CN102051274B - Solid water-saving toilet cleaner - Google Patents
Solid water-saving toilet cleaner Download PDFInfo
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- CN102051274B CN102051274B CN 200910198517 CN200910198517A CN102051274B CN 102051274 B CN102051274 B CN 102051274B CN 200910198517 CN200910198517 CN 200910198517 CN 200910198517 A CN200910198517 A CN 200910198517A CN 102051274 B CN102051274 B CN 102051274B
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- weight ratio
- solid water
- sodium
- cleaning agent
- active agent
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- 239000007787 solid Substances 0.000 title claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 9
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 9
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 9
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 7
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims abstract description 5
- 229940045870 sodium palmitate Drugs 0.000 claims abstract description 4
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 claims abstract description 4
- 244000060011 Cocos nucifera Species 0.000 claims abstract description 3
- 235000013162 Cocos nucifera Nutrition 0.000 claims abstract description 3
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 claims abstract description 3
- 239000012459 cleaning agent Substances 0.000 claims description 18
- 239000013543 active substance Substances 0.000 claims description 9
- 235000013599 spices Nutrition 0.000 claims description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 7
- 150000001408 amides Chemical class 0.000 claims description 6
- 238000013268 sustained release Methods 0.000 claims description 6
- 239000012730 sustained-release form Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- LXAHHHIGZXPRKQ-UHFFFAOYSA-N 5-fluoro-2-methylpyridine Chemical compound CC1=CC=C(F)C=N1 LXAHHHIGZXPRKQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- ANBZTKMYPDMODS-YPKPFQOOSA-N (z)-n,n-diethyloctadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CC)CC ANBZTKMYPDMODS-YPKPFQOOSA-N 0.000 claims description 3
- CWNSVVHTTQBGQB-UHFFFAOYSA-N N,N-Diethyldodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CC)CC CWNSVVHTTQBGQB-UHFFFAOYSA-N 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- -1 sodium alkyl benzene Chemical class 0.000 claims description 2
- 244000063299 Bacillus subtilis Species 0.000 abstract description 8
- 235000014469 Bacillus subtilis Nutrition 0.000 abstract description 8
- 239000003795 chemical substances by application Substances 0.000 abstract description 7
- 238000011010 flushing procedure Methods 0.000 abstract description 6
- 238000004140 cleaning Methods 0.000 abstract description 4
- 238000013270 controlled release Methods 0.000 abstract 3
- 244000005700 microbiome Species 0.000 abstract 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract 1
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 abstract 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical group [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 abstract 1
- 230000001877 deodorizing effect Effects 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 230000009965 odorless effect Effects 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical compound N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 description 6
- TVWHNULVHGKJHS-UHFFFAOYSA-N Uric acid Natural products N1C(=O)NC(=O)C2NC(=O)NC21 TVWHNULVHGKJHS-UHFFFAOYSA-N 0.000 description 6
- 239000004202 carbamide Substances 0.000 description 6
- 229940116269 uric acid Drugs 0.000 description 6
- 210000002700 urine Anatomy 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 230000005180 public health Effects 0.000 description 5
- 230000001580 bacterial effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- 238000000855 fermentation Methods 0.000 description 3
- 230000004151 fermentation Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 206010011409 Cross infection Diseases 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 206010029803 Nosocomial infection Diseases 0.000 description 2
- 239000001055 blue pigment Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 230000009967 tasteless effect Effects 0.000 description 2
- QQXDYWHKPKEBJU-UHFFFAOYSA-N CCCCCCCCCCCCCCCCCC[Na] Chemical compound CCCCCCCCCCCCCCCCCC[Na] QQXDYWHKPKEBJU-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- RFAFBXGYHBOUMV-UHFFFAOYSA-N calcium chromate Chemical compound [Ca+2].[O-][Cr]([O-])(=O)=O RFAFBXGYHBOUMV-UHFFFAOYSA-N 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000005183 environmental health Effects 0.000 description 1
- 239000003845 household chemical Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a solid water-saving toilet cleaner which can be used for cleaning and deodorizing a toilet. The toilet cleaner comprises a microorganism, a forming controlled release agent, a scale dissolver and a surfactant, wherein the microorganism is Bacillus subtilis the content of which is 104-108cfu/g; the weight content of the forming controlled release agent is 0.5%-80%, and the forming controlled release agent is selected from one or more of rosin, sodium sulfate, sodium palmitate and potassium palmitate; the weight content of the surfactant is 0.5%-50%, and the surfactant is selected from one or both of sulfonic acid and cocoanut fatty acid diethanolamide; and the weight content of the scale dissolver is 0.5%-50%, and the scale dissolver is selected from disodium ethylene diaminetetraacetate or tetrasodium ethylene diaminetetraacetate. After the solid water-saving toilet cleaner is placed at the bottom of the toilet, the toilet can be clean and odorless without flushing, thus the toilet cleaner is convenient to use, is safe and environmentally friendly and ensures that water resources are saved.
Description
Technical field
The invention belongs to household chemicals and sanitising agent field, related to a kind of solid water saving cleaning agent, can be used for the cleaning and the taste removal of urinal.
Background technology
Staple in the urine is water, uric acid, urea and inorganic salt etc., easy scale formation and peculiar smell is arranged.The tradition urinal need and use various sanitising agents to keep clean, the tasteless and scale removal of urinal through a large amount of flushing with clean water after each the use.
Clear water is non-renewable resource, and flushing causes a large amount of wastes; Have also that water washes in the utilization, but in water treatment also need the energy, and need to transform pipeline; Water a large amount of during flushing pour water drain, have increased treatment pressure of sewage.
Traditional urinal has flush button, and the hand contact causes the cross infection of bacterium easily; And the urinal cost of auto-flushing is high.During flushing, the pressure that water dashes can make the bacterium in the urinal be disseminated in the air in whole lavatory, influences environmental health.
Therefore need a kind of method, make urinal after each the use, no longer need wash by water and to keep clean and tasteless,, and alleviate treatment pressure of sewage with water saving.
Summary of the invention
The present invention aims to provide a kind of solid water saving cleaning agent, is used for the cleaning and the taste removal of urinal.
Technical scheme is that a kind of solid water saving cleaning agent comprises mikrobe, moulding sustained release dosage, scale remover and tensio-active agent; Mikrobe is a subtilis, and its content is 10
4～10
8Cfu/g;
The weight ratio of moulding sustained release dosage is 0.5%～80%, is preferably 10%～75%, is selected from rosin, sodium sulfate, sodium palmitate and the Potassium palmitate one or more;
The tensio-active agent weight ratio is 0.5%～50%, is preferably 5%～40%, is selected from sulfonate surfactant or the alkylol amide type tensio-active agent one or more;
The scale remover weight ratio is 0.5%～50%, is preferably 5%～50%, is selected from EDTA Disodium or tetrasodium ethylenediamine tetraacetate.
Subtilis can be selected dry powder or fermented liquid for use.
Preferred, moulding sustained release dosage rosiny weight ratio is 5～50%, and the weight ratio of sodium sulfate is 10%～70%.
Sulfonate surfactant in the tensio-active agent is preferably at least a in the sodium alkyl benzene sulfonate of alkyl sodium sulfonate or C12～C18 of C12～C18.
Alkylol amide in the tensio-active agent is at least a in coconut acid diethanolamide (claiming coconut oil diethanol amide or lauric acid amide of ethanol again), lauric acid diethyl amide or the oleic acid diethyl amide.
This solid water saving cleaning agent also can comprise pigment and spices, and the weight ratio of pigment is 0.01～2%, and the weight ratio of spices is 0.01～2%.
In general, the solid of per 30～60g water saving cleaning agent is in public health infrastructure, as duration of service of common office building reaching one month; About duration of service in about week of bigger market of flow of the people and hospital.
The advantage of solid water saving cleaning agent of the present invention is need not sanitary facility is done any replacing, and this sanitising agent is processed nuggets, is placed on the urinal bottom, can constitute anhydrous urinal; Compositions such as uric acid and urea in this sanitising agent degradable urine need not bath and just can keep urinal cleaning, non-scaling, free from extraneous odour, can save great lot of water resources.Also avoided the cross infection that need cause, much cleaner convenience by flush button.And the nuggets had good sustained release effect of processing, duration of service is long, therefore can not rise by cost.Handling ease, employed mikrobe be to human body and environmentally friendly, safety and environmental protection more.
Embodiment
Embodiment 1
Sodium sulfate 600g, coconut oil diethanol amide 150g, EDTA Disodium 100g, blue pigments 10g and spices 1g add fermentation of bacillus subtilis liquid (10 after pulverizing and mixing
9Cfu/g) 10g mixing; Rosin 129g and the above-mentioned raw materials of temperature 30 ℃～40 ℃ of meltings mixed, compound stalk forming is processed the fritter of 3cmx3cmx3cm again, and wherein the bacillus subtilis bacterial content is 10
7Cfu/g.During use made fritter being placed on the urinal bottom gets final product.
The cleaning agent fritter of gained can the uric acid in the urine be degraded fully, and degradable urea is more than 50%; Use the back urinal not have fouling, free from extraneous odour.
The solid of per 30～60g water saving cleaning agent is generally one thoughtful three months duration of service in public health infrastructure; Like common office building, can reach one month duration of service; About duration of service in about week of bigger market of flow of the people and hospital.
Embodiment 2
Sodium sulfate 150g, sodium palmitate 100g, lauric acid diethyl amide 200g, sodium laurylsulfonate 50g, EDTA Disodium 200g, yellow ultramarine 5g and spices 5g add fermentation of bacillus subtilis liquid (10 after pulverizing and mixing
8Cfu/g) 20g mixing; Rosin 270g is heated to 30 ℃～40 ℃ thawings, mixes with above-mentioned raw materials, compound stalk forming is processed the fritter of 3cmx3cmx3cm, and wherein the bacillus subtilis bacterial content is 2x10
6Cfu/g.During use made fritter being placed on the urinal bottom gets final product.
The cleaning agent fritter of gained can the uric acid in the urine be degraded fully, and degradable urea is more than 50%; Use the back urinal not have fouling, free from extraneous odour.
The solid water saving cleaning agent of per 30～60g is in public health infrastructure, and like common office building, can reach one month duration of service; About duration of service in about week of bigger market of flow of the people and hospital.
Embodiment 3
Subtilis dry powder (5 * 10
8Cfu/g) 10g, sodium sulfate 50g, rosin 490g, octadecyl sodium sulfonate 100g, tetrasodium ethylenediamine tetraacetate 350g pulverize and mix the back compound stalk forming, process the fritter of 3cmx3cmx3cm, and wherein the bacillus subtilis bacterial content is 5x10
6Cfu/g.During use made fritter being placed on the urinal bottom gets final product.
The cleaning agent fritter of gained can the uric acid in the urine be degraded fully, and degradable urea is more than 50%; Use the back urinal not have fouling, free from extraneous odour.
The solid water saving cleaning agent of per 30～60g is in public health infrastructure, and like common office building, can reach one month duration of service; About duration of service in about week of bigger market of flow of the people and hospital.
Embodiment 4
Sodium sulfate 50g, rosin 50g, oleic acid diethyl amide 200g, X 2073 200g, tetrasodium ethylenediamine tetraacetate 474g, blue pigments 1g, spices 10g pulverize and mix, and add fermentation of bacillus subtilis liquid (10
7Cfu/g) compound stalk forming behind the 15g mixing is processed the fritter of 5cm * 5cmx3cm, and wherein the bacillus subtilis bacterial content is 1.5x10
5Cfu/g.During use made fritter being placed on the urinal bottom gets final product.
The cleaning agent fritter of gained can the uric acid in the urine be degraded fully, and degradable urea is more than 50%; Use the back urinal not have fouling, free from extraneous odour.
The solid of per 30～60g water saving cleaning agent is in public health infrastructure, as duration of service of common office building reaching one month; About duration of service in about week of bigger market of flow of the people and hospital.
Claims (3)
1. a solid water saving cleaning agent is characterized in that, comprises mikrobe, moulding sustained release dosage, scale remover and tensio-active agent; Mikrobe is a subtilis, and its content is 10
4～10
8Cfu/g;
The weight ratio of moulding sustained release dosage is 10%～75%, is selected from rosin, sodium sulfate, sodium palmitate or the Potassium palmitate one or more; Said rosiny weight ratio is 5～50%, and the weight ratio of said sodium sulfate is 10%～70%;
The tensio-active agent weight ratio is 5%～50%, is selected from sulfonate surfactant or the alkylol amide type tensio-active agent one or more; Described alkylol amide type tensio-active agent is at least a in coconut acid diethanolamide, lauric acid diethyl amide or the oleic acid diethyl amide; Described sulfonate surfactant is at least a in the sodium alkyl benzene sulfonate of alkyl sodium sulfonate or C12～C18 of C12～C18;
The scale remover weight ratio is 5%～50%, is selected from EDTA Disodium or tetrasodium ethylenediamine tetraacetate.
2. the described solid water saving of claim 1 cleaning agent is characterized in that described subtilis is dry powder or fermented liquid.
3. the described solid water saving of claim 1 cleaning agent is characterized in that also comprise pigment and spices, the weight ratio of pigment is 0.01～2%, and the weight ratio of spices is 0.01～2%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910198517 CN102051274B (en) | 2009-11-10 | 2009-11-10 | Solid water-saving toilet cleaner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910198517 CN102051274B (en) | 2009-11-10 | 2009-11-10 | Solid water-saving toilet cleaner |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102051274A CN102051274A (en) | 2011-05-11 |
| CN102051274B true CN102051274B (en) | 2012-12-05 |
Family
ID=43956077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910198517 Expired - Fee Related CN102051274B (en) | 2009-11-10 | 2009-11-10 | Solid water-saving toilet cleaner |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102051274B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103756801A (en) * | 2013-12-25 | 2014-04-30 | 苏州市邦成电子科技有限公司 | Boiler disincrustant |
| CN104450239A (en) * | 2014-11-03 | 2015-03-25 | 赵君雄 | Block-shaped low-solubility cleaning agent for flush toilet |
| CN104498230A (en) * | 2014-12-18 | 2015-04-08 | 镇江拜因诺生物科技有限公司 | Microbial surface detergent |
| CN105695158A (en) * | 2016-03-15 | 2016-06-22 | 王玉兴 | Microorganism antibacterial toilet cleaner |
| GB2589341B (en) * | 2019-11-27 | 2023-01-04 | Advanced Bacterial Sciences Ltd | Composition and method for uric acid removal |
| CN113025438B (en) * | 2021-03-15 | 2022-06-10 | 湖南品六生物科技有限公司 | Sterilization and virus killing toilet cleaner |
| CN116904275B (en) * | 2023-06-30 | 2024-07-09 | 广州市爱家有方日用品有限公司 | Biological enzyme catalytic decomposition pipeline dredging agent and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1248285A (en) * | 1997-02-20 | 2000-03-22 | 雷克特和科尔曼印度有限公司 | Toilet cleaning block |
| CN1354241A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Cleaning agent for toilet pan |
| CN1528689A (en) * | 2003-09-26 | 2004-09-15 | 中国人民解放军军事医学科学院卫生学 | No-water-flusing toilet for treating excrement and urin using microorganism |
-
2009
- 2009-11-10 CN CN 200910198517 patent/CN102051274B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1248285A (en) * | 1997-02-20 | 2000-03-22 | 雷克特和科尔曼印度有限公司 | Toilet cleaning block |
| CN1354241A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Cleaning agent for toilet pan |
| CN1528689A (en) * | 2003-09-26 | 2004-09-15 | 中国人民解放军军事医学科学院卫生学 | No-water-flusing toilet for treating excrement and urin using microorganism |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102051274A (en) | 2011-05-11 |
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Granted publication date: 20121205 Termination date: 20131110 |