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CN102703252A - Hydrocarbon cleaning agent with surface activity - Google Patents

Hydrocarbon cleaning agent with surface activity Download PDF

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Publication number
CN102703252A
CN102703252A CN201210118630XA CN201210118630A CN102703252A CN 102703252 A CN102703252 A CN 102703252A CN 201210118630X A CN201210118630X A CN 201210118630XA CN 201210118630 A CN201210118630 A CN 201210118630A CN 102703252 A CN102703252 A CN 102703252A
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CN
China
Prior art keywords
carbon hydrogen
hydrogen detergent
cleaning agent
agent
active agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201210118630XA
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Chinese (zh)
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CN102703252B (en
Inventor
肖连庄
林再发
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Sunglobe Cleaning Technology Co ltd
Original Assignee
DONGGUAN XINQIU WASH TECHNOLOGY CO LTD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DONGGUAN XINQIU WASH TECHNOLOGY CO LTD filed Critical DONGGUAN XINQIU WASH TECHNOLOGY CO LTD
Priority to CN 201210118630 priority Critical patent/CN102703252B/en
Publication of CN102703252A publication Critical patent/CN102703252A/en
Application granted granted Critical
Publication of CN102703252B publication Critical patent/CN102703252B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The invention provides a hydrocarbon cleaning agent with surface activity, which comprises the following components in parts by weight: 48-80% of hydrocarbon cleaning agent, 8-40% of oleic acid, 6-25% of triisopropanolamine and 6-20% of fatty alcohol polyoxyethylene ether phosphate. The hydrocarbon cleaning agent with surface activity has the characteristics that triisopropanolamine and oleic acid are added to the hydrocarbon solvent, hydroxy in the oleic acid molecule is substituted by amino in the triisopropanolamine molecule under certain conditions to generate amide type surfactant, fatty alcohol polyoxyethylene ether phosphate is used for solubilizing the amide type surfactant in the hydrocarbon solvent, and thus the hydrocarbon cleaning agent has surface activity; therefore, the dissolving capacity of the hydrocarbon cleaning agent to polar substances is enhanced, and the hydrocarbon cleaning agent can form an emulsion solution with water and can be removed by simply washing with water; the hydrocarbon cleaning agent can be used as a multifunctional cleaning agent for removing wax, removing rosin, degumming and the like; and the energy consumption is reduced, a water-based cleaning agent is not needed, the hydrocarbon cleaning agent can be well emulsified by water to achieve the removal purpose, and the cost is saved.

Description

A kind of have a surface-active agent for carbon hydrogen detergent
Technical field
The present invention relates to the clean-out system technical field, particularly, relate to a kind of surface-active agent for carbon hydrogen detergent that has.
Background technology
In the industrial cleaning agent field, halohydrocarbon clean-out system such as trichloroethane, meeting such as trichloromethane methyl bromofom ODS has bigger toxicity and corrodibility, thereby environment and human health is caused bigger destruction.For this reason, the carbon hydrocarbon clean-out system of alternative halohydrocarbon clean-out system has also been developed in the enhancing of Along with people's environmental consciousness.Like application number is that 200810053280.7 patent of invention discloses a kind of Environmental Safety property agent for carbon hydrogen detergent; Clean-out system is made up of at 140-200 ℃ positive structure or isoparaffin 2-4 kind boiling range; It is strong to wash down ability, and thing is residual, and the ozone layer destroying coefficient is zero; To environment and body harmless, alternative halohydrocarbon clean-out system.
It is 201010128398.9 patent of invention that the applicant also applies on March 7th, 2010 application number application number; This patent discloses a kind of modification agent for carbon hydrogen detergent: in agent for carbon hydrogen detergent, add additive; Agent for carbon hydrogen detergent comprises that taking off aromatic hydrocarbon solvent, low aromatic hydrocarbon solvent, carbonatoms is 10~13 normal paraffin or isoparaffin; Promptly in usually said agent for carbon hydrogen detergent D40, D60, D65, D80 and agent for carbon hydrogen detergent C10, C11, C12, C13, add part alcohols additive, ester class additive and ether additive; Make agent for carbon hydrogen detergent after the modification not only cleaning force be strong, KB value height, aniline point be low; Can clean polymer pollutents such as wax, resin, printing ink, rosin, and with low cost.
Yet the application finds that in actual use it mainly is alkane derivative that the agent for carbon hydrogen detergent composition constitutes, and this clean-out system belongs to non-polar compound, and mineral substance wet goods apolar substance is had good solvability, is usually used in the process of metal working smeary and cleans.But it is bigger to have smell, and volatilization not exclusively has the shortcoming of small amount of residual.After having cleaned, need to reach the purpose of removing agent for carbon hydrogen detergent, exist the energy consumption height, waste big shortcoming through oven dry or aqueous cleaning agent cleaning.
Summary of the invention
In order to solve the problems of the technologies described above; The invention provides a kind of surface-active agent for carbon hydrogen detergent that has; Through in hydrocarbon solvent, adding tri-isopropanolamine and oleic acid, the hydroxyl in the oleic acid molecular is replaced by the amino in the tri-isopropanolamine molecule and generates the acid amide type tensio-active agent under certain condition, and in hydrocarbon solvent, makes agent for carbon hydrogen detergent have surfactivity through the aliphatic alcohol polyoxyvinethene phosphate solubilising; Thereby both strengthened the dissolving power of agent for carbon hydrogen detergent to polar material; Can form emulsified soln with water well again, and can just get rid of agent for carbon hydrogen detergent with washing simply, reduce the burden of later process.
Technical scheme of the present invention is following: a kind of have a surface-active agent for carbon hydrogen detergent, comprises the each component of following weight part:
Agent for carbon hydrogen detergent 48-80%;
Oleic acid 8-40%;
Tri-isopropanolamine 6-25%;
Aliphatic alcohol polyoxyvinethene phosphate 6-20%.
Preferably, the each component that comprises following weight part:
Agent for carbon hydrogen detergent 50-70%;
Oleic acid 10-20%;
Tri-isopropanolamine 10-15%;
Aliphatic alcohol polyoxyvinethene phosphate 10-15%.
Said agent for carbon hydrogen detergent is for taking off the perfume compound solvent.
The said perfume compound solvent that takes off is selected from D30, D40, D60 (S), D80, the compsn of one or more among D110 or the D130.
Said agent for carbon hydrogen detergent is low aromatic hydrocarbon solvent.
Said agent for carbon hydrogen detergent is low aromatic hydrocarbon solvent.
Low aromatic hydrocarbon solvent is selected from DSP80, DSP100 or its compsn.
Said agent for carbon hydrogen detergent is that carbonatoms is the alkane of 10-13.
Said agent for carbon hydrogen detergent is that boiling range is 140~245 ℃ of normal paraffin solvents or isoparaffin solvent.
Said normal paraffin solvent is selected from heptane, octane, nonane or decane; Said isoparaffin solvent is selected from heptane isomers.
Said preparation method with surface-active agent for carbon hydrogen detergent mixes for by prescription weighing each component, gets final product.
Beneficial effect of the present invention is: according to the invention have surface-active agent for carbon hydrogen detergent and have very high surfactivity, can be used as at paraffin removal, removes rosin; Remove multifuctional cleaning agents such as glue; And can reduce energy consumption, remove aqueous cleaning agent from, directly water just can reach good emulsification agent for carbon hydrogen detergent; Reach the purpose of removal, practice thrift cost.
Embodiment
Embodiment 1:
A kind of have a surface-active agent for carbon hydrogen detergent, comprises each component of following weight part:
Agent for carbon hydrogen detergent 48%;
Oleic acid 40%;
Tri-isopropanolamine 6%;
Aliphatic alcohol polyoxyvinethene phosphate 6%.
Said agent for carbon hydrogen detergent is D40.
Embodiment 2:
A kind of have a surface-active agent for carbon hydrogen detergent, comprises each component of following weight part:
Agent for carbon hydrogen detergent 80%;
Oleic acid 8%;
Tri-isopropanolamine 6%;
Aliphatic alcohol polyoxyvinethene phosphate 6%.
Said agent for carbon hydrogen detergent is D65.
Embodiment 3:
A kind of have a surface-active agent for carbon hydrogen detergent, comprises each component of following weight part:
Agent for carbon hydrogen detergent 50%;
Oleic acid 20%;
Tri-isopropanolamine 15%;
Aliphatic alcohol polyoxyvinethene phosphate 15%.
Said agent for carbon hydrogen detergent is D60.
Embodiment 4:
A kind of have a surface-active agent for carbon hydrogen detergent, comprises each component of following weight part:
Agent for carbon hydrogen detergent 60%;
Oleic acid 20%;
Tri-isopropanolamine 14%;
Aliphatic alcohol polyoxyvinethene phosphate 6-%.
Said agent for carbon hydrogen detergent is C10.
Embodiment 5:
A kind of have a surface-active agent for carbon hydrogen detergent, comprises each component of following weight part:
Agent for carbon hydrogen detergent 70%;
Oleic acid 10%;
Tri-isopropanolamine 10%;
Aliphatic alcohol polyoxyvinethene phosphate 10%.
Said agent for carbon hydrogen detergent is C13.
Embodiment 6:
A kind of have a surface-active agent for carbon hydrogen detergent, comprises each component of following weight part:
Agent for carbon hydrogen detergent 50%;
Oleic acid 20%;
Tri-isopropanolamine 15%;
Aliphatic alcohol polyoxyvinethene phosphate 15%.
Said agent for carbon hydrogen detergent is 140~245 ℃ of normal paraffin solvents.
Embodiment 7:
A kind of have a surface-active agent for carbon hydrogen detergent, comprises each component of following weight part:
Agent for carbon hydrogen detergent 55%;
Oleic acid 20%;
Tri-isopropanolamine 10%;
Aliphatic alcohol polyoxyvinethene phosphate 15%.
Said agent for carbon hydrogen detergent is 140~245 ℃ of isoparaffin solvents.
The said preparation method with surface-active agent for carbon hydrogen detergent of embodiment 1-7 mixes for by prescription weighing each component, gets final product.Preparation embodiment 1-7 is said to have surface-active agent for carbon hydrogen detergent, and detects its performance, and data are following:
Project Data
Boiling range ℃ 145~226
Flash-point (remaining silent) ℃ 55
Aniline point ℃ 32
Surface tension (20 ℃)/(mN/m) 42
Moment of dipole (20 ℃)/(10-30C.m) 8.6
Dispersed (20 ℃)/% in the water 73
Above content is to combine concrete preferred implementation to the further explain that the present invention did, and can not assert that practical implementation of the present invention is confined to these explanations.For the those of ordinary skill of technical field under the present invention, under the prerequisite that does not break away from the present invention's design, its framework form can be flexible and changeable, can the subseries product.Just make some simple deduction or replace, all should be regarded as belonging to the scope of patent protection that the present invention is confirmed by claims of being submitted to.

Claims (9)

1. one kind has surface-active agent for carbon hydrogen detergent, it is characterized in that, comprises the each component of following weight part:
Agent for carbon hydrogen detergent 48-80%;
Oleic acid 8-40%;
Tri-isopropanolamine 6-25%;
Aliphatic alcohol polyoxyvinethene phosphate 6-20%.
2. as claimed in claim 1 have a surface-active agent for carbon hydrogen detergent, it is characterized in that, comprises the each component of following weight part:
Agent for carbon hydrogen detergent 50-70%;
Oleic acid 10-20%;
Tri-isopropanolamine 10-15%;
Aliphatic alcohol polyoxyvinethene phosphate 10-15%.
3. as claimed in claim 1 have a surface-active agent for carbon hydrogen detergent, it is characterized in that said agent for carbon hydrogen detergent is for taking off the perfume compound solvent.
4. as claimed in claim 3 have a surface-active agent for carbon hydrogen detergent, it is characterized in that the said perfume compound solvent that takes off is selected from D30, D40, D60 (S), D80, the compsn of one or more among D110 or the D130.
5. as claimed in claim 1 have a surface-active agent for carbon hydrogen detergent, it is characterized in that, said agent for carbon hydrogen detergent is low aromatic hydrocarbon solvent.
6. as claimed in claim 5 have a surface-active agent for carbon hydrogen detergent, it is characterized in that low aromatic hydrocarbon solvent is selected from DSP80, DSP100 or its compsn.
7. as claimed in claim 1 have a surface-active agent for carbon hydrogen detergent, it is characterized in that said agent for carbon hydrogen detergent is that carbonatoms is the alkane of 10-13.
8. as claimed in claim 1 have a surface-active agent for carbon hydrogen detergent, it is characterized in that said agent for carbon hydrogen detergent is that boiling range is 140~245 ℃ of normal paraffin solvents or isoparaffin solvent.
9. as claimed in claim 8 have a surface-active agent for carbon hydrogen detergent, it is characterized in that said normal paraffin solvent is selected from heptane, octane, nonane or decane; Said isoparaffin solvent is selected from heptane isomers.
CN 201210118630 2012-04-20 2012-04-20 Hydrocarbon cleaning agent with surface activity Expired - Fee Related CN102703252B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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CN102703252B CN102703252B (en) 2013-10-30

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103232903A (en) * 2013-04-28 2013-08-07 广西大学 Components of environment-friendly narrow-fraction hydrocarbon cleaning agent
CN103966034A (en) * 2014-05-26 2014-08-06 深圳市荣强科技有限公司 Surfactant for paraffin removal water and preparation method thereof
CN105297058A (en) * 2015-11-09 2016-02-03 广东新球清洗科技股份有限公司 Environment-friendly easily-rinsed easily-cleaned water draining agent and preparation method thereof and application
CN105316128A (en) * 2015-11-26 2016-02-10 广东新球清洗科技股份有限公司 Anti-static hydrocarbon cleaner
CN105969556A (en) * 2016-05-13 2016-09-28 北京九州柏林生物科技有限公司 Dewaxing decontamination agent
CN106118898A (en) * 2016-06-20 2016-11-16 苏州科斯曼照明工程有限公司 A kind of outdoor landscape lights surface clean Precerving liquid and preparation method thereof
CN107164127A (en) * 2017-06-05 2017-09-15 段钰 A kind of high-efficiency environment friendly cleaning agent
CN107190270A (en) * 2017-07-07 2017-09-22 苏州龙腾万里化工科技有限公司 A kind of environment-friendly type agent for carbon hydrogen detergent
CN108034506A (en) * 2017-12-30 2018-05-15 广州市白云化工实业有限公司 Seal gluing cleaning agent and preparation method thereof
CN108856116A (en) * 2018-07-13 2018-11-23 深圳市鑫承诺环保产业股份有限公司 A kind of anhydrous cleaning method of precision cutting tool
CN109266454A (en) * 2018-09-28 2019-01-25 东莞优诺电子焊接材料有限公司 A kind of cleaning agent and its preparation method and application of museum exhibit cabinet glass
CN109266456A (en) * 2018-08-03 2019-01-25 天津普罗米新材料有限公司 A kind of environment protection multifunctional agent for carbon hydrogen detergent
CN110042010A (en) * 2019-05-28 2019-07-23 马鞍山华之杰金属表面处理剂有限公司 A kind of environment protection type multifunctional agent for carbon hydrogen detergent and preparation method thereof
CN112010773A (en) * 2020-08-18 2020-12-01 深圳市辛骏翔科技有限公司 Dehydrating agent and preparation method thereof, and hydrocarbon water cutting agent and preparation method thereof
CN114164055A (en) * 2021-12-08 2022-03-11 安美科技股份有限公司 A kind of hydrocarbon degumming agent and preparation process thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1605619A (en) * 2003-10-12 2005-04-13 王忠恕 High-efficiency washing wax
CN101591590A (en) * 2008-05-28 2009-12-02 天津市华阳新兴科技有限公司 A kind of environmental protection and safety type hydrocarbon cleaning agent
CN102161941A (en) * 2011-03-14 2011-08-24 耿建 Environment-friendly hydrocarbon cleaning agent
CN102191141A (en) * 2010-03-17 2011-09-21 东莞市新球防锈有限公司 Modified hydrocarbon cleaning agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1605619A (en) * 2003-10-12 2005-04-13 王忠恕 High-efficiency washing wax
CN101591590A (en) * 2008-05-28 2009-12-02 天津市华阳新兴科技有限公司 A kind of environmental protection and safety type hydrocarbon cleaning agent
CN102191141A (en) * 2010-03-17 2011-09-21 东莞市新球防锈有限公司 Modified hydrocarbon cleaning agent
CN102161941A (en) * 2011-03-14 2011-08-24 耿建 Environment-friendly hydrocarbon cleaning agent

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103232903A (en) * 2013-04-28 2013-08-07 广西大学 Components of environment-friendly narrow-fraction hydrocarbon cleaning agent
CN103966034A (en) * 2014-05-26 2014-08-06 深圳市荣强科技有限公司 Surfactant for paraffin removal water and preparation method thereof
CN105297058A (en) * 2015-11-09 2016-02-03 广东新球清洗科技股份有限公司 Environment-friendly easily-rinsed easily-cleaned water draining agent and preparation method thereof and application
CN105316128A (en) * 2015-11-26 2016-02-10 广东新球清洗科技股份有限公司 Anti-static hydrocarbon cleaner
CN105969556B (en) * 2016-05-13 2018-11-30 北京九州柏林生物科技有限公司 Paraffin removal detergent
CN105969556A (en) * 2016-05-13 2016-09-28 北京九州柏林生物科技有限公司 Dewaxing decontamination agent
CN106118898A (en) * 2016-06-20 2016-11-16 苏州科斯曼照明工程有限公司 A kind of outdoor landscape lights surface clean Precerving liquid and preparation method thereof
CN107164127A (en) * 2017-06-05 2017-09-15 段钰 A kind of high-efficiency environment friendly cleaning agent
CN107190270A (en) * 2017-07-07 2017-09-22 苏州龙腾万里化工科技有限公司 A kind of environment-friendly type agent for carbon hydrogen detergent
CN108034506A (en) * 2017-12-30 2018-05-15 广州市白云化工实业有限公司 Seal gluing cleaning agent and preparation method thereof
CN108856116A (en) * 2018-07-13 2018-11-23 深圳市鑫承诺环保产业股份有限公司 A kind of anhydrous cleaning method of precision cutting tool
CN109266456A (en) * 2018-08-03 2019-01-25 天津普罗米新材料有限公司 A kind of environment protection multifunctional agent for carbon hydrogen detergent
CN109266454A (en) * 2018-09-28 2019-01-25 东莞优诺电子焊接材料有限公司 A kind of cleaning agent and its preparation method and application of museum exhibit cabinet glass
CN110042010A (en) * 2019-05-28 2019-07-23 马鞍山华之杰金属表面处理剂有限公司 A kind of environment protection type multifunctional agent for carbon hydrogen detergent and preparation method thereof
CN112010773A (en) * 2020-08-18 2020-12-01 深圳市辛骏翔科技有限公司 Dehydrating agent and preparation method thereof, and hydrocarbon water cutting agent and preparation method thereof
CN114164055A (en) * 2021-12-08 2022-03-11 安美科技股份有限公司 A kind of hydrocarbon degumming agent and preparation process thereof

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GR01 Patent grant
C56 Change in the name or address of the patentee
CP02 Change in the address of a patent holder

Address after: 523000 Guangdong city of Dongguan province at the Songshan Lake high tech Industrial Development Zone, Road No. 4 Keyuan pine building No. 16 layer

Patentee after: DONGGUAN XINQIU WASH TECHNOLOGY Co.,Ltd.

Address before: 523000 Guangdong province Dongguan City Xiegang town south of the village of Golden Sun Industrial City Star Technology Industrial Park, Dongguan new ball cleaning technology Co. Ltd.

Patentee before: Dongguan Xinqiu Wash Technology Co.,Ltd.

C56 Change in the name or address of the patentee
CP03 Change of name, title or address

Address after: 523808 Guangdong city of Dongguan province at the Songshan Lake high tech Industrial Development Zone, Road No. 4 Keyuan pine building No. 16 layer

Patentee after: GUANGDONG SUNGLOBE CLEANING TECHNOLOGY Co.,Ltd.

Address before: 523000 Guangdong city of Dongguan province at the Songshan Lake high tech Industrial Development Zone, Road No. 4 Keyuan pine building No. 16 layer

Patentee before: Dongguan Xinqiu Wash Technology Co.,Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20131030