CN102001866B - Manufacturing method of ceramic imitating concavo-convex reticulation of sesame stone - Google Patents
Manufacturing method of ceramic imitating concavo-convex reticulation of sesame stone Download PDFInfo
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- CN102001866B CN102001866B CN201010590233A CN201010590233A CN102001866B CN 102001866 B CN102001866 B CN 102001866B CN 201010590233 A CN201010590233 A CN 201010590233A CN 201010590233 A CN201010590233 A CN 201010590233A CN 102001866 B CN102001866 B CN 102001866B
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- 239000000919 ceramic Substances 0.000 title claims abstract description 34
- 239000004575 stone Substances 0.000 title claims abstract description 33
- 241000207961 Sesamum Species 0.000 title claims abstract description 20
- 235000003434 Sesamum indicum Nutrition 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 24
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910000480 nickel oxide Inorganic materials 0.000 claims abstract description 18
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims abstract description 18
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 12
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 12
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims abstract description 12
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000292 calcium oxide Substances 0.000 claims abstract description 6
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 238000000227 grinding Methods 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 12
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- 235000011194 food seasoning agent Nutrition 0.000 claims description 9
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 claims description 5
- 235000012255 calcium oxide Nutrition 0.000 claims description 5
- 238000005245 sintering Methods 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- QOSTVEDABRQTSU-UHFFFAOYSA-N 1,4-bis(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NC)=CC=C2NC QOSTVEDABRQTSU-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 239000002002 slurry Substances 0.000 abstract description 9
- 238000010304 firing Methods 0.000 abstract description 4
- 238000009377 nuclear transmutation Methods 0.000 abstract description 4
- 230000000007 visual effect Effects 0.000 abstract description 4
- 238000009826 distribution Methods 0.000 abstract description 3
- 229910000428 cobalt oxide Inorganic materials 0.000 abstract 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 abstract 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 1
- 229910000410 antimony oxide Inorganic materials 0.000 abstract 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 abstract 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 abstract 1
- 210000003298 dental enamel Anatomy 0.000 description 9
- 239000000446 fuel Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004579 marble Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 210000001161 mammalian embryo Anatomy 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000015895 biscuits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
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Abstract
The invention discloses a manufacturing method of ceramic imitating the concavo-convex reticulation of sesame stone due to the furnace transmutation of a glaze layer in the firing process. The method comprises the steps of: preparing first glaze slurry containing tin dioxide, zirconium dioxide, nickel oxide and cobalt oxide, second glaze slurry containing cobalt oxide, nickel oxide, chromic oxide, ferric oxide and manganese dioxide, third glaze slurry containing tin dioxide, zirconium dioxide, nickel oxide and antimony oxide, and fourth glaze slurry containing diboron trioxide, calcium oxide, strontium oxide and zinc oxide; and orderly applying the first glaze slurry, the second glaze slurry, the third glaze slurry and the fourth glaze slurry on a ceramic body. After the firing, the glaze layer of the ceramic product has furnace transmutation and concavo-convex reticulations appear on the surface of the glaze layer; the concave parts are like scales in which color spots in grayish black and white and the like appear, and the depth and the distribution of the color spots are similar to the sesame stone and appearance visual effect of the sesame stone is provided; and the convex parts are white striped color spots among the scales and mutually connected to form reticulations.
Description
Technical field
The present invention relates to the method for manufacture of pottery, relate in particular to the method for manufacture of ceramic with bag appearance.
Background technology
Have the ceramic of stone grain effect owing to have special appreciation effect, receive human consumer's favor, have the vast market space as vase, ornaments, apparatus or collectibles.Therefore, it becomes a developing direction of decorating ceramic products.
Chinese invention patent ublic specification of application CN1218020A has proposed a kind of method that on pottery, forms marble pattern; Provide at first that a high-density, viscosity are little, the ground-coat enamel of high-consistency, then that proportion is little, viscosity big, the cover-coat enamel of low denseness is slowly poured in the ground-coat enamel, because the drop of two kinds of glaze proportions and viscosity; Cover-coat enamel does not decompose in ground-coat enamel immediately; And float on the top layer of ground-coat enamel, then the paddling glaze makes it produce marble grain, then the biscuiting embryo partly is dipped in to roll in the glaze and turns around; Muffle painting is overlying on the embryo, in high temperature, fires after the completion glazing program and promptly produce marble grain.This method operation is difficult to control, and reproducibility is relatively poor, and yield rate is low, and is difficult to form the natural color spot that can not form stone.
The disclosed pottery with bag top layer of CN1241497A, CN1424190A, CN1546294A, CN1727147A, CN1887558A and CN101585210A is to adopt mechanical means that one or more mill bases are dispersed in the biscuit of ceramics surface, burns till the back ceramic surface and shows that the plurality of color pulp color embodies the stone speckle.But these method complicated operations, and because speckle is too regular, imitative stone effect is relatively poor.
CN1923747A thinks, pigment is wrapped in the frit, can form the stone imitation pattern glazed ceramic after burning till, but because the pigment patch is too small, the stone material pattern occurs and the natural stone gap is bigger.
CN101066890A thinks, on ceramic paste preforms, executes one deck ground-coat enamel, preparation ground-coat enamel base; Ground-coat enamel base surface is picked the color glaze that contains bubble, form marbling because the color glaze slurry bubble vanishes, this method applicability can be strong; Can be applicable to the ceramic product that type is complicated; But color spot is single, and the ceramic product surface finish is relatively poor, and is far away with natural stone texture gap.
Summary of the invention
The object of the present invention is to provide a kind of operation simple and easy, transmutation occurs and form the process for preparing ceramic of imitating the concavo-convex reticulate pattern of sesame stone at sintering procedure glaze layer.
This method may further comprise the steps:
A. preparation contains tindioxide 11～13% by weight percentage; ZIRCONIUM DIOXIDE 99.5 78～82%; Nickel oxide 4～6%, the first color base material of powder blue 2～4% adds water by 50～60% of the first color base material weight and grinds; The first color base material after will grinding in the first color base material and 20: 100 ratio of transparent parent glaze weight ratio mixes with transparent parent glaze, adds first glaze slip that water is made into total solid content 50～52%;
B. preparation contains powder blue 14～16% by weight percentage; Nickel oxide 9～11%, chromium sesquioxide 14～16%, red stone 18～22%; The second color base material of Manganse Dioxide 38～42%; Add water by 50～60% of the second color base material weight and grind, the second color base material after will grinding in the second color base material and 20: 100 ratio of transparent parent glaze weight ratio mixes with transparent parent glaze, adds second glaze slip that water is made into total solid content 50～52%;
C. preparation contains tindioxide 11～13% by weight percentage; ZIRCONIUM DIOXIDE 99.5 68～72%; Nickel oxide 2～4%, the tertiary color sill of weisspiessglanz 9～11% adds water by 50～60% of tertiary color sill weight and grinds; Tertiary color sill after will grinding in tertiary color sill and 20: 100 ratio of transparent parent glaze weight ratio mixes with transparent parent glaze, adds the 3rd glaze slip that water is made into total solid content 50～52%;
D. prepare trioxygen-containingization two boron 38～42% by weight percentage; Quicklime 28～32%; Strontium oxide 14～16%, the 4th color base material of zinc oxide 14～16% adds water by 50～60% of the 4th color base material weight and grinds; The 4th color base material after will grinding in the 4th color base material and 20: 100 ratio of transparent parent glaze weight ratio mixes with transparent parent glaze, adds the 4th glaze slip that water is made into total solid content 50～52%;
E. on ceramic body, execute first glaze slip; Second glaze slip is executed in seasoning after 0.5～1 hour; The 3rd glaze slip is executed in seasoning after 1～1.5 hour again; The 4th glaze slip is executed in seasoning after 1～1.5 hour again, and the ratio of the consumption of first glaze slip, second glaze slip, the 3rd glaze slip and the 4th glaze slip is 1: 0.55～0.65: 0.35～0.45: 0.14～0.18;
F. the ceramic body after the glazing is fired: in the time of 200～800 ℃, per hour heat up 180～200 ℃; Per hour heat up in the time of 800～1100 ℃ 90～100 ℃; Per hour heat up in the time of 1100～1260 ℃ 50～60 ℃; Cease fire when arriving 1260～1270 ℃ and lower the temperature, cooling back ceramic body becomes the imitative concavo-convex reticulate pattern ceramic of sesame stone.
Among the present invention, transparent parent glaze is the normal transparent glaze that uses in the ceramic industry, perhaps becomes frit.
In steps A, the weight percentage of the preferred first color base material is a tindioxide 12%, ZIRCONIUM DIOXIDE 99.5 80%, nickel oxide 5%, powder blue 3%.
In step B, the preferred second color base material weight percentage composition is a powder blue 15%, nickel oxide 10%, chromium sesquioxide 15%, red stone 20%, Manganse Dioxide 40%.
In step C, the weight percentage of preferred tertiary color sill is a tindioxide 10%, ZIRCONIUM DIOXIDE 99.5 70%, nickel oxide 3%, weisspiessglanz 10%.
In step D, the weight percentage of preferred the 4th color base material is a boron trioxide 40%, quicklime 30%, strontium oxide 15%, zinc oxide 15%.
In step e, the ratio of the consumption of first glaze slip, second glaze slip, the 3rd glaze slip and the 4th glaze slip is 1: 0.6: 0.4: 0.18.
In step F; When sintering procedure is 800～900 ℃ in temperature; Adopt the reduction mode to fire, promptly strengthen firing rate but do not increase air flow quantity, fuel burns under anoxic condition in the kiln; Other TR in addition adopts mode of oxidizing to fire i.e. fuel perfect combustion under the sufficient state of oxygen.
The present invention transmutation occurs at sintering process glaze layer, and the ceramic after burning till occurs concavo-convex at the glaze laminar surface, and recessed portion is as scale; Occur multiple color spots such as grey black and white in the scale, the color spot depth and distribution situation are close with sesame stone, have sesame stone outward appearance visual effect; Protruding part is the white stripes color spot, and is interconnected to form netted between scale; Glazing operation of the present invention is not difficult to control, and sintering procedure and common glazed ceramic are basic identical.Owing to adopt low plumbous, low cadmium material, product meets California, USA 65 and the plumbous cadmium standard of European Union.
Description of drawings
Fig. 1 is the ceramic appearance design sketch that the method for embodiment 1 is made.
Fig. 2 is the local surfaces appearance figure of Fig. 1 ceramic.
Embodiment
Embodiment 1
Preparation by weight percentage contains tindioxide 12%; ZIRCONIUM DIOXIDE 99.5 80%; Nickel oxide 5%, the first color base material of powder blue 3% adds water by 60% of the first color base material weight and grinds; The first color base material after will grinding in the first color base material and 20: 100 ratio of transparent parent glaze weight ratio mixes with transparent parent glaze, adds first glaze slip that water is made into total solid content 50%.
Preparation by weight percentage contains powder blue 15%; Nickel oxide 10%; Chromium sesquioxide 15%, red stone 20%, the second color base material of Manganse Dioxide 40%; The second color base material after will grinding in the second color base material and 20: 100 ratio of transparent parent glaze weight ratio mixes with transparent parent glaze, adds second glaze slip that water is made into total solid content 50%.
Preparation by weight percentage contains tindioxide 10%; ZIRCONIUM DIOXIDE 99.5 70%; Nickel oxide 3%, the tertiary color sill of weisspiessglanz 10% adds water by 60% of tertiary color sill weight and grinds; Tertiary color sill after will grinding in tertiary color sill and 20: 100 ratio of transparent parent glaze weight ratio mixes with transparent parent glaze, adds the 3rd glaze slip that water is made into total solid content 50%.
Prepare trioxygen-containingization two boron 40% by weight percentage; Quicklime 30%; Strontium oxide 15%, the 4th color base material of zinc oxide 15% adds water by 60% of the 4th color base material weight and grinds; The 4th color base material after will grinding in the 4th color base material and 20: 100 ratio of transparent parent glaze weight ratio mixes with transparent parent glaze, adds the 3rd glaze slip that water is made into total solid content 50%.
On ceramic body, adopt infusion method to execute first glaze slip; Seasoning adopts spraying method evenly to spray second glaze slip after 0.8 hour; Seasoning adopts spraying method evenly to spray the 3rd glaze slip after 1 hour again; Seasoning adopts spraying method evenly to spray the 4th glaze slip after 1 hour again, and the dried thickness of first glaze slip is about 0.2mm, and the ratio of the consumption of first glaze slip, second glaze slip, the 3rd glaze slip and the 4th glaze slip is 1: 0.37: 0.30: 0.25.
Ceramic body after the glazing is fired: when beginning, slowly heat, the moisture in the ceramic body is slowly evaporated, prevent the ceramic body distortion; Heat and to be elevated to 80 ℃ after 1 hour, strengthen firepower afterwards gradually, after 1 hour, be elevated to 200 ℃; Between 200～800 ℃, per hour heat up 200 ℃, after temperature is elevated to 800 ℃, between 800～900 ℃; Adopt the reduction mode to fire, promptly strengthen firing rate but do not increase air flow quantity, fuel incomplete combustion under anoxic condition in the kiln; Temperature is elevated to 900 ℃ after 1 hour, increases air flow quantity afterwards, fuel perfect combustion in the kiln; Between 900～1100 ℃, per hour heat up 100 ℃, per hour heat up 60 ℃ between 1100～1260 ℃, the cooling of ceasing fire when arriving 1260 ℃; Open kiln behind the cool to room temperature, ceramic body becomes the imitative concavo-convex reticulate pattern ceramic of sesame stone.
This ceramic outward appearance visual effect is as depicted in figs. 1 and 2, and Fig. 2 is 1: 1 a local surfaces outside drawing of chi in proportion, and is visible from Fig. 1 and Fig. 2; The glaze laminar surface occurs concavo-convex, and recessed portion multiple color spots such as grey black and white occur as scale in the scale; The color spot depth and distribution situation are close with sesame stone, have clear and definite sesame stone outward appearance visual effect, and protruding part is between scale; Be the white stripes color spot, and be interconnected to form netted.
Claims (7)
1. the method for manufacture of the concavo-convex reticulate pattern pottery of imitative sesame stone is characterized in that, may further comprise the steps:
A. preparation contains tindioxide 11～13% by weight percentage; ZIRCONIUM DIOXIDE 99.5 78～82%; Nickel oxide 4～6%, the first color base material of powder blue 2～4% adds water by 50～60% of the first color base material weight and grinds; The first color base material after will grinding in the first color base material and 20: 100 ratio of transparent parent glaze weight ratio mixes with transparent parent glaze, adds first glaze slip that water is made into total solid content 50～52%;
B. preparation contains powder blue 14～16% by weight percentage; Nickel oxide 9～11%, chromium sesquioxide 14～16%, red stone 18～22%; The second color base material of Manganse Dioxide 38～42%; Add water by 50～60% of the second color base material weight and grind, the second color base material after will grinding in the second color base material and 20: 100 ratio of transparent parent glaze weight ratio mixes with transparent parent glaze, adds second glaze slip that water is made into total solid content 50～52%;
C. preparation contains tindioxide 11～13% by weight percentage; ZIRCONIUM DIOXIDE 99.5 68～72%; Nickel oxide 2～4%, the tertiary color sill of weisspiessglanz 9～11% adds water by 50～60% of tertiary color sill weight and grinds; Tertiary color sill after will grinding in tertiary color sill and 20: 100 ratio of transparent parent glaze weight ratio mixes with transparent parent glaze, adds the 3rd glaze slip that water is made into total solid content 50～52%;
D. prepare trioxygen-containingization two boron 38～42% by weight percentage; Quicklime 28～32%; Strontium oxide 14～16%, the 4th color base material of zinc oxide 14～16% adds water by 50～60% of the 4th color base material weight and grinds; The 4th color base material after will grinding in the 4th color base material and 20: 100 ratio of transparent parent glaze weight ratio mixes with transparent parent glaze, adds the 4th glaze slip that water is made into total solid content 50～52%;
E. on ceramic body, execute first glaze slip; Second glaze slip is executed in seasoning after 0.5～1 hour; The 3rd glaze slip is executed in seasoning after 1～1.5 hour again; The 4th glaze slip is executed in seasoning after 1～1.5 hour again, and the ratio of the consumption of first glaze slip, second glaze slip, the 3rd glaze slip and the 4th glaze slip is 1: 0.55～0.65: 0.35～0.45: 0.14～0.18;
F. the ceramic body after the glazing is fired: in the time of 200～800 ℃, per hour heat up 180～200 ℃; Per hour heat up in the time of 800～1100 ℃ 90～100 ℃; Per hour heat up in the time of 1100～1260 ℃ 50～60 ℃; Cease fire when arriving 1260～1270 ℃ and lower the temperature, cooling back ceramic body becomes the imitative concavo-convex reticulate pattern ceramic of sesame stone.
2. according to the method for manufacture of the concavo-convex reticulate pattern pottery of the said imitative sesame stone of claim 1, it is characterized in that in steps A, the weight percentage of the first color base material is a tindioxide 12%, ZIRCONIUM DIOXIDE 99.5 80%, nickel oxide 5%, powder blue 3%.
3. according to the method for manufacture of the concavo-convex reticulate pattern pottery of the said imitative sesame stone of claim 1, it is characterized in that in step B, the second color base material weight percentage composition is a powder blue 15%, nickel oxide 10%, chromium sesquioxide 15%, red stone 20%, Manganse Dioxide 40%.
4. according to the method for manufacture of the concavo-convex reticulate pattern pottery of the said imitative sesame stone of claim 1, it is characterized in that in step C, the weight percentage of tertiary color sill is a tindioxide 10%, ZIRCONIUM DIOXIDE 99.5 70%, nickel oxide 3%, weisspiessglanz 10%.
5. according to the method for manufacture of the concavo-convex reticulate pattern pottery of the said imitative sesame stone of claim 1, it is characterized in that in step D, the weight percentage of the 4th color base material is a boron trioxide 40%, quicklime 30%, strontium oxide 15%, zinc oxide 15%.
6. according to the method for manufacture of the concavo-convex reticulate pattern pottery of the said imitative sesame stone of claim 1, it is characterized in that in step e, the ratio of the consumption of first glaze slip, second glaze slip, the 3rd glaze slip and the 4th glaze slip is 1: 0.6: 0.4: 0.18.
7. according to the method for manufacture of the concavo-convex reticulate pattern pottery of the said imitative sesame stone of claim 1, it is characterized in that in step F, when sintering procedure is 800～900 ℃ in temperature, adopt the reduction mode to fire, other TR in addition adopts mode of oxidizing to fire.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201010590233A CN102001866B (en) | 2010-12-07 | 2010-12-07 | Manufacturing method of ceramic imitating concavo-convex reticulation of sesame stone |
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| CN201010590233A CN102001866B (en) | 2010-12-07 | 2010-12-07 | Manufacturing method of ceramic imitating concavo-convex reticulation of sesame stone |
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| CN104446671B (en) * | 2014-12-04 | 2016-01-06 | 广东省陶瓷研究所 | Ceramic glaze is formed the method for snakeskin scale appearance effect |
| CN105036738A (en) * | 2015-07-21 | 2015-11-11 | 陈树波 | Manufacturing method of imitation India red stone concave and convex cobwebbing ceramic |
| CN105060935A (en) * | 2015-07-24 | 2015-11-18 | 苏小洁 | Manufacturing method for imitative Sangpu mountain gneissic granite concave-convex anilox ceramic |
| CN105036807A (en) * | 2015-07-24 | 2015-11-11 | 陈晓湘 | Manufacturing method of imitation India red stone line ceramic |
| CN105060934A (en) * | 2015-07-24 | 2015-11-18 | 陈佩娟 | Manufacturing method for branchite imitating knurled ceramic |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1218020A (en) * | 1997-11-25 | 1999-06-02 | 协和陶瓷厂股份有限公司 | Method for forming marbling on ceramics |
| CN1887558A (en) * | 2006-07-20 | 2007-01-03 | 广东东鹏陶瓷股份有限公司 | Material distributing method and device for making ceramic tile with imitative stone grains |
| CN101066890A (en) * | 2007-06-01 | 2007-11-07 | 山东茂华硅工有限公司 | Process of forming decorative marble patterns on ceramic product |
-
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- 2010-12-07 CN CN201010590233A patent/CN102001866B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1218020A (en) * | 1997-11-25 | 1999-06-02 | 协和陶瓷厂股份有限公司 | Method for forming marbling on ceramics |
| CN1887558A (en) * | 2006-07-20 | 2007-01-03 | 广东东鹏陶瓷股份有限公司 | Material distributing method and device for making ceramic tile with imitative stone grains |
| CN101066890A (en) * | 2007-06-01 | 2007-11-07 | 山东茂华硅工有限公司 | Process of forming decorative marble patterns on ceramic product |
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| CN102001866A (en) | 2011-04-06 |
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