CN102819681B - Method of predicting homochromatism formula of brocade cotton fabric by using computer color matching system - Google Patents
Method of predicting homochromatism formula of brocade cotton fabric by using computer color matching system Download PDFInfo
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Abstract
本发明公开了一种采用电脑配色系统预测锦棉织物同色性配方的方法,包括如下步骤:1)组成混合织物;2)建立棉的基础数据库一;3)建立锦纶的基础数据库二;4)采用基础数据库一配色打样;5)给出修色配方继续打样;6)直到色差满足要求,获得活性染料的染色配方和纯锦纶织物沾色色样;7)获得酸性染料染色配方一;8)采用基础数据库二配色打样,将所得色样输入电脑给出修色配方继续打样;9)直到色差满足要求,获得酸性染料染色配方二,减去配方一可获得酸性染料染色配方三;10)活性染料的染色配方和酸性染料染色配方三即为锦棉织物的同色性配方。本发明更符合锦棉织物染色的实际情况,配色效果良好。The invention discloses a method for predicting the same-color formula of nylon and cotton fabrics by using a computer color matching system, comprising the following steps: 1) forming a mixed fabric; 2) establishing a basic database of cotton; Use the basic database for color matching proofing; 5) give the color correction formula and continue proofing; 6) until the color difference meets the requirements, obtain the dyeing formula of reactive dyes and the staining color sample of pure nylon fabric; 7) obtain acid dye dyeing formula 1; 8) use Basic database two color matching proofing, input the obtained color sample into the computer to give the color correction formula and continue proofing; 9) Until the color difference meets the requirements, obtain the acid dye dyeing formula 2, subtract formula 1 to obtain the acid dye dyeing formula 3; 10) Reactive dyes The dyeing formula and acid dye dyeing formula three are the same color formula of nylon cotton fabric. The invention is more in line with the actual situation of nylon-cotton fabric dyeing, and the color matching effect is good.
Description
技术领域 technical field
本发明涉及一种采用电脑配色系统预测锦棉织物同色性配方的方法。The invention relates to a method for predicting the same-color formula of nylon-cotton fabrics by using a computer color matching system.
背景技术 Background technique
随着我国纺织产业的升级,为了改善国内印染业的生产条件,便于国际贸易的交流,印染企业相继引进测色配色仪器。与人工配色相比,电脑配色具有节省染化料用量,缩短生产周期,提高生产效率的优点。在实际应用过程中,由于对测配色仪器及配色理论的不完全了解,配色软件中的配色功能并未得到充分的利用。With the upgrading of my country's textile industry, in order to improve the production conditions of the domestic printing and dyeing industry and facilitate international trade exchanges, printing and dyeing enterprises have successively introduced color measuring and matching instruments. Compared with manual color matching, computer color matching has the advantages of saving the amount of dyes and chemicals, shortening the production cycle and improving production efficiency. In the actual application process, due to the incomplete understanding of the color matching instrument and color matching theory, the color matching function in the color matching software has not been fully utilized.
同色性是指将两种纤维染成相近的色相或色调,而且表观色深或颜色浓淡相近,颜色鲜艳度也接近。同色染色是双组分纤维纺织品采用最多的一种染色方法。双组分织物的同色性染色是当前染色技术中的一个难题。产品重现性差,仿色困难,回修率高,引起劳动力成本与染化料、能源的浪费。平目前,我国的双组分纤维织物的染整加工多数仍停留在经验加工水上,染色产品质量受诸多主观与客观因素的影响,急需建立多组分纤维特别是常规双组分纤维织物的同色性测配色方法,以减少无谓的劳动力、染化料与能源的浪费,提高生产效率。The same color means that two fibers are dyed into similar hue or tone, and the apparent color depth or color shade is similar, and the color brightness is also close. Same-color dyeing is the most widely used dyeing method for bicomponent fiber textiles. The homochromatic dyeing of two-component fabrics is a difficult problem in the current dyeing technology. Product reproducibility is poor, color dithering is difficult, and the repair rate is high, causing labor costs, dyeing materials, and energy waste. At present, most of the dyeing and finishing of bicomponent fiber fabrics in my country still stays on the level of empirical processing, and the quality of dyed products is affected by many subjective and objective factors. The color matching method can be used to reduce unnecessary labor, waste of dyeing materials and energy, and improve production efficiency.
对于锦棉织物同色染色,一般是将锦纶和棉两种纤维染色,通过配色获得两种纤维各自的配方。由于配色过程中,未考虑染棉的活性染料对锦纶的沾色和染锦纶的酸性染料对棉的沾色,需要有经验的技术人员对配方进行再调整才能得到同色性较好的配方。For the same color dyeing of nylon and cotton fabrics, generally two fibers of nylon and cotton are dyed, and the respective formulas of the two fibers are obtained through color matching. In the process of color matching, the staining of nylon by reactive dyes dyed cotton and the staining of cotton by acid dyes dyed nylon are not taken into account. Experienced technicians need to readjust the formula to obtain a formula with better color matching.
发明内容 Contents of the invention
本发明的目的在于提供一种采用电脑配色系统预测锦棉织物同色性配方的方法,本发明充分考虑锦棉织物染色过程中,染棉的活性染料对锦纶的沾色和染锦纶的酸性染料对棉的沾色,获得的配方对锦棉织物的同色性较好。The object of the present invention is to provide a kind of method that adopts computer color matching system to predict the same color formula of nylon-cotton fabric, the present invention fully considers in the dyeing process of nylon-cotton fabric, the staining of the reactive dye of dyed cotton to nylon and the effect of the acid dye of dyed nylon on nylon-cotton fabric. For staining of cotton, the obtained formula has better same-color property to nylon-cotton fabric.
目前,测配色仪器已广泛应用于各类单组分纤维、织物和皮革等的配色打样。电脑测配色应用首先需要建立基础数据库,一般将各种染料浓度由浅到深分成几个浓度档次依次对织物染色,然后测试色样输入电脑,根据来样由基础数据计算出配方进行染色,最后进行配方修正直到色样符合客户要求。At present, color matching instruments have been widely used in color matching proofing of various single-component fibers, fabrics and leathers. The application of computer color matching first needs to establish a basic database. Generally, the concentration of various dyes is divided into several concentration levels from light to dark to dye the fabric in sequence, and then the test color sample is input into the computer, and the formula is calculated from the basic data according to the sample. Formula correction until the color sample meets customer requirements.
根据电脑配色的基本原理,在一定染色浓度范围内,纤维上染料上染量与染浴中使用的染料浓度呈一定的线性关系。According to the basic principle of computer color matching, within a certain range of dyeing concentration, the amount of dye on the fiber has a certain linear relationship with the concentration of dye used in the dye bath.
K/S=kc (1)K/S=kc (1)
其中K表示被测织物的吸收系数;S表示被测织物的散射系数(通常,不需要K、S的具体数值,仅计算K/S的比值,因此称作“K/S”值,表示被测织物的表观色深度);c表示被测织物上的染料浓度,k表示被测织物上染单位浓度的染料所获得的K/S值。Among them, K represents the absorption coefficient of the tested fabric; S represents the scattering coefficient of the measured fabric (usually, the specific values of K and S are not required, and only the ratio of K/S is calculated, so it is called "K/S" value, which means the value of the tested fabric The apparent color depth of the tested fabric); c indicates the dye concentration on the tested fabric, and k indicates the K/S value obtained by dyeing the unit concentration of the tested fabric.
同理,对于多个染料配色(K/S)m关系式为:Similarly, for multiple dye color matching (K/S) m relational formula is:
式中:(K/S)m表示目标色织物的表观色深;In the formula: (K/S) m represents the apparent color depth of the target colored fabric;
(K/S)0表示空白织物的表观色深;(K/S) 0 represents the apparent color depth of the blank fabric;
ki表示空白织物上各染料单位浓度的K/S值;k i represents the K/S value of each dye unit concentration on the blank fabric;
ci表示各染料的浓度。c i represent the concentration of each dye.
(K/S)m和(K/S)0可以由测色系统测试得到,而ki必须通过制作基础数据曲线得到,确定了一个染料的基础数据曲线,也就确定了该染料在一定染色浓度范围内单位浓度的K/S值(即ki)。根据ki可以计算出配方中各个染料的用量。(K/S) m and (K/S) 0 can be obtained by the color measurement system, and ki must be obtained by making the basic data curve, and the basic data curve of a dye is determined, which also determines the color of the dye in a certain dyeing The K/S value of unit concentration within the concentration range (ie k i ). According to ki, the dosage of each dye in the formula can be calculated.
建立酸性染料对锦纶织物的电脑测配色基础数据库和活性染料对棉织物的电脑测配色基础数据库,调用相应的基础数据库对锦纶和棉进行配色、染色和修色,可以分别获得与目标色一致的酸性染料染色配方和活性染料染色配方。但在染色过程中,酸性染料会对棉沾色,而活性染料会对锦纶沾色,所以获得的染色配方对锦棉织物染色后,双组分织物的同色性会存在一定的问题。Establish the basic database of computer color matching of acid dyes on nylon fabrics and the basic database of computer color matching of reactive dyes on cotton fabrics, and call the corresponding basic databases for color matching, dyeing and color correction of nylon and cotton, and can obtain the same color as the target color respectively. Acid dye dyeing formula and reactive dye dyeing formula. But in the dyeing process, acid dyes can stain cotton, and reactive dyes can stain nylon, so after the obtained dyeing formula dyes nylon and cotton fabrics, there will be certain problems in the same color of the two-component fabrics.
以活性/酸性染料染棉/锦纶织物而言,棉织物上的表观色深值由三部分组成,即空白棉织物的表观色深值、活性染料上染棉织物的表观色深值和酸性染料对棉织物沾色的表观色深值。而锦纶织物上的表观色深值也由三部分组成,即空白锦纶织物的表观色深值、酸性染料上染涤纶织物的表观色深值和活性染料对涤纶织物沾色的表观色深值,关系式如下:For cotton/nylon fabrics dyed with reactive/acid dyes, the apparent color depth value on cotton fabrics consists of three parts, namely, the apparent color depth value of blank cotton fabrics and the apparent color depth value of cotton fabrics dyed with reactive dyes The apparent color depth value of cotton fabric stained with acid dyes. The apparent color depth value on nylon fabric is also composed of three parts, that is, the apparent color depth value of blank nylon fabric, the apparent color depth value of polyester fabric dyed with acid dye, and the apparent color depth value of polyester fabric stained by reactive dye. Color depth value, the relationship is as follows:
(K/S)棉=(K/S)棉0+(K/S)活性染料+(K/S)酸性染料沾色 (3)(K/S) cotton = (K/S) cotton 0 + (K/S) reactive dye + (K/S) acid dye staining (3)
(K/S)锦纶=(K/S)锦纶0+(K/S)酸性染料+(K/S)活性染料沾色 (4)(K/S) nylon = (K/S) nylon 0 + (K/S) acid dye + (K/S) reactive dye staining (4)
要使锦棉双组份织物在染色后获得同一色泽,则To make nylon-cotton two-component fabrics obtain the same color after dyeing, then
(K/S)棉=(K/S)锦纶 (5)(K/S) Cotton = (K/S) Nylon (5)
式中:In the formula:
(K/S)棉、(K/S)锦纶分别表示目标色样的表观色深;(K/S) Cotton and (K/S) Nylon respectively indicate the apparent color depth of the target color sample;
(K/S)棉0、(K/S)锦纶0分别表示空白棉织物和锦纶织物的表观色深值;(K/S) cotton 0 , (K/S) nylon 0 represent the apparent color depth value of blank cotton fabric and nylon fabric respectively;
(K/S)活性染料表示活性染料上染棉织物的表观色深值;(K/S) Reactive dyes represent the apparent color depth of cotton fabrics dyed with reactive dyes;
(K/S)酸性染料表示酸性染料上染锦纶织物的表观色深值;(K/S) acid dye indicates the apparent color depth of nylon fabric dyed with acid dye;
(K/S)酸性染料沾色表示酸性染料对棉织物沾色的表观色深值;(K/S) Acid dye staining indicates the apparent color depth value of acid dye staining on cotton fabric;
(K/S)活性染料沾色表示活性染料对锦纶织物沾色的表观色深值。(K/S) Reactive dye staining indicates the apparent color depth value of reactive dye staining on nylon fabric.
经过实验发现,酸性染料对棉的沾色甚微,但是活性染料对锦纶的沾色比较明显,即(K/S)活性染料>>(K/S)酸性染料沾色而(K/S)酸性染料>(K/S)活性染料沾色。After experiments, it was found that the staining of acid dyes on cotton was slight, but the staining of nylon by reactive dyes was more obvious, that is, (K/S) reactive dyes >> (K/S) acid dyes and (K/S) Acid dye > (K/S) reactive dye staining .
则公式(3)可简化为:Then formula (3) can be simplified as:
(K/S)棉=(K/S)棉0+(K/S)活性染料(6)(K/S) cotton = (K/S) cotton 0 + (K/S) reactive dye (6)
公式(5)可转化为:Formula (5) can be transformed into:
(K/S)棉0+(K/S)活性染料=(K/S)锦纶0+(K/S)酸性染料+(K/S)活性染料沾色(7)(K/S) cotton 0 + (K/S) reactive dye = (K/S) nylon 0 + (K/S) acid dye + (K/S) reactive dye staining (7)
如果将(K/S)活性染料沾色设为目标色样,采用酸性染料对锦纶织物的电脑测配色基础数据库进行配色和修色,可以获得一组酸性染料配方,即这组酸性染料染色配方对锦纶织物的染色效果与活性染料对锦纶织物的沾色效果相同。If (K/S) reactive dye staining is set as the target color sample, and acid dyes are used to match and repair the computer-based color matching database of nylon fabrics, a set of acid dye formulas can be obtained, that is, this set of acid dye dyeing formulas The dyeing effect on nylon fabric is the same as that of reactive dyes on nylon fabric.
为了达到上述目的,本发明的技术方案是:In order to achieve the above object, technical scheme of the present invention is:
一种采用电脑配色系统预测锦棉织物同色性配方的方法,包括如下步骤:A kind of method adopting computer color matching system to predict nylon-cotton fabric homochromatic formula, comprises the steps:
1)以纯棉和纯锦纶织物按照锦棉织物中的锦棉比例,组成混合织物;1) Use pure cotton and pure nylon fabrics to form mixed fabrics according to the proportion of nylon and cotton in nylon and cotton fabrics;
2)对步骤1)所述的混合织物采用不同浓度的活性染料染色建立锦棉织物中棉的基础数据库(简称基础数据库一);2) Dyeing the mixed fabric described in step 1) with different concentrations of reactive dyes to establish a basic database of cotton in nylon-cotton fabrics (referred to as basic database 1);
3)对步骤1)所述的混合织物采用不同浓度的酸性染料染色建立锦棉织物中锦纶的基础数据库(简称基础数据库二);3) Dyeing the mixed fabric described in step 1) with different concentrations of acid dyes to establish a basic database of nylon in nylon-cotton fabrics (referred to as basic database 2);
4)根据目标色,采用步骤2)所述的基础数据库一对空白的混合织物进行电脑配色,根据配方进行打样;4) According to the target color, use the basic database described in step 2) to carry out computer color matching on a pair of blank mixed fabrics, and carry out proofing according to the formula;
5)将步骤4)打样所得纯棉织物色样输入电脑,由电脑给出修色配方,根据修色配方继续打样;5) Input the pure cotton fabric color sample obtained in step 4) into the computer, and the computer will give the color correction formula, and continue proofing according to the color correction formula;
6)重复步骤5),直到纯棉织物色样与目标色的色差满足要求,获得活性染料的染色配方和一块采用该染色配方的纯锦纶织物沾色色样。6) Repeat step 5) until the color difference between the pure cotton fabric color sample and the target color meets the requirements, and obtain the dyeing formula of reactive dyes and a stained color sample of pure nylon fabric using the dyeing formula.
7)根据步骤6)所述的纯锦纶织物沾色色样,采用基础数据库二对空白的混合织物进行电脑配色,获得酸性染料染色配方一;7) According to the staining color sample of pure nylon fabric described in step 6), computer color matching is carried out on the blank mixed fabric by using the basic database 2 to obtain the acid dye dyeing formula 1;
8)根据目标色,采用基础数据库二对空白的混合织物进行电脑配色,根据配方进行打样,将打样所得纯锦纶织物色样输入电脑,由电脑给出修色配方,根据修色配方继续打样;8) According to the target color, use the basic database 2 to carry out computer color matching on the blank mixed fabric, and carry out proofing according to the formula, input the color sample of pure nylon fabric obtained from the proofing into the computer, and the computer will give the color correction formula, and continue proofing according to the color correction formula;
9)重复步骤8),直到纯锦纶织物色样与目标色的色差满足要求,获得酸性染料染色配方二,将酸性染料染色配方二减去酸性染料染色配方一获得酸性染料染色配方三;9) Repeat step 8) until the color difference between the pure nylon fabric color sample and the target color meets the requirements, and obtain the acid dye dyeing formula 2, and subtract the acid dye dyeing formula 1 from the acid dye dyeing formula 2 to obtain the acid dye dyeing formula 3;
10)将步骤6)所述的活性染料的染色配方和步骤9)所述的酸性染料染色配方三混合即为锦棉织物的同色性配方。10) Mix the dyeing formula of reactive dyes described in step 6) and the dyeing formula of acid dyes described in step 9) to obtain the same-color formula for nylon-cotton fabrics.
所述的步骤1)中混合织物为两块织物,一块纯锦纶织物和一块纯棉织物。The mixed fabric in step 1) is two pieces of fabric, one piece of pure nylon fabric and one piece of pure cotton fabric.
所述的步骤2)中相对应的基础数据库一是根据目标色需要,选择相应的活性染料,这些染料分别对混合织物按不同浓度梯度染色后得到的纯棉织物色样所制得的基础色样,将这些基础色样采用测配色仪器测试后输入电脑后所建立的基础数据库。The corresponding basic database in the step 2) is to select the corresponding reactive dyes according to the needs of the target color. After testing these basic color samples with a color matching instrument, input them into the basic database established by the computer.
所述的步骤3)中相对应的基础数据库二是根据目标色需要,选择相应的酸性染料,这些染料分别对混合织物按不同浓度梯度染色后得到的纯锦纶织物色样所制得的基础色样,将这些基础色样采用测配色仪器测试后输入电脑后所建立的基础数据库。The corresponding basic database in step 3) The second is to select the corresponding acid dyes according to the needs of the target color. These dyes are used to dye the mixed fabrics according to different concentration gradients. After testing these basic color samples with a color matching instrument, input them into the basic database established by the computer.
所述的步骤6)和步骤9)中配方的染色织物与目标色样之间的色差为1以下时为满足要求。The requirement is met when the color difference between the dyed fabric of the recipe in step 6) and step 9) and the target color sample is less than 1.
本发明的有益效果是:第一本发明建立电脑测配色基础数据库的方法与传统的双组分织物电脑套色方法不同,如果按照传统的双组分织物电脑套色方法,基础数据库由单组分织物染色后制得的基础色样组成,各组分织物的配方由该基础数据库确定,与实际的染色情况差异较大,几乎无法实现双组分织物的同色,而由本发明的电脑套色方法,充分考虑了锦棉织物染色中的沾色问题,所获得的各染料单位浓度的K/S值(即ki)由混合织物染色制得的基础数据曲线获得,更符合锦棉织物染色的实际情况,配色效果良好。第二本发明充分考虑了染色中的沾色问题,根据酸性染料对棉的沾色甚微,但活性染料对锦纶的沾色比较明显的情况,采用先对棉织物配色再对锦纶织物配色的方法,使配色误差大幅度地降低,第三本发明更符合目前市场对织物色泽同色性快速响应的要求,是提高产品档次,接轨国际市场,适应新时期准确、快速、优质要求的必然之路。The beneficial effects of the present invention are: the first method of the present invention to establish the computer color matching basic database is different from the traditional two-component fabric computer color registration method, if according to the traditional two-component fabric computer color registration method, the basic database consists of single-component fabric The composition of the basic color sample obtained after dyeing, the formula of each component fabric is determined by the basic database, which is quite different from the actual dyeing situation, and it is almost impossible to realize the same color of the two-component fabric, but by the computer color registration method of the present invention, fully Considering the staining problem in the dyeing of nylon-cotton fabrics, the obtained K/S value of each dye unit concentration (ie ki ) is obtained from the basic data curve obtained by dyeing mixed fabrics, which is more in line with the actual situation of nylon-cotton fabric dyeing , the color matching effect is good. The second present invention has fully considered the staining problem in the dyeing, according to the staining of acid dyestuff to cotton is very little, but the situation that reactive dyestuff is more obvious to the staining of nylon, adopts the method of first matching the color of cotton fabric and then matching the color of nylon fabric The third method is to greatly reduce the color matching error. The third invention is more in line with the current market requirements for rapid response to the same color of fabrics. It is an inevitable way to improve product grades, connect with the international market, and adapt to the requirements of accuracy, speed, and high quality in the new era. .
具体实施方式 Detailed ways
下面结合具体实施例,进一步阐述本发明。应理解,这些实施例仅用于说明本发明而不用于限制本发明的范围。此外应理解,在阅读了本发明讲授的内容之后,本领域技术人员可以对本发明作各种改动或修改,这些等价形式同样落于本申请所附权利要求书所限定的范围。实Below in conjunction with specific embodiment, further illustrate the present invention. It should be understood that these examples are only used to illustrate the present invention and are not intended to limit the scope of the present invention. In addition, it should be understood that after reading the content taught by the present invention, those skilled in the art may make various changes or modifications to the present invention, and these equivalent forms also fall within the scope defined by the appended claims of the present application. Reality
实施例1Example 1
1)对锦纶和棉的重量比为3:7的锦棉平纹交织布染色,首先以重量比为3:7的一块纯锦纶平纹织物和一块纯棉平纹织物组成的混合织物模拟该锦棉平纹交织布。1) To dye nylon-cotton plain weave fabric with a weight ratio of nylon and cotton of 3:7, first simulate the nylon-cotton plain weave with a mixed fabric composed of a piece of pure nylon plain weave fabric and a piece of pure cotton plain weave fabric with a weight ratio of 3:7 Interwoven cloth.
下述的步骤2)、步骤3)中基础数据库中的基础色样为各类染料对混合织物分不同的浓度梯度染色后所得到棉组分和锦纶组分的表观深度,即:The basic color samples in the basic database in the following steps 2) and 3) are the apparent depths of the cotton component and the nylon component obtained by dyeing the mixed fabric with different concentration gradients of various dyes, namely:
式中:K表示被测织物的吸收系数;S表示被测织物的散射系数;(K/S)m表示目标色织物的表观色深;(K/S)t表示未染色织物的表观色深;ci〞表示各染料上染织物上的染料浓度;kiˊ表示织物上各染料单位浓度的K/S值。其中(K/S)m(表示目标色织物的表观色深)和(K/S)t(表示未染色织物的表观色深)可以由测色系统测试得到,而ki必须通过制作基础数据曲线得到,也就是说将未染色织物和染色样采用测配色仪器测试后输入电脑,建立基础数据库。根据线性关系K/S=kc来制作各染料相对于本实施例的混合织物中棉组分和锦纶组分各自的基础数据曲线,从而可以确定该染料在一定染色浓度范围内单位浓度的K/S值(即ki)。根据ki可以计算出配方中各个染料的用量,如表1所示。In the formula: K represents the absorption coefficient of the tested fabric; S represents the scattering coefficient of the measured fabric; (K/S) m represents the apparent color depth of the target colored fabric; (K/S) t represents the apparent color depth of the undyed fabric Color depth ; c i " represents the dye concentration on the dyed fabric of each dye; ) and (K/S) t (representing the apparent color depth of the undyed fabric) can be obtained by the color measurement system, and ki must be obtained by making the basic data curve, that is to say, the undyed fabric and the dyed sample are measured Input computer after the color matching instrument test, set up basic database.Make each dyestuff relative to the basic data curve of cotton component and polyamide fiber component in the mixed fabric of the present embodiment according to linear relationship K/S=kc, thereby can determine this dyestuff The K/S value of unit concentration (ie ki ) within a certain range of dyeing concentration. According to ki , the dosage of each dye in the formula can be calculated, as shown in Table 1.
2)对步骤1)所述的混合织物采用不同浓度的活性染料染色建立锦棉织物中棉的基础数据库一;本实施例采用活性红3BS、活性黄3RF、活性黄3RS、活性藏青RGB、活性蓝M-2GE对复合织物中的棉组分染色,染料对纯棉织物重的百分率分别为0.3%、0.6%、0.9%、1.2%、1.5%、2%、2.5%、3%、4%;匀染剂1g/L,元明粉、纯碱用量由使用染料的总浓度确定,不同染料浓度下元明粉和纯碱的用量如表2所示。2) The mixed fabric described in step 1) is dyed with different concentrations of reactive dyes to establish the basic database 1 of cotton in nylon fabric; this embodiment uses reactive red 3BS, reactive yellow 3RF, reactive yellow 3RS, reactive navy blue RGB, reactive Blue M-2GE dyes the cotton component in the composite fabric, and the percentages of the dye to the weight of the pure cotton fabric are 0.3%, 0.6%, 0.9%, 1.2%, 1.5%, 2%, 2.5%, 3%, 4% Leveling agent 1g/L, sodium sulfate, soda ash consumption is determined by the total concentration of dyestuff used, and the consumption of sodium sulfate and soda ash is as shown in table 2 under different dye concentrations.
使用纯碱调节染液pH值为8~9,60℃始染,保温染色10min后加入一半的元明粉,再保温染色10min后加入另一半的元明粉,保温染色10min后以2℃/min升温至90℃,加入一半的纯碱,再保温染色10min后加入另一半的纯碱,保温染色20min后水洗、烘干,浴比1:25。将这些基础色样采用测配色仪器测试后输入电脑后所建立的基础数据库(简称基础数据库一)。Use soda ash to adjust the pH value of the dyeing solution to 8-9, start dyeing at 60°C, add half of the sodium sulfate after 10 minutes of heat preservation and dyeing, add the other half of sodium sulfate after 10 minutes of heat preservation and dyeing, and then dye at 2°C/min after heat preservation for 10 minutes Raise the temperature to 90°C, add half of the soda ash, and then add the other half of the soda ash after 10 minutes of heat preservation and dyeing, wash and dry with water after 20 minutes of heat preservation and dyeing, the bath ratio is 1:25. These basic color samples are tested by a color matching instrument and input into the basic database established by the computer (referred to as the basic database 1).
3)对步骤1)所述的混合织物采用不同浓度的酸性染料染色建立锦棉织物中锦纶的基础数据库二;本实施例采用酸性红N-2RBL、酸性黄M-R、酸性蓝N-R对纯锦纶织物染色,染料对织物重的百分率分别为0.3%、0.6%、0.9%、1.2%、1.5%、2%、2.5%、3%、4%;匀染剂1.5g/L,使用醋酸调节染液pH值为4~5,40℃始染,以1℃/min升温至95℃,保温染色40min后以1℃/min降温至60℃后水洗、烘干,浴比1:25。将这些基础色样采用测配色仪器测试后输入电脑后所建立的基础数据库(简称基础数据库二)。3) The mixed fabric described in step 1) is dyed with different concentrations of acid dyes to establish the basic database of nylon in nylon cotton fabric 2; in this embodiment, acid red N-2RBL, acid yellow M-R, and acid blue N-R are used for pure nylon fabric For dyeing, the percentages of dyes to fabric weight are 0.3%, 0.6%, 0.9%, 1.2%, 1.5%, 2%, 2.5%, 3%, 4%; leveling agent 1.5g/L, use acetic acid to adjust the dyeing solution The pH value is 4-5. Dyeing is started at 40°C, and the temperature is raised to 95°C at 1°C/min. After 40 minutes of heat preservation, the temperature is lowered to 60°C at 1°C/min, and then washed and dried. The liquor ratio is 1:25. These basic color samples are tested by a color matching instrument and input into the basic database established by the computer (referred to as basic database 2).
4)根据目标色,采用步骤2)所述的基础数据库一对空白的混合织物进行电脑配色,根据配方进行打样;选取藏青色的色样,对锦棉平纹织物进行同色性配方预测后根据配方染色。4) According to the target color, use the basic database described in step 2) to carry out computer color matching on a pair of blank mixed fabrics, and make a sample according to the formula; select a navy blue color sample, and predict the formula of the same color of nylon-cotton plain weave fabric according to the formula dyeing.
5)将步骤4)打样所得纯棉织物色样输入电脑,由电脑给出修色配方,根据修色配方继续打样;将打样所得色样输入电脑,由电脑给出修色配方,根据修色配方继续打样:5) Input the pure cotton fabric color sample obtained in step 4) into the computer, and the computer will give the color correction formula, and continue proofing according to the color correction formula; input the color sample obtained from the proofing into the computer, and the computer will give the color correction formula, according to the color correction formula The formula continues to proof:
6)重复步骤5),直到纯棉织物色样与目标色的色差值小于1,获得活性染料的染色配方和一块采用该染色配方的纯锦纶织物沾色色样。6) Repeat step 5) until the color difference between the pure cotton fabric color sample and the target color is less than 1, and obtain the dyeing formula of reactive dyes and a stained color sample of pure nylon fabric using the dyeing formula.
7)根据步骤6)所述的纯锦纶织物沾色色样,采用基础数据库二对空白的混合织物进行电脑配色,获得酸性染料染色配方一;7) According to the staining color sample of pure nylon fabric described in step 6), computer color matching is carried out on the blank mixed fabric by using the basic database 2 to obtain the acid dye dyeing formula 1;
8)根据目标色,采用基础数据库二对空白的混合织物进行电脑配色,根据配方进行打样,将打样所得纯锦纶织物色样输入电脑,由电脑给出修色配方,根据修色配方继续打样;8) According to the target color, use the basic database 2 to carry out computer color matching on the blank mixed fabric, and carry out proofing according to the formula, input the color sample of pure nylon fabric obtained from the proofing into the computer, and the computer will give the color correction formula, and continue proofing according to the color correction formula;
9)重复步骤8),直到纯锦纶织物色样与目标色的色差值小于1,获得酸性染料染色配方二,将酸性染料染色配方二减去酸性染料染色配方一可获得酸性染料染色配方三;9) Repeat step 8) until the color difference between the pure nylon fabric color sample and the target color is less than 1, and the acid dye dyeing formula 2 is obtained. Subtract the acid dye dyeing formula 1 from the acid dye dyeing formula 2 to obtain the acid dye dyeing formula 3 ;
10)步骤6)所述的活性染料的染色配方和步骤9)所述的酸性染料染色配方三混合即为锦棉织物的同色性配方。10) The dyeing formula of the reactive dye described in step 6) and the dyeing formula of the acid dye described in step 9) are mixed to form the same-color formula of nylon-cotton fabric.
选取藏青色的色样,对锦棉平纹织物进行同色性配方预测后根据配方染色,将打样所得色样输入电脑,由电脑给出修色配方,根据修色配方继续打样:将染色后色样测试后输入电脑进行色差判定,然后根据再次给出的配方进行修色。Select a navy blue color sample, predict the formula of the same color of nylon-cotton plain weave fabric, and then dye it according to the formula. Input the color sample obtained from the proofing into the computer, and the computer will give the color correction formula, and continue proofing according to the color correction formula: the dyed color sample After the test, enter the computer to judge the color difference, and then carry out color correction according to the formula given again.
重复上述步骤直到色样与目标色的色差满足要求,打样结束,该过程重复至色差值小于1。每次染色样与目标色样间的色差结果和同色性色差如表3所示。Repeat the above steps until the color difference between the color sample and the target color meets the requirements, the proofing is over, and the process is repeated until the color difference value is less than 1. The color difference results and homochromatic color difference between each dyed sample and the target color sample are shown in Table 3.
由表3可得:色样在第二次修色后达到棉和锦纶之间的色差△E(CMC 2:1)=1.56,可以达到工厂实际对锦/棉交织物色差的要求。It can be obtained from Table 3 that after the second color correction, the color sample reaches the color difference between cotton and nylon △E(CMC 2:1)=1.56, which can meet the factory's actual requirements for the color difference of nylon/cotton interwoven fabrics.
实施例2Example 2
本实施例主要步骤如实施例1相同,区别在于:采用锦纶和棉的重量比为4:6的锦棉斜纹交织布,目标色样为咖啡色,对锦棉平纹交织布染色,首先以重量比为4:6的一块纯锦纶斜纹织物和一块纯棉斜纹织物组成的混合织物模拟该锦棉斜纹纹交织布。The main steps of this embodiment are the same as those in Example 1, the difference is that nylon-cotton twill interwoven fabric with a weight ratio of nylon and cotton of 4:6 is used, and the target color sample is brown. A mixed fabric composed of a piece of pure nylon twill fabric and a piece of pure cotton twill fabric with a ratio of 4:6 simulates the nylon-cotton twill weave fabric.
同理按实施例1的方法建立基础数据库。根据所选取的咖啡色目标色样,对混合织物中的棉和锦纶分别进行配方预测后根据配方染色,将染色后色样测试后输入电脑进行色差判定,然后根据再次给出的配方进行修色,该过程重复至色差值小于1。每次染色样与目标色样间的色差结果和同色性色差如表4所示。:由表4可得:色样在棉第二次修色和锦纶第三次修色后,两者之间的色差△E(CMC 2:1)=1.26,可以达到工厂实际对锦/棉交织物色差的要求。Similarly, establish the basic database according to the method of Embodiment 1. According to the selected brown target color sample, the cotton and nylon in the mixed fabric are respectively predicted and dyed according to the formula. After the dyed color sample is tested, it is input into the computer for color difference judgment, and then the color is repaired according to the given formula again. This process is repeated until the color difference value is less than 1. The color difference results and homochromatic color difference between each dyed sample and the target color sample are shown in Table 4. : It can be obtained from Table 4: after the second color correction of cotton and the third color correction of nylon, the color difference between the two is △E(CMC 2:1)=1.26, which can reach the actual color adjustment of nylon/cotton in the factory. Requirements for cross-fabric color difference.
实施例3Example 3
本实施例主要步骤同实施例1,区别在于改变其中的织物面料交织比,织物组织结构,染料种类、数量,染料的浓度梯度,染色工艺,可获得不同数量的基础数据组数。如表5所示,表5为每次所采用的不同锦棉织物的各个参数表。由表5知,根据本发明的配色方法,可以获得任意的,根据人员需要目标色的不同锦棉交织物,不同染料,不同染色工艺和不同浓度梯度的基础数据,在此不穷举。The main steps of this embodiment are the same as those of Embodiment 1, the difference being that the number of basic data groups of different numbers can be obtained by changing the interweaving ratio of fabric, fabric structure, dye type and quantity, dye concentration gradient, and dyeing process. As shown in Table 5, Table 5 is each parameter table of different nylon-cotton fabrics adopted each time. Known from Table 5, according to the color matching method of the present invention, can obtain arbitrary, according to personnel need the basic data of different polyamide-cotton interwoven fabrics of target color, different dyestuffs, different dyeing processes and different concentration gradients, not exhaustive here.
表1Table 1
注:表1仅用于说明步骤(1),基础数据种类繁多,数据库庞大,不能穷举,仅仅列出一部分。Note: Table 1 is only used to illustrate step (1). There are many types of basic data and a huge database, so it cannot be exhaustive, but only a part is listed.
表2Table 2
表3table 3
注:同色性的测定方法为拆开根据该配方染色的锦/棉交织物的经纱和纬纱,以棉作为标准样,锦纶为测试样,在测配色系统上测出ΔE。Note: The method of measuring the same color is to disassemble the warp and weft yarns of the nylon/cotton interwoven fabric dyed according to the formula, take cotton as the standard sample, and nylon as the test sample, and measure ΔE on the color matching system.
表4Table 4
表5table 5
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