CN102939979A - Insecticide combination containing emamectin benzoate and hexaflumuron - Google Patents
Insecticide combination containing emamectin benzoate and hexaflumuron Download PDFInfo
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- CN102939979A CN102939979A CN 201210494412 CN201210494412A CN102939979A CN 102939979 A CN102939979 A CN 102939979A CN 201210494412 CN201210494412 CN 201210494412 CN 201210494412 A CN201210494412 A CN 201210494412A CN 102939979 A CN102939979 A CN 102939979A
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- CN
- China
- Prior art keywords
- hexaflumuron
- emamectin benzoate
- dimension salt
- combination containing
- insecticide combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000002917 insecticide Substances 0.000 title abstract description 7
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 title abstract 5
- 230000000361 pesticidal effect Effects 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 6
- 239000000375 suspending agent Substances 0.000 claims abstract description 6
- 239000002270 dispersing agent Substances 0.000 claims abstract description 5
- 239000000839 emulsion Substances 0.000 claims abstract description 3
- 150000003839 salts Chemical class 0.000 claims description 31
- 238000009736 wetting Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 10
- 238000005516 engineering process Methods 0.000 abstract description 6
- 230000000749 insecticidal effect Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000001228 spectrum Methods 0.000 abstract description 4
- 239000004480 active ingredient Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 17
- 241000238631 Hexapoda Species 0.000 description 12
- 239000012895 dilution Substances 0.000 description 8
- 238000010790 dilution Methods 0.000 description 8
- 238000005507 spraying Methods 0.000 description 8
- 230000009286 beneficial effect Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000004562 water dispersible granule Substances 0.000 description 6
- 230000009931 harmful effect Effects 0.000 description 5
- 241000256259 Noctuidae Species 0.000 description 4
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000575 pesticide Substances 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 3
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 3
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 3
- 241000426497 Chilo suppressalis Species 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 241000255967 Helicoverpa zea Species 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 241000256257 Heliothis Species 0.000 description 2
- 241000721703 Lymantria dispar Species 0.000 description 2
- 241000255685 Malacosoma neustria Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 150000007945 N-acyl ureas Chemical class 0.000 description 2
- -1 acyl group ureas Chemical class 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- 239000005660 Abamectin Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- HRYILSDLIGTCOP-UHFFFAOYSA-N N-benzoylurea Chemical compound NC(=O)NC(=O)C1=CC=CC=C1 HRYILSDLIGTCOP-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 240000003377 Shepherdia canadensis Species 0.000 description 1
- 235000018324 Shepherdia canadensis Nutrition 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000000853 biopesticidal effect Effects 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 1
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticide combination containing emamectin benzoate and hexaflumuron. The weight ratio of the emamectin benzoate and the hexaflumuron which are effective active ingredients is (1-20): (2-25), preferably, (1-12): (2-15). According to known technologies in the technical field, conventional additives and filling agents are added into the insecticide combination containing the emamectin benzoate and the hexaflumuron to be prepared into wettable powders, water dispersing agents, suspending agents, water emulsions or microemulsions. According to the insecticide combination, pesticide effects are enhanced than effects before the emamectin benzoate and the hexaflumuron are compounded, costs are reduced, insecticidal spectrum is extended, safety is improved, the manufacture is simple, and the costs are low.
Description
Technical field
The invention belongs to agricultural technology field, relate in particular to a kind of Pesticidal combination that contains first dimension salt and HEXAFLUMURON.
Background technology
The agricultural chemicals of all liquid state and the solid-state agricultural chemicals of sizable solvability is arranged in organic solvent for a long time, no matter be insecticide, bactericide or weed killer herbicide, major part is made the form of pulvis or missible oil and is used, but owing to containing in the elegant type of pulvis and the missible oil in a large number to people and animals and the harmful inflammable organic solvent of environment, so that produce poisoning in the process of production, accumulating and use, there is potential safety hazard.Especially in the long-term process of using, the resistance of having made deposits yields reduces drug effect greatly, and a large amount of organic matters evaporate into and caused serious environmental pollution in the air.
It has super-high-efficient first dimension salt full name emamectin-benzoate, low toxicity (preparation is closely nontoxic), low-residual, the nuisanceless characteristics that wait biopesticide, with Avermectin at first insecticidal activity improved 3 orders of magnitude, active high to the larva of lepidopterous insects and other many insects, existing stomach poison function is double action of contace poison again, (has good effect under 0.084 ~ 2g/ha) at low-down dosage, and in the process of pest control, beneficial insect is not injured, be conducive to the integrated control to insect, enlarged in addition insecticidal spectrum, reduced the toxicity to people and animals.
HEXAFLUMURON belongs to the benzoyl urea insecticide; it is novel acylureas insecticides; except having other acyl group ureas desinsection characteristics; insecticidal spectrum is wider, especially the insect of genus heliothis is had special efficacy, and is respond well to noctuidae pests such as gypsymoth, tent caterpillar, dysychira abietis, sweet Lay noctuid, the real noctuids of paddy; invalid to mite; the power of knocking down is strong, and insecticidal effect is rapider than other acylureas, has higher contact ovicidal activity.
The purpose of this invention is to provide the low Pesticidal combination that contains first dimension salt and HEXAFLUMURON of a kind of good drug efficacy, consumption.
The technical solution adopted for the present invention to solve the technical problems is: a kind of Pesticidal combination that contains first dimension salt and HEXAFLUMURON, wherein the weight proportion of effective active composition first dimension salt and HEXAFLUMURON is 1 ~ 20:2 ~ 25,1 ~ 12:2 ~ 15 preferably, the described Pesticidal combination that contains first dimension salt and HEXAFLUMURON adds conventional auxiliary agent and fills out agent by technology well-known in the art, makes wetting powder, water dispersant, suspending agent, aqueous emulsion or microemulsion.
The invention has the beneficial effects as follows: a kind of Pesticidal combination that contains first dimension salt and HEXAFLUMURON has strengthened than both composite drug effects before, has reduced cost, has enlarged insecticidal spectrum, and safety is improved, and makes simple, with low cost.
Embodiment
For a better understanding of the present invention, the invention will be further described below in conjunction with embodiment, but the scope of protection of present invention is not limited to the scope that embodiment represents.
Embodiment 1
The 35% first dimension salt hexaflumuron water dispersible granule control dysychira abietis test of pesticide effectiveness:
By weight first dimension salt 15%, HEXAFLUMURON 20%, two naphthyl sulfonic acid receive 3%, DW3%, SP3%, ammonium sulfate 1%, polyethylene glycol 1%, kaolin adds to 100%, production technology makes 35% first dimension salt HEXAFLUMURON water dispersant routinely, this proportioning is by 4000 times of dilution sprayings, and the effect of 72 hours control dysychira abietises is 94.1%～95.5% behind the medicine.
25% first dimension salt and 10% hexaflumuron water dispersible granule dilute respectively 4500 times and 4000 times of uses in the same way, and 72 hours preventive effects are respectively 83.3% and 82.1% behind the medicine,
75% first dimension salt hexaflumuron water dispersible granule is by 4000 times of dilution sprayings, the effect of 72 hours control dysychira abietises is that 85.4%～90.18%. and preparation cost are far above the cost of the present embodiment proportioning behind the medicine, the inventor does not find that test medicine has harmful effect to crop in experiment, to beneficial insect safety.
Embodiment 2
The 14% first dimension salt HEXAFLUMURON wetting powder control cotton bollworm test of pesticide effectiveness:
Add to 100% by weight first dimension salt 9%, HEXAFLUMURON 5%, dodecylbenzene sodium sulfonate 2%, alkylnaphthalene sulfonate formaldehyde condensation products 1%, white carbon 3%, kaolin, production technology makes 14% first dimension salt HEXAFLUMURON wetting powder routinely, this proportioning is by 3500 times of dilution sprayings, and the effect of 72 hours control cotton bollworms is 92.3%～96.1% behind the medicine.
10% emamectin benzoate water dispersible granule and 3% HEXAFLUMURON wetting powder dilute respectively 4000 times and 3000 times of uses after the same method, and 72 hours its preventive effects are respectively 76.3% and 78.9% behind the medicine.
8% first dimension salt HEXAFLUMURON wetting powder is by 4000 times of dilution sprayings, and the effect of 72 hours control cotton bollworms is 77.2%～83.5% behind the medicine, and the inventor does not find that test medicine has harmful effect to crop in experiment, to beneficial insect safety.
Embodiment 3
The blue or green worm test of pesticide effectiveness of 10% first dimension salt HEXAFLUMURON suspending agent control Chinese cabbage:
Add to 100% by weight first dimension salt 8%, HEXAFLUMURON 2%, polycarboxylate 3%, soapberry powder 6%, silicone compound 0.1% hydroxyethylcellulose 0.1%, ethylene glycol 2%, deionized water, mix making 10% first dimension salt HEXAFLUMURON suspending agent.This proportioning is by 3000 times of dilution sprayings, and 72 hours blue or green worm effects of control Chinese cabbage are 92.8%～97.6% behind the medicine.
10% emamectin benzoate water dispersible granule and 3% hexaflumuron water dispersible granule dilute respectively 8000 times and 7000 times of uses after the same method, and 72 hours preventive effects are respectively 79.6% and 82.9% behind the medicine.
7% first dimension salt HEXAFLUMURON suspending agent is by 4000 times of dilution sprayings, and 72 hours blue or green worm effects of control Chinese cabbage are 73.5～84.2% behind the medicine, and the inventor does not find that test medicine has harmful effect to crop in experiment, to beneficial insect safety.
Embodiment 4
The 20% first dimension salt HEXAFLUMURON microemulsion control rice-stem borer test of pesticide effectiveness:
Supply 100% by weight first dimension salt 16%, HEXAFLUMURON 4%, N one octylpyrrolidone 17%, toluene 4%, ethylene glycol monomethyl ether 4%, ethyl acetate 3%, agricultural newborn 34#6%, triethanolamine salt 5%, ethylene glycol 2%, silicone oil 0.35%, deionized water, make 20% first dimension salt HEXAFLUMURON microemulsion.This proportioning is by 3500 times of dilution sprayings, and 72 hours control rice-stem borer effects are 92.8%～97.1% behind the medicine.
16% emamectin benzoate water dispersant and 4% 5 percent of hexaflumuron emulsifiable concentrate dilute respectively 5000 times and 4500 times of uses according to same method, and 72 hours preventive effects are respectively 82.4% and 78.7% behind the medicine.
40% first dimension salt HEXAFLUMURON microemulsion is by 4000 times of dilution sprayings, 72 hours control rice-stem borer effects are 83.3%～91.2% behind the medicine, and the preparation cost is far above the cost of this example proportioning, and the inventor does not find that test medicine has harmful effect to crop in experiment, to beneficial insect safety.
A kind of Pesticidal combination of first dimension salt and HEXAFLUMURON that contains of the present invention is to larva and other many insects of lepidopterous insects, especially the insect of genus heliothis there is special efficacy, respond well to noctuidae pests such as gypsymoth, tent caterpillar, dysychira abietis, sweet Lay noctuid, the real noctuids of paddy.
Claims (3)
1. one kind contains the Pesticidal combination that first is tieed up salt and HEXAFLUMURON, it is characterized in that: wherein the weight proportion of effective active composition first dimension salt and HEXAFLUMURON is 1 ~ 20:2 ~ 25.
2. described a kind of Pesticidal combination that contains first dimension salt and HEXAFLUMURON according to claim 1, it is characterized in that: wherein the weight proportion of effective active composition first dimension salt and HEXAFLUMURON is 1 ~ 12:2 ~ 15.
3. described a kind of Pesticidal combination that contains first dimension salt and HEXAFLUMURON according to claim 1 and 2, it is characterized in that: described Pesticidal combination can be made into wetting powder, water dispersant, suspending agent, aqueous emulsion or microemulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210494412 CN102939979A (en) | 2012-11-28 | 2012-11-28 | Insecticide combination containing emamectin benzoate and hexaflumuron |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210494412 CN102939979A (en) | 2012-11-28 | 2012-11-28 | Insecticide combination containing emamectin benzoate and hexaflumuron |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102939979A true CN102939979A (en) | 2013-02-27 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210494412 Pending CN102939979A (en) | 2012-11-28 | 2012-11-28 | Insecticide combination containing emamectin benzoate and hexaflumuron |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102939979A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105941434A (en) * | 2016-06-13 | 2016-09-21 | 清华大学 | Controlled-release abamectin nanometer aqueous dispersion agent and preparation method thereof |
| CN106359423A (en) * | 2016-08-20 | 2017-02-01 | 广东中迅农科股份有限公司 | Novel methylaminoavermectin and hexaflumuron suspension and preparation method thereof |
| CN113243382A (en) * | 2021-05-18 | 2021-08-13 | 江苏东南植保有限公司 | Emamectin benzoate and hexaflumuron water dispersible granule and preparation method and preparation device thereof |
-
2012
- 2012-11-28 CN CN 201210494412 patent/CN102939979A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105941434A (en) * | 2016-06-13 | 2016-09-21 | 清华大学 | Controlled-release abamectin nanometer aqueous dispersion agent and preparation method thereof |
| CN105941434B (en) * | 2016-06-13 | 2018-06-22 | 清华大学 | A kind of controlled release avermectin nanometer water dispersant and preparation method thereof |
| CN106359423A (en) * | 2016-08-20 | 2017-02-01 | 广东中迅农科股份有限公司 | Novel methylaminoavermectin and hexaflumuron suspension and preparation method thereof |
| CN113243382A (en) * | 2021-05-18 | 2021-08-13 | 江苏东南植保有限公司 | Emamectin benzoate and hexaflumuron water dispersible granule and preparation method and preparation device thereof |
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Application publication date: 20130227 |