CN102936402A - Low-smoke heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition and preparation method thereof - Google Patents
Low-smoke heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition and preparation method thereof Download PDFInfo
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- CN102936402A CN102936402A CN2011102334427A CN201110233442A CN102936402A CN 102936402 A CN102936402 A CN 102936402A CN 2011102334427 A CN2011102334427 A CN 2011102334427A CN 201110233442 A CN201110233442 A CN 201110233442A CN 102936402 A CN102936402 A CN 102936402A
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- acrylonitrile
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- styrene resin
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 41
- 239000004417 polycarbonate Substances 0.000 title claims abstract description 33
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 32
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 31
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 title claims abstract description 29
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 27
- 239000011342 resin composition Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title abstract description 6
- 239000000779 smoke Substances 0.000 title abstract 4
- 239000011347 resin Substances 0.000 claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 10
- 239000003607 modifier Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000004734 Polyphenylene sulfide Substances 0.000 claims abstract description 7
- 229920000069 polyphenylene sulfide Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 235000019504 cigarettes Nutrition 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 6
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 3
- QOVCUELHTLHMEN-UHFFFAOYSA-N 1-butyl-4-ethenylbenzene Chemical compound CCCCC1=CC=C(C=C)C=C1 QOVCUELHTLHMEN-UHFFFAOYSA-N 0.000 claims description 2
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical group CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 claims description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 2
- DBWWINQJTZYDFK-UHFFFAOYSA-N 2-ethenyl-1,4-dimethylbenzene Chemical compound CC1=CC=C(C)C(C=C)=C1 DBWWINQJTZYDFK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 2
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 2
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- FEEPBTVZSYQUDP-UHFFFAOYSA-N heptatriacontanediamide Chemical compound NC(=O)CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(N)=O FEEPBTVZSYQUDP-UHFFFAOYSA-N 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 229940059574 pentaerithrityl Drugs 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- -1 polyethylene Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 2
- 239000004246 zinc acetate Substances 0.000 claims description 2
- 229920007019 PC/ABS Polymers 0.000 abstract description 8
- 239000000956 alloy Substances 0.000 abstract description 8
- 238000012545 processing Methods 0.000 abstract description 5
- 229910045601 alloy Inorganic materials 0.000 abstract description 4
- 238000000354 decomposition reaction Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 229910052736 halogen Inorganic materials 0.000 abstract description 2
- 150000002367 halogens Chemical class 0.000 abstract description 2
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 abstract 2
- 239000012994 photoredox catalyst Substances 0.000 abstract 1
- 239000012745 toughening agent Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 4
- 238000011056 performance test Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
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Abstract
The invention discloses a low-smoke heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene (PC/ABS) resin composition and a preparation method thereof. The composition consists of the following raw materials by weight: 55-75% of PC resin; 10-28% of ABS resin; 10-40% of a phosphorus-nitrogen halogen-free environment-friendly intumescent flame retardant; 3-10% of a heat-resistant modifier; 0.6-3% of a toughening agent; and 0.6-3% of a processing aid. On the basis of maintaining the original excellent mechanical properties and processing performance of PC and ABS resin, the product provided in the invention adopts the phosphorus-nitrogen halogen-free environment-friendly intumescent flame retardant, so that the product not only can have excellent flame retardance, but also achieves a low smoke effect, and at the same time, the flame retardant decomposition is reduced during processing. The flame retardance can reach the 1.6mmV-0 grade. The adding of a proper molecular weight of polyphenylene sulfide also improves the heat deformation temperature of the composition, so that the multiple requirements of low smoke, heat resistance, no halogen and flame retardance for a PC/ABS alloy at specific occasions can be satisfied.
Description
Technical field
The present invention relates to a kind of low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition and preparation method thereof, belong to technical field of polymer materials.
Background technology
Polycarbonate (PC) and acrylonitrile-butadiene-phenylethene grafted copolymer (ABS) alloy are the thermoplastic alloys of a class excellent property, have very high shock strength, thermotolerance and dimensional stability.Due to its various advantages had, be widely used in industrial spare and accessory parts, the shell of electric equipment products and driving member, office equipment and other field.Along with the development of electronic enterprises, the thermal value of all kinds of electronic devices and components sharply rises at present, and the thermotolerance of the sheating material that this just uses electronic enterprises is had higher requirement; And the PC/ABS alloy material produces a large amount of smog in combustion processes, especially fire retardation PC/ABS is all the more so, the electronic product made from it, once circuit for generating short circuit initiation fire, a large amount of smog is by serious threat people's life security.Along with the raising of living standards of the people, the increasingly stringent of environmentally safe requirement, the PC/ABS alloy material with flame retardant properties is widely used.In recent years, the hidden danger of health problem is subject to people's strong interest containing brominated flame retardant, Halogen class fire retardation PC/ABS alloy material be subject to attention and welcome.
Therefore, develop a kind of low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin, meet the requirement of field of electronics for the low cigarette of PC/ABS alloy material, heat-resisting, halogen-free flameproof, also meet the policy of national environmental protection.
Summary of the invention
The purpose of this invention is to provide a kind of low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition.
Another object of the present invention is for the preparation method of this composition is provided.
In order to achieve the above object, the present invention is achieved through the following technical solutions.
A kind of low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition is comprised of the following raw material in weight part:
PC resin 55-75%;
ABS resinoid 10-28%;
P-N type halogen-free environment-friendly type expanding fire retardant 10-40%;
Heat-proof modifier 3-10%;
Toughner 0.6-3%;
Processing aid 0.6-3%.
Described PC resin is one or both mixing in aliphatics and aromatic copolycarbonate, as 141R and the 121R of GE company;
Described acrylonitrile-butadiene-styrene resin, the product that the trade mark that can adopt ，Ru Taiwan, commercially available prod Qi Mei industrial corporation to produce is PA747S;
Described P-N type halogen-free environment-friendly type expanding fire retardant is selected from one or several mixtures in ammonium polyphosphate, tetramethylolmethane, dipentaerythritol, many tetramethylolmethanes, zinc borate, zinc acetate and trimeric cyanamide;
The polymkeric substance that described heat-proof modifier is substituted phenylethylene or polyphenylene sulfide, wherein, substituted phenylethylene is 2-methyl styrene, 4-butylstyrene, alpha-methyl styrene, 2,5-dimethyl styrene etc.; The numerical value that the polyphenylene sulfide polymerization degree is 20 to 500, the alpha-methyl styrene of Taiwan Qi Mei company;
Described toughner is polyhexamethylene adipamide, as the 1125AC of DUPONT company;
Described processing aid is tetrafluoroethylene, paraffin, Hinered phenols, low molecular weight polyethylene, calcium stearate, Zinic stearas, stearic amide, methylene bis stearic amide and N, one or more in N-ethylene bis stearic acid amide (EBS) and white mineral oil.
The preparation method of above-mentioned low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition, comprise the steps:
After in proportion PC resin, ABS resinoid, fire retardant, heat-proof modifier, toughner, processing aid fully being mixed in super mixer, in the twin screw extruder that is 40: 1 in length-to-diameter ratio, melting mixing is disperseed, extruding pelletization, be low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin of the present invention.
Product of the present invention is on the basis that has retained the original good mechanical property of PC, ABS resin and processing characteristics, adopt P-N type halogen-free environment-friendly type expanding fire retardant, not only make product possess excellent flame retardant properties, also played the effect of low cigarette, reduced the decomposition of fire retardant in the course of processing simultaneously; Its flame retardant properties can reach the 1.6mmV-0 level.Adding of the polyphenylene sulfide of suitable molecular weight also improved its heat-drawn wire, thus meet in specific occasion to the low cigarette of PC/ABS alloy, heat-resistant halogen-free flame-retardant multiple requesting.
Embodiment
Further set forth technical characterstic of the present invention below in conjunction with specific embodiment.
The PC resin is selected the 141R of GE company;
The ABS resinoid is selected 747 of Taiwan Qi Mei company;
P-N type halogen-free environment-friendly type expanding fire retardant is selected the graduate ANTI-610 of oil of SPC;
Heat-proof modifier is selected alpha-methyl styrene and the polyphenylene sulfide of Taiwan Qi Mei company;
Toughner is selected the polyhexamethylene adipamide 1125AC of E.I.Du Pont Company;
Oxidation inhibitor in processing aid is selected 1010 and 168 of Switzerland's Ciba; Anti-dripping agent is the tetrafluoroethylene Teflon 30N of E.I.Du Pont Company, the domestic EBS of processing and lubrication selection of auxiliary, industrial white mineral oil commonly used.
By PC resin, ABS resinoid, fire retardant, heat-proof modifier, toughner, processing aid, in high-speed mixer, the rotating speed turned with per minute 800 under 70～90 ℃ mixes fully and mixes 4～5 minutes; Mixed material is sent in twin screw extruder, the high speed shear of screw rod, mixing and carry under, material is able to sufficient fusing, dispersion, compound; Finally by twin screw extruder, extrude under 220-230 ℃, cooling, dry, pelletizing, obtain the blend product.The length-to-diameter ratio of twin-screw extrusion equipment used is 40: 1; And control and vacuum-pumping equipment with accurate temperature, screw speed is at 300～500 rev/mins.
The standard batten that mixture prepared by each embodiment is injection molded into test use by standard size carries out various performance tests, and the physicals in each embodiment is pressed respectively ASTM standard and U.S. UL standard testing, and test result is as shown in table 3.
Table 1 embodiment 1-5 fill a prescription (parts by weight)
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| The PC resin | 55 | 60 | 65 | 68 | 70 |
| The ABS resinoid | 18 | 16 | 12 | 10 | 10 |
| Fire retardant | 20 | 18 | 18 | 17.8 | 15 |
| Heat-proof modifier | 5.4 | 4.4 | 3.4 | 3 | 3 |
| Toughner | 1 | 0.8 | 0.6 | 0.6 | 1 |
| Processing aid | 0.6 | 0.8 | 1 | 0.6 | 1 |
Table 2 performance test methods
| Physicals | Testing method |
| Tensile strength | ASTM D638 |
| Elongation at break | ASTM D638 |
| The Izod notched Izod impact strength | ASTM D256 |
| Flexural strength | ASTM D790 |
| Modulus in flexure | ASTM D790 |
[0036]
| Heat-drawn wire | ASTM D648 |
| Flame retardant resistance | UL94 |
The performance test results of table 3 embodiment 1-5
| Physicals | 1 | 2 | 3 | 4 | 5 |
| Tensile strength (Mpa) | 55 | 58 | 62 | 63 | 64 |
| Elongation at break (%) | 46 | 44 | 41 | 40 | 38 |
| Flexural strength (Mpa) | 89 | 95 | 99 | 101 | 105 |
| Modulus in flexure (Mpa) | 2490 | 2540 | 2600 | 2618 | 2650 |
| Izod notched Izod impact strength J/m | 400 | 440 | 460 | 466 | 478 |
| Heat-drawn wire (℃, 1.82Mpa) | 111 | 106 | 101 | 99.5 | 99 |
| Flame retardant resistance (1.6mm) | V-0 | V-0 | V-0 | V-0 | V-0 |
From embodiment 1-5, can find, material possesses outstanding flame retardant properties, and flame retardant resistance reaches UL941.6mm V-0 level; Realizing having given material favorable comprehensive mechanical property and higher heat-drawn wire under material halogen-free flameproof condition simultaneously.
Claims (10)
1. one kind low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition is characterized in that: the following raw material in weight part, consist of:
PC resin 55-75%;
ABS resinoid 10-28%;
P-N type halogen-free environment-friendly type expanding fire retardant 10-40%;
Heat-proof modifier 3-10%;
Toughner 0.6-3%;
Processing aid 0.6-3%.
2. low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition according to claim 1, it is characterized in that: described PC resin is one or both mixing in aliphatics and aromatic copolycarbonate.
3. low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition according to claim 2, it is characterized in that: described PC resin is 141R and 121R.
4. low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition according to claim 1, is characterized in that: the product that described acrylonitrile-butadiene-styrene resin is PA747S.
5. low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition according to claim 1, it is characterized in that: described P-N type halogen-free environment-friendly type expanding fire retardant is selected from one or several mixtures in ammonium polyphosphate, tetramethylolmethane, dipentaerythritol, many tetramethylolmethanes, zinc borate, zinc acetate and trimeric cyanamide.
6. low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition according to claim 1, is characterized in that: the polymkeric substance that described heat-proof modifier is substituted phenylethylene or polyphenylene sulfide.
7. low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition according to claim 6, it is characterized in that: described substituted phenylethylene is 2-methyl styrene, the 4-butylstyrene, one or more mixing in alpha-methyl styrene and 2,5-dimethyl styrene; The alpha-methyl styrene that polyphenylene sulfide is Taiwan Qi Mei company, the polymerization degree is 20-500.
8. low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition according to claim 1, it is characterized in that: described toughner is 1125AC.
9. low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition according to claim 1, it is characterized in that: described processing aid is tetrafluoroethylene, paraffin, Hinered phenols, low molecular weight polyethylene, calcium stearate, Zinic stearas, stearic amide, methylene bis stearic amide and N, one or more in N-ethylene bis stearic acid amide and white mineral oil.
10. a method for preparing the described composition of claim 1, is characterized in that: comprise the steps:
After in proportion PC resin, ABS resinoid, fire retardant, heat-proof modifier, toughner, processing aid fully being mixed in super mixer, in the twin screw extruder that is 40: 1 in length-to-diameter ratio, melting mixing is disperseed, extruding pelletization, obtain low cigarette heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin.
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| CN2011102334427A CN102936402A (en) | 2011-08-15 | 2011-08-15 | Low-smoke heat-resistant halogen-free flame-retardant polycarbonate/acrylonitrile-butadiene-styrene resin composition and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103421294A (en) * | 2013-08-23 | 2013-12-04 | 苏州长盛机电有限公司 | Halogen-free flame-retardant enhanced PC/ABS alloy and preparation method thereof |
| CN103724970A (en) * | 2013-12-31 | 2014-04-16 | 奉化市旭日新材料有限公司 | Flame-retardant polycarbonate/acrylonitrile butadiene styrene resin |
| CN103724967A (en) * | 2013-12-17 | 2014-04-16 | 浙江普利特新材料有限公司 | Flame-retarding PC (Polycarbonate)/ABS (Acrylonitrile Butadiene Styrene) blend material for automobile interior trimmings and preparing method thereof |
| CN103740082A (en) * | 2013-12-28 | 2014-04-23 | 重庆普利特新材料有限公司 | UL94-5VA-grade high-performance flame-retardant reinforced PC (polycarbonate)/ABS (acrylonitrile butadiene styrene) blend and preparation method thereof |
| CN103756276A (en) * | 2013-12-28 | 2014-04-30 | 上海普利特复合材料股份有限公司 | Highly environmental-friendly flame retardant reinforced PC (Polycarbonate)/ABS (Acrylonitrile Butadiene Styrene) blending material and preparation method thereof |
| CN106633752A (en) * | 2016-09-26 | 2017-05-10 | 珠海格力电器股份有限公司 | Halogen-free flame-retardant PC/ABS alloy material and preparation method and application thereof |
| CN118702985A (en) * | 2024-08-27 | 2024-09-27 | 飞红线缆集团有限公司 | A wear-resistant low-smoke halogen-free power cable and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1266454A (en) * | 1997-08-11 | 2000-09-13 | 拜尔公司 | Flame resistant polycarbonate ABS moulding materials |
| CN101139459A (en) * | 2007-08-30 | 2008-03-12 | 上海金发科技发展有限公司 | Non-bittern flame-proof thermostable polycarbonate and acrylonitrile-butadiene-phenylethene grafted copolymer alloy resin and method for preparing same |
| CN101205359A (en) * | 2007-11-30 | 2008-06-25 | 上海锦湖日丽塑料有限公司 | Polycarbonate resin / styryl resin non-halogen flame-retardant composite material |
| CN101397396A (en) * | 2007-09-27 | 2009-04-01 | 上海金发科技发展有限公司 | Polycarbonate and acrylic nitrile-butadiene-phenylethylene grafted copolymer heat resisting and flame-retardant alloy |
-
2011
- 2011-08-15 CN CN2011102334427A patent/CN102936402A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1266454A (en) * | 1997-08-11 | 2000-09-13 | 拜尔公司 | Flame resistant polycarbonate ABS moulding materials |
| CN101139459A (en) * | 2007-08-30 | 2008-03-12 | 上海金发科技发展有限公司 | Non-bittern flame-proof thermostable polycarbonate and acrylonitrile-butadiene-phenylethene grafted copolymer alloy resin and method for preparing same |
| CN101397396A (en) * | 2007-09-27 | 2009-04-01 | 上海金发科技发展有限公司 | Polycarbonate and acrylic nitrile-butadiene-phenylethylene grafted copolymer heat resisting and flame-retardant alloy |
| CN101205359A (en) * | 2007-11-30 | 2008-06-25 | 上海锦湖日丽塑料有限公司 | Polycarbonate resin / styryl resin non-halogen flame-retardant composite material |
Non-Patent Citations (1)
| Title |
|---|
| 张晴 等: "膨胀阻燃PC/ABS合金材料燃烧性能研究", 《科技信息（学术研究）》 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103421294A (en) * | 2013-08-23 | 2013-12-04 | 苏州长盛机电有限公司 | Halogen-free flame-retardant enhanced PC/ABS alloy and preparation method thereof |
| CN103724967A (en) * | 2013-12-17 | 2014-04-16 | 浙江普利特新材料有限公司 | Flame-retarding PC (Polycarbonate)/ABS (Acrylonitrile Butadiene Styrene) blend material for automobile interior trimmings and preparing method thereof |
| CN103740082A (en) * | 2013-12-28 | 2014-04-23 | 重庆普利特新材料有限公司 | UL94-5VA-grade high-performance flame-retardant reinforced PC (polycarbonate)/ABS (acrylonitrile butadiene styrene) blend and preparation method thereof |
| CN103756276A (en) * | 2013-12-28 | 2014-04-30 | 上海普利特复合材料股份有限公司 | Highly environmental-friendly flame retardant reinforced PC (Polycarbonate)/ABS (Acrylonitrile Butadiene Styrene) blending material and preparation method thereof |
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| CN103724970A (en) * | 2013-12-31 | 2014-04-16 | 奉化市旭日新材料有限公司 | Flame-retardant polycarbonate/acrylonitrile butadiene styrene resin |
| CN103724970B (en) * | 2013-12-31 | 2016-02-03 | 奉化市旭日新材料有限公司 | A kind of Flame-retardant polycarbonate/acrylobutadiene butadiene styrene resin |
| CN106633752A (en) * | 2016-09-26 | 2017-05-10 | 珠海格力电器股份有限公司 | Halogen-free flame-retardant PC/ABS alloy material and preparation method and application thereof |
| CN118702985A (en) * | 2024-08-27 | 2024-09-27 | 飞红线缆集团有限公司 | A wear-resistant low-smoke halogen-free power cable and preparation method thereof |
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