CN1023081C - Composition of fluorite flotation regulator - Google Patents
Composition of fluorite flotation regulator Download PDFInfo
- Publication number
- CN1023081C CN1023081C CN 91112718 CN91112718A CN1023081C CN 1023081 C CN1023081 C CN 1023081C CN 91112718 CN91112718 CN 91112718 CN 91112718 A CN91112718 A CN 91112718A CN 1023081 C CN1023081 C CN 1023081C
- Authority
- CN
- China
- Prior art keywords
- acid
- composition
- salt
- waterglass
- fluorite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000010436 fluorite Substances 0.000 title claims abstract description 46
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical group [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 title claims abstract description 45
- 239000000203 mixture Substances 0.000 title claims abstract description 40
- 238000005188 flotation Methods 0.000 title abstract description 14
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 40
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 40
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000002253 acid Substances 0.000 claims abstract description 30
- 150000003839 salts Chemical class 0.000 claims abstract description 26
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 24
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 229910002651 NO3 Inorganic materials 0.000 claims description 5
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims description 5
- 150000003891 oxalate salts Chemical class 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000012141 concentrate Substances 0.000 abstract description 23
- 238000011084 recovery Methods 0.000 abstract description 19
- 239000003607 modifier Substances 0.000 abstract description 3
- 239000003513 alkali Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 17
- 229910004261 CaF 2 Inorganic materials 0.000 description 14
- 239000010428 baryte Substances 0.000 description 7
- 229910052601 baryte Inorganic materials 0.000 description 7
- 229910021532 Calcite Inorganic materials 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000010453 quartz Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- 229910052611 pyroxene Inorganic materials 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910052613 tourmaline Inorganic materials 0.000 description 2
- 239000011032 tourmaline Substances 0.000 description 2
- 229940070527 tourmaline Drugs 0.000 description 2
- MPPQGYCZBNURDG-UHFFFAOYSA-N 2-propionyl-6-dimethylaminonaphthalene Chemical compound C1=C(N(C)C)C=CC2=CC(C(=O)CC)=CC=C21 MPPQGYCZBNURDG-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 241001504664 Crossocheilus latius Species 0.000 description 1
- 229910020218 Pb—Zn Inorganic materials 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 230000004520 agglutination Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hcl hcl Chemical compound Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- ANOBYBYXJXCGBS-UHFFFAOYSA-L stannous fluoride Chemical compound F[Sn]F ANOBYBYXJXCGBS-UHFFFAOYSA-L 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
The present invention is a composition for use as a fluorite flotation modifier which is an improvement over the fluorite flotation modifier described in the patent' 87105202 granted. In the prior art, fluorite flotation adopts acid, alkali and synergist as a regulator. The invention uses the composition of water glass, acid and one or two soluble salts of the acid as the regulator, and forms the composition series, namely any acid and corresponding salt in sulfuric acid, hydrochloric acid, oxalic acid and acetic acid, the combination proportion range is: water glass, acid and salt = 1-2: 1-5: 0.5-1. The invention has strong adaptability, good stability, high concentrate quality, high recovery rate and low cost.
Description
The present invention relates to a kind of composition as fluorite adjustment agent, it is the improvement to used adjustment agent in the fluorite method of putting down in writing in No. 87105202 granted patent documents.
Method according to No. 87105202 patent applications, the adjustment agent of fluorite is that acid adds alkali and adds synergist, effect is than the obvious improvement of prior art, but because of synergist (carboxymethyl cellulose or calgon or prodan) price expensive, solubility is low, the amount of allocating into is few, and effect is still very good inadequately, is of limited application.Take a broad view of domestic and international fluorite present situation, the improvement of adjusting agent in the traditional handicraft is had acid system and alkaline system, the former adds waterglass for acid, and is stronger to the inhibition of siliceous minerals such as quartz, but poor stability, the flotation froth breaking seldom adopts in the production; The latter for waterglass add slaine (as US2893915, US3207304, SU1128984, SU671855 SU1002014), strengthens the inhibition to calcite, but turbidity sediment and losing efficacy easily.From prior art, can find out, the someone did not expect adjusting adding acid in the agent at alkaline system, or in acid system, add salt and improve, main cause is " acidic water glass " easily agglutination and make and adjust agent and lost efficacy, those skilled in the art attentively work hard in alkaline system.Exhausted expect in alkaline system, adding acid less or in the acid system with salt.
The purpose of this invention is to provide a kind of medicament source easily, the adjustment agent composition of make up a prescription convenience, solubility height, stable transparent, said composition is used in the fluorite technology can suppress associated minerals such as barite, calcite, quartz, mica effectively, fluorite is fully swum, thereby improve the selectivity and the rate of recovery of fluorite.
Purpose of the present invention realizes by the following method: with waterglass add acid and one or both soluble-salts of forming with this acid (as being two kinds of salt, then the ratio of these two kinds of salt is 0.5: 0.1～1.0), its combination is than being: waterglass: acid: salt=1～2: 1～5: 0.5～1(weight ratio, down together), combination liquid pH≤3, be the aqueous solution of stable transparent, its concentration is 1～20%(percentage by weight).
Purpose of the present invention can also realize by the following method:
1. add oxalic acid (H with waterglass
2C
2O
4), salt uses the solubility oxalates (as Na
2C
2O
4), it makes up than being: waterglass: oxalic acid: solubility oxalates=2: 3: 1.Use oxalic acid and oxalates to separate better effects if when flotation contains the more fluorite ore deposit of pyroxene, the fluorite rate of recovery is higher.
2. add acetic acid (CH with waterglass
3COOH) add solubility acetate (as CH
3COONa, CH
3COOK etc.) adjust the agent composition, it makes up than being: waterglass: acetic acid: solubility acetate=2: 5: 1.The composition that uses this type of acid and salt thereof to form more is adapted to fluorite to be separated with quartz.
3. add nitric acid (HNO with waterglass
3) and solubility nitrate (NaNO
3, KNO
3Deng), it makes up than being: waterglass: nitric acid: solubility nitrate=1: 1: 0.5.This based composition is more effective to the fluorite of fine-grained disseminated grain.
4. add hydrochloric acid (HCl) with waterglass and soluble-salt hydrochlorate (as NaCl, KCl etc.) adjusts the agent composition, it makes up than being: waterglass: hydrochloric acid: soluble-salt hydrochlorate=1: 1: 0.5, it more is applicable to separates fluorite and barite.
5. add sulfuric acid (H with waterglass
2SO
4) and soluble sulphate (as Na
2SO
4, FeSO
4, ZnSO
4, (NH
4)
2SO
4, Al
2(SO
4)
3) being mixed into composition, it makes up than being: waterglass: sulfuric acid: soluble sulphate=1: 1: 0.5, this based composition is more effective to separating fluorite and calcite.
6. add sulfuric acid with waterglass and add two kinds of soluble sulphates [as Na
2SO
4Add (NH
4)
2SO
4] make composition, it makes up than being: waterglass: sulfuric acid: two kinds of soluble sulphates=1: 1: 0.5, wherein the ratio of two kinds of salt is: 0.5: 0.1～1.0.
Above-mentioned hydrochloric acid, nitric acid, sulfuric acid etc. can substitute mutually, also can substitute mutually with the corresponding salt of this acid.
Concrete grammar of the present invention is: take sample ore, with grinde ore to fluorite monomer dissociation rate greater than 95%, being diluted with water to concentration is 25～30%(solid) ore pulp, available any composition of the present invention adjusts agent, with oleic acid (or fatty acid soaps) as the collecting foaming agent of holding concurrently, under near neutral (PH=6.5～7.0) medium and normal temperature (20～30 ℃) condition, carry out flotation, roughly select foam and promptly get fluorite concentrate selected 5～7 times, the consumption of composition is according to ore character and grade and decide, generally roughly select 500～1500 gram/tons, selected 500～800 gram/tons, flotation flowsheet adopts " set composite ".So obtain concentrate grade and can reach 98～99%CaF
2, the rate of recovery reaches 85～90%.
The invention will be further described with embodiment below:
Embodiment 1: adopt fluorite-pyroxene ore deposit, contain 45%CaF
2, be milled to less than 0.074mm to the ore deposit, account for 88%, be diluted to pulp density 25%(solid), add composition (waterglass: oxalic acid: sodium oxalate=2: 3: 1) adjust agent, roughly select consumption 1200 gram/tons, stirred 3 minutes; Add oleic acid 360 gram/tons, stirred 3 minutes, flotation is 6 minutes under normal temperature (20～22 ℃) condition, and foam is after primary cleaning, and chats 1 merges to enter with the interior ore pulp of initial separatory cell to be scanned, and selects foam to return again and roughly selects or handle separately output time concentrate (loop 1); Selected composition 400 gram/tons that add for the second time, chats 2 returns in advance into roughly selecting, for the third time selected not dosing, the 4th the selected composition 200 gram/tons that add again, third and fourth, five, six selected chats return last operation (loop II) successively, the process that all sorts all adopts common flotation device, pH values of pulp=6.5～7.0, the final fluorite concentrate rate of recovery 85.3%, grade 98.6%CaF
2(primes).
Example 2. usefulness somewhere fluorite-quartz mines contain " sludge " up to 20%, the present invention are opposed than test experiment I intermixture (H with No. 87105202 patents
2SO
4: Na
2SiO
3: CMC=1: 1: 0.1) adjust agent, consumption restrains/rams the loose soil with a stone-roller after sowing for roughly selecting 1000, and selected 500 gram/tons, grade is given the ore deposit by 67%() bring up to 98.5%CaF
2(concentrate), the fluorite rate of recovery 83%; (waterglass: acetic acid: sodium acetate=2: 5: 1), method is with example one, and consumption 800 gram/tons (roughly selecting) and 400 gram/tons (selected) obtain concentrate grade 99%CaF with composition for the experiment II
2(select quality), the rate of recovery 88%.
Example 3. methods are with example one.Fluorite ore deposit, somewhere grade is low (to contain 38.4%CaF
2), disseminated grain size carefully (is milled to 90%-0.074mm, fluorite monomer rate is 93%), with composition (waterglass: nitric acid: sodium nitrate=1: 1: 0.5) adjust agent, consumption 1500 gram/tons (roughly selecting) and 800 gram/tons (selected), obtain fluorite concentrate grade 98.2%(primes), the rate of recovery 80%.Use KNO
3Replace NaNO
3Also get analog result.
Example 4. methods are with example one.Somewhere fluorite-calcite ore contains 65%CaF
2, 18.5%CaCO
3, conventional dose can not make fluorite separate with calcite, and (waterglass: sulfuric acid: sodium sulphate=1: 1: 0.5) adjust agent, consumption 1400 gram/tons (roughly selecting) and 600 gram/tons (selected) obtain fluorite concentrate grade 98.8%CaF with composition
2(select quality), the rate of recovery 90.5%.
Example 5. somewhere fluorite-barite deposits contain 60%CaF
2, 21%BaSO
4Adopt prior art can only obtain fluorite-barite bulk concentrate (defective), with composition (waterglass: hydrochloric acid: sodium chloride=1: 1: 0.5) consumption 900 gram/tons (roughly selecting) and 300 gram/tons (selected), method is with example one, fluorite is accurately separated, fluorite concentrate grade 98.5%CaF with barite
2(primes), the rate of recovery 89.4%; Obtain the barite concentrate of high-quality simultaneously, (proportion＞4.2), its rate of recovery 96%.
The white tungsten mine tailing in example 6. somewheres (contains 20.5%CaF
2), handle because of the floatation process that does not have success, be forced to store up for a long time.(waterglass: sulfuric acid: sodium sulphate=1: 1: 0.5) adjust agent, method is with example one, and consumption 1000 gram/tons (roughly selecting) and 300 gram/tons (selected) obtain unprecedented good index, concentrate grade 98.2%CaF with composition
2(primes), the rate of recovery 88%.
Example 7. somewhere Pb-Zn tailings (contain 25.6%CaF
2), with conventional beneficiation method flotation, concentrate sulfur-bearing severe overweight, (waterglass: sulfuric acid: ferrous sulfate=1: 1: 0.5), method is with example one, consumption 1600 gram/tons (selected) and 800 gram/tons (selected), fluorite concentrate grade 98.6%CaF with composition
2(primes), the rate of recovery 81.3%.
Example 8. somewhere fluorite-quartz-MICAs contain 70%CaF
2, (waterglass: sulfuric acid: zinc sulfate=1: 1: 0.5), method is with example one, consumption 800 gram/tons (roughly selecting) and 400 gram/tons (selected), fluorite concentrate grade 99.25%CaF with composition
2(select quality), the rate of recovery reaches 91.95%.
Example 9. somewheres contain the fluorite ore deposit of tourmaline, grade 61.5%CaF
2, use the prior art flotation, form " off standard " because of being mingled with tourmaline in the fluorite concentrate; (waterglass: sulfuric acid: aluminum sulfate=1: 1: 0.5) method is with example one, and consumption 1000 gram/tons (selected) and 400 gram/tons (selected) obtain fluorite concentrate grade 98.3%CaF with composition
2(primes), the rate of recovery 90.4%.
Example 10. somewheres contain the fluorite ore deposit of garnet, pyroxene, grade 50.5%CaF
2, use the prior art test of many times, all do not obtain qualified fluorite concentrate, (waterglass: sulfuric acid: sodium sulphate: ammonium sulfate=1: 1: 0.25: 0.25), method obtains fluorite concentrate grade 98.8%CaF with example one to adopt composition
2, (primes), the rate of recovery 86.8%.
Above embodiment as can be seen, the present invention compared with prior art has a lot of advantages, promptly waterglass adds acid and forms fluorite with soluble-salt that this acid is formed and adjusts agent composition series, its adaptability is strong, good stability, concentrate high-quality, rate of recovery height, cost is low, remarkable in economical benefits.
1. said composition can not only make fluorite and quartzy FLOTATION SEPARATION, and fluorite and barite, fluorite and calcite, fluorite and mica etc. are separated, and this is that prior art institute is inaccessible.
2. the easy gel of acidic water glass is rotten in the prior art, the easy flocculation sediment of salt waterglass and losing efficacy, and present composition stable performance, the solubility height, preparation is convenient.
3. the fluorite concentrate grade that obtains usually of prior art is 97%CaF
2, the present invention can obtain grade and reach 98～99%CaF
2Fluorite concentrate.
4. the medicament of prior art use is more expensive, and flotation recovery rate is low, and present composition cost is lower, fluorite rate of recovery height.
Those of ordinary skills can do some improvement to the present invention fully, for example available some other acid and salt thereof, as sulfurous acid, phosphoric acid, etching acid and corresponding salt thereof, or monoxone, benzoic acid, phthalic acid and corresponding salt thereof or the like, obviously, these improve and all do not deviate from and surpass category of the present invention.
Claims (7)
1, a kind of composition as fluorite adjustment agent comprises waterglass (Na
2SiO
3) one or both soluble-salts of adding acid and forming with this acid, as be two kinds of salt, then the ratio of these two kinds of salt is 0.5: 0.1～1.0, its combination is than being: waterglass: acid: salt=1～2: 1～5: 0.5～1 (weight ratio, down together), combination liquid pH≤3 are the aqueous solution of stable transparent, and its concentration is 1～20% (percentage by weight).
2,, it is characterized in that acid is oxalic acid (H according to the composition of claim 1
2C
2O
4), salt is the solubility oxalates, it makes up than being: waterglass: oxalic acid: solubility oxalates=2: 3: 1.
3,, it is characterized in that acid is acetic acid (CH according to the composition of claim 1
3COOH), salt is solubility acetate, and it makes up than being: waterglass: acetic acid: solubility acetate=2: 5: 1.
4,, it is characterized in that acid is nitric acid (HNO according to the composition of claim 1
3), salt is solubility nitrate, it makes up than being: waterglass: acetic acid: solubility nitrate=1: 1: 0.5.
5, according to the composition of claim 1, it is characterized in that acid is hydrochloric acid (HCl), salt is the soluble-salt hydrochlorate, it makes up than being: waterglass: acetic acid: soluble-salt hydrochlorate=1: 1: 0.5.
6,, it is characterized in that acid is sulfuric acid (H according to the composition of claim 1
2SO
4), salt is soluble sulphate, it makes up than being: waterglass: sulfuric acid: solubility nitrate=1: 1: 0.5.
7,, it is characterized in that acid is sulfuric acid (H according to the composition of claim 1
2SO
4), salt is two kinds of soluble sulphates, it makes up than being: waterglass: sulfuric acid: two kinds of soluble sulphates=1: 1: 0.5, wherein the ratio of two kinds of salt is: 0.5: 0.1～1.0.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91112718 CN1023081C (en) | 1991-12-31 | 1991-12-31 | Composition of fluorite flotation regulator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91112718 CN1023081C (en) | 1991-12-31 | 1991-12-31 | Composition of fluorite flotation regulator |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1063058A CN1063058A (en) | 1992-07-29 |
| CN1023081C true CN1023081C (en) | 1993-12-15 |
Family
ID=4911043
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91112718 Expired - Fee Related CN1023081C (en) | 1991-12-31 | 1991-12-31 | Composition of fluorite flotation regulator |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1023081C (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1944088A1 (en) * | 2007-01-12 | 2008-07-16 | Omya Development Ag | Process of purification of minerals based on calcium carbonate by flotation in the presence of quaternary imidazollum methosulfate |
| CN101507948B (en) * | 2009-04-03 | 2012-04-25 | 陕西新星浮选剂有限责任公司 | Collecting agent for floatation of fluorite under low-temperature condition |
| CN101712014B (en) * | 2009-12-08 | 2012-03-21 | 湖南省铸万有实业有限公司 | Multicategory-impurity single fluorite ore dressing method |
| CN102151615B (en) * | 2010-12-21 | 2013-01-16 | 北京矿冶研究总院 | Fluorite flotation method in a high salinity alkaline water environment |
| CN102489408B (en) * | 2011-12-19 | 2013-04-10 | 湖南有色金属研究院 | Flotation method for separating copper form mica |
| CN102658242B (en) * | 2012-04-25 | 2013-06-19 | 白银有色集团股份有限公司 | Mineral separation process of complex fluorite difficult to separate |
| CN102896047B (en) * | 2012-10-08 | 2014-12-24 | 湖南有色金属研究院 | Method for beneficiating high-peat copper sulphide ore |
| CN104694736B (en) * | 2015-03-23 | 2017-01-11 | 东北大学 | Calcium roasting floatation separation method for bastnaesite |
| CN105149100B (en) * | 2015-08-07 | 2018-01-19 | 广州有色金属研究院 | A kind of method that barite is reclaimed from Pb-Zn tailings |
| CN105689148B (en) * | 2016-04-22 | 2018-05-08 | 云南罗平锌电股份有限公司 | It is a kind of to suppress calcium, the method for magnesium in ore dressing process |
| CN106179763A (en) * | 2016-06-27 | 2016-12-07 | 洛阳丰瑞氟业有限公司 | Fluorite flotation calcium carbonate inhibitor and preparation method thereof |
| CN106492994B (en) * | 2016-11-02 | 2018-11-20 | 广西大学 | A kind of preparation method of olivine mineral inhibitor |
| CN115090409B (en) * | 2022-06-16 | 2024-08-13 | 中化地质矿山总局地质研究院 | Ore dressing method for fluorite ore |
-
1991
- 1991-12-31 CN CN 91112718 patent/CN1023081C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1063058A (en) | 1992-07-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1023081C (en) | Composition of fluorite flotation regulator | |
| US3450257A (en) | Processing of clay | |
| US3337048A (en) | Method for beneficiating clay by flotation | |
| CN115350817A (en) | A lepidolite flotation collector and beneficiation method | |
| GB1298927A (en) | Removal of fluorine values from aqueous solutions of fluosilicic acid | |
| US3259242A (en) | Beneficiation of apatite-calcite ores | |
| US4436616A (en) | Process for the beneficiation of phosphate ores | |
| LU505722B1 (en) | Flotation reagent and flotation method for marmatite and jamesonite | |
| CN1015601B (en) | Method for flotation of fluorite | |
| CN115814957A (en) | Inhibitor for high-calcium fluorite ore and flotation method | |
| CN111215247B (en) | Inhibitor for high-calcium fluorite direct flotation and flotation method | |
| CN113477409A (en) | Calcium-containing gangue combined inhibitor for scheelite flotation and preparation and application methods thereof | |
| CN108043589B (en) | Application of polyaspartic acid in flotation of fluorite ore | |
| US4324653A (en) | Process for the treatment of phosphate ores with silico-carbonate gangue | |
| CN117505082A (en) | Flotation method for mud-containing high-sulfur copper ores | |
| CN113499858A (en) | Application of polyepoxysuccinic acid as inhibitor in fluorite ore | |
| US3910836A (en) | Pyrochlore flotation | |
| CN109127151B (en) | Oxidized ore mineral flotation collector | |
| CN113877721A (en) | Method for deeply removing micro-fine particle black and white mica from granite type metal ore tailings | |
| CN110465412B (en) | Molybdenite beneficiation inhibitor and preparation method thereof | |
| CN110773322A (en) | A kind of forward and reverse flotation process of quartz-calcite type fluorite ore | |
| CN104209192A (en) | Mineral separation process for gangue mineral comprising calcium and magnesium | |
| US5439116A (en) | Process for the recovery of micas by flotation and micas thus obtained | |
| US2168762A (en) | cacos | |
| DE931223C (en) | Process for purifying calcium chloride |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |