CN102102239A - Method for manufacturing inorganic nano germanium-containing polyester fibers - Google Patents
Method for manufacturing inorganic nano germanium-containing polyester fibers Download PDFInfo
- Publication number
- CN102102239A CN102102239A CN2009102015621A CN200910201562A CN102102239A CN 102102239 A CN102102239 A CN 102102239A CN 2009102015621 A CN2009102015621 A CN 2009102015621A CN 200910201562 A CN200910201562 A CN 200910201562A CN 102102239 A CN102102239 A CN 102102239A
- Authority
- CN
- China
- Prior art keywords
- inorganic nano
- germanium
- germanic
- containing polyester
- polyester fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 45
- 239000000835 fiber Substances 0.000 title claims abstract description 32
- 229910052732 germanium Inorganic materials 0.000 title claims abstract description 22
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000009987 spinning Methods 0.000 claims abstract description 20
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 238000007380 fibre production Methods 0.000 claims abstract description 4
- 238000001291 vacuum drying Methods 0.000 claims abstract 2
- 239000000843 powder Substances 0.000 claims description 11
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 229920002959 polymer blend Polymers 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 1
- 239000004594 Masterbatch (MB) Substances 0.000 abstract description 6
- 210000003205 muscle Anatomy 0.000 abstract description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 150000002500 ions Chemical class 0.000 abstract description 3
- 229910052726 zirconium Inorganic materials 0.000 abstract description 3
- 230000036760 body temperature Effects 0.000 abstract description 2
- 230000004060 metabolic process Effects 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract description 2
- 230000017531 blood circulation Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000011858 nanopowder Substances 0.000 abstract 1
- 238000009413 insulation Methods 0.000 description 9
- 238000010792 warming Methods 0.000 description 7
- 150000001450 anions Chemical class 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- 230000001788 irregular Effects 0.000 description 2
- 208000014994 muscles ache Diseases 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 235000012771 pancakes Nutrition 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Abstract
The invention provides a method for manufacturing inorganic nano germanium-containing polyester fibers. In the method, a special inorganic nano germanium-containing polyester master batch is blended with polyester chips in percentage by weight, vacuum drying is performed in a gradual heating process, a polyester fiber production process is applied, the spinning temperature is 270 to 295 DEG C, and the drawing times is 3.6 to 4.5 times. The long-acting functional inorganic nano germanium-containing polyester fibers formed by mixed development of germanium and zirconium composite inorganic nano powder can promote human metabolism, relieve fatigue feeling, promote blood circulation, assuage muscle sore and fatigue and relax muscles to assist sleeping. When the textiles with the inorganic nano germanium-containing polyester fibers are worn, the concealed germanium metal energy with permanent effect is continuously released due to human body temperature so as to provide healthy electrode negative ions for the human body.
Description
Technical field
The present invention relates to textile industry, relate in particular to the manufacture method of the germanic polyester fiber of a kind of inorganic nano of synthetic fiber production field.
Background technology
Along with people's living standard day by day improves, more and more higher to the requirement of health, health, beauty treatment, health care, environmental protection are that main material obtains further extensively and dark people's research.Germanium metal is a kind of semiconductor element, do not contain toxicity, its characteristic is only can discharge anion for 32 ℃ at normal temperature, because the outermost track of germanium has 4 electronics irregular movements, the temperature more than 32 ℃ will stimulate wherein 1 negatron of 4 electronics to de-orbit.Germanium metal can Yin Wendu (heat), the power of light, electromagnetic wave etc. and make negative free ion often change and disengage, and our health also can be got used to its variation.The germanic polyester fiber of inorganic nano of the long-acting type function that utilization germanium metal and zirconia inorganic nanometer powder (can excite the releasing far infrared and anion of germanium energy) mixed developing form, can stimulate circulation, thus have relax muscles ache, tired and relax one's muscles and help to fall asleep.The up-to-date nanometer technology of the germanic polyester fiber utilization of inorganic nano, after germanium metal and zirconia be main material micronizing, make the composite nano inoganic powder, make the inorganic nano master batch of high-load, then with the polyester blend spinning, germanic polyester fiber is made, utilize the activity and the antioxidant effect of germanium, the germanic polyester fiber of inorganic nano can promote human body metabolism, slow down sense of fatigue, when we dress these textiless, can will contain interior because of body temperature, the germanium metal energy with permanent effect discharges continually provides the electrode of human body beneficial's health anion.
Summary of the invention
The object of the present invention is to provide the manufacture method of the germanic polyester fiber of a kind of inorganic nano.
The present invention at first wants the germanic polyester master particle of special inorganic nano, with germanium metal and zirconia is main material micronizing, grind to form 100～300 nanometer grade powders, these two kinds of powders are mixed and made into powder mixture, powder mixture by weight 20-30: 80-70 and fibre-forming polymer blend, is processed into the master batch that is applicable to that polyester fiber is produced through special process again.Special master batch and polyester slice blend are made into the germanic polyester fiber of inorganic nano through the polyester fiber production technology.
The germanic polyester fiber technological process of production of inorganic nano is: with the germanic polyester master particle of inorganic nano with percentage by weight 8%～15% and polyester slice blend, after vacuumize, fusion, spinning machine spinning, obtain as-spun fibre to the up-coiler bucket of reeling, fall by the path.Spin before this in process, spinning temperature is 270 ℃～295 ℃, with 275 ℃～285 ℃ be good, spinning speed is 1100～1500 meters/minute.Through drawing-off, curl, cut off and make the germanic polyester fiber of inorganic nano.Drafting multiple of the present invention is 3.6～4.5 times.
The germanic polyester fiber of inorganic nano of the present invention cross section can be any cross section of known melt spinning, as circle, triangle, trilobal cross, hollow shape, pancake,, L shaped, T shape, W shape, polygon, dog bone shape or the like.Its monofilament fineness was 0.8 dawn～10 dawn.
Technical characterstic of the present invention: 1. germanium metal is a kind of semiconductor element, do not contain toxicity, its characteristic is only can discharge anion for 32 ℃ at normal temperature, because the outermost track of germanium has 4 electronics irregular movements, the temperature more than 32 ℃ will stimulate wherein 1 negatron of 4 electronics to de-orbit.Germanium can Yin Wendu (heat), the power of light, electromagnetic wave etc. and make negative free ion often change and disengage; Zirconium can excite the releasing far infrared and anion of germanium energy, the germanic polyester fiber of inorganic nano of the long-acting type function that utilization germanium and zirconium composite nano inoganic powder mixed developing form, can stimulate circulation, relax muscles ache, tired and relax one's muscles and help to fall asleep.
2. an amount of multiple human body trace elements necessary such as selenium, magnesium, cobalt, chromium, manganese, copper, Ni-V-Fe that import in inorganic nano material play a role in health care by skin absorbs.
The specific embodiment
Embodiment 1
The production fiber number is the germanic polyester fiber of hollow type inorganic nano of 6.67 DENIER (dtex).
Is that 15% ratio is added in the polyester slice with the germanic master batch of special inorganic nano with percentage by weight, carry out vacuumize, elder generation's constant temperature was 100 ℃ of insulations 1 hour, be warming up to 130 ℃ of insulations 3 hours, progressively be warming up to 145 ℃ of insulations to obtaining dry crystallization section, dry run generally needs 12 hours.Use existing spinning equipment, i.e. spinning on the LHV451 spinning machine, spinning temperature is 272 ℃, winding speed is 1200m/min, drawing-off on LHV903 first break draft machine, drafting multiple is 4.3 times, obtains the germanic polyester fiber of trilobal cross inorganic nano of 6.67 DENIER (dtex).
Embodiment 2
The production fiber number is the germanic polyester fiber of inorganic nano of 0.89 DENIER (dtex).
Is that 8% ratio is added in the polyester slice with the germanic polyester master particle of special inorganic nano with percentage by weight, carry out vacuumize, be warming up to 80 ℃ of insulations 1 hour earlier, be warming up to 120 ℃ of insulations 2 hours, progressively be warming up to 145 ℃ of insulations to obtaining dry crystallization section, dry run generally needs 14 hours.Use existing spinning equipment, i.e. spinning on the LHV451 spinning machine, coiling and molding is an as-spun fibre again, spinning temperature is 280 ℃, and winding speed is 1350m/min, drawing-off on LHV903 first break draft machine, drafting multiple is 3.8 times, obtains the germanic polyester fiber of 0.89dtex inorganic nano.
Embodiment 3
The production fiber number is the germanic polyester fiber of cross inorganic nano of 1.67 DENIER (dtex).
Is that 12% ratio is added in the polyester slice with the germanic master batch of special inorganic nano with percentage by weight, carry out vacuumize, elder generation's constant temperature was 60 ℃ of insulations 1 hour, be warming up to 100 ℃ of insulations 2 hours, progressively be warming up to 145 ℃ of insulations to obtaining dry crystallization section, dry run generally needs 14 hours.Use existing spinning equipment, i.e. spinning on the LHV451 spinning machine, used spinning spinneret is cross spinnerets, spinning temperature is 280 ℃, winding speed is 1300m/min, drawing-off on LHV903 first break draft machine, drafting multiple is 3.8 times, obtains the germanic polyester fiber of the cross inorganic nano of 1.67dtex.
The manufacture method of the germanic polyester fiber of a kind of inorganic nano of the present invention is not limited to above embodiment.
Claims (3)
1. the manufacture method of the germanic polyester fiber of inorganic nano, use the polyester fiber production technology, it is characterized in that the germanic polyester master particle of inorganic nano with percentage by weight and polyester slice blend, adopt vacuum drying process to carry out drying, spinning temperature is controlled at 270 ℃～295 ℃, and drafting multiple is 3.6～4.5 times.
2. the manufacture method of the germanic polyester fiber of a kind of inorganic nano according to claim 1, it is characterized in that: the germanic polyester master particle of described inorganic nano is for being the material micronizing of leading with germanium metal and zirconia, grind to form 100～300 nanometer grade powders, these two kinds of powders are mixed and made into powder mixture, powder mixture is made by weight 20-30: 80-70 and fibre-forming polymer blend.
3. the manufacture method of the germanic polyester fiber of a kind of inorganic nano according to claim 1 is characterized in that: the germanic polyester master particle percentage by weight of described inorganic nano is 8%～15%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009102015621A CN102102239A (en) | 2009-12-22 | 2009-12-22 | Method for manufacturing inorganic nano germanium-containing polyester fibers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009102015621A CN102102239A (en) | 2009-12-22 | 2009-12-22 | Method for manufacturing inorganic nano germanium-containing polyester fibers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102102239A true CN102102239A (en) | 2011-06-22 |
Family
ID=44155289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009102015621A Pending CN102102239A (en) | 2009-12-22 | 2009-12-22 | Method for manufacturing inorganic nano germanium-containing polyester fibers |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102102239A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102747447A (en) * | 2012-05-14 | 2012-10-24 | 毛盈军 | Cooling and chilling fiber, preparation method thereof, and textile product thereof |
| CN103275462A (en) * | 2013-06-18 | 2013-09-04 | 许东东 | Preparation method for polyester fiber color master batch having effects of increasing blood circulation and resisting fatigue |
| CN103352377A (en) * | 2013-07-09 | 2013-10-16 | 熊银河 | Titanium-germanium alloy yarn textile fabric and preparation method thereof |
| CN105862162A (en) * | 2016-05-31 | 2016-08-17 | 江南大学 | Method for preparing Ge-containing composite health fiber |
| CN106854778A (en) * | 2016-12-28 | 2017-06-16 | 厦门安踏体育用品有限公司 | The manufacture method of negative ion antibiotic polyester fiber, polyester fiber, fabric and clothes |
| CN111118666A (en) * | 2020-01-07 | 2020-05-08 | 常宁市科博织造有限公司 | Germanium-containing decompression anti-fatigue fiber and preparation method thereof |
| CN112877847A (en) * | 2021-01-11 | 2021-06-01 | 佳莱科技有限公司 | Beauty yarn and preparation method thereof and fabric |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1081480A (en) * | 1993-07-19 | 1994-02-02 | 珠海经济特区天年高科技产业公司 | Super-fine biochemical mixture and microelement biological fiber thereof |
| CN1108316A (en) * | 1994-03-11 | 1995-09-13 | 江苏省纺织研究所 | Far-infrared radiation polyester fibre |
| CN101067226A (en) * | 2007-06-08 | 2007-11-07 | 南京中脉科技发展有限公司 | Far infrared fiber containing Ge element and producing method thereof |
| CN101070641A (en) * | 2007-06-12 | 2007-11-14 | 江苏盛虹化纤有限公司 | Comprehensive-function polytrimethylene terephthalate fiber and fabric thereof |
| KR20080042635A (en) * | 2006-11-09 | 2008-05-15 | 최명부 | Functional composition polyester spinning yarn manufacturing method |
| CN101307510A (en) * | 2007-05-18 | 2008-11-19 | 上海德福伦化纤有限公司 | Process for preparing bamboo charcoal fiber |
-
2009
- 2009-12-22 CN CN2009102015621A patent/CN102102239A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1081480A (en) * | 1993-07-19 | 1994-02-02 | 珠海经济特区天年高科技产业公司 | Super-fine biochemical mixture and microelement biological fiber thereof |
| CN1108316A (en) * | 1994-03-11 | 1995-09-13 | 江苏省纺织研究所 | Far-infrared radiation polyester fibre |
| KR20080042635A (en) * | 2006-11-09 | 2008-05-15 | 최명부 | Functional composition polyester spinning yarn manufacturing method |
| CN101307510A (en) * | 2007-05-18 | 2008-11-19 | 上海德福伦化纤有限公司 | Process for preparing bamboo charcoal fiber |
| CN101067226A (en) * | 2007-06-08 | 2007-11-07 | 南京中脉科技发展有限公司 | Far infrared fiber containing Ge element and producing method thereof |
| CN101070641A (en) * | 2007-06-12 | 2007-11-14 | 江苏盛虹化纤有限公司 | Comprehensive-function polytrimethylene terephthalate fiber and fabric thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102747447A (en) * | 2012-05-14 | 2012-10-24 | 毛盈军 | Cooling and chilling fiber, preparation method thereof, and textile product thereof |
| CN103275462A (en) * | 2013-06-18 | 2013-09-04 | 许东东 | Preparation method for polyester fiber color master batch having effects of increasing blood circulation and resisting fatigue |
| CN103275462B (en) * | 2013-06-18 | 2015-06-03 | 许东东 | Preparation method for polyester fiber color master batch having effects of increasing blood circulation and resisting fatigue |
| CN103352377A (en) * | 2013-07-09 | 2013-10-16 | 熊银河 | Titanium-germanium alloy yarn textile fabric and preparation method thereof |
| CN103352377B (en) * | 2013-07-09 | 2016-01-20 | 熊银河 | A kind of titanium germanium alloy yarn textiles cloth and preparation method thereof |
| CN105862162A (en) * | 2016-05-31 | 2016-08-17 | 江南大学 | Method for preparing Ge-containing composite health fiber |
| CN106854778A (en) * | 2016-12-28 | 2017-06-16 | 厦门安踏体育用品有限公司 | The manufacture method of negative ion antibiotic polyester fiber, polyester fiber, fabric and clothes |
| CN111118666A (en) * | 2020-01-07 | 2020-05-08 | 常宁市科博织造有限公司 | Germanium-containing decompression anti-fatigue fiber and preparation method thereof |
| CN112877847A (en) * | 2021-01-11 | 2021-06-01 | 佳莱科技有限公司 | Beauty yarn and preparation method thereof and fabric |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102031581B (en) | Method for producing super-refreshing cool-feel health care polyester fiber | |
| CN102102239A (en) | Method for manufacturing inorganic nano germanium-containing polyester fibers | |
| CN105908269B (en) | Manufacturing method of special-shaped hollow warmth keeping polyester drawn textured yarn | |
| CN102534848B (en) | Production method of coffee polyester multifunctional fiber | |
| CN102560720A (en) | Method for manufacturing inorganic nanometer seaweed carbon polyester fiber | |
| CN102031584A (en) | Method for preparing composite antibacterial polyester fiber from nano zinc oxide and titanium dioxide | |
| CN101671858A (en) | Method for manufacturing coconut carbon fibre | |
| CN102634863B (en) | Constant-pressure positive ion dyeable cooling polyester filament yarn and production method thereof | |
| CN101748512A (en) | Polyester composite fiber and method for producing same | |
| CN101307510A (en) | Process for preparing bamboo charcoal fiber | |
| CN103653279A (en) | Underwear and production method thereof | |
| CN108221078A (en) | A kind of manufacturing method of polyester filament | |
| CN103114360B (en) | A kind of linen-cotton mixes the preparation method of yarn | |
| CN109355729A (en) | A kind of manufacturing method of Tai Ji stone and polyester fiber composite material | |
| CN102031580A (en) | Method for manufacturing anti-ultraviolet polyester fibers | |
| CN104153036A (en) | Antibacterial polyester wool top and manufacturing method thereof | |
| CN101314873A (en) | Preparation of polypropylene nano-magnetic fibre | |
| CN102560723A (en) | Production method of inorganic nanometer quantum energy healthy functional polyester fiber | |
| CN101343780A (en) | Chinese aloe viscose fiber and preparation thereof | |
| CN105887231B (en) | A kind of manufacture method of fused mass directly spinning high strength polyester filament yarn | |
| CN102409430B (en) | Cross cool easy cation-dyeable polyester (ECDP) fiber and production method thereof | |
| CN104328599B (en) | A kind of composite three-layer screen cloth and manufacture method thereof | |
| CN109082728A (en) | A kind of vegetable protein nanofiber and preparation method thereof containing graphene | |
| CN105862167A (en) | Production method of antistatic/noctilucent bifunctional low stretch yarns | |
| CN102443875A (en) | Uvioresistant fiber and production method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110622 |