CN101903970A - Dual Plasma Ion Source - Google Patents
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- CN101903970A CN101903970A CN2008801219714A CN200880121971A CN101903970A CN 101903970 A CN101903970 A CN 101903970A CN 2008801219714 A CN2008801219714 A CN 2008801219714A CN 200880121971 A CN200880121971 A CN 200880121971A CN 101903970 A CN101903970 A CN 101903970A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/02—Details
- H01J37/04—Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement or ion-optical arrangement
- H01J37/08—Ion sources; Ion guns
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- H—ELECTRICITY
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- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J27/00—Ion beam tubes
- H01J27/02—Ion sources; Ion guns
- H01J27/16—Ion sources; Ion guns using high-frequency excitation, e.g. microwave excitation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/02—Details
- H01J37/04—Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement or ion-optical arrangement
- H01J37/06—Electron sources; Electron guns
- H01J37/077—Electron guns using discharge in gases or vapours as electron sources
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- H—ELECTRICITY
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- H01J2237/00—Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
- H01J2237/06—Sources
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- H01J2237/06325—Cold-cathode sources
- H01J2237/06366—Gas discharge electron sources
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- H—ELECTRICITY
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- H01J2237/00—Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
- H01J2237/06—Sources
- H01J2237/08—Ion sources
- H01J2237/0815—Methods of ionisation
- H01J2237/082—Electron beam
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- H—ELECTRICITY
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Abstract
Description
技术领域technical field
本发明整体上涉及离子注入系统,尤其涉及用于利用双等离子体离子源进行离子注入的系统和方法。The present invention relates generally to ion implantation systems, and more particularly to systems and methods for ion implantation using dual plasma ion sources.
背景技术Background technique
在半导体器件和进一步的产品的制造中,离子注入系统用于将掺杂元素注入到半导体工件、显示面板和玻璃基板等中。为了制造n型和/或p型掺杂区域,或者在工件中形成钝化层,典型的离子注入系统或离子注入机用杂质的离子束对工件进行注入。在用于掺杂半导体时,离子注入系统将已选择的离子种类注射到所述工件中,以产生期望的非本征材料性质。典型地,掺杂剂原子或分子被电离并隔离、被加速和/或减速、被形成束,以及被注入到工件中。掺杂剂离子以物理方式撞击且进入工件的表面,且典型地停留在工件表面的下面且位于其晶格结构中。In the manufacture of semiconductor devices and further products, ion implantation systems are used to implant dopant elements into semiconductor workpieces, display panels and glass substrates, etc. To create n-type and/or p-type doped regions, or to form a passivation layer in a workpiece, a typical ion implantation system or ion implanter implants an ion beam of impurities into the workpiece. When used to dope semiconductors, ion implantation systems inject ion species into the workpiece that have been selected to produce desired extrinsic material properties. Typically, dopant atoms or molecules are ionized and isolated, accelerated and/or decelerated, beamed, and implanted into the workpiece. The dopant ions physically impinge on and enter the surface of the workpiece, and typically lodge beneath the surface of the workpiece and in its crystalline lattice structure.
典型的离子注入系统通常是复杂的分系统的集合,其中每个分系统对掺杂剂离子执行特定动作。可以以气体形式(例如工艺气体)或以固体形式(随后被蒸发)引入掺杂剂元素,其中所述掺杂剂元素被设置在电离腔的内部且通过适合的电离过程进行电离。在过去十年间,所谓的“Bemas-style”离子源已经被广泛地接收作为用于高电流和中电流离子注入系统的工业标准。例如,电离腔被保持在低压力下(例如真空),其中例如丝位于电离腔内且被加热到电子被从丝发射出的温度点。然后,来自所述丝的带负电的电子被吸引到所述腔内的电性相反的阳极,其中在从丝到阳极的行进过程中,电子与掺杂剂源元素(例如分子或原子)碰撞,这会导致电子与源气体材料分离,从而使所述源气体电离且产生等离子体,即来自掺杂剂源元素的多个带正电的离子和带负电的电子。带正电的离子随后被经由引出电极通过引出缝或孔从所述腔“引出”,其中通常沿着离子束路径朝向工件引导离子。A typical ion implantation system is usually a complex collection of subsystems, where each subsystem performs a specific action on the dopant ions. The dopant elements can be introduced in gaseous form (eg process gas) or in solid form (which is subsequently evaporated), wherein said dopant elements are arranged inside the ionization chamber and ionized by a suitable ionization process. During the past decade, so-called "Bemas-style" ion sources have gained wide acceptance as the industry standard for high and medium current ion implantation systems. For example, an ionization chamber is maintained at a low pressure (eg, vacuum) with eg a wire within the ionization chamber and heated to a point at which electrons are emitted from the wire. Negatively charged electrons from the filament are then attracted to an oppositely charged anode within the cavity, where during travel from the filament to the anode, the electrons collide with dopant source elements such as molecules or atoms , which causes electrons to separate from the source gas material, thereby ionizing the source gas and creating a plasma, ie, a plurality of positively charged ions and negatively charged electrons from the dopant source element. Positively charged ions are then "extracted" from the chamber via extraction electrodes through extraction slots or holes, where the ions are generally directed along the ion beam path toward the workpiece.
上述类型的被加热的丝阴极通常会随着时间快速地退化(degrade)。因此,已经开发出了对这种类型的离子源的常见的变体,且将其部署在商业离子注入系统中,其采用间接加热的阴极(IHC),其中电子发射器是被设置在电离腔内的圆筒形阴极,通常直径为10mm,厚度为5mm。所述阴极被由从位于阴极后面的丝引出的电子束加热,从而被保护免受电离腔的严酷环境的影响。在其它专利中(例如被共同受让给本发明的申请人的第5,497,006号美国专利)示出一个示例性IHC离子源。Heated filament cathodes of the type described above typically degrade rapidly over time. Therefore, a common variant of this type of ion source has been developed and deployed in commercial ion implantation systems, which employ an indirectly heated cathode (IHC) where the electron emitter is placed in the ionization chamber The inner cylindrical cathode is usually 10mm in diameter and 5mm thick. The cathode is heated by an electron beam drawn from a wire located behind the cathode, thus being protected from the harsh environment of the ionization chamber. An exemplary IHC ion source is shown in other patents, such as commonly assigned US Patent No. 5,497,006 to the applicant of the present invention.
在丝阴极的情形中,阴极加热器的功率通常在几百瓦的量级上,而在IHC的情形中,所述功率通常在一千瓦的量级上。在用标准注入气体(如三氟化硼(BF3)、磷化氢(PH3)和砷化氢(AsH3))进行操作时,典型的最大被引出的离子束电流处于50到100mA的范围内,需要数百瓦的放电功率(阴极电压乘以阴极电流)。在具有这些阴极加热器功率和放电功率的情况下,离子源的壁通常会达到超过400摄氏度的温度。对于标准气体的操作,因为防止了磷和砷在壁上的凝结,从而极大地减少在改变种类时的交叉污染,所以这些高壁温度是有利的。In the case of filament cathodes, the power of the cathode heater is typically on the order of a few hundred watts, while in the case of IHC the power is typically on the order of a kilowatt. Typical maximum extracted ion beam currents are in the range of 50 to 100 mA when operating with standard implant gases such as boron trifluoride (BF 3 ), phosphine (PH 3 ), and arsine (AsH 3 ). In the range, hundreds of watts of discharge power (cathode voltage multiplied by cathode current) is required. With these cathode heater powers and discharge powers, the walls of the ion source typically reach temperatures in excess of 400 degrees Celsius. For standard gas operation, these high wall temperatures are advantageous because condensation of phosphorus and arsenic on the walls is prevented, thereby greatly reducing cross-contamination when changing species.
对于低能量硼注入,已经证实了在生产量上具有实质的改进,例如,使用大的单个带电离子(例如癸硼烷(B10H14)或十八硼烷(B18H22))。为了防止分子的分解,这样的大分子等离子体的放电功率和等离子体密度与标准注入气体相比必须保持在更低的水平上。通常,引出的离子电流为5到10mA,仅需要几十瓦的放电功率。尽管上述的标准源可以使用标准注入气体在这些低的功率下稳定地运行,但是在运行癸硼烷或十八硼烷时会遇到问题。对于丝与气体接触的Bernas源的情形,所述丝受到硼烷的攻击(attack),而无法保持稳定的放电。在IHC的情形中,放电更加稳定,但大分子的热分解高得难以接受。由于阴极的高辐射功率,分解同时发生在热阴极和壁上,热阴极和壁很难保持处于低的温度。Substantial improvements in throughput have been demonstrated for low energy boron implantation, for example, using large single charged ions such as decaborane (B 10 H 14 ) or octadecaborane (B 18 H 22 )). To prevent molecular breakdown, the discharge power and plasma density of such macromolecular plasmas must be kept at lower levels compared to standard injection gases. Usually, the extracted ion current is 5 to 10mA, and only tens of watts of discharge power is required. While the above-mentioned standard sources can run stably at these low powers using standard injection gases, problems are encountered when running decaborane or octadecaborane. In the case of a Bernas source where the wire is in contact with the gas, the wire is attacked by borane and cannot maintain a stable discharge. In the case of IHC, the discharge is more stable, but the thermal decomposition of macromolecules is unacceptably high. Due to the high radiant power of the cathode, the decomposition takes place simultaneously on the hot cathode and the walls, which are difficult to keep at a low temperature.
在用气体(例如癸硼烷和十八硼烷)进行操作时所遇到的上述问题,可以通过从电离腔去除电子源来克服。在第6,686,595号的美国专利中描述了一种这样的方案,其中传统的宽束电子枪被安装在电离腔的外部,且电子束通过孔被引导到电离腔中。但是,在这样的源配置中,由于电子枪设计的基本原理限制,注射到电离腔中的电子电流被限制于几十毫安。因为在标准离子束电流为50到100mA时用标准注入气体的操作需要数百毫安到数安培的电子电流,所以这样的离子源配置不适合于这样的操作。实际上,离子注入系统制造商们已经充分认识到这样的问题,至少例如在第7,022,999号美国专利中描述了一种方案,其中已经提出将电离腔配置成两种分离的操作模式:一种模式用于低电子电流电离应用;和一种模式用于高电子电流电离应用。可替代地,已在第US2006/0169915号美国专利申请公开出版物中提出了一种离子源配置,其中第一电子源和第二电子源位于电弧腔的相对的两端,其中每个电子源被在所谓的“热”操作模式和“冷”操作模式中的一个中被激励。The above-mentioned problems encountered when operating with gases such as decaborane and octadecaborane can be overcome by removing the source of electrons from the ionization chamber. One such solution is described in US Patent No. 6,686,595, where a conventional broad beam electron gun is mounted outside the ionization chamber and the electron beam is directed into the ionization chamber through an aperture. However, in such a source configuration, the electron current injected into the ionization chamber is limited to a few tens of milliamperes due to fundamental limitations of electron gun design. Since operation with standard implant gases at standard ion beam currents of 50 to 100 mA requires electron currents of hundreds of milliamperes to several amperes, such an ion source configuration is not suitable for such operation. Indeed, manufacturers of ion implantation systems are well aware of such problems, at least for example in one approach described in U.S. Patent No. 7,022,999, in which it has been proposed to configure the ionization chamber into two separate modes of operation: a mode One mode for low electron current ionization applications; and one mode for high electron current ionization applications. Alternatively, an ion source configuration has been proposed in U.S. Patent Application Publication No. US2006/0169915, wherein a first electron source and a second electron source are located at opposite ends of the arc chamber, wherein each electron source is activated in one of the so-called "hot" and "cold" operating modes.
因此,为了满足离子注入工业的更多需求,对于可以用于大分子气体(所谓的“分子种类”)在低源壁温和低放电功率进行操作以及对于标准注入气体(所谓的“单体种类”)在高壁温和高放电功率下进行操作的离子源,存在需求。Therefore, in order to meet the more demands of the ion implantation industry, for the operation at low source wall temperature and low discharge power for macromolecular gases (so-called "molecular species") and for standard implant gases (so-called "monomeric species") ) There is a need for an ion source that operates at high wall temperature and high discharge power.
发明内容Contents of the invention
本发明通过提供一种两等离子体或双等离子体离子源系统和方法克服了对现有技术的限制,其用于有效地操作可以利用大分子(例如癸硼烷和十八硼烷)以及诸如BF3、PH3和AsH3的标准注入气体的离子源。因此,以下提出了本发明的简化的发明内容,以提供对本发明的某些方面的基本理解。这种发明内容不是对本发明的详尽概括。不是要区别本发明的重要的或关键元件,也不是要描述本发明的范围。其目的是以简化的形式提出本发明的一些概念,作为随后提出的更详细的描述的前序。本发明整体上涉及在离子注入系统中使用的离子源,其中所述离子源包含两个或多个等离子体腔,使得第一等离子体腔是可操作的以产生用于注入到第二等离子体腔中的电子,使得第二等离子体腔可以有效率地且有效地产生用于注入离子注入系统的离子线束中的离子。The present invention overcomes the limitations of the prior art by providing a two-plasma or dual-plasma ion source system and method that can utilize macromolecules (such as decaborane and octadecaborane) and materials such as Ion source for standard implant gases of BF 3 , PH 3 and AsH 3 . Therefore, the following presents a simplified summary of the invention in order to provide a basic understanding of some aspects of the invention. This summary is not an exhaustive overview of the invention. It is intended to identify key or critical elements of the invention or to delineate the scope of the invention. Its purpose is to present some concepts of the invention in a simplified form as a prelude to the more detailed description that is presented later. The present invention relates generally to an ion source for use in an ion implantation system, wherein the ion source comprises two or more plasma chambers such that a first plasma chamber is operable to generate an ion source for implantation into a second plasma chamber electrons so that the second plasma chamber can efficiently and effectively generate ions for implantation into the ion beam of the ion implantation system.
根据本发明的一个示例性方面,提供了一种离子源,所述离子源包括:第一等离子体腔(在下文被称为电子源等离子体腔)包括用于从第一源气体的电离产生等离子体的等离子体产生部件;和第二等离子体腔(在下文被称为离子源等离子体腔),来自电子源等离子体腔的电子被注入到第二等离子体腔中,从而从第二源气体产生等离子体。所述离子源可以包含高压引出系统,所述高电压引出系统包括被配置以通过在其中形成的引出孔从所述离子源等离子体腔引出离子的电极系统。According to an exemplary aspect of the present invention, there is provided an ion source comprising: a first plasma chamber (hereinafter referred to as an electron source plasma chamber) comprising a chamber for generating plasma from ionization of a first source gas; and a second plasma chamber (hereinafter referred to as an ion source plasma chamber) into which electrons from the electron source plasma chamber are injected, thereby generating plasma from a second source gas. The ion source may include a high voltage extraction system including an electrode system configured to extract ions from the ion source plasma chamber through an extraction aperture formed therein.
根据本发明的另一示例性方面,提供了一种用于产生离子的方法,所述方法包括:在第一等离子体腔中形成电子源等离子体;从所述第一等离子体产生腔中形成的等离子体中引出电子;以便将被引出的电子引导到第二等离子体腔中,由此被引出的电子在第二等离子体腔内产生等离子体;以及通过设置于所述第二等离子体腔中的引出孔引出离子。According to another exemplary aspect of the present invention, there is provided a method for generating ions, the method comprising: forming an electron source plasma in a first plasma chamber; extracting electrons in the plasma; so as to guide the extracted electrons into the second plasma chamber, whereby the extracted electrons generate plasma in the second plasma chamber; and passing through the extraction holes arranged in the second plasma chamber extract ions.
根据本发明的又一方面,提供了一种离子注入系统,其包括用于将离子注射到离子线束中用于注入到工件中的离子源,所述离子源包括:用于从第一源气体的电离中产生等离子体的第一等离子体腔(电子源等离子体腔);和第二等离子体腔(离子源等离子体腔),来自所述电子源等离子体腔的电子被注射到第二等离子腔中,用于从第二源气体产生等离子体。离子注入系统包括引出系统,所述引出系统包括被配置以通过在其中形成的引出孔从所述离子源等离子体腔引出离子的电极。According to yet another aspect of the present invention, there is provided an ion implantation system comprising an ion source for injecting ions into an ion beam for implantation into a workpiece, the ion source comprising: A first plasma chamber (electron source plasma chamber) that generates plasma in the ionization of A plasma is generated from a second source gas. The ion implantation system includes an extraction system including an electrode configured to extract ions from the ion source plasma chamber through an extraction aperture formed therein.
为了实现前述的目的和相关的目的,本发明包括下文中被全面地描述的且在权利要求中特别指出的特征。下述描述和附图详细阐述了本发明的特定说明性实施例。然而,这些实施例只是可以采用本发明的原理的多种方式中的少数几个的代表。结合附图考虑时,通过对本发明的下述详细描述,本发明的其它目的、优点以及新颖特征将会变得清楚。To the accomplishment of the foregoing and related ends, the invention comprises the features hereinafter fully described and particularly pointed out in the claims. The following description and drawings set forth in detail certain illustrative embodiments of the invention. These embodiments are representative, however, of a few of the many ways in which the principles of the invention may be employed. Other objects, advantages and novel features of the invention will become apparent from the following detailed description of the invention when considered in conjunction with the accompanying drawings.
附图说明Description of drawings
图1示出根据本发明的一个方面的示例性离子源的等距透视图;Figure 1 shows an isometric perspective view of an exemplary ion source according to one aspect of the present invention;
图2示出根据本发明的一个方面的示例性离子源的横截面透视图;Figure 2 shows a cross-sectional perspective view of an exemplary ion source according to an aspect of the present invention;
图3示出根据本发明的另一个示例性方面的用于从离子源产生和引出离子的示例性方法的方块图;和3 illustrates a block diagram of an exemplary method for generating and extracting ions from an ion source according to another exemplary aspect of the invention; and
图4是根据本发明的另一个方面的利用示例性离子源的示例性离子注入系统的示意图。4 is a schematic diagram of an exemplary ion implantation system utilizing an exemplary ion source according to another aspect of the invention.
具体实施方式Detailed ways
本发明通常涉及在离子注入中使用的改进的离子源设备。更具体地是,本发明的系统和方法提供了一种有效的方式,用以电离大分子电离气体来产生分子离子注入种类(诸如碳硼烷、癸硼烷、十八硼烷和二十硼烷(icosaboranes),以及用以电离标准电离气体来产生单体离子注入种类(诸如三氟化硼、磷化氢和砷化氢)。应当理解:离子注入种类的上述列表被提供仅为说明性目的,且不应当认为代表可用于产生离子注入种类的电离气体的完整列表。因此,现在将参照附图描述本发明,其中相似参考数字自始至终用于表示相似的元件。应当理解,这些方面的描述只是说明性的,且不应将被理解成具有任何限制意义。在以下描述中,为了说明目的,对许多特定细节进行阐述,用以提供对本发明的全面理解。然而,对于本领域的技术人员来说将明白在没有这些特定细节的情况下,也可以实施本发明。The present invention generally relates to improved ion source apparatus for use in ion implantation. More specifically, the systems and methods of the present invention provide an efficient way to ionize macromolecular ionized gases to produce molecular ion-implanted species such as carborane, decaborane, octadecaborane, and eicosaborane alkanes (icosaboranes), and ionized standard ionized gases used to ionize monomeric ion-implanted species (such as boron trifluoride, phosphine, and arsine). It should be understood that the above list of ion-implanted species is provided for illustration only purpose, and should not be considered to represent a complete list of ionized gases that can be used to produce ion implanted species. Accordingly, the present invention will now be described with reference to the accompanying drawings, wherein like reference numerals are used throughout to represent like elements. It should be understood that descriptions of these aspects It is only illustrative, and should not be interpreted as having any limiting meaning.In the following description, for the purpose of illustration, many specific details are set forth in order to provide a comprehensive understanding of the present invention.However, for those skilled in the art It will be understood, however, that the invention may be practiced without these specific details.
现在参照图1和图2,其显示了根据本发明的简化示例性的离子源100,其中离子源100适合实施本发明的一个或更多个方面。应当注意,在图1中描绘的离子源100被提供仅是为了说明性目的,且不是要包括离子源的所有方面、部件和特征。相反地,描绘示例性离子源100,从而便于对本发明的进一步理解。Referring now to FIGS. 1 and 2 , there is shown a simplified
例如,离子源100包括被设置靠近第二等离子体腔116的第一等离子体腔102。第一等离子体腔102包括气体源供给线106,并配置了用于从第一源气体产生等离子体的等离子体产生部件104。源气体由气体供给线106被引入到第一等离子体腔102中。源气体可以包括下述中的至少一种:例如氩气(Ar)和氙气(Xe)的惰性气体;例如三氟化硼(BF3)、砷化氢(AsH3)和磷化氢(PH3)的标准离子注入气体;以及例如氧气(O2)和三氟化氮(NF3)的活性气体。同样也应当理解,源气体的上述列表被提供仅是为说明性目的,且不应当被认为是表示可以被运送至第一等离子体腔的源气体的完整列表。For example,
等离子体产生部件104可以包括阴极108/阳极110的组合,其中阴极108可以包括简单的Bernas类型的丝配置,或者在图1和图2中所示类型的间接加热的阴极。可替代地,等离子体产生部件104可以包括RF(射频)感应线圈天线,其被支撑且具有直接安装在气体约束腔内的射频引导段,以将电离能量传送至气体电离区域,例如如在被共同受让给本发明的申请人的第5,661,308号美国专利中所公开的。The
第一或电子源等离子体腔102限定了孔112,该孔112形成进入离子注入系统的高真空区域中的通路,即压力比第一等离子体腔102中的源气体的压力低很多的区域。孔112提供抽吸孔,用于保持源气体纯度处于高水平,如在下文中将进一步讨论的。The first or electron
电子源等离子体腔102还限定了孔114,所述孔114形成用于从电子源等离子体腔102引出电子的引出孔。在优选的实施例中,如图2中所示,引出孔114被设置成可更换的阳极元件110的形式,其中形成了孔114。同理,本领域的技术人员将认识到,可以将电子源等离子体腔102配置成具有(相对于阴极108)被正向偏压的电极119,用于以所谓的非折回(non-reflex)模式吸引来自等离子体的电子。可替代地,电极119可以相对于阴极108进行负向偏压,用以使电子以所谓的折回(reflex)模式被排拆而返回到电子源等离子体腔102中。应当理解:这种折回模式配置将需要对等离子体腔壁进行适当的偏压,以及对电极119进行电性绝缘和独立偏压。The electron
如前所述,本发明的离子源100还包括第二或离子源腔116。第二离子源等离子体腔116包括用于将离子源气体引入到离子源等离子体腔116的第二气体源供给线118,且被进一步配置成容纳来自电子源等离子体腔102的电子,从而通过电子与第二源气体之间的碰撞在其中产生等离子体。第二源气体可以包括上文列出的用于电子源等离子体腔102的任何气体,或任何大分子气体(例如碳硼烷(C2B10H12)、癸硼烷(B10H14)和十八硼烷(B18H22)或二十硼烷)。同样应当理解:源气体的上述列表被提供仅是为了说明性目的,且不应当认为是表示可以被运送至第二等离子体腔116的源气体的完整列表。As previously mentioned, the
第二或离子源等离子体腔116限定了与第一等离子体腔102的引出孔114对准的孔117,从而在它们之间形成通路,用于允许被从第一等离子体腔102引出的电子流入到第二等离子体腔116中。优选地,离子源等离子体腔116被配置成具有正向偏压的电极119,用于以所谓的非折回模式吸引被注入到离子源等离子体腔116中的电子,以在电子与气体分子之间产生期望的碰撞,来产生电离等离子体。可替代地,电极119可以被负向偏压,以使得以所谓的折回(reflex)模式将电子排拆而返回到离子源等离子体腔116中。The second or ion
引出孔120被配置在第二等离子体腔116中,以引出离子用以形成离子束,以便用通常的方式进行注入。An
重要的是注意到,第二等离子体腔116优选地利用外部偏压电力供给装置115相对于第一等离子体腔102被正向偏压。因此电子被从电子源等离子体腔102引出,且被注入到离子源等离子体腔116中以产生等离子体;在第二等离子体腔116中在由第一等离子体腔102提供的电子与通过第二气体源供给线118被供给至第二等离子体腔116的供给气体之间引起碰撞。It is important to note that the
应当注意的是,第一等离子体腔102和第二等离子体腔116可以有三个开口的边界:进气口(例如,第一气体供应入口122和第二气体供应入口124)、到高真空区域的开口(例如,抽吸孔112和引出孔120)和公共边界孔114和117,其分别在第一和第二等离子体腔102和104之间形成公共通路。优选地,由于在下文中将讨论的原因,与进入高真空区域的孔112和120(即,第一等离子体腔孔112和第二等离子体腔孔120)相比,公共边界孔114和117的面积保持很小。It should be noted that the
在根据本发明的一个示例性离子源配置中,本发明的离子源包括由马塞诸萨州(MA)Beverly市的艾克塞利斯科技公司(AxcelisTechnologies,Inc)制造且销售的所述类型的标准IHC离子源的部件,其中离子源等离子体腔包括被配置有标准阳极的标准电弧腔、引出系统和源供给管。标准IHC源的被内部加热的阴极元件被去除且被安装其位置上的小电子源等离子体腔替代,该小电子源等离子体腔包含与由Axcelis Technologies制造并销售的所述类型的标准IHC离子源相似的部件,其包括电弧腔、标准内部加热的阴极元件和源供给管。In one exemplary ion source configuration according to the invention, ion sources of the invention include those of the type described and sold by Axcelis Technologies, Inc. of Beverly, MA. Components of a standard IHC ion source, wherein the ion source plasma chamber includes a standard arc chamber configured with a standard anode, an extraction system, and a source supply tube. The internally heated cathode element of the standard IHC source was removed and replaced in its place by a small electron source plasma chamber containing a standard IHC ion source of the type described and manufactured and sold by Axcelis Technologies. components including the arc chamber, standard internally heated cathode elements and source supply tubes.
两个等离子体腔还共有沿着引出孔定向的磁场,该磁场由标准Axcelis源磁体提供,被用参考标记130表示。众所周知,通过在等离子体产生腔中感应垂直磁场,电离过程(以及在这种情况下电子产生过程)变得更加有效。同理,在优选实施例中,电磁构件130被优选地沿着第一和第二等离子体腔102和116之间的共有边界的轴线,分别设置到第一和第二等离子体腔102和116的外部。所述电磁元件130感应出捕获电子的磁场,以提高电离过程的效率。The two plasma chambers also share a magnetic field oriented along the extraction aperture, provided by a standard Axcelis source magnet, indicated by
电子源腔102与离子源等离子体腔116还优选地通过在它们之间设置的绝缘构件126进行热绝缘,被耦合到离子源等离子体腔116的唯一的功率是小量的辐射功率,该小量的辐射功率通常在10W的量级上,通过由孔114、117所形成的公共边界孔由阴极108提供,与被注射到离子源等离子体腔166中的电子电流相关的放电功率,对于癸硼烷或十八硼烷放电来说通常是10W。被耦合到离子源等离子体腔116的低量功率便于保持壁温足够低,从而防止大分子气体的分解。电子源腔102通过绝缘构件126与离子源等离子体腔116电绝缘。The
在优选实施例中,离子源等离子体腔116被配置有引出孔120,该引出孔120的面积为约300mm2(5mm×60mm)。电子源腔102也被配置有总面积为300mm2的抽吸孔112。由两个等离子体腔共有的孔114和117所形成的公共边界孔优选地具有在30mm2(4×7.5mm)量级上的面积。在这种配置中,在用被耦合至电子源等离子体腔102的氩气体源和被耦合至离子源等离子体腔116的癸硼烷或十八硼烷气体源进行操作时,轻易地通过引出孔120获得大约5mA的引出离子束电流。在这些条件下,在电子源腔102中的氩气放电电流和电压(通常在0.2A@40v 的量级上)产生被注射到离子源等离子体腔116中的0.1A的电子电流(且偏压电力供给装置115上的电压设定为100V)。在相同的物理配置中,在离子源等离子体腔116中切换成磷化氢作为气体源时,将电子源等离子体放电参数增加到5A@60V使被注射到离子源等离子体中的电子电流在偏压供给装置上设定为120V时增加到3A,其中超过50mA的离子束电流被通过引出孔120引出。In a preferred embodiment, the ion
如前面所指出的,优选地,与由孔114和117所产生的公共边界孔相比,将电子源等离子体腔抽吸孔112和离子源等离子体腔抽吸孔120的面积选择成很大,这会导致在每个腔102和116中具有相对较高的气体纯度。参照上述示例,氩气通过30mm2的公共引出孔114流入离子源等离子体腔116并通过300mm2的引出孔120流出。结果,在离子源等离子体腔116中的氩气密度仅为电子源等离子体腔102中的氩气密度的10%。根据同样的推理,通过气体供给线118被供给离子源等离子体腔116的第二气体(其可以流入电子源等离子体腔102中)的密度仅为离子源等离子体腔116中的第二气体密度的10%。在典型应用中,电子源等离子体腔102中的氩气密度与离子源等离子体腔116中的第二气体密度大致相等,使得每个等离子体腔气体具有90%的纯度。As previously indicated, the area of the electron source plasma
由于前述离子源硬件配置,本发明的发明人认识到利用来自第一等离子体腔102的电子在第二等离子体腔116中形成分子离子种类(如癸硼烷(B10H14)或十八硼烷(B18H12)离子),例如可以避免与阴极相关的典型的离子源污染问题,同时这样的硬件的功耗属性可以实现(enable)典型地与分子种类电离相关的宽范围的电子电流电离应用以及典型地与单体种类电离相关的高电子电流电离应用。Due to the foregoing ion source hardware configuration, the inventors of the present invention realized that molecular ion species such as decaborane (B 10 H 14 ) or octadecaborane were formed in the
如图3中所示,根据本发明的方法200开始于步骤202,其通过气体供给线106将第一气体供给至处于真空条件下的第一等离子体腔102(参见图1),以及通过第二气体源供给线118将第二气体供给至也处于真空状态的第二等离子体腔116(参见图1)。例如,离子源100(图1)包括第一等离子体腔102,该第一等离子体腔102包含第一气体,且被配置有用于从第一气体产生等离子体的等离子体产生部件104(图1)。As shown in FIG. 3, the
在步骤204,等离子体产生部件104(参见图1)被通电,以在第一等离子体腔102(参见图1)中通过等离子体产生部件104和第一源气体(例如,氩气)的相互作用产生等离子体。例如,可以用放电电流为0.4毫安、放电电压为60伏的直流放电产生等离子体。在步骤206,电子被从在第一等离子体腔102(参见图1)中产生的等离子体中引出,且被通过分别由在第一和第二等离子体腔102和116中形成的孔114和117所形成的公共边界区域注射到第二等离子体腔116(参见图1)中,从而允许在它们之间具有流体连通(例如,包括电子、离子和等离子体的流体)。在步骤208,通过气体线118被供给的位于第二等离子体腔116中的第二气体被从第一等离子体腔102(参见图1)中引出的电子撞击,从而在第二等离子体腔116(参见图1)中形成第二等离子体。最后,在步骤210离子被通过引出孔120(图1)从第二等离子体腔116(参见图1)的等离子体中引出。At
因此,本发明对“双等离子体离子源”进行了描述。应该理解,所描述的这样的双等离子体离子源为了使用可以被合并到如图4的示例性离子注入系统300中所示出的离子注入系统中。离子注入设备300(也被称为离子注入机)被可操作地耦合到控制器302,所述控制器302用于控制在离子注入设备300上所实施的各种操作和过程。根据本发明,离子注入设备300包括上文所述的用于产生一定量的离子的双等离子体离子源组件306,所述一定量的离子用于产生沿离子束路径P行进的离子束308,来将离子注入到被保持在工件支撑平台312上的工件310(例如,半导体工件、显示面板等)中。所述离子可以由例如氩气(Ar)和氙气(Xe)的惰性气体;例如三氟化硼(BF3)、砷化氢(AsH3)和磷化氢(PH3)的标准离子注入气体;例如氧气(O2)和三氟化氮(NF3)的活性气体;以及例如癸硼烷(B10H14)和十八硼烷(B18H22)的大分子气体形成。Accordingly, the present invention describes a "dual plasma ion source". It should be understood that such a dual plasma ion source as described may be incorporated into an ion implantation system as shown in the exemplary ion implantation system 300 of FIG. 4 for use. Ion implantation apparatus 300 (also referred to as an ion implanter) is operatively coupled to a
离子源组件306包括第一等离子体腔314(例如,等离子体腔或电弧腔)和第二等离子体腔316,其中第一等离子体腔314被配置有等离子体产生部件318,该等离子体产生部件318可以包括阴极108(参见图2)和阳极110(参见图2),用于由通过第一气体供给装置301的第一气体供给线322被引入到第一等离子体腔314中的第一气体,来产生等离子体。例如,等离子体产生部件318可以在可替代的选择中包括射频(RF)感应线圈。第一气体可以包括下述中的至少一种:例如氩气(Ar)和氙气(Xe)的惰性气体;例如三氟化硼(BF3)、砷化氢(AsH3)和磷化氢(PH3)的标准离子注入气体;和例如氧气(O2)和三氟化氮(NF3)的活性气体。The
第二等离子体腔316被设置成通过在第一和第二等离子体腔314和316之间形成的公共边界孔326而与第一等离子体腔314流体连通,其中第二等离子体腔316包含从第二气体供给装置320通过第二气体供给线328所引入的第二气体。第二气体可以包括下述中的至少一种:例如氩气(Ar)和氙气(Xe)的惰性气体;例如三氟化硼(BF3)、砷化氢(AsH3)和磷化氢(PH3)的标准离子注入气体;例如氧气(O2)和三氟化氮(NF3)的活性气体;以及例如癸硼烷(B10H14)和十八硼烷(B18H22)的大分子气体。The
第二等离子体腔316优选地通过偏压电力供给装置332相对于第一等离子体腔314被正向偏压,使能够从第一等离子体腔314引出电子用于注射到第二等离子体腔316中。当被引出的电子与第二等离子体腔316中的第二气体碰撞时,它们在第二等离子体腔316中产生等离子体。引出孔334被设置在第二等离子体腔316中,以从在第二等离子体腔316中所形成的等离子体引出离子。The
离子注入系统300还包括与源组件306相关的引出电极组件331,其中引出电极组件331被偏压,以吸引来自源组件306的带电离子用于通过引出孔引出。线束组件336也被设置在离子源组件306的下游,其中线束组件336通常接收来自所述源306的带电离子。例如,线束组件336包括束引导装置(beam guide)342、质量分析装置338和分辨孔340,其中线束组件336是可操作的,以沿着离子束路径P运送离子,用于注入工件310中。The ion implantation system 300 also includes an
例如,质量分析装置338还包括场产生部件(例如未显示的磁体),其中质量分析装置338通常提供跨过离子束308的磁场,从而根据与从源306引出的离子相关的荷质比以变化的轨迹偏转来自离子束308的离子。例如,行进通过磁场的离子经受一种力,所述力沿着束路径P引导具有期望的荷质比的单个离子且偏转具有不期望的荷质比的离子远离束路径P。如果通过质量分析装置338,那么离子束308被引导通过分辨孔340,其中离子束308可以被加速、减速、聚焦或以其他方式进行修改,用于注入到设置于终端工作站344内的工件310中。For example,
虽然已经关于特定的优选实施例对本发明进行了描述,但是显然在本领域技术人员阅读和理解了本发明的说明书和附图之后,将可能和会想到等同的替代和修改。尤其是,关于由上述部件(组件、装置、电路等)执行的各种功能,除非被另外指示,用于描述这些部件的术语(包括对“装置”的提及)是要对应于执行所描述的部件的特定功能的任何部件(即,功能等同),即使结构上不等同于执行本发明的在此处示出的示例性实施例中的功能的被公开的结构。此外,虽然仅对于几个实施例中的一个公开了本发明的特定特征,但是如对于任何特定的应用可能是期望的和有利的,这样的特征可以与其它实施例的一个或更多的其它特征结合。While the invention has been described with respect to certain preferred embodiments, it is obvious that equivalent substitutions and modifications will occur and occur to those skilled in the art after reading and understanding the specification and drawings of the invention. In particular, with respect to the various functions performed by the components (components, means, circuits, etc.) described above, unless otherwise indicated, terms used to describe these components (including references to "means") are to correspond to Any component that performs the specified function of the component (ie, functionally equivalent), even if not structurally equivalent to the disclosed structure that performs the function in the exemplary embodiments of the invention shown herein. Furthermore, while specific features of the invention have been disclosed with respect to only one of several embodiments, such features may be combined with one or more other embodiments of other embodiments, as may be desirable and advantageous for any particular application. feature combination.
Claims (25)
Applications Claiming Priority (3)
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| US98157607P | 2007-10-22 | 2007-10-22 | |
| US60/981,576 | 2007-10-22 | ||
| PCT/US2008/012008 WO2009054966A1 (en) | 2007-10-22 | 2008-10-22 | Double plasma ion source |
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| CN101903970A true CN101903970A (en) | 2010-12-01 |
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| EP (1) | EP2203928A1 (en) |
| JP (1) | JP5524070B2 (en) |
| KR (1) | KR101562785B1 (en) |
| CN (1) | CN101903970A (en) |
| WO (1) | WO2009054966A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109300758A (en) * | 2018-09-27 | 2019-02-01 | 德淮半导体有限公司 | Ion Implantation Equipment and ion source generating device |
| CN112313774A (en) * | 2018-04-20 | 2021-02-02 | 珀金埃尔默健康科学加拿大股份有限公司 | Mass analyzers including ion sources and reaction cells and systems and methods for using the same |
| CN115305436A (en) * | 2022-08-05 | 2022-11-08 | 清华大学 | Ion diffusion equipment with double plasma excitation sources and design method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US9627180B2 (en) * | 2009-10-01 | 2017-04-18 | Praxair Technology, Inc. | Method for ion source component cleaning |
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| JPS61290629A (en) * | 1985-06-18 | 1986-12-20 | Rikagaku Kenkyusho | Electron beam excited ion source |
| KR900003310B1 (en) * | 1986-05-27 | 1990-05-14 | 리가가구 겡큐소 | Ion generator |
| US4841197A (en) * | 1986-05-28 | 1989-06-20 | Nihon Shinku Gijutsu Kabushiki Kaisha | Double-chamber ion source |
| JPH088072B2 (en) * | 1986-07-03 | 1996-01-29 | 日本真空技術株式会社 | Ion source |
| JPH0752635B2 (en) * | 1988-10-18 | 1995-06-05 | 日新電機株式会社 | Ion source device |
| US5252892A (en) * | 1989-02-16 | 1993-10-12 | Tokyo Electron Limited | Plasma processing apparatus |
| JP2819420B2 (en) | 1989-11-20 | 1998-10-30 | 東京エレクトロン株式会社 | Ion source |
| JPH06176724A (en) * | 1992-01-23 | 1994-06-24 | Tokyo Electron Ltd | Ion source device |
| KR0158234B1 (en) * | 1992-03-02 | 1999-02-18 | 이노우에 아키라 | Ion implantation system |
| US5661308A (en) * | 1996-05-30 | 1997-08-26 | Eaton Corporation | Method and apparatus for ion formation in an ion implanter |
-
2008
- 2008-10-22 CN CN2008801219714A patent/CN101903970A/en active Pending
- 2008-10-22 WO PCT/US2008/012008 patent/WO2009054966A1/en not_active Ceased
- 2008-10-22 KR KR1020107011288A patent/KR101562785B1/en not_active Expired - Fee Related
- 2008-10-22 JP JP2010531026A patent/JP5524070B2/en active Active
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112313774A (en) * | 2018-04-20 | 2021-02-02 | 珀金埃尔默健康科学加拿大股份有限公司 | Mass analyzers including ion sources and reaction cells and systems and methods for using the same |
| CN112313774B (en) * | 2018-04-20 | 2022-04-08 | 珀金埃尔默健康科学加拿大股份有限公司 | Mass analyzers including ion sources and reaction cells and systems and methods for using them |
| CN109300758A (en) * | 2018-09-27 | 2019-02-01 | 德淮半导体有限公司 | Ion Implantation Equipment and ion source generating device |
| CN115305436A (en) * | 2022-08-05 | 2022-11-08 | 清华大学 | Ion diffusion equipment with double plasma excitation sources and design method thereof |
| CN115305436B (en) * | 2022-08-05 | 2024-01-16 | 清华大学 | Ion diffusion equipment with double plasma excitation sources and design method thereof |
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| Publication number | Publication date |
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| EP2203928A1 (en) | 2010-07-07 |
| JP5524070B2 (en) | 2014-06-18 |
| KR20100100823A (en) | 2010-09-15 |
| WO2009054966A1 (en) | 2009-04-30 |
| KR101562785B1 (en) | 2015-10-23 |
| JP2011501382A (en) | 2011-01-06 |
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