CN102823603A - Sterilization compound containing chloroisobromine cyanuric acid - Google Patents
Sterilization compound containing chloroisobromine cyanuric acid Download PDFInfo
- Publication number
- CN102823603A CN102823603A CN2012103456286A CN201210345628A CN102823603A CN 102823603 A CN102823603 A CN 102823603A CN 2012103456286 A CN2012103456286 A CN 2012103456286A CN 201210345628 A CN201210345628 A CN 201210345628A CN 102823603 A CN102823603 A CN 102823603A
- Authority
- CN
- China
- Prior art keywords
- bactericide
- copper
- azoles
- bacterium
- isocyanuric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 9
- 230000001954 sterilising effect Effects 0.000 title abstract description 6
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 title abstract description 4
- 238000004659 sterilization and disinfection Methods 0.000 title abstract 5
- 241000894006 Bacteria Species 0.000 claims abstract description 45
- 229910052802 copper Inorganic materials 0.000 claims abstract description 32
- 239000010949 copper Substances 0.000 claims abstract description 32
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 28
- 150000002460 imidazoles Chemical class 0.000 claims abstract description 12
- 150000003852 triazoles Chemical class 0.000 claims abstract description 10
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 claims abstract description 8
- 150000002780 morpholines Chemical class 0.000 claims abstract description 7
- 150000002916 oxazoles Chemical class 0.000 claims abstract description 7
- 150000001408 amides Chemical class 0.000 claims abstract description 6
- 239000003814 drug Substances 0.000 claims abstract description 5
- 150000001555 benzenes Chemical class 0.000 claims abstract description 4
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims abstract description 4
- 150000008056 dicarboxyimides Chemical class 0.000 claims abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 claims description 119
- 239000003899 bactericide agent Substances 0.000 claims description 112
- DZZOJKGQQSORQI-UHFFFAOYSA-N N1C(=O)NC(=O)NC1=O.ClBr Chemical compound N1C(=O)NC(=O)NC1=O.ClBr DZZOJKGQQSORQI-UHFFFAOYSA-N 0.000 claims description 36
- 150000003851 azoles Chemical class 0.000 claims description 36
- -1 pyroles Chemical class 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 33
- 239000000417 fungicide Substances 0.000 claims description 19
- 150000002148 esters Chemical class 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000005784 Fluoxastrobin Substances 0.000 claims description 12
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims description 12
- 230000000855 fungicidal effect Effects 0.000 claims description 12
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims description 10
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims description 8
- 239000005776 Fenhexamid Substances 0.000 claims description 8
- UDSJPFPDKCMYBD-UHFFFAOYSA-N Metsulfovax Chemical compound S1C(C)=NC(C)=C1C(=O)NC1=CC=CC=C1 UDSJPFPDKCMYBD-UHFFFAOYSA-N 0.000 claims description 8
- 239000005869 Pyraclostrobin Substances 0.000 claims description 8
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 8
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 8
- 150000001336 alkenes Chemical class 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- YEOCHZFPBYUXMC-UHFFFAOYSA-L copper benzoate Chemical compound [Cu+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 YEOCHZFPBYUXMC-UHFFFAOYSA-L 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- VDLGAVXLJYLFDH-UHFFFAOYSA-N fenhexamid Chemical compound C=1C=C(O)C(Cl)=C(Cl)C=1NC(=O)C1(C)CCCCC1 VDLGAVXLJYLFDH-UHFFFAOYSA-N 0.000 claims description 8
- 239000011737 fluorine Substances 0.000 claims description 8
- 229910052731 fluorine Inorganic materials 0.000 claims description 8
- CJPQIRJHIZUAQP-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)alaninate Chemical compound CC=1C=CC=C(C)C=1N(C(C)C(=O)OC)C(=O)CC1=CC=CC=C1 CJPQIRJHIZUAQP-UHFFFAOYSA-N 0.000 claims description 8
- 150000002825 nitriles Chemical class 0.000 claims description 8
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 8
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims description 8
- WOSNCVAPUOFXEH-UHFFFAOYSA-N thifluzamide Chemical compound S1C(C)=NC(C(F)(F)F)=C1C(=O)NC1=C(Br)C=C(OC(F)(F)F)C=C1Br WOSNCVAPUOFXEH-UHFFFAOYSA-N 0.000 claims description 8
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 6
- 230000002070 germicidal effect Effects 0.000 claims description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical class C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 claims description 6
- 239000011717 all-trans-retinol Substances 0.000 claims description 5
- 235000019169 all-trans-retinol Nutrition 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 5
- PPDBOQMNKNNODG-NTEUORMPSA-N (5E)-5-(4-chlorobenzylidene)-2,2-dimethyl-1-(1,2,4-triazol-1-ylmethyl)cyclopentanol Chemical compound C1=NC=NN1CC1(O)C(C)(C)CC\C1=C/C1=CC=C(Cl)C=C1 PPDBOQMNKNNODG-NTEUORMPSA-N 0.000 claims description 4
- RMOGWMIKYWRTKW-UONOGXRCSA-N (S,S)-paclobutrazol Chemical compound C([C@@H]([C@@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1 RMOGWMIKYWRTKW-UONOGXRCSA-N 0.000 claims description 4
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 claims description 4
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims description 4
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 claims description 4
- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 claims description 4
- RQDJADAKIFFEKQ-UHFFFAOYSA-N 4-(4-chlorophenyl)-2-phenyl-2-(1,2,4-triazol-1-ylmethyl)butanenitrile Chemical compound C1=CC(Cl)=CC=C1CCC(C=1C=CC=CC=1)(C#N)CN1N=CN=C1 RQDJADAKIFFEKQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000005740 Boscalid Substances 0.000 claims description 4
- 239000005741 Bromuconazole Substances 0.000 claims description 4
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims description 4
- 239000005746 Carboxin Substances 0.000 claims description 4
- 239000005752 Copper oxychloride Substances 0.000 claims description 4
- 239000005757 Cyproconazole Substances 0.000 claims description 4
- 239000005760 Difenoconazole Substances 0.000 claims description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 4
- 239000005785 Fluquinconazole Substances 0.000 claims description 4
- 239000005786 Flutolanil Substances 0.000 claims description 4
- 239000005787 Flutriafol Substances 0.000 claims description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 4
- 239000005867 Iprodione Substances 0.000 claims description 4
- 239000005800 Kresoxim-methyl Substances 0.000 claims description 4
- WLLGXSLBOPFWQV-UHFFFAOYSA-N MGK 264 Chemical compound C1=CC2CC1C1C2C(=O)N(CC(CC)CCCC)C1=O WLLGXSLBOPFWQV-UHFFFAOYSA-N 0.000 claims description 4
- 239000005802 Mancozeb Substances 0.000 claims description 4
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims description 4
- 239000005807 Metalaxyl Substances 0.000 claims description 4
- 239000005808 Metalaxyl-M Substances 0.000 claims description 4
- CFZLNRGUBAVQNO-UHFFFAOYSA-N N-(3,5-Dichlorophenyl)succinimide Chemical compound ClC1=CC(Cl)=CC(N2C(CCC2=O)=O)=C1 CFZLNRGUBAVQNO-UHFFFAOYSA-N 0.000 claims description 4
- JHXVRRJXCDAINK-UHFFFAOYSA-N NC(=O)N.N#CC#N Chemical compound NC(=O)N.N#CC#N JHXVRRJXCDAINK-UHFFFAOYSA-N 0.000 claims description 4
- 239000005985 Paclobutrazol Substances 0.000 claims description 4
- 239000005813 Penconazole Substances 0.000 claims description 4
- 239000005820 Prochloraz Substances 0.000 claims description 4
- 239000005822 Propiconazole Substances 0.000 claims description 4
- 239000005823 Propineb Substances 0.000 claims description 4
- 239000005839 Tebuconazole Substances 0.000 claims description 4
- 239000005842 Thiophanate-methyl Substances 0.000 claims description 4
- 239000005846 Triadimenol Substances 0.000 claims description 4
- 239000005859 Triticonazole Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- BESJRHHIPGWPTC-UHFFFAOYSA-N azane;copper Chemical compound N.[Cu] BESJRHHIPGWPTC-UHFFFAOYSA-N 0.000 claims description 4
- LJOZMWRYMKECFF-UHFFFAOYSA-N benodanil Chemical compound IC1=CC=CC=C1C(=O)NC1=CC=CC=C1 LJOZMWRYMKECFF-UHFFFAOYSA-N 0.000 claims description 4
- 229940118790 boscalid Drugs 0.000 claims description 4
- WYEMLYFITZORAB-UHFFFAOYSA-N boscalid Chemical compound C1=CC(Cl)=CC=C1C1=CC=CC=C1NC(=O)C1=CC=CN=C1Cl WYEMLYFITZORAB-UHFFFAOYSA-N 0.000 claims description 4
- HJJVPARKXDDIQD-UHFFFAOYSA-N bromuconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCC(Br)C1 HJJVPARKXDDIQD-UHFFFAOYSA-N 0.000 claims description 4
- 239000006013 carbendazim Substances 0.000 claims description 4
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical group C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 claims description 4
- GYSSRZJIHXQEHQ-UHFFFAOYSA-N carboxin Chemical compound S1CCOC(C)=C1C(=O)NC1=CC=CC=C1 GYSSRZJIHXQEHQ-UHFFFAOYSA-N 0.000 claims description 4
- HKMOPYJWSFRURD-UHFFFAOYSA-N chloro hypochlorite;copper Chemical compound [Cu].ClOCl HKMOPYJWSFRURD-UHFFFAOYSA-N 0.000 claims description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 4
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 claims description 4
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 claims description 4
- ZCXLQZOQWCXFNN-UHFFFAOYSA-N copper;hexanedioic acid Chemical compound [Cu].OC(=O)CCCCC(O)=O ZCXLQZOQWCXFNN-UHFFFAOYSA-N 0.000 claims description 4
- IURRXCRWRKQLGC-UHFFFAOYSA-N copper;quinolin-8-ol Chemical compound [Cu].C1=CN=C2C(O)=CC=CC2=C1.C1=CN=C2C(O)=CC=CC2=C1 IURRXCRWRKQLGC-UHFFFAOYSA-N 0.000 claims description 4
- CWVRPJSBNHNJSI-XQNSMLJCSA-N coumoxystrobin Chemical compound C1=C2OC(=O)C(CCCC)=C(C)C2=CC=C1OCC1=CC=CC=C1\C(=C/OC)C(=O)OC CWVRPJSBNHNJSI-XQNSMLJCSA-N 0.000 claims description 4
- FWBOFUGDKHMVPI-UHFFFAOYSA-K dicopper;2-oxidopropane-1,2,3-tricarboxylate Chemical compound [Cu+2].[Cu+2].[O-]C(=O)CC([O-])(C([O-])=O)CC([O-])=O FWBOFUGDKHMVPI-UHFFFAOYSA-K 0.000 claims description 4
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims description 4
- VMNULHCTRPXWFJ-UJSVPXBISA-N enoxastrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)\C=C\C1=CC=C(Cl)C=C1 VMNULHCTRPXWFJ-UJSVPXBISA-N 0.000 claims description 4
- JFSPBVWPKOEZCB-UHFFFAOYSA-N fenfuram Chemical compound O1C=CC(C(=O)NC=2C=CC=CC=2)=C1C JFSPBVWPKOEZCB-UHFFFAOYSA-N 0.000 claims description 4
- IJJVMEJXYNJXOJ-UHFFFAOYSA-N fluquinconazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1N1C(=O)C2=CC(F)=CC=C2N=C1N1C=NC=N1 IJJVMEJXYNJXOJ-UHFFFAOYSA-N 0.000 claims description 4
- FQKUGOMFVDPBIZ-UHFFFAOYSA-N flusilazole Chemical compound C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 FQKUGOMFVDPBIZ-UHFFFAOYSA-N 0.000 claims description 4
- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 claims description 4
- IQECZGDVZMVJSH-UHFFFAOYSA-N furan 1H-pyrazole Chemical class O1C=CC=C1.N1N=CC=C1 IQECZGDVZMVJSH-UHFFFAOYSA-N 0.000 claims description 4
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical group O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 claims description 4
- UFHLMYOGRXOCSL-UHFFFAOYSA-N isoprothiolane Chemical compound CC(C)OC(=O)C(C(=O)OC(C)C)=C1SCCS1 UFHLMYOGRXOCSL-UHFFFAOYSA-N 0.000 claims description 4
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 claims description 4
- 239000011565 manganese chloride Substances 0.000 claims description 4
- 229940099607 manganese chloride Drugs 0.000 claims description 4
- OXOKTPUZOHPXSA-UHFFFAOYSA-L manganese(2+);n-propyl-n-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1-carboxamide;dichloride Chemical compound Cl[Mn]Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl OXOKTPUZOHPXSA-UHFFFAOYSA-L 0.000 claims description 4
- ZQEIXNIJLIKNTD-GFCCVEGCSA-N metalaxyl-M Chemical compound COCC(=O)N([C@H](C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-GFCCVEGCSA-N 0.000 claims description 4
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 claims description 4
- 150000002923 oximes Chemical class 0.000 claims description 4
- AMEKQAFGQBKLKX-UHFFFAOYSA-N oxycarboxin Chemical compound O=S1(=O)CCOC(C)=C1C(=O)NC1=CC=CC=C1 AMEKQAFGQBKLKX-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- WBTYBAGIHOISOQ-UHFFFAOYSA-N pent-4-en-1-yl 2-[(2-furylmethyl)(imidazol-1-ylcarbonyl)amino]butanoate Chemical compound C1=CN=CN1C(=O)N(C(CC)C(=O)OCCCC=C)CC1=CC=CO1 WBTYBAGIHOISOQ-UHFFFAOYSA-N 0.000 claims description 4
- WUHLVXDDBHWHLQ-UHFFFAOYSA-N pentazole Chemical class N=1N=NNN=1 WUHLVXDDBHWHLQ-UHFFFAOYSA-N 0.000 claims description 4
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 claims description 4
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 claims description 4
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 claims description 4
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 claims description 4
- ROZUQUDEWZIBHV-UHFFFAOYSA-N tecloftalam Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(=O)NC1=CC=CC(Cl)=C1Cl ROZUQUDEWZIBHV-UHFFFAOYSA-N 0.000 claims description 4
- LITQZINTSYBKIU-UHFFFAOYSA-F tetracopper;hexahydroxide;sulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]S([O-])(=O)=O LITQZINTSYBKIU-UHFFFAOYSA-F 0.000 claims description 4
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical group COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 claims description 4
- 229930192474 thiophene Natural products 0.000 claims description 4
- VJQYLJSMBWXGDV-UHFFFAOYSA-N tiadinil Chemical compound N1=NSC(C(=O)NC=2C=C(Cl)C(C)=CC=2)=C1C VJQYLJSMBWXGDV-UHFFFAOYSA-N 0.000 claims description 4
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 claims description 4
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 claims description 4
- YNWVFADWVLCOPU-MAUPQMMJSA-N uniconazole P Chemical compound C1=NC=NN1/C([C@@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MAUPQMMJSA-N 0.000 claims description 4
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 claims description 4
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical group C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 claims description 3
- BKBSMMUEEAWFRX-NBVRZTHBSA-N (E)-flumorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(F)=CC=1)=C\C(=O)N1CCOCC1 BKBSMMUEEAWFRX-NBVRZTHBSA-N 0.000 claims description 3
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 claims description 3
- VGPIBGGRCVEHQZ-UHFFFAOYSA-N 1-(biphenyl-4-yloxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC(C=C1)=CC=C1C1=CC=CC=C1 VGPIBGGRCVEHQZ-UHFFFAOYSA-N 0.000 claims description 3
- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 claims description 3
- YTOPFCCWCSOHFV-UHFFFAOYSA-N 2,6-dimethyl-4-tridecylmorpholine Chemical compound CCCCCCCCCCCCCN1CC(C)OC(C)C1 YTOPFCCWCSOHFV-UHFFFAOYSA-N 0.000 claims description 3
- DHVLDKHFGIVEIP-UHFFFAOYSA-N 2-bromo-2-(bromomethyl)pentanedinitrile Chemical compound BrCC(Br)(C#N)CCC#N DHVLDKHFGIVEIP-UHFFFAOYSA-N 0.000 claims description 3
- NMWKWBPNKPGATC-UHFFFAOYSA-N 4,5,6,7-tetrachloro-2-benzofuran-1(3H)-one Chemical compound ClC1=C(Cl)C(Cl)=C2COC(=O)C2=C1Cl NMWKWBPNKPGATC-UHFFFAOYSA-N 0.000 claims description 3
- 239000005745 Captan Substances 0.000 claims description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 3
- 239000005761 Dimethomorph Substances 0.000 claims description 3
- 239000005781 Fludioxonil Substances 0.000 claims description 3
- 239000005789 Folpet Substances 0.000 claims description 3
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 claims description 3
- 239000005821 Propamocarb Substances 0.000 claims description 3
- 239000005840 Tetraconazole Substances 0.000 claims description 3
- 229940117949 captan Drugs 0.000 claims description 3
- FKLFBQCQQYDUAM-UHFFFAOYSA-N fenpiclonil Chemical compound ClC1=CC=CC(C=2C(=CNC=2)C#N)=C1Cl FKLFBQCQQYDUAM-UHFFFAOYSA-N 0.000 claims description 3
- MUJOIMFVNIBMKC-UHFFFAOYSA-N fludioxonil Chemical group C=12OC(F)(F)OC2=CC=CC=1C1=CNC=C1C#N MUJOIMFVNIBMKC-UHFFFAOYSA-N 0.000 claims description 3
- HKIOYBQGHSTUDB-UHFFFAOYSA-N folpet Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C2=C1 HKIOYBQGHSTUDB-UHFFFAOYSA-N 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- UWVQIROCRJWDKL-UHFFFAOYSA-N oxadixyl Chemical compound CC=1C=CC=C(C)C=1N(C(=O)COC)N1CCOC1=O UWVQIROCRJWDKL-UHFFFAOYSA-N 0.000 claims description 3
- WZZLDXDUQPOXNW-UHFFFAOYSA-N propamocarb Chemical group CCCOC(=O)NCCCN(C)C WZZLDXDUQPOXNW-UHFFFAOYSA-N 0.000 claims description 3
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 claims description 3
- 238000001228 spectrum Methods 0.000 abstract description 4
- 125000003785 benzimidazolyl group Chemical class N1=C(NC2=C1C=CC=C2)* 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 239000003206 sterilizing agent Substances 0.000 abstract 9
- 238000013329 compounding Methods 0.000 abstract 2
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 125000005543 phthalimide group Chemical class 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 16
- 241000233866 Fungi Species 0.000 description 8
- 238000000034 method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 241000700605 Viruses Species 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 244000000010 microbial pathogen Species 0.000 description 3
- 244000052769 pathogen Species 0.000 description 3
- 230000001717 pathogenic effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000009885 systemic effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- 239000005739 Bordeaux mixture Substances 0.000 description 1
- 241000233652 Chytridiomycota Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 102100025287 Cytochrome b Human genes 0.000 description 1
- 108010075028 Cytochromes b Proteins 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- IWDQPCIQCXRBQP-UHFFFAOYSA-M Fenaminosulf Chemical compound [Na+].CN(C)C1=CC=C(N=NS([O-])(=O)=O)C=C1 IWDQPCIQCXRBQP-UHFFFAOYSA-M 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 241000204031 Mycoplasma Species 0.000 description 1
- 241000233654 Oomycetes Species 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 241000221300 Puccinia Species 0.000 description 1
- 241001361634 Rhizoctonia Species 0.000 description 1
- 241000606701 Rickettsia Species 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 229930182692 Strobilurin Natural products 0.000 description 1
- 241001052560 Thallis Species 0.000 description 1
- 241000722133 Tilletia Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 241000221576 Uromyces Species 0.000 description 1
- 241000221566 Ustilago Species 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 239000003619 algicide Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 244000144987 brood Species 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ALKZAGKDWUSJED-UHFFFAOYSA-N dinuclear copper ion Chemical compound [Cu].[Cu] ALKZAGKDWUSJED-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- CUILPNURFADTPE-UHFFFAOYSA-N hypobromous acid Chemical compound BrO CUILPNURFADTPE-UHFFFAOYSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 230000006540 mitochondrial respiration Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 210000001082 somatic cell Anatomy 0.000 description 1
- 230000004763 spore germination Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000012873 virucide Substances 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a sterilization compound containing chloroisobromine cyanuric acid, comprising a raw medicine formed by compounding a sterilizing agent A and a sterilizing agent B, wherein the proportion of the sterilizing agent A to the sterilizing agent B is (1-80):(1-80); the sterilizing agent A is the chloroisobromine cyanuric acid; and the sterilizing agent B is any one of the following types of the sterilizing agents: copper preparations, methoxy acrylic esters, triazoles, amides, benzimidazoles, thiocarbamates, substituted benzenes, dicarboximides, phthalimides, imidazoles, morpholines, carbamates, oxazoles and the like. The sterilization compound is formed by compounding the sterilizing agent A and the sterilizing agent B so that not only a sterilization spectrum is enlarged, but also the drug resistance of bacteria is slowed; and the sterilization compound has an obvious lasting synergistic effect.
Description
Technical field
The present invention relates to technical field of pesticide, specifically, relate to a kind of bactericidal composition that contains chlorobromide isocyanuric acid.
Background technology
Bactericide is the one type of agricultural chemicals that is used to prevent and treat the plant disease that is caused by various pathogenic microorganisms, refers generally to fungicide.But in the world, normally as the general name of medicament of all kinds of pathogenic microorganisms of control.Along with the development of bactericide, distinguish subclass such as bactericide, virucide, algicide again.According to investigations, the whole world pathogenic microorganism (fungi, strong bacterium, rickettsia, mycoplasma, virus, algae etc.) harmful to plant has more than 80,000 kinds.Using bactericide is a kind of cost-effective method of controlling plant diseases.
Early stage bactericide all is an inorganic compound, is wherein still using so far like Cosan and copper agent (like bordeaux mixture).Twentieth century four the fifties, developed the organosulfureous fungicides that three main series are arranged: beautiful type of good fortune, generation gloomy type of (like zineb) and trichloro-methylthio diformazan carboxylic acid imide, organochlorine, organic mercury, organoarsenic fungicide also have development in addition.These bactericide are protectant mostly, and limitation is arranged in the application.Since the sixties, more the bactericide of polyvoltine type constantly occurs, and wherein most important progress is the appearance of systemic fungicide.Meanwhile, farm antibiotics also has development faster.Organic mercury, organo-arsenic and some organochlorine bactericide are because of toxicity or problem of environmental pollution gradually are eliminated.The systemics bactericide of a new generation further enlarges the market of bactericide owing to control efficiency improves.To the eighties, the kind of bactericide is above 200 kinds.
Chlorobromide isocyanuric acid, english common name: chloroisobromine cyanuric acid, spray in crop surface and can discharge hypobromous acid (HOBr) and hypochlorous acid (HOCL) at leisure, the ability of strong kill bacteria, fungi and virus is arranged.In addition, because of initiation material is rich in sylvite and trace element crowd, therefore, chlorobromide isocyanuric acid not only has the ability of strong prevention and kill bacteria, fungi and virus, and effect such as promotion crop alimentary growth is arranged.
Yet in the real process of agricultural production, preventing and treating the problem that disease is easy to generate most is the drug-fast generation of germ.The different cultivars composition carries out composite, is to prevent and treat the very common method of resistance germ.
Copper agent, all effective to fungi, bacterium, and do not have resistance, there is not volatility.Its sterilizing mechanisms is: moisture copper is the copper of biologically active; Moisture copper copper ion releasing; Act on a plurality of sites after copper ion is absorbed, cause nonspecific protein denaturation, and then cause three results: 1, suppress the sprouting of the brood body of fungi and bacterium; 2, suppress the growth of bacterium; 3, stop the growth of mycelia.This series bactericidal agent mainly comprises: copper acetate, network ammonia copper, basic copper sulfate, copper sulphate, Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, Kocide SD, amber adipic acid copper, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper, copper rosinate.
Methoxy acrylic bactericide (claiming Strobilurin abroad) is a kind of bionical bactericide, is a landmark disinfectant use in agriculture after benzimidazole and triazole type, at present, has become one type of very important bactericide.It has fungicidal spectrum very widely, almost all known fungies are all had control efficiency, and using dosage is low.Its mechanism of action all is to suppress mitochondrial respiration through the electronics transmission of blocking between cytochrome b and the c1, can effectively prevent and treat the pathogen series that other bactericide is produced resistance.This series bactericidal agent mainly comprises: Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, ZJ0712, Fluoxastrobin, fluoxastrobin, nitrile Fluoxastrobin, kresoxim-methyl, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
Triazole bactericidal agent, common feature is on its chemical constitution, contains hydroxyl (ketone group), substituted-phenyl and 1,2 on the main chain, 4-triazole group compound.Triazole bactericidal agent is except that to Mastigomycotina, the middle oomycetes non-activity, and the pathogen of Ascomycotina, Basidiomycotina and Deuteromycotina is all had activity, and its mechanism of action is damaged somatic cells film function for to influence the sterols biosynthesis.This series bactericidal agent mainly comprises: penta ring bacterium, bromuconazole, cyproconazole, ether azoles, alkene azoles alcohol, smart alkene azoles alcohol, oxole bacterium, RH-7592, Fluquinconazole, Flusilazole, Flutriafol, own azoles alcohol, acid amides azoles, cycltebuconazole, ring penta azoles bacterium, nitrile bacterium azoles, imidazoles, paclobutrazol, penconazole, Difenoconazole, propiconazole, prothioconazoles, simeconazoles, Tebuconazole, fluorine ether azoles, triazolone, triadimenol, triticonazole, uniconazole P.
Acid amide fungicides is the organic compound that contains amide structure in the chemical constitution.Rust pathogen Uromyces, Puccinia and black rust pathogen Ustilago, Tilletia to the wheat class; And the soil fungis such as Rhizoctonia that on crops such as tomato, eggplant, cucumber, cause root rot, fusarium wilt are effectively, and are effective especially to Basidiomycetes.This series bactericidal agent mainly comprises: M 9834, smart M 9834, benodanil, Boscalid, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, different metsulfovax, third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, fenhexamid, thifluzamide, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil.
Benzimidazole germicide is one type of organic bactericide of parent with the benzimidazole ring that bactericidal activity is arranged, and inhales bactericidal activity in nearly all this compounds all shows.This series bactericidal agent mainly comprises carbendazim, thiophanate methyl etc.
The thiocarbamates bactericide, its main mechanism: COASH is destroyed in (1), thereby influences oxidation of fatty acids; (2) suppressing with copper, iron etc. is the activity of the enzyme of prothetic group.This series bactericidal agent mainly comprises: mancozeb, zineb, Carbatene, Propineb, tmtd, Isoprothiolane.
Substituted beneze-group fungicides contain the organic bactericide of phenyl ring in the chemical constitution, its most of kind has efficiently, the characteristics of low toxicity, wide spectrum.This series bactericidal agent mainly comprises pcnb, tpn, fenaminosulf etc.
Dicarboximide fungicide is one type of broad-spectrum germicide, and spore germination, the mycelial growth of fungi all had inhibitory action, causes thalli morphology to change, and the mycelia top has produced abnormal branch and swelling.This series bactericidal agent mainly comprises iprodione, dimethachlon, procymidone etc.
The imidazoles bactericide is one type of broad-spectrum germicide, and this series bactericidal agent mainly comprises Prochloraz, cyanogen frost azoles, presses down mould azoles, efficiently presses down mould azoles, prochloraz-manganese chloride complex complex compound, fluorine bacterium azoles, pefurazoate etc.
Summary of the invention
The objective of the invention is to overcome the defective of prior art, a kind of bactericidal composition that contains chlorobromide isocyanuric acid is provided.
For addressing the above problem, the technical scheme that the present invention adopted is:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid is characterized in that: it comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-80: 1-80 by bactericide A and the composite former medicine that forms of bactericide B;
Said bactericide A is a chlorobromide isocyanuric acid;
Optional one of which in the bactericide that said bactericide B is following classification: copper agent, methoxy acrylic, triazole type, amide-type, benzimidazole, thiocarbamates, substituted benzene, pyroles, dicarboximide class, phthalimide class, imidazoles, morpholine class, carbamates He oxazole class, and other types.
Say further:
Said copper agent bactericide is an optional one of which in the following bactericide: copper acetate, network ammonia copper, basic copper sulfate, copper sulphate, Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, Kocide SD, amber adipic acid copper, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper, copper rosinate.
Said methoxy acrylic bactericide is an optional one of which in the following bactericide: Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, ZJ0712, Fluoxastrobin, fluoxastrobin, nitrile Fluoxastrobin, kresoxim-methyl, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
Said triazole bactericidal agent is an optional one of which in the following bactericide: penta ring bacterium; Bromuconazole; Cyproconazole; The ether azoles; Alkene azoles alcohol; Smart alkene azoles alcohol; Oxole bacterium; RH-7592; Fluquinconazole; Flusilazole; Flutriafol; Tricyclazole; Own azoles alcohol; The acid amides azoles; Cycltebuconazole; Encircle penta azoles bacterium; Nitrile bacterium azoles; Imidazoles; Paclobutrazol; Bitertanol; Penconazole; Difenoconazole; Propiconazole; Prothioconazoles; Tetraconazole; Simeconazoles; Tebuconazole; Fluorine ether azoles; Triazolone; Triadimenol; Triticonazole; Uniconazole P.
Said acid amide fungicides is an optional one of which in the following bactericide: M 9834, smart M 9834, benodanil, Boscalid, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, different metsulfovax, third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, fenhexamid, thifluzamide, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil.
Said benzimidazole germicide is carbendazim or thiophanate methyl.
Said thiocarbamates bactericide is an optional one of which in the following bactericide: mancozeb, zineb, Carbatene, Propineb, tmtd, Isoprothiolane.
Said substituted beneze-group fungicides are tpn; Said pyroles bactericide is fludioxonil or fenpiclonil; Said dicarboximide fungicide is iprodione, dimethachlon or procymidone; Said phthalimide series bactericidal agent is captan or folpet; Said carbamate fungicide is Propamocarb or the mould prestige of second.
Said imidazoles bactericide is an optional one of which in the following bactericide: Prochloraz, cyanogen frost azoles, press down mould azoles, efficiently press down mould azoles, prochloraz-manganese chloride complex complex compound, fluorine bacterium azoles, pefurazoate;
Said morpholine series bactericidal agent is an optional one of which in the following bactericide: dimethomorph, flumorph, tridemorph, bacterium quinoline, butadiene morpholine;
Suo Shu oxazole series bactericidal agent is optional one of which: oxazole bacterium ketone, SYP-Z048 、 hymexazo, a Wakil in the following bactericide.
Said other series bactericidal agents are Rabcide, Yekuzuo, bromothalonil.
Furtherly, the proportioning of said bactericide A and bactericide B is: 2: 1.
Again furtherly, said bactericide be missible oil, micro emulsion, water and milk, suspending agent (comprising: do outstanding, water is outstanding and oil outstanding), all formulations such as pulvis, soluble liquid, wetting powder, granula, soluble powder, water dispersible granules or suspension emulsion.
Owing to adopted technique scheme, compared with prior art, the present invention adopts bactericide A and forms with bactericide B is composite, has not only enlarged fungicidal spectrum, has also slowed down the pesticide resistance of germ, has significantly lasting synergistic effect.
Below in conjunction with embodiment the present invention is further specified.
Embodiment
A kind of bactericidal composition that contains chlorobromide isocyanuric acid comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-80: 1-80 by bactericide A and the composite former medicine that forms of bactericide B;
Said bactericide A is a chlorobromide isocyanuric acid;
Optional one of which in the bactericide that said bactericide B is following classification: copper agent, methoxy acrylic, triazole type, amide-type, benzimidazole, thiocarbamates, substituted benzene, pyroles, dicarboximide class, phthalimide class, imidazoles, morpholine class, carbamates He oxazole class, and other types.
Said copper agent bactericide is an optional one of which in the following bactericide: copper acetate, network ammonia copper, basic copper sulfate, copper sulphate, Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, Kocide SD, amber adipic acid copper, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper, copper rosinate.
Said methoxy acrylic bactericide is an optional one of which in the following bactericide: Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, ZJ0712, Fluoxastrobin, fluoxastrobin, nitrile Fluoxastrobin, kresoxim-methyl, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
Said triazole bactericidal agent is an optional one of which in the following bactericide: penta ring bacterium; Bromuconazole; Cyproconazole; The ether azoles; Alkene azoles alcohol; Smart alkene azoles alcohol; Oxole bacterium; RH-7592; Fluquinconazole; Flusilazole; Flutriafol; Tricyclazole; Own azoles alcohol; The acid amides azoles; Cycltebuconazole; Encircle penta azoles bacterium; Nitrile bacterium azoles; Imidazoles; Paclobutrazol; Bitertanol; Penconazole; Difenoconazole; Propiconazole; Prothioconazoles; Tetraconazole; Simeconazoles; Tebuconazole; Fluorine ether azoles; Triazolone; Triadimenol; Triticonazole; Uniconazole P.
Said acid amide fungicides is an optional one of which in the following bactericide: M 9834, smart M 9834, benodanil, Boscalid, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, different metsulfovax, third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, fenhexamid, thifluzamide, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil.
Said benzimidazole germicide is carbendazim or thiophanate methyl.
Said thiocarbamates bactericide is an optional one of which in the following bactericide: mancozeb, zineb, Carbatene, Propineb, tmtd, Isoprothiolane.
Said substituted beneze-group fungicides are tpn; Said pyroles bactericide is fludioxonil or fenpiclonil; Said dicarboximide fungicide is iprodione, dimethachlon or procymidone; Said phthalimide series bactericidal agent is captan or folpet; Said carbamate fungicide is Propamocarb or the mould prestige of second.
Said imidazoles bactericide is an optional one of which in the following bactericide: Prochloraz, cyanogen frost azoles, press down mould azoles, efficiently press down mould azoles, prochloraz-manganese chloride complex complex compound, fluorine bacterium azoles, pefurazoate;
Said morpholine series bactericidal agent is an optional one of which in the following bactericide: dimethomorph, flumorph, tridemorph, bacterium quinoline, butadiene morpholine;
Suo Shu oxazole series bactericidal agent is optional one of which: oxazole bacterium ketone, SYP-Z048 、 hymexazo, a Wakil in the following bactericide.
Said other series bactericidal agents are Rabcide, Yekuzuo, bromothalonil.
One of preferred as technique scheme, the proportioning of said bactericide A and bactericide B is: 2: 1.
Embodiment 1:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 2:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 3:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 4:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 5:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 6:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 7:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 8:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 9:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 10:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 11:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 12:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 13:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 14:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 15:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Embodiment 16:
A kind of bactericidal composition that contains chlorobromide isocyanuric acid, each raw material components and consumption are following:
Claims (10)
1. bactericidal composition that contains chlorobromide isocyanuric acid, it is characterized in that: it comprises that wherein, the proportioning of bactericide A and bactericide B is: 1-80: 1-80 by bactericide A and the composite former medicine that forms of bactericide B;
Said bactericide A is a chlorobromide isocyanuric acid;
Optional one of which in the bactericide that said bactericide B is following classification: copper agent, methoxy acrylic, triazole type, amide-type, benzimidazole, thiocarbamates, substituted benzene, pyroles, dicarboximide class, phthalimide class, imidazoles, morpholine class, carbamates He oxazole class, and other types.
2. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said copper agent bactericide is an optional one of which in the following bactericide: copper acetate, network ammonia copper, basic copper sulfate, copper sulphate, Thiodiazole-copper, the mould copper of thiophene, copper 8-hydroxyquinolinate, copper oxychloride, Kocide SD, amber adipic acid copper, copper citrate, kilnitamin copper, copper benzoate, rotten ester acid copper, copper rosinate.
3. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said methoxy acrylic bactericide is an optional one of which in the following bactericide: Enestroburin, alkene oxime amine, azoles bacterium ester, azoles amine bacterium ester, pyraclostrobin, ZJ0712, Fluoxastrobin, fluoxastrobin, nitrile Fluoxastrobin, kresoxim-methyl, pyraclostrobin, oxime bacterium ester, ZEN 90160, SYP-3375.
4. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said triazole bactericidal agent is an optional one of which in the following bactericide: penta ring bacterium, bromuconazole, cyproconazole, ether azoles, alkene azoles alcohol, smart alkene azoles alcohol, oxole bacterium, RH-7592, Fluquinconazole, Flusilazole, Flutriafol, tricyclazole, own azoles alcohol, acid amides azoles, cycltebuconazole, ring penta azoles bacterium, nitrile bacterium azoles, imidazoles, paclobutrazol, bitertanol, penconazole, Difenoconazole, propiconazole, prothioconazoles, tetraconazole, simeconazoles, Tebuconazole, fluorine ether azoles, triazolone, triadimenol, triticonazole, uniconazole P.
5. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said acid amide fungicides is an optional one of which in the following bactericide: M 9834, smart M 9834, benodanil, Boscalid, carboxin, methuroxam, fenhexamid, white urea cyanogen, flutolanil, the spirit of furan pyrazoles, different metsulfovax, third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, fenhexamid, thifluzamide, fenfuram, frost spirit, oxycarboxin, pyrrole metsulfovax, tecloftalam, thifluzamide, tiadinil.
6. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said benzimidazole germicide is carbendazim or thiophanate methyl.
7. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said thiocarbamates bactericide is an optional one of which in the following bactericide: mancozeb, zineb, Carbatene, Propineb, tmtd, Isoprothiolane.
8. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said substituted beneze-group fungicides are tpn; Said pyroles bactericide is fludioxonil or fenpiclonil; Said dicarboximide fungicide is iprodione, dimethachlon or procymidone; Said phthalimide series bactericidal agent is captan or folpet; Said carbamate fungicide is Propamocarb or the mould prestige of second.
9. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that:
Said imidazoles bactericide is an optional one of which in the following bactericide: Prochloraz, cyanogen frost azoles, press down mould azoles, efficiently press down mould azoles, prochloraz-manganese chloride complex complex compound, fluorine bacterium azoles, pefurazoate;
Said morpholine series bactericidal agent is an optional one of which in the following bactericide: dimethomorph, flumorph, tridemorph, bacterium quinoline, butadiene morpholine;
Suo Shu oxazole series bactericidal agent is optional one of which: oxazole bacterium ketone, SYP-Z048 、 hymexazo, a Wakil in the following bactericide.
10. the bactericidal composition that contains chlorobromide isocyanuric acid according to claim 1 is characterized in that: said other series bactericidal agents are Rabcide, Yekuzuo, bromothalonil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103456286A CN102823603A (en) | 2012-09-13 | 2012-09-13 | Sterilization compound containing chloroisobromine cyanuric acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103456286A CN102823603A (en) | 2012-09-13 | 2012-09-13 | Sterilization compound containing chloroisobromine cyanuric acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102823603A true CN102823603A (en) | 2012-12-19 |
Family
ID=47327078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103456286A Pending CN102823603A (en) | 2012-09-13 | 2012-09-13 | Sterilization compound containing chloroisobromine cyanuric acid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102823603A (en) |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103503885A (en) * | 2013-03-26 | 2014-01-15 | 铜陵福成农药有限公司 | Plant bactericide mainly comprising bismerthiazol and application thereof |
| CN103651464A (en) * | 2013-12-26 | 2014-03-26 | 山东康乔生物科技有限公司 | Pyraclostrobine and dichloro-1, 3, 5-triazinetrione-containing sterilization composition |
| CN103814922A (en) * | 2014-02-18 | 2014-05-28 | 中国水稻研究所 | Carbendazim and copper abietate containing bactericidal composition |
| CN103947657A (en) * | 2014-04-11 | 2014-07-30 | 江苏东宝农药化工有限公司 | Bactericide composition with synergic effect and preparation method thereof |
| CN103960246A (en) * | 2014-05-06 | 2014-08-06 | 江苏东宝农药化工有限公司 | Synergistic bactericide composition and preparation method thereof |
| CN104025955A (en) * | 2014-06-27 | 2014-09-10 | 融安县金宜林生物技术有限责任公司 | Sarcandra glabra seedling stage disease and insect pest prevention method |
| CN104336018A (en) * | 2014-10-22 | 2015-02-11 | 江苏东宝农药化工有限公司 | Bactericidal composition using fluxapyroxad and chlorobromoisocyanaria acid as main active ingredients |
| WO2015003666A3 (en) * | 2013-07-08 | 2015-03-12 | 中国中化股份有限公司 | Pesticide composition containing flumorph and organic copper |
| CN104521991A (en) * | 2014-12-18 | 2015-04-22 | 广西田园生化股份有限公司 | Compound composition containing 2-(p-fluorophenyl)-5-methanesulfonyl-1,3,4-oxadiazole and chlorobromoisocyanuric acid and preparation |
| CN104705325A (en) * | 2015-03-16 | 2015-06-17 | 广东中迅农科股份有限公司 | Sterilizing composition containing zhongshengmycin and chlorobromoisocyanaria acid |
| CN105746529A (en) * | 2016-04-01 | 2016-07-13 | 广西南宁益土生物科技有限责任公司 | Sterilization composition containing flutolanil and symclosene |
| CN105746531A (en) * | 2016-04-01 | 2016-07-13 | 广西南宁益土生物科技有限责任公司 | Fungicidal composition containing hexaconazole and trichloroisocyanuric acid |
| CN105766932A (en) * | 2016-04-01 | 2016-07-20 | 广西南宁益土生物科技有限责任公司 | Sterilization composition containing trifloxystrobin and trichloroisocyanuric acid |
| CN105766951A (en) * | 2016-04-01 | 2016-07-20 | 广西南宁益土生物科技有限责任公司 | Sterilizing compound containing thifluzamide and trichloro-isocyanuric acid |
| CN106070270A (en) * | 2016-07-13 | 2016-11-09 | 陈志勤 | A kind of composition pesticide and application thereof |
| CN106614655A (en) * | 2016-12-16 | 2017-05-10 | 张宗斌 | Sterilization composition for preventing and curing rice blast |
| CN106810361A (en) * | 2017-01-17 | 2017-06-09 | 张学杰 | A kind of water-soluble fertilizer for preventing and treating wheat scab |
| CN106912320A (en) * | 2017-05-09 | 2017-07-04 | 中科天华生物科技有限公司 | A kind of culture medium for paper mulberry nursery and preparation method thereof |
| WO2018006463A1 (en) * | 2016-07-07 | 2018-01-11 | 江苏辉丰农化股份有限公司 | Fungicidal composition |
| CN107743961A (en) * | 2017-11-28 | 2018-03-02 | 广西南宁途御科技有限公司 | A kind of complex composition and preparation of the lactams of ketoxime containing isolonglifolene and chlorobromide isocyanuric acid |
| CN110122496A (en) * | 2019-06-19 | 2019-08-16 | 中国农业科学院植物保护研究所 | A kind of pharmaceutical composition and its application containing sodium dichloro cyanurate and copper 8-hydroxyquinolinate |
| CN110521728A (en) * | 2019-09-20 | 2019-12-03 | 漯河市农业科学院 | A kind of microbicide compositions for wheat powdery mildew prevention and treatment |
| CN110741869A (en) * | 2019-11-29 | 2020-02-04 | 贵州黎源上品农业科技开发有限公司 | Method for improving fruit setting rate and yield of Bufna |
| CN111213659A (en) * | 2020-03-29 | 2020-06-02 | 邢宇俊 | Bactericidal composition containing metconazole and chlorobromoisocyanuric acid |
| CN112369325A (en) * | 2020-10-21 | 2021-02-19 | 甘肃亚盛农业研究院有限公司 | Safe, low-toxicity and high-efficiency sterilization method for plant explants |
| CN112715562A (en) * | 2021-01-08 | 2021-04-30 | 黑龙江巨卓作物科学有限公司 | Bactericidal composition containing chlorobromoisocyanuric acid and tricyclazole |
| CN116035012A (en) * | 2023-01-09 | 2023-05-02 | 河南科技学院 | Sterilization composition containing bromoisocyanuric acid and fluxapyroxad hydroxylamine |
-
2012
- 2012-09-13 CN CN2012103456286A patent/CN102823603A/en active Pending
Non-Patent Citations (1)
| Title |
|---|
| 刘安敏等: "防治水稻细菌性基腐病药剂筛选试验", 《农药》 * |
Cited By (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103503885B (en) * | 2013-03-26 | 2015-09-30 | 铜陵福成农药有限公司 | A kind of take Yekuzuo as bactericide and the application thereof of main component |
| CN103503885A (en) * | 2013-03-26 | 2014-01-15 | 铜陵福成农药有限公司 | Plant bactericide mainly comprising bismerthiazol and application thereof |
| WO2015003666A3 (en) * | 2013-07-08 | 2015-03-12 | 中国中化股份有限公司 | Pesticide composition containing flumorph and organic copper |
| CN103651464A (en) * | 2013-12-26 | 2014-03-26 | 山东康乔生物科技有限公司 | Pyraclostrobine and dichloro-1, 3, 5-triazinetrione-containing sterilization composition |
| CN103651464B (en) * | 2013-12-26 | 2015-12-30 | 山东康乔生物科技有限公司 | A kind of bactericidal composition containing pyraclostrobin and dichlord isocyanurice acid |
| CN103814922A (en) * | 2014-02-18 | 2014-05-28 | 中国水稻研究所 | Carbendazim and copper abietate containing bactericidal composition |
| CN103814922B (en) * | 2014-02-18 | 2015-09-30 | 中国水稻研究所 | A kind of bactericidal composition containing carbendazim and copper rosinate |
| CN103947657A (en) * | 2014-04-11 | 2014-07-30 | 江苏东宝农药化工有限公司 | Bactericide composition with synergic effect and preparation method thereof |
| CN103960246A (en) * | 2014-05-06 | 2014-08-06 | 江苏东宝农药化工有限公司 | Synergistic bactericide composition and preparation method thereof |
| CN104025955A (en) * | 2014-06-27 | 2014-09-10 | 融安县金宜林生物技术有限责任公司 | Sarcandra glabra seedling stage disease and insect pest prevention method |
| CN104025955B (en) * | 2014-06-27 | 2016-01-13 | 融安县金宜林生物技术有限责任公司 | The prevention and controls of Chloranthus glaber seedling stage diseases and pests |
| CN104336018A (en) * | 2014-10-22 | 2015-02-11 | 江苏东宝农药化工有限公司 | Bactericidal composition using fluxapyroxad and chlorobromoisocyanaria acid as main active ingredients |
| CN104521991A (en) * | 2014-12-18 | 2015-04-22 | 广西田园生化股份有限公司 | Compound composition containing 2-(p-fluorophenyl)-5-methanesulfonyl-1,3,4-oxadiazole and chlorobromoisocyanuric acid and preparation |
| CN104521991B (en) * | 2014-12-18 | 2017-01-04 | 广西田园生化股份有限公司 | A kind of containing methylsulfonyl bacterium azoles and the complex composition of chlorobromide isocyanuric acid and preparation |
| CN104705325A (en) * | 2015-03-16 | 2015-06-17 | 广东中迅农科股份有限公司 | Sterilizing composition containing zhongshengmycin and chlorobromoisocyanaria acid |
| CN104705325B (en) * | 2015-03-16 | 2018-02-16 | 广东中迅农科股份有限公司 | A kind of bactericidal composition containing Zhongshengmycin and chlorobromide isocyanuric acid |
| CN105766932B (en) * | 2016-04-01 | 2018-05-18 | 台州贝蕾丝电子商务有限公司 | A kind of bactericidal composition of containing trifloxystrobin and sym-closene |
| CN105746529B (en) * | 2016-04-01 | 2018-06-22 | 南宁市君辉农业科技发展有限责任公司 | Bactericidal composition containing flutolanil and trichloroisocyanuric acid |
| CN105766932A (en) * | 2016-04-01 | 2016-07-20 | 广西南宁益土生物科技有限责任公司 | Sterilization composition containing trifloxystrobin and trichloroisocyanuric acid |
| CN105766951A (en) * | 2016-04-01 | 2016-07-20 | 广西南宁益土生物科技有限责任公司 | Sterilizing compound containing thifluzamide and trichloro-isocyanuric acid |
| CN105746531A (en) * | 2016-04-01 | 2016-07-13 | 广西南宁益土生物科技有限责任公司 | Fungicidal composition containing hexaconazole and trichloroisocyanuric acid |
| CN105746531B (en) * | 2016-04-01 | 2018-10-19 | 泉州市梅鑫机械配件有限公司 | A kind of bactericidal composition containing hexaconazole and sym-closene |
| CN105766951B (en) * | 2016-04-01 | 2018-05-18 | 台州贝蕾丝电子商务有限公司 | A kind of bactericidal composition containing thifluzamide and sym-closene |
| CN105746529A (en) * | 2016-04-01 | 2016-07-13 | 广西南宁益土生物科技有限责任公司 | Sterilization composition containing flutolanil and symclosene |
| WO2018006463A1 (en) * | 2016-07-07 | 2018-01-11 | 江苏辉丰农化股份有限公司 | Fungicidal composition |
| CN106070270A (en) * | 2016-07-13 | 2016-11-09 | 陈志勤 | A kind of composition pesticide and application thereof |
| CN106614655A (en) * | 2016-12-16 | 2017-05-10 | 张宗斌 | Sterilization composition for preventing and curing rice blast |
| CN106810361A (en) * | 2017-01-17 | 2017-06-09 | 张学杰 | A kind of water-soluble fertilizer for preventing and treating wheat scab |
| CN106912320A (en) * | 2017-05-09 | 2017-07-04 | 中科天华生物科技有限公司 | A kind of culture medium for paper mulberry nursery and preparation method thereof |
| CN107743961A (en) * | 2017-11-28 | 2018-03-02 | 广西南宁途御科技有限公司 | A kind of complex composition and preparation of the lactams of ketoxime containing isolonglifolene and chlorobromide isocyanuric acid |
| CN110122496A (en) * | 2019-06-19 | 2019-08-16 | 中国农业科学院植物保护研究所 | A kind of pharmaceutical composition and its application containing sodium dichloro cyanurate and copper 8-hydroxyquinolinate |
| CN110122496B (en) * | 2019-06-19 | 2020-10-13 | 中国农业科学院植物保护研究所 | Pharmaceutical composition containing sodium dichloroisocyanurate and oxine-copper and application thereof |
| CN110521728A (en) * | 2019-09-20 | 2019-12-03 | 漯河市农业科学院 | A kind of microbicide compositions for wheat powdery mildew prevention and treatment |
| CN110741869A (en) * | 2019-11-29 | 2020-02-04 | 贵州黎源上品农业科技开发有限公司 | Method for improving fruit setting rate and yield of Bufna |
| CN111213659A (en) * | 2020-03-29 | 2020-06-02 | 邢宇俊 | Bactericidal composition containing metconazole and chlorobromoisocyanuric acid |
| CN112369325A (en) * | 2020-10-21 | 2021-02-19 | 甘肃亚盛农业研究院有限公司 | Safe, low-toxicity and high-efficiency sterilization method for plant explants |
| CN112715562A (en) * | 2021-01-08 | 2021-04-30 | 黑龙江巨卓作物科学有限公司 | Bactericidal composition containing chlorobromoisocyanuric acid and tricyclazole |
| CN116035012A (en) * | 2023-01-09 | 2023-05-02 | 河南科技学院 | Sterilization composition containing bromoisocyanuric acid and fluxapyroxad hydroxylamine |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102823603A (en) | Sterilization compound containing chloroisobromine cyanuric acid | |
| CN103918677A (en) | Thifluzamide-containing sterilization composition | |
| CN103918691A (en) | Imazalil-containing sterilization composition | |
| CN103371184A (en) | Fungicidal composition containing prochloraz manganese complex | |
| CN103371149A (en) | Compounded synergia sterilizing composite | |
| CN103004819A (en) | Fluopicolide-containing bactericide composition | |
| CN108112592A (en) | A kind of bactericidal composition containing bronopol | |
| CN105010357B (en) | Bactericidal composition and its application | |
| CN117617266A (en) | Sterilization composition containing bacillus bailii TCS001 and boscalid and application thereof | |
| CN108812674A (en) | A kind of bactericidal composition of fluorine-containing ether bacterium amide and methoxy acrylic | |
| CN101961032A (en) | Blending preparation of chemical pesticide and biological pesticide and application thereof | |
| CN101755808B (en) | Fungicidal composition containing hexaconazole and prochloraz manganese | |
| CN104206387B (en) | A kind of synergetic pesticide composition of fluorine-containing azoles bacterium aniline | |
| CN103004802A (en) | Biocidal composition and its application | |
| CN102845436A (en) | Bactericide composition containing fluoro-ether bacterium amide and dimethomorph | |
| CN104137836B (en) | A kind of bactericidal composition of fluorine-containing azoles bacterium aniline and methoxy acrylic | |
| CN101720767B (en) | Bactericidal composition containing dithianone and prochloraz manganese | |
| CN105076141A (en) | Composition containing coumoxystrobin and related bactericide | |
| CN105851059A (en) | Germicidal composition containing bromothalonil and copper preparation | |
| CN104412990B (en) | A kind of bactericidal composition of fluorine-containing ether bacterium amide | |
| CN108244128A (en) | A kind of bactericidal composition containing fenbendazole and copper agent | |
| CN105010364B (en) | A kind of bactericidal composition containing thiabendazole and thiafuramide and its application | |
| CN108112594A (en) | A kind of bactericidal composition containing bronopol | |
| CN103210937A (en) | Composition comprising coumoxystrobin and other bactericides | |
| Hong et al. | Co-delivery strategy of fungicide and plant immune inducer based on ZnAl layered double hydroxide for sustainable control of rice sheath blight |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20121219 |