CN102911600B - modified rosin resin - Google Patents
modified rosin resin Download PDFInfo
- Publication number
- CN102911600B CN102911600B CN201210423497.9A CN201210423497A CN102911600B CN 102911600 B CN102911600 B CN 102911600B CN 201210423497 A CN201210423497 A CN 201210423497A CN 102911600 B CN102911600 B CN 102911600B
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- CN
- China
- Prior art keywords
- butyl
- kilograms
- rosin
- thiophenol
- tolyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 title claims abstract description 23
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 title claims abstract description 23
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 239000011347 resin Substances 0.000 title claims abstract description 13
- 229920005989 resin Polymers 0.000 title claims abstract description 13
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 claims abstract description 33
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims abstract description 22
- -1 (2,4-di-tert-butyl-phenyl) phosphorous acid ester Chemical class 0.000 claims abstract description 20
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 16
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000001530 fumaric acid Substances 0.000 claims abstract description 11
- 229910052740 iodine Inorganic materials 0.000 claims abstract description 11
- 239000011630 iodine Substances 0.000 claims abstract description 11
- 150000002632 lipids Chemical class 0.000 claims abstract description 11
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 11
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000004056 anthraquinones Chemical class 0.000 claims abstract description 9
- 235000011187 glycerol Nutrition 0.000 claims abstract description 9
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims abstract description 9
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000470 constituent Substances 0.000 claims abstract description 5
- 239000003973 paint Substances 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000010422 painting Methods 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000032050 esterification Effects 0.000 description 4
- 238000005886 esterification reaction Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000007259 addition reaction Methods 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of modified rosin resin, relate to chemical technology field, it includes the constituent of following weight percent: primary rosin 55-60%; Fumaric acid 5-10%; Glycerine 15-24.82%; Low iodine number lipid acid 10-20%; Anthraquinone 0.01-0.05%; Three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 0.02-0.05%; 2,6 ditertiary butyl p cresol 0.01-0.05%; 4,4-bis-(a 6-tertiary butyl-tolyl) thiophenol 0.03-0.05%; Trisnonylphenyl phosphite 0.01-0.05%.The present invention can solve horse road marking paint actual production and application in there is painting after easy to change, the problem of poor fluidity.
Description
Technical field
The present invention relates to chemical technology field, especially a kind of Gum Rosin for the production of horse road marking paint.
Background technology
The modified rosin resin used in general production horse road marking paint process carries out addition reaction by rosin and cis-butenedioic anhydride or fumaric acid, conjugated double bond is disappeared, stable chemical nature, oxidation stain tendency lowers, esterification is carried out again with polyvalent alcohol, reduce the acid number of product, improve softening temperature, thus reach service requirements.But due to the oxidizable characteristic of rosin, horse road marking paint is easy to change also there is painting in actual production and application after, the problems such as poor fluidity.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of modified rosin resin, it can solve horse road marking paint actual production and application in there is painting after easy to change, the problem of poor fluidity.
In order to solve the problem, technical scheme of the present invention is:
The weight percent of this modified rosin resin constituent is: primary rosin 55%; Fumaric acid 10%; Glycerine 15%; Low iodine number lipid acid 19.85%; Anthraquinone 0.01%; Three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 0.05%; 2,6 ditertiary butyl p cresol 0.05%; 4,4-bis-(a 6-tertiary butyl-tolyl) thiophenol 0.03%; Trisnonylphenyl phosphite 0.01%;
The weight percent of this modified rosin resin constituent is: primary rosin 60%; Fumaric acid 5%; Glycerine 24.82%; Low iodine number lipid acid 10%; Anthraquinone 0.05%; Three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 0.02%; 2,6 ditertiary butyl p cresol 0.01%; 4,4-bis-(a 6-tertiary butyl-tolyl) thiophenol 0.05%; Trisnonylphenyl phosphite 0.05%.
Owing to adopting technique scheme, the present invention has following beneficial effect:
1, the present invention introduces low iodine number lipid acid Substitute For Partial rosin and carries out esterification, improves discolouration, increases resin to the wetting action of powder.
2, due to the introducing of low iodine number lipid acid, by increasing the amount of fumaric acid, addition reaction can be promoted, conjugated double bond thoroughly reacted, reduces oxidation stain further, solving after there is painting in application easy to change, the problems such as poor fluidity.
3,2,6 ditertiary butyl p cresol, the various antioxidant such as trisnonylphenyl phosphite, agent of losing lustre, adding of stablizer can make Gum Rosin tendency to oxidize in pyroreaction and product stock lower.
4, utilize the Gum Rosin of sustainable use to replace in horse road marking paint and day by day reduce petroleum resin, minimizing carbon emission amount, be conducive to environment protection.
Embodiment
By embodiment, the present invention is described in further detail below:
Embodiment 1--makes 4000 kilograms of modified rosin resins:
The raw material adopted: primary rosin 2200 kilograms; Fumaric acid 400 kilograms; Glycerine 600 kilograms; 794 kilograms, low iodine number lipid acid; Anthraquinone 0.4 kilogram; Three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 2 kilograms; 2,6 ditertiary butyl p cresol 2 kilograms; 4,4-bis-(a 6-tertiary butyl-tolyl) thiophenol 1.2 kilograms; Trisnonylphenyl phosphite 0.4 kilogram.
Making step is:
(1) 2200 kilograms of primary rosins are put in melting kettle, pass into CO 2 gas-shielded, be warming up to 200 DEG C of fusing rosin, completely after fusing, suction esterification pot;
(2) maintenance passes into CO 2 gas-shielded, starts stirring, drops into 400 kilograms of fumaric acid, be warming up to 200 DEG C, be incubated 1 hour;
(3) 0.4 kilogram of anthraquinone is added successively, 2 kilogram three (2,4-di-tert-butyl-phenyl) phosphorous acid ester, 0.6 kilogram 4,4-bis-(a 6-tertiary butyl-tolyl) thiophenol, 600 kilograms of glycerine, 794 kilograms low iodine number lipid acid, were slowly warmed up to 265-270 DEG C with 5 hours, then add 0.6 kilogram 4,4-bis-(a 6-tertiary butyl-tolyl) thiophenol continues insulation at 265-270 DEG C, to acid value≤20;
(4) vacuumize, after one hour, when softening temperature is at 95-102 DEG C, vacuum pump is stopped in acid value≤18, uses carbon dioxide release, is cooled to less than 230 DEG C;
(5) add 2,6 ditertiary butyl p cresol 2 kilograms, trisnonylphenyl phosphite 0.4 kilogram stirs 30 minutes, namely completes after filtration.
Embodiment 2--makes 4000 kilograms of modified rosin resins:
The raw material adopted: primary rosin 2400 kilograms; Fumaric acid 200 kilograms; Glycerine 992.8 kilograms; 400 kilograms, low iodine number lipid acid; Anthraquinone 2 kilograms; Three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 0.8 kilogram; 2,6 ditertiary butyl p cresol 0.4 kilogram; 4,4-bis-(a 6-tertiary butyl-tolyl) thiophenol 2 kilograms; Trisnonylphenyl phosphite 2 kilograms.
Making step is:
(1) 2400 kilograms of primary rosins are put in melting kettle, pass into CO 2 gas-shielded, be warming up to 200 DEG C of fusing rosin, completely after fusing, suction esterification pot;
(2) maintenance passes into CO 2 gas-shielded, starts stirring, drops into 200 kilograms of fumaric acid, be warming up to 200 DEG C, be incubated 1 hour;
(3) 2 kilograms of anthraquinones are added successively, 0.8 kilogram of three (2,4-di-tert-butyl-phenyl) phosphorous acid ester, 1 kilogram 4,4-bis-(a 6-tertiary butyl-tolyl) thiophenol, 992.8 kilograms of glycerine, 400 kilograms low iodine number lipid acid, were slowly warmed up to 265-270 DEG C with 5 hours, add 1 kilogram 4 again, 4-bis-(a 6-tertiary butyl-tolyl) thiophenol, continues insulation at 265-270 DEG C, to acid value≤20;
(4) vacuumize, after one hour, when softening temperature is at 95-102 DEG C, vacuum pump is stopped in acid value≤18, uses carbon dioxide release, is cooled to less than 230 DEG C;
(5) add 0.4 kilogram of 2,6 ditertiary butyl p cresol, 2 kilograms of trisnonylphenyl phosphites stir 30 minutes, namely complete after filtration.
Claims (2)
1. a modified rosin resin, is characterized in that the constituent having following weight percent: primary rosin 55%; Fumaric acid 10%; Glycerine 15%; Low iodine number lipid acid 19.85%; Anthraquinone 0.01%; Three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 0.05%; 2,6 ditertiary butyl p cresol 0.05%; 4,4-bis-(a 6-tertiary butyl-tolyl) thiophenol 0.03%; Trisnonylphenyl phosphite 0.01%.
2. a modified rosin resin, is characterized in that the constituent having following weight percent: primary rosin 60%; Fumaric acid 5%; Glycerine 24.82%; Low iodine number lipid acid 10%; Anthraquinone 0.05%; Three (2,4-di-tert-butyl-phenyl) phosphorous acid ester 0.02%; 2,6 ditertiary butyl p cresol 0.01%; 4,4-bis-(a 6-tertiary butyl-tolyl) thiophenol 0.05%; Trisnonylphenyl phosphite 0.05%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210423497.9A CN102911600B (en) | 2012-10-30 | 2012-10-30 | modified rosin resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210423497.9A CN102911600B (en) | 2012-10-30 | 2012-10-30 | modified rosin resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102911600A CN102911600A (en) | 2013-02-06 |
| CN102911600B true CN102911600B (en) | 2015-10-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210423497.9A Expired - Fee Related CN102911600B (en) | 2012-10-30 | 2012-10-30 | modified rosin resin |
Country Status (1)
| Country | Link |
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| CN (1) | CN102911600B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103421430B (en) * | 2013-08-20 | 2015-01-28 | 广西梧州龙鱼漆业有限公司 | Modified abietate for water-based alkyd resin and method for manufacturing modified abietate |
| CN103436177A (en) * | 2013-08-28 | 2013-12-11 | 广西梧州龙鱼漆业有限公司 | Low-iodine value fatty acid modified rosin resin and preparation method thereof |
| JP6477689B2 (en) * | 2014-03-28 | 2019-03-06 | 荒川化学工業株式会社 | Tackifying resin, adhesive composition containing the same, tackifying resin for hot melt adhesive, hot melt adhesive composition, styrene-conjugated diene block copolymer adhesive composition And styrene-conjugated diene block copolymer system hot-melt adhesive composition |
| CN104031558A (en) * | 2014-06-29 | 2014-09-10 | 陈昆 | Preparation method of rosin glyceride |
| JP7179784B2 (en) | 2017-06-30 | 2022-11-29 | クレイトン・ポリマーズ・エル・エル・シー | Light-colored rosin ester composition and method for producing the same |
| CN113045423B (en) * | 2021-03-16 | 2023-12-29 | 江西金安林产实业有限公司 | High-performance resin based on polymerized rosin base and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101033372A (en) * | 2007-04-12 | 2007-09-12 | 广西梧州金原树脂有限公司 | Rosin modified road guide line resin process flow and production formula |
| CN101134873A (en) * | 2006-08-30 | 2008-03-05 | 东莞市佳景印刷材料有限公司 | Abietyl modified aqueous resin amination liquid and preparation method thereof |
| CN102226059A (en) * | 2011-05-10 | 2011-10-26 | 天津市天宁树脂有限公司 | Phenol-free resin for offset printing ink and preparation method thereof |
| CN102532495A (en) * | 2012-01-10 | 2012-07-04 | 南宁哈利玛化工有限公司 | Rosin modified composite resin and preparation method |
| CN102676062A (en) * | 2012-05-15 | 2012-09-19 | 普洱科茂林化有限公司 | Low-temperature resistant rosin thickening resin, preparation method and usage thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005133052A (en) * | 2003-10-29 | 2005-05-26 | Hitachi Kasei Polymer Co Ltd | Resin for offset ink |
| CN100358959C (en) * | 2005-10-28 | 2008-01-02 | 中国林业科学研究院林产化学工业研究所 | High stability colorless rosin pentaerythritol ester and preparation method thereof |
| US20070179277A1 (en) * | 2006-02-02 | 2007-08-02 | Dallavia Anthony J | Rosin ester with low color and process for preparing same |
-
2012
- 2012-10-30 CN CN201210423497.9A patent/CN102911600B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101134873A (en) * | 2006-08-30 | 2008-03-05 | 东莞市佳景印刷材料有限公司 | Abietyl modified aqueous resin amination liquid and preparation method thereof |
| CN101033372A (en) * | 2007-04-12 | 2007-09-12 | 广西梧州金原树脂有限公司 | Rosin modified road guide line resin process flow and production formula |
| CN102226059A (en) * | 2011-05-10 | 2011-10-26 | 天津市天宁树脂有限公司 | Phenol-free resin for offset printing ink and preparation method thereof |
| CN102532495A (en) * | 2012-01-10 | 2012-07-04 | 南宁哈利玛化工有限公司 | Rosin modified composite resin and preparation method |
| CN102676062A (en) * | 2012-05-15 | 2012-09-19 | 普洱科茂林化有限公司 | Low-temperature resistant rosin thickening resin, preparation method and usage thereof |
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| Publication number | Publication date |
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| CN102911600A (en) | 2013-02-06 |
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