CN102701856B - Fertilizer produced by using coal special for humic acid desertification control - Google Patents
Fertilizer produced by using coal special for humic acid desertification control Download PDFInfo
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- CN102701856B CN102701856B CN201210192627.2A CN201210192627A CN102701856B CN 102701856 B CN102701856 B CN 102701856B CN 201210192627 A CN201210192627 A CN 201210192627A CN 102701856 B CN102701856 B CN 102701856B
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- humic acids
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- 239000004021 humic acid Substances 0.000 title claims abstract description 23
- 239000003337 fertilizer Substances 0.000 title claims abstract description 22
- 239000003245 coal Substances 0.000 title claims abstract description 15
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title abstract 3
- 238000003756 stirring Methods 0.000 claims abstract description 19
- YNWVFADWVLCOPU-MDWZMJQESA-N (1E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol Chemical compound C1=NC=NN1/C(C(O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MDWZMJQESA-N 0.000 claims abstract description 13
- RMOGWMIKYWRTKW-UONOGXRCSA-N (S,S)-paclobutrazol Chemical compound C([C@@H]([C@@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1 RMOGWMIKYWRTKW-UONOGXRCSA-N 0.000 claims abstract description 13
- 239000005985 Paclobutrazol Substances 0.000 claims abstract description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000000376 reactant Substances 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 230000008569 process Effects 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 5
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 4
- 239000003415 peat Substances 0.000 claims description 14
- 241000195940 Bryophyta Species 0.000 claims description 13
- 239000002817 coal dust Substances 0.000 claims description 10
- 241000196324 Embryophyta Species 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 239000003077 lignite Substances 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 4
- 230000003179 granulation Effects 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 235000015320 potassium carbonate Nutrition 0.000 claims description 3
- 230000006872 improvement Effects 0.000 abstract description 7
- 238000000605 extraction Methods 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 4
- 238000003912 environmental pollution Methods 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 3
- 244000025254 Cannabis sativa Species 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 229910000388 diammonium phosphate Inorganic materials 0.000 abstract 1
- 235000019838 diammonium phosphate Nutrition 0.000 abstract 1
- 229910000027 potassium carbonate Inorganic materials 0.000 abstract 1
- 239000002689 soil Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- 208000035240 Disease Resistance Diseases 0.000 description 1
- 229920002683 Glycosaminoglycan Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 210000003097 mucus Anatomy 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000008121 plant development Effects 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 239000002688 soil aggregate Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention provides a fertilizer produced by using coal special for humic acid desertification control. The fertilizer comprise the following components in parts by weight: 0.04-0.07 part of uniconazole, 0.05-0.08 part of paclobutrazol, 10-25 parts of grass carbon and 100-120 parts of a humic acid reactant. The pH of the fertilizer is 6-8. A method for preparing the fertilizer comprises the following steps of: adding 100-120 kilograms of coal powder and 200-300 kilograms of water into a reaction kettle, and stirring; adding 3-8 kilograms of nitric acid into the reaction kettle; stirring, and heating to 55-65 DEG C; reacting for 60 minutes; adding 5-8 kilograms of sodium hydroxide or potassium carbonate; adding 10-15 kilograms of grass carbon, and stirring; heating to 70-85 DEG C; reacting for 60 minutes; adding 2-5 kilograms of diammonium hydrogen phosphate; stirring; adding remaining materials; and granulating. The fertilizer can be applied to improvement and treatment of land desertification, and has the advantages of easy and practical process, freeness from environmental pollution, low extraction cost, high raw material utilization ratio and high fertilizer utilization ratio.
Description
Technical field
The invention belongs to a kind of with coal production humic acids desertification treatment special fertilizer.
Background technology
Desertification of land problem is an important environmental problem of our times, and China is one of the most serious country of desertification of land harm in the world.According to statistics, China's desertification of land now still increases to be often close on the speed of ten thousand mu year by year.If actively do not adopt an effective measure control desertification of land, will constitute a serious threat to the mankind's living environment.Desertification of land area water resources is seriously deficient, and desertification soil quality is thick, leaks that fertile phenomenon is serious with Louing, has become and has affected the key constraints that China's desert is afforested.Therefore, how to improve the water utilization rate in soil desertification area, the fertilizer conservation water retention capacity that improves soil has become the key of dealing with problems.
Summary of the invention
The object of this invention is to provide a kind of coal production humic acids desertification treatment special fertilizer of using, can have features simple and practical process for improvement and the improvement of desertification of land, free from environmental pollution, extraction cost is low, raw material availability and the high advantage of fertilizer efficiency utilization ratio.
For this reason, a kind of with coal production humic acids desertification treatment special fertilizer,
The humic acids reactant of the peat composed of rotten mosses of the paclobutrazol of the uniconazole that it contains 0.04～0.07 weight part, 0.05～0.08 weight part, 10～25 weight parts, 100～120 weight parts;
Its pH is 6～8;
It is to consist of following technological process: select humic acids content more than 50%, the weathered coal that moisture is less than 30%, brown coal, be ground into 80～120 object coal dust ends, get coal dust end 100～120 kg, 200～300 kilograms, water joins in reactor and stirs, the nitric acid of 3～8 kilograms are joined in reactor, stir, heating, temperature is 55～65 ℃, react 60 minutes, make coal dust end fully be oxidized to the small organic molecule that plant easily absorbs, and then add sodium hydroxide or the salt of wormwood of 5～8 kilograms, add again the peat composed of rotten mosses of 10～15 kilograms to stir, be heated to 70～85 ℃, react 60 minutes, the Secondary ammonium phosphate that adds again 2～5 kilograms, stir, temperature 60 C, sealed reaction 20 minutes, reaction mass requires moisture content to be controlled at 30% left and right, pH is 6～8, then reenter the uniconazole of 0.04～0.07 kilogram, the paclobutrazol of 0.05～0.08 kilogram, mixing and stirring, then material is delivered to and in tablets press, carried out granulation with travelling belt, the particle transport of making is to drying machine drying, 55～60 ℃ of bake out temperatures, cooling, cooled particle is sieved, be divided into evengranular product, packing is finished product.
The humic acids reactant of the peat composed of rotten mosses of the paclobutrazol of the uniconazole that it contains 0.05～0.07 weight part, 0.05～0.07 weight part, 18～24 weight parts, 110～120 weight parts.
The humic acids reactant of the peat composed of rotten mosses of the paclobutrazol of the uniconazole that it contains 0.06 weight part, 0.07 weight part, 23 weight parts, 115 weight parts.
The present invention can have features simple and practical process for improvement and the improvement of desertification of land, and extraction cost is low, raw material availability and the high advantage of fertilizer efficiency utilization ratio.The method is simple and practical, free from environmental pollution, whole production process non-pollution discharge, and extraction cost is low, is only 50% of traditional method cost, and raw material availability is 100%.In the present invention, contain the required several mineral materials of plant and trace elements and plant growth regulator, be beneficial to the dark bundle of root system of plant development, accelerate plant tillering, before promoting, table well developed root system, is beneficial to the Revegetation in desert soil.The present invention is from weathered coal, brown coal, the effective constituent of extracting in peat can increase the water conservation of desert prone soil, fertilizer-preserving ability, the nutritive ingredient providing is increased substantially by the specific absorption of plant, fertilizer efficiency performance is permanent, can effectively improve Soil structure, reduce volume weight of soils, soil cell size is corresponding increase also, strengthened the permeability of soil, in addition the organic matter in fertilizer provides for microorganism good existence and breeding environment, in microorganism continual generation in soil, is separated process, produce a large amount of mucopolysaccharides, the useful meta-bolites that improves Soil structure such as polypeptide, mucus and mineral substance with plant secretion, organic colloid combines, form soil aggregate, promoted the fertilizer that holds of soil, water conservation, cold-resistant, disease resistance, insulated capacity, and then foster and apply fertilizer and recover soil fertility, thereby reduce and change the trend of global desertification.
Embodiment
Dryer of the present invention is roller dryer, and dryer is bought or self-control all can.
Embodiment 1: a kind of with coal production humic acids desertification treatment special fertilizer, the humic acids reactant of the paclobutrazol of the uniconazole that it contains 0.04～0.07 weight part, 0.05～0.08 weight part, the peat composed of rotten mosses of 10～25 weight parts, 100～120 weight parts; The peat composed of rotten mosses is plant ash, or plant corruption thing.Its pH is 6～8.
It is to consist of following technological process: select humic acids content more than 50%, the weathered coal that moisture is less than 30%, brown coal, be ground into 80～120 object coal dust ends, get coal dust end 100～120 kg, 200～300 kilograms, water joins in reactor and stirs, the nitric acid of 3～8 kilograms are joined in reactor, stir, heating, temperature is 55～65 ℃, react 60 minutes, make coal dust end fully be oxidized to the small organic molecule that plant easily absorbs, and then add sodium hydroxide or the salt of wormwood of 5～8 kilograms, add again the peat composed of rotten mosses of 10～15 kilograms to stir, be heated to 70～85 ℃, react 60 minutes, the Secondary ammonium phosphate that adds again 2～5 kilograms, stir, temperature 60 C, sealed reaction 20 minutes, reaction mass requires moisture content to be controlled at 30% left and right, pH is 6～8, then reenter the uniconazole of 0.04～0.07 kilogram, the paclobutrazol of 0.05～0.08 kilogram, mixing and stirring, again material is delivered to and in tablets press, carried out granulation with travelling belt, this technique without any need for binding agent get final product granulation, and the uniform particles of making, smooth, the particle transport of making is to drying machine drying, 55～60 ℃ of bake out temperatures, cooling, cooled particle is sieved, be divided into evengranular product, packing is finished product.Coal dust end refers to that humic acids content more than 50%, moisture are less than 30% weathered coal, the powder that brown coal powder is broken into.
Embodiment 2: as different from Example 1, and the humic acids reactant of the paclobutrazol of the uniconazole that it contains 0.05～0.07 weight part, 0.05～0.07 weight part, the peat composed of rotten mosses of 18～24 weight parts, 110～120 weight parts.All the other steps are identical, therefore be not repeated.
Embodiment 3: as different from Example 1, and the humic acids reactant of the paclobutrazol of the uniconazole that it contains 0.06 weight part, 0.07 weight part, the peat composed of rotten mosses of 23 weight parts, 115 weight parts.All the other steps are identical, therefore be not repeated.
In a word, the present invention can have features simple and practical process for improvement and the improvement of desertification of land, and free from environmental pollution, extraction cost is low, and raw material availability and the high advantage of fertilizer efficiency utilization ratio, can promote the use of.
Claims (2)
1. with a coal production humic acids desertification treatment special fertilizer, it is characterized in that:
The humic acids reactant of the peat composed of rotten mosses of the paclobutrazol of the uniconazole that it contains 0.04～0.07 weight part, 0.05～0.08 weight part, 10～25 weight parts, 100～120 weight parts;
Its pH is 6～8;
It is to consist of following technological process: select humic acids content more than 50%, the weathered coal that moisture is less than 30%, brown coal, be ground into 80～120 object coal dust ends, get coal dust end 100～120 kg, 200～300 kilograms, water joins in reactor and stirs, the nitric acid of 3～8 kilograms are joined in reactor, stir, heating, temperature is 55～65 ℃, react 60 minutes, make coal dust end fully be oxidized to the small organic molecule that plant easily absorbs, and then add sodium hydroxide or the salt of wormwood of 5～8 kilograms, add again the peat composed of rotten mosses of 10～25 kilograms to stir, be heated to 70～85 ℃, react 60 minutes, the Secondary ammonium phosphate that adds again 2～5 kilograms, stir, temperature 60 C, sealed reaction 20 minutes, reaction mass requires moisture content to be controlled at 30% left and right, pH is 6～8, then reenter the uniconazole of 0.04～0.07 kilogram, the paclobutrazol of 0.05～0.08 kilogram, mixing and stirring, then material is delivered to and in tablets press, carried out granulation with travelling belt, the particle transport of making is to drying machine drying, 55～60 ℃ of bake out temperatures, cooling, cooled particle is sieved, be divided into evengranular product, packing is finished product,
Or its uniconazole, the paclobutrazol of 0.05～0.07 weight part, humic acids reactant of the peat composed of rotten mosses of 18～24 weight parts, 110～120 weight parts of containing 0.05～0.07 weight part.
2. press described in claims 1 with coal production humic acids desertification treatment special fertilizer, it is characterized in that: the humic acids reactant of the paclobutrazol of the uniconazole that it contains 0.06 weight part, 0.07 weight part, the peat composed of rotten mosses of 23 weight parts, 115 weight parts.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210192627.2A CN102701856B (en) | 2012-06-13 | 2012-06-13 | Fertilizer produced by using coal special for humic acid desertification control |
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| CN201210192627.2A CN102701856B (en) | 2012-06-13 | 2012-06-13 | Fertilizer produced by using coal special for humic acid desertification control |
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| CN102701856A CN102701856A (en) | 2012-10-03 |
| CN102701856B true CN102701856B (en) | 2014-04-16 |
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| CN106278749A (en) * | 2016-08-29 | 2017-01-04 | 董栋 | A kind of basic material preparing high-activity biological fertilizer and the fertilizer made thereof |
| CN111253196A (en) * | 2020-02-04 | 2020-06-09 | 中化农业（临沂）研发中心有限公司 | Humic acid chelated medium and trace element fertilizer and preparation method thereof |
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| JP3119296B2 (en) * | 1996-07-31 | 2000-12-18 | 実孝 山本 | Citrus anti-icing agent and method for preventing icing with it |
| CN1181119C (en) * | 2002-07-16 | 2004-12-22 | 方宁 | Technology of producing sodium humate with coal |
| CN101177295B (en) * | 2007-11-05 | 2010-10-27 | 稷山县兴乡腐植酸肥业开发有限公司 | Special fertilizer for desert and desertification treatment and preparation method thereof |
| CN101550042A (en) * | 2009-05-07 | 2009-10-07 | 赵俊武 | Seedling strengthen agent |
| CN101967072B (en) * | 2010-08-11 | 2013-11-06 | 西北农林科技大学 | Organic-inorganic compound fertilizer |
| CN102239794B (en) * | 2011-04-13 | 2013-02-06 | 方宁 | Process for producing environmentally-friendly full-degradable liquid mulch film capable of turning into fertilizer by using coal humic acid |
| CN102181064B (en) * | 2011-04-13 | 2012-10-03 | 方宁 | Technology for producing high-purity humate by using coal |
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