CN102476177A - Upward drawing method for copper alloy wire blank - Google Patents
Upward drawing method for copper alloy wire blank Download PDFInfo
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Abstract
本发明涉及一种使铜合金液态成型为铜合金线坯的制备方法,其包括配料、原料的熔炼、拉丝和清洗形成成品,其在原料的熔炼和拉丝步骤之间还包括如下步骤,将结晶器放入熔化的铜合金液体中,向结晶器的外套的进水口注入冷水,使冷水从外套的出水口出来,在气压的作用下熔化的铜合金液体依次进入石墨模的圆锥台形下部、圆柱形中部和倒圆锥台形上部,铜合金液体在这个过程中依次冷却,形成铜合金线坯,在牵引装置的作用下,所述铜合金线坯进入下一步拉丝步骤,本发明投资少、工艺简单、节能环保。
The present invention relates to a preparation method for forming copper alloy into copper alloy wire billet in liquid state, which includes batching, smelting of raw materials, wire drawing and cleaning to form a finished product, and further includes the following steps between the steps of smelting of raw materials and wire drawing, crystallizing Put the molten copper alloy liquid into the molten copper alloy liquid, inject cold water into the water inlet of the outer jacket of the crystallizer, so that the cold water comes out from the water outlet of the outer jacket, and the molten copper alloy liquid enters the frustum-shaped lower part of the graphite mold, the cylindrical In the middle part and the upper part of the inverted truncated cone, the copper alloy liquid is cooled sequentially during this process to form a copper alloy wire blank. Under the action of the traction device, the copper alloy wire blank enters the next step of wire drawing. The invention has less investment and simple process ,Energy saving and environmental protection.
Description
技术领域 technical field
本发明属于铜合金加工领域,特别涉及到一种铜合金线坯的生产工艺。The invention belongs to the field of copper alloy processing, and in particular relates to a production process of a copper alloy wire billet.
背景技术 Background technique
包括电线用铜线的铜丝有如下几种生产工艺,如连铸连轧法、挤压法、水平连铸法、上引成型法,连铸连轧制法需要采用大型设备,先是把铜和各种其它元素如锡、磷、硅、锰等按照配比加入到熔炉中熔化,然后铸锭成型,再是采用大型设备进行挤压,然后进行拉伸,最后清洗以形成成品。如下所示:Copper wire including copper wire for electric wires has the following production processes, such as continuous casting and rolling, extrusion, horizontal continuous casting, and upward forming method. The continuous casting and rolling method requires large-scale equipment. First, the copper And various other elements such as tin, phosphorus, silicon, manganese, etc. are added to the furnace according to the ratio to melt, and then cast into ingots, then extruded by large equipment, then stretched, and finally cleaned to form a finished product. As follows:
配料→熔化→升温→连铸连轧→拉丝→清洗Batching→melting→heating→continuous casting and rolling→drawing→cleaning
挤压法的工艺流程为:The process flow of extrusion method is:
配料→熔化→升温→铸锭→挤压→拉丝→清洗Batching→melting→heating→ingot casting→extrusion→drawing→cleaning
水平连铸法的工艺流程为:The technological process of horizontal continuous casting method is:
配料→熔化→升温→水平连铸→拉丝→清洗Batching→melting→heating→horizontal continuous casting→drawing→cleaning
上引成型法的工艺流程为:The process flow of the upward forming method is as follows:
配料→熔化→升温→上引成型→拉丝→清洗Batching→melting→heating→upward forming→drawing→cleaning
连铸连轧法的优点是制造的线坯组织致密、均匀,生产效率高,缺点是只适合于大规模生产、投资大,风险高,且生产的线坯含氧量稍高,有杂质。The advantage of the continuous casting and rolling method is that the manufactured wire billet has dense and uniform structure and high production efficiency. The disadvantage is that it is only suitable for large-scale production, large investment, high risk, and the produced wire billet has a slightly higher oxygen content and impurities.
挤压法生产的优点是适合于中、大型生产规模,线坯组织高度致密,缺点是生产效率低,接头不牢固,有杂质,不适宜生产小规模线材。The advantage of extrusion production is that it is suitable for medium and large-scale production scale, and the wire billet structure is highly dense. The disadvantage is that the production efficiency is low, the joint is not firm, and there are impurities, so it is not suitable for the production of small-scale wire.
水平连铸法生产的优点是适合于各种生产规模,效率一般,缺点是线坯表面易氧化,组织为铸造组织,有疏松。The advantage of the horizontal continuous casting method is that it is suitable for various production scales, and the efficiency is average. The disadvantage is that the surface of the wire billet is easily oxidized, and the structure is a casting structure with looseness.
而传统的上引成型法生产的优点是适合于各种生产规模,产品含氧量低,杂质较少,质量稳定,可生产细微或超细微丝;缺点是生产效率一般,线坯为铸造组织,疏松,有成分不均匀现象。The advantage of the traditional upward forming method is that it is suitable for various production scales, the product has low oxygen content, less impurities, stable quality, and can produce fine or ultra-fine microfilaments; the disadvantage is that the production efficiency is average, and the wire billet is a casting structure. , Loose, with uneven composition.
发明内容 Contents of the invention
本发明要解决的技术问题是提供一种投资少、工艺简单、可生产细微线材且节能环保的铜合金线坯上引法。The technical problem to be solved by the present invention is to provide a copper alloy wire billet up-drawing method with low investment, simple process, capable of producing fine wire rods, energy saving and environmental protection.
本发明所采取的技术方案是一种铜合金线坯上引法,包括配料、原料的熔炼、拉丝和清洗形成成品,其在原料的熔炼和拉丝步骤之间还包括如下步骤,将结晶器放入熔炼后的铜合金液体中,所述结晶器包括外套、设置在外套上的进水口和出水口、套装在外套内的铜套和套装在铜套内的石墨模,所述石墨模由圆锥台形下部、圆柱形中部和倒圆锥台形上部组成,向外套的进水口注入冷水,使冷水从外套的出水口出来,在气压的作用下熔化的铜合金液体依次进入石墨模的圆锥台形下部、圆柱形中部和倒圆锥台形上部,铜合金液体在这个过程中依次冷却,形成铜合金线坯,在牵引装置的作用下,所述铜合金线坯进入下一步拉丝步骤。The technical solution adopted by the present invention is a copper alloy wire billet up-drawing method, including batching, raw material smelting, wire drawing and cleaning to form a finished product, which also includes the following steps between the raw material smelting and wire drawing steps, placing the crystallizer into the copper alloy liquid after smelting, the crystallizer includes a jacket, a water inlet and a water outlet arranged on the jacket, a copper jacket set in the jacket and a graphite mold set in the copper jacket, and the graphite mold consists of a cone Consisting of a frustum-shaped lower part, a cylindrical middle part and an inverted truncated cone-shaped upper part, inject cold water into the water inlet of the jacket, so that the cold water comes out from the water outlet of the jacket, and the molten copper alloy liquid enters the frusto-conical lower part of the graphite mold, the cylinder in turn under the action of air pressure In the middle part and the upper part of the inverted truncated cone, the copper alloy liquid is cooled sequentially during this process to form a copper alloy wire billet. Under the action of the pulling device, the copper alloy wire billet enters the next wire drawing step.
本发明中,所述铜合金液体的温度设置为其熔点温度加上50~100℃。冷水的水压为2~4MPa;所述牵引装置的牵引速度为500~1500mm/min;所述的牵引方式为向上牵引后暂停,再向下反推,再向上牵引,如此反复进行。In the present invention, the temperature of the copper alloy liquid is set to its melting point plus 50-100°C. The hydraulic pressure of the cold water is 2-4MPa; the pulling speed of the pulling device is 500-1500mm/min; the pulling way is to pause after pulling upwards, then reverse downwards, and then pull upwards, and so on repeatedly.
本发明所述的铜合金为铜-锌-锰合金系的铜合金。The copper alloy described in the present invention is a copper alloy of copper-zinc-manganese alloy system.
本发明的有益效果是铜合金液体直接成型为铜合金线坯,适合于不同规模企业,其步骤和传统上引成型法相同,不同之处在上引成型这一步。The beneficial effect of the invention is that the copper alloy liquid is directly formed into a copper alloy wire billet, which is suitable for enterprises of different scales. The steps are the same as the traditional up-draw forming method, and the difference lies in the up-draw forming step.
在本发明中,配置好的铜合金经电炉熔化后,升温到该合金熔点之上50~100℃,合金均匀化后,即可开始上引成型;将装有外套的石墨模装置垂直放入铜合金液体中,使底部距金属液面为80~100cm,这时,铜合金液体在大气压的作用下进入石墨模的圆锥台形下部,由于石墨模四壁有冷水流动,使石墨模的内外壁形成温度梯度及石墨模的上下部形成温度梯度,铜合金液体遇急冷凝固成型,在牵引装置的牵引下,牵引方式为牵引-暂停-反推-牵引,这样成型的铜合金线坯向上移动,下面的铜合金液体在大气压作用下向上移动,遇冷变成固体,这个由液体—固体的过程连续不断,因此形成了无限长的杆。在铜合金线坯成型的最初阶段,先向石墨模内插入一根铜合金线坯,利用这根铜合金线坯把遇冷成型的铜合金线坯拉出结晶器,实现拉丝步骤。In the present invention, after the configured copper alloy is melted in an electric furnace, the temperature is raised to 50-100°C above the melting point of the alloy. After the alloy is homogenized, the upward forming can be started; In the copper alloy liquid, the distance from the bottom to the metal liquid surface is 80-100cm. At this time, the copper alloy liquid enters the lower part of the frustum of the graphite mold under the action of atmospheric pressure. Since the four walls of the graphite mold have cold water flowing, the inner and outer walls of the graphite mold The temperature gradient is formed and the upper and lower parts of the graphite mold form a temperature gradient. The copper alloy liquid is rapidly cooled and solidified. Under the traction of the traction device, the traction mode is traction-pause-reverse push-traction, so that the formed copper alloy wire billet moves upward. The copper alloy liquid below moves upward under the action of atmospheric pressure and becomes solid when it is cooled. This process from liquid to solid is continuous, thus forming an infinitely long rod. In the initial stage of copper alloy wire billet forming, a copper alloy wire billet is inserted into the graphite mold first, and the copper alloy wire billet formed after being cooled is pulled out of the crystallizer by using this copper alloy wire billet to realize the wire drawing step.
本发明生产的铜合金线坯产品质量稳定,无杂质,表面无氧化,内部组织含氧量低,可进行连续拉拔,生产细微线材,特别适合于中、小型铜合金线材厂的生产,降低了生产成本,减少了固定资本的投资规模,降低了风险,是中小型企业发展的可靠途径。The copper alloy wire billet produced by the invention has stable quality, no impurities, no oxidation on the surface, low oxygen content in the internal tissue, can be continuously drawn, and can produce fine wire rods, and is especially suitable for the production of medium and small copper alloy wire rod factories, reducing It reduces production costs, reduces the investment scale of fixed capital, and reduces risks. It is a reliable way for the development of small and medium-sized enterprises.
附图说明 Description of drawings
图1是本发明的带有熔炉的结晶器的结构示意图;Fig. 1 is the structural representation of the crystallizer with melting furnace of the present invention;
图2是本发明的结晶器的结构示意图;Fig. 2 is the structural representation of crystallizer of the present invention;
图3是本发明的石墨模的结构示意图。Fig. 3 is a schematic structural view of the graphite mold of the present invention.
在图中,1熔炉、2铜合金液体、3铜套、4冷水、5石墨模、6出水口、7铜合金线坯、8进水口、9外套、10倒圆锥台形上部、11圆柱形中部、12圆锥台形下部、13牵引装置。In the figure, 1 melting furnace, 2 copper alloy liquid, 3 copper sleeve, 4 cold water, 5 graphite mold, 6 water outlet, 7 copper alloy wire blank, 8 water inlet, 9 jacket, 10 inverted frustum-shaped upper part, 11 cylindrical middle part , 12 frustum-shaped lower parts, 13 traction devices.
具体实施方式Detailed ways
本发明包括配料、原料的熔炼、上引成型、拉丝和清洗形成成品,其具体步骤是,先将铜和锡、磷、硅、锰等材料按照配比加入到熔炉1中,锡、磷、硅、锰等材料最高可达总原料的10%,材料熔化后,将结晶器放入熔化后的铜合金液体2中,铜合金液体2的温度为铜合金液体2本身的熔点温度加上50℃。如附图1-3所示,所述的结晶器包括外套9、设置在外套9上的进水口8和出水口6、套装在外套9内的铜套3和套装在铜套3内的石墨模5,所述石墨模5由圆锥台形下部12、圆柱形中部11和倒圆锥台形上部10组成,向外套9的进水口8注入冷水4,使冷水4从外套9的出水口6出来,其中冷水的水压为3MPa。在气压的作用下熔化的铜合金液体2依次进入石墨模5的圆锥台形下部12、圆柱形中部11和倒圆锥台形上部10,铜合金液体2在这个过程中依次冷却,形成铜合金线坯7,在牵引装置13的作用下,铜合金线坯7向上移动,移动速度为1000mm/min,牵引方式为:The present invention includes batching, smelting of raw materials, upward forming, wire drawing and cleaning to form finished products. The specific steps are: firstly, copper, tin, phosphorus, silicon, manganese and other materials are added to the
牵引→暂停→反推→牵引Traction→Pause→Reverse thrust→Tow
牵引完后,铜合金线坯7固化,铜合金线坯7进入下一步拉丝步骤。After drawing, the copper alloy wire blank 7 is solidified, and the copper alloy wire blank 7 enters the next wire drawing step.
在最初的上引成型步骤中,预先向石墨模5内放入铜合金线坯,铜合金液体2在遇到铜合金线坯而后冷却时,铜合金液体2变为固态且和铜合金线坯紧密连接,从而进入下一步的拉丝和清洗形成成品步骤。这部分技术属于现有技术,不再赘述。In the initial upward forming step, the copper alloy wire blank is placed in the
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| CN103050188A (en) * | 2012-12-21 | 2013-04-17 | 江苏中容铜业有限公司 | Method for producing oxygen-free copper alloy-clad aluminum conductor for use in communication |
| CN107553064A (en) * | 2016-06-30 | 2018-01-09 | 张家港市金港镇宏业海绵复合厂 | Copper phosphorus board production technology |
| CN111842825A (en) * | 2020-08-04 | 2020-10-30 | 镇江尚恩工程机械制造有限公司 | Vertical continuous casting and drawing equipment for ultra-long superalloy pipes and using method thereof |
| AU2018201354B2 (en) * | 2017-03-06 | 2021-02-04 | Hui, Martin | Cold-drawn processing apparatus and processing method |
| CN112570674A (en) * | 2021-01-21 | 2021-03-30 | 中铁建电气化局集团康远新材料有限公司 | Oxygen-free copper rod crystallizer |
| CN113857443A (en) * | 2021-09-28 | 2021-12-31 | 江阴金属材料创新研究院有限公司 | Copper or copper alloy ultra-micro wire upward-leading equipment and upward-leading production process |
| CN114558998A (en) * | 2022-03-24 | 2022-05-31 | 北京市金合益科技发展有限公司 | Crystallizer, copper melting furnace and copper-clad steel production line with same |
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| CN103050188A (en) * | 2012-12-21 | 2013-04-17 | 江苏中容铜业有限公司 | Method for producing oxygen-free copper alloy-clad aluminum conductor for use in communication |
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| CN113857443A (en) * | 2021-09-28 | 2021-12-31 | 江阴金属材料创新研究院有限公司 | Copper or copper alloy ultra-micro wire upward-leading equipment and upward-leading production process |
| CN113857443B (en) * | 2021-09-28 | 2024-01-12 | 杭州奥宇金属制品有限公司 | Copper or copper alloy ultra-microfilament upward-guiding equipment and upward-guiding production process |
| CN114558998A (en) * | 2022-03-24 | 2022-05-31 | 北京市金合益科技发展有限公司 | Crystallizer, copper melting furnace and copper-clad steel production line with same |
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