CN102211837A - Method for treating urban sewage through water step-feed multi-stage aeration biological denitrification and biological filter - Google Patents
Method for treating urban sewage through water step-feed multi-stage aeration biological denitrification and biological filter Download PDFInfo
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- 239000010865 sewage Substances 0.000 title claims abstract description 108
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000005273 aeration Methods 0.000 title claims abstract description 18
- 230000000694 effects Effects 0.000 claims abstract description 12
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 6
- 238000012856 packing Methods 0.000 claims abstract description 4
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 claims description 18
- 239000005416 organic matter Substances 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 9
- 229910052799 carbon Inorganic materials 0.000 abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 5
- 239000010802 sludge Substances 0.000 abstract description 5
- 230000007547 defect Effects 0.000 abstract description 2
- 238000010992 reflux Methods 0.000 abstract description 2
- 239000003344 environmental pollutant Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 description 2
- 238000012851 eutrophication Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000011001 backwashing Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
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Abstract
本发明涉及分段进水多级曝气生物脱氮处理污水方法及生物滤池。本发明生物滤池分隔成三段,每段均包括缺氧区和好氧区,每个区内上部是填料区,底部是承托层,填料区中填放陶粒滤料;各区之间通过过水区连通,在各空间中设曝气装置的为好氧区,其他为缺好氧区,3个缺氧区的底部有进入口。解决了曝气生物滤池需要较大的回流比的缺陷。本发明综合分段进水多级AO活性污泥工艺、曝气生物滤池工艺的技术优点,克服了各自存在的不足,获得了更加高效的污水脱氮效果,将污水碳源优先用于反硝化脱氮,降低了曝气系统曝气量,减小了动力消耗。对于COD在150~200mg/L、TN(总氮)在40~50mg/L的城市污水,其出水COD可保持在40mg/L以下、TN可保持在13mg/L以下,氨氮可保持在3mg/L以下。
The invention relates to a multi-stage aeration biological denitrification method for treating sewage by subsection water inflow and a biofilter. The biofilter of the present invention is divided into three sections, each section includes anoxic zone and aerobic zone, the upper part of each zone is a packing zone, the bottom is a supporting layer, and ceramsite filter material is filled in the packing zone; between the zones Connected through the water-passing area, the aeration device in each space is an aerobic area, and the others are anaerobic areas, and the bottoms of the three anoxic areas have inlets. The defect that the aerated biological filter requires a relatively large reflux ratio is solved. The present invention integrates the technical advantages of the multi-stage AO activated sludge process and the biological aerated filter process, overcomes the shortcomings of each, obtains a more efficient sewage denitrification effect, and preferentially uses the sewage carbon source for denitrification denitrification Nitrogen reduces the aeration volume of the aeration system and reduces power consumption. For urban sewage with a COD of 150-200 mg/L and a TN (total nitrogen) of 40-50 mg/L, the effluent COD can be kept below 40 mg/L, TN can be kept below 13 mg/L, and ammonia nitrogen can be kept at 3 mg/L. Below L.
Description
技术领域technical field
本发明涉及一种城市污水生物脱氮处理的方法与装置,特别涉及一种分段进水多级曝气生物脱氮处理污水方法及生物滤池。The invention relates to a method and device for biological denitrification treatment of urban sewage, in particular to a method for biological denitrification treatment of sewage by segmented water inflow and multi-stage aeration and a biological filter.
背景技术Background technique
控制水体富营养化、改善城市水环境的关键就是控制污染物的排放量,而城市污水处理则起到至关重要的作用。水体富营养化的主要指标是TN、TP,由于化学除磷效果稳定,因此如何更有效的解决生物脱氮问题已迫在眉睫。The key to controlling water eutrophication and improving urban water environment is to control the discharge of pollutants, and urban sewage treatment plays a vital role. The main indicators of water eutrophication are TN and TP. Since the effect of chemical phosphorus removal is stable, how to solve the problem of biological nitrogen removal more effectively is imminent.
在本发明之前已经有分段进水多级AO活性污泥工艺,该工艺脱氮效果明显,处理出水能达到《城镇污水处理厂污染物排放标准》(GB18918-2002)中一级A标准。但一是分段进水多级AO活性污泥法工艺对污水碳氮比要求较高,一般要求污水碳氮比大于5;二是分段进水多级AO活性污泥法工艺作为污水活性污泥法之一,存在对污水碳源利用效率低于生物膜法的问题;三是工艺中需设置沉淀池,而沉淀出水悬浮物(SS)相对于过滤法高;而作为生物膜法的普通曝气生物滤池虽然无需沉淀池及污泥回流,但是无法像AO分段进水工艺那样实现分段进水,有效解决反硝化碳源利用问题。同样,本发明之前已经有曝气生物滤池工艺,该工艺对污水有机物去除能力强,具有污水脱氮的作用,但需要较大的回流比(≥2)才能有较好的脱氮效果。Before the present invention, there has been a multi-stage AO activated sludge process with multi-stage water inflow. This process has obvious denitrification effect, and the treated water can reach the first-class A standard in the "Pollutant Discharge Standards for Urban Sewage Treatment Plants" (GB18918-2002). However, one is that the multi-stage AO activated sludge process of multi-stage water inflow has higher requirements on the carbon-nitrogen ratio of sewage, and the carbon-nitrogen ratio of sewage is generally required to be greater than 5; First, there is a problem that the utilization efficiency of sewage carbon sources is lower than that of the biofilm method; third, a sedimentation tank needs to be set up in the process, and the suspended solids (SS) in the sedimentation water is higher than that of the filtration method; Although the filter does not require sedimentation tanks and sludge return, it cannot achieve segmented water intake like the AO segmented water intake process, which effectively solves the problem of denitrification carbon source utilization. Similarly, before the present invention, there has been a biological aerated filter process, which has a strong ability to remove organic matter in sewage and has the effect of denitrification of sewage, but requires a larger reflux ratio (≥2) to have a better denitrification effect.
发明内容Contents of the invention
本发明的目的就在于克服上述缺陷,设计、研制一种分段进水多级曝气生物脱氮处理城市污水方法及生物滤池。The purpose of the present invention is to overcome the above-mentioned defects, design and develop a multi-stage aerated biological denitrification method for urban sewage treatment and a biofilter.
本发明的技术方案是:Technical scheme of the present invention is:
分段进水多级曝气生物脱氮处理城市污水方法,其主要技术步骤在于:The main technical steps of the multi-stage aeration biological denitrification treatment method for urban sewage by subsection water inflow are as follows:
(1)污水分成三部分分别进入生物滤池的三段,每段均包括缺氧区、好氧区;(1) The sewage is divided into three parts and enters three sections of the biofilter, each section includes anoxic zone and aerobic zone;
(2)第一部分污水与回流污水在第一缺氧区底部合并,在第一缺氧区发生脱除回流污水中硝态氮的作用;(2) The first part of sewage and the return sewage are merged at the bottom of the first anoxic zone, and the effect of removing nitrate nitrogen in the return sewage occurs in the first anoxic zone;
(3)接着污水通过过第一过水区流入第一好氧区,去除污水有机物、氨氮并转化为硝态氮;(3) Then the sewage flows into the first aerobic zone through the first water-passing zone to remove sewage organic matter and ammonia nitrogen and convert them into nitrate nitrogen;
(4)第一部分污水、回流污水通过第二过水区与第二部分污水在第二缺氧区的底部合并进入第二缺氧区,脱除污水中硝态氮;(4) The first part of sewage and the return sewage are merged into the second anoxic zone at the bottom of the second anoxic zone through the second water passing zone and the second part of the sewage to remove nitrate nitrogen in the sewage;
(5)接着第一部分污水、回流污水和第二部分污水通过第三过水区流入第二好氧区,去除污水有机物和氨氮并转化为硝态氮;(5) Then the first part of the sewage, the return sewage and the second part of the sewage flow into the second aerobic zone through the third water passing zone, and remove the sewage organic matter and ammonia nitrogen and convert them into nitrate nitrogen;
(6)接着第一部分污水、回流污水和第二部分污水通过第四过水区进入第三缺氧区的底部与第三部分污水合并,进入第三缺氧区,脱除污水中硝态氮;(6) Then the first part of sewage, return sewage and the second part of sewage enter the bottom of the third anoxic zone through the fourth water passing zone and merge with the third part of sewage, enter the third anoxic zone, and remove nitrate nitrogen in the sewage ;
(7)接着第一部分污水、回流污水、第二部分和第三部分污水通过第五过水区流入第三好氧区,去除污水有机物和氨氮并转化为硝态氮;(7) Then the first part of the sewage, the return sewage, the second part and the third part of the sewage flow into the third aerobic zone through the fifth water passing zone, and the organic matter and ammonia nitrogen of the sewage are removed and converted into nitrate nitrogen;
(8)污水经过上述处理后一部分通过出水管排出,另一部分通过回流管回流至第一缺氧区底部。(8) After the above treatment, part of the sewage is discharged through the outlet pipe, and the other part is returned to the bottom of the first anoxic zone through the return pipe.
本发明另一技术方案是:Another technical scheme of the present invention is:
所述生物滤池,其主要技术特征在于生物滤池分隔成三段,每段均包括缺氧区和好氧区,每个区内上部是填料区,底部是承托层,填料区中填放陶粒滤料;各区之间通过过水区连通,在各空间中设曝气装置的为好氧区,其他为缺好氧区,3个缺氧区的底部有进入口。The main technical feature of the biofilter is that the biofilter is divided into three sections, each section includes an anoxic zone and an aerobic zone, the upper part of each zone is a packing area, the bottom is a supporting layer, and the filling area is filled with Put the ceramsite filter material; each area is connected through the water area, and the aeration device in each space is an aerobic area, and the others are anaerobic areas, and the bottom of the three anoxic areas has inlets.
本发明专利是一种分段进水多级曝气生物滤池,共有三段,每段均由缺氧区和好氧区组成,原污水分成三部分分别从每段的缺氧区底部进水;三段曝气生物滤池均从底部进水,上部出水;缺氧区由下至上依次为配水区、承托板、滤料层,承托板上装有滤头,承托板与滤料层之间为承托层;好氧区由下至上依次为配水区、承托板、滤料层,承托板上装有滤头,承托板与滤料层之间为承托层,配水区底部安装有穿孔曝气管。污水流经一级缺氧区后,经连通区流入一级好氧区,依次进入二、三级处理区,完成对污水的净化。The patent of the present invention is a segmented multi-stage aerated biological filter, which has three sections, each section is composed of anoxic zone and aerobic zone, and the raw sewage is divided into three parts to enter water from the bottom of the anoxic zone of each section; The three-stage biological aerated filter all enters water from the bottom and leaves water from the upper part; the anoxic zone consists of water distribution area, support plate and filter material layer from bottom to top. The support plate is equipped with filter head, support plate and filter material layer The support layer is in between; the aerobic area is the water distribution area, the support plate, and the filter layer from bottom to top. The filter head is installed on the support plate, and the support layer is between the support plate and the filter material layer. The water distribution area Perforated aeration tubes are installed at the bottom. After the sewage flows through the first-level anoxic zone, it flows into the first-level aerobic zone through the connecting zone, and then enters the second and third-level treatment zones in turn to complete the purification of sewage.
本发明的技术创新的本质是综合分段进水多级AO活性污泥工艺、曝气生物滤池工艺的技术优点,克服了传统多级AO活性污泥工艺对污水碳源利用率不高、曝气生物滤池不能对污水深度脱氮的不足,通过集合二者的优点,去除二者的不足,获得了更加高效的污水脱氮效果。特别对碳氮比在3~5之间的污水脱氮效果依然显著,取得了1加1大于2的技术效果,产生了一种处理效果更优的污水生物脱氮工艺技术。The essence of the technical innovation of the present invention is to integrate the technical advantages of the multi-stage AO activated sludge process of water inflow and the biological aerated filter process. The biological filter can't denitrify the sewage deeply. By combining the advantages of the two, the deficiencies of the two can be eliminated, and a more efficient sewage denitrification effect can be obtained. In particular, the denitrification effect of sewage with a carbon-to-nitrogen ratio between 3 and 5 is still significant, and the technical effect of 1 plus 1 greater than 2 has been achieved, and a sewage biological denitrification process technology with better treatment effect has been produced.
本发明解决了低氮碳比城市污水反硝化碳源问题,将污水碳源优先用于反硝化脱氮,降低了曝气系统曝气量,减小了动力消耗。对于COD在150~200mg/L、TN(总氮)在40~50mg/L的城市污水,其出水COD可保持在40mg/L以下、TN可保持在13mg/L以下,氨氮可保持在3mg/L以下,低于《城镇污水处理厂污染物排放标准》(GB18918-2002)中一级A标准。The invention solves the problem of the denitrification carbon source of urban sewage with low nitrogen-to-carbon ratio, preferentially uses the sewage carbon source for denitrification and denitrification, reduces the aeration volume of the aeration system, and reduces power consumption. For urban sewage with a COD of 150-200mg/L and a TN (total nitrogen) of 40-50mg/L, the effluent COD can be kept below 40mg/L, TN can be kept below 13mg/L, and ammonia nitrogen can be kept at 3mg/L. Below L, lower than the Class A standard in the "Pollutant Discharge Standards for Urban Sewage Treatment Plants" (GB18918-2002).
附图说明Description of drawings
图1——本发明分段进水多级曝气生物滤池示意图。Fig. 1 ——Schematic diagram of multi-stage biological aerated filter with multi-stage water inflow in the present invention.
图中各标号所示:Each label in the figure shows:
第一缺氧区1、第一过水区2、第一好氧区3、第二过水区4、第二缺氧区5、第三过水区6、第二好氧区7、第四过水区8、第三缺氧区9、第五过水区10、第三好氧区11、第一承托层12、第二承托层13;第三承托层14、第四承托层15、第五承托层16、第六承托层17、进水系统18、曝气系统19、出水管20、回流管21、回流泵22、反冲洗系统23。The first anoxic zone 1, the first water-
具体实施方式Detailed ways
本发明的技术思路是依据生物脱氮的硝化与反硝化原理,借鉴了AO工艺分段进水在缺氧段补充反硝化碳源的构思,从而与曝气生物滤池相结合,两者互补,产生协同作用,从而达到更好的生物脱氮效果。The technical idea of the present invention is based on the principle of nitrification and denitrification of biological denitrification, and draws lessons from the concept of supplementing the denitrification carbon source in the anoxic section of the AO process, so as to combine with the biological aerated filter, and the two complement each other to produce Synergistic effect, so as to achieve better biological denitrification effect.
具体说明如下。The details are as follows.
如图1所示:As shown in Figure 1:
本发明中的生物滤池分为三段,每段均有缺氧区和好氧区;第一段包括第一缺氧区1、承托层12、第一过水区2、第一好氧区3、第二承托层13、第二过水区4;第二段包括第二缺氧区5、第三承托层14、第三过水区6、第二好氧区7、第四承托层15、第四过水区8;第三段包括第三缺氧区9、第五承托层16、第五过水区10、第三好氧区11、第六承托层17;进水系统18分别连通每段的底部;曝气系统19分别从每个过水区顶部向下布设与第一好氧区3.第二好氧区7、第三好氧区11连通;出水管20设置于第三好氧区11的上部;回流管21从第三好氧区11的上部通过回流水泵22连接至第一缺氧区1的底部;反冲洗系统23分别连通每段的底部。上述结构构成生物滤池。The biofilter in the present invention is divided into three sections, each section has anoxic zone and aerobic zone;
具体方法如下:The specific method is as follows:
污水通过进水系统18分成三部分分别进入生物滤池,第一部分污水进入第一缺氧区1的底部,第二部分污水进入第二缺氧区5的底部,第三部分污水进入第三缺氧区9的底部;第一部分污水与回流污水在第一缺氧区1底部合并,在第一缺氧区1发生脱除回流污水中硝态氮的作用;接着在第一缺氧区1处理过的污水通过第一过水区2流入第一好氧区3,去除污水有机物、氨氮转化为硝态氮的作用,在此通过曝气系统19保持水中溶解氧浓度为2mg/L;第一部分污水、回流污水通过第二过水区4与第二部分污水在第二缺氧区5的底部合并进入第二缺氧区5,脱除污水中硝态氮;接着第一部分污水、回流污水和第二部分污水通过第三过水区6流入第二好氧区7,去除污水有机物和氨氮并转化为硝态氮,在此通过曝气系统19保持水中溶解氧浓度为2mg/L;接着第一部分污水、回流污水和第二部分污水通过第四过水区8进入第三缺氧区9的底部与第三部分污水合并,进入第三缺氧区9,脱除污水中硝态氮;接着第一部分污水、回流污水、第二部分和第三部分污水通过第五过水区10流入第三好氧区11,去除污水有机物和氨氮并转化为硝态氮,曝气系统19保持水中溶解氧浓度为2mg/L;污水经过上述处理后一部分通过出水管排出,另一部分通过回流管21回流至第一缺氧区1底部。The sewage is divided into three parts through the
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| CN103319047A (en) * | 2013-06-29 | 2013-09-25 | 惠州市众惠环保工程有限公司 | Landfill leachate treatment system |
| CN104071897A (en) * | 2014-07-21 | 2014-10-01 | 太原理工大学 | Coking wastewater treatment process by step water inlet multistage anoxic/aerobic biofilm process |
| CN104609560A (en) * | 2015-02-15 | 2015-05-13 | 华东理工大学 | Method for performing nitrogen biological removal on low-temperature low-carbon nitrogen ratio sewage |
| CN104628136A (en) * | 2015-02-15 | 2015-05-20 | 华东理工大学 | Biological enhanced nitrogen removal treatment method of degradation-resistant high-concentration organic industrial wastewater |
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| CN104628136A (en) * | 2015-02-15 | 2015-05-20 | 华东理工大学 | Biological enhanced nitrogen removal treatment method of degradation-resistant high-concentration organic industrial wastewater |
| CN104609560B (en) * | 2015-02-15 | 2017-04-12 | 华东理工大学 | Method for performing nitrogen biological removal on low-temperature low-carbon nitrogen ratio sewage |
| CN104628136B (en) * | 2015-02-15 | 2017-04-19 | 华东理工大学 | Biological enhanced nitrogen removal treatment method of degradation-resistant high-concentration organic industrial wastewater |
| CN105541008A (en) * | 2015-12-22 | 2016-05-04 | 浙江大学 | An efficient denitrifying and carbon-removing device for culture wastewater anaerobic biogas slurry with a low C/N ratio and a process thereof |
| CN105541008B (en) * | 2015-12-22 | 2017-12-26 | 浙江大学 | The low C/N of breeding wastewater is than anaerobism biogas slurry efficient denitrification carbon removal treatment technique |
| CN105668943B (en) * | 2016-04-01 | 2018-12-25 | 福州大学 | For the multi-stage aeration biological filter tank of purification of water quality and its purification process |
| CN105668943A (en) * | 2016-04-01 | 2016-06-15 | 福州大学 | Multistage aeration biofilter for water quality purification and purification technique thereof |
| CN106348522A (en) * | 2016-08-25 | 2017-01-25 | 广西壮族自治区环境保护科学研究院 | Low-energy-consumption intensifying-denitrifying integrated reactor |
| CN108046538A (en) * | 2017-12-29 | 2018-05-18 | 桑德生态科技有限公司 | A kind of rural domestic sewage treatment system and method |
| CN110104893A (en) * | 2019-05-29 | 2019-08-09 | 临邑禹王植物蛋白有限公司 | A kind of sewage water treatment method and system for use in carrying using AO technique drop total nitrogen |
| CN119612765A (en) * | 2024-11-26 | 2025-03-14 | 中冶赛迪工程技术股份有限公司 | High-concentration degradation-resistant wastewater treatment system |
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