CN103131331B - Settling water-based grinding fluid and preparation method thereof - Google Patents
Settling water-based grinding fluid and preparation method thereof Download PDFInfo
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 238000000227 grinding Methods 0.000 title claims abstract description 45
- 239000012530 fluid Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 239000000314 lubricant Substances 0.000 claims abstract description 16
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 15
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 claims abstract description 15
- ZNSMNVMLTJELDZ-UHFFFAOYSA-N Bis(2-chloroethyl)ether Chemical compound ClCCOCCCl ZNSMNVMLTJELDZ-UHFFFAOYSA-N 0.000 claims abstract 4
- 229920000223 polyglycerol Polymers 0.000 claims abstract 4
- 239000007788 liquid Substances 0.000 claims description 39
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 34
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 33
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 21
- -1 alkyl isothiazole quinoline ketone Chemical class 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- FZQSLXQPHPOTHG-UHFFFAOYSA-N [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 Chemical compound [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 FZQSLXQPHPOTHG-UHFFFAOYSA-N 0.000 claims description 12
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 11
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 2
- 239000004135 Bone phosphate Substances 0.000 claims 1
- 101000631695 Homo sapiens Succinate dehydrogenase assembly factor 3, mitochondrial Proteins 0.000 claims 1
- 102100028996 Succinate dehydrogenase assembly factor 3, mitochondrial Human genes 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 1
- 229960004418 trolamine Drugs 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 14
- 239000013556 antirust agent Substances 0.000 abstract description 9
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 8
- 239000003899 bactericide agent Substances 0.000 abstract description 6
- 230000002265 prevention Effects 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 22
- 238000004062 sedimentation Methods 0.000 description 18
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 16
- 239000005711 Benzoic acid Substances 0.000 description 10
- 235000010233 benzoic acid Nutrition 0.000 description 10
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 10
- 235000011187 glycerol Nutrition 0.000 description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 description 10
- 229920000056 polyoxyethylene ether Polymers 0.000 description 10
- DLNPJWYSCKUGHI-UHFFFAOYSA-N 1-hydroxypyridine-2-thione;sodium Chemical compound [Na].ON1C=CC=CC1=S DLNPJWYSCKUGHI-UHFFFAOYSA-N 0.000 description 8
- HPGGRRWTQXPMHJ-UHFFFAOYSA-N 3-iodoprop-1-ynyl carbamate Chemical compound NC(=O)OC#CCI HPGGRRWTQXPMHJ-UHFFFAOYSA-N 0.000 description 8
- RKMOGOGTQIHYMN-UHFFFAOYSA-N 4-(2-methylphenyl)-2h-benzotriazole Chemical compound CC1=CC=CC=C1C1=CC=CC2=NNN=C12 RKMOGOGTQIHYMN-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 6
- 230000000855 fungicidal effect Effects 0.000 description 6
- 239000000417 fungicide Substances 0.000 description 6
- QAOMZDFCQJQQQS-UHFFFAOYSA-N 3-methyl-2h-isoquinolin-1-one Chemical compound C1=CC=C2C(=O)NC(C)=CC2=C1 QAOMZDFCQJQQQS-UHFFFAOYSA-N 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical group CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 239000003082 abrasive agent Substances 0.000 description 2
- 229960002684 aminocaproic acid Drugs 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000012897 dilution medium Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- LWBHHRRTOZQPDM-UHFFFAOYSA-N undecanedioic acid Chemical compound OC(=O)CCCCCCCCCC(O)=O LWBHHRRTOZQPDM-UHFFFAOYSA-N 0.000 description 2
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- UYCIUCIKUGYNBR-UHFFFAOYSA-N 2-iodoethyl carbamate Chemical compound NC(=O)OCCI UYCIUCIKUGYNBR-UHFFFAOYSA-N 0.000 description 1
- KDMQPGCHNLHSAH-UHFFFAOYSA-N 3-butyl-1,2-thiazol-4-one Chemical compound CCCCC1=NSCC1=O KDMQPGCHNLHSAH-UHFFFAOYSA-N 0.000 description 1
- SDSHANKXUIMGJQ-UHFFFAOYSA-N 3-ethyl-1,2-thiazol-4-one Chemical compound CCC1=NSCC1=O SDSHANKXUIMGJQ-UHFFFAOYSA-N 0.000 description 1
- RYZXCMIPPGQXGJ-UHFFFAOYSA-N 3-iodopropyl carbamate Chemical compound NC(=O)OCCCI RYZXCMIPPGQXGJ-UHFFFAOYSA-N 0.000 description 1
- HFJUZCICZORSHO-UHFFFAOYSA-N 3-propyl-1,2-thiazol-4-one Chemical compound CCCC1=NSCC1=O HFJUZCICZORSHO-UHFFFAOYSA-N 0.000 description 1
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- XLLBTSILSOJMTH-UHFFFAOYSA-N iodomethyl carbamate Chemical compound NC(=O)OCI XLLBTSILSOJMTH-UHFFFAOYSA-N 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229940094541 polyglycerin-10 Drugs 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- DXNCZXXFRKPEPY-UHFFFAOYSA-N tridecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCC(O)=O DXNCZXXFRKPEPY-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Lubricants (AREA)
Abstract
Description
技术领域technical field
本发明涉及研磨液技术领域，尤其涉及沉降性水基研磨液及其制备方法。The invention relates to the technical field of grinding fluid, in particular to a sedimentation water-based grinding fluid and a preparation method thereof.
背景技术Background technique
研磨加工时，工件以及砂轮都会产生大量的磨屑和砂轮粉末等微细颗粒，如果这些微细颗粒沉降不好，悬浮在加工液中，过滤不完全，重新渗入到砂轮-工件的界面间，将极大影响研磨精度。但现有的以水为稀释介质的研磨液普遍存在使用寿命短、成本高的缺点，某些产品还存在环保不友好、稀释不均匀、易引起工人皮肤过敏等问题。由于研磨液稀释比例高，对其防锈性能要求很高，普通的研磨液只能提供短期的工序间防锈效果，目前，大多研磨加工，需要在加工后做进一步防锈处理。目前还有不少的沉降性研磨液还采用亚硝酸钠作为合成研磨液中防锈的主要成分，亚硝酸钠防锈性能良好，但是一直潜在的致癌物质。由于研磨液一般使用时循环量较大，对其消泡性能要求较高，泡沫应该能够迅速破除。但是传递的添加水性消泡剂的方法，是一种治标不治本的方法。During grinding, the workpiece and the grinding wheel will produce a large amount of fine particles such as grinding debris and grinding wheel powder. If these fine particles do not settle well, they will be suspended in the processing fluid, filtered incompletely, and re-infiltrate into the interface between the grinding wheel and the workpiece, which will be very serious. Greatly affects the grinding accuracy. However, the existing abrasives that use water as the dilution medium generally have the disadvantages of short service life and high cost. Some products also have problems such as unfriendly environmental protection, uneven dilution, and easy skin allergies for workers. Due to the high dilution ratio of the grinding fluid, the requirements for its anti-rust performance are very high. Ordinary grinding fluid can only provide short-term anti-rust effect between processes. At present, most grinding processes require further anti-rust treatment after processing. At present, there are still many sedimentation abrasives that use sodium nitrite as the main anti-rust component in the synthetic abrasive. Sodium nitrite has good anti-rust performance, but it has always been a potential carcinogen. Since the grinding liquid generally has a large circulation volume during use, the requirements for its defoaming performance are relatively high, and the foam should be able to break quickly. However, the method of adding a water-based defoamer is a method that treats the symptoms but not the root cause.
因此，为了克服现有技术的不足，研制一种具有优良沉降性的合成研磨液具有重大的应用价值和现实意义。Therefore, in order to overcome the deficiencies of the prior art, it is of great application value and practical significance to develop a synthetic grinding liquid with excellent settling properties.
发明内容Contents of the invention
本实发明的目的在于提供一种以水为稀释介质的研磨液，具有沉降性好、消泡快、防锈好、使用寿命长及综合性价比高的特点。The purpose of the present invention is to provide a grinding liquid with water as the dilution medium, which has the characteristics of good settling property, fast defoaming, good rust prevention, long service life and high comprehensive cost performance.
本发明的另一目的还在于提供上述沉降性水基研磨液的制备方法。Another object of the present invention is to provide a method for preparing the above-mentioned settling water-based grinding liquid.
为了实现以上发明目的，本发明采用以下技术方案：一种沉降性水基研磨液，包括按质量百分比计的如下各组分：In order to achieve the above object of the invention, the present invention adopts the following technical solutions: a kind of sedimentation water-based grinding liquid, comprising the following components by mass percentage:
沉降剂 5～20%，Precipitating agent 5～20%,
防锈剂 25～60%，Antirust agent 25～60%,
润滑剂 15～40%，Lubricant 15～40%,
杀菌剂 1～3%，Fungicide 1～3%,
余量为水，The balance is water,
所述沉降剂为聚二氯乙基醚四甲基乙二胺、聚合甘油和乙二醇单丁醚中的一种或数种的混合物。The settling agent is one or a mixture of polydichloroethyl ether tetramethylethylenediamine, polyglycerin and ethylene glycol monobutyl ether.
进一步地，所述沉降剂中各组分占所述磨削液总质量的百分比为：Further, the percentage of each component in the settling agent to the total mass of the grinding fluid is:
聚二氯乙基醚四甲基乙二胺 0.5～2.5%，Polydichloroethyl ether tetramethylethylenediamine 0.5～2.5%,
聚合甘油 3.5～12.5%，Polyglycerin 3.5～12.5%,
乙二醇单丁醚 1～5%。Ethylene glycol monobutyl ether 1~5%.
进一步地，所述防锈剂为含氮杂环三元羧酸、单乙醇胺、三乙醇胺、十一碳二元酸、十二碳二元酸、十三碳二元酸、苯甲酸、甲基苯并三氮唑和氢氧化钾中的一种或数种的混合物。Further, the rust inhibitor is nitrogen-containing heterocyclic tricarboxylic acid, monoethanolamine, triethanolamine, undecanedioic acid, dodecanedioic acid, tridecanedioic acid, benzoic acid, methyl One or more mixtures of benzotriazole and potassium hydroxide.
进一步地，所述润滑剂为四硼酸钾、异构醇聚氧乙烯醚和丙三醇中的一种或数种的混合物。Further, the lubricant is one or a mixture of potassium tetraborate, isomeric alcohol polyoxyethylene ether and glycerin.
进一步地，所述杀菌剂为烷基异噻唑啉酮、碘代烷基氨基甲酸酯、1-羟基-2(1H)-吡啶硫酮钠中的一种或数种的混合物;Further, the bactericide is one or a mixture of alkylisothiazolinone, iodoalkylcarbamate, 1-hydroxy-2(1H)-pyridinethione sodium;
一种沉降性水基研磨液，包括按质量百分比计如下的各组分：A kind of sedimentation water-based grinding fluid, comprises the following components by mass percentage:
沉降剂:Settling agent:
聚二氯乙基醚四甲基乙二胺 0.5～2.5%Polydichloroethyl ether tetramethylethylenediamine 0.5～2.5%
聚合甘油 6～10%，Polyglycerin 6～10%,
乙二醇单丁醚 1～5%，Ethylene glycol monobutyl ether 1～5%,
防锈剂:Rust inhibitor:
含氮杂环三元羧酸 2～5%，Nitrogen-containing heterocyclic tricarboxylic acid 2～5%,
单乙醇胺 6～12%，Monoethanolamine 6～12%,
三乙醇胺 10～20%，Triethanolamine 10-20%,
十一碳二元酸 2～6%，Undecane dibasic acid 2～6%,
十二碳二元酸 2～6%，Dodecanoic acid 2～6%,
苯甲酸 2～5%，Benzoic acid 2～5%,
甲基苯并三氮唑 0.1～1%，Tolyl benzotriazole 0.1～1%,
氢氧化钾 2～5%，Potassium hydroxide 2～5%,
润滑剂:lubricant:
四硼酸钾 4～10%，Potassium tetraborate 4～10%,
异构醇聚氧乙烯醚 4～10%，Isomerized alcohol polyoxyethylene ether 4～10%,
丙三醇 8～16%，Glycerol 8～16%,
杀菌剂:Fungicide:
烷基异噻唑啉酮 1～3%，Alkylisothiazolinone 1～3%,
余量为水。The balance is water.
所述的沉降性水基研磨液的制备方法，包括如下具体步骤：The preparation method of described subsidence water-based grinding fluid comprises the following specific steps:
A）按配方称量或量取沉降剂、防锈剂、润滑剂、杀菌剂和水；A) Weigh or measure sedimentation agent, antirust agent, lubricant, fungicide and water according to the formula;
B）将防锈剂与水混合，搅拌30min，直至成为透明均匀液体；B) Mix the antirust agent with water and stir for 30 minutes until it becomes a transparent and uniform liquid;
C）向步骤B所得透明均匀液体中加入步骤A所称量的沉降剂、润滑剂和杀菌剂、搅拌均匀，冷却静置，过滤后即得所述沉降性水基研磨液；C) adding the sedimentation agent, lubricant and bactericide weighed in step A to the transparent and uniform liquid obtained in step B, stirring evenly, cooling and standing, and filtering to obtain the settling water-based grinding liquid;
较佳地，步骤B中，所述防锈剂与所述水混合后加热至50℃，再搅拌。Preferably, in step B, the rust inhibitor is mixed with the water, heated to 50° C., and then stirred.
本发明采用防锈剂，润滑剂和沉降剂材料，能够极大地降低研磨工作液的表面张力，配制的研磨工作液自身具有起泡少、消泡快的效果；本发明利用新型的沉降剂体系配制的研磨液，能够将这些微粒很快沉降，从而保持研磨液澄清，方便过滤；新型防锈剂体系的采用使得配制的研磨液具有更好的防锈效果；更佳的杀菌剂组合使得配制的研磨液对细菌和霉菌抵抗能力更强，不易发霉变质，使用寿命更长；此外，本发明的研磨液还具有低污染，废液处理简单的特点。因此，总的来说，本发明的研磨液具有以下有益效果：The invention adopts antirust agent, lubricant and sedimentation agent materials, which can greatly reduce the surface tension of the grinding working fluid, and the prepared grinding working fluid itself has the effect of less foaming and quick defoaming; the invention utilizes a new type of sedimentation agent system The prepared grinding liquid can quickly settle these particles, so as to keep the grinding liquid clear and easy to filter; the adoption of the new anti-rust agent system makes the prepared grinding liquid have better anti-rust effect; better fungicide combination makes the preparation The abrasive liquid of the present invention has stronger resistance to bacteria and mold, is less prone to mildew and deterioration, and has a longer service life; in addition, the abrasive liquid of the present invention also has the characteristics of low pollution and simple waste liquid treatment. Therefore, in general, grinding liquid of the present invention has the following beneficial effects:
1.极佳的抗泡效果，优异的磨屑沉降性能；1. Excellent anti-foaming effect, excellent wear debris settling performance;
2.不含硫、磷、氯和亚硝酸盐的化合物，有利于环境保护；2. Does not contain sulfur, phosphorus, chlorine and nitrite compounds, which is conducive to environmental protection;
3.防锈、冷却和清洗性能优良；3. Excellent anti-rust, cooling and cleaning performance;
4.优异的润滑性能，极大地延长砂轮寿命，改善工件光洁度；4. Excellent lubricating performance, greatly prolonging the life of the grinding wheel and improving the finish of the workpiece;
5.优异的抑菌杀菌效果，不含任何易腐败物质，不发臭，使用寿命长。5. Excellent antibacterial and bactericidal effect, does not contain any perishable substances, does not stink, and has a long service life.
具体实施方式Detailed ways
以下将结合具体实施例对本发明所述沉降性水基研磨液及其制备方法做进一步描述和说明，但下述实施例并不限制本发明的保护范围。The sedimentary water-based grinding liquid and its preparation method of the present invention will be further described and illustrated in conjunction with specific examples below, but the following examples do not limit the protection scope of the present invention.
一种沉降性水基研磨液，包括如下组分：沉降剂、防锈剂、润滑剂、杀菌剂和水。A settling water-based grinding fluid comprises the following components: settling agent, antirust agent, lubricant, bactericide and water.
其中，沉降剂为聚二氯乙基醚四甲基乙二胺、聚合甘油及乙二醇单丁醚中的一种或数种的混合物，沉降剂优选为它们的混合物；Wherein, the settling agent is one or more mixtures of polydichloroethyl ether tetramethylethylenediamine, polyglycerin and ethylene glycol monobutyl ether, and the settling agent is preferably their mixture;
防锈剂为由含氮杂环三元羧酸、单乙醇胺、三乙醇胺、十一碳二元酸、十二碳二元酸、苯甲酸、甲基苯并三氮唑及氢氧化钾中的一种或数种的混合物，其中含氮杂环三元羧酸可以为2,4,6-三(氨基己酸基)-1,3,5-三嗪,防锈剂优选为它们的混合物。The rust inhibitor is composed of nitrogen-containing heterocyclic tricarboxylic acid, monoethanolamine, triethanolamine, undecanedibasic acid, dodecanedibasic acid, benzoic acid, methylbenzotriazole and potassium hydroxide One or several mixtures, wherein the nitrogen-containing heterocyclic tricarboxylic acid can be 2,4,6-tris(aminocaproic acid)-1,3,5-triazine, and the rust inhibitor is preferably a mixture of them .
润滑剂为四硼酸钾、异构醇聚氧乙烯醚及丙三醇中的一种或数种的混合物，润滑剂优选为它们的混合物。The lubricant is potassium tetraborate, isomeric alcohol polyoxyethylene ether and glycerin or a mixture of several, and the lubricant is preferably a mixture of them.
杀菌剂为烷基异噻唑啉酮、碘代烷基氨基甲酸酯、1-羟基-2(1H)-吡啶硫酮钠中的一种或数种的混合物。其中，烷基异喹啉酮为甲基异噻唑啉酮、乙基异噻唑啉酮、丙基异噻唑啉酮、异丙基异噻唑啉酮、丁基异噻唑啉酮等，优选为甲基异噻唑啉酮。碘代烷基氨基甲酸酯、为碘代甲基氨基甲酸酯、碘代乙基氨基甲酸酯、碘代丙基氨基甲酸酯、碘代异丙基基氨基甲酸酯、碘代丁基氨基甲酸酯、碘代丙炔氨基甲酸酯等，优选为碘代丙炔氨基甲酸酯。The bactericide is one or a mixture of alkylisothiazolinone, iodoalkyl carbamate, and 1-hydroxy-2(1H)-pyridinethione sodium. Among them, the alkylisothiazolinone is methylisothiazolinone, ethylisothiazolinone, propylisothiazolinone, isopropylisothiazolinone, butylisothiazolinone, etc., preferably methylisothiazolinone Linone. Iodoalkyl carbamate, iodomethyl carbamate, iodoethyl carbamate, iodopropyl carbamate, iodoisopropyl carbamate, iodo Butyl carbamate, iodopropynyl carbamate, etc. are preferably iodopropynyl carbamate.
杀菌剂优选为甲基异噻唑啉酮、碘代丙炔氨基甲酸酯及1-羟基-2(1H)-吡啶硫酮钠的混合物。The fungicide is preferably a mixture of methylisothiazolinone, iodopropynyl carbamate and sodium 1-hydroxy-2(1H)-pyridinethione.
实施例一Embodiment one
一种沉降性水基研磨液，各组分的质量百分比如下：A kind of sedimentation water-based grinding liquid, the mass percent of each component is as follows:
聚二氯乙基醚四甲基乙二胺 1％，Polydichloroethyl ether tetramethylethylenediamine 1%,
聚合甘油 8％，Polyglycerin 8%,
乙二醇单丁醚 2%，Ethylene glycol monobutyl ether 2%
2,4,6-三(氨基己酸基)-1,3,5-三嗪 3％，2,4,6-tris(aminocaproic acid)-1,3,5-triazine 3%,
单乙醇胺 8%，Monoethanolamine 8%,
三乙醇胺 12%，Triethanolamine 12%,
十一碳二元酸 3%，Undecane dibasic acid 3%
十二碳二元酸 3%，Dodecane dibasic acid 3%
苯甲酸 2%，Benzoic acid 2%
甲基苯并三氮唑 0.5％，Tolylbenzotriazole 0.5%,
氢氧化钾 2.5%，Potassium Hydroxide 2.5%,
四硼酸钾 6%，Potassium tetraborate 6%
异构醇聚氧乙烯醚 7%，Isomerized alcohol polyoxyethylene ether 7%
丙三醇 9%，Glycerol 9%
甲基异喹啉酮 0.5％，Methylisoquinolinone 0.5%,
水 32%。Water 32%.
实施例二Embodiment two
一种沉降性水基研磨液，由下述质量百分比的各组分组成：A kind of sedimentation water-based grinding liquid, is made up of each component of following mass percentage:
聚二氯乙基醚四甲基乙二胺 1%，Polydichloroethyl ether tetramethylethylenediamine 1%,
聚合甘油 8%，Polyglycerin 8%,
乙二醇单丁醚 2%，Ethylene glycol monobutyl ether 2%
含氮杂环三元羧酸 3%，Nitrogen-containing heterocyclic tricarboxylic acid 3%
单乙醇胺 8%，Monoethanolamine 8%,
三乙醇胺 12%，Triethanolamine 12%,
十一碳二元酸 4%，Undecane dibasic acid 4%
十二碳二元酸 2%，Dodecanoic acid 2%
苯甲酸 2%，Benzoic acid 2%
甲基苯并三氮唑 0.5%，Tolylbenzotriazole 0.5%,
氢氧化钾 2.5%，Potassium Hydroxide 2.5%,
四硼酸钾 6%，Potassium tetraborate 6%
异构醇聚氧乙烯醚 6%，Isomerized alcohol polyoxyethylene ether 6%
丙三醇 8%，Glycerol 8%
甲基异喹啉酮 0.5％，Methylisoquinolinone 0.5%,
碘代丙炔基氨基甲酸酯 0.5％，Iodopropynyl carbamate 0.5%,
水 32%。Water 32%.
实施例三Embodiment three
一种沉降性水基研磨液，由下述质量百分比的各组分组成：A kind of sedimentation water-based grinding liquid, is made up of each component of following mass percentage:
聚二氯乙基醚四甲基乙二胺 1%，Polydichloroethyl ether tetramethylethylenediamine 1%,
聚合甘油 10%，Polyglycerin 10%,
乙二醇单丁醚 2%，Ethylene glycol monobutyl ether 2%
含氮杂环三元羧酸 3%，Nitrogen-containing heterocyclic tricarboxylic acid 3%
单乙醇胺 6%，Monoethanolamine 6%
三乙醇胺 16%，Triethanolamine 16%,
十一碳二元酸 3%，Undecane dibasic acid 3%
十二碳二元酸 3%，Dodecane dibasic acid 3%
苯甲酸 2%，Benzoic acid 2%
甲基苯并三氮唑 0.5%，Tolylbenzotriazole 0.5%,
氢氧化钾 2.5%，Potassium Hydroxide 2.5%,
四硼酸钾 6%，Potassium tetraborate 6%
异构醇聚氧乙烯醚 4%，Isomerized alcohol polyoxyethylene ether 4%
丙三醇 8%，Glycerol 8%
甲基异喹啉酮 0.5％，Methylisoquinolinone 0.5%,
1-羟基-2(1H)-吡啶硫酮钠 0.5%，1-Hydroxy-2(1H)-pyridinethione sodium 0.5%,
水 32%。Water 32%.
实施例四Embodiment four
一种沉降性水基研磨液，由下述质量百分比的各组分组成：A kind of sedimentation water-based grinding liquid, is made up of each component of following mass percentage:
聚二氯乙基醚四甲基乙二胺1%，Polydichloroethyl ether tetramethylethylenediamine 1%,
聚合甘油 8%，Polyglycerin 8%,
乙二醇单丁醚 2%，；Ethylene glycol monobutyl ether 2%;
含氮杂环三元羧酸 3%，Nitrogen-containing heterocyclic tricarboxylic acid 3%
单乙醇胺 6%，Monoethanolamine 6%
三乙醇胺 16%，Triethanolamine 16%,
十一碳二元酸 3%，Undecane dibasic acid 3%
十二碳二元酸 2%，Dodecanoic acid 2%
苯甲酸 2%，Benzoic acid 2%
甲基苯并三氮唑 0.5%，Tolylbenzotriazole 0.5%,
氢氧化钾 2.5%，Potassium Hydroxide 2.5%,
四硼酸钾 6%，Potassium tetraborate 6%
异构醇聚氧乙烯醚 4%，Isomerized alcohol polyoxyethylene ether 4%
丙三醇 8%，Glycerol 8%
甲基异喹啉酮 0.5％，Methylisoquinolinone 0.5%,
碘代丙炔基氨基甲酸酯 0.25％，Iodopropynyl carbamate 0.25%,
1-羟基-2(1H)-吡啶硫酮钠 0.25％，1-Hydroxy-2(1H)-pyridinethione sodium 0.25%,
水 34%。Water 34%.
实施例五Embodiment five
一种沉降性水基研磨液，由下述质量百分比的各组分组成：A kind of sedimentation water-based grinding liquid, is made up of each component of following mass percentage:
聚二氯乙基醚四甲基乙二胺 1％，Polydichloroethyl ether tetramethylethylenediamine 1%,
聚合甘油 9%，Polyglycerin 9%,
乙二醇单丁醚 2%，Ethylene glycol monobutyl ether 2%
含氮杂环三元羧酸 3%，Nitrogen-containing heterocyclic tricarboxylic acid 3%
单乙醇胺 6%，Monoethanolamine 6%
三乙醇胺 16%，Triethanolamine 16%,
十一碳二元酸 3%，Undecane dibasic acid 3%
十二碳二元酸 3%，Dodecane dibasic acid 3%
苯甲酸 2%，Benzoic acid 2%
甲基苯并三氮唑 0.5%，Tolylbenzotriazole 0.5%,
氢氧化钾 2.5%，Potassium Hydroxide 2.5%,
四硼酸钾 6%，Potassium tetraborate 6%
异构醇聚氧乙烯醚 6%；Isomerized alcohol polyoxyethylene ether 6%;
丙三醇 7%，Glycerol 7%
碘代丙炔基氨基甲酸酯 0.5％，Iodopropynyl carbamate 0.5%,
1-羟基-2(1H)-吡啶硫酮钠0.5%，1-Hydroxy-2(1H)-pyridinethione sodium 0.5%,
水 34%。Water 34%.
实施例六Embodiment six
一种沉降性水基研磨液，由下述质量百分比的各组分组成：A kind of sedimentation water-based grinding liquid, is made up of each component of following mass percentage:
聚二氯乙基醚四甲基乙二胺 0.5%，Polydichloroethyl ether tetramethylethylenediamine 0.5%,
聚合甘油 6%，Polyglycerin 6%
乙二醇单丁醚 5%，Ethylene glycol monobutyl ether 5%
含氮杂环三元羧酸 2%，Nitrogen-containing heterocyclic tricarboxylic acid 2%
单乙醇胺 12%，Monoethanolamine 12%,
三乙醇胺 10%，Triethanolamine 10%,
十一碳二元酸 2%，Undecane dibasic acid 2%
十二碳二元酸 6%，Dodecanoic acid 6%
苯甲酸 2%，Benzoic acid 2%
甲基苯并三氮唑 0.5%，Tolylbenzotriazole 0.5%,
氢氧化钾 2%，Potassium Hydroxide 2%,
四硼酸钾 4%，Potassium tetraborate 4%
异构醇聚氧乙烯醚 10%，Isomerized alcohol polyoxyethylene ether 10%,
丙三醇 8%，Glycerol 8%
甲基异喹啉酮 1％，Methylisoquinolinone 1%
碘代丙炔基氨基甲酸酯 1％，Iodopropynyl carbamate 1%,
1-羟基-2(1H)-吡啶硫酮钠 1%，1-Hydroxy-2(1H)-pyridinethione sodium 1%,
水 27%。Water 27%.
实施例七Embodiment seven
一种沉降性水基研磨液，由下述质量百分比的各组分组成：A kind of sedimentation water-based grinding liquid, is made up of each component of following mass percentage:
聚二氯乙基醚四甲基乙二胺 2.5%，Polydichloroethyl ether tetramethylethylenediamine 2.5%,
聚合甘油 6%，Polyglycerin 6%
乙二醇单丁醚 1%，Ethylene glycol monobutyl ether 1%
含氮杂环三元羧酸 5%，Nitrogen-containing heterocyclic tricarboxylic acid 5%,
单乙醇胺 6%，Monoethanolamine 6%
三乙醇胺 20%，Triethanolamine 20%,
十一碳二元酸 6%，Undecane dibasic acid 6%
十二碳二元酸 2%，Dodecanoic acid 2%
苯甲酸 5%，Benzoic acid 5%
甲基苯并三氮唑 1%，Tolyl benzotriazole 1%
氢氧化钾 5%，Potassium Hydroxide 5%,
四硼酸钾 6%，Potassium tetraborate 6%
异构醇聚氧乙烯醚 4%，Isomerized alcohol polyoxyethylene ether 4%
丙三醇 8%，Glycerol 8%
碘代丙炔基氨基甲酸酯 1.5％，Iodopropynyl carbamate 1.5%,
1-羟基-2(1H)-吡啶硫酮钠 1%，1-Hydroxy-2(1H)-pyridinethione sodium 1%,
水 20%。Water 20%.
实施例八Embodiment eight
制备实施例一至七所述的沉降性水基研磨液的方法，包括以下步骤：The method for preparing the described subsidence water-based abrasive liquid of embodiment one to seven may further comprise the steps:
A）按配方称量或量取沉降剂、防锈剂、润滑剂、杀菌剂和水；A) Weigh or measure sedimentation agent, antirust agent, lubricant, fungicide and water according to the formula;
B）将防锈剂与水混合，加热至50℃，然后搅拌30min,直至成为透明均匀液体；B) Mix the antirust agent with water, heat to 50°C, and then stir for 30 minutes until it becomes a transparent and uniform liquid;
C）向步骤B所得透明均匀液体中加入步骤A所称量的沉降剂、润滑剂和杀菌剂、搅拌均匀，冷却静置，过滤后即得所述沉降性水基研磨液。C) Add the sedimentation agent, lubricant and bactericide weighed in step A to the transparent and uniform liquid obtained in step B, stir evenly, cool and stand still, and filter to obtain the settling water-based grinding liquid.
为了进一步说明本申请所述沉降性水基研磨液的性能，将按照本申请实施例1所述配方和实施例8所述制备方法制备的沉降性水基研磨液进行了检测，检测方法和项目和结果如表1。In order to further illustrate the performance of the sedimentary water-based grinding liquid described in this application, the sedimentary water-based grinding liquid prepared according to the formula described in Example 1 of this application and the preparation method described in Example 8 was tested, the detection method and the project And the results are shown in Table 1.
表1本发明所述沉降性水基研磨液的性能检测结果Table 1 The performance detection result of the sedimentation water-based grinding fluid of the present invention
以上内容是结合具体的优选实施方式对本发明所作的进一步详细说明，不能认定本发明的具体实施只局限于这些说明。对于本发明所属技术领域的普通技术人员来说，在不脱离本发明构思的前提下，其架构形式能够灵活多变，可以派生系列产品。只是做出若干简单推演或替换，都应当视为属于本发明由所提交的权利要求书确定的专利保护范围。The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be assumed that the specific implementation of the present invention is limited to these descriptions. For those of ordinary skill in the technical field to which the present invention belongs, on the premise of not departing from the concept of the present invention, its structural form can be flexible and changeable, and a series of products can be derived. Just making some simple deductions or replacements should be deemed to belong to the patent protection scope of the present invention determined by the submitted claims.
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| CN103131331A (en) | 2013-06-05 |
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Effective date of registration: 20191105 Address after: 516700 floor 1, plant 3, Anxing smart Park, Xinhe Industrial Zone, Hekou Town, Luhe County, Shanwei City, Guangdong Province Patentee after: Guangdong Hengchang technology Lubricant Co., Ltd Address before: 523000 natural lake village, Rome management Industrial Zone, Qingxi Town, Dongguan, Guangdong Patentee before: Dongguan City Yinxing Technology Development Co., Ltd. |