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CN101906356A - A kind of washing liquid and preparation method thereof - Google Patents

A kind of washing liquid and preparation method thereof Download PDF

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CN101906356A
CN101906356A CN 201010251760 CN201010251760A CN101906356A CN 101906356 A CN101906356 A CN 101906356A CN 201010251760 CN201010251760 CN 201010251760 CN 201010251760 A CN201010251760 A CN 201010251760A CN 101906356 A CN101906356 A CN 101906356A
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mass percentage
laundry detergent
accurately measured
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laundry
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CN101906356B (en
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赵建洲
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JIANGSU AITEFU 84 CO Ltd
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JIANGSU AITEFU 84 CO Ltd
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Abstract

The invention discloses laundry liquid and a preparation method thereof. Mild surfactants with mild washing property, high decontamination capacity, no pollution on the environment, such as fatty alcohol-polyoxyethylene ether (AEO9), dodecyl dimethylaminoacetate (BS-12), dodecyl dimethyl benzyl ammonium chloride (1227), distearyl dimethyl ammonium chloride (D1821), polyethylene glycol 6000DS diester, coconut oil diethanolamine (6501) and the like are prepared into the laundry liquid according to a certain proportion and a process; clothes washed by the laundry liquid have soft textile fibers and comfortable wear; and the laundry liquid is mainly used for washing personal clothes, sheets and bedding bags of households, sheets and bedding bags of hotels and the like.

Description

一种洗衣液及制备方法 A kind of washing liquid and preparation method thereof

技术领域technical field

本发明涉及一种洗衣液及制备方法,主要用于家庭个人衣物、床单、被套和宾馆、酒店床单、被套等织物的清洁洗涤。The invention relates to a laundry detergent and a preparation method thereof, which are mainly used for cleaning and washing of family personal clothes, bed sheets, quilt covers, hotels, hotel bed sheets, quilt covers and other fabrics.

背景技术Background technique

肥皂、洗衣粉作为传统的织物洗涤清洁用品已使用数十年,在人们的日常生活中可谓举足轻重,历史价值无可非议,但肥皂在洗涤过程中需要搓擦、机洗则无发使用,洗衣粉在洗涤过种中需要先用水浸泡溶解,给人们洗涤过程带来了额外的麻烦,同时一些传统的肥皂、洗衣粉中均为块状和粉状固体,其成型过程中需要添加大量的固体填充剂,这些填充剂大多则是起一个成型作用,其对洗涤效果本身毫无意义,增加了成本还大量浪费了物质资源,且大多填充剂均为含磷的矿物质对人类赖依生存的环境造成不良影响,与现代人们追求的节约型和环境友好型社会已不合节拍。Soap and washing powder have been used as traditional fabric washing and cleaning products for decades. They play an important role in people's daily life and their historical value is beyond reproach. The washed seeds need to be soaked and dissolved in water first, which brings additional troubles to the washing process. At the same time, some traditional soaps and washing powders are all lumpy and powdery solids, and a large amount of solid fillers need to be added during the molding process. , most of these fillers play a molding role, which is meaningless to the washing effect itself, increases the cost and wastes a lot of material resources, and most of the fillers are phosphorus-containing minerals, which cause harm to the environment that human beings depend on for survival. Adverse effects are out of rhythm with the energy-saving and environment-friendly society pursued by modern people.

发明内容Contents of the invention

本发明的目的是:提供一种洗衣液及制备方法,避开上述传统肥皂、洗衣粉存在的缺点,以追求节约、环保、高效为出发点,对衣物洗涤去污能力强,洗涤后织物纤维柔软,手感好,穿着舒适。The purpose of the present invention is: to provide a kind of laundry liquid and preparation method, avoid the shortcoming that above-mentioned traditional soap, washing powder exist, take the pursuit of saving, environmental protection, high efficiency as the starting point, strong decontamination ability to clothes washing, the fabric fiber after washing is soft , feel good, comfortable to wear.

本发明的技术解决方案是:该洗衣液中各个组分的质量百分比含量为:The technical solution of the present invention is: the mass percent content of each component in this washing liquid is:

AEO9                                1.0%~18.0%AEO 9 1.0%~18.0%

BS-12                               0.5%~10.0%BS-12 0.5%~10.0%

1227                                0.5%~10.0%1227 0.5%~10.0%

D182                                10.4%~6.0%D182 10.4%~6.0%

聚乙二醇6000DS双脂                  1.0%~10.0%Polyethylene glycol 6000DS double fat 1.0%~10.0%

6501                                0.2%~6.0%6501 0.2%~6.0%

乙二醇二硬脂酸酯(EGDS)              0.5%~5.0%Ethylene glycol distearate (EGDS) 0.5%~5.0%

柠檬酸                              0.01%~1.0%Citric acid 0.01%~1.0%

香精                                0.02%~1.0%Fragrance 0.02%~1.0%

去离子水                            33.0%~95.87%。Deionized water 33.0% to 95.87%.

如上所述一种洗衣液,其中组分AEO9为织物净洗剂的活性组分,其主要洗净作用,其所占的质量百分比是1.0%~18.0%,优选是5.0%~10.0%。A laundry liquid as described above, wherein component AEO 9 is an active component of fabric detergent, and its main cleaning effect is 1.0%-18.0% by mass, preferably 5.0%-10.0%.

如上所述一种洗衣液,其中组分BS-12,为两性表面活性剂,配伍性良好,对皮肤刺激性低,生物降解性好,具有优良的去污杀菌、柔软性、抗静电性、耐硬水性和防锈性等优点,其所占的质量百分比是0.5%~10.0%,优选是2.0%~8.0%。A laundry detergent as mentioned above, wherein the component BS-12 is an amphoteric surfactant, has good compatibility, low skin irritation, good biodegradability, excellent decontamination and sterilization, softness, antistatic properties, It has the advantages of hard water resistance and rust resistance, and its mass percentage is 0.5% to 10.0%, preferably 2.0% to 8.0%.

如上所述一种洗衣液,其中组分1227为一种阳离子表面活性剂,属非氧化性杀菌剂,具有广谱、高效的杀菌灭藻能力,能有效地控制水中菌藻繁殖和粘泥生长,并具有良好的粘泥剥离作用和一定的分散、渗透作用,同时具有一定的去油、除臭能力和缓蚀、柔软、抗静电、乳化、调理作用,其所占的质量百分比是0.5%~10.0%,优选是1.5%~6.0%。A laundry detergent as mentioned above, wherein component 1227 is a cationic surfactant, which is a non-oxidizing bactericide, has broad-spectrum, high-efficiency sterilization and algae killing ability, and can effectively control the growth of bacteria and algae and slime in water , and has a good slime stripping effect and a certain dispersion and penetration effect, and has a certain degreasing, deodorizing ability, corrosion inhibition, softness, antistatic, emulsification, conditioning effect, and its mass percentage is 0.5%~ 10.0%, preferably 1.5% to 6.0%.

如上所述一种洗衣液,其中组分D1821是一种织物柔软剂,与阳离子、非离子、两性离子表面活性剂或染料有良好的配伍性,有较好的乳化分散性、抗静电性和防腐蚀性能。其所占的质量百分比是0.4%~6.0%,优选是1.0%~3.0%。A laundry detergent as mentioned above, wherein component D1821 is a fabric softener, which has good compatibility with cationic, nonionic, zwitterionic surfactants or dyes, and has good emulsifying dispersibility, antistatic properties and Anti-corrosion properties. Its mass percentage is 0.4%-6.0%, preferably 1.0%-3.0%.

如上所述一种洗衣液,其中组分聚乙二醇6000DS双脂是一种优良的增稠剂,具有增稠、增溶、乳化功能,其所占的质量百分比是1.0%~10.0%,优选是3.0%~7.0%。A laundry detergent as mentioned above, wherein the component polyethylene glycol 6000DS double fat is an excellent thickener, which has thickening, solubilizing and emulsifying functions, and its mass percentage is 1.0% to 10.0%, Preferably it is 3.0% to 7.0%.

如上所述一种洗衣液,其中组分6501为非离子表面活性剂,具有良好的发泡、稳泡、渗透去污、抗硬水、增稠等功能,其所占的质量百分比是0.2%~6.0%,优选是1.5%~4.0%。A laundry detergent as described above, wherein component 6501 is a nonionic surfactant, which has good functions of foaming, foam stabilization, penetration and decontamination, anti-hard water, thickening, etc., and its mass percentage is 0.2%~ 6.0%, preferably 1.5% to 4.0%.

如上所述一种洗衣液,其中组分乙二醇二硬脂酸酯为珠光剂,在洗衣液中可产生明显的珠光,使洗衣液的感观更宜被人接受,同时对洗液液具有增稠和调理功能,其所占的质量百分比为0.5%~5.0%,优选是0.8%~3.5%。A kind of laundry detergent as mentioned above, wherein component ethylene glycol distearate is pearlescent agent, can produce obvious pearlescent in laundry detergent, makes the sensory effect of laundry detergent more suitable to be accepted by the people, simultaneously to lotion liquid It has thickening and conditioning functions, and its mass percentage is 0.5%-5.0%, preferably 0.8%-3.5%.

如上所述一种洗衣液,其中组分柠檬酸主要起调节洗衣液PH值作用,其所占的质量百分比为0.01%~1.0%,优选是0.03%~0.07%。The aforementioned laundry detergent, wherein the component citric acid mainly plays a role in adjusting the pH value of the laundry detergent, and its mass percentage is 0.01%-1.0%, preferably 0.03%-0.07%.

如上所述一种洗衣液,其中组分香精为辅助成分,主要是用来改善洗液气味,使织物洗涤消后气味芳香,感觉更宜人,其所占的质量百分比是0.02%~1.0%,优选是0.05%~0.7%。A laundry detergent as mentioned above, wherein the component essence is an auxiliary component, which is mainly used to improve the smell of the lotion, so that the smell of the fabric after washing is fragrant, and the feeling is more pleasant, and its mass percentage is 0.02% to 1.0%. Preferably it is 0.05% to 0.7%.

该洗衣液的制备方法包括以下步骤:(1)、将准确计量的去离子水加入反应釜,缓慢加入准确计量的聚乙二醇6000DS双脂并升温至65℃,搅拌至完全溶解;(2)、缓慢加入准确计量的AEO9搅拌至完全溶解;(3)、边搅拌边加入准确计量的BS-12,观察反应釜内至完全形成清澈透明均一的溶液;(4)、依次加入准确计量的1227、D1821,搅拌溶解;(5)、边搅拌边加入准确计量的6501,充分搅拌20分钟,回流25分钟;(6)、搅拌冷却至40℃加入准确计量的乙二醇二硬脂酸酯、香精,继续搅拌并回流20分钟;(7)、边搅拌边加入准确计量的柠檬酸;(8)、静置消泡,检验各项指标合格后按包装要求分装。The preparation method of the laundry detergent comprises the following steps: (1), adding accurately measured deionized water into the reactor, slowly adding accurately measured polyethylene glycol 6000DS double grease and heating up to 65°C, stirring until completely dissolved; (2) ), slowly add accurately measured AEO 9 and stir until completely dissolved; (3), add accurately measured BS-12 while stirring, and observe the inside of the reactor until a clear, transparent and uniform solution is completely formed; (4), sequentially add accurately measured (5) Add accurately measured 6501 while stirring, fully stir for 20 minutes, reflux for 25 minutes; (6), stir and cool to 40°C and add accurately measured ethylene glycol distearic acid Esters, flavors, continue to stir and reflux for 20 minutes; (7), add accurately measured citric acid while stirring; (8), stand for defoaming, and subpackage according to packaging requirements after checking all indicators are qualified.

具体实施方式Detailed ways

下面结合具体实施例进一步说明本发明的技术解决方案,这些实施例不能理解为是对技术解决方案的限制。The technical solutions of the present invention will be further described below in conjunction with specific embodiments, and these embodiments should not be construed as limitations on the technical solutions.

实施例1:Example 1:

依以下质量百分比取各组分:AEO9 1.0%,BS-12 0.5%,1227 0.5%,D1821 0.4%,聚乙二醇6000DS双脂1.0%,6501 0.2%,乙二醇二硬脂酸酯(EGDS)0.5%,柠檬酸0.01%,香精0.02%,去离子水95.87%。The components are taken according to the following mass percentages: AEO 9 1.0%, BS-12 0.5%, 1227 0.5%, D1821 0.4%, polyethylene glycol 6000DS double fat 1.0%, 6501 0.2%, ethylene glycol distearate (EGDS) 0.5%, citric acid 0.01%, essence 0.02%, deionized water 95.87%.

依以下步骤制备该洗衣液:(1)、将准确计量的去离子水加入反应釜,缓慢加入准确计量的聚乙二醇6000DS双脂并升温至65℃,搅拌至完全溶解;(2)、缓慢加入准确计量的AEO9搅拌至完全溶解;(3)、边搅拌边加入准确计量的BS-12,观察反应釜内至完全形成清澈透明均一的溶液;(4)、依次加入准确计量的1227、D1821,搅拌溶解;(5)、边搅拌边加入准确计量的6501,充分搅拌20分钟,回流25分钟;(6)、搅拌冷却至40℃加入准确计量的乙二醇二硬脂酸酯、香精,继续搅拌并回流20分钟;(7)、边搅拌边加入准确计量的柠檬酸;(8)、静置消泡,检验各项指标合格后按包装要求分装。Prepare the laundry detergent according to the following steps: (1), add accurately measured deionized water into the reactor, slowly add accurately measured polyethylene glycol 6000DS double grease and heat up to 65°C, and stir until completely dissolved; (2), Slowly add accurately measured AEO 9 and stir until completely dissolved; (3), add accurately measured BS-12 while stirring, and observe the reaction kettle until a clear, transparent and uniform solution is completely formed; (4), sequentially add accurately measured 1227 , D1821, stir to dissolve; (5), add accurately measured 6501 while stirring, fully stir for 20 minutes, and reflux for 25 minutes; (6), stir and cool to 40°C and add accurately measured ethylene glycol distearate, Essence, continue to stir and reflux for 20 minutes; (7), add accurately measured citric acid while stirring; (8), let it stand for defoaming, and pack according to the packaging requirements after the inspection of all indicators is qualified.

实施例2:Example 2:

该洗衣液的制备方法同实施例1,其中各组分的质量百分比如下:AEO9 5.0%,BS-12 2.0%,1227 1.5%,D18211.0%,聚乙二醇6000DS双脂3.0%,6501 1.5%,乙二醇二硬脂酸酯(EGDS)0.8%,柠檬酸0.03%,香精0.05%,去离子水85.12%。The preparation method of this laundry detergent is the same as in Example 1, wherein the mass percent of each component is as follows: AEO 9 5.0%, BS-12 2.0%, 1227 1.5%, D182 11.0%, polyethylene glycol 6000DS double fat 3.0%, 6501 1.5%, ethylene glycol distearate (EGDS) 0.8%, citric acid 0.03%, essence 0.05%, deionized water 85.12%.

实施例3:Example 3:

该洗衣液的制备方法同实施例1,其中各组分的质量百分比如下:AEO9 7.5%,BS-12 5.0%,1227 3.75%,D18212.0%,聚乙二醇6000DS双脂5.0%,6501 2.75%,乙二醇二硬脂酸酯(EGDS)2.15%,柠檬酸0.05%,香精0.375%,去离子水71.425%。The preparation method of this laundry detergent is the same as in Example 1, wherein the mass percent of each component is as follows: AEO 9 7.5%, BS-12 5.0%, 1227 3.75%, D182 12.0%, polyethylene glycol 6000DS double fat 5.0%, 6501 2.75%, ethylene glycol distearate (EGDS) 2.15%, citric acid 0.05%, essence 0.375%, deionized water 71.425%.

实施例4:Example 4:

该洗衣液的制备方法同实施例1,其中各组分的质量百分比如下:AEO9 10.0%,BS-12 8.0%,1227 6.0%,D1821 3.0%,聚乙二醇6000DS双脂7.0%,6501 4.0%,乙二醇二硬脂酸酯(EGDS)3.5%,柠檬酸0.07%,香精0.7%,去离子水57.73%。The preparation method of this laundry detergent is the same as in Example 1, wherein the mass percent of each component is as follows: AEO 9 10.0%, BS-12 8.0%, 1227 6.0%, D1821 3.0%, polyethylene glycol 6000DS double fat 7.0%, 6501 4.0%, ethylene glycol distearate (EGDS) 3.5%, citric acid 0.07%, essence 0.7%, deionized water 57.73%.

实施例5:Example 5:

该洗衣液的制备方法同实施例1,其中各组分的质量百分比如下:AEO9 9.5%,BS-12 5.25%,1227 5.25%,D1821 3.4%,聚乙二醇6000DS双脂5.5%,6501 3.1%,乙二醇二硬脂酸酯(EGDS)2.75%,柠檬酸0.505%,香精0.51%,去离子水64.235%。The preparation method of this laundry detergent is the same as in Example 1, wherein the mass percent of each component is as follows: AEO 9 9.5%, BS-12 5.25%, 1227 5.25%, D1821 3.4%, polyethylene glycol 6000DS double fat 5.5%, 6501 3.1%, ethylene glycol distearate (EGDS) 2.75%, citric acid 0.505%, essence 0.51%, deionized water 64.235%.

实施例6:Embodiment 6:

该洗衣液的制备方法同实施例1,其中各组分的质量百分比如下:AEO9 18.0%,BS-12 10.0%,1227 10.0%,D1821 6.0%,聚乙二醇6000DS双脂10.0%,6501 6.0%,乙二醇二硬脂酸酯(EGDS)5.0%,柠檬酸1.0%,香精1.0%,去离子水33.0%。The preparation method of this laundry detergent is the same as in Example 1, wherein the mass percent of each component is as follows: AEO 9 18.0%, BS-12 10.0%, 1227 10.0%, D1821 6.0%, polyethylene glycol 6000DS double fat 10.0%, 6501 6.0%, ethylene glycol distearate (EGDS) 5.0%, citric acid 1.0%, essence 1.0%, deionized water 33.0%.

Claims (10)

1.一种洗衣液,其特征是:该洗衣液包括脂肪醇聚氧乙烯醚(AEO9)、十二烷基二甲基胺乙内酯(BS-12)、十二烷基二甲基苄基氯化铵(1227)、双十八烷基二甲基氯化铵(D1821)、聚乙二醇6000DS双脂和椰子油二乙醇胺(6501),其中各组分质量百分比如下:1. a laundry liquid, it is characterized in that: this laundry liquid comprises fatty alcohol polyoxyethylene ether (AEO 9 ), lauryl dimethyl betaine (BS-12), lauryl dimethyl betaine Benzyl ammonium chloride (1227), dioctadecyl dimethyl ammonium chloride (D1821), polyethylene glycol 6000DS double fat and coconut oil diethanolamine (6501), wherein the mass percentage of each component is as follows: AEO9                                1.0%~18.0%AEO 9 1.0%~18.0% BS-12                               0.5%~10.0%BS-12 0.5%~10.0% 1227                                0.5%~10.0%1227 0.5%~10.0% D1821                               0.4%~6.0%D1821 0.4%~6.0% 聚乙二醇6000DS双脂                  1.0%~10.0%Polyethylene glycol 6000DS double fat 1.0%~10.0% 6501                                0.2%~6.0%6501 0.2%~6.0% 乙二醇二硬脂酸酯(EGDS)              0.5%~5.0%Ethylene glycol distearate (EGDS) 0.5%~5.0% 柠檬酸                              0.01%~1.0%Citric acid 0.01%~1.0% 香精                                0.02%~1.0%Fragrance 0.02%~1.0% 去离子水                            33.0%~95.87%。Deionized water 33.0% to 95.87%. 2.根据权利要求1所述的一种洗衣液,其特征是:其中AEO9的质量百分比是5.0%~10.0%。2. A laundry detergent according to claim 1, wherein the mass percentage of AEO 9 is 5.0%-10.0%. 3.根据权利要求1所述的一种洗衣液,其特征是:其中BS-12的质量百分比是2.0%~8.0%。3. A laundry detergent according to claim 1, characterized in that: wherein the mass percentage of BS-12 is 2.0% to 8.0%. 4.根据权利要求1所述的一种洗衣液,其特征是:其中1227的质量百分比是1.5%~6.0%。4. A laundry detergent according to claim 1, wherein the mass percentage of 1227 is 1.5%-6.0%. 5.根据权利要求1所述的一种洗衣液,其特征是:其中D1821的质量百分比是1.0%~3.0%。5. A laundry liquid according to claim 1, wherein the mass percentage of D1821 is 1.0%-3.0%. 6.根据权利要求1所述的一种洗衣液,其特征是:其中聚乙二醇6000DS双脂的质量百分比是3.0%~7.0%。6. A laundry detergent according to claim 1, characterized in that: wherein the mass percentage of polyethylene glycol 6000DS double fat is 3.0% to 7.0%. 7.根据权利要求1所述的一种洗衣液,其特征是:其中6501的质量百分比是1.5%~4.0%。7. A laundry detergent according to claim 1, wherein the mass percentage of 6501 is 1.5%-4.0%. 8.根据权利要求1所述的一种洗衣液,其特征是:其中乙二醇二硬脂酸酯(EGDS)的质量百分比是0.8%~3.5%。8. A laundry detergent according to claim 1, wherein the mass percentage of ethylene glycol distearate (EGDS) is 0.8% to 3.5%. 9.根据权利要求1所述的一种洗衣液,其特征是:其中柠檬酸的质量百分比是0.03%~0.07%,香精的质量百分比是0.05%~0.7%。9. A laundry liquid according to claim 1, wherein the mass percentage of citric acid is 0.03%-0.07%, and the mass percentage of essence is 0.05%-0.7%. 10.根据权利要求1所述的一种洗衣液的制备方法,其特征是该制备方法包括以下步骤:(1)、将准确计量的去离子水加入反应釜,缓慢加入准确计量的聚乙二醇6000DS双脂并升温至65℃,搅拌至完全溶解;(2)、缓慢加入准确计量的AEO9搅拌至完全溶解;(3)、边搅拌边加入准确计量的BS-12,观察反应釜内至完全形成清澈透明均一的溶液;(4)、依次加入准确计量的1227、D1821,搅拌溶解;(5)、边搅拌边加入准确计量的6501,充分搅拌20分钟,回流25分钟;(6)、搅拌冷却至40℃加入准确计量的乙二醇二硬脂酸酯、香精,继续搅拌并回流20分钟;(7)、边搅拌边加入准确计量的柠檬酸;(8)、静置消泡,检验各项指标合格后按包装要求分装。10. The preparation method of a kind of laundry detergent according to claim 1, characterized in that the preparation method comprises the following steps: (1), accurately metered deionized water is added to the reactor, slowly adding accurately metered polyethylene glycol Alcohol 6000DS double fat and heat up to 65°C, stir until completely dissolved; (2), slowly add accurately measured AEO 9 and stir until completely dissolved; (3), add accurately measured BS-12 while stirring, observe the inside of the reaction kettle Until a clear, transparent and uniform solution is completely formed; (4), add accurately measured 1227 and D1821 in sequence, and stir to dissolve; (5), add accurately measured 6501 while stirring, fully stir for 20 minutes, and reflux for 25 minutes; (6) . Stir and cool to 40°C, add accurately measured ethylene glycol distearate and essence, continue to stir and reflux for 20 minutes; (7), add accurately measured citric acid while stirring; (8), stand for defoaming , after the inspection of each index is qualified, it will be repacked according to the packaging requirements.
CN2010102517601A 2010-08-12 2010-08-12 Laundry liquid and preparation method thereof Withdrawn - After Issue CN101906356B (en)

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CN105671947A (en) * 2016-01-25 2016-06-15 苏州印丝特纺织数码科技有限公司 Antistatic fabric softener
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CN106118906A (en) * 2016-06-23 2016-11-16 李建 A kind of high-efficiency bactericidal liquid detergent
CN106118904A (en) * 2016-06-23 2016-11-16 李建 There is the liquid detergent of antibacterial effect
CN106901138A (en) * 2017-01-22 2017-06-30 舟山金星水产有限公司 Hairtail technology for removing offensive smell
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CN102352284A (en) * 2011-08-16 2012-02-15 太仓市新鹿染整有限公司 Fabric softening conditioner
CN103740477A (en) * 2013-12-23 2014-04-23 吴江亿泰真空设备科技有限公司 All-effect washing agent
CN104017668A (en) * 2014-06-05 2014-09-03 广州立白企业集团有限公司 Emulsus dish washing detergent
CN104745325A (en) * 2015-04-08 2015-07-01 湖州市石淙万红丝织厂 Novel stain remover for surface of textile fabric and preparation method of stain remover
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CN113481067A (en) * 2021-06-02 2021-10-08 兰州石化职业技术学院 Laundry detergent with anti-bacterial function and preparation method thereof

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