CN103173800A - Nickel plating brightener and preparation and use method thereof - Google Patents
Nickel plating brightener and preparation and use method thereof Download PDFInfo
- Publication number
- CN103173800A CN103173800A CN2013100999247A CN201310099924A CN103173800A CN 103173800 A CN103173800 A CN 103173800A CN 2013100999247 A CN2013100999247 A CN 2013100999247A CN 201310099924 A CN201310099924 A CN 201310099924A CN 103173800 A CN103173800 A CN 103173800A
- Authority
- CN
- China
- Prior art keywords
- nickel plating
- agent
- plating brightener
- add
- brightener
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 64
- 238000007747 plating Methods 0.000 title claims abstract description 40
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 17
- 239000004902 Softening Agent Substances 0.000 claims abstract description 15
- 239000000080 wetting agent Substances 0.000 claims abstract description 14
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims abstract description 12
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 9
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims abstract description 8
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- TVDSBUOJIPERQY-UHFFFAOYSA-N prop-2-yn-1-ol Chemical compound OCC#C TVDSBUOJIPERQY-UHFFFAOYSA-N 0.000 claims abstract description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 6
- RMZNRWHXSGBBSM-UHFFFAOYSA-N [Na]CC#C Chemical compound [Na]CC#C RMZNRWHXSGBBSM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 6
- 239000011734 sodium Substances 0.000 claims abstract description 6
- 239000012530 fluid Substances 0.000 claims description 14
- 241000080590 Niso Species 0.000 claims description 7
- 239000004327 boric acid Substances 0.000 claims description 7
- 150000002815 nickel Chemical class 0.000 claims description 7
- HCMGUYVGXYMWRB-UHFFFAOYSA-N 1-propoxyperoxypropane Chemical compound CCCOOOCCC HCMGUYVGXYMWRB-UHFFFAOYSA-N 0.000 claims description 5
- 101000606654 Arabidopsis thaliana Peroxidase 59 Proteins 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 150000002541 isothioureas Chemical class 0.000 claims description 5
- XSUMSESCSPMNPN-UHFFFAOYSA-N propane-1-sulfonate;pyridin-1-ium Chemical compound C1=CC=NC=C1.CCCS(O)(=O)=O XSUMSESCSPMNPN-UHFFFAOYSA-N 0.000 claims description 5
- 239000001384 succinic acid Substances 0.000 claims description 5
- 238000005282 brightening Methods 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 2
- REEBJQTUIJTGAL-UHFFFAOYSA-N 3-pyridin-1-ium-1-ylpropane-1-sulfonate Chemical compound [O-]S(=O)(=O)CCC[N+]1=CC=CC=C1 REEBJQTUIJTGAL-UHFFFAOYSA-N 0.000 abstract 2
- JVSJDKRMKRFRBT-UHFFFAOYSA-N 2-prop-2-ynoxypropan-1-ol Chemical compound OCC(C)OCC#C JVSJDKRMKRFRBT-UHFFFAOYSA-N 0.000 abstract 1
- ICCLGNPZARKJKF-UHFFFAOYSA-N 3-[amino(azaniumylidene)methyl]sulfanylpropanoate Chemical compound NC(=N)SCCC(O)=O ICCLGNPZARKJKF-UHFFFAOYSA-N 0.000 abstract 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 abstract 1
- 229960002645 boric acid Drugs 0.000 abstract 1
- 235000010338 boric acid Nutrition 0.000 abstract 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 abstract 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 abstract 1
- 229960005137 succinic acid Drugs 0.000 abstract 1
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000013064 chemical raw material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Landscapes
- Electroplating And Plating Baths Therefor (AREA)
Abstract
The invention discloses a nickel plating brightener and a preparation and use method thereof. The nickel plating brightener is formed by adding a major brightening agent, a softening agent and a wetting agent to a working base solution, wherein per liter of the nickel plating brightener contains the major brightening agent: 10-50 g/L of PPS (Pyridinium Propyl Sulfobetaine) and 10-30 g/L of PAP (Propargyl Alcohol Propoxylate), the softening agent: 10-200 g/L of PS (Propargyl Sodium Sulfonate) and 1-10 g/L of S-ATPN (S-Carboxyethyl Isothiourea Thiuronium) and the wetting agent: 20-100 g/L of MA-80 (Butanedioic Acid Diethyl Sodium Sulfonate); and the working base solution contains the following components: 200-320 g/L of nickelous sulfate NiSO4.6H2O, 45-55 g/L of nickel chloride NiCl2.6H2O, 40-50 g/L of boracic acid H3BO3, 0.8-1 g/L of sodium saccharin and the balance of water. The nickel plating brightener disclosed by the invention has the advantages of easiness for raw material obtaining, low cost, easiness for operation, good plating effect and stability in product quality.
Description
Technical field
The present invention relates to the metal finishing auxiliary agent, be specifically related to nickel plating brightener and preparation using method thereof.
Background technology
Nickel plating brightener generally was divided into for four generations at present through the development of many decades.First-generation nickel plating brightener is take metal-salt as main body; The second master that is combined on behalf of 1.4-butynediol and asccharin; The third generation is epoxy compounds and the asccharin of 1.4-butynediol; In the 4th generation, is take the combination of pyridine derivate and ynamine compounds and propiolic alcohol derivative and softening agent as most typical representative.In this several generations nickel plating brightener, third and fourth generation nickel plating brightener and its intermediate in close relations.In fact the intermediate of nickel plating brightener is exactly a kind of certain chemical raw material that can be used for directly preparing nickel plating brightener, as M, the N of preparation acid copper plating brightening agent, SP, P etc.As long as fully realize and skilled usefulness, purposes, using method and the preparation skill of having grasped commercially available all kinds intermediate, intermediate improved just can make the better first kind of performance (elementary) nickel plating brightener and Equations of The Second Kind (secondary) nickel plating brightener.With the first kind, Equations of The Second Kind intermediate, can improve commonly used the 4th generation nickel plating brightener.With the epoxy compounds of 1.4-butynediol (as 791, BE) and asccharin be the third generation brightening agent of Typical Representative, because its cost is low, synthesis technique is the factor such as open basically, is current comparatively widely used secondary nickel plating brightener.Add some intermediates to improve to it, improve the integral level of third generation nickel plating brightener.Elementary brightening agent adds a small amount of intermediate with asccharin to be improved, and second-class brightener also can be by roughly the same method improvement, and Electroplating Production producer just can both reach and improve the quality of products thus, the purpose that reduces production costs again.
Summary of the invention
The object of the invention is to: a kind of nickel plating brightener and preparation using method thereof are provided, not only improve the quality of product, can also reduce production costs, and adjust when component is lacked of proper care, be not controlled by the producer that produces additive.
Technical solution of the present invention is: add key light agent, softening agent, wetting agent composition nickel plating brightener in the work base fluid; Key light agent in every liter of nickel plating brightener: propane sulfonic acid pyridinium salt (PPS) 10-50g/L, propiolic alcohol propoxy-ether (PAP) 10-30g/L; Softening agent: propargyl sodium sulfonate (PS) 10-200g/L, S-propyloic isothiourea salt (ATPN) 1-10g/L; Wetting agent: succinic acid two is ester sodium sulfonate (MA-80) 20-100g/L; The work base fluid comprises following component: single nickel salt NiSO
46H
2O 200-320g/L, nickelous chloride NiCl
26H
2O 45-55g/L, boric acid H
3BO
340-50g/L, soluble saccharin 0.8-1g/L, all the other water.
Wherein, the preparation using method of nickel plating brightener: get single nickel salt NiSO
46H
2O, nickelous chloride NiCl
26H
2O, boric acid H
3BO
3, soluble saccharin is made into the work base fluid; Add the key light agent, add softening agent, add wetting agent according to 1ml/L according to 6ml/L according to 1ml/L in the work base fluid, add water and be made into 1 liter of nickel plating brightener; Adjust pH value 4-5; Plating temperature 50-60 ℃, current density 0.1-10A/dm
2
The raw material of nickel plating brightener of the present invention is easy to get, and is with low cost, simple to operate, and plating is effective, constant product quality.
Embodiment
Further illustrate technical solution of the present invention below in conjunction with specific embodiment, these embodiment can not be interpreted as it is restriction to technical scheme.
Embodiment 1:
Get single nickel salt NiSO
46H
2O 200g, nickelous chloride NiCl
26H
2O 45g, boric acid H
3BO
340g, soluble saccharin 0.8g are made into the work base fluid; Add key light agent propane sulfonic acid pyridinium salt (PPS) 10g, propiolic alcohol propoxy-ether (PAP) 10g according to 1ml/L in the work base fluid; Add softening agent propargyl sodium sulfonate (PS) 10g, S-propyloic isothiourea salt (ATPN) 1g according to 6ml/L; Add wetting agent succinic acid two ester sodium sulfonate (MA-80) 20g according to 1ml/L; Add water and be made into 1 liter of nickel plating brightener; Adjust pH value 4; 50 ℃ of plating temperatures, current density 10A/dm
2
Key light agent consumption 330ml/KAH; Softening agent consumption 1000ml/KAH; Wetting agent consumption 140ml/KAH.
Embodiment 2:
Get single nickel salt NiSO
46H
2O 260g, nickelous chloride NiCl
26H
2O 50g, boric acid H
3BO
345g, soluble saccharin 0.9g are made into the work base fluid; Add key light agent propane sulfonic acid pyridinium salt (PPS) 30g, propiolic alcohol propoxy-ether (PAP) 20g according to 1ml/L in the work base fluid; Add softening agent propargyl sodium sulfonate (PS) 105g, S-propyloic isothiourea salt (ATPN) 5.5g according to 6ml/L; Add wetting agent succinic acid two ester sodium sulfonate (MA-80) 60g according to 1ml/L; Add water and be made into 1 liter of nickel plating brightener; Adjust pH value 4.5; 55 ℃ of plating temperatures, current density 5.0A/dm
2,Key light agent consumption 330ml/KAH; Softening agent consumption 1000ml/KAH; Wetting agent consumption 140ml/KAH.
Embodiment 3:
Get single nickel salt NiSO
46H
2O 320g, nickelous chloride NiCl
26H
2O 55g, boric acid H
3BO
350g, soluble saccharin 1g are made into the work base fluid; Add key light agent propane sulfonic acid pyridinium salt (PPS) 50g, propiolic alcohol propoxy-ether (PAP) 30g according to 1ml/L in the work base fluid; Add softening agent propargyl sodium sulfonate (PS) 200g, S-propyloic isothiourea salt (ATPN) 10g according to 6ml/L; Add wetting agent succinic acid two ester sodium sulfonate (MA-80) 100g according to 1ml/L; Add water and be made into 1 liter of nickel plating brightener; Adjust pH value 5; 60 ℃ of plating temperatures, current density 0.1A/dm
2,Key light agent consumption 330ml/KAH; Softening agent consumption 1000ml/KAH; Wetting agent consumption 140ml/KAH.
Claims (2)
1. nickel plating brightener, is characterized in that: add key light agent, softening agent, wetting agent composition nickel plating brightener in the work base fluid; Key light agent in every liter of nickel plating brightener: propane sulfonic acid pyridinium salt (PPS) 10-50g/L, propiolic alcohol propoxy-ether (PAP) 10-30g/L; Softening agent: propargyl sodium sulfonate (PS) 10-200g/L, S-propyloic isothiourea salt (ATPN) 1-10g/L; Wetting agent: succinic acid two is ester sodium sulfonate (MA-80) 20-100g/L; The work base fluid comprises following component: single nickel salt NiSO
46H
2O 200-320g/L, nickelous chloride NiCl
26H
2O 45-55g/L, boric acid H
3BO
340-50g/L, soluble saccharin 0.8-1g/L, all the other water.
2. the preparation using method of nickel plating brightener, is characterized in that preparing using method as follows: get single nickel salt NiSO
46H
2O, nickelous chloride NiCl
26H
2O, boric acid H
3BO
3, soluble saccharin is made into the work base fluid; Add the key light agent, add softening agent, add wetting agent according to 1ml/L according to 6ml/L according to 1ml/L in the work base fluid, add water and be made into 1 liter of nickel plating brightener; Adjust pH value 4-5; Plating temperature 50-60 ℃, current density 0.1-10A/dm
2
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100999247A CN103173800A (en) | 2013-03-27 | 2013-03-27 | Nickel plating brightener and preparation and use method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013100999247A CN103173800A (en) | 2013-03-27 | 2013-03-27 | Nickel plating brightener and preparation and use method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103173800A true CN103173800A (en) | 2013-06-26 |
Family
ID=48633974
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013100999247A Pending CN103173800A (en) | 2013-03-27 | 2013-03-27 | Nickel plating brightener and preparation and use method thereof |
Country Status (1)
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|---|---|
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103911635A (en) * | 2014-03-21 | 2014-07-09 | 复旦大学 | Copper electroplating solution |
| CN105088288A (en) * | 2015-08-31 | 2015-11-25 | 武汉吉和昌化工科技股份有限公司 | Brightener for direct nickel plating of steel and iron elements and nickel plating solution thereof |
| CN105463518A (en) * | 2016-01-11 | 2016-04-06 | 湖北德美科技有限公司 | Full bright nickel plating softening agent and preparation method thereof |
| CN105463520A (en) * | 2016-01-11 | 2016-04-06 | 湖北德美科技有限公司 | Barrel nickel plating softening agent and preparation method thereof |
| CN105463519A (en) * | 2016-01-11 | 2016-04-06 | 湖北德美科技有限公司 | Barrel nickel plating major brightening agent and preparation method thereof |
| CN105648480A (en) * | 2016-01-11 | 2016-06-08 | 湖北德美科技有限公司 | Full-bright nickel plating major brightening agent and preparing method thereof |
| CN106086947A (en) * | 2016-08-11 | 2016-11-09 | 太仓市凯福士机械有限公司 | A kind of holding limpid additive of plating solution |
| TWI674341B (en) * | 2017-06-15 | 2019-10-11 | 美商羅門哈斯電子材料有限公司 | Environmentally friendly nickel electroplating compositions and methods |
| CN110484945A (en) * | 2019-09-03 | 2019-11-22 | 福建南平南孚电池有限公司 | Electroplate liquid and use its shell electric plating method to battery |
| CN111748830A (en) * | 2020-07-22 | 2020-10-09 | 六安市金安区宝德龙科技创新有限公司 | High-speed barrel nickel plating brightener and preparation method thereof |
| CN112251740A (en) * | 2020-10-21 | 2021-01-22 | 广州三孚新材料科技股份有限公司 | Chemical nickel plating brightener for heterojunction solar cell and preparation method thereof |
| CN116083975A (en) * | 2023-02-06 | 2023-05-09 | 南通麦特隆新材料科技有限公司 | A kind of all-bright nickel additive and preparation method thereof |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103911635A (en) * | 2014-03-21 | 2014-07-09 | 复旦大学 | Copper electroplating solution |
| CN103911635B (en) * | 2014-03-21 | 2016-02-24 | 复旦大学 | A kind of copper electroplating solution |
| CN105088288A (en) * | 2015-08-31 | 2015-11-25 | 武汉吉和昌化工科技股份有限公司 | Brightener for direct nickel plating of steel and iron elements and nickel plating solution thereof |
| CN105648480A (en) * | 2016-01-11 | 2016-06-08 | 湖北德美科技有限公司 | Full-bright nickel plating major brightening agent and preparing method thereof |
| CN105463520A (en) * | 2016-01-11 | 2016-04-06 | 湖北德美科技有限公司 | Barrel nickel plating softening agent and preparation method thereof |
| CN105463519A (en) * | 2016-01-11 | 2016-04-06 | 湖北德美科技有限公司 | Barrel nickel plating major brightening agent and preparation method thereof |
| CN105463518A (en) * | 2016-01-11 | 2016-04-06 | 湖北德美科技有限公司 | Full bright nickel plating softening agent and preparation method thereof |
| CN106086947A (en) * | 2016-08-11 | 2016-11-09 | 太仓市凯福士机械有限公司 | A kind of holding limpid additive of plating solution |
| TWI674341B (en) * | 2017-06-15 | 2019-10-11 | 美商羅門哈斯電子材料有限公司 | Environmentally friendly nickel electroplating compositions and methods |
| CN110484945A (en) * | 2019-09-03 | 2019-11-22 | 福建南平南孚电池有限公司 | Electroplate liquid and use its shell electric plating method to battery |
| CN111748830A (en) * | 2020-07-22 | 2020-10-09 | 六安市金安区宝德龙科技创新有限公司 | High-speed barrel nickel plating brightener and preparation method thereof |
| CN112251740A (en) * | 2020-10-21 | 2021-01-22 | 广州三孚新材料科技股份有限公司 | Chemical nickel plating brightener for heterojunction solar cell and preparation method thereof |
| CN116083975A (en) * | 2023-02-06 | 2023-05-09 | 南通麦特隆新材料科技有限公司 | A kind of all-bright nickel additive and preparation method thereof |
| CN116083975B (en) * | 2023-02-06 | 2025-09-19 | 南通麦特隆新材料科技有限公司 | All-optical nickel additive and preparation method thereof |
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Application publication date: 20130626 |