CN102057936B - Nitenpyram and indoxacarb compound agricultural pesticide - Google Patents
Nitenpyram and indoxacarb compound agricultural pesticide Download PDFInfo
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- CN102057936B CN102057936B CN 201110022781 CN201110022781A CN102057936B CN 102057936 B CN102057936 B CN 102057936B CN 201110022781 CN201110022781 CN 201110022781 CN 201110022781 A CN201110022781 A CN 201110022781A CN 102057936 B CN102057936 B CN 102057936B
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- nitenpyram
- indoxacarb
- pesticide
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- brown planthopper
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- 239000005907 Indoxacarb Substances 0.000 title claims abstract description 58
- CFRPSFYHXJZSBI-DHZHZOJOSA-N (E)-nitenpyram Chemical compound [O-][N+](=O)/C=C(\NC)N(CC)CC1=CC=C(Cl)N=C1 CFRPSFYHXJZSBI-DHZHZOJOSA-N 0.000 title claims abstract description 56
- 229940079888 nitenpyram Drugs 0.000 title claims abstract description 56
- 239000000575 pesticide Substances 0.000 title claims abstract description 31
- -1 indoxacarb compound Chemical class 0.000 title description 2
- VBCVPMMZEGZULK-NRFANRHFSA-N indoxacarb Chemical compound C([C@@]1(OC2)C(=O)OC)C3=CC(Cl)=CC=C3C1=NN2C(=O)N(C(=O)OC)C1=CC=C(OC(F)(F)F)C=C1 VBCVPMMZEGZULK-NRFANRHFSA-N 0.000 claims abstract description 57
- 241001556089 Nilaparvata lugens Species 0.000 abstract description 21
- 241000607479 Yersinia pestis Species 0.000 abstract description 14
- 241000209094 Oryza Species 0.000 abstract description 12
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 12
- 235000009566 rice Nutrition 0.000 abstract description 12
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 230000000749 insecticidal effect Effects 0.000 abstract description 5
- 231100000053 low toxicity Toxicity 0.000 abstract description 5
- 238000001228 spectrum Methods 0.000 abstract description 4
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract 5
- 230000005923 long-lasting effect Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 19
- 239000000203 mixture Substances 0.000 description 16
- 241000819999 Nymphes Species 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 7
- 231100000225 lethality Toxicity 0.000 description 7
- 241000238631 Hexapoda Species 0.000 description 6
- 241000176086 Sogatella furcifera Species 0.000 description 5
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 4
- 241000258937 Hemiptera Species 0.000 description 4
- 241000255777 Lepidoptera Species 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 241000239290 Araneae Species 0.000 description 2
- 239000005885 Buprofezin Substances 0.000 description 2
- 239000005906 Imidacloprid Substances 0.000 description 2
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 2
- 229940056881 imidacloprid Drugs 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
- 239000005660 Abamectin Substances 0.000 description 1
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 108010052164 Sodium Channels Proteins 0.000 description 1
- 102000018674 Sodium Channels Human genes 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229930014345 anabasine Natural products 0.000 description 1
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 210000002569 neuron Anatomy 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 210000004894 snout Anatomy 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229940126121 sodium channel inhibitor Drugs 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
烯啶虫胺和茚虫威复配农药，属于复配农药技术领域。其特征在于含有重量百分含量的以下物质：烯啶虫胺1.5～2.5％，茚虫威1.5～2.5％。该复配农药对水稻褐飞虱的共毒系数大于120，两者复配具有明显的增效作用，对水稻褐飞虱等同翅目害虫和鳞翅目害虫有较好防治效果。该复配农药低毒、杀虫谱较广，速效性和持效性好，生产成本低。 The invention relates to a compound pesticide of nitenpyram and indoxacarb, which belongs to the technical field of compound pesticides. It is characterized in that it contains the following substances in percentage by weight: 1.5-2.5 percent of nitenpyram and 1.5-2.5 percent of indoxacarb. The co-toxicity coefficient of the compound pesticide to rice brown planthopper is greater than 120, the compound of the two has obvious synergistic effect, and has good control effect on rice brown planthopper and other homopteran pests and lepidopteran pests. The compound pesticide has low toxicity, wide insecticidal spectrum, good quick-acting and long-lasting effects, and low production cost.
Description
Technical field
The invention belongs to technical field of compounded pesticide, be specially Nitenpyram and indoxacarb Recompounded pesticide.
Background technology
Paddy rice is the principal item in China cereal crops, and cultivated area is large, and disease, worm, crop smothering kind are many, and harm is heavy.According to agricultural sector statistics, every year due to illness, the harm such as worm, grass, production loss reaches 20～30%.The agricultural chemicals quantity that disease, worm, crop smothering on the control paddy rice uses accounts for 50% left and right of China's agricultural chemicals year usage amount.Area is controlled to the medicine of rice grub in the whole nation, and throughout the year 1,200,000,000 mu of left and right, insect outbreak year medicine is controlled area can be larger.
The pesticide species of control Insect Pests in Rice as the control rice leaf roller, for many years, uses the desinsection list, and chlopyrifos is more, nearly 3～5 years, uses the medicaments such as Avermectin, Affirm (Merck Co.) hydrochloride.Large area control to rice leaf roller has reached good effect, but develop immunity to drugs afterwards for many years owing to using, control efficiency descends year by year, in recent years introduce the medicaments such as indoxacarb that du pont company produces, Rynaxypyr, lepidoptera pest on the control paddy rice, dosage is few, and preventive effect is good, but pesticide price is high, and spread uses also certain difficulty.And for example prevent and treat the rice fulgorid class pest, since the nineties in last century, used Buprofezin (claiming again buprofezin), the agricultural chemicals such as Imidacloprid are got the control of national rice fulgorid and have been gone larger achievement.But since this century, the agricultural chemicals such as Imidacloprid have produced stronger pesticide resistance to brown planthopper, and control efficiency descends.So that the medicament exploitation of control rice fulgorid becomes the task of top priority.
In China paddy rice producing region, especially the rice district's paddy growth middle and later periods on the south the Yangtze river basin, lepidoptera pest such as snout moth's larva, rice leaf roller and homoptera pest such as rice fulgorid class are mixed often sends out.Especially rice leaf roller and brown planthopper become the primary pest of paddy rice middle and later periods.When selecting pesticide species, consider the double former medicine kind of controlling effect, can receive that just preventive effect is good, reach again saving of labor, economical purpose.For this reason, some obligate insecticides are carried out composite, enlarging insecticidal spectrum just has this purpose.
Summary of the invention
For the above-mentioned problems in the prior art, the object of the invention is to design provides the wider Nitenpyram of a kind of low toxicity, insecticidal spectrum and the technical scheme of indoxacarb Recompounded pesticide, its quick-acting and lasting effect are good, and paddy rice lepidoptera pest and homoptera pest are had better control efficiency.
Described Nitenpyram and indoxacarb Recompounded pesticide is characterized in that containing the following material of weight percentage: Nitenpyram 1.5～2.5%, indoxacarb 1.5～2.5%.
Described Nitenpyram and indoxacarb Recompounded pesticide is characterized in that: Nitenpyram content is 1.6～2.2%, and indoxacarb content is 1.6～2.2%.
Described Nitenpyram and indoxacarb Recompounded pesticide is characterized in that: Nitenpyram content is 1.8～2.0%, and indoxacarb content is 1.8～2.0%.
Nitenpyram (Nitenpyram) is anabasine insecticide, and low toxicity, good water solubility, desinsection principle are mainly that insect cynapse acceptor is had the nerve block effect.To homoptera pest such as rice fulgorid have efficiently, low toxicity, interior suction and without advantages such as cross resistances.
Indoxacarb, English common name (Indoxacarb) has another name called safety hit, An Guan, Ammate, Vatar.To the little poison of higher mammal, fool proof to people, animal, fool proof to birds and aquatile.The insecticidal mechanism of indoxacarb is the sodium channel inhibitor, and the main sodium channel of passing through in blocking-up insect nerve cell makes the coordination of target pest impaired, numb fraud occurs, and is finally lethal.
Described Nitenpyram and indoxacarb Recompounded pesticide according to its purposes, can be processed multiple formulation, as aqueous emulsion, add solvent, emulsifier to make by former medicine; Also can make water dispersant, add bleeding agent, diffusant, wetting agent, binding agent, filler etc. to make by former medicine.The production technology that specifically is mixed and usual auxiliaries all belong to existing known technology, do not repeat them here.
Above-mentioned Nitenpyram and indoxacarb Recompounded pesticide, greater than 120, both are composite has obvious synergistic effect, and the homoptera pests such as Brown Planthopper and lepidoptera pest are had better control efficiency to the co-toxicity coefficient of Brown Planthopper.This Recompounded pesticide low toxicity, insecticidal spectrum are wider, and quick-acting and lasting effect are good, and production cost is low.
Proportioning in present patent application is the weight percentage of the pure material of active ingredient.
Embodiment
Below the invention will be further described by specific embodiment, and further illustrate beneficial effect of the present invention in conjunction with corresponding test.
Formula one: Nitenpyram 1.6%, indoxacarb 2.4%.
Formula two: Nitenpyram 1.8%, indoxacarb 2.2%.
Formula three: Nitenpyram 2.0%, indoxacarb 2.0%.
Formula four: Nitenpyram 2.2%, indoxacarb 1.8%.
Formula five: Nitenpyram 2.4%, indoxacarb 1.6%.
Test one. the proportioning screening of above-mentioned Recompounded pesticide to Brown Planthopper.
1. reagent agent:
1.1 test medicine: the 95% former medicine of Nitenpyram is provided by capital, Shandong fluffy biological medicine company limited company, and the 92% former medicine of indoxacarb is made into 4% Nitenpyram indoxacarb mixed agent certainly by du pont company production.
1.2 medicament preparation: adopt clear water to make solvent, be mixed with 2% indoxacarb aqueous emulsion and 5.0% Nitenpyram aqua.
1.3 blank (CK): adopt clear water to do blank.
2. proportion design:
1) Nitenpyram
2) indoxacarb
3) 4% Nitenpyram indoxacarb mixture (formula 1) ratio 1:1.5
4) 4% Nitenpyram indoxacarb mixture (formula 2) ratio 1:1.2
5) 4% Nitenpyram indoxacarb mixture (formula 3) ratio 1:1.0
6) 4% Nitenpyram indoxacarb mixture (formula 4) ratio 1:0.8
7) 4% Nitenpyram indoxacarb mixture (formula 5) ratio 1:0.6
3. for the examination insect: brown planthopper 3～4 instar larvaes;
4. test method: with reference to the agricultural industry criteria NY/T1154.7-2006 of the People's Republic of China (PRC), adopt the seedling method of soaking.
5. the selection result, see Table 1-8.
Table 1 Nitenpyram is to the test of pesticide effectiveness of brown planthopper 3-4 nymph in age table as a result
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) |
| 20.0000 | 76 | 74 | 97.4 |
| 10.0000 | 98 | 84 | 85.7 |
| 5.0000 | 102 | 80 | 78.4 |
| 2.5000 | 80 | 46 | 57.5 |
| 1.2500 | 92 | 34 | 37.0 |
| 0.6250 | 72 | 22 | 30.6 |
| CK | 80 | 8 | 10.0 |
Table 2 indoxacarb is to the test of pesticide effectiveness of brown planthopper 3-4 nymph in age table as a result
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) |
| 50.0000 | 96 | 68 | 70.8 |
| 25.0000 | 90 | 52 | 57.8 |
| 12.5000 | 82 | 40 | 48.8 |
| 6.2500 | 86 | 34 | 39.5 |
| 3.1250 | 66 | 18 | 27.3 |
| CK | 222 | 26 | 11.7 |
Table 3 Nitenpyram indoxacarb mixture (formula 1) is to the test of pesticide effectiveness of brown planthopper 3-4 nymph in age table as a result
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) |
| 40.0000 | 124 | 122 | 98.4 |
| 20.0000 | 72 | 64 | 88.9 |
| 10.0000 | 130 | 110 | 84.6 |
| 5.0000 | 88 | 60 | 68.2 |
| 2.5000 | 98 | 58 | 59.2 |
| CK | 222 | 26 | 11.7 |
Table 4 Nitenpyram indoxacarb mixture (formula 2) is to the test of pesticide effectiveness of brown planthopper 3-4 nymph in age table as a result
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) |
| 40.0000 | 150 | 150 | 100.0 |
| 20.0000 | 216 | 208 | 96.3 |
| 10.0000 | 164 | 128 | 78.0 |
| 5.0000 | 248 | 164 | 66.1 |
| 2.5000 | 174 | 94 | 54.0 |
| CK | 222 | 26 | 11.7 |
Table 5 Nitenpyram indoxacarb mixture (formula 3) is to the test of pesticide effectiveness of brown planthopper 3-4 nymph in age table as a result
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) |
| 40.0000 | 204 | 204 | 100.0 |
| 20.0000 | 188 | 178 | 94.7 |
| 10.0000 | 230 | 188 | 81.7 |
| 5.0000 | 140 | 84 | 60.0 |
| 2.5000 | 152 | 82 | 53.9 |
| CK | 222 | 26 | 11.7 |
Table 6 Nitenpyram indoxacarb mixture (formula 4) is to the test of pesticide effectiveness of brown planthopper 3-4 nymph in age table as a result
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) |
| 40.0000 | 184 | 184 | 100.0 |
| 20.0000 | 168 | 164 | 97.6 |
| 10.0000 | 86 | 72 | 83.7 |
| 5.0000 | 116 | 84 | 72.4 |
| 2.5000 | 102 | 52 | 51.0 |
| CK | 222 | 26 | 11.7 |
Table 7 Nitenpyram indoxacarb mixture (formula 5) is to the test of pesticide effectiveness of brown planthopper 3-4 nymph in age table as a result
| Dosage (mg/L) | The examination borer population | Dead borer population | Lethality (%) |
| 40.0000 | 106 | 106 | 100.0 |
| 20.0000 | 98 | 90 | 91.8 |
| 10.0000 | 92 | 78 | 84.8 |
| 5.0000 | 102 | 72 | 70.6 |
| 2.5000 | 100 | 54 | 54.0 |
| CK | 222 | 26 | 11.7 |
Table 8 Nitenpyram indoxacarb is to the toxicity test of brown planthopper 3-4 nymph in age table as a result
| Reagent and proportioning (%) | LC 50 | The toxicity regression line | 95% confidence interval | Co-toxicity coefficient |
| Nitenpyram | 2.1695 | y=4.4250+1.7095x | 1.7254 ～2.6329 | ? |
| Indoxacarb | 20.0672 | y=3.6131+1.0648x | 14.6315 ～31.1832 | ? |
| 4% Nitenpyram. indoxacarb mixture (formula 1) | 2.4522 | y=4.4181+1.4938x | 1.4328 ～3.4701 | 190.3 |
| 4% Nitenpyram. indoxacarb mixture (formula 2) | 3.2486 | y=4.0066+1.9414x | 1.7032 ～4.6743 | 121.2 |
| 4% Nitenpyram. indoxacarb mixture (formula 3) | 3.4381 | y=3.9388+1.9880x | 2.6787 ～4.1698 | 128.7 |
| 4% Nitenpyram. indoxacarb mixture (formula 4) | 3.0829 | y=3.8904+2.2693x | 2.2307 ～3.9025 | 176.0 |
| 4% Nitenpyram. indoxacarb mixture (formula 5) | 2.8379 | y=4.1880+1.7924x | 1.8367～3.8101 | 188.3 |
The selection result shows: the co-toxicity coefficient of 5 proportionings of 4% Nitenpyram indoxacarb mixed agent is all greater than 120, reach 121.2-190.3, showing that both are composite has an obvious synergistic effect, can according to cure mainly, the double factors such as object and production cost of controlling consider to select optimization of C/C composites.
Test two. the field control effectiveness test of above-mentioned Recompounded pesticide to Brown Planthopper.Be the reliability of checking proportioning screening, heading stage carried out 4% Nitenpyram indoxacarb mixed agent (formula 3) field trial at hybrid rice (excellent No. one of middle Zhejiang) in by the end of August, 2010-September.
1. field reagent kind and consumption:
(1) 4% Nitenpyram indoxacarb mixed agent (formula 3) mu consumption 100 grams;
(2) 3% indoxacarb aqueous emulsion mu consumption 80 grams;
(3) 5% Nitenpyram aqua mu consumption 50 grams;
(4) blank.
2. method: adopt deployment residential quarter, triplicate.Before medication, 7 days, 11 days employing dish bat methods after medicine are investigated hundred clumps of worm amounts of brown planthopper adult, nymph and the spider of each residential quarter.Calculate after medicine the brown planthopper insect population decline rate, control efficiency of 7 days, 11 days and to the fragmentation effect of spider.
3. result of the test sees Table 9.
Result of the test shows: 4% Nitenpyram indoxacarb mixed agent (formula 3) mu is used 100 grams, and after medicine, the insect population decline rate of 7 days, 11 days brown planthoppers is respectively 75.7% and 82.1%, and control efficiency is respectively 81.1% and 86.1%.Compare with the contrast medicament, higher than indoxacarb, slightly lower than the control efficiency of mu with the Nitenpyram of 50 grams.Carry out the field control effectiveness test of Brown Planthopper with formula 1-2 and formula 4-5, also can reach the test effect similar to formula 3.
Claims (3)
1. Nitenpyram and indoxacarb Recompounded pesticide, is characterized in that active component is Nitenpyram and indoxacarb, and the weight percentage of Nitenpyram is 1.5～2.5%, and the weight percentage of indoxacarb is 1.5～2.5%.
2. Nitenpyram as claimed in claim 1 and indoxacarb Recompounded pesticide, it is characterized in that: Nitenpyram content is 1.6～2.2%, indoxacarb content is 1.6～2.2%.
3. Nitenpyram as claimed in claim 1 and indoxacarb Recompounded pesticide, it is characterized in that: Nitenpyram content is 1.8～2.0%, indoxacarb content is 1.8～2.0%.
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| CN102626110B (en) * | 2012-03-20 | 2014-07-02 | 永农生物科学有限公司 | Indoxacarb-containing complex pesticide composition |
| CN105123734A (en) * | 2015-08-01 | 2015-12-09 | 华中农业大学 | Preparation method of mixed insecticide composed of avermectin, nitenpyram, and indoxacarb |
| CN104982452A (en) * | 2015-08-01 | 2015-10-21 | 华中农业大学 | Insecticidal composition containing nitenpyram and indoxacarb and preparation method of insecticidal composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101243798A (en) * | 2008-01-11 | 2008-08-20 | 湖南万家丰科技有限公司 | Insecticidal composition containing indoxacarb |
| CN101574085A (en) * | 2008-05-09 | 2009-11-11 | 上海杜邦农化有限公司 | Agricultural composition containing indoxacarb and imidacloprid and application thereof |
| CN101755804A (en) * | 2009-11-10 | 2010-06-30 | 深圳诺普信农化股份有限公司 | Indoxacarb-containing aqueous emulsion and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101243798A (en) * | 2008-01-11 | 2008-08-20 | 湖南万家丰科技有限公司 | Insecticidal composition containing indoxacarb |
| CN101574085A (en) * | 2008-05-09 | 2009-11-11 | 上海杜邦农化有限公司 | Agricultural composition containing indoxacarb and imidacloprid and application thereof |
| CN101755804A (en) * | 2009-11-10 | 2010-06-30 | 深圳诺普信农化股份有限公司 | Indoxacarb-containing aqueous emulsion and preparation method thereof |
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