CN102603215A - Preparation method of glass fiber film-forming agent - Google Patents
Preparation method of glass fiber film-forming agent Download PDFInfo
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- CN102603215A CN102603215A CN2012100725083A CN201210072508A CN102603215A CN 102603215 A CN102603215 A CN 102603215A CN 2012100725083 A CN2012100725083 A CN 2012100725083A CN 201210072508 A CN201210072508 A CN 201210072508A CN 102603215 A CN102603215 A CN 102603215A
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- Prior art keywords
- forming agent
- preparation
- glass fiber
- spun glass
- membrane
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 73
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 239000003365 glass fiber Substances 0.000 title abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 46
- 239000011347 resin Substances 0.000 claims abstract description 46
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 23
- 239000003960 organic solvent Substances 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011521 glass Substances 0.000 claims description 56
- 230000000694 effects Effects 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 11
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 9
- 238000010792 warming Methods 0.000 claims description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 7
- 150000002170 ethers Chemical class 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 3
- 125000000373 fatty alcohol group Chemical group 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 4
- 229920013636 polyphenyl ether polymer Polymers 0.000 abstract 6
- 238000000614 phase inversion technique Methods 0.000 abstract 1
- 238000010008 shearing Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 32
- 239000004721 Polyphenylene oxide Substances 0.000 description 17
- 229920006380 polyphenylene oxide Polymers 0.000 description 17
- 238000000034 method Methods 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 7
- 229920000647 polyepoxide Polymers 0.000 description 6
- 239000003822 epoxy resin Substances 0.000 description 5
- 239000011152 fibreglass Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 229920001955 polyphenylene ether Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000004434 industrial solvent Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a preparation method of a glass fiber film-forming agent. The preparation method comprises the following steps that: mixing polyphenyl ether and an organic solvent, increasing the temperature to 100 DEG C-105 DEG C to obtain resin solution; and adding an emulsifying agent in the resin solution, adding water under the high-speed shearing action, and utilizing a phase inversion method to prepare the glass fiber film-forming agent. Compared with the prior art, the preparation method utilizes the polyphenyl ether as a raw material to prepare the glass fiber film-forming agent for the first time, and the polyphenyl ether has the advantages of large rigidity, high heat resistance, fire retardance, higher strength, good electrical performance and the like so as to ensure that glass fiber utilizing the glass fiber film-forming agent has good mechanical property. Furthermore, the good interface binding force between the glass fiber utilizing the glass fiber film-forming agent and polyphenyl ether resin to be enhanced at the later stage can be ensured as the structure of the film forming agent which is prepared by taking the polyphenyl ether as the raw material is the same as that of the polyphenyl ether resin to be enhanced at the later stage.
Description
Technical field
The present invention relates to glass manufacturing technology field, more particularly, relate to a kind of preparation method of spun glass membrane-forming agent.
Background technology
Glass fiber infiltration agent is to be used for a kind of surface treatment agent that fiberglass surfacing applies, and is most important to the manufacturing of spun glass, determined the transaction capabilities and the performance of fiber in matrix material of fiber.Treating compound is to mix the polycomponent aqueous solution or the emulsion that forms by membrane-forming agent, coupling agent and static inhibitor etc., and ability effectively lubricating fiberglass surfacing makes spun glass smooth, soft, wear-resisting, and gives the later stage matrix material remarkable performance.The effect of treating compound mainly shows the following aspects: lubrication protection effect, bonding boundling effect, prevent the accumulation of fiberglass surfacing static charge and make spun glass obtain with the good consistency of base material etc.Under the effect of treating compound, fiberglass product has application performances such as ideal physicals, mechanical property, chemical property, electric property and ageing-resistant performance.
Membrane-forming agent is a most important component in the glass fiber treating compound, can form a kind of continuously uniform film with performances such as certain flexibility, extensibility and rub resistances on the glass surface, and the use properties that reaches the glass later stage is had important role.The membrane-forming agent that in spun glass, uses at present mainly is divided into four big types, comprises epoxies membrane-forming agent, polyester membrane-forming agent, polyurethanes membrane-forming agent and PVA class membrane-forming agent.Wherein, the epoxy resin membrane-forming agent is mainly small molecular weight epoxy resin membrane-forming agent, and high molecular expoxy resin is solid at normal temperatures; Fusing point is higher, the emulsification difficulty, and the organic solvent addition is bigger; Very harsh to emulsification condition and equipment requirements, thus limited its use; The synthesis technique of polyester membrane-forming agent is complicated, needs pyroreaction and production cycle long, and cost is higher, has limited the popularization of polyester membrane-forming agent; The expensive raw material price of polyurethanes membrane-forming agent, cost is too high, and range of application is also narrow; The molecular weight of PVA class membrane-forming agent is lower, be difficult for giving good stiffness of precursor and cutting property, and price is higher.
Ppe is the high-strength engineering plastic that grows up the sixties in 20th century; Chemical name is for gathering 2,6-dimethyl--1,4-phenylate; Be called for short PPO (Polyphenylene Oxide) or PPE (Polypheylene ether), be called polyphenylene oxide or polyhenylene ether again.Ppe not only has good physical and mechanical property, electric insulating quality and thermotolerance, and the creep resistant under its high temperature is better.Therefore, the inventor considers, is feedstock production spun glass membrane-forming agent with ppe, improves the mechanical property of the spun glass that uses this spun glass membrane-forming agent.
Summary of the invention
In view of this; The technical problem that the present invention will solve is to provide a kind of preparation method of spun glass membrane-forming agent; Use the spun glass and the back of this spun glass membrane-forming agent to expect between the enhanced polyphenylene oxide resin good interface bonding force is arranged, use the spun glass of this spun glass membrane-forming agent to have the good mechanical performance.
In order to solve above technical problem, the present invention provides a kind of preparation method of spun glass membrane-forming agent, may further comprise the steps:
Step a) is mixed ppe and organic solvent, is warming up to 100～105 ℃, obtains resin solution;
Step b) adds emulsifying agent in said resin solution, under the high speed shear effect, add entry, continues high speed shear and obtains the spun glass membrane-forming agent.
Preferably, said organic solvent is toluene, YLENE or propylene glycol monomethyl ether.
Preferably, the mass ratio of said ppe and organic solvent is 1: (0.1～0.5).
Preferably, said emulsifying agent is a Fatty Alcohol(C12-C14 and C12-C18) ethers emulsifying agent.
Preferably, the soaking time of said step a) is 3～5h.
Preferably, the said emulsifying agent that in resin solution, adds carries out under 90～100 ℃.
Preferably, the temperature of said water is 90～100 ℃.
Preferably, said step b) is specially:
Step b1) in said resin solution, adds emulsifying agent, obtain mixing solutions;
Step b2) in said mixing solutions, adding entry under the high speed shear effect, continuing high speed shear and obtain the spun glass membrane-forming agent.
Accordingly, the present invention also provides a kind of spun glass membrane-forming agent of technique scheme preparation.
Accordingly, the present invention also provides a kind of treating compound, comprises the described spun glass membrane-forming agent of technique scheme.
The present invention provides a kind of preparation method of spun glass membrane-forming agent, may further comprise the steps: ppe and organic solvent are mixed, be warming up to 100～105 ℃, obtain resin solution; In said resin solution, add emulsifying agent, under the high speed shear effect, add entry, continue high speed shear, utilize the phase reversion method to prepare the spun glass membrane-forming agent.Compared with prior art; The present invention is that feedstock production has obtained the spun glass membrane-forming agent first with ppe; Because advantages such as ppe has that rigidity is big, thermotolerance is high, difficult combustion, intensity is higher and electrical property is good, thereby guaranteed to use the spun glass of this spun glass membrane-forming agent to have the good mechanical performance.And; Owing to the membrane-forming agent that with ppe is feedstock production is structurally approaching with back expectation enhanced polyphenylene oxide resin, thereby guaranteed to use the spun glass of this spun glass membrane-forming agent and back to expect between the enhanced polyphenylene oxide resin good interface bonding force is arranged.
Embodiment
Carry out clear, intactly description in the face of the technical scheme in the embodiment of the invention down, obviously, described embodiment only is the present invention's part embodiment, rather than whole embodiment.Based on the embodiment among the present invention, those of ordinary skills are not making the every other embodiment that is obtained under the creative work prerequisite, all belong to the scope of the present invention's protection.
The invention discloses a kind of preparation method of spun glass membrane-forming agent, it is characterized in that, may further comprise the steps: step a) is mixed ppe and organic solvent, is warming up to 100～105 ℃, obtains resin solution; Step b) adds emulsifying agent in said resin solution, under the high speed shear effect, add entry, continues high speed shear, obtains the spun glass membrane-forming agent.
The present invention is with the raw material of ppe as preparation spun glass membrane-forming agent, and ppe (PPO) not only has good physical and mechanical property, electric insulating quality and thermotolerance, and the creep resistant under its high temperature is better.Ppe is the high-strength engineering plastic that grows up the sixties in 20th century, and chemical name is for gathering 2,6-dimethyl--1; The 4-phenylate; Be called for short PPO (Polyphenylene Oxide) or PPE (Polypheylene ether), be called polyphenylene oxide or polyhenylene ether again, structural formula is following:
In addition; The present invention does not have special restriction for the organic solvent that adopts; The organic solvent that can adopt the field personnel to know, the preferred employing and the good organic solvent of ppe consistency is like toluene, YLENE or propylene glycol monomethyl ether; More preferably adopt and the good environment-friendly type organic solvent of ppe consistency, most preferably be propylene glycol monomethyl ether (2-MP).Propylene glycol monomethyl ether is a kind of low toxicity advanced industrial solvent, and existing ehter bond in the molecule has carbonyl again, and carbonyl has formed the structure of ester again, contains alkyl simultaneously again.Therefore, propylene glycol monomethyl ether is existing nonpolar part in a part, and the polarity part is arranged again, and this two-part functional group both mutual restriction repels, and plays its inherent effect again separately, thereby apolar substance and polar material are all had very strong dissolving power.
Consider that from the properties of ppe the present invention is warming up to 100～105 ℃ with after ppe and the organic solvent mixing, is preferably 102～105 ℃, more preferably 105 ℃; Soaking time is preferably 3～5h, more preferably 5h.With ppe and solvent, ppe dissolves under this temperature, and forming heavy-gravity liquid is resin solution, has guaranteed that the phase reversion legal system is equipped with carrying out smoothly of spun glass membrane-forming agent.Simultaneously, the mass ratio of ppe and organic solvent is the important factor that influences the viscosity of resin solution, and then influences the final character of membrane-forming agent.The ppe that the present invention adopts and the mass ratio of organic solvent are preferably 1: (0.1～0.5), more preferably 1: (0.2～0.3), more preferably 1: 0.2.
After preparing resin solution, prepare the step of spun glass membrane-forming agent, said step b) is specially: step b1) in said resin solution, add emulsifying agent, obtain mixing solutions; Step b2) in said mixing solutions, adds entry under the high speed shear effect, continuing high speed shear, preparing the spun glass membrane-forming agent.
In preparation spun glass membrane-forming agent process, in the high speed shear process, realized phase reversion.The phase reversion method promptly becomes oil-in-water state with polymkeric substance from the water-in-oil state-transition through phase reversion; Be a kind of effective ways that prepare the macromolecule resin emulsion, can macromolecule resin be made corresponding emulsion by means of the effect that adds emulsifying agent and through physics emulsive method.For the present invention, because the fusing point of PPO resin is higher, even be heated to softening temperature; Resin also can be met cold moment and is transformed into arborescens, can't form flowability liquid preferably, therefore; The present invention adds emulsifying agent in said resin solution, adopt the emulsification of phase reversion method to the PPO resin.As preferably, the present invention adopts preferably that cloud point is higher, emulsifying capacity emulsifying agent, more preferably environment-friendly type Fatty Alcohol(C12-C14 and C12-C18) ethers emulsifying agent preferably.
According to the present invention, the said emulsifying agent that in resin solution, adds preferably carries out under 90～100 ℃, and more preferably 95～100 ℃, more preferably 95 ℃.Therefore, after step a) prepares resin solution, preferably lower the temperature, in said resin solution, add emulsifying agent after preferably reducing to 95 ℃.In addition, in the step b), the temperature of said water is preferably 90～100 ℃, and more preferably 95～100 ℃, more preferably 95 ℃.
In the prior art, polyurethanes membrane-forming agent and epoxy resin membrane-forming agent are two types of important membrane-forming agents, and it is-NHCOO-that epoxy resin has following structural formula that the primary structure of urethane contains ammonia ester bond:
Though urethane and epoxy resin all have stronger ehter bond of polarity and amine ester bond; The effect of certain bonding interface is arranged; But, when the spun glass that uses membrane-forming agent is used for the polyphenylene ether resin matrix and strengthens, according to the principle of similar compatibility; The glass surface IT when strengthening the PPO matrix resin of spun glass membrane-forming agent that is coated with the present invention preparation is littler, and binding ability is better.Experimental result shows; The spun glass polyphenylene ether resin matrix that utilization is coated with the spun glass membrane-forming agent of the present invention's preparation strengthens; The interface bonding of polyphenylene oxide resin matrix strengthens; Cushioned the impact of extraneous power to material, mechanical properties such as the stretching of material, bending, impact are greatly improved.
In sum; The present invention is that feedstock production has obtained the spun glass membrane-forming agent first with ppe; Because advantages such as ppe has that rigidity is big, thermotolerance is high, difficult combustion, intensity is higher and electrical property is good, thereby guaranteed to use the spun glass of this spun glass membrane-forming agent to have the good mechanical performance.And; Owing to the membrane-forming agent that with ppe is feedstock production is structurally approaching with back expectation enhanced polyphenylene oxide resin, thereby guaranteed to use the spun glass of this spun glass membrane-forming agent and back to expect between the enhanced polyphenylene oxide resin good interface bonding force is arranged.
In order to further specify technical scheme of the present invention; Below in conjunction with embodiment the preferred embodiment of the invention is described; Describe just to further specifying feature and advantage of the present invention but should be appreciated that these, rather than to the restriction of claim of the present invention.
The chemical reagent that the embodiment of the invention and comparative example adopt is commercial.
Embodiment 1
100g ppe and 50g propylene glycol monomethyl ether are mixed, be warming up to 105 ℃, insulation 5h, ppe dissolves fully, obtains resin solution;
In said resin solution, add 20g Fatty Alcohol(C12-C14 and C12-C18) ethers emulsifying agent, obtain mixing solutions;
At the water that in said mixing solutions, adds 90 ℃ of 25g under the high speed shear effect, take place to change the back mutually and stir, obtain the spun glass membrane-forming agent after the dilution.
Embodiment 2
100g ppe and 30g propylene glycol monomethyl ether are mixed, be warming up to 105 ℃, insulation 5h, ppe dissolves fully, obtains resin solution;
In said resin solution, add 10g Fatty Alcohol(C12-C14 and C12-C18) ethers emulsifying agent, obtain mixing solutions;
At the water that in said mixing solutions, adds 90 ℃ of 40g under the high speed shear effect, take place to change the back mutually and stir, obtain the spun glass membrane-forming agent after the dilution.
Embodiment 3
100g ppe and 20g propylene glycol monomethyl ether are mixed, be warming up to 105 ℃, insulation 5h, ppe dissolves fully, obtains resin solution;
In said resin solution, add 15g Fatty Alcohol(C12-C14 and C12-C18) ethers emulsifying agent, obtain mixing solutions;
At the water that in said mixing solutions, adds 90 ℃ of 30g under the high speed shear effect, take place to change the back mutually and stir, obtain the spun glass membrane-forming agent after the dilution.
Comparative example 1
With the epoxy of import and polyurethane film-forming agent as the spun glass membrane-forming agent.
The membrane-forming agent that provides with the embodiment of the invention and comparative example respectively is a raw material, adopts following method to prepare treating compound:
The membrane-forming agent that respectively the 11.2wt% embodiment of the invention 1～3 or comparative example 1 is provided, 0.8% coupling agent, 3% lubricant and the water of 85wt% mix, and obtain treating compound.
The treating compound of above-mentioned preparation is coated on fiberglass surfacing, obtains the spun glass after treating compound is handled, the glass fiber wire-drawing after treating compound is handled applies, and is used to strengthen matrix PPO resin then, obtains batten respectively.The batten of above-mentioned preparation is carried out mechanical property detects, then with batten in 90 ℃ water, the performance of then batten being boiled behind 500h, 1000h, 1500h, the 2000h detects.Table 1 is the performance test results of the batten of the membrane-forming agent preparation that provides with the embodiment of the invention 1 and comparative example 1.
The results of property of the batten that the membrane-forming agent that table 1 provides with the embodiment of the invention 1 and comparative example 1 prepares
Can find out from above-mentioned test result, the good mechanical properties of the batten of the membrane-forming agent preparation that provides with the embodiment of the invention 1, especially in water, boil certain hour after, mechanical property obviously is better than the batten of the membrane-forming agent preparation that comparative example 1 provides.
To the above-mentioned explanation of the disclosed embodiments, make this area professional and technical personnel can realize or use the present invention.Multiple modification to these embodiment will be conspicuous concerning those skilled in the art, and defined General Principle can realize under the situation that does not break away from the spirit or scope of the present invention in other embodiments among this paper.Therefore, the present invention will can not be restricted to these embodiment shown in this paper, but will meet and principle disclosed herein and features of novelty the wideest corresponding to scope.
Claims (10)
1. the preparation method of a spun glass membrane-forming agent is characterized in that, may further comprise the steps:
Step a) is mixed ppe and organic solvent, is warming up to 100～105 ℃, obtains resin solution;
Step b) adds emulsifying agent in said resin solution, under the high speed shear effect, add entry, continues high speed shear and obtains the spun glass membrane-forming agent.
2. preparation method according to claim 1 is characterized in that, said organic solvent is toluene, YLENE or propylene glycol monomethyl ether.
3. preparation method according to claim 1 is characterized in that, the mass ratio of said ppe and organic solvent is 1: (0.1～0.5).
4. preparation method according to claim 1 is characterized in that, said emulsifying agent is a Fatty Alcohol(C12-C14 and C12-C18) ethers emulsifying agent.
5. preparation method according to claim 1 is characterized in that, the soaking time of said step a) is 3～5h.
6. preparation method according to claim 1 is characterized in that, the said emulsifying agent that in resin solution, adds carries out under 90～100 ℃.
7. preparation method according to claim 1 is characterized in that, the temperature of said water is 90～100 ℃.
8. preparation method according to claim 1 is characterized in that, said step b) is specially:
Step b1) in said resin solution, adds emulsifying agent, obtain mixing solutions;
Step b2) in said mixing solutions, adding entry under the high speed shear effect, continuing high speed shear and obtain the spun glass membrane-forming agent.
9. the spun glass membrane-forming agent of any preparation of claim 1～8.
10. a treating compound comprises the described spun glass membrane-forming agent of claim 9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210072508.3A CN102603215B (en) | 2012-03-19 | 2012-03-19 | Preparation method of glass fiber film-forming agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210072508.3A CN102603215B (en) | 2012-03-19 | 2012-03-19 | Preparation method of glass fiber film-forming agent |
Publications (2)
| Publication Number | Publication Date |
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| CN102603215A true CN102603215A (en) | 2012-07-25 |
| CN102603215B CN102603215B (en) | 2014-11-05 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210072508.3A Active CN102603215B (en) | 2012-03-19 | 2012-03-19 | Preparation method of glass fiber film-forming agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12180337B2 (en) | 2019-08-20 | 2024-12-31 | Shpp Global Technologies B.V. | Poly (phenylene ether) based compatibilizing material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3476589A (en) * | 1965-10-22 | 1969-11-04 | Gen Electric | Glass fibers sized with polyphenylene oxide derivatives |
| JP2001261380A (en) * | 2000-03-21 | 2001-09-26 | Nippon Sheet Glass Co Ltd | Sizing agent for glass fiber and glass fiber strand sticking the same |
| CN1675427A (en) * | 2002-09-30 | 2005-09-28 | 上海宏联电子材料有限公司 | Sizing agent for glass fiber yarn and glass fiber yarn using the same |
-
2012
- 2012-03-19 CN CN201210072508.3A patent/CN102603215B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3476589A (en) * | 1965-10-22 | 1969-11-04 | Gen Electric | Glass fibers sized with polyphenylene oxide derivatives |
| JP2001261380A (en) * | 2000-03-21 | 2001-09-26 | Nippon Sheet Glass Co Ltd | Sizing agent for glass fiber and glass fiber strand sticking the same |
| CN1675427A (en) * | 2002-09-30 | 2005-09-28 | 上海宏联电子材料有限公司 | Sizing agent for glass fiber yarn and glass fiber yarn using the same |
Non-Patent Citations (2)
| Title |
|---|
| 梅自强: "《纺织工业中的表面活性剂》", 31 December 2001, 中国石化出版社 * |
| 陈开勋等: "《精细化工产品化学及应用》", 31 December 1995, 西北大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12180337B2 (en) | 2019-08-20 | 2024-12-31 | Shpp Global Technologies B.V. | Poly (phenylene ether) based compatibilizing material |
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| CN102603215B (en) | 2014-11-05 |
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