CN102806809A - Aspartame polyurea surface decorative layer and construction method - Google Patents
Aspartame polyurea surface decorative layer and construction method Download PDFInfo
- Publication number
- CN102806809A CN102806809A CN2012103099768A CN201210309976A CN102806809A CN 102806809 A CN102806809 A CN 102806809A CN 2012103099768 A CN2012103099768 A CN 2012103099768A CN 201210309976 A CN201210309976 A CN 201210309976A CN 102806809 A CN102806809 A CN 102806809A
- Authority
- CN
- China
- Prior art keywords
- layer
- asparagus fern
- fern polyureas
- polyureas
- spraying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002396 Polyurea Polymers 0.000 title claims abstract description 66
- 238000010276 construction Methods 0.000 title claims abstract description 12
- 108010011485 Aspartame Proteins 0.000 title abstract 6
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 title abstract 6
- 229960003438 aspartame Drugs 0.000 title abstract 6
- 235000010357 aspartame Nutrition 0.000 title abstract 6
- 239000000605 aspartame Substances 0.000 title abstract 6
- 238000005034 decoration Methods 0.000 claims abstract description 26
- 238000005507 spraying Methods 0.000 claims abstract description 25
- 239000003973 paint Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 6
- 238000004381 surface treatment Methods 0.000 claims abstract description 5
- 238000007639 printing Methods 0.000 claims abstract description 4
- 239000010410 layer Substances 0.000 claims description 66
- 241000432824 Asparagus densiflorus Species 0.000 claims description 59
- 239000002932 luster Substances 0.000 claims description 23
- 239000011247 coating layer Substances 0.000 claims description 20
- 239000011241 protective layer Substances 0.000 claims description 15
- 239000002966 varnish Substances 0.000 claims description 14
- 239000011521 glass Substances 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 8
- 239000011159 matrix material Substances 0.000 claims description 8
- 239000005056 polyisocyanate Substances 0.000 claims description 8
- 229920001228 polyisocyanate Polymers 0.000 claims description 8
- 239000004923 Acrylic lacquer Substances 0.000 claims description 6
- 238000007605 air drying Methods 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 238000007790 scraping Methods 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 5
- -1 ester compound Chemical class 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- 230000008030 elimination Effects 0.000 claims description 4
- 238000003379 elimination reaction Methods 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 238000003854 Surface Print Methods 0.000 claims description 2
- 238000006748 scratching Methods 0.000 abstract 1
- 230000002393 scratching effect Effects 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 229920000805 Polyaspartic acid Polymers 0.000 description 5
- 239000011094 fiberboard Substances 0.000 description 5
- 108010064470 polyaspartate Proteins 0.000 description 5
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 4
- 238000010422 painting Methods 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241000432767 Asparagus setaceus Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229940074869 marquis Drugs 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Images
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to planar decoration, and discloses an aspartame polyurea surface decorative layer, which comprises an aspartame polyurea white matt paint layer, a picture layer and an aspartame polyurea protection layer which are sequentially coated on a substrate surface needing to be decorated. The invention also discloses a construction method of the surface decorative layer. The construction method comprises the following steps of: (1) surface treatment; (3) spraying of the aspartame polyurea white matt paint layer; (5) printing or copying of pictures; and (6) spraying of the protection layer. The decorative layer provided by the invention has the main advantages of high hardness, high brightness, high fullness, high weather resistance, high flexibility and high scratching resistance. The aspartame polyurea surface decorative layer is combined with a flatbed printer to process a decorative product applied to the outdoor. The problem that the outdoor decorative material is dull and monotone is solved, and the personalization is obvious.
Description
Technical field
The present invention relates to plane decoration, especially relate to a kind of asparagus fern polyureas surface decoration layer and construction method thereof.
Background technology
Furniture, billboard and decoration painting all need carry out surperficial paints and lacquers protection, are that UV class or acrylic compounds all can't resolve the anti-marquis's problem of surface paint but traditional handicraft uses, so receive very large limitation in the use.At first can not use and the open air; Secondly present paint all exists richness bad, influences attractive in appearance.Hardness is bad, and the bad product storage life that causes of scratch resistance is short, not durable; The 3rd because the more crisp product that just causes of paint back product is not suitable for cutting.
Poly-aspartic acid esters and suitable isocyanates such as the reaction of hexamethylene diisocyanate (HDI) tripolymer, filmed excellent wear-resisting property and hardness, ultraviolet aging resistance performance are one type of important asparagus fern polyureas macromolecular materials.But the reaction of amine terminated polyether and MDI semi-prepolymer has only the 5-45 gel time of second in the conventional spray paint asparagus fern SPUA (SPUA), must could construct with professional equipment; Compare with this kind situation; Poly-aspartic acid esters and HDI tripolymer reaction gel time can extend to more than 15 minutes; Like Bayer poly-aspartic acid esters NH1420 and the reaction of HDI tripolymer, gel time is at 15-20min, and Bayer poly-aspartic acid esters NH1520 gel time is more than 120min; Need not the professional equipment construction, make manual brushing or conventional spraying become possibility.But the gel time of NH1420 resin 15-20min can't use in the conventional urethane paint field for the pot-life of 3-4h polyurethane coating.Though NH-1520 has sufficiently long pot-life, because of it costs an arm and a leg, and the Tg vitrification point is high, has serious cold short phenomenon, and the acrylic resin of the toughness of must arranging in pairs or groups is very limited its scope of application.
Summary of the invention
In order to overcome shortcoming of the prior art, the object of the invention is to provide a kind of high hard, Gao Liang, high plentiful, Gao Naihou, high pliable and tough, high anti-asparagus fern polyureas surface decoration layer of scraping and can carry out cutting.
The objective of the invention is to realize that a kind of asparagus fern polyureas surface decoration layer comprises the white low luster coating layer of asparagus fern polyureas, image layers, the asparagus fern polyureas protective layer that are coated on the matrix surface that needs to decorate successively through following technical measures.
As a kind of optimal way, also be provided with the image basic unit of solidifying image between white low luster coating layer of said asparagus fern polyureas and the image layers.
Concrete, image basic unit of institute is an one pack system acrylic lacquer layer.
If said matrix is to comprise the bad materials of surface attachment such as glass, ceramic tile and metal, also have additional the epoxy paint layer that one deck is used to increase surface attachment between the white low luster coating layer of said matrix surface and asparagus fern polyureas.
Concrete, said asparagus fern polyureas protective layer comprises asparagus fern polyureas layer of varnish and/or asparagus fern polyureas matte varnish layer.
The invention also discloses and be used for the above-mentioned white low luster coating layer of arbitrary surface decoration layer asparagus fern polyureas or/and the aggretion type modification poly-aspartic ester compound of asparagus fern polyureas protective layer, it has following general structure:
, wherein
R is the alkyl of 10 or 10 following carbon atoms,
Y is polyisocyanates or the performed polymer that contains polyisocyanates,
X is the carbon-chain structure of straight chain or ring-type.
The invention also discloses the construction method of above-mentioned surface decoration layer, it comprises the steps:
(1), surface treatment: the matrix surface that will decorate polishes, cleans, dry, impurity elimination is handled;
(3), the white low luster coating layer of spraying asparagus fern polyureas: at the white low luster coating of the surface in last step spraying asparagus fern polyureas, thickness was 0.2～0.6mm, 50 minutes air drying time;
(5), printing or printed images: at surface printing or the printed patterns or the color as required in a last step;
(6), spraying protective layer: at image layers surface one or more layers asparagus fern polyureas layer of varnish of spraying and/or asparagus fern polyureas matte varnish layer, be used to increase surperficial resistance to scraping, protective layer thickness was 0.2～0.8mm, 10 hours air drying time.
In order to increase the adhesion effect on surfaces such as bad material of surface attachment such as glass, ceramic tile, metal; Also be provided with step (2), spraying adhesion layer between step (1) and the step (3): in the bad material surface spraying one deck epoxy paint layer of surface adhesion force; Be used to increase the surface attachment effect; The adhesion layer coating layer thickness is 0.2～0.8mm, 50 degrees centigrade of 4 hours drying times;
In order to make image layers in following process, do not drawn flower, also be provided with step (4) between step (3) and the step (5), apply image basic unit: apply one deck one pack system acrylic lacquer layer at the white low luster coating laminar surface of asparagus fern polyureas.
The present invention adopts percentage elongation, mechanical strength, hardness ratio poly-aspartic acid esters monomer better, a kind of macromolecular aggretion type modification asparatate ester compounds of the big leap ahead of gel time as the white low luster coating layer of asparagus fern polyureas in the surface decoration layer or/and the raw material of asparagus fern polyureas protective layer.Thereby gel time is prolonged, and surface drying time shortens; Thereby having solved traditional handicraft, to be to use the UV class still be the surface paint weatherability problem that acrylic compounds all can't resolve.Main characteristics of the present invention is high hard, and Gao Liang is high plentiful, and Gao Naihou is high pliable and tough, high anti-scraping.The present invention combines flat-panel printer to use, and can process and can be applied to outdoor decorative product.Solved the present situation of the stiff dullness of outdoor decoration material, outstanding personalized.The machinable sheet material of the present invention comprises: wood-block (solid wood, glued board, density board) sheet metal (iron, aluminium, copper ...) plastic plate (ABS, PC, PE, PP, PVC ...) cement products, ceramic tile, glass etc.
Description of drawings
Fig. 1 is the layer structural representation of the embodiment of the invention 1;
Fig. 2 is the layer structural representation of the embodiment of the invention 2.
The specific embodiment
Below in conjunction with embodiment and contrast accompanying drawing the present invention is done further explain.
Like Fig. 1, a kind of glass drawing board with asparagus fern polyureas surface decoration layer, its construction procedure is following:
(1), surface treatment: glass plate 1 cleaning surfaces, drying, impurity elimination are handled;
(2), spraying adhesion layer: in glass pane surface spraying one deck epoxy paint layer 2, be used to increase the surface attachment effect, the adhesion layer coating layer thickness was 0.2～0.8mm, is 0.7mm in the present embodiment, 4 hours 50 degrees centigrade of drying times;
(3), the white low luster coating layer 3 of spraying asparagus fern polyureas: at the white low luster coating of the surface in last step spraying asparagus fern polyureas, thickness was 0.2～0.6mm, is 0.5mm in the present embodiment, 50 minutes air drying time;
(4), apply image basic unit: at the very thin one deck one pack system of white low luster coating layer 3 surface-coated of asparagus fern polyureas acrylic lacquer layer 4;
(5), printing or printed images: the image-based laminar surface as required screen printing pattern become image layers 5;
(6), spraying protective layer: at image layers 5 surface spraying one deck asparagus fern polyureas layer of varnish 6, be used to increase surperficial resistance to scraping, protective layer thickness is 0.2～0.8mm, be 0.6mm in the present embodiment, polishes after dry 10 hours at normal temperatures.
The asparagus fern polyurea compound is an aggretion type modification poly-aspartic ester compound in the white low luster coating layer of asparagus fern polyureas of above-mentioned glass drawing board and asparagus fern polyureas layer of varnish, and it has following general structure:
, wherein
R is the alkyl of 10 or 10 following carbon atoms,
Y is polyisocyanates or the performed polymer that contains polyisocyanates,
X is the carbon-chain structure of straight chain or ring-type.
The technical indicator of above-mentioned glass drawing board decorative layer: (final products effect)
1) surface drying time 30---60 minute;
2) do solid work the polishing of 10 hours time;
3) hardness: H-12 hour, 2H-36 hour, 3H was above after-30 days, the highlyest can reach 5H;
4) lustrous surface can directly be regulated 0～105 greater than 100 degree;
5) abrasion resistance index is that loss is less than 20 milligrams under 750 gram forces 500 change;
6) UV resistant index: do not have obvious xanthochromia in 4500 hours.
Like Fig. 2, a kind of middle fiberboard decoration painting with asparagus fern polyureas surface decoration layer that can carry out cutting, its construction procedure is following:
(1), surface treatment: middle fiberboard 10 surface rubbings, cleaning, drying, impurity elimination are handled;
(3), the white low luster coating layer 13 of spraying asparagus fern polyureas: at the white low luster coating of middle fiberboard 10 surface spraying asparagus fern polyureas, thickness was 0.2～0.6mm, is 0.4mm in the present embodiment, 50 minutes air drying time;
(4), apply image basic unit: at the very thin one deck one pack system of white low luster coating layer 13 surface-coated of asparagus fern polyureas acrylic lacquer layer 14;
(5), print image: become image layers 15 with the flat-panel printer print pattern as required at the image-based laminar surface;
(6), spraying protective layer: at image layers 15 surface spraying one deck asparagus fern polyureas layer of varnish 16; Spray one deck asparagus fern polyureas matte varnish layer 17 again on asparagus fern polyureas layer of varnish 16 surfaces; Be used to increase surperficial resistance to scraping; Protective layer thickness is 0.2～0.8mm, is 0.8mm in the present embodiment, polish after dry 10 hours at normal temperatures.
The asparagus fern polyurea compound is an aggretion type modification poly-aspartic ester compound in white low luster coating layer of the asparagus fern polyureas of fiberboard decoration painting and the asparagus fern polyureas layer of varnish in above-mentioned, and it has following general structure:
, wherein
R is the alkyl of 10 or 10 following carbon atoms,
Y is polyisocyanates or the performed polymer that contains polyisocyanates,
X is the carbon-chain structure of straight chain or ring-type.
The technical indicator of fiberboard decoration painting in above-mentioned: (final products effect)
1) surface drying time 30---60 minute;
2) do solid work the polishing of 10 hours time;
3) hardness: H-12 hour, 2H-36 hour, 3H was above after-30 days, the highlyest can reach 5H;
4) lustrous surface can directly be regulated 0～105 greater than 100 degree;
5) abrasion resistance index is that loss is less than 20 milligrams under 750 gram forces 500 change;
6) pliability: allow the no vestige of 180 degree bendings;
7) UV resistant index: do not have obvious xanthochromia in 4500 hours.
More than be that asparagus fern polyureas surface decoration layer of the present invention is set forth; Be used for helping to understand the present invention; But embodiment of the present invention is not restricted to the described embodiments; Any change that does not deviate under the principle of the invention to be done, modification, substitute, combination, simplify, all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (10)
1. an asparagus fern polyureas surface decoration layer is characterized in that: comprise the white low luster coating layer of asparagus fern polyureas, image layers, the asparagus fern polyureas protective layer that are coated on the matrix surface that needs decoration successively.
2. asparagus fern polyureas surface decoration layer according to claim 1 is characterized in that: also be provided with the image basic unit of solidifying image between white low luster coating layer of said asparagus fern polyureas and the image layers.
3. asparagus fern polyureas surface decoration layer according to claim 2 is characterized in that: image basic unit of institute is an one pack system acrylic lacquer layer.
4. according to claim 1 or 2 or 3 described asparagus fern polyureas surface decoration layers, it is characterized in that: said matrix is for comprising glass, ceramic tile and metal.
5. asparagus fern polyureas surface decoration layer according to claim 4 is characterized in that: have additional the epoxy paint layer that one deck is used to increase surface attachment between the white low luster coating layer of said matrix surface and asparagus fern polyureas.
6. according to claim 1 or 2 or 3 or 5 described asparagus fern polyureas surface decoration layers, it is characterized in that: said asparagus fern polyureas protective layer comprises asparagus fern polyureas layer of varnish and/or asparagus fern polyureas matte varnish layer.
7. one kind is used for like the described white low luster coating layer of arbitrary surface decoration layer asparagus fern polyureas of claim 1 to 6 or/and the aggretion type modification poly-aspartic ester compound of asparagus fern polyureas protective layer is characterized in that having following general structure:
, wherein
R is the alkyl of 10 or 10 following carbon atoms,
Y is polyisocyanates or the performed polymer that contains polyisocyanates,
X is the carbon-chain structure of straight chain or ring-type.
8. the construction method like the described arbitrary surface decoration layer of claim 1 to 6 is characterized in that comprising the steps:
(1), surface treatment: the matrix surface that will decorate polishes, cleans, dry, impurity elimination is handled;
(3), the white low luster coating layer of spraying asparagus fern polyureas: at the white low luster coating of the surface in last step spraying asparagus fern polyureas, thickness was 0.2～0.6mm, 50 minutes air drying time;
(5), printing or printed images: at surface printing or the printed patterns or the color as required in a last step;
(6), spraying protective layer: at image layers surface one or more layers asparagus fern polyureas layer of varnish of spraying and/or asparagus fern polyureas matte varnish layer, be used to increase surperficial resistance to scraping, protective layer thickness was 0.2～0.8mm, 10 hours air drying time.
9. construction method according to claim 8; It is characterized in that also being provided with step (2), spraying adhesion layer between step (1) and the step (3): in the bad material surface spraying one deck epoxy paint layer of surface adhesion force; Be used to increase the surface attachment effect; The adhesion layer coating layer thickness is 0.2～0.8mm, 50 degrees centigrade of 4 hours drying times.
10. according to Claim 8 or 9 described construction methods; It is characterized in that also being provided with between step (3) and the step (5) step (4), apply image basic unit: apply one deck one pack system acrylic lacquer layer at the white low luster coating laminar surface of asparagus fern polyureas, make image layers in following process, do not drawn flower.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103099768A CN102806809A (en) | 2012-08-28 | 2012-08-28 | Aspartame polyurea surface decorative layer and construction method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103099768A CN102806809A (en) | 2012-08-28 | 2012-08-28 | Aspartame polyurea surface decorative layer and construction method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102806809A true CN102806809A (en) | 2012-12-05 |
Family
ID=47230748
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103099768A Pending CN102806809A (en) | 2012-08-28 | 2012-08-28 | Aspartame polyurea surface decorative layer and construction method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102806809A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104108274A (en) * | 2013-04-22 | 2014-10-22 | 陶源 | Sintering-free ceramic color painting |
| CN105542640A (en) * | 2016-02-22 | 2016-05-04 | 江苏苏博特新材料股份有限公司 | Preparation method of one-component polyaspartic ester finishing paint |
| CN110396053A (en) * | 2019-07-30 | 2019-11-01 | 深圳市前海博扬研究院有限公司 | Asparagus fern polyureas performed polymer and preparation method and a kind of coating |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101024618A (en) * | 2007-02-12 | 2007-08-29 | 江苏省化工研究所有限公司 | Method for preparing aspartate |
| WO2009003596A1 (en) * | 2007-07-03 | 2009-01-08 | Bayer Materialscience Ag | Medical adhesives for surgery |
| CN101812267A (en) * | 2010-05-24 | 2010-08-25 | 唐山市思远涂料有限公司 | Antistatic, heat-insulating and corrosion-resistance coating |
| CN201649553U (en) * | 2010-01-08 | 2010-11-24 | 于俊 | Imaged floor coating structure |
| WO2011041288A1 (en) * | 2009-09-29 | 2011-04-07 | Ppg Industries Ohio, Inc. | Substrates coated with clear polyurea film-forming compositions |
| CN102391771A (en) * | 2011-10-14 | 2012-03-28 | 洛阳七维防腐工程材料有限公司 | Thick paste quick-drying type weather-resistant and wear-resistant coating for wind turbine blades and preparation method thereof |
-
2012
- 2012-08-28 CN CN2012103099768A patent/CN102806809A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101024618A (en) * | 2007-02-12 | 2007-08-29 | 江苏省化工研究所有限公司 | Method for preparing aspartate |
| WO2009003596A1 (en) * | 2007-07-03 | 2009-01-08 | Bayer Materialscience Ag | Medical adhesives for surgery |
| WO2011041288A1 (en) * | 2009-09-29 | 2011-04-07 | Ppg Industries Ohio, Inc. | Substrates coated with clear polyurea film-forming compositions |
| CN201649553U (en) * | 2010-01-08 | 2010-11-24 | 于俊 | Imaged floor coating structure |
| CN101812267A (en) * | 2010-05-24 | 2010-08-25 | 唐山市思远涂料有限公司 | Antistatic, heat-insulating and corrosion-resistance coating |
| CN102391771A (en) * | 2011-10-14 | 2012-03-28 | 洛阳七维防腐工程材料有限公司 | Thick paste quick-drying type weather-resistant and wear-resistant coating for wind turbine blades and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104108274A (en) * | 2013-04-22 | 2014-10-22 | 陶源 | Sintering-free ceramic color painting |
| CN105542640A (en) * | 2016-02-22 | 2016-05-04 | 江苏苏博特新材料股份有限公司 | Preparation method of one-component polyaspartic ester finishing paint |
| CN110396053A (en) * | 2019-07-30 | 2019-11-01 | 深圳市前海博扬研究院有限公司 | Asparagus fern polyureas performed polymer and preparation method and a kind of coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1704049B1 (en) | Textured screen-printed laminates | |
| TWI631020B (en) | In-mold transcription film including elastic texture and method for manufacturing the same | |
| CN101469247A (en) | Bicomponent polyurethane coating composition, preparation and coating method thereof | |
| US10280333B2 (en) | Coating compositions | |
| CN104530930B (en) | Orange-peel coating | |
| CN108300277B (en) | 3D laser etching high-flexibility UV type PVD finish paint | |
| CN107249871A (en) | Vacuum forming three-dimensionally shaped product decoration laminated film, its manufacture method and three-dimensionally shaped product trailing | |
| KR101964094B1 (en) | Matt coating composition, matt coating sheet and the manufacturing method of the same | |
| CN101787229A (en) | Spraying type ultraviolet cured woodware varnish | |
| WO2014051112A1 (en) | Hydraulic transfer film and method for manufacturing decorated molded article using same | |
| WO2009029432A3 (en) | Process of powder coating aluminium substrates | |
| CN110643270A (en) | Heat-curable coating agent, cured product, and film | |
| CN110774790A (en) | Antibacterial corrosion-resistant heat transfer printing film and production process thereof | |
| JP4807300B2 (en) | Decorative sheet | |
| CN102806809A (en) | Aspartame polyurea surface decorative layer and construction method | |
| CN202806162U (en) | Radix asparagi polyurea surface decoration layer | |
| JP7777918B2 (en) | Film and manufacturing method thereof | |
| KR101382432B1 (en) | Colored steelsheet with superior clarity and manufacturing method thereof | |
| KR101516328B1 (en) | composition of paint for preventing attachment of advertisement material and adhesion method thereof | |
| CN111332056A (en) | Antibacterial corrosion-resistant heat transfer printing film and production process thereof | |
| WO2011126333A2 (en) | Multilayer sheet for molding which is highly glossy even after a molding process, and method for preparing same | |
| CN115873287B (en) | Interior film | |
| CN101935475A (en) | UV curable plastic paint | |
| JP6094124B2 (en) | Hydraulic transfer film and method for producing decorative molded product using the same | |
| CN119546715A (en) | Coating composition and in-mold coating method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20121205 |