CN102885036A - Microemulsion pesticide and production method thereof - Google Patents
Microemulsion pesticide and production method thereof Download PDFInfo
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- CN102885036A CN102885036A CN 201210367298 CN201210367298A CN102885036A CN 102885036 A CN102885036 A CN 102885036A CN 201210367298 CN201210367298 CN 201210367298 CN 201210367298 A CN201210367298 A CN 201210367298A CN 102885036 A CN102885036 A CN 102885036A
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- agitator tank
- former medicine
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- cyclohexanone
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- 239000004530 micro-emulsion Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- 239000000575 pesticide Substances 0.000 title abstract description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 75
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000203 mixture Substances 0.000 claims abstract description 25
- 238000009472 formulation Methods 0.000 claims abstract description 23
- 239000005660 Abamectin Substances 0.000 claims abstract description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 11
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 claims abstract description 7
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 claims abstract description 7
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims abstract description 4
- 239000005916 Methomyl Substances 0.000 claims abstract description 4
- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 claims abstract description 4
- UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 claims abstract description 4
- 239000003814 drug Substances 0.000 claims description 27
- -1 polyoxyethylene Polymers 0.000 claims description 26
- 239000002917 insecticide Substances 0.000 claims description 20
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 13
- 230000000295 complement effect Effects 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 11
- 238000009313 farming Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 238000005303 weighing Methods 0.000 claims description 10
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 9
- OWYSSKOUATWAAO-UHFFFAOYSA-N C1(=CC=CC=C1)C=1C(=C(C(=C(C1)O)C=C)C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound C1(=CC=CC=C1)C=1C(=C(C(=C(C1)O)C=C)C1=CC=CC=C1)C1=CC=CC=C1 OWYSSKOUATWAAO-UHFFFAOYSA-N 0.000 claims description 9
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
- 239000005903 Gamma-cyhalothrin Substances 0.000 claims description 6
- ZXQYGBMAQZUVMI-GCMPRSNUSA-N gamma-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- ZSBXGIUJOOQZMP-UHFFFAOYSA-N Isomatrine Natural products C1CCC2CN3C(=O)CCCC3C3C2N1CCC3 ZSBXGIUJOOQZMP-UHFFFAOYSA-N 0.000 claims description 3
- ZSBXGIUJOOQZMP-JLNYLFASSA-N Matrine Chemical compound C1CC[C@H]2CN3C(=O)CCC[C@@H]3[C@@H]3[C@H]2N1CCC3 ZSBXGIUJOOQZMP-JLNYLFASSA-N 0.000 claims description 3
- 229930014456 matrine Natural products 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 239000003995 emulsifying agent Substances 0.000 abstract description 3
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 abstract description 2
- 229950008167 abamectin Drugs 0.000 abstract description 2
- ZXQYGBMAQZUVMI-RDDWSQKMSA-N (1S)-cis-(alphaR)-cyhalothrin Chemical compound CC1(C)[C@H](\C=C(/Cl)C(F)(F)F)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-RDDWSQKMSA-N 0.000 abstract 1
- TVFWYUWNQVRQRG-UHFFFAOYSA-N 2,3,4-tris(2-phenylethenyl)phenol Chemical compound C=1C=CC=CC=1C=CC1=C(C=CC=2C=CC=CC=2)C(O)=CC=C1C=CC1=CC=CC=C1 TVFWYUWNQVRQRG-UHFFFAOYSA-N 0.000 abstract 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 abstract 1
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 abstract 1
- 229960001591 cyfluthrin Drugs 0.000 abstract 1
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 abstract 1
- 239000005910 lambda-Cyhalothrin Substances 0.000 abstract 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 abstract 1
- 239000004557 technical material Substances 0.000 abstract 1
- MBNMHBAJUNHZRE-UHFFFAOYSA-M thiosultap monosodium Chemical compound [Na+].OS(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O MBNMHBAJUNHZRE-UHFFFAOYSA-M 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 11
- 238000005338 heat storage Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 230000000749 insecticidal effect Effects 0.000 description 8
- 239000003960 organic solvent Substances 0.000 description 6
- 241000238631 Hexapoda Species 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- DSOOGBGKEWZRIH-UHFFFAOYSA-N nereistoxin Chemical compound CN(C)C1CSSC1 DSOOGBGKEWZRIH-UHFFFAOYSA-N 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- UCSJYZPVAKXKNQ-HZYVHMACSA-N streptomycin Chemical compound CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](C=O)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](NC(N)=N)[C@H](O)[C@@H](NC(N)=N)[C@H](O)[C@H]1O UCSJYZPVAKXKNQ-HZYVHMACSA-N 0.000 description 2
- 230000009885 systemic effect Effects 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000001458 anti-acid effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000000853 biopesticidal effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 1
- 229960001231 choline Drugs 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000003997 cyclic ketones Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003398 denaturant Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 1
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002858 neurotransmitter agent Substances 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229960005322 streptomycin Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000005062 synaptic transmission Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a microemulsion pesticide, which consists of the following components in percentage by weight: 3.5 to 35 percent of technical material, 3 to 20 percent of methanol, 2 to 10 percent of cyclohexanone, 2 to 6 percent of pesticide emulsifier No.404, 2 to 6 percent of tri-styrylphenol polyoxyethylene polyoxypropylene ether, 2 to 6 percent of nonylphenol polyoxyethylene ether, and the balance of water, wherein the chemical material is one or two of beta-cypermethrin, lambda-cyhalothrin, cyfluthrin, methomyl, carbosulfan, monosultap, bisultap, diafenthiuron, hexaflumuron, emamectin benzoate, abamectin and sophocarpidine. The invention has the advantages of wide application range, stable formulation, simple formula and convenience for production.
Description
Technical field
The present invention relates to a kind of insecticide, specifically a kind of microemulsion insecticide and production method thereof belong to the microemulsion insecticide field.
Background technology
A large amount of uses along with agricultural chemicals have brought serious pollution to natural environment, have caused the common concern of the parties concerned.Particularly in today that environmental protection is day by day improved and is strict with, the cry that reduces pesticide pollution more and more adds strongly.The pollution that causes in the applying pesticides process has a large amount of subsidy compositions such as poisonous organic solvents etc. in murder by poisoning that the drift of farm chemical ingredients itself disperses, causes with water and soil loss and the residual and preparation on crop, fruit.In recent years, in countries such as the U.S., in the pesticidal preparations to an organic solvent restriction increasingly stringent, thereby impel the formulations of pesticide to constantly update and to develop, wherein Water-borne modification is exactly one of dominant direction of formulations of pesticide development.Therefore, with water section or replace all that the microemulsion of organic solvent just arises at the historic moment in the missible oil.Microemulsion is comprised of liquid pesticide, surfactant, water, stabilizing agent etc., belong to thermodynamics through the time stable dispersion, mainly take water as medium, do not contain or contain less organic solvent, thereby do not fire not quick-fried, production operation, storing is safe, low in the pollution of the environment, saves a large amount of organic solvents; The pesticide dispersion degree is high, reaches the miniaturization degree, and the agricultural chemicals particle is generally 0.1～0.01 micron, and outward appearance is similar to transparent or sub-translucent liquid; Good dispersion in water is strong to the target body permeability, adhesive force good.
Yet, the problems such as layering, crystallization, muddiness, floccule often appear in present microemulsion product in market, particularly in-20 ℃ the north, such as areas such as Heilungkiang, the Inner Mongol, also the phenomenon of freezing can occur, thereby greatly affect the development of this formulation in technical field of pesticide.In addition, the organic solvent that adds in the microemulsion--stupid kind solvent such as toluene, dimethylbenzene and stupid etc., environmental pollution is serious.
Summary of the invention
The objective of the invention is for the deficiencies in the prior art, a kind of microemulsion insecticide and production method thereof are provided, after adding methyl alcohol, cyclohexanone, triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether, agricultural newborn 404#, polyoxyethylene nonylphenol ether, the product forms that obtains is stable, synergy is remarkable, and the preparation method is simple.
For addressing the above problem, the present invention by the following technical solutions:
A kind of microemulsion insecticide is grouped into by the one-tenth of following percetage by weight:
The former medicine of 3.5-35%, 3-20% methyl alcohol, 2-10% cyclohexanone, the newborn 404# of 2-6% farming, 2-6% triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether, 2-6% polyoxyethylene nonylphenol ether, water complementary;
Wherein, described former medicine is one or both in beta-cypermethrin, gamma cyhalothrin, cyfloxylate, Methomyl, carbosulfan, desinsection list, dimehypo, diafenthiuron, HEXAFLUMURON, first dimension salt, Avermectin, the matrine.
Preferably, the one-tenth by following percetage by weight is grouped into:
20% former medicine, 10% methyl alcohol, 5% cyclohexanone, 4% agricultural newborn 404#, 4% triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether, 4% polyoxyethylene nonylphenol ether, water complementary.
Preferably, 20% former medicine is grouped into by the one-tenth of following percetage by weight: 0.3% Avermectin, 19.7% desinsection list.
Avermectin is the natural materials from Soil Microorganism grey streptomycin.Wherein the strongest with the Bla composition activity, be that good antibiotic desinsection is hidden agent extremely from.Be characterized in the broad-spectrum high efficacy low-residual and to people and animals and Environmental security, stomach toxicity and the action of contace poison of insect hidden from agent without cross resistance extremely with chemistry commonly used again, thereby become one of present China suitability for industrialized production large-tonnage biopesticide.The desinsection list belongs to nereistoxin pesticide.It is extremely strong interior suction, stomach toxicity, tagging has the good bionical insecticide of stifling ovicidal action, noresidue concurrently.Avermectin mainly shields, and without systemic activity, and the longevity of residure is short, and the desinsection list has systemic action, and the longevity of residure is long.There is greatest differences in both chemical constitutions, and each self-applying rake mark is also different.The Avermectin Main Function suppresses neurotransmission in insect neurotransmitter GABA, and the desinsection list is the second phthalein choline competitive inhibitor of insect, makes the insect paralysis.The two is used with, and good preventive effect can be arranged, and can delay again the generation of insect pest resistance.
Methyl alcohol claims again " another name for " or " another name for ", is the colourless volatile liquid of alcohol smell that has, for the manufacture of formaldehyde and agricultural chemicals etc., and as the denaturant of organic extractant and alcohol etc.;
Cyclohexanone, for carbonylic carbon atom is included in saturated cyclic ketones in the hexatomic ring, colourless transparent liquid is industrial main as organic synthesis raw material and solvent;
The triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether, cas 99734-09-5, molecular formula C
30H
24O
.(C
2H
4O) N, model 1601 in the present invention as emulsifier and stabilizing agent, reduces resolution ratio;
Polyoxyethylene nonylphenol ether has another name called OP-10, and this product has good infiltration, emulsification, dispersion, antiacid, alkali resistant, anti-hard water, anti-reduction, oxidation resistance, in the present invention as emulsifier and stabilizing agent;
The production method of above-mentioned microemulsion insecticide may further comprise the steps:
(1) takes by weighing each raw material according to above-mentioned prescription;
(2) first former medicine is joined in the agitator tank, again methyl alcohol, cyclohexanone are joined in the agitator tank, stir, 15-25 minute;
(3) triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether, agricultural newborn 404# and polyoxyethylene nonylphenol ether are joined in the agitator tank of above-mentioned steps (2), stirred 20-30 minute, to fully dissolving;
(4) at last water is joined in the agitator tank of above-mentioned steps (3), stirred 25-30 minute, obtain formulation products.
The invention has the advantages that:
1, applied widely: former medicine can adopt the materials such as beta-cypermethrin, gamma cyhalothrin, cyfloxylate, Methomyl, carbosulfan, desinsection list, dimehypo, diafenthiuron, HEXAFLUMURON, first dimension salt, Avermectin, matrine;
2, formulation is stable: after adding triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether, agricultural newborn 404# and polyoxyethylene nonylphenol ether, less than 1%, cold storage-25 ℃ 90 days is not freezed non-crystallizable, and is higher than missible oil stability in 60 ℃ of 90 days resolution ratios of heat storage;
3 prescriptions are simple, convenient for production: only need an agitator tank, working condition requires low.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein only is used for description and interpretation the present invention, is not intended to limit the present invention.
Except as otherwise noted, the percentage that adopts among the present invention is percetage by weight.
Embodiment 1
20% abamectin pest killing list microemulsion
0.3% Avermectin, 19.7% desinsection list, 10% methyl alcohol, 5% cyclohexanone, 4% agricultural newborn 1601#, 4% agricultural newborn 404#, 4% agricultural newborn OP-10, water complementary.
Production method:
(1) takes by weighing each raw material according to above-mentioned prescription;
(2) first Avermectin, the former medicine of desinsection list are joined in the agitator tank, again methyl alcohol, cyclohexanone are joined in the agitator tank, stir 15-25 minute;
(3) the newborn 1601# of farming, agricultural newborn 404# and agricultural newborn OP-10 are joined in the agitator tank of above-mentioned steps (2), stirred 20-30 minute, to fully dissolving;
(4) at last water is joined in the agitator tank of above-mentioned steps (3), stirred 25-30 minute, obtain formulation products.
The result:
Be 0.1% in 60 ℃ of 90 days resolution ratios of heat storage, cold storage-25 ℃ 90 days is not freezed non-crystallizable;
Synergy is remarkable: by comparative trial, preparation of the present invention is compared with the insecticide of former medicine content with formulation with routine, and other condition is identical, and insecticidal effect increases by 50%.
Embodiment 2
20% avermectin micro-emulsion
One-tenth by following percetage by weight is grouped into:
20% Avermectin, 10% methyl alcohol, 5% cyclohexanone, 4% agricultural newborn 1601#, 4% agricultural newborn 404#, 4% agricultural newborn OP-10, water complementary.
Production method:
(1) takes by weighing each raw material according to above-mentioned prescription;
(2) first the former medicine of 20% Avermectin is joined in the agitator tank, again methyl alcohol, cyclohexanone are joined in the agitator tank, stir, 15-25 minute;
(3) the newborn 1601# of farming, agricultural newborn 404# and agricultural newborn OP-10 are joined in the agitator tank of above-mentioned steps (2), stirred 20-30 minute, to fully dissolving;
(4) at last water is joined in the agitator tank of above-mentioned steps (3), stirred 25-30 minute, obtain formulation products.
The result:
Be 0.1% in 60 ℃ of 90 days resolution ratios of heat storage, cold storage-25 ℃ 90 days is not freezed non-crystallizable;
Synergy is remarkable: by comparative trial, preparation of the present invention is compared with the insecticide of former medicine content with formulation with routine, and other condition is identical, and insecticidal effect increases by 40%.
Embodiment 3
20% desinsection list microemulsion
One-tenth by following percetage by weight is grouped into:
20% desinsection list, 10% methyl alcohol, 5% cyclohexanone, 4% agricultural newborn 1601#, 4% agricultural newborn 404#, 4% agricultural newborn OP-10, water complementary.
Production method:
(1) takes by weighing each raw material according to above-mentioned prescription;
(2) first the former medicine of 20% desinsection list is joined in the agitator tank, again methyl alcohol, cyclohexanone are joined in the agitator tank, stir 15-25 minute;
(3) the newborn 1601# of farming, agricultural newborn 404# and agricultural newborn OP-10 are joined in the agitator tank of above-mentioned steps (2), stirred 20-30 minute, to fully dissolving;
(4) at last water is joined in the agitator tank of above-mentioned steps (3), stirred 25-30 minute, obtain formulation products.
The result:
Be 0.1% in 60 ℃ of 90 days resolution ratios of heat storage, cold storage-25 ℃ 90 days is not freezed non-crystallizable;
Synergy is remarkable: by comparative trial, preparation of the present invention is compared with the insecticide of former medicine content with formulation with routine, and other condition is identical, and insecticidal effect increases by 40%.
Embodiment 4
15% diafenthiuron microemulsion
One-tenth by following percetage by weight is grouped into:
15% diafenthiuron, 10% methyl alcohol, 5% cyclohexanone, 4% agricultural newborn 1601#, 4% agricultural newborn 404#, 4% agricultural newborn OP-10, water complementary.
Production method:
(1) takes by weighing each raw material according to above-mentioned prescription;
(2) first the former medicine of 15% diafenthiuron is joined in the agitator tank, again methyl alcohol, cyclohexanone are joined in the agitator tank, stir, 15-25 minute;
(3) the newborn 1601# of farming, agricultural newborn 404# and agricultural newborn OP-10 are joined in the agitator tank of above-mentioned steps (2), stirred 20-30 minute, to fully dissolving;
(4) at last water is joined in the agitator tank of above-mentioned steps (3), stirred 25-30 minute, obtain formulation products.
The result:
Be 0.1% in 60 ℃ of 90 days resolution ratios of heat storage, cold storage-25 ℃ 90 days is not freezed non-crystallizable;
Synergy is remarkable: by comparative trial, preparation of the present invention is compared with the insecticide of former medicine content with formulation with routine, and other condition is identical, and insecticidal effect increases by 38%.
Embodiment 5
3.5% gamma cyhalothrin microemulsion
One-tenth by following percetage by weight is grouped into:
3.5% gamma cyhalothrin, 10% methyl alcohol, 5% cyclohexanone, 4% agricultural newborn 1601#, 4% agricultural newborn 404#, 4% agricultural newborn OP-10, water complementary.
Production method:
(1) takes by weighing each raw material according to above-mentioned prescription;
(2) first the former medicine of 3.5% gamma cyhalothrin is joined in the agitator tank, again methyl alcohol, cyclohexanone are joined in the agitator tank, stir, 15-25 minute;
(3) the newborn 1601# of farming, agricultural newborn 404# and agricultural newborn OP-10 are joined in the agitator tank of above-mentioned steps (2), stirred 20-30 minute, to fully dissolving;
(4) at last water is joined in the agitator tank of above-mentioned steps (3), stirred 25-30 minute, obtain formulation products.
The result:
Be 0.1% in 60 ℃ of 90 days resolution ratios of heat storage, cold storage-25 ℃ 90 days is not freezed non-crystallizable;
Synergy is remarkable: by comparative trial, preparation of the present invention is compared with the insecticide of former medicine content with formulation with routine, and other condition is identical, and insecticidal effect increases by 30%.
Embodiment 6
20% cyfloxylate microemulsion
One-tenth by following percetage by weight is grouped into:
20% cyfloxylate, 10% methyl alcohol, 5% cyclohexanone, 4% agricultural newborn 1601#, 4% agricultural newborn 404#, 4% agricultural newborn OP-10, water complementary.
Production method:
(1) takes by weighing each raw material according to above-mentioned prescription;
(2) first the former medicine of 20% cyfloxylate is joined in the agitator tank, again methyl alcohol, cyclohexanone are joined in the agitator tank, stir, 15-25 minute;
(3) the newborn 1601# of farming, agricultural newborn 404# and agricultural newborn OP-10 are joined in the agitator tank of above-mentioned steps (2), stirred 20-30 minute, to fully dissolving;
(4) at last water is joined in the agitator tank of above-mentioned steps (3), stirred 25-30 minute, obtain formulation products.
The result:
Be 0.1% in 60 ℃ of 90 days resolution ratios of heat storage, cold storage-25 ℃ 90 days is not freezed non-crystallizable;
Synergy is remarkable: by comparative trial, preparation of the present invention is compared with the insecticide of former medicine content with formulation with routine, and other condition is identical, and insecticidal effect increases by 35%.
Embodiment 7
25% dimehypo microemulsion
One-tenth by following percetage by weight is grouped into:
25% dimehypo, 10% methyl alcohol, 5% cyclohexanone, 4% agricultural newborn 1601#, 4% agricultural newborn 404#, 4% agricultural newborn OP-10, water complementary.
Production method:
(1) takes by weighing each raw material according to above-mentioned prescription;
(2) first the former medicine of 25% dimehypo is joined in the agitator tank, again methyl alcohol, cyclohexanone are joined in the agitator tank, stir, 15-25 minute;
(3) the newborn 1601# of farming, agricultural newborn 404# and agricultural newborn OP-10 are joined in the agitator tank of above-mentioned steps (2), stirred 20-30 minute, to fully dissolving;
(4) at last water is joined in the agitator tank of above-mentioned steps (3), stirred 25-30 minute, obtain formulation products.
The result:
Be 0.1% in 60 ℃ of 90 days resolution ratios of heat storage, cold storage-25 ℃ 90 days is not freezed non-crystallizable;
Synergy is remarkable: by comparative trial, preparation of the present invention is compared with the insecticide of former medicine content with formulation with routine, and other condition is identical, and insecticidal effect increases by 36%.
Embodiment 8
35% first dimension salt microemulsion
One-tenth by following percetage by weight is grouped into:
35% first dimension salt, 10% methyl alcohol, 5% cyclohexanone, 4% agricultural newborn 1601#, 4% agricultural newborn 404#, 4% agricultural newborn OP-10, water complementary.
Production method:
(1) takes by weighing each raw material according to above-mentioned prescription;
(2) first the former medicine of 35% first dimension salt is joined in the agitator tank, again methyl alcohol, cyclohexanone are joined in the agitator tank, stir 15-25 minute;
(3) the newborn 1601# of farming, agricultural newborn 404# and agricultural newborn OP-10 are joined in the agitator tank of above-mentioned steps (2), stirred 20-30 minute, to fully dissolving;
(4) at last water is joined in the agitator tank of above-mentioned steps (3), stirred 25-30 minute, obtain formulation products.
The result:
Be 0.1% in 60 ℃ of 90 days resolution ratios of heat storage, cold storage-25 ℃ 90 days is not freezed non-crystallizable;
Synergy is remarkable: by comparative trial, preparation of the present invention is compared with the insecticide of former medicine content with formulation with routine, and other condition is identical, and insecticidal effect increases by 35%.
Among each embodiment of the present invention, used chemical industry material is used material in the production of this area, all can obtain from market, and can not exert an influence for the production result; The equipment of using in each operation all adopts conventional equipment used in the current production, there is no special feature.
It should be noted that at last: the above only is the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment the present invention is had been described in detail, for a person skilled in the art, it still can be made amendment to the technical scheme that aforementioned each embodiment puts down in writing, and perhaps part technical characterictic wherein is equal to replacement.Within the spirit and principles in the present invention all, any modification of doing, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. microemulsion insecticide is grouped into by the one-tenth of following percetage by weight:
The former medicine of 3.5-35%, 3-20% methyl alcohol, 2-10% cyclohexanone, the newborn 404# of 2-6% farming, 2-6% triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether, 2-6% polyoxyethylene nonylphenol ether, water complementary;
Wherein, described former medicine is one or both in beta-cypermethrin, gamma cyhalothrin, cyfloxylate, Methomyl, carbosulfan, desinsection list, dimehypo, diafenthiuron, HEXAFLUMURON, first dimension salt, Avermectin, the matrine.
2. microemulsion insecticide according to claim 1, it is characterized in that: the one-tenth by following percetage by weight is grouped into: 20% former medicine, 10% methyl alcohol, 5% cyclohexanone, 4% agricultural newborn 404#, 4% triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether, 4% polyoxyethylene nonylphenol ether, water complementary.
3. microemulsion insecticide according to claim 2, it is characterized in that: 20% former medicine is grouped into by the one-tenth of following percetage by weight: 0.3% Avermectin, 19.7% desinsection list.
4. the production method of a microemulsion insecticide as claimed in claim 1 is characterized in that, may further comprise the steps:
(1) takes by weighing each raw material according to above-mentioned prescription;
(2) first former medicine is joined in the agitator tank, again methyl alcohol, cyclohexanone are joined in the agitator tank, stir, 15-25 minute;
(3) triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether, agricultural newborn 404# and polyoxyethylene nonylphenol ether are joined in the agitator tank of above-mentioned steps (2), stirred 20-30 minute, to fully dissolving;
(4) at last water is joined in the agitator tank of above-mentioned steps (3), stirred 25-30 minute, obtain formulation products.
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| CN 201210367298 CN102885036A (en) | 2012-09-28 | 2012-09-28 | Microemulsion pesticide and production method thereof |
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| CN 201210367298 CN102885036A (en) | 2012-09-28 | 2012-09-28 | Microemulsion pesticide and production method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651525A (en) * | 2013-12-06 | 2014-03-26 | 济南凯因生物科技有限公司 | Missible oil for controlling meadow moth |
| CN103975915A (en) * | 2014-05-23 | 2014-08-13 | 青岛金正农药有限公司 | Additive composition for emamectin benzoate microemulsion and application method of additive composition |
| CN104170831A (en) * | 2013-05-23 | 2014-12-03 | 海安县国力化工有限公司 | Pesticide |
| CN105724440A (en) * | 2016-04-26 | 2016-07-06 | 江苏东珠景观股份有限公司 | Cinnamomum camphora insecticide and preparation method thereof |
| CN106719780A (en) * | 2016-12-26 | 2017-05-31 | 中国农业科学院植物保护研究所 | A kind of synergetic pesticide composition containing gamma cyhalothrin Yu HEXAFLUMURON |
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2012
- 2012-09-28 CN CN 201210367298 patent/CN102885036A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104170831A (en) * | 2013-05-23 | 2014-12-03 | 海安县国力化工有限公司 | Pesticide |
| CN103651525A (en) * | 2013-12-06 | 2014-03-26 | 济南凯因生物科技有限公司 | Missible oil for controlling meadow moth |
| CN103975915A (en) * | 2014-05-23 | 2014-08-13 | 青岛金正农药有限公司 | Additive composition for emamectin benzoate microemulsion and application method of additive composition |
| CN103975915B (en) * | 2014-05-23 | 2016-04-13 | 青岛金正农药有限公司 | A kind of assistant composition for emamectin benzoate microemulsion and application method thereof |
| CN105724440A (en) * | 2016-04-26 | 2016-07-06 | 江苏东珠景观股份有限公司 | Cinnamomum camphora insecticide and preparation method thereof |
| CN106719780A (en) * | 2016-12-26 | 2017-05-31 | 中国农业科学院植物保护研究所 | A kind of synergetic pesticide composition containing gamma cyhalothrin Yu HEXAFLUMURON |
| CN106719780B (en) * | 2016-12-26 | 2019-04-02 | 中国农业科学院植物保护研究所 | A kind of synergetic pesticide composition containing gamma cyhalothrin and flubenzuron |
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