯酸酯、丙氧化三羟甲基丙烷三丙烯酸酯、双季戊四醇六丙烯酸酯中的一种或两种以上的混合物。The monomers are 2-phenoxyethyl acrylate, butyl acrylate, urethane monoacrylate, isobornyl acrylate, isobornyl methacrylate, dicyclopentenyl acrylate, acrylic acid 2 -Ethoxyethoxyethyl ester, 1,4-butanediol diacrylate, propoxylated neopentyl glycol diacrylate, triethylene glycol dimethacrylate, 2-ethylhexyl acrylate Ester, Hexylene Glycol Diacrylate, Diethylene Glycol Diacrylate, Neopentyl Glycol Diacrylate, Triethylene Glycol Diacrylate, Tripropylene Glycol Diacrylate, Trimethylol Propane One of triacrylate, ethoxylated trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, propoxylated trimethylolpropane triacrylate, dipentaerythritol hexaacrylate or A mixture of two or more.
所述的分散剂为改性丙烯酸盐嵌段共聚物、烯酸嵌段共聚物、带有锚式基团的超分散剂和有机改性聚硅氧烷中的一种或两种以上。优选为BYK公司的disperbyk系列的改性丙烯酸盐嵌段共聚物,BASF公司的EFKA系列的烯酸嵌段共聚物,上海三正公司的CH系列的带有锚式基团的超分散剂,TEGO公司的dispers系列的含有机改性聚硅氧烷的润湿分散剂。The dispersant is one or more of modified acrylate block copolymers, alkene acid block copolymers, hyperdispersants with anchor groups and organically modified polysiloxanes. It is preferably the modified acrylate block copolymer of the disperbyk series of BYK company, the olefin acid block copolymer of the EFKA series of BASF company, the CH series hyperdispersant with anchor group of Shanghai Sanzheng company, TEGO The company's dispersers series of wetting and dispersing agents containing organomodified polysiloxanes.
所述的光引发剂为苯基双(2,4,6-三甲基苯甲酰基)氧化膦、1-(4-吗啉苯基)-2-(二甲基胺)-2-苄基-1-丁酮、2-苯甲酰基苯甲酸甲酯、4-苯基二苯甲酮、2,4,6-三甲基苯甲酰基-二苯基氧化膦、2-羟基-2-甲基-1-苯基-1-丙酮、1-羟基-环已基-苯基甲酮、2-甲基-1-[4-甲硫基苯基]-2-吗啉基-1-丙酮、安息香双甲醚、2-异丙基硫杂蒽酮和2,4-二乙基硫杂蒽酮中的一种或两种以上的混合物。The photoinitiator is phenyl bis(2,4,6-trimethylbenzoyl) phosphine oxide, 1-(4-morpholine phenyl)-2-(dimethylamine)-2-benzyl -1-butanone, 2-benzoylbenzoic acid methyl ester, 4-phenylbenzophenone, 2,4,6-trimethylbenzoyl-diphenylphosphine oxide, 2-hydroxy-2 -Methyl-1-phenyl-1-propanone, 1-hydroxy-cyclohexyl-phenylmethanone, 2-methyl-1-[4-methylthiophenyl]-2-morpholinyl-1 - One or a mixture of two or more of acetone, benzoin dimethyl ether, 2-isopropylthioxanthone and 2,4-diethylthioxanthone.
夺氢型光引发剂需要配合助引发剂——氢供体,氢供体主要为叔胺类化合物,如脂肪族叔胺、乙醇胺类叔胺、叔胺型苯甲酸酯、活性胺等。光引发剂2-异丙基硫杂蒽酮和2,4-二乙基硫杂蒽酮为夺氢型,需要氢供体,重量比为2-异丙基硫杂蒽酮或2,4-二乙基硫杂蒽酮:氢供体=2:1。The hydrogen abstraction photoinitiator needs to be combined with a co-initiator-hydrogen donor, and the hydrogen donor is mainly a tertiary amine compound, such as aliphatic tertiary amine, ethanolamine tertiary amine, tertiary amine benzoate, active amine, etc. The photoinitiator 2-isopropylthioxanthone and 2,4-diethylthioxanthone are hydrogen abstraction type, need hydrogen donor, the weight ratio is 2-isopropylthioxanthone or 2,4 - Diethylthioxanthone: hydrogen donor = 2:1.
所述流平剂为聚丙烯酸酯类聚合物、聚醚改性聚硅氧烷共聚物、有机硅聚合物的一种或两种以上。优选常州市宏亚化工有限公司HY3066和BYK公司BYK-300、BYK-306、BYK-307、BYK-310、BYK-315、BYK-320、BYK-323、BYK-325、BYK-331、BYK-333、BYK-335、BYK-337、BYK-344、BYK-346、BYK-354、BYK-356、BYK-358N、BYK-361N、BYK-370、BYK-371、BYK-390、BYK-410、BYK-077的聚丙烯酸酯类聚合物,长辉集团BNK-LK600和南京德诺化工DN-1082的聚醚改性聚硅氧烷共聚物,迪高公司100、300、432、435、460、450、484的有机硅聚合物。The leveling agent is one or more of polyacrylate polymers, polyether-modified polysiloxane copolymers, and silicone polymers. Changzhou Hongya Chemical Co., Ltd. HY3066 and BYK Company BYK-300, BYK-306, BYK-307, BYK-310, BYK-315, BYK-320, BYK-323, BYK-325, BYK-331, BYK- 333, BYK-335, BYK-337, BYK-344, BYK-346, BYK-354, BYK-356, BYK-358N, BYK-361N, BYK-370, BYK-371, BYK-390, BYK-410, Polyacrylate polymer of BYK-077, polyether-modified polysiloxane copolymer of BNK-LK600 of Changhui Group and DN-1082 of Nanjing Denuo Chemical Industry Co., Ltd. 100, 300, 432, 435, 460, 450, 484 silicone polymers.
上述品红UV喷墨油墨的制备方法,包括如下步骤:The preparation method of above-mentioned magenta UV inkjet ink, comprises the steps:
(1)将预聚物、单体和分散剂混合,搅拌混合均匀,得到A组分;(1) Mix the prepolymer, monomer and dispersant, stir and mix evenly to obtain component A;
(2)将品红颜料加入A组分中,先置于电动搅拌器上进行预分散,然后倒入研磨机进行高速研磨,使颜料在连接料(成膜树脂、单体和分散剂)中充分润湿分散,得到油墨色浆,即B组分;(2) Add magenta pigment to component A, place it on an electric mixer for pre-dispersion, then pour it into a grinder for high-speed grinding, so that the pigment is in the binder (film-forming resin, monomer and dispersant) Fully wet and disperse to obtain ink color paste, that is, component B;
(3)将成膜树脂、单体、流平剂和光引发剂或光引发剂和助引发剂按照油墨配方混合配制成油墨稀释剂,得到C组分;(3) Mix the film-forming resin, monomer, leveling agent and photoinitiator or photoinitiator and co-initiator according to the ink formula to prepare ink diluent to obtain component C;
(4)将B组分与C组分混合,使用电动搅拌器搅拌均匀,得到所述油墨。(4) Mix component B and component C, and stir evenly with an electric mixer to obtain the ink.
步骤(1)中,所述的A组分放置在恒温磁力搅拌器上搅拌混合均匀,搅拌时间为20~40min,(常温)。如果是固态分散剂,须先在一定温度下加热使其溶解。In step (1), the component A is placed on a constant temperature magnetic stirrer to stir and mix evenly, and the stirring time is 20-40min, (normal temperature). If it is a solid dispersant, it must be heated at a certain temperature to dissolve it.
步骤(2)中,所述的B组分的预分散时间为20~40min,预分散的速率为330r/min~800r/min。高速研磨时间为60~120mim,高速研磨的速率为1800r/min~2500r/min。In step (2), the pre-dispersion time of the B component is 20-40 minutes, and the pre-dispersion rate is 330r/min-800r/min. The high-speed grinding time is 60~120mim, and the speed of high-speed grinding is 1800r/min~2500r/min.
步骤(4)中,所述的B组分和C组分混合,搅拌时间为30~60mim。In step (4), the components B and C are mixed, and the stirring time is 30-60 min.
本发明品红UV喷墨油墨符合喷墨印刷的要求,粒径小于0.5μm,粘度为20-30cP(25℃),表面张力为20-35mN/m(25℃),固化速度为30-50m/min(光源线功率为200W/cm),电导率为<18μs/cm,使用速度为80m/min的UV喷墨印刷机进行印刷获得印刷样张,通过基于工业CCD的数字质量评价系统对印刷样张进行评价,印刷质量较好。The magenta UV inkjet ink of the present invention meets the requirements of inkjet printing, the particle size is less than 0.5μm, the viscosity is 20-30cP (25°C), the surface tension is 20-35mN/m (25°C), and the curing speed is 30-50m /min (the line power of the light source is 200W/cm), the conductivity is <18μs/cm, and the printing sample is obtained by printing with a UV inkjet printer with a speed of 80m/min, and the printing sample is evaluated by the digital quality evaluation system based on industrial CCD Evaluation, printing quality is good.
本发明品红UV喷墨油墨的制备方法,由色浆和油墨制备两步,所需设备为电动搅拌器和高速研磨设备,工艺简单。The preparation method of the magenta UV inkjet ink of the present invention comprises two steps of preparing the color paste and the ink, and the required equipment is an electric stirrer and high-speed grinding equipment, and the process is simple.
本发明的品红UV喷墨油墨是由市售的颜料、预聚物、单体和助剂等制备加工而成。本发明的品红UV喷墨油墨可应用于喷墨印刷设备,主要针对短版印刷活件,可实现按需和可变数据印刷,操作方便。The magenta UV inkjet ink of the present invention is prepared and processed from commercially available pigments, prepolymers, monomers and auxiliary agents. The magenta UV inkjet ink of the present invention can be applied to inkjet printing equipment, mainly for short-run printing jobs, can realize on-demand and variable data printing, and is easy to operate.
具体实施方式 Detailed ways
下面结合具体实施例,进一步阐述本发明。应理解,这些实施例仅用于说明本发明而不用于限制本发明的范围。此外,本领域技术人员对本发明所做的各种改动或修改,这些等价形式同样落于本申请所要求保护的范围内。本发明实施例中的配比均为以重量计。Below in conjunction with specific embodiment, further illustrate the present invention. It should be understood that these examples are only used to illustrate the present invention and are not intended to limit the scope of the present invention. In addition, various changes or modifications made by those skilled in the art to the present invention, and these equivalent forms also fall within the scope of protection claimed by the present application. The proportions in the embodiments of the present invention are all by weight.
【实施例1】【Example 1】
将预聚物30份、单体42份、分散剂8份混合,放置在恒温磁力搅拌器上搅拌30分钟混合均匀;加入偶氮红20份,使用搅拌器将混合物搅拌30分钟进行预分散后,使用高速研磨机研磨90分钟,得到品红油墨色浆。其中偶氮红选自汽巴公司的RT-355-D,预聚物为超支化的聚酯丙烯酸树脂选自氰特公司的EB150系列,单体为市售的丙烯酸2-乙氧乙氧基乙酯、己二醇二丙烯酸酯和三羟甲基丙烷三丙烯酸酯的混合物,比例为丙烯酸2-乙氧乙氧基乙酯、己二醇二丙烯酸酯和三羟甲基丙烷三丙烯酸酯=5:3:2(重量比),分散剂为含有机改性聚硅氧烷的分散剂选自TEGO公司的dispers系列。Mix 30 parts of prepolymer, 42 parts of monomer, and 8 parts of dispersant, place on a constant temperature magnetic stirrer and stir for 30 minutes to mix evenly; add 20 parts of azo red, and use a stirrer to stir the mixture for 30 minutes for pre-dispersion , using a high-speed grinder to grind for 90 minutes to obtain a magenta ink paste. Wherein the azo red is selected from the RT-355-D of Ciba, the prepolymer is a hyperbranched polyester acrylic resin selected from the EB150 series of Cytec, and the monomer is commercially available acrylic acid 2-ethoxyethoxy Mixture of ethyl ester, hexanediol diacrylate and trimethylolpropane triacrylate in the ratio of 2-ethoxyethoxyethyl acrylate, hexanediol diacrylate and trimethylolpropane triacrylate= 5:3:2 (weight ratio), the dispersant is a dispersant containing organically modified polysiloxane selected from the dispersers series of TEGO Company.
将单体20份、成膜树脂50份、光引发剂10份(包括氢供体活性胺)混合,加入色浆20份,使用搅拌器搅拌30分钟,可获得品红UV喷墨油墨。单体为市售的丙烯酸2-乙氧乙氧基乙酯、己二醇二丙烯酸酯和三羟甲基丙烷三丙烯酸酯的混合物,比例为丙烯酸2-乙氧乙氧基乙酯、己二醇二丙烯酸酯和三羟甲基丙烷三丙烯酸酯=5:3:2(重量比),成膜树脂为超支化的聚酯丙烯酸树脂选自氰特公司的EB150系列,光引发剂为2-甲基-1-[4-甲硫基苯基]-2-吗啉基-1-丙酮、2-异丙基硫杂蒽酮及其氢供体活性胺的混合物,比例为2-甲基-1-[4-甲硫基苯基]-2-吗啉基-1-丙酮:2-异丙基硫杂蒽酮:活性胺=2:2:1(重量比)。Mix 20 parts of monomer, 50 parts of film-forming resin, and 10 parts of photoinitiator (including hydrogen donor active amine), add 20 parts of color paste, and stir with a stirrer for 30 minutes to obtain magenta UV inkjet ink. The monomer is a commercially available mixture of 2-ethoxyethoxyethyl acrylate, hexanediol diacrylate and trimethylolpropane triacrylate in a ratio of 2-ethoxyethoxyethyl acrylate, hexanediol Alcohol diacrylate and trimethylolpropane triacrylate = 5:3:2 (weight ratio), the film-forming resin is a hyperbranched polyester acrylic resin selected from Cytec's EB150 series, and the photoinitiator is 2- A mixture of methyl-1-[4-methylthiophenyl]-2-morpholinyl-1-propanone, 2-isopropylthioxanthone and their hydrogen-donating active amines in the ratio of 2-methyl -1-[4-methylthiophenyl]-2-morpholino-1-propanone:2-isopropylthioxanthone:active amine=2:2:1 (weight ratio).
【实施例2】[Example 2]
将预聚物30份、单体51份、分散剂4份混合,放置在恒温磁力搅拌器上搅拌30分钟混合均匀;加入喹吖啶酮红15份,使用搅拌器将混合物搅拌30分钟进行预分散后,使用高速研磨机研磨90分钟,得到品红油墨色浆。其中喹吖啶酮红选自汽巴公司的微高丽5B-K,预聚物为市售的聚酯丙烯酸酯,单体为市售的2-苯氧基乙基丙烯酸酯、邻苯二甲酸二乙醇二丙烯酸酯和乙氧基化的三羟甲基丙烷三丙烯酸酯的混合物,比例为丙烯酸2-苯氧基乙基丙烯酸酯:邻苯二甲酸二乙醇二丙烯酸酯:乙氧基化的三羟甲基丙烷三丙烯酸酯=9:6:1(重量比),分散剂为选自BASF公司的EFKA系列。Mix 30 parts of prepolymer, 51 parts of monomer, and 4 parts of dispersant, place on a constant temperature magnetic stirrer and stir for 30 minutes to mix evenly; add 15 parts of quinacridone red, and use a stirrer to stir the mixture for 30 minutes for pre-treatment. After dispersion, use a high-speed grinder to grind for 90 minutes to obtain a magenta ink paste. Wherein the quinacridone red is selected from Ciba Company's Micro Korea 5B-K, the prepolymer is a commercially available polyester acrylate, and the monomer is a commercially available 2-phenoxyethyl acrylate, phthalic acid A mixture of diethanol diacrylate and ethoxylated trimethylolpropane triacrylate in a ratio of 2-phenoxyethyl acrylate: phthalate diethanol diacrylate: ethoxylated Trimethylolpropane triacrylate=9:6:1 (weight ratio), and the dispersant is EFKA series selected from BASF Company.
将单体30份、成膜树脂46份、光引发剂1份(包括氢供体活性胺)、流平剂5份混合,加入色浆20份,使用搅拌器搅拌30分钟,可获得品红UV喷墨油墨。单体为市售的2-苯氧基乙基丙烯酸酯、邻苯二甲酸二乙醇二丙烯酸酯和乙氧基化的三羟甲基丙烷三丙烯酸酯的混合物,比例为丙烯酸2-苯氧基乙基丙烯酸酯:邻苯二甲酸二乙醇二丙烯酸酯:乙氧基化的三羟甲基丙烷三丙烯酸酯=9:6:1(重量比),成膜树脂为超支化的聚酯丙烯酸树脂选自氰特公司的EB150系列,光引发剂为2,4,6-三甲基苯甲酰基-二苯基氧化膦、2-异丙基硫杂蒽酮及其氢供体活性胺的混合物,比例为2,4,6-三甲基苯甲酰基-二苯基氧化膦:2-异丙基硫杂蒽酮:活性胺=1:2:1(重量比),流平剂为长辉集团的BNK-LK600。Mix 30 parts of monomer, 46 parts of film-forming resin, 1 part of photoinitiator (including hydrogen donor active amine), and 5 parts of leveling agent, add 20 parts of color paste, and stir for 30 minutes with a stirrer to obtain magenta UV inkjet ink. The monomer is a commercially available mixture of 2-phenoxyethyl acrylate, diethylene phthalate diacrylate, and ethoxylated trimethylolpropane triacrylate in proportions of 2-phenoxy acrylate Ethylacrylate: phthalate diethylene diacrylate: ethoxylated trimethylolpropane triacrylate = 9:6:1 (weight ratio), film-forming resin is hyperbranched polyester acrylic resin Selected from Cytec's EB150 series, the photoinitiator is a mixture of 2,4,6-trimethylbenzoyl-diphenylphosphine oxide, 2-isopropylthioxanthone and its hydrogen donor active amine , the ratio is 2,4,6-trimethylbenzoyl-diphenylphosphine oxide:2-isopropylthioxanthone:active amine=1:2:1 (weight ratio), the leveling agent is long Fai Group's BNK-LK600.
【实施例3】[Example 3]
将预聚物30份、单体48份、分散剂12份混合,搅拌30分钟混合均匀;加入偶氮红10份,使用搅拌器将混合物搅拌30分钟进行预分散后,使用高速研磨机研磨60分钟,得到品红油墨色浆。其中偶氮红选自汽巴公司的RT-355-D,预聚物为市售的聚酯丙烯酸酯,单体为市售的丙烯酸异冰片酯、二缩三乙二醇二甲基丙烯酸酯和三羟甲基丙烷三甲基丙烯酸酯的混合物,比例为丙烯酸异冰片酯:二缩三乙二醇二甲基丙烯酸酯:三羟甲基丙烷三甲基丙烯酸酯=7:9:4(重量比),分散剂为选自BYK公司的byk-168。Mix 30 parts of prepolymer, 48 parts of monomer, and 12 parts of dispersant, and stir for 30 minutes to mix evenly; add 10 parts of azo red, use a stirrer to stir the mixture for 30 minutes for pre-dispersion, and use a high-speed grinder to grind for 60 Minutes to get magenta ink paste. Wherein the azo red is selected from the RT-355-D of Ciba Company, the prepolymer is commercially available polyester acrylate, and the monomer is commercially available isobornyl acrylate, triethylene glycol dimethacrylate and trimethylolpropane trimethacrylate, the ratio is isobornyl acrylate: triethylene glycol dimethacrylate: trimethylolpropane trimethacrylate = 7:9:4 ( weight ratio), the dispersant is byk-168 selected from BYK company.
将单体20份、成膜树脂42份、光引发剂6份、流平剂2份混合,加入色浆30份,使用搅拌器搅拌60分钟,可获得品红UV喷墨油墨。单体为市售的丙烯酸异冰片酯、二缩三乙二醇二甲基丙烯酸酯和三羟甲基丙烷三甲基丙烯酸酯的混合物,比例为丙烯酸异冰片酯:二缩三乙二醇二甲基丙烯酸酯:三羟甲基丙烷三甲基丙烯酸酯=7:9:4(重量比),成膜树脂为高官能聚酯丙烯酸树脂,选自天骄公司的TJ8901,光引发剂为安息香双甲醚,流平剂为迪高公司的460。Mix 20 parts of monomer, 42 parts of film-forming resin, 6 parts of photoinitiator, and 2 parts of leveling agent, add 30 parts of color paste, and stir for 60 minutes with a stirrer to obtain magenta UV inkjet ink. The monomer is a mixture of commercially available isobornyl acrylate, triethylene glycol dimethacrylate and trimethylolpropane trimethacrylate in a ratio of isobornyl acrylate: triethylene glycol dimethacrylate Methacrylate: trimethylolpropane trimethacrylate=7:9:4 (weight ratio), film-forming resin is high-functional polyester acrylic resin, selected from TJ8901 of Tianjiao Company, photoinitiator is benzoin bis Methyl ether, leveling agent is Tego 460.
【实施例4】【Example 4】
将预聚物15份、单体60份、分散剂10份混合,搅拌30分钟混合均匀;加入偶氮红15份,使用搅拌器将混合物搅拌30分钟进行预分散后,使用高速研磨机研磨120分钟,得到品红油墨色浆。其中偶氮红选自科莱恩公司的Permanent CarmineFBB02,预聚物为超支化聚酯丙烯酸树脂选自SATORMAR公司的CN系列,单体为市售的丙烯酸2-乙氧乙氧基乙酯,丙氧基化新戊二醇二丙烯酸酯和二缩三丙二醇二丙烯酸酯的混合物,比例为丙烯酸2-乙氧乙氧基乙酯:丙氧基化新戊二醇二丙烯酸酯:二缩三丙二醇二丙烯酸酯=5:6:3(重量比),分散剂为烯酸嵌段共聚物选自BASF公司的EFKA系列。Mix 15 parts of prepolymer, 60 parts of monomer, and 10 parts of dispersant, and stir for 30 minutes to mix evenly; add 15 parts of azo red, use a stirrer to stir the mixture for 30 minutes for pre-dispersion, and use a high-speed grinder to grind 120 Minutes to get magenta ink paste. Wherein the azo red is selected from Clariant's Permanent CarmineFBB02, the prepolymer is a hyperbranched polyester acrylic resin selected from the CN series of SATORMAR company, and the monomer is commercially available 2-ethoxyethoxyethyl acrylate, propoxy A mixture of neopentyl glycol diacrylate and tripropylene glycol diacrylate in a ratio of 2-ethoxyethoxyethyl acrylate: propoxylated neopentyl glycol diacrylate: tripropylene glycol diacrylate Acrylate = 5:6:3 (weight ratio), and the dispersant is an alkene acid block copolymer selected from the EFKA series of BASF.
将单体27份、成膜树脂30份、光引发剂10份、流平剂3份混合,加入色浆30份,使用搅拌器搅拌45分钟,可获得品红UV喷墨油墨。单体为市售的丙烯酸2-乙氧乙氧基乙酯,丙氧基化新戊二醇二丙烯酸酯和二缩三丙二醇二丙烯酸酯的混合物,比例为丙烯酸2-乙氧乙氧基乙酯:丙氧基化新戊二醇二丙烯酸酯:二缩三丙二醇二丙烯酸酯=5:6:3(重量比),成膜树脂为聚酯丙烯酸树脂,选自SATORMAR公司的CN系列,光引发剂为2-羟基-2-甲基-1-苯基-1-丙酮和1-羟基-环已基-苯基甲酮的混合物,重量比为2-羟基-2-甲基-1-苯基-1-丙酮:1-羟基-环已基-苯基甲酮=1:1,流平剂为南京德诺化工的DN-1082。Mix 27 parts of monomer, 30 parts of film-forming resin, 10 parts of photoinitiator, and 3 parts of leveling agent, add 30 parts of color paste, and stir for 45 minutes with a stirrer to obtain magenta UV inkjet ink. The monomer is a commercially available mixture of 2-ethoxyethoxyethyl acrylate, propoxylated neopentyl glycol diacrylate and tripropylene glycol diacrylate in a ratio of 2-ethoxyethoxyethyl acrylate Ester: propoxylated neopentyl glycol diacrylate: tripropylene glycol diacrylate = 5:6:3 (weight ratio), film-forming resin is polyester acrylic resin, selected from CN series of SATORMAR company, light The initiator is a mixture of 2-hydroxy-2-methyl-1-phenyl-1-propanone and 1-hydroxy-cyclohexyl-phenylmethanone, the weight ratio of 2-hydroxy-2-methyl-1- Phenyl-1-propanone: 1-hydroxy-cyclohexyl-phenyl ketone = 1:1, leveling agent is DN-1082 of Nanjing Denuo Chemical Industry.
【实施例5】【Example 5】
将预聚物30份、单体40份、分散剂5份混合,搅拌30分钟混合均匀;加入喹吖啶酮红25份,使用搅拌器将混合物搅拌30分钟进行预分散后,使用高速研磨机研磨90分钟,得到品红油墨色浆。其中喹吖啶酮红选自汽巴公司的微高丽5B-K,预聚物为超支化的聚酯丙烯酸树脂选自氰特公司的EB150系列,单体为市售的丙烯酸2-乙氧乙氧基乙酯和三羟甲基丙烷三丙烯酸酯的混合物,比例为丙烯酸2-乙氧乙氧基乙酯和三羟甲基丙烷三丙烯酸酯=3:2(重量比),分散剂为带有锚式基团的超分散剂选自上海三正公司的CH系列。Mix 30 parts of prepolymer, 40 parts of monomer, and 5 parts of dispersant, and stir for 30 minutes to mix evenly; add 25 parts of quinacridone red, use a stirrer to stir the mixture for 30 minutes for pre-dispersion, and use a high-speed grinder Grinding for 90 minutes yielded a magenta ink paste. Among them, quinacridone red is selected from Ciba's micro-Korea 5B-K, and the prepolymer is a hyperbranched polyester acrylic resin selected from Cytek's EB150 series, and the monomer is commercially available acrylic acid 2-ethoxyethylene A mixture of oxyethyl ester and trimethylolpropane triacrylate, the ratio is 2-ethoxyethoxyethyl acrylate and trimethylolpropane triacrylate = 3:2 (weight ratio), the dispersant is tape The hyperdispersant with anchor group is selected from the CH series of Shanghai Sanzheng Company.
将单体30份、成膜树脂50份、光引发剂5份(包括氢供体活性胺)混合,加入色浆15份,使用搅拌器搅拌60分钟,可获得品红UV喷墨油墨。单体为市售的丙烯酸2-乙氧乙氧基乙酯和三羟甲基丙烷三丙烯酸酯的混合物,比例为丙烯酸2-乙氧乙氧基乙酯和三羟甲基丙烷三丙烯酸酯=3:2(重量比),成膜树脂为超支化的聚酯丙烯酸树脂选自氰特公司的EB150系列,光引发剂为2-异丙基硫杂蒽酮及其氢供体活性胺,比例为2-异丙基硫杂蒽酮:活性胺=2:1(重量比)。Mix 30 parts of monomer, 50 parts of film-forming resin, and 5 parts of photoinitiator (including hydrogen donor active amine), add 15 parts of color paste, and stir for 60 minutes with a stirrer to obtain magenta UV inkjet ink. The monomer is a commercially available mixture of 2-ethoxyethoxyethyl acrylate and trimethylolpropane triacrylate in a ratio of 2-ethoxyethoxyethyl acrylate to trimethylolpropane triacrylate= 3:2 (weight ratio), the film-forming resin is hyperbranched polyester acrylic resin selected from the EB150 series of Cytec, the photoinitiator is 2-isopropylthioxanthone and its hydrogen donor active amine, the ratio It is 2-isopropylthioxanthone:active amine=2:1 (weight ratio).
【实施例6】[Example 6]
将预聚物25份、单体40份、分散剂10份混合,搅拌30分钟混合均匀;加入喹吖啶酮和吡咯并吡咯二酮混合红25份,使用搅拌器将混合物搅拌30分钟进行预分散后,使用高速研磨机研磨60分钟,得到品红油墨色浆。其中喹吖啶酮和吡咯并吡咯二酮混合红选自汽巴公司的微高丽4B-K,预聚物为市售的聚氨酯丙烯酸树脂,单体为市售的丙烯酸2-乙氧乙氧基乙酯,二缩三丙二醇二丙烯酸酯和新戊二醇二丙烯酸酯的混合物,比例为丙烯酸2-乙氧乙氧基乙酯:二缩三丙二醇二丙烯酸酯和新戊二醇二丙烯酸酯=2:3:3(重量比),分散剂为烯酸嵌段共聚物选自BASF公司的EFKA系列。Mix 25 parts of prepolymer, 40 parts of monomer, and 10 parts of dispersant, and stir for 30 minutes to mix evenly; add 25 parts of quinacridone and diketopyrrolopyrrole mixed red, and use a stirrer to stir the mixture for 30 minutes for pretreatment. After dispersion, use a high-speed grinder to grind for 60 minutes to obtain a magenta ink paste. Wherein the mixed red of quinacridone and diketopyrrolopyrrole is selected from the micro-Korea 4B-K of Ciba Company, the prepolymer is a commercially available polyurethane acrylic resin, and the monomer is a commercially available acrylic acid 2-ethoxyethoxy Ethyl ester, a mixture of tripropylene glycol diacrylate and neopentyl glycol diacrylate in the ratio 2-ethoxyethoxyethyl acrylate:tripropylene glycol diacrylate and neopentyl glycol diacrylate= 2:3:3 (weight ratio), the dispersant is an alkene acid block copolymer selected from the EFKA series of BASF.
将单体35份、成膜树脂40份、光引发剂5份(包括氢供体活性胺)混合,加入色浆20份,使用搅拌器搅拌60分钟,可获得品红UV喷墨油墨。单体为市售的丙烯酸2-乙氧乙氧基乙酯,二缩三丙二醇二丙烯酸酯和新戊二醇二丙烯酸酯的混合物,比例为丙烯酸2-乙氧乙氧基乙酯:二缩三丙二醇二丙烯酸酯和新戊二醇二丙烯酸酯=2:3:3(重量比),成膜树脂为高官能聚酯丙烯酸树脂,选自天骄公司的TJ8901,光引发剂为2-甲基-1-[4-甲硫基苯基]-2-吗啉基-1-丙酮、2-异丙基硫杂蒽酮及其氢供体活性胺的混合物,比例为2-甲基-1-[4-甲硫基苯基]-2-吗啉基-1-丙酮:2-异丙基硫杂蒽酮:活性胺=2:2:1(重量比)。Mix 35 parts of monomer, 40 parts of film-forming resin, and 5 parts of photoinitiator (including hydrogen donor active amine), add 20 parts of color paste, and stir for 60 minutes with a stirrer to obtain magenta UV inkjet ink. The monomer is a mixture of commercially available 2-ethoxyethoxyethyl acrylate, tripropylene glycol diacrylate and neopentyl glycol diacrylate in a ratio of 2-ethoxyethoxyethyl acrylate:dipropylene glycol diacrylate Tripropylene glycol diacrylate and neopentyl glycol diacrylate=2:3:3 (weight ratio), the film-forming resin is a high-functional polyester acrylic resin, selected from TJ8901 of Tianjiao Company, and the photoinitiator is 2-methyl - a mixture of 1-[4-methylthiophenyl]-2-morpholinyl-1-propanone, 2-isopropylthioxanthone and its hydrogen-donating active amine in the ratio of 2-methyl-1 -[4-methylthiophenyl]-2-morpholino-1-propanone:2-isopropylthioxanthone:active amine=2:2:1 (weight ratio).
实施例1-6所制备油墨的性能,如表1所示。本发明所制备的品红UV喷墨油墨符合喷墨印刷的要求,粒径小于0.5μm,粘度为20~30cP(25℃),表面张力为20~35mN/m(25℃),固化速度为30~50m/min(光源线功率为200W/cm),电导率为<18μs/cm。The properties of the inks prepared in Examples 1-6 are shown in Table 1. The magenta UV inkjet ink prepared by the present invention meets the requirements of inkjet printing, the particle size is less than 0.5 μm, the viscosity is 20~30cP (25°C), the surface tension is 20~35mN/m (25°C), and the curing speed is 30~50m/min (line power of light source is 200W/cm), conductivity <18μs/cm.
表1实施例1-6所制备的油墨性能The prepared ink performance of table 1 embodiment 1-6
注:粘度和表面张力均在25℃的环境下测试,固化光源的线功率为200W/cm。Note: Viscosity and surface tension are tested at 25°C, and the linear power of the curing light source is 200W/cm.
将本发明油墨和进口的(Sunjet)品红UV喷墨油墨使用带有XAAR喷头的UV喷墨印刷机(速度为80m/min)进行喷印,获得印刷样张,并采用基于工业CCD的数字质量评价系统对印刷样张进行评价,本发明品红UV喷墨油墨各项测试指标达到进口油墨的水平,在线条的模糊度、线宽、对比度和色块的密度等印刷质量方面,本发明品红UV喷墨油墨优于进口墨。Use the ink of the present invention and imported (Sunjet) magenta UV inkjet ink to print using a UV inkjet printer (speed 80m/min) with an XAAR nozzle to obtain a printing sample, and use digital quality based on industrial CCD The evaluation system evaluates the printing proofs. The various test indicators of the magenta UV inkjet ink of the present invention reach the level of imported inks. In terms of printing quality such as blurring of lines, line width, contrast and density of color blocks, the magenta UV inkjet ink of the present invention has the highest printing quality. UV inkjet ink is better than imported ink.
在本发明的其他实施例中,可采用在发明内容中列举的、不同于实施例1-6的颜料、预聚物、成膜树脂、单体、分散剂、光引发剂和流平剂,进行不同的搭配和组合,均可获得本发明油墨的性能和应用效果。本发明的油墨通过搅拌和高速研磨的方法制备,可应用于高速喷墨印刷设备,不同于普通的喷绘和印染。In other embodiments of the present invention, the pigments, prepolymers, film-forming resins, monomers, dispersants, photoinitiators and leveling agents listed in the Summary of the Invention that are different from Examples 1-6 can be used, The performance and application effect of the ink of the present invention can be obtained through different collocations and combinations. The ink of the invention is prepared by stirring and high-speed grinding, and can be applied to high-speed ink-jet printing equipment, which is different from ordinary ink-jet printing and printing and dyeing.
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| CN1613925A (en) * | 2004-09-22 | 2005-05-11 | 东华大学 | Ultraviolet light curing printing ink for digital printing and dyeing preparation thereof |
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| TWI292426B (en) * | 2001-12-25 | 2008-01-11 | Benq Corp |
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| CN1613925A (en) * | 2004-09-22 | 2005-05-11 | 东华大学 | Ultraviolet light curing printing ink for digital printing and dyeing preparation thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106773276A (en) * | 2017-03-28 | 2017-05-31 | 青岛海信电器股份有限公司 | Quantum dot color filter and preparation method, liquid crystal panel, liquid crystal display |
| CN106773276B (en) * | 2017-03-28 | 2019-08-09 | 青岛海信电器股份有限公司 | Quantum dot color filter and preparation method, liquid crystal display panel, liquid crystal display |
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