CN102009270A - Surface protection sheet for laser material processing - Google Patents
Surface protection sheet for laser material processing Download PDFInfo
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- CN102009270A CN102009270A CN2010105223811A CN201010522381A CN102009270A CN 102009270 A CN102009270 A CN 102009270A CN 2010105223811 A CN2010105223811 A CN 2010105223811A CN 201010522381 A CN201010522381 A CN 201010522381A CN 102009270 A CN102009270 A CN 102009270A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/36—Removing material
- B23K26/38—Removing material by boring or cutting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/18—Working by laser beam, e.g. welding, cutting or boring using absorbing layers on the workpiece, e.g. for marking or protecting purposes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/70—Auxiliary operations or equipment
- B23K26/702—Auxiliary equipment
- B23K26/706—Protective screens
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K37/00—Auxiliary devices or processes, not specially adapted for a procedure covered by only one of the other main groups of this subclass
- B23K37/06—Auxiliary devices or processes, not specially adapted for a procedure covered by only one of the other main groups of this subclass for positioning the molten material, e.g. confining it to a desired area
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/241—Polyolefin, e.g.rubber
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/255—Polyesters
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/02—Iron or ferrous alloys
- B23K2103/04—Steel or steel alloys
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/02—Iron or ferrous alloys
- B23K2103/04—Steel or steel alloys
- B23K2103/05—Stainless steel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/08—Non-ferrous metals or alloys
- B23K2103/10—Aluminium or alloys thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/266—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension of base or substrate
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- Engineering & Computer Science (AREA)
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- Optics & Photonics (AREA)
- Mechanical Engineering (AREA)
- Plasma & Fusion (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Laser Beam Processing (AREA)
- Adhesive Tapes (AREA)
- Laminated Bodies (AREA)
Abstract
本发明的目的是提供一种激光加工用表面保护片,其被应用于激光束照射面的相对侧表面,该保护片在激光切割加工中可保护应用对象的表面,并使挂渣不易出现。根据本发明,提供一种激光加工用表面保护片1,其在通过激光束6照射在工件2上的切割工艺中,被应用于工件2的激光束照射表面2a的相对侧表面上,其包括基底层和形成在该基底层一个表面上的粘合剂层,其中所述基底层由基于JIS K7199(1999)于290℃测量的熔融粘度不大于200Pa.s的树脂材料制成,厚度为0.01-0.12mm。
The object of the present invention is to provide a surface protection sheet for laser processing, which is applied to the opposite side surface of the laser beam irradiation surface, the protection sheet can protect the surface of the applied object during laser cutting processing, and prevent dross from appearing. According to the present invention, there is provided a surface protection sheet 1 for laser processing, which is applied on the opposite side surface of the laser beam irradiated surface 2a of the workpiece 2 in the cutting process of irradiating the workpiece 2 with the laser beam 6, which comprises A base layer and an adhesive layer formed on one surface of the base layer, wherein the base layer is made of a resin material having a melt viscosity of not more than 200 Pa.s measured at 290° C. based on JIS K7199 (1999), and has a thickness of 0.01 -0.12mm.
Description
本申请是申请日为2006年6月27日、申请号为200680023392.7的中国专利申请的分案申请。This application is a divisional application of a Chinese patent application with an application date of June 27, 2006 and an application number of 200680023392.7.
发明领域field of invention
本发明涉及一种激光加工用表面保护片,其被应用于通过激光束辐照进行切割加工的工件。The present invention relates to a surface protection sheet for laser processing, which is applied to a workpiece subjected to cutting processing by laser beam irradiation.
背景技术Background technique
在运输、加工、包覆等过程中,应用树脂材料片以保护如金属板、涂层金属板、铝制窗扇、树脂板、装饰铜板、氯乙烯层压钢板、玻璃板等元件表面是惯常的操作。During transportation, processing, cladding, etc., it is customary to apply sheets of resin material to protect the surface of components such as metal plates, coated metal plates, aluminum window sashes, resin plates, decorative copper plates, vinyl chloride laminated steel plates, glass plates, etc. operate.
表面保护片所需要的性能包括应用到施用对象后保护层无脱离和层离,而剥离和去除后施用对象上无残留粘合剂层。此外,它包括在对具有应用于其上的表面保护片的加工物体进行处理后,在施用对象上无表面保护片的脱离和层离、损伤、和粘合剂残留等。例如,JP-A-2000-328022和JP-A-2002-302657公开了用于金属板的表面保护片。The required properties of the surface protection sheet include no peeling and delamination of the protective layer after application to the object of application, and no residual adhesive layer on the object of application after peeling and removal. In addition, it includes no detachment and delamination, damage, adhesive residue, etc. of the surface protective sheet on the application object after processing the processed object having the surface protective sheet applied thereto. For example, JP-A-2000-328022 and JP-A-2002-302657 disclose surface protective sheets for metal plates.
在用于板元件等的加工方法中,激光切割加工具有突出的优点。该优点是,与冲压加工不同,不需要各种冲模而只需要输入工作的设计数据,当加工对象(下文,也称作工件)特别是金属板时,比冲压加工需要更短的时间,甚至适用于较厚的工件,并且不需要润滑剂。因此,激光切割加工市场逐渐扩大。然而,激光切割工艺需要高压(约0.5-1.5Mpa)辅助气体供应。Among processing methods for plate elements and the like, laser cutting processing has outstanding advantages. This advantage is that, unlike stamping work, various dies are not required but only the design data of the work needs to be input. When the processing object (hereinafter, also referred to as a workpiece) is a metal plate in particular, it takes a shorter time than stamping work, and even Suitable for thicker workpieces and does not require lubricants. Therefore, the laser cutting processing market is gradually expanding. However, the laser cutting process requires high pressure (about 0.5-1.5Mpa) assist gas supply.
在某些情形中,出于外观等原因,需要对具有应用到其上的表面保护片的工件进行激光切割加工。在这种情况下,由于辅助气体的影响,会产生不希望发生的表面保护片与工件脱离的问题。为了解决这种问题,JP-A-2-295688,JP-A-7-241688和JP-A-2001-212690提出了能够抑制激光切割加工期间发生分层的激光切割加工方法。这些加工方法能够抑制保护片的分层。In some cases, for reasons of appearance or the like, it is desirable to perform laser cutting on a workpiece having a surface protection sheet applied thereto. In this case, due to the influence of the assist gas, there arises a problem that the surface protection sheet is undesirably detached from the workpiece. In order to solve such problems, JP-A-2-295688, JP-A-7-241688 and JP-A-2001-212690 propose laser cutting processing methods capable of suppressing delamination during laser cutting processing. These processing methods can suppress delamination of the protective sheet.
发明内容Contents of the invention
然而,上述现有技术文献中公开的所有方法都具有在激光束的照射下,工件表面的表面保护片的层离问题。其原因被认为是辅助气体只对激光束照射的表面产生影响。不过,仍没有实施将表面保护片应用在对其进行激光束照射的工件表面的相对侧。本发明的发明人进行了如下的激光切割加工,其中将上述现有技术文献中的表面保护片应用在对其激光束照射的工件表面的相对侧,但发现产生了新问题,当没有使用表面保护片进行激光切割工艺时,根本没有发现这些问题。即,切割部分周边出现了毛刺(挂渣)。图2是挂渣的说明图。图2(A)是平面视图,其中柱状通孔300是通过激光切割加工形成的。本发明发明人实施的激光切割加工中,激光束照射在表面保护片100应用于其上的工件200表面的相对侧表面200a上。图2(B)为沿图2(A)I-I的剖视图,其中在激光束照射表面200a的相对侧表面上出现高度t的挂渣210。一旦出现这种挂渣210,非优选地,就需要除去该挂渣的另外的步骤。此外,由于在工件200的激光切割加工中,与表面保护片100接触的表面主要是一种有棱角的台面,没有表面保护片100,工件自身在安放于其上时可能受损害。However, all the methods disclosed in the above-mentioned prior art documents have the problem of delamination of the surface protection sheet on the surface of the workpiece under the irradiation of the laser beam. The reason for this is considered to be that the assist gas only affects the surface irradiated with the laser beam. However, application of the surface protection sheet to the opposite side of the workpiece surface to which the laser beam is irradiated has not yet been practiced. The inventors of the present invention have conducted laser cutting processing in which the surface protection sheet in the above prior art document is applied to the opposite side of the workpiece surface to which the laser beam is irradiated, but found that a new problem arises when the surface is not used These problems were not found at all when the protective sheet was subjected to the laser cutting process. That is, burrs (dross) appeared around the cut portion. Fig. 2 is an explanatory diagram of dross. FIG. 2(A) is a plan view in which a columnar via
本发明目的是提供激光加工用表面保护片,其被应用在激光束照射面的相对侧表面,从而能够保护加工物体的表面,这是保护片的最基本作用,并且在激光切割加工过程中不容易产生挂渣。The object of the present invention is to provide a surface protection sheet for laser processing, which is applied on the opposite side surface of the laser beam irradiation surface, thereby being able to protect the surface of the processed object, which is the most basic function of the protection sheet, and does not need to be used during the laser cutting process. It is easy to produce dross.
本发明的发明人已发现,应用于激光束照射表面的相对侧表面的表面保护片防止在激光切割加工期间工件的熔融物被辅助气体容易地吹落,而所述吹落促进挂渣的形成。基于此,他们已发现不容易产生这个问题的激光加工用表面保护片,本发明特征在于如下:The inventors of the present invention have found that the surface protection sheet applied to the side surface opposite to the laser beam irradiated surface prevents the melt of the workpiece from being easily blown off by the assist gas during the laser cutting process, which promotes the formation of dross . Based on this, they have found a surface protection sheet for laser processing that is not prone to this problem, and the present invention is characterized by the following:
(1)一种激光加工用表面保护片,其在通过激光束照射在工件上的切割工艺中,被应用于工件的激光束照射面的相对侧的表面,其包括基底层和形成在该基底层一个表面上的粘合剂层,其中所述基底层由基于JIS K7199(1999)于290℃测量的熔融粘度不大于200Pa.s的树脂材料制成,且其厚度为0.01-0.12mm。(1) A surface protection sheet for laser processing, which is applied to the surface on the opposite side of the laser beam irradiated surface of the workpiece in a cutting process in which the workpiece is irradiated with a laser beam, which includes a base layer and a base layer formed on the base layer. An adhesive layer on one surface of the base layer, wherein the base layer is made of a resin material having a melt viscosity of not more than 200 Pa.s measured at 290° C. based on JIS K7199 (1999), and has a thickness of 0.01 to 0.12 mm.
(2)根据(1)所述的表面保护片,其中所述树脂材料包括聚酯基树脂。(2) The surface protection sheet according to (1), wherein the resin material includes a polyester-based resin.
(3)根据(2)所述的表面保护片,其中所述聚酯基树脂为聚(对苯二甲酸乙二醇酯)树脂。(3) The surface protection sheet according to (2), wherein the polyester-based resin is a poly(ethylene terephthalate) resin.
(4)根据(1)所述的表面保护片,其中所述树脂材料包括聚烯烃基树脂。(4) The surface protection sheet according to (1), wherein the resin material includes a polyolefin-based resin.
(5)根据(1)-(4)任一项所述的表面保护片,其中所述工件为金属板。(5) The surface protection sheet according to any one of (1) to (4), wherein the workpiece is a metal plate.
(6)根据(5)所述的表面保护片,其中所述金属板为不锈钢板。(6) The surface protection sheet according to (5), wherein the metal plate is a stainless steel plate.
(7)根据(5)所述的表面保护片,其中所述金属板为铝板。(7) The surface protection sheet according to (5), wherein the metal plate is an aluminum plate.
使用本发明中的激光加工用表面保护片,在激光切割加工期间不容易出现挂渣。因此,使得工件特别是金属板等在激光照射面的相对侧表面带有损伤保护的条件下进行激光切割加工成为可能。在本发明的一个实施方式中,通过在激光束照射的表面(图2(B)中的200a侧)上安装表面保护片,该表面保护片与较少的因辅助气体引起分层有关,使传统上不能实现的对其两个表面均带有保护片的工件进行激光切割加工成为可能。Using the surface protection sheet for laser processing in the present invention, dross is less likely to occur during laser cutting processing. Therefore, it is possible to perform laser cutting processing on workpieces, especially metal plates, etc., with damage protection on the side surfaces opposite to the laser irradiation surface. In one embodiment of the present invention, by installing a surface protection sheet on the surface irradiated by the laser beam (side 200a in FIG. Laser cutting of workpieces with protective sheets on both surfaces, which was not possible traditionally, becomes possible.
附图说明Description of drawings
图1简要表明了本发明激光加工用表面保护片的使用。图2为激光切割加工中出现的挂渣的说明图。Fig. 1 schematically shows the use of the surface protection sheet for laser processing of the present invention. FIG. 2 is an explanatory diagram of dross that occurs during laser cutting.
图中的符号如下:The symbols in the figure are as follows:
1激光加工用表面保护片;2工件;3加工头;31会聚透镜;4割嘴;41气体导入口;5气体供应装置;51导入管;6激光束;7辅助气体;100表面保护片;200工件;210挂渣;300通孔1 surface protection sheet for laser processing; 2 workpiece; 3 processing head; 31 converging lens; 4 cutting nozzle; 41 gas inlet; 5 gas supply device; 51 introduction tube; 6 laser beam; 7 auxiliary gas; 100 surface protection sheet; 200 workpieces; 210 dross; 300 through holes
本发明的最佳实施方式BEST MODE FOR CARRYING OUT THE INVENTION
本发明激光加工用表面保护片包含基底层和粘合剂层。基底层是由具有特定熔融粘度的树脂材料制成,并具有在特定范围内的厚度。粘合剂层可形成于基底层的一个表面上。The surface protection sheet for laser processing of the present invention comprises a base layer and an adhesive layer. The base layer is made of a resin material having a specific melt viscosity, and has a thickness within a specific range. An adhesive layer may be formed on one surface of the base layer.
构成基底层的树脂材料的熔融粘度是基于JIS K7199(1999)测量的。更为具体的,按照下文说明的方法获取测量样品,通过测试压力和体积流动速率的测量方法,在290℃使用毛细管冲模获取熔融粘度。获得测试样品的具体方法如下:The melt viscosity of the resin material constituting the base layer is measured based on JIS K7199 (1999). More specifically, a measurement sample was obtained in accordance with the method described below, and the melt viscosity was obtained at 290° C. using a capillary die by testing the pressure and volume flow rate measurement methods. The specific method of obtaining test samples is as follows:
·当构成基底层的树脂材料透明时,对树脂材料进行压片(palletize)以得到测试样品。· When the resin material constituting the base layer is transparent, the resin material is palletized to obtain a test sample.
·当粘合剂层和基底层可以分离时,使用有机溶剂等去除粘合剂层,并只对基底层进行精切割得到测试样品。• When the adhesive layer and the base layer can be separated, remove the adhesive layer using an organic solvent, etc., and fine-cut only the base layer to obtain a test sample.
·当粘合剂层和基底层不易分离时,对整个表面保护片进行精切割得到测试样品,通过测量测试样品获得的熔融粘度作为构成基底层的树脂材料的熔融粘度。• When the adhesive layer and the base layer are not easily separated, the entire surface protection sheet is finely cut to obtain a test sample, and the melt viscosity obtained by measuring the test sample is taken as the melt viscosity of the resin material constituting the base layer.
·当基底层具有多层结构时,对整个基底层进行精切割得到测试样品。• When the base layer has a multi-layer structure, fine-cut the entire base layer to obtain a test sample.
本发明中,将具有经如上所述测试方法测量的熔融粘度不大于200Pa·s,优选不超过150Pa·s,更优选20至100Pa·s的树脂材料作为基底层材料。当熔融粘度超过200Pa·s时,激光切割部分中的基底层不易被吹走,结果容易产生挂渣。当熔融粘度在上述优选范围内时,挂渣更容易被辅助气体吹走,从而膜的形成变得更容易。In the present invention, a resin material having a melt viscosity of not more than 200 Pa·s, preferably not more than 150 Pa·s, more preferably 20 to 100 Pa·s as measured by the above-mentioned test method is used as the base layer material. When the melt viscosity exceeds 200 Pa·s, the base layer in the laser cut part is not easily blown away, and as a result, dross is easily generated. When the melt viscosity is within the above preferred range, the dross is more easily blown away by the assist gas, so that the film formation becomes easier.
具有在290℃测得的不超过200Pa·s熔融粘度的树脂材料典型地包括聚酯基树脂。其中,可提及聚(对苯二甲酸乙二醇酯)、聚(对苯二甲酸丁二醇酯)、聚(萘二甲酸乙二醇酯)、聚(对苯二甲酸丙二醇酯)、聚(乳酸)、聚碳酸酯等。此外,可提及酰胺基聚合物,例如尼龙-6、尼龙-66、尼龙-12等;苯乙烯基聚合物,例如HIPS,GPPS等;丙烯酸基聚合物,例如聚(甲基丙烯酸甲酯)等;聚烯烃基树脂,例如丙烯基聚合物,乙烯基聚合物,乙烯基共聚的聚合物等。作为丙烯基聚合物,可提及均聚物系列、嵌段聚合物系列、无规聚合物系列等。作为乙烯基聚合物,可提及低密度、高密度、线性低密度聚合物等。作为乙烯基共聚物,可提及乙烯和极性聚合物例如醋酸乙烯酯、甲基丙烯酸甲酯、丙烯酸等的共聚物,及类似物。可使用这些聚合物的单独一种或两种或其更多种的任意混合作为树脂材料。上述的这些树脂熔融粘度不必在前述的范围内,并且本发明所使用的树脂可从这些按JIS定义的方法测量的这些树脂中容易地获得。此外,基底层可被制成具有多层结构以及类似结构。Resin materials having a melt viscosity of not more than 200 Pa·s measured at 290°C typically include polyester-based resins. Among them, mention may be made of poly(ethylene terephthalate), poly(butylene terephthalate), poly(ethylene naphthalate), poly(trimethylene terephthalate), Poly(lactic acid), polycarbonate, etc. In addition, amide-based polymers such as nylon-6, nylon-66, nylon-12, etc.; styrene-based polymers such as HIPS, GPPS, etc.; acrylic-based polymers such as poly(methyl methacrylate) can be mentioned. etc.; polyolefin-based resins, such as propylene-based polymers, vinyl polymers, vinyl-copolymerized polymers, etc. As the propylene-based polymer, there may be mentioned homopolymer series, block polymer series, random polymer series, and the like. As the vinyl polymer, there may be mentioned low density, high density, linear low density polymers and the like. As the vinyl copolymer, there may be mentioned copolymers of ethylene and polar polymers such as vinyl acetate, methyl methacrylate, acrylic acid, and the like, and the like. A single one of these polymers or an arbitrary mixture of two or more of them can be used as the resin material. The above-mentioned melt viscosities of these resins are not necessarily within the aforementioned ranges, and the resins used in the present invention can be easily obtained from these resins measured by the methods defined by JIS. In addition, the base layer may be made to have a multi-layer structure and the like.
在不会削弱本发明效果的范围内,基底层可包含适当的添加剂,例如填料(如,碳酸钙、滑石、氧化钙等)、防结块剂、润滑剂、二氧化钛、用于着色的有机和无机颜料、用于防降解的抗氧化剂等、UV吸收剂、光稳定剂、抗静电剂等。此外,也可加入一种用于改善基底层弹性的增塑剂等。另外,对基底层表面可进行表面处理例如电晕处理等处理,目的是改善其与后处理剂、粘合剂和底涂层剂的粘附性。为了避免挂渣产生和确保作为保护片的作用,基底层的厚度下限是0.01mm,优选0.02mm。上限为0.12mm,优选0.10mm,更优选0.05mm。The base layer may contain appropriate additives such as fillers (such as calcium carbonate, talc, calcium oxide, etc.), anti-blocking agents, lubricants, titanium dioxide, organic and Inorganic pigments, antioxidants for anti-degradation, etc., UV absorbers, light stabilizers, antistatic agents, etc. In addition, a plasticizer or the like for improving the elasticity of the base layer may also be added. In addition, surface treatment such as corona treatment can be carried out on the surface of the base layer to improve its adhesion with post-treatment agents, adhesives and primers. In order to avoid dross generation and ensure the function as a protective sheet, the lower limit of the thickness of the base layer is 0.01mm, preferably 0.02mm. The upper limit is 0.12 mm, preferably 0.10 mm, more preferably 0.05 mm.
下面对粘合剂层进行说明Adhesive layer is explained below
粘合剂层形成在基底层的一个表面上。粘合剂层仅需要对不锈钢板具有粘附性,该不锈钢板为典型工件。作为粘合剂层材料的粘合剂,可使用已知的橡胶基粘合剂、丙烯酸基粘合剂、聚酯基粘合剂和聚氨酯基粘合剂。在这些粘合剂中,从对金属板的粘附性、脱模性和成本方面考虑,优选橡胶基粘合剂和丙烯酸基粘合剂。优选使用这些粘合剂的粘合剂层,因为除不锈钢板外,其对金属板和玻璃板也具有粘附性。An adhesive layer is formed on one surface of the base layer. The adhesive layer only needs to have adhesion to the stainless steel plate, which is a typical workpiece. As the adhesive of the adhesive layer material, known rubber-based adhesives, acrylic-based adhesives, polyester-based adhesives, and polyurethane-based adhesives can be used. Among these adhesives, rubber-based adhesives and acrylic-based adhesives are preferable from the viewpoints of adhesion to metal plates, mold release, and cost. Adhesive layers of these adhesives are preferably used because of their adhesion to metal plates and glass plates in addition to stainless steel plates.
作为橡胶基粘合剂,例如,可提及天然橡胶基粘合剂、合成橡胶基粘合剂等。作为合成橡胶基粘合剂,用作主要成分的有苯乙烯基弹性体,例如聚丁二烯、聚异戊二烯、丁基橡胶、聚异丁烯、苯乙烯-丁二烯-苯乙烯嵌段共聚物等,苯乙烯基弹性体,例如苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物、苯乙烯-乙烯-丁烯无规共聚物等,乙烯-丙烯橡胶,丙烯-丁烯橡胶,乙烯-丙烯-丁烯橡胶等。As the rubber-based adhesive, for example, natural rubber-based adhesives, synthetic rubber-based adhesives, and the like can be mentioned. As synthetic rubber-based adhesives, styrene-based elastomers such as polybutadiene, polyisoprene, butyl rubber, polyisobutylene, styrene-butadiene-styrene block are used as main components Copolymers, etc., styrene-based elastomers, such as styrene-ethylene-butylene-styrene block copolymers, styrene-ethylene-butylene random copolymers, etc., ethylene-propylene rubber, propylene-butylene rubber, Ethylene-propylene-butene rubber, etc.
作为丙烯酸基粘合剂,使用例如,烷基(甲基)丙烯酸酯诸如(甲基)丙烯酸丁酯、(甲基)丙烯酸2-乙基己酯等作为主要成分的单体混合物的共聚物,必要时,使用其它单体作为用于改性的可共聚单体,所述其它单体诸如含羟基的单体(例如,2-羟乙基(甲基)丙烯酸酯等)、含羧基的单体(例如(甲基)丙烯酸等)、苯乙烯基单体(例如苯乙烯等)、乙烯酯(例如醋酸乙烯酯等)、及类似单体。丙烯酸基粘合剂可通过常规的聚合方法如溶液聚合方法、乳液聚合方法、UV聚合方法等获得。As the acrylic-based adhesive, for example, a copolymer of a monomer mixture of an alkyl (meth)acrylate such as butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, etc. as a main component is used, If necessary, other monomers such as hydroxyl group-containing monomers (for example, 2-hydroxyethyl (meth)acrylate, etc.), carboxyl group-containing monomers, etc., are used as copolymerizable monomers for modification. monomers (such as (meth)acrylic acid, etc.), styrene-based monomers (such as styrene, etc.), vinyl esters (such as vinyl acetate, etc.), and similar monomers. The acrylic-based adhesive can be obtained by a conventional polymerization method such as a solution polymerization method, an emulsion polymerization method, a UV polymerization method, and the like.
必要时,为控制这些粘合剂等的粘附性,可以添加例如交联剂、增粘剂、软化剂、烯烃基树脂、硅酮基聚合物、液态丙烯酸基共聚物、磷酸酯系列化合物、抗老化剂、光稳定剂如受阻胺系列光稳定剂等、UV吸收剂和其它例如适当的添加剂,例如填料、颜料等,如氧化钙、氧化镁、碳酸钙、二氧化硅、氧化锌和二氧化钛。If necessary, in order to control the adhesiveness of these adhesives and the like, for example, crosslinking agents, tackifiers, softeners, olefin-based resins, silicone-based polymers, liquid acrylic-based copolymers, phosphate ester series compounds, Anti-aging agents, light stabilizers such as hindered amine series light stabilizers, etc., UV absorbers and other suitable additives such as fillers, pigments, etc., such as calcium oxide, magnesium oxide, calcium carbonate, silicon dioxide, zinc oxide and titanium dioxide .
增粘剂的加入有效地改善了粘合性,相对每100重量份的上述粘合剂,增粘剂添加量优选0-50重量份,特别是0-30重量份,特别优选0-10重量份,以此来改善粘合性能从而避免由于内聚力减少等原因出现的粘合剂残留问题。本文中,0重量份是指未添加增粘剂。The addition of the tackifier effectively improves the adhesion, relative to every 100 parts by weight of the above adhesive, the amount of the tackifier added is preferably 0-50 parts by weight, especially 0-30 parts by weight, particularly preferably 0-10 parts by weight In order to improve the adhesive performance and avoid the problem of adhesive residue due to the reduction of cohesion and other reasons. Herein, 0 parts by weight means that no tackifier is added.
作为增粘剂,可使用例如一种或多种已知的合适粘合剂,如石油基树脂(例如脂肪族系列、芳香族系列、脂肪族-芳香族共聚物系列、脂环族系列等)、香豆酮-茚基树脂、萜烯基树脂、萜烯-苯酚基树脂、聚合松香基树脂、(烷基)苯酚基树脂、二甲苯基树脂及其氢化系列树脂等。As the tackifier, for example, one or more known suitable adhesives such as petroleum-based resins (e.g. aliphatic series, aromatic series, aliphatic-aromatic copolymer series, alicyclic series, etc.) can be used , coumarone-indenyl resins, terpene-based resins, terpene-phenol-based resins, polymerized rosin-based resins, (alkyl)phenol-based resins, xylyl resins and their hydrogenated series resins, etc.
软化剂的添加对改善粘合性能通常是有效的。作为软化剂,可使用例如,一种或多种低分子量的二烯基聚合物、聚异丁烯、氢化聚异戊二烯、氢化聚丁二烯及其衍生物,其添加量可适当地确定。特别地,每100重量份的上述粘合剂,是0-40重量份,特别是0-20重量份,特别是0-10重量份。本文所用0重量份是指未添加软化剂。当添加量不大于40重量份时,即使在高温或暴露于室外等环境下,粘合剂残留也很少。The addition of softeners is usually effective in improving adhesive properties. As the softener, for example, one or more of low-molecular-weight diene-based polymers, polyisobutylene, hydrogenated polyisoprene, hydrogenated polybutadiene, and derivatives thereof can be used, and the addition amount thereof can be appropriately determined. In particular, per 100 parts by weight of the above adhesive, it is 0-40 parts by weight, especially 0-20 parts by weight, especially 0-10 parts by weight. As used herein, 0 parts by weight means that no softener is added. When the added amount is not more than 40 parts by weight, there will be little adhesive residue even under high temperature or exposure to outdoor environment.
粘合剂层厚度可根据粘合性能等适当确定。通常,厚度设定为0.001-0.050mm,尤其是0.002-0.020mm,特别是0.003-0.015mm。必要时,粘合剂层也通过临时安装隔板等进行保护直到实际应用。The thickness of the adhesive layer can be appropriately determined according to adhesive performance and the like. Usually, the thickness is set at 0.001-0.050mm, especially 0.002-0.020mm, especially 0.003-0.015mm. When necessary, the adhesive layer is also protected until actual use by temporarily installing a partition or the like.
激光加工用表面保护片可根据已知的粘合片形成方法制成,该已知方法例如包括将粘合剂组合物溶解在溶剂中得到的溶液或加热所述组合物得到的液态熔融体施加到基底层的方法、包括在隔板上形成粘合剂层并将该粘合剂层转移和粘附到基底层的方法、包括挤出并形成用于在基底层上形成粘合剂层的材料以涂布基底层的方法、包括以两层或多层方式共挤出基底层和粘合剂层的方法、包括将粘合剂层单层层压到基底层上的方法或将层压层与粘合剂层的两层层压到基底层上的方法、包括层压粘合剂层与基底层或层压层等的两层或多层等的方法,等等。The surface protection sheet for laser processing can be produced according to a known adhesive sheet forming method including, for example, a solution obtained by dissolving an adhesive composition in a solvent or applying a liquid melt obtained by heating the composition. A method to a base layer, comprising forming an adhesive layer on a separator and transferring and adhering the adhesive layer to the base layer, comprising extruding and forming an adhesive layer for forming the adhesive layer on the base layer The method of coating the base layer, the method including co-extruding the base layer and the adhesive layer in two or more layers, the method including monolayer lamination of the adhesive layer on the base layer or laminating A method of laminating two layers of an adhesive layer and an adhesive layer on a base layer, a method including laminating two or more layers of an adhesive layer and a base layer or a laminate layer, etc., and the like.
本发明激光加工用表面保护片可具有脱模层。作为用于形成脱模层的后处理剂,通常使用溶剂型或非溶剂型硅酮基聚合物或长链烷基聚合物制成的后处理剂。具体地,可使用Peeloil(Ipposha Yushi KogyoCo.,Ltd.制造)、Shin-Etsu硅树脂(Shin-Etsu Chemical Co.,Ltd.制造)等。作为形成脱模层的方法,可使用例如,已知的涂布方法如使用辊涂机(例如,凹辊法等)进行涂布的方法、通过喷雾等形式的雾化方法等。The surface protection sheet for laser processing of the present invention may have a release layer. As a post-treatment agent for forming a release layer, a post-treatment agent made of a solvent-type or non-solvent type silicone-based polymer or a long-chain alkyl polymer is generally used. Specifically, Peeloil (manufactured by Ipposha Yushi Kogyo Co., Ltd.), Shin-Etsu silicone resin (manufactured by Shin-Etsu Chemical Co., Ltd.), or the like can be used. As a method of forming the release layer, for example, a known coating method such as a method of coating using a roll coater (eg, a gravure method, etc.), an atomization method by spraying or the like, and the like can be used.
对本发明激光加工用表面保护片应用说明见下文。The description of the application of the surface protection sheet for laser processing of the present invention is given below.
图1表示本发明激光加工用表面保护片的应用。将本发明激光加工用表面保护片1粘附在通过激光束6照射进行切割处理的工件2上。本图显示的设备中,激光束6通过加工头3的会聚透镜31聚焦,然后从割嘴4处照射工件2。但是,本发明激光束发生器不限于图中显示的一种。辅助气体7从割嘴4与激光束6一同在约0.5-1.5MPa的高压下喷向工件2。辅助气体7自气体供应装置5例如气体柱等由导入管51和气体导入口41供应。对于辅助气体7,根据工件2的材料和所需要切断表面的质量可适当使用不同的气体。典型地,使用氮气、空气等。Fig. 1 shows the application of the surface protection sheet for laser processing of the present invention. A
工件2为切割对象,其例如是金属板、被涂布的金属板、铝窗扇、树脂板、装饰性铜板、氯乙烯层压钢板、玻璃板等。在易于产生挂渣且需要优良外观的金属板,尤其是不锈钢板和铝制板情况下,本发明效果尤为突出。The
通过激光束6照射进行的切割加工包括,激光束6从工件2的一侧照射以形成穿透到照射面的相对侧的切割截面,从而使至少工件的一部分断开。如图2所示,它可以是去除柱状部分的加工,或者将大工件分成多个小件的加工。在切割加工中,本发明用于激光加工的表面保护片1将被粘附在工件2(加工对象)的激光束照射面2a的相对侧的表面上。换言之,通过向表面2a照射激光束6进行切割加工,此表面2a为带有本发明应用于工件2的激光加工用表面保护片1的工件2应用表面的相对侧的表面。将本发明用于激光加工的表面保护片1应用到工件2的激光束照射面2a的相对侧的表面上,至少应用到通过切割加工切割下的那部分上。工件2中,将本发明的激光加工表面保护片应用到其上的表面,可避免由于固定激光加工设备等而引起的破坏,此外,不容易引发挂渣。The cutting process by irradiation of the
实施例Example
下文中通过参考实施例更详细解释本发明,不应解释为对发明的限制。Hereinafter, the present invention is explained in more detail by referring to examples, which should not be construed as limiting the invention.
(实施例1)(Example 1)
将异氰酸酯系列交联剂(3重量份,CORONATE L,NIPPONPOLYURETHANE INDUSTRY CO.,LTD.生产)加入到包含丙烯酸基粘合剂(重量份100,基于聚苯乙烯的重均分子重量为600,000)的乙酸乙酯溶液中,得到丙烯酸基粘合剂溶液,该丙烯酸基粘合剂含有丙烯酸2-乙基己酯(2EHA,30wt%)、丙烯酸乙酯(EA,60%),甲基丙烯酸甲酯(MMA,6wt%)和丙烯酸2-羟乙基酯(HEA,4wt%)。An isocyanate series crosslinking agent (3 parts by weight, CORONATE L, produced by NIPPONPOLYURETHANE INDUSTRY CO., LTD.) was added to acetic acid containing an acrylic-based adhesive (100 parts by weight, with a weight-average molecular weight of 600,000 based on polystyrene). In ethyl ester solution, obtain acrylic base adhesive solution, this acrylic base adhesive contains 2-ethylhexyl acrylate (2EHA, 30wt%), ethyl acrylate (EA, 60%), methyl methacrylate ( MMA, 6 wt%) and 2-hydroxyethyl acrylate (HEA, 4 wt%).
厚度为0.038mm的聚(对苯二甲酸乙二醇酯)膜(Tetoron Film G2,Teijin DuPont Films Japan Limited制造)直接用作基底层。采样于基底层的树脂材料在290℃的熔融粘度为74pa·s。A poly(ethylene terephthalate) film (Tetoron Film G2, manufactured by Teijin DuPont Films Japan Limited) having a thickness of 0.038 mm was directly used as the base layer. The melt viscosity at 290° C. of the resin material sampled in the base layer was 74 Pa·s.
丙烯酸基粘合剂溶液被应用到前述提及的基底层并且干燥,形成0.010mm厚的粘合剂层,由此得到激光加工用表面保护片。The acrylic-based adhesive solution was applied to the aforementioned base layer and dried to form an adhesive layer with a thickness of 0.010 mm, whereby a surface protection sheet for laser processing was obtained.
(实施例2)(Example 2)
在冲模温度为250℃时,通过T型冲模方法将聚(对苯二甲酸丁二醇酯)(DURANEX 200FP,WinTech Polymer Ltd.制造)制成膜以得到0.04mm厚的基底层。取样于基底层的树脂材料在290℃的熔融粘度为26pa·s。Poly(butylene terephthalate) (DURANEX 200FP, manufactured by WinTech Polymer Ltd.) was formed into a film by a T-die method at a die temperature of 250° C. to obtain a 0.04 mm thick base layer. The melt viscosity at 290° C. of the resin material sampled from the base layer was 26 Pa·s.
将实施例1中采用的丙烯酸基粘合剂溶液应用到该基底层,并且干燥形成0.005mm厚的粘合剂层,由此,得到激光加工用表面保护片。The acrylic-based adhesive solution used in Example 1 was applied to the base layer, and dried to form an adhesive layer with a thickness of 0.005 mm, whereby a surface protection sheet for laser processing was obtained.
(实施例3)(Example 3)
除了0.05mm厚的聚(对苯二甲酸乙二醇酯)膜(Tetoron Film G2,Teijin DuPont Films Japan Limited制造)被用作基底层,以与实施例1相同方式,得到激光加工用表面保护片。Except that a 0.05 mm thick poly(ethylene terephthalate) film (Tetoron Film G2, manufactured by Teijin DuPont Films Japan Limited) was used as the base layer, in the same manner as in Example 1, a surface protection sheet for laser processing was obtained .
(实施例4)(Example 4)
低密度聚乙烯(MIRASON 68P,Mitsui Chemicals,Inc.)被用作基底层材料,苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物(Tuftec H1062,AsahiKasei Corporation制造,重量份为100)和氢化石油树脂(ARKONP-100,Arakawa Chemical Industries,Ltd.制造,重量份为50)的混合物被用作粘合剂层材料。通过T型冲模方法在模温度为170℃共挤出这些材料以得到激光加工用表面保护片,在厚度为0.05mm的基底层上形成厚度为0.01mm的粘合剂层。取样于前述基底层的树脂材料在290℃的熔融粘度为47pa·s。Low-density polyethylene (MIRASON 68P, Mitsui Chemicals, Inc.) was used as the base layer material, and styrene-ethylene-butylene-styrene block copolymer (Tuftec H1062, manufactured by AsahiKasei Corporation, 100 parts by weight) and hydrogenated A mixture of petroleum resin (ARKONP-100, manufactured by Arakawa Chemical Industries, Ltd., 50 parts by weight) was used as the adhesive layer material. These materials were co-extruded by a T-die method at a die temperature of 170° C. to obtain a surface protection sheet for laser processing, and an adhesive layer with a thickness of 0.01 mm was formed on a base layer with a thickness of 0.05 mm. The melt viscosity at 290° C. of the resin material sampled from the base layer was 47 pa·s.
(实施例5)(Example 5)
除了粘合剂层厚度设定为5μm外,与实施例1相同方式,得到激光加工用表面保护片。A surface protection sheet for laser processing was obtained in the same manner as in Example 1 except that the thickness of the adhesive layer was set to 5 μm.
(对比例1)(comparative example 1)
在模温度为160℃通过吹膜方法,将低密度聚乙烯(SUMIKATHENE F208,Sumitomo Chemical Co.,Ltd.制造)制成膜以得到0.11mm厚的基底层。取样于前述基底层的树脂材料在290℃的熔融粘度为285Pa·s。Low-density polyethylene (SUMIKATHENE F208, manufactured by Sumitomo Chemical Co., Ltd.) was formed into a film by a film blowing method at a mold temperature of 160°C to obtain a base layer of 0.11 mm thick. The melt viscosity at 290° C. of the resin material sampled from the base layer was 285 Pa·s.
对基底层的一个表面进行电晕放电处理,并将用于实施例1中的丙烯酸基粘合剂溶液应用到该处理后的表面,并干燥以形成0.010mm厚的粘合剂层,由此,得到激光加工用表面保护片。One surface of the base layer was subjected to corona discharge treatment, and the acrylic-based adhesive solution used in Example 1 was applied to the treated surface, and dried to form a 0.010 mm thick adhesive layer, whereby , to obtain a surface protection sheet for laser processing.
(对比例2)(comparative example 2)
除基底层厚度设定为0.06mm之外,以与对比例1相同的方式得到激光加工用表面保护片。A surface protection sheet for laser processing was obtained in the same manner as in Comparative Example 1 except that the thickness of the base layer was set to 0.06 mm.
(对比例3)(comparative example 3)
除了0.125mm厚的聚(对苯二甲酸乙二醇酯)膜(Tetoron Film G2,Teijin DuPont Films Japan Limited制造)被用作基底层之外,与实施例1相同方式得到激光加工用表面保护片。如实施例1相同,取样于基底层的树脂材料在290℃的熔融粘度为74Pa·s。A surface protection sheet for laser processing was obtained in the same manner as in Example 1, except that a 0.125 mm thick poly(ethylene terephthalate) film (Tetoron Film G2, manufactured by Teijin DuPont Films Japan Limited) was used as the base layer . As in Example 1, the melt viscosity at 290° C. of the resin material sampled from the base layer was 74 Pa·s.
(对比例4)(comparative example 4)
在模温度为230℃,通过T型冲模方法将聚丙烯(Novatech PPFL6H,Japan Polypropylene Corporation制造)制成膜,以得到0.04mm厚的基底层。取样于基底层的树脂材料在290℃的熔融粘度为422Pa·s。Polypropylene (Novatech PPFL6H, manufactured by Japan Polypropylene Corporation) was formed into a film by a T-die method at a mold temperature of 230°C to obtain a base layer of 0.04 mm thick. The melt viscosity at 290° C. of the resin material sampled from the base layer was 422 Pa·s.
对基底层的一个表面进行电晕放电处理,并将用于实施例1中的丙烯酸基粘合剂溶液应用到处理后的表面,并且干燥形成0.010mm厚的粘合剂层,由此,得到激光加工用表面保护片。One surface of the base layer was subjected to corona discharge treatment, and the acrylic-based adhesive solution used in Example 1 was applied to the treated surface, and dried to form an adhesive layer with a thickness of 0.010 mm, whereby, Surface protection sheet for laser processing.
(对比例5)(comparative example 5)
在冲模温度为270℃,通过T型冲模将聚(对苯二甲酸丁二醇酯)(DURANEX 800FP,WinTech Polymer Ltd.制造)制成膜,以得到0.04mm厚的基底层。取样于基底层的树脂材料在290℃的熔融粘度为295Pa·s。Poly(butylene terephthalate) (DURANEX 800FP, manufactured by WinTech Polymer Ltd.) was formed into a film through a T-die at a die temperature of 270° C. to obtain a base layer of 0.04 mm thick. The melt viscosity at 290° C. of the resin material sampled from the base layer was 295 Pa·s.
实施例1中的丙烯酸基粘合剂溶液应用到基底层的一个表面,并且干燥形成0.005mm厚的粘合剂层,由此,得到激光加工用表面保护片。The acrylic-based adhesive solution in Example 1 was applied to one surface of the base layer, and dried to form an adhesive layer with a thickness of 0.005 mm, whereby a surface protection sheet for laser processing was obtained.
(熔融粘度测量)(melt viscosity measurement)
通过前述的方法测量熔融粘度。具体地,使用JIS K7199中描述的毛细管流变仪(Capirograph 1B,Toyo Seiki Seisaku-sho,Ltd.制造),并在割嘴直径D为1.0mm,成型段长度(land length)L为30mm,剪切速率为10sec-1的情况下进行测量。Melt viscosity was measured by the aforementioned method. Specifically, a capillary rheometer (Capirograph 1B, manufactured by Toyo Seiki Seisaku-sho, Ltd.) described in JIS K7199 was used, and the cutting nozzle diameter D was 1.0 mm, and the land length L was 30 mm. The measurement was performed at a cutting rate of 10 sec -1 .
(激光切割加工条件)(Laser cutting processing conditions)
使用二氧化碳气体激光加工机(LC-3015θII,AMADA CO.,LTD.制造)和振荡器(OLC-420HII,AMADA CO.,LTD.制造),并在切割速率2200mm/min、输出功率3000W、频率0Hz、占空系数(duty)100、氮气压力0.85MPa,割嘴直径2.0mm、割嘴间隙0.3mm、激光束聚焦在工件(金属板)的上表面以下1.0mm处的情况下进行线切割加工。Using a carbon dioxide gas laser processing machine (LC-3015θII, manufactured by AMADA CO., LTD.) and an oscillator (OLC-420HII, manufactured by AMADA CO., LTD.), and at a cutting rate of 2200mm/min, an output power of 3000W, and a frequency of 0Hz , duty factor (duty) 100, nitrogen pressure 0.85MPa, cutting nozzle diameter 2.0mm, cutting nozzle gap 0.3mm, laser beam focused on the upper surface of the workpiece (metal plate) at 1.0mm below the wire cutting process.
(激光切割加工测试)(laser cutting processing test)
使用2.0mm厚的SUS304(2B饰面)作为工件。每一实施例或对比例中得到的激光加工用表面保护片被应用到其上的一个表面。在前述条件下,通过将激光束照射在应用有前述片的表面的相对侧表面而进行切割加工测试。Use 2.0mm thick SUS304 (2B finish) as the workpiece. The surface protective sheet for laser processing obtained in each example or comparative example was applied to one surface thereon. Under the aforementioned conditions, a cutting process test was performed by irradiating a laser beam on the side surface opposite to the surface to which the aforementioned sheet was applied.
测试后,测定应用有前述片的表面上出现的挂渣高度。从切割边缘面的高度减去金属板厚度(2.0mm)得到的差值作为挂渣的高度。作为测量仪器,使用JIS B7503(1997)描述的、最小刻度为0.01mm的指示表。按10mm的间距测量10个点从而得到平均值。结果列于表1中。After the test, the height of dross occurring on the surface to which the aforementioned sheet was applied was determined. The difference obtained by subtracting the thickness of the metal plate (2.0 mm) from the height of the cutting edge surface is taken as the height of dross. As a measuring instrument, an indicating gauge described in JIS B7503 (1997) with a minimum scale of 0.01 mm is used. Ten points were measured at intervals of 10 mm to obtain an average value. The results are listed in Table 1.
另外,实施例5得到的激光加工用表面保护片被应用到工件的一个表面上,SPV-M-4002E(NITTO DENKO CORPORATION制造)被应用到工件的另一表面,所得试样作为实施例6。在实施例6中,在前述条件下,通过将激光束照射到应用有M-4002E的表面进行切割加工测试。In addition, the surface protection sheet for laser processing obtained in Example 5 was applied to one surface of the workpiece, and SPV-M-4002E (manufactured by NITTO DENKO CORPORATION) was applied to the other surface of the workpiece, and the obtained sample was used as Example 6. In Example 6, under the aforementioned conditions, a cutting process test was performed by irradiating a laser beam to the surface to which M-4002E was applied.
对未应用表面保护片的工件进行激光切割加工作为对比例6。Laser cutting was performed on a workpiece without a surface protection sheet as Comparative Example 6.
表1Table 1
如表1所示,其阐明了每个实施例的激光加工用表面保护片都可降低挂渣的高度到与没有应用表面保护片的实施例相同的水平。As shown in Table 1, it illustrates that the surface protection sheet for laser processing of each embodiment can reduce the height of dross to the same level as that of the embodiment without the application of the surface protection sheet.
本申请基于在日本提交的专利申请号为NO.2005-187216的申请,在此引入其全文内容以供参考。This application is based on Patent Application No. 2005-187216 filed in Japan, the entire contents of which are incorporated herein by reference.
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| JP2005187216 | 2005-06-27 | ||
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| CNA2006800233927A Division CN101208172A (en) | 2005-06-27 | 2006-06-27 | Surface protection sheet for laser material processing |
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| US (2) | US20090123740A1 (en) |
| EP (1) | EP1900470B1 (en) |
| KR (1) | KR20080023263A (en) |
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| CN113547210A (en) * | 2021-07-15 | 2021-10-26 | Tcl华星光电技术有限公司 | Particulate matter adhesion device and laser treatment process |
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| CN112122797A (en) * | 2020-09-24 | 2020-12-25 | 松山湖材料实验室 | Laser processing slag removal method, system, computer equipment and readable storage medium |
| CN113547210A (en) * | 2021-07-15 | 2021-10-26 | Tcl华星光电技术有限公司 | Particulate matter adhesion device and laser treatment process |
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| US9089930B2 (en) | 2015-07-28 |
| WO2007001078A1 (en) | 2007-01-04 |
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| TW200706629A (en) | 2007-02-16 |
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| EP1900470A1 (en) | 2008-03-19 |
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