CN102816658B - Environment-friendly cleaning emulsion and preparation method thereof - Google Patents
Environment-friendly cleaning emulsion and preparation method thereof Download PDFInfo
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- CN102816658B CN102816658B CN201210324975.0A CN201210324975A CN102816658B CN 102816658 B CN102816658 B CN 102816658B CN 201210324975 A CN201210324975 A CN 201210324975A CN 102816658 B CN102816658 B CN 102816658B
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- 239000000839 emulsion Substances 0.000 title claims abstract description 88
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000004140 cleaning Methods 0.000 title abstract description 25
- 238000004945 emulsification Methods 0.000 title 1
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 77
- 239000010431 corundum Substances 0.000 claims abstract description 77
- 239000002245 particle Substances 0.000 claims abstract description 64
- 239000004094 surface-active agent Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 26
- 230000008719 thickening Effects 0.000 claims description 26
- 239000000976 ink Substances 0.000 claims description 21
- 239000000080 wetting agent Substances 0.000 claims description 21
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 20
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 20
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 20
- 229920002401 polyacrylamide Polymers 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 18
- -1 polyoxyethylene nonylphenol Polymers 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 10
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 10
- 235000010234 sodium benzoate Nutrition 0.000 claims description 10
- 239000004299 sodium benzoate Substances 0.000 claims description 10
- 235000019580 granularity Nutrition 0.000 claims description 7
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 6
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 6
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 6
- 235000010241 potassium sorbate Nutrition 0.000 claims description 6
- 239000004302 potassium sorbate Substances 0.000 claims description 6
- 229940069338 potassium sorbate Drugs 0.000 claims description 6
- 239000000811 xylitol Substances 0.000 claims description 6
- 235000010447 xylitol Nutrition 0.000 claims description 6
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 6
- 229960002675 xylitol Drugs 0.000 claims description 6
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 4
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 claims description 4
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 235000010199 sorbic acid Nutrition 0.000 claims description 4
- 239000004334 sorbic acid Substances 0.000 claims description 4
- 229940075582 sorbic acid Drugs 0.000 claims description 4
- 229960003885 sodium benzoate Drugs 0.000 claims description 2
- 239000003755 preservative agent Substances 0.000 abstract description 13
- 230000002335 preservative effect Effects 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 9
- 230000009471 action Effects 0.000 abstract description 6
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention belongs to the technical field of chemical industry for daily use, and particularly relates to an environment-friendly cleaning emulsion. The environment-friendly cleaning emulsion comprises the following components in percentage by weight: 1-5% of hydrophilic surfactant, 5-10% of humectant, 0.05-0.2% of preservative, 30-60% of corundum, 0.05-1.5% of thickener and the balance of water, wherein the particle size of the corundum is 200-4000 meshes. Compared with the prior art, the corundum which can greatly increase the friction of the emulsion is added in the cleaning emulsion, and the cleaning effect of the hydrophilic surfactant is combined. When in use, oil stains and fouling can be easily, quickly and thoroughly cleaned under the action of an extremely small force by simply pouring a small amount of emulsion. Furthermore, the corundum itself is an inorganic substance, so that the environmental pollution problem caused by an organic substance can be avoided, thereby ensuring that the cleaning emulsion is relatively environment-friendly; and the surface of a cleaned object can not be damaged. Besides, the invention also discloses a preparation method of the environment-friendly cleaning emulsion.
Description
Technical field
The invention belongs to daily-use chemical industry technical field, particularly clean emulsion of a kind of environment-friendly type and preparation method thereof.
Background technology
At present, the sanitising agent on market is of a great variety, but is mostly all the soil-removing action that relies on some organic compositions, therefore can cause pollution to a certain degree to environment; Although these sanitising agents have its cleaning effect, but when removing the glass dirt of kitchen oil stain, factory building, equipment, Highrise buildings and building etc., conventionally sanitising agent first need to be sprayed on these greasy dirts or dirt, then use instrument wiping wipe oil or dirt, in the process of wiping, generally need to use larger strength just can complete, spended time is longer, and particularly the glass outer wall cleaning up of Highrise buildings is more difficult, and cleaning performance is also not fully up to expectations.
In view of this, necessary preferably clean emulsion of environment-friendly type and preparation method thereof of a kind of environmental protection, laborsaving, cleaning effect that provides.
Summary of the invention
One of object of the present invention is: for the deficiencies in the prior art, and the preferably clean emulsion of environment-friendly type of a kind of environmental protection, laborsaving, cleaning effect is provided, use this clean emulsion can remove easily, rapidly the glass dirt etc. of kitchen oil stain, factory building, equipment, Highrise buildings and building etc., overcoming sanitising agent of the prior art, can cause pollution to a certain degree, degreasing to environment time, need to spend compared with great strength and the not good deficiency of cleaning performance.
To achieve these goals, the present invention adopts following technical scheme: a kind of environment-friendly type cleans emulsion, by weight percentage, comprise following component, hydrophilic surfactant active 1～5%, wetting Agent for Printing Inks 5～10%, sanitas 0.5～2 ‰, corundum 30～60%, thickening material 0.5～15 ‰, surplus is water, and the particle diameter of described corundum is 200～4000 orders.
As a kind of improvement of the clean emulsion of environment-friendly type of the present invention, the pH value of described clean emulsion is 7～9, and density is 1～2.5g/cm
3, the emulsion of meta-alkalescence has better effect for wipe oil etc., and the emulsion of slant acidity not only can be dissolved a part of corundum, but also can cause corrosion to cleaned body surface.In addition, density is too large, need to expend more corundum, cause the increase of production cost, and density is too little, does not have again good friction, labor-saving effect.
A kind of improvement as the clean emulsion of environment-friendly type of the present invention, described corundum comprises that particle diameter is respectively the corundum particle of 200～600 orders, 601～2000 orders and three kinds of granularities of 2001～4000 objects, and the weight ratio of the corundum particle of three kinds of granularities is followed successively by (2～4): (2～4): (6～1).Wherein, 200～600 object corundum particles are wipe oil and dirt etc. preferably; 600～2000 object corundum particles are not easy to scratch the surface of cleaned object; can play the effect of the cleaned object of protection; and 2000～4000 object corundum particles have the effect of polishing; make the surface-brightening of cleaned object as newly, and can keep time of growing.The mixing of the corundum particle of three kinds of granularities makes emulsion of the present invention both have cleaning action, can also effectively protect cleaned object surface and cleaned object is carried out to surface finish.Preferably, three's mass ratio is 1:1:1.
As a kind of improvement of the clean emulsion of environment-friendly type of the present invention, described thickening material is the mixture of polyacrylamide and carboxymethyl cellulose, and the mass ratio of the two is (1～9): (9～1).Wherein, polyacrylamide has good flocculence and adsorptivity, and the surface that it can be adsorbed on corundum particle makes corundum particle be difficult for running off.Carboxymethyl cellulose has good dispersiveness, makes to be separated from each other between corundum particle, and to form uniform emulsion, not sedimentation, also not stratified.
As a kind of improvement of the clean emulsion of environment-friendly type of the present invention, the matter average molecular weight of described polyacrylamide is 100～3,000,000, and the matter average molecular weight of described carboxymethyl cellulose is 300～1500.The molecular weight that polyacrylamide is selected is larger, is in order to make it have higher viscosity, to be coated on tightly the surface of corundum particle, prevents the loss of corundum particle.And the molecular weight that carboxymethyl cellulose is selected is lower, be in order to make it have good dispersiveness, prevent layering and the sedimentation of emulsion of the present invention, in addition, carboxymethyl cellulose itself also has certain cleaning action.
As a kind of improvement of the clean emulsion of environment-friendly type of the present invention, described hydrophilic surfactant active is at least one in polyoxyethylene nonylphenol ether, polyoxyethylene octylphenol ether and dodecyl phenol polyethenoxy ether.These several tensio-active agents are also emulsifying agents in fact, are that the present invention can exist with the form of emulsion.Meanwhile, they also have good wetting, infiltration, dispersion, solubilising and cleaning function, can reach certain clean effect.
As a kind of improvement of the clean emulsion of environment-friendly type of the present invention, described wetting Agent for Printing Inks is at least one in sorbyl alcohol, Xylitol and glycerol.
As a kind of improvement of the clean emulsion of environment-friendly type of the present invention, described sanitas is at least one in Sorbic Acid, potassium sorbate and Sodium Benzoate.
As a kind of improvement of the clean emulsion of environment-friendly type of the present invention, described clean emulsion also comprises ten thousand/essence to 10/10000ths, make clean emulsion there is the fragrance of pleasant.
With respect to prior art, the present invention has added this inorganic substance (in the present invention, the particle diameter of corundum is 200～4000 orders) that can greatly increase emulsion frictional force of corundum (being aluminium sesquioxide) in clean emulsion, and in conjunction with hydrophilic surfactant active's cleaning action, use this clean emulsion to remove kitchen oil stain, factory building, equipment, during glass dirt of Highrise buildings and building etc. etc., only need pour out a small amount of emulsion in towel, on moistening cleaning tissue etc., just can use minimum power light, fast, remove up hill and dale greasy dirt and dirt, and because corundum also has certain polishing action, after having cleaned, cleaned position light as new, and can keep the time of growing.And, because corundum itself is inorganic substance, can not bring the problem of environmental pollution as organism, therefore relatively environmental protection, in addition, can not damage being cleaned the surface of object yet.In addition, the present invention, by adding a certain amount of thickening material, can make corundum dispersed, not sedimentation, thus form stable emulsion.The use of a certain amount of sanitas and wetting Agent for Printing Inks can make the shelf-time of clean emulsion of the present invention more of a specified duration, and the quality guaranteed period is more of a specified duration.In addition, clean emulsion of the present invention can also be for wiping glass for vehicle window, and the cleaning glass after wiping is clean, does not stay any vestige.
Another object of the present invention is to provide the preparation method of the clean emulsion of a kind of environment-friendly type, comprise the following steps: the first step, hydrophilic surfactant active, wetting Agent for Printing Inks, sanitas and thickening material are pressed respectively to (1～5%): (5～10%): (0.5～2 ‰): the part by weight of (0.5～15 ‰) is added to the water, stir, obtain premixed liquid.
Second step, the particle diameter that is 30～60% by weight percent is that 200～4000 object corundum add in the premixed liquid that the first step obtains, and obtains the clean emulsion of environment-friendly type after stirring.
With respect to prior art, the present invention is by first preparing premixed liquid, again to the operation that adds corundum in premixed liquid, can obtain dispersed fine, not sedimentation, not stratified clean emulsion, and whole process is simple, and without complicated operation, time saving and energy saving, cost is lower.And the clean emulsion preparing can be removed greasy dirt and dirt easily, fast, up hill and dale.
Embodiment
Below in conjunction with embodiment, the present invention and beneficial effect thereof are described in further detail, but embodiments of the present invention are not limited to this.
Embodiment 1: the present embodiment provides a kind of environment-friendly type to clean emulsion, by weight percentage, comprise following component, hydrophilic surfactant active's polyoxyethylene nonylphenol ether 2%, wetting Agent for Printing Inks sorbyl alcohol 8%, sanitas Sorbic Acid 1 ‰, 300 object corundum particles 20%, 1000 object corundum particles 20%, 2500 object corundum particles 20%, thickening material polyacrylamide (matter average molecular weight is 1,500,000) 1 ‰, thickening material carboxymethyl cellulose (matter average molecular weight is 600) 1 ‰, essence ten thousand/, surplus is water.
The pH of this clean emulsion is 7, and density is 2.5g/cm
3.Wherein, corundum particle is α-Al
2o
3.
The preparation method of the clean emulsion of the present embodiment comprises the following steps: the first step, the carboxymethyl cellulose that the thickening material polyacrylamide that is 1,500,000 by hydrophilic surfactant active's polyoxyethylene nonylphenol ether, wetting Agent for Printing Inks sorbyl alcohol, sanitas Sorbic Acid and matter average molecular weight, matter average molecular weight are 600 and essence respectively by 3%, 7%, 1 ‰, 1 ‰, 1 ‰ and ten thousand/ part by weight be added to the water, stir, obtain premixed liquid.
Second step, the 3000 object corundum particles that the 300 object corundum particles that are 20% by weight percent, 1000 object corundum particles that weight percent is 20% and weight percent are 20% add in the premixed liquid that the first step obtains, after stirring, obtain the clean emulsion of environment-friendly type, this emulsion is white, evenly whole, have no layering, and within standing 1 year, also have no any layering and sedimentation phenomenon; Even place it in the boot of automobile, with car, jolt and within three months, also have no any layering and sedimentation phenomenon.
During actual use, only need pour out clean emulsion that a small amount of the present embodiment prepares on towel or moistening cleaning tissue, just can use minimum power to remove easily, fast, up hill and dale greasy dirt and dirt.
Embodiment 2: the present embodiment provides a kind of environment-friendly type to clean emulsion, by weight percentage, comprise following component, hydrophilic surfactant active's polyoxyethylene octylphenol ether 5%, wetting Agent for Printing Inks Xylitol 10%, potassium sorbate preservative 2 ‰, 400 object corundum particles 10%, 1200 object corundum particles 15%, 3500 object corundum particles 20%, thickening material polyacrylamide (matter average molecular weight is 2,000,000) 5 ‰, thickening material carboxymethyl cellulose (matter average molecular weight is 500) 5 ‰, essence 5/10000ths, surplus is water.
The pH of this clean emulsion is 8, and density is 1.5g/cm
3.Wherein, corundum particle is α-Al
2o
3.
The preparation method of the clean emulsion of the present embodiment comprises the following steps: the first step, the carboxymethyl cellulose that the thickening material polyacrylamide that is 2,000,000 by hydrophilic surfactant active's polyoxyethylene octylphenol ether, wetting Agent for Printing Inks Xylitol, potassium sorbate preservative and matter average molecular weight, matter average molecular weight are 500 and essence are added to the water by 5%, 10%, 2 ‰, 5 ‰, 5 ‰ and 5/10000ths part by weight respectively, stir, obtain premixed liquid.
Second step, the 3500 object corundum particles that the 400 object corundum particles that are 10% by weight percent, 1200 object corundum particles that weight percent is 15% and weight percent are 20% add in the premixed liquid that the first step obtains, after stirring, obtain the clean emulsion of environment-friendly type, this emulsion is white, evenly whole, have no layering, and within standing 1 year, also have no any layering and sedimentation phenomenon; Even place it in the boot of automobile, with car, jolt and within three months, also have no any layering and sedimentation phenomenon.
During actual use, only need pour out clean emulsion that a small amount of the present embodiment prepares on towel or moistening cleaning tissue, just can use minimum power to remove easily, fast, up hill and dale greasy dirt and dirt.
Embodiment 3: the present embodiment provides a kind of environment-friendly type to clean emulsion, by weight percentage, comprise following component, hydrophilic surfactant active's polyoxyethylene nonylphenol ether 2%, wetting Agent for Printing Inks glycerol 8%, preservative sodium benzoate 1.5 ‰, 500 object corundum particles 10%, 1800 object corundum particles 10%, 2500 object corundum particles 15%, thickening material polyacrylamide (matter average molecular weight is 1,000,000) 10 ‰, thickening material carboxymethyl cellulose (matter average molecular weight is 1000) 2 ‰, essence 2/10000ths, surplus is water.
The pH of this clean emulsion is 9, and density is 2g/cm
3.Wherein, corundum particle is α-Al
2o
3.
The preparation method of the clean emulsion of the present embodiment comprises the following steps: the first step, the carboxymethyl cellulose that the thickening material polyacrylamide that is 1,000,000 by hydrophilic surfactant active's polyoxyethylene nonylphenol ether, wetting Agent for Printing Inks glycerol, preservative sodium benzoate and matter average molecular weight, matter average molecular weight are 1000 and essence are added to the water by 2%, 8%, 1.5 ‰, 10 ‰, 2 ‰ and 10/10000ths part by weight respectively, stir, obtain premixed liquid.
Second step, the 2500 object corundum particles that the 500 object corundum particles that are 10% by weight percent, 1800 object corundum particles that weight percent is 10% and weight percent are 15% add in the premixed liquid that the first step obtains, after stirring, obtain the clean emulsion of environment-friendly type, this emulsion is white, evenly whole, have no layering, and within standing 1 year, also have no any layering and sedimentation phenomenon; Even place it in the boot of automobile, with car, jolt and within three months, also have no any layering and sedimentation phenomenon.
During actual use, only need pour out clean emulsion that a small amount of the present embodiment prepares on towel or moistening cleaning tissue, just can use minimum power to remove easily, fast, up hill and dale greasy dirt and dirt.
Embodiment 4: the present embodiment provides a kind of environment-friendly type to clean emulsion, by weight percentage, comprise following component, hydrophilic surfactant active's dodecyl phenol polyethenoxy ether 4%, wetting Agent for Printing Inks glycerol 6%, preservative sodium benzoate 0.5 ‰, 600 object corundum particles 12%, 2000 object corundum particles 12%, 4000 object corundum particles 18%, thickening material polyacrylamide (matter average molecular weight is 3,000,000) 12 ‰, thickening material carboxymethyl cellulose (matter average molecular weight is 1500) 3 ‰, essence 7/10000ths, surplus is water.
The pH of this clean emulsion is 7.5, and density is 1.7g/cm
3.Wherein, corundum particle is α-Al
2o
3.
The preparation method of the clean emulsion of the present embodiment comprises the following steps: the first step, the carboxymethyl cellulose that the thickening material polyacrylamide that is 3,000,000 by hydrophilic surfactant active's dodecyl phenol polyethenoxy ether, wetting Agent for Printing Inks glycerol, preservative sodium benzoate and matter average molecular weight, matter average molecular weight are 1500 and essence are added to the water by 4%, 6%, 0.5 ‰, 15 ‰, 3 ‰ and 7/10000ths part by weight respectively, stir, obtain premixed liquid.
Second step, the 4000 object corundum particles that the 600 object corundum particles that are 12% by weight percent, 2000 object corundum particles that weight percent is 12% and weight percent are 18% add in the premixed liquid that the first step obtains, after stirring, obtain the clean emulsion of environment-friendly type, this emulsion is white, evenly whole, have no layering, and within standing 1 year, also have no any layering and sedimentation phenomenon; Even place it in the boot of automobile, with car, jolt and within three months, also have no any layering and sedimentation phenomenon.
During actual use, only need pour out clean emulsion that a small amount of the present embodiment prepares on towel or moistening cleaning tissue, just can use minimum power to remove easily, fast, up hill and dale greasy dirt and dirt.
Embodiment 5: the present embodiment provides a kind of environment-friendly type to clean emulsion, by weight percentage, comprise following component, hydrophilic surfactant active's polyoxyethylene nonylphenol ether 1%, wetting Agent for Printing Inks glycerol 5%, preservative sodium benzoate 0.5 ‰, 200 object corundum particles 10%, 700 object corundum particles 10%, 2100 object corundum particles 5%, thickening material polyacrylamide (matter average molecular weight is 2,500,000) 1 ‰, thickening material carboxymethyl cellulose (matter average molecular weight is 1000) 2 ‰, essence 8/10000ths, surplus is water.
The pH of this clean emulsion is 7, and density is 1g/cm
3.Wherein, corundum particle is γ-Al
2o
3.
The preparation method of the clean emulsion of the present embodiment comprises the following steps: the first step, the carboxymethyl cellulose that the thickening material polyacrylamide that is 2,500,000 by hydrophilic surfactant active's polyoxyethylene nonylphenol ether, wetting Agent for Printing Inks glycerol, preservative sodium benzoate and matter average molecular weight, matter average molecular weight are 1000 and essence are added to the water by 1%, 5%, 0.5 ‰, 1 ‰, 2 ‰ and 8/10000ths part by weight respectively, stir, obtain premixed liquid.
Second step, the 2100 object corundum particles that the 200 object corundum particles that are 10% by weight percent, 700 object corundum particles that weight percent is 10% and weight percent are 5% add in the premixed liquid that the first step obtains, after stirring, obtain the clean emulsion of environment-friendly type, this emulsion is white, evenly whole, have no layering, and within standing 1 year, also have no any layering and sedimentation phenomenon; Even place it in the boot of automobile, with car, jolt and within three months, also have no any layering and sedimentation phenomenon.
During actual use, only need pour out clean emulsion that a small amount of the present embodiment prepares on towel or moistening cleaning tissue, just can use minimum power to remove easily, fast, up hill and dale greasy dirt and dirt.
Embodiment 6: the present embodiment provides a kind of environment-friendly type to clean emulsion, by weight percentage, comprise following component, hydrophilic surfactant active's polyoxyethylene octylphenol ether 1%, hydrophilic surfactant active's polyoxyethylene nonylphenol ether 3%, wetting Agent for Printing Inks Xylitol 2%, wetting Agent for Printing Inks glycerol 4%, potassium sorbate preservative 1 ‰, preservative sodium benzoate 0.5 ‰, 300 object corundum particles 12%, 1100 object corundum particles 18%, 3100 object corundum particles 16%, thickening material polyacrylamide (matter average molecular weight is 2,200,000) 4 ‰, thickening material carboxymethyl cellulose (matter average molecular weight is 700) 4 ‰, essence 9/10000ths, surplus is water.
The pH of this clean emulsion is 8, and density is 1.7/cm
3.Wherein, corundum particle is α-Al
2o
3.
The preparation method of the clean emulsion of the present embodiment comprises the following steps: the first step, the carboxymethyl cellulose that the thickening material polyacrylamide that is 2,200,000 by hydrophilic surfactant active's polyoxyethylene octylphenol ether, hydrophilic surfactant active's polyoxyethylene nonylphenol ether, wetting Agent for Printing Inks Xylitol, wetting Agent for Printing Inks glycerol, potassium sorbate preservative, preservative sodium benzoate and matter average molecular weight, matter average molecular weight are 700 and essence are added to the water by 1%, 3%, 2%, 4%, 1 ‰, 0.5 ‰, 4 ‰, 4 ‰ and 9/10000ths part by weight respectively, stir, obtain premixed liquid.
Second step, the 3100 object corundum particles that the 300 object corundum particles that are 12% by weight percent, 1100 object corundum particles that weight percent is 18% and weight percent are 16% add in the premixed liquid that the first step obtains, after stirring, obtain the clean emulsion of environment-friendly type, this emulsion is white, evenly whole, have no layering, and within standing 1 year, also have no any layering and sedimentation phenomenon; Even place it in the boot of automobile, with car, jolt and within three months, also have no any layering and sedimentation phenomenon.
During actual use, only need pour out clean emulsion that a small amount of the present embodiment prepares on towel or moistening cleaning tissue, just can use minimum power to remove easily, fast, up hill and dale greasy dirt and dirt.
The announcement of book and instruction according to the above description, those skilled in the art in the invention can also change and revise above-mentioned embodiment.Therefore, the present invention is not limited to embodiment disclosed and described above, to modifications and changes more of the present invention, also should fall in the protection domain of claim of the present invention.In addition,, although used some specific terms in this specification sheets, these terms just for convenience of description, do not form any restriction to the present invention.
Claims (7)
1. the clean emulsion of environment-friendly type, is characterized in that, by weight percentage, comprises following component:
Hydrophilic surfactant active 1～5%
Wetting Agent for Printing Inks 5～10%
Sanitas 0.5～2 ‰
Corundum 30～60%
Thickening material 0.5～15 ‰
Surplus is water, described corundum comprises that particle diameter is respectively the corundum particle of 200～600 orders, 601～2000 orders and three kinds of granularities of 2001～4000 objects, and the weight ratio of the corundum particle of three kinds of granularities is followed successively by (2～4): (2～4): (6～1), described thickening material is the mixture of polyacrylamide and carboxymethyl cellulose, and the mass ratio of the two is (1～9): (9～1), the matter average molecular weight of described polyacrylamide is 100～3,000,000, and the matter average molecular weight of described carboxymethyl cellulose is 300～1500.
2. the clean emulsion of environment-friendly type according to claim 1, is characterized in that: the pH value of described clean emulsion is 7～9, and density is 1～2.5g/cm
3.
3. the clean emulsion of environment-friendly type according to claim 1, is characterized in that: described hydrophilic surfactant active is at least one in polyoxyethylene nonylphenol ether, polyoxyethylene octylphenol ether and dodecyl phenol polyethenoxy ether.
4. the clean emulsion of environment-friendly type according to claim 1, is characterized in that: described wetting Agent for Printing Inks is at least one in sorbyl alcohol, Xylitol and glycerol.
5. the clean emulsion of environment-friendly type according to claim 1, is characterized in that: described sanitas is at least one in Sorbic Acid, potassium sorbate and Sodium Benzoate.
6. the clean emulsion of environment-friendly type according to claim 1, is characterized in that: described clean emulsion also comprises ten thousand/and essence to 10/10000ths.
7. a preparation method for the clean emulsion of environment-friendly type claimed in claim 1, is characterized in that, comprises the following steps:
The first step, hydrophilic surfactant active, wetting Agent for Printing Inks, sanitas and thickening material are pressed respectively to (1～5%): (5～10%): (0.5～2 ‰): the part by weight of (0.5～15 ‰) is added to the water, stir, obtain premixed liquid, wherein, described thickening material is the mixture of polyacrylamide and carboxymethyl cellulose, and the mass ratio of the two is (1～9): (9～1), the matter average molecular weight of described polyacrylamide is 100～3,000,000, and the matter average molecular weight of described carboxymethyl cellulose is 300～1500;
Second step, the corundum that is 30～60% by weight percent adds in the premixed liquid that the first step obtains, after stirring, obtain the clean emulsion of environment-friendly type, wherein, described corundum comprises that particle diameter is respectively the corundum particle of 200～600 orders, 601～2000 orders and three kinds of granularities of 2001～4000 objects, and the weight ratio of the corundum particle of three kinds of granularities is followed successively by (2～4): (2～4): (6～1).
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| EP4298170A4 (en) * | 2021-02-23 | 2025-01-29 | Hercules LLC | RHEOLOGY MODIFIER COMPOSITIONS AND ARCHITECTURAL COATING COMPOSITIONS DERIVED THEREFROM |
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| CN105623528A (en) * | 2015-12-31 | 2016-06-01 | 万嘉裕 | Shoeshine and manufacturing method thereof |
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| CN1087942A (en) * | 1992-12-07 | 1994-06-15 | 田地 | Soap with abrasive |
| CN101463292A (en) * | 2008-11-28 | 2009-06-24 | 江苏海迅实业集团股份有限公司 | Surface treating agent for glass of vehicle and ship |
| CN101735905A (en) * | 2008-11-17 | 2010-06-16 | 周绪书 | Tableware detergent and preparation method |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1087942A (en) * | 1992-12-07 | 1994-06-15 | 田地 | Soap with abrasive |
| CN101735905A (en) * | 2008-11-17 | 2010-06-16 | 周绪书 | Tableware detergent and preparation method |
| CN101463292A (en) * | 2008-11-28 | 2009-06-24 | 江苏海迅实业集团股份有限公司 | Surface treating agent for glass of vehicle and ship |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP4298170A4 (en) * | 2021-02-23 | 2025-01-29 | Hercules LLC | RHEOLOGY MODIFIER COMPOSITIONS AND ARCHITECTURAL COATING COMPOSITIONS DERIVED THEREFROM |
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