CN1021431C - Method for manufacturing colored glaze sand - Google Patents
Method for manufacturing colored glaze sand Download PDFInfo
- Publication number
- CN1021431C CN1021431C CN 87107814 CN87107814A CN1021431C CN 1021431 C CN1021431 C CN 1021431C CN 87107814 CN87107814 CN 87107814 CN 87107814 A CN87107814 A CN 87107814A CN 1021431 C CN1021431 C CN 1021431C
- Authority
- CN
- China
- Prior art keywords
- glaze
- sand
- colored glaze
- red lead
- quartz
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004576 sand Substances 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000006004 Quartz sand Substances 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 6
- 238000005245 sintering Methods 0.000 claims abstract description 6
- 239000010433 feldspar Substances 0.000 claims abstract description 5
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 4
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910021538 borax Inorganic materials 0.000 claims abstract description 3
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 3
- 239000010436 fluorite Substances 0.000 claims abstract description 3
- 239000011133 lead Substances 0.000 claims abstract description 3
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 abstract description 4
- 239000011230 binding agent Substances 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract description 2
- 238000005034 decoration Methods 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 5
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000002932 luster Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- JOSWYUNQBRPBDN-UHFFFAOYSA-P ammonium dichromate Chemical compound [NH4+].[NH4+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O JOSWYUNQBRPBDN-UHFFFAOYSA-P 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229960004643 cupric oxide Drugs 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Finishing Walls (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention provides a method for preparing colored glaze sand, which is characterized in that a layer of colored glaze is attached to the outer surface of quartz sand, and the method comprises the steps of firstly preparing the colored glaze material, then adding water or a binder, uniformly stirring the quartz sand, sintering at the temperature of 900 ℃ for processing materials with 620 ℃ and cooling. The glaze formula comprises red lead, feldspar, quartz powder, borax and colorant, wherein at least one of calcite, fluorite and kaolin is added, and the red lead accounts for 20-80% of the total weight. Compared with the existing colored glaze sand, the colored glaze sand prepared by the invention has the advantages of good color, low cost, multiple varieties and firm glaze combination, and is particularly suitable for being used as building decoration materials.
Description
The invention belongs to agglomerated material for building, especially the manufacture method of coloured glaze sand.
Present domestic a kind of color-enamel sand that has, it utilizes " involucrum pigment " technology and the Chinese pottery glaze technology of the U.S., burns till glaze sand with red lead, and the system of reburning one deck ceramic glaze is made the electric furnace sintering.This color-enamel sand once obtained in 1986 You Lika invention gold medal.But this color-enamel sand color and luster is relatively poor, need fire 1-3 time, complex process, and kind is few, the energy consumption height.
The purpose of this invention is to provide the manufacture method of a kind of novel sintered material-coloured glaze sand, its sintering temperature is low, and technology is simple, and cost is lower, and the glaze color and luster is good, and in conjunction with firm.
Technical essential of the present invention is: the outside mortise one deck gluzed enamel that makes quartz sand aggregate.Concrete grammar is: be mixed with the coloured glaze glaze with certain particle size with starting material earlier, add suitable quantity of water and/or tackiness agent, quartz sand then, mix thoroughly, under certain atmosphere (oxidation or reducing atmosphere), fire, cooling forms, and the coloured glaze glaze can be prepared earlier, the thin mixing of regrinding, also can earlier levigately prepare burden mixing again.Sintering temperature is 620-1200 ℃, is preferably 650-900 ℃.Add red lead, feldspar, silica powder, borax in its glaze formula, in addition, add one of them at least in three kinds in the calcite, fluorite, kaolin.Red lead accounts for the 20-80% of gross weight, and tackiness agent adopts polyvinyl alcohol water solution, four carbonoxides etc.
Satisfy different needs for producing other different colors, can add tinting material in glaze, this tinting material can be solid metal, metal oxide and metallic salt, as adding MnO, potassium permanganate, Cr
2O
3, CO
2O
3, CuO, Fe
2O
3, BaCO
3, Mn, Ba, Cr, potassium bichromate, ammonium dichromate, SnO, CdS, U
2O
3, U
2O
4Deng, can add wherein one or more.In order further to stablize its quality, in the coloured glaze glaze or after adding quartz sand, also stablizer can be added again, as TiO
2, Fe
2O
3, ZnO, MgO etc.
Advantage of the present invention is, firing temperature is low, wide ranges, but once-firing, and technology is simple, and cost is low, and coloured glaze sand color and luster is better, and is wide in variety, and glaze is in conjunction with firmly.Be particularly suitable for doing material of construction.
Below be the embodiment of coloured glaze sand manufacture method.
Embodiment 1, bright red coloured glaze sand blending process (%): red lead 65, Cr
2O
312.Silica powder 10, feldspar 9, kaolin 20 after mixing is levigate, added quartz sand 1: 10, mixed all, added suitable quantity of water, 650 ℃ of sintering, oxidizing atmosphere, insulation, coming out of the stove water spray cooling (but air cooling) sometimes.
Embodiment 2: true yellow coloured glaze sand preparation (%): red lead 80.5, calcite 2, Cr
2O
36, silica powder 9, cupric oxide 0.5, Feldspar Powder 1, yellow soda ash 1 behind the levigate mixing, adds quartz sand with 6: 100 ratios, mixes thoroughly, adds suitable amount of adhesive, in oxidizing atmosphere, in 750 ℃ of sintered heat insulatings, the water-cooled of coming out of the stove.
Make aggregate with coloured glaze sand, add white sand, binding agent, sanitas etc. again and be mixed with coating, do outer wall building coating.
Claims (4)
1, a kind of manufacture method of coloured glaze sand, it is characterized in that being mixed with the coloured glaze glaze with starting material earlier, add suitable quantity of water and/or tackiness agent then, quartz sand is mixed all, under 620-1200 ℃ of temperature and oxidation or reducing atmosphere, fire, cool off and form, red lead, feldspar, silica powder, borax and tinting material are arranged in the glaze formula, at least add one of them in three kinds in the calcite, fluorite, kaolin, red lead accounts for the 20-80.5% of gross weight.
2, method according to claim 1 is characterized in that tackiness agent is a polyvinyl alcohol water solution, tetracol phenixin.
3, method according to claim 1 is characterized in that sintering temperature is 650-900 ℃.
4, according to claim 1,2,3 or 4 described methods, it is characterized in that adding in the glaze formula stablizer, stablizer uses TiO
2, Fe
2O
3, ZnO or MgO.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 87107814 CN1021431C (en) | 1987-11-13 | 1987-11-13 | Method for manufacturing colored glaze sand |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 87107814 CN1021431C (en) | 1987-11-13 | 1987-11-13 | Method for manufacturing colored glaze sand |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1033041A CN1033041A (en) | 1989-05-24 |
| CN1021431C true CN1021431C (en) | 1993-06-30 |
Family
ID=4816248
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 87107814 Expired - Fee Related CN1021431C (en) | 1987-11-13 | 1987-11-13 | Method for manufacturing colored glaze sand |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1021431C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1325411C (en) * | 2006-03-09 | 2007-07-11 | 胡祥仁 | Multicolor glass sand for building decoration |
| CN106242306A (en) * | 2016-08-08 | 2016-12-21 | 太仓市科教新城琉璃艺术策划中心 | Chromatophilous coloured glaze |
| CN110194902A (en) * | 2019-05-30 | 2019-09-03 | 广东涂耐可建筑涂料有限公司 | A kind of high-temperature calcination coloring color sand and its production method |
-
1987
- 1987-11-13 CN CN 87107814 patent/CN1021431C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1033041A (en) | 1989-05-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |