CN102229837A - Antiwear agent for petroleum diesel oil and application method thereof - Google Patents
Antiwear agent for petroleum diesel oil and application method thereof Download PDFInfo
- Publication number
- CN102229837A CN102229837A CN2011101305450A CN201110130545A CN102229837A CN 102229837 A CN102229837 A CN 102229837A CN 2011101305450 A CN2011101305450 A CN 2011101305450A CN 201110130545 A CN201110130545 A CN 201110130545A CN 102229837 A CN102229837 A CN 102229837A
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- Prior art keywords
- biofuel
- fatty acid
- derivative
- acid ester
- ester
- Prior art date
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 23
- 239000002283 diesel fuel Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 11
- 239000003208 petroleum Substances 0.000 title abstract 8
- -1 aliphatic ester Chemical class 0.000 claims abstract description 51
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 42
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004519 grease Substances 0.000 claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 7
- 230000005494 condensation Effects 0.000 claims abstract description 7
- 238000009833 condensation Methods 0.000 claims abstract description 7
- 150000002148 esters Chemical class 0.000 claims abstract description 7
- 239000002551 biofuel Substances 0.000 claims description 45
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 36
- 239000000194 fatty acid Substances 0.000 claims description 36
- 229930195729 fatty acid Natural products 0.000 claims description 36
- 150000001408 amides Chemical class 0.000 claims description 24
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- 229920005862 polyol Polymers 0.000 claims description 18
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 12
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 12
- 239000000600 sorbitol Substances 0.000 claims description 12
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 6
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 6
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 6
- 230000000813 microbial effect Effects 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 239000010773 plant oil Substances 0.000 claims description 6
- 150000003077 polyols Chemical class 0.000 claims description 6
- 239000005017 polysaccharide Substances 0.000 claims description 6
- 229920001282 polysaccharide Polymers 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 claims description 6
- 239000000811 xylitol Substances 0.000 claims description 6
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 6
- 229960002675 xylitol Drugs 0.000 claims description 6
- 235000010447 xylitol Nutrition 0.000 claims description 6
- 239000000126 substance Substances 0.000 abstract description 4
- 239000003225 biodiesel Substances 0.000 abstract 5
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 244000005700 microbiome Species 0.000 abstract 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 241000863032 Trieres Species 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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Abstract
The invention relates to an antiwear agent for petroleum diesel oil and an application method thereof. The invention is characterized in that the antiwear agent for the petroleum diesel oil composed of biodiesel is added into the petroleum diesel oil, the content of the antiwear agent for the petroleum diesel oil in the petroleum diesel oil is 0.8-5wt%, the biodiesel comprises aliphatic ester A generated by reaction of animal and plant grease, microalgae grease, microorganism grease and low carbon alcohol with the carbon chain length of 1-5; or the antiwear agent for the petroleum diesel oil composed of a derivate of the biodiesel is added into the petroleum diesel, the content of the derivate of the biodiesel in the diesel is 50-500 ppm, the derivate of the biodiesel is dihydric alcohol aliphatic ester B obtained by carrying out ester crosslinking on the aliphatic ester A and one or two dihydric alcohols from ethylene glycol, propylene glycol, butylene glycol, pentanediol and condensation ethylene glycol. Compared with the prior art, the invention has the advantages that discharge of harmful substances is reduced, the environment is protected, and the lubricating property of the diesel can be greatly improved.
Description
Technical field
The present invention relates to a kind of petrifaction diesel additive and using method thereof.
Background technology
Tail gas pollution after the petrifaction diesel burning is quite serious; in order to reduce emission of harmful substances; the protection environment; the use clean diesel is imperative; and sulphur content, aromaticity content and relative density thereof are the main method of producing clean diesel in the reduction petrifaction diesel, but this method causes the diesel fuel lubricity performance to reduce again greatly, and the decline of oilness causes the wear problem of squirt pump again; make engine that unstable idle running take place, power and acceleration characteristics descend.
Summary of the invention
Goal of the invention of the present invention is to provide a kind of emission of harmful substances, protection environment of can reducing, and the petrifaction diesel that can improve the diesel fuel lubricity performance again greatly is with anti-wear agent and using method thereof.
Petrifaction diesel of the present invention is achieved in that the derivative that comprises biofuel, biofuel with anti-wear agent; Biofuel comprises that animal-plant oil, microalgae grease, microbial oil and carbon chain lengths are the fatty acid ester A that the reaction of 1-5 low-carbon alcohol generates; The biofuel derivative be fatty acid ester A with comprise ethylene glycol, propylene glycol, butyleneglycol, defend that in the dibasic alcohol of two pure and mild condensation ethylene glycol one or both carry out the reaction of ester friendshipizations and must dibasic alcohol fatty acid ester B; Perhaps the biofuel derivative is that fatty acid ester A reacts single substituted amide or the disubstituted amide C that generates with primary amine or diethanolamine respectively; Perhaps the biofuel derivative is the polyol ester D that fatty acid ester A and the polyol reaction that comprises glycerol, Sorbitol Powder, Xylitol, sorbitol, polysaccharide polyol form; Perhaps the derivative of biofuel is the two or more mixture among dibasic alcohol fatty acid ester B, single substituted amide or disubstituted amide C, the polyol ester D.
Petrifaction diesel of the present invention is to realize like this with the anti-wear agent using method, the petrifaction diesel that is made of biofuel is added in the petrifaction diesel with anti-wear agent, this petrifaction diesel is 0.8-5wt% with the content that anti-wear agent adds in petrifaction diesel, and biofuel comprises that animal-plant oil, microalgae grease, microbial oil and carbon chain lengths are the fatty acid ester A that the reaction of 1-5 low-carbon alcohol generates;
Perhaps the petrifaction diesel that the derivative by biofuel is constituted adds in the petrifaction diesel with anti-wear agent, the content of the derivative of biofuel in diesel oil is 50-500ppm, the derivative of biofuel be fatty acid ester A with comprise ethylene glycol, propylene glycol, butyleneglycol, defend that in the dibasic alcohol of two pure and mild condensation ethylene glycol one or both carry out the reaction of ester friendshipizations and must dibasic alcohol fatty acid ester B; Perhaps the biofuel derivative is that fatty acid ester A reacts single substituted amide or the disubstituted amide C that generates with primary amine or diethanolamine respectively; Perhaps the biofuel derivative is the polyol ester D that fatty acid ester A and the polyol reaction that comprises glycerol, Sorbitol Powder, Xylitol, sorbitol, polysaccharide polyol form; Perhaps the derivative of biofuel is the two or more mixture among dibasic alcohol fatty acid ester B, single substituted amide or disubstituted amide C, the polyol ester D.
Petrifaction diesel of the present invention with anti-wear agent owing to be to contain the polar group lubricant; be easy to be attached on the inwall of squirt pump and form protective membrane; prevented petrifaction diesel washing away effectively to the squirt pump inwall; therefore; the present invention has can reduce emission of harmful substances, protection environment, can improve the advantage of diesel fuel lubricity performance again greatly.
Description of drawings:
Fig. 1 is the oilness index situation of cleaning petrifaction diesel after using the present invention.
Embodiment:
Now in conjunction with the embodiments the present invention is done and describes in further detail:
Petrifaction diesel of the present invention is achieved in that the derivative that comprises biofuel, biofuel with anti-wear agent; Biofuel comprises that animal-plant oil, microalgae grease, microbial oil and carbon chain lengths are the fatty acid ester A that the reaction of 1-5 low-carbon alcohol generates; The biofuel derivative be fatty acid ester A with comprise ethylene glycol, propylene glycol, butyleneglycol, defend that in the dibasic alcohol of two pure and mild condensation ethylene glycol one or both carry out the reaction of ester friendshipizations and must dibasic alcohol fatty acid ester B; Perhaps the biofuel derivative is that fatty acid ester A reacts single substituted amide or the disubstituted amide C that generates with primary amine or diethanolamine respectively; Perhaps the biofuel derivative is the polyol ester D that fatty acid ester A and the polyol reaction that comprises glycerol, Sorbitol Powder, Xylitol, sorbitol, polysaccharide polyol form; Perhaps the derivative of biofuel is the two or more mixture among dibasic alcohol fatty acid ester B, single substituted amide or disubstituted amide C, the polyol ester D.
Petrifaction diesel of the present invention is to realize like this with the anti-wear agent using method, the petrifaction diesel that is made of biofuel is added in the petrifaction diesel with anti-wear agent, this petrifaction diesel is 0.8-5wt% with the content that anti-wear agent adds in petrifaction diesel, and biofuel comprises that animal-plant oil, microalgae grease, microbial oil and carbon chain lengths are the fatty acid ester A that the reaction of 1-5 low-carbon alcohol generates;
Perhaps the petrifaction diesel that the derivative by biofuel is constituted adds in the petrifaction diesel with anti-wear agent, the content of the derivative of biofuel in diesel oil is 50-500ppm, the derivative of biofuel be fatty acid ester A with comprise ethylene glycol, propylene glycol, butyleneglycol, defend that in the dibasic alcohol of two pure and mild condensation ethylene glycol one or both carry out the reaction of ester friendshipizations and must dibasic alcohol fatty acid ester B; Perhaps the biofuel derivative is that fatty acid ester A reacts single substituted amide or the disubstituted amide C that generates with primary amine or diethanolamine respectively; Perhaps the biofuel derivative is the polyol ester D that fatty acid ester A and the polyol reaction that comprises glycerol, Sorbitol Powder, Xylitol, sorbitol, polysaccharide polyol form; Perhaps the derivative of biofuel is the two or more mixture among dibasic alcohol fatty acid ester B, single substituted amide or disubstituted amide C, the polyol ester D.
Clean the oilness index situation of petrifaction diesel after using the present invention as shown in Figure 1:
(annotate: according to the requirement of derv fuel oil standard GB 19147-2009, the wear scar diameter that oilness records according to high-frequency reciprocating trier HFRR method).
Claims (2)
1. petrifaction diesel anti-wear agent is characterized in that comprising the derivative of biofuel, biofuel; Biofuel comprises that animal-plant oil, microalgae grease, microbial oil and carbon chain lengths are the fatty acid ester A that the reaction of 1-5 low-carbon alcohol generates; The biofuel derivative be fatty acid ester A with comprise ethylene glycol, propylene glycol, butyleneglycol, defend that in the dibasic alcohol of two pure and mild condensation ethylene glycol one or both carry out the reaction of ester friendshipizations and must dibasic alcohol fatty acid ester B; Perhaps the biofuel derivative is that fatty acid ester A reacts single substituted amide or the disubstituted amide C that generates with primary amine or diethanolamine respectively; Perhaps the biofuel derivative is the polyol ester D that fatty acid ester A and the polyol reaction that comprises glycerol, Sorbitol Powder, Xylitol, sorbitol, polysaccharide polyol form; Perhaps the derivative of biofuel is the two or more mixture among dibasic alcohol fatty acid ester B, single substituted amide or disubstituted amide C, the polyol ester D.
2. petrifaction diesel anti-wear agent using method, it is characterized in that the petrifaction diesel that will be made of biofuel adds in the petrifaction diesel with anti-wear agent, this petrifaction diesel is 0.8-5wt% with the content that anti-wear agent adds in petrifaction diesel, and biofuel comprises that animal-plant oil, microalgae grease, microbial oil and carbon chain lengths are the fatty acid ester A that the reaction of 1-5 low-carbon alcohol generates;
Perhaps the petrifaction diesel that the derivative by biofuel is constituted adds in the petrifaction diesel with anti-wear agent, the content of the derivative of biofuel in diesel oil is 50-500ppm, the derivative of biofuel be fatty acid ester A with comprise ethylene glycol, propylene glycol, butyleneglycol, defend that in the dibasic alcohol of two pure and mild condensation ethylene glycol one or both carry out the reaction of ester friendshipizations and must dibasic alcohol fatty acid ester B; Perhaps the biofuel derivative is that fatty acid ester A reacts single substituted amide or the disubstituted amide C that generates with primary amine or diethanolamine respectively; Perhaps the biofuel derivative is the polyol ester D that fatty acid ester A and the polyol reaction that comprises glycerol, Sorbitol Powder, Xylitol, sorbitol, polysaccharide polyol form; Perhaps the derivative of biofuel is the two or more mixture among dibasic alcohol fatty acid ester B, single substituted amide or disubstituted amide C, the polyol ester D.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101305450A CN102229837A (en) | 2011-05-19 | 2011-05-19 | Antiwear agent for petroleum diesel oil and application method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101305450A CN102229837A (en) | 2011-05-19 | 2011-05-19 | Antiwear agent for petroleum diesel oil and application method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102229837A true CN102229837A (en) | 2011-11-02 |
Family
ID=44842444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011101305450A Pending CN102229837A (en) | 2011-05-19 | 2011-05-19 | Antiwear agent for petroleum diesel oil and application method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102229837A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031165A (en) * | 2012-12-12 | 2013-04-10 | 深圳英迪创新科技有限公司 | Fuel additive as well as preparation method and application of fuel additive |
| CN103173254A (en) * | 2011-12-23 | 2013-06-26 | 北京石油化工学院 | Ultra-low-sulfur diesel lubricating property improver and preparation method thereof |
| CN104593104A (en) * | 2014-03-31 | 2015-05-06 | 江苏创新石化有限公司 | Fatty acid ester diesel fuel anti-wear agent preparation method |
| CN105062696A (en) * | 2015-04-16 | 2015-11-18 | 彭才文 | Single-tower countercurrent supercritical non-catalytic continuous esterification process method |
| CN108003950A (en) * | 2016-10-28 | 2018-05-08 | 中国石油化工股份有限公司 | Composition and Dresel fuel compositions and their preparation method with diesel oil abrasion resistance |
| CN108018092A (en) * | 2016-10-28 | 2018-05-11 | 中国石油化工股份有限公司 | Composition and Dresel fuel compositions and their preparation method with diesel oil abrasion resistance |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0798364A1 (en) * | 1996-03-25 | 1997-10-01 | Oronite Japan Limited | Diesel fuel additives and diesel fuel composition |
| US5891203A (en) * | 1998-01-20 | 1999-04-06 | Ethyl Corporation | Fuel lubricity from blends of a diethanolamine derivative and biodiesel |
| EP0773279B1 (en) * | 1995-11-13 | 2006-08-09 | Afton Chemical Limited | Fuel additive |
| CN1990835A (en) * | 2005-12-29 | 2007-07-04 | 中国石油化工股份有限公司 | Application of modified biological diesel oil as low sulfur diesel oil antiwear agent |
| EP1209217B1 (en) * | 2000-11-24 | 2009-02-25 | Clariant Produkte (Deutschland) GmbH | Fuel oils with improved lubricating activity, containing reaction products of fatty acids with short-chained oil-soluble amines |
-
2011
- 2011-05-19 CN CN2011101305450A patent/CN102229837A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0773279B1 (en) * | 1995-11-13 | 2006-08-09 | Afton Chemical Limited | Fuel additive |
| EP0798364A1 (en) * | 1996-03-25 | 1997-10-01 | Oronite Japan Limited | Diesel fuel additives and diesel fuel composition |
| US5891203A (en) * | 1998-01-20 | 1999-04-06 | Ethyl Corporation | Fuel lubricity from blends of a diethanolamine derivative and biodiesel |
| EP1209217B1 (en) * | 2000-11-24 | 2009-02-25 | Clariant Produkte (Deutschland) GmbH | Fuel oils with improved lubricating activity, containing reaction products of fatty acids with short-chained oil-soluble amines |
| CN1990835A (en) * | 2005-12-29 | 2007-07-04 | 中国石油化工股份有限公司 | Application of modified biological diesel oil as low sulfur diesel oil antiwear agent |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103173254A (en) * | 2011-12-23 | 2013-06-26 | 北京石油化工学院 | Ultra-low-sulfur diesel lubricating property improver and preparation method thereof |
| CN103173254B (en) * | 2011-12-23 | 2016-10-12 | 北京石油化工学院 | A kind of ultra-low-sulphur diesel improver for lubricating performance and preparation method thereof |
| CN103031165A (en) * | 2012-12-12 | 2013-04-10 | 深圳英迪创新科技有限公司 | Fuel additive as well as preparation method and application of fuel additive |
| CN103031165B (en) * | 2012-12-12 | 2015-01-07 | 深圳英迪创新科技有限公司 | Fuel additive as well as preparation method and application of fuel additive |
| CN104593104A (en) * | 2014-03-31 | 2015-05-06 | 江苏创新石化有限公司 | Fatty acid ester diesel fuel anti-wear agent preparation method |
| CN105062696A (en) * | 2015-04-16 | 2015-11-18 | 彭才文 | Single-tower countercurrent supercritical non-catalytic continuous esterification process method |
| CN108003950A (en) * | 2016-10-28 | 2018-05-08 | 中国石油化工股份有限公司 | Composition and Dresel fuel compositions and their preparation method with diesel oil abrasion resistance |
| CN108018092A (en) * | 2016-10-28 | 2018-05-11 | 中国石油化工股份有限公司 | Composition and Dresel fuel compositions and their preparation method with diesel oil abrasion resistance |
| CN108003950B (en) * | 2016-10-28 | 2020-04-24 | 中国石油化工股份有限公司 | Composition with diesel anti-wear properties, diesel composition and preparation method thereof |
| CN108018092B (en) * | 2016-10-28 | 2020-04-28 | 中国石油化工股份有限公司 | Compositions with diesel antiwear properties and diesel compositions and methods for their preparation |
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Application publication date: 20111102 |