CN101816363A - A Formula Effectively Improving the Quality of Cocoa Butter Replacement Chocolate - Google Patents
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Abstract
本发明提供了一种改善月桂酸类代可可脂(CBS)巧克力品质的配方,以该巧克力的总重量为基准,包括:油脂30%~45%,可可粉10~15%,白砂糖15%~30%,蔗糖替代品5%~25%,脱脂奶粉10%~20%,乳化剂0.3%~0.5%。本发明还提供了利用所述配方制备巧克力的方法。本发明的巧克力可有效改善传统巧克力的易起霜问题,赋予巧克力持久的光滑表面,并含有丰富的益生因子而兼具营养和保健功能,且本发明通过恰当的工艺,使制得的巧克力具有宜人的香味、清凉的口感以及清脆的质地。The invention provides a formula for improving the quality of lauric acid cocoa butter substitute (CBS) chocolate, which comprises: 30%-45% of oil, 10-15% of cocoa powder and 15% of white sugar, based on the total weight of the chocolate ~30%, sucrose substitute 5%~25%, skimmed milk powder 10%~20%, emulsifier 0.3%~0.5%. The invention also provides a method for preparing chocolate using the formula. The chocolate of the invention can effectively improve the problem of easy blooming of traditional chocolate, endow the chocolate with a long-lasting smooth surface, contain rich probiotic factors and have both nutrition and health functions, and the invention makes the prepared chocolate have Pleasant aroma, cool taste and crisp texture.
Description
技术领域technical field
本发明提供了一种月桂酸类代可可脂(CBS)巧克力的配方,具体为一种有效改善CBS巧克力起霜缺陷,并可制备出具有宜人香味、清凉口感以及清脆质地的巧克力的配方。The invention provides a formula of lauric acid cocoa butter substitute (CBS) chocolate, specifically a formula that can effectively improve the blooming defect of CBS chocolate, and can prepare chocolate with pleasant fragrance, cool taste and crisp texture.
背景技术Background technique
月桂酸类代可可脂是可可脂代用品中的一大系列,它以棕榈仁油、椰子油等为原料,通过氢化、酯交换、分提或几种方式相结合等处理而得到。加氢到接近饱和的月桂酸型脂受热熔化相当迅速和彻底,并且不饱和脂肪酸(如油酸和亚油酸)含量很低,使这些脂肪具有很好的氧化稳定性。相对于可可脂而言,月桂酸类代可可脂配方灵活并且成本较低,在加工过程中无需调温,简化了生产工艺,甚至可以完全取代可可脂用于代可可脂巧克力或代可可脂巧克力涂层制品的生产中。但是,严重的起霜现象却是此类巧克力的一大缺陷,特别是可可脂含量超过4%~6%时产品极易起霜。巧克力起霜的形成是一个非常复杂的过程,如何解决起霜问题已经成为一个世界性难题。Lauric acid cocoa butter substitutes are a large series of cocoa butter substitutes, which are obtained from palm kernel oil, coconut oil, etc., through hydrogenation, transesterification, fractionation or a combination of several methods. The lauric fat hydrogenated to near saturation melts quite quickly and thoroughly when heated, and the content of unsaturated fatty acids (such as oleic acid and linoleic acid) is very low, which makes these fats have good oxidation stability. Compared with cocoa butter, lauric cocoa butter substitutes have flexible formula and lower cost, no need to adjust the temperature during processing, which simplifies the production process, and can even completely replace cocoa butter for cocoa butter substitute chocolate or cocoa butter substitute chocolate In the production of coated products. However, serious blooming phenomenon is a major defect of this type of chocolate, especially when the cocoa butter content exceeds 4% to 6%, the product is very easy to bloom. The formation of chocolate bloom is a very complicated process, how to solve the problem of bloom has become a worldwide problem.
国内外对月桂酸类代可可脂巧克力起霜现象的研究,部分对比了霜和基质中的甘三酯组成,部分分析了晶型变化、油脂的相容性、组分的迁移、宏观性质之间的关系。对甘三酯组成的分析发现,月桂酸类代可可脂与可可脂甘三酯组成的显著差异与巧克力的起霜关系密切。从组分迁移的理论可知,巧克力中部分油脂组分向表面迁移并发生重结晶导致了起霜的形成。因此,有效抑制油脂的迁移是解决起霜问题的一个关键。如果能够有效地抑制巧克力中油脂的迁移,对于改善巧克力产品的起霜问题、促进巧克力行业的发展将具有重要意义。Domestic and foreign studies on the blooming phenomenon of lauric acid cocoa butter substitute chocolate, partly compared the composition of triglycerides in the cream and the matrix, and partly analyzed the crystal form change, oil compatibility, migration of components, and macroscopic properties. relationship between. The analysis of the composition of triglycerides found that the significant difference in the composition of triglycerides between cocoa butter substitutes of lauric acid and cocoa butter was closely related to the blooming of chocolate. From the theory of component migration, it can be known that some fat components in chocolate migrate to the surface and recrystallize, leading to the formation of bloom. Therefore, effectively inhibiting the migration of grease is a key to solve the problem of blooming. If the migration of oil in chocolate can be effectively inhibited, it will be of great significance for improving the blooming problem of chocolate products and promoting the development of the chocolate industry.
多元醇具有多个极性羟基,它可与液态甘三酯的极性区域相互作用,形成网络效应,抑制液态酯的迁移而抗霜。这些多元糖醇包括木糖醇、赤藓糖醇、异麦芽糖醇、麦芽糖醇、山梨醇、甘露醇、乳糖醇等。这些糖醇的甜度与蔗糖相当或约为蔗糖的一半,热值明显低于蔗糖,可少量替代蔗糖用于巧克力生产而不影响巧克力原有的浓香口感。Polyols have multiple polar hydroxyl groups, which can interact with the polar regions of liquid triglycerides to form a network effect, inhibit the migration of liquid esters and resist frost. These polysaccharide alcohols include xylitol, erythritol, isomalt, maltitol, sorbitol, mannitol, lactitol and the like. The sweetness of these sugar alcohols is equivalent to or about half that of sucrose, and its calorific value is significantly lower than that of sucrose. It can be used in chocolate production instead of sucrose in a small amount without affecting the original rich taste of chocolate.
目前还未见多元糖醇用于抑制代可可脂巧克力起霜方面的技术报道,也未见相关的产品上市。At present, there is no technical report on the use of polysaccharide alcohols for suppressing the blooming of cocoa butter substitute chocolate, and no related products are listed.
发明内容Contents of the invention
本发明的目的是提供一种有效改善起霜问题的月桂酸类代可可脂巧克力配方,其中含有一定量的低能量蔗糖替代品,因而兼具营养保健的功效。The object of the present invention is to provide a lauric acid-based cocoa butter substitute chocolate formula that can effectively improve the blooming problem, which contains a certain amount of low-energy sucrose substitute, thus having the effect of nutrition and health care.
一方面,本发明提供了一种有效改善起霜问题的月桂酸类代可可脂巧克力配方,以该巧克力的总重量为基准,包括:On the one hand, the present invention provides a kind of lauric acid cocoa butter substitute chocolate formula that effectively improves the blooming problem, based on the total weight of the chocolate, comprising:
油脂30%~45%,可可粉10~15%,白砂糖15%~30%,蔗糖替代品5%~25%,脱脂奶粉10%~20%,以及乳化剂0.3%~0.5%。30% to 45% of fat, 10% to 15% of cocoa powder, 15% to 30% of white sugar, 5% to 25% of sucrose substitute, 10% to 20% of skimmed milk powder, and 0.3% to 0.5% of emulsifier.
本发明的技术方案:多元醇具有多个极性羟基,它可与液态甘三酯的极性区域相互作用,形成网络效应,抑制液态酯的迁移而抗霜。与此同时,这些糖醇还具有预防龋齿和改善肠道的功效,带领巧克力向营养、健康方向发展。The technical scheme of the present invention: the polyol has multiple polar hydroxyl groups, which can interact with the polar regions of the liquid triglyceride to form a network effect, inhibit the migration of the liquid ester and resist frost. At the same time, these sugar alcohols also have the effect of preventing dental caries and improving intestinal tract, leading the development of chocolate in the direction of nutrition and health.
在实际生产中,原料糖醇必须是经过精磨的粉末料。与蔗糖相比,糖醇更容易吸水,从而导致巧克力浆料的粘稠,影响巧克力的加工,因而涉及到产品配方、乳化剂的选择以及加工工艺等问题。In actual production, the raw material sugar alcohol must be finely ground powder. Compared with sucrose, sugar alcohols are easier to absorb water, which leads to the viscosity of chocolate slurry and affects the processing of chocolate, which involves issues such as product formulation, emulsifier selection and processing technology.
油脂是巧克力的基础物料之一,它不但赋予巧克力良好的香味,同时也是巧克力制造过程中凝固成型的工艺基础,影响着巧克力在贮存过程中品质的变化,在巧克力制品中起着极其重要的作用。根据本发明的具体实施方案,本发明所述配方中油脂总含量为30%~40%。该油脂包括天然可可脂和月桂酸类代可可脂,其中这两种油脂的重量比为1~3∶7~9。例如,所述天然可可脂和月桂酸类代可可脂在巧克力中的含量分别为5%~10%和25%~30%。油脂含量的多少直接影响巧克力的口感、色泽和风味。本发明中,所用月桂酸类代可可脂具有与可可脂相近的熔化行为,但是与天然可可脂的相容性较差,添加可可脂较多时将导致体系的共晶软化,并且天然可可脂价格昂贵,不宜多加。Fat is one of the basic materials of chocolate. It not only gives chocolate a good fragrance, but also is the basis of solidification and molding technology in the chocolate manufacturing process. It affects the quality change of chocolate during storage and plays an extremely important role in chocolate products. . According to a specific embodiment of the present invention, the total fat content in the formula of the present invention is 30%-40%. The oil comprises natural cocoa butter and lauric acid cocoa butter substitutes, wherein the weight ratio of the two oils is 1-3:7-9. For example, the contents of the natural cocoa butter and lauric cocoa butter substitutes in chocolate are 5%-10% and 25%-30%, respectively. The amount of fat content directly affects the taste, color and flavor of chocolate. In the present invention, the cocoa butter substitute of lauric acid has a melting behavior similar to that of cocoa butter, but the compatibility with natural cocoa butter is poor. Adding more cocoa butter will cause the eutectic softening of the system, and the price of natural cocoa butter Expensive, should not add more.
根据本发明的具体实施方案,巧克力配方中所述的乳化剂包括卵磷脂和吐温60。卵磷脂和吐温60混合物的总添加量为0.3%~0.5%,且卵磷脂和吐温60的重量比为3~1∶1~3,并根据试验结果确定最优的添加重量比为1∶1。巧克力浆料中油脂具有亲油性,而糖及其他粉料物质表现为亲水性。吐温60为亲水性乳化剂,卵磷脂为亲油性乳化剂,这两种性质的乳化剂复配可有效改善巧克力浆料的加工性能,并有利于巧克力产品的清脆质地。According to a particular embodiment of the invention, said emulsifier in the chocolate formulation comprises lecithin and Tween 60. The total addition amount of lecithin and Tween 60 mixture is 0.3% ~ 0.5%, and the weight ratio of lecithin and Tween 60 is 3 ~ 1: 1 ~ 3, and according to the test results, it is determined that the optimal addition weight ratio is 1 : 1. Fat in chocolate mass is lipophilic, while sugar and other powdery substances are hydrophilic. Tween 60 is a hydrophilic emulsifier, and lecithin is a lipophilic emulsifier. The combination of these two types of emulsifiers can effectively improve the processing performance of chocolate paste, and is conducive to the crisp texture of chocolate products.
本发明的有益效果:本发明提供了一种有效改善起霜问题的月桂酸类代可可脂巧克力配方,制得的巧克力产品在长时间的贮存过程中保持表面光泽,为解决起霜这一难题提供了新思路。Beneficial effects of the present invention: the present invention provides a lauric acid cocoa butter substitute chocolate formula that can effectively improve the problem of blooming, and the prepared chocolate product maintains surface luster during long-term storage. Provided new ideas.
本发明中所使用的抗霜成分为天然的多元醇,具有防龋齿和改善肠道的功效,制得的巧克力具有特殊的香味、清凉的口感和清脆的质地。The anti-frost component used in the invention is natural polyhydric alcohol, which has the functions of preventing dental caries and improving intestinal tract, and the prepared chocolate has special fragrance, cool taste and crisp texture.
附图说明Description of drawings
图1未添加木糖醇的对照组巧克力显微镜图片。Fig. 1 Microscopic picture of control group chocolate without adding xylitol.
图2添加10%木糖醇的巧克力的显微镜图片。Fig. 2 Microscopic pictures of chocolate with 10% xylitol added.
由图2可以看出木糖醇的添加有效地改善了巧克力体系的结晶网络结构,使复杂的分散颗粒均匀地包裹在均匀的连续相中,从而有效地改善了油脂的迁移并延缓起霜。It can be seen from Figure 2 that the addition of xylitol effectively improves the crystallization network structure of the chocolate system, making complex dispersed particles evenly wrapped in a uniform continuous phase, thereby effectively improving the migration of oil and delaying blooming.
具体实施方式Detailed ways
为了更好地对本发明进行说明,通过下面的实施例来加以进一步的描述,但是本发明并没有局限于这些实施例。In order to illustrate the present invention better, the following examples are used for further description, but the present invention is not limited to these examples.
实施例1Example 1
本实例中的具有改善起霜问题的CBS巧克力配方为:The CBS chocolate formula with improved blooming problem in this example is:
油脂:350重量份(包含50重量份天然可可脂和300重量份月桂酸类代可可脂),可可粉:150重量份,白砂糖:250重量份,木糖醇:100重量份,脱脂奶粉:150份,香兰素:1重量份,卵磷脂:2重量份,吐温60:2重量份。Grease: 350 parts by weight (comprising 50 parts by weight of natural cocoa butter and 300 parts by weight of lauric cocoa butter substitute), cocoa powder: 150 parts by weight, white sugar: 250 parts by weight, xylitol: 100 parts by weight, skimmed milk powder: 150 parts, vanillin: 1 part by weight, lecithin: 2 parts by weight, Tween 60: 2 parts by weight.
利用本实例制做巧克力的方法为:The method of making chocolate using this example is as follows:
按配方量称取所述CBS巧克力配方的各种组分,将油脂加热熔化,倒入预热至50~55℃的球磨机中,再逐步加入粉状原料糖粉、可可粉以及奶粉等,然后在55~60℃温度下进行精磨。其中,在精磨开始第1小时内添加乳化剂的20%~30%,在精磨第5个小时再添加乳化剂的20%~30%,第7个小时将剩余乳化剂加入,精磨约8个小时后达到要求的细度,即得到本实例的巧克力浆料,之后出料,置于40~50℃烘箱中保存,然后倒入巧克力模具中成型。注模后的巧克力浆料迅速置于5℃环境中冷却结晶0.5小时,脱模,形成具有优良光泽度及特殊香味的巧克力。Weigh the various components of the CBS chocolate formula according to the formula, heat and melt the oil, pour it into a ball mill preheated to 50-55 ° C, and then gradually add powdered raw materials such as sugar powder, cocoa powder and milk powder, and then Fine grinding is carried out at a temperature of 55-60°C. Among them, 20% to 30% of the emulsifier is added within the first hour of fine grinding, 20% to 30% of the emulsifier is added in the fifth hour of fine grinding, and the remaining emulsifier is added in the seventh hour. After about 8 hours, the desired fineness is reached, that is, the chocolate slurry of this example is obtained, and then discharged, placed in an oven at 40-50° C. for preservation, and then poured into chocolate molds for molding. The chocolate slurry after injection molding is quickly placed in an environment of 5° C. for cooling and crystallization for 0.5 hour, and demolded to form chocolate with excellent gloss and special fragrance.
巧克力浆料制备的具体操作步骤为:将熔化的油脂倒入预热至50~55℃的球磨机中,并逐步加入配方中的粉状原料进行精磨,所述的乳化剂分成三次添加入精磨的巧克力料中,至巧克力浆料细度<25μm即得到精磨好的巧克力浆料。The specific operation steps for the preparation of the chocolate slurry are as follows: pour the melted oil into a ball mill preheated to 50-55°C, and gradually add the powdered raw materials in the formula for fine grinding. In the ground chocolate mass, finely ground chocolate slurry is obtained until the fineness of the chocolate slurry is less than 25 μm.
实施例2Example 2
本实例中的具有改善起霜问题的CBS巧克力配方为:The CBS chocolate formula with improved blooming problem in this example is:
油脂:350重量份(包含50重量份天然可可脂和300重量份月桂酸类代可可脂),可可粉:150重量份,白砂糖:200重量份,赤藓糖醇:150重量份,脱脂奶粉:150份,香兰素:1重量份,卵磷脂:2重量份,吐温60:2重量份。Fat: 350 parts by weight (comprising 50 parts by weight of natural cocoa butter and 300 parts by weight of lauric cocoa butter substitute), cocoa powder: 150 parts by weight, white sugar: 200 parts by weight, erythritol: 150 parts by weight, skimmed milk powder : 150 parts, vanillin: 1 part by weight, lecithin: 2 parts by weight, Tween 60: 2 parts by weight.
利用本实例制做巧克力的方法同实施例1。本实施例中赤藓糖醇的甜度低于蔗糖,热值为蔗糖的1/10,且结晶性好,吸湿性低,因此非常适合于糖尿病患者或肥胖者食用。The method that utilizes this example to make chocolate is with embodiment 1. The sweetness of erythritol in this embodiment is lower than that of sucrose, and its caloric value is 1/10 of that of sucrose. It has good crystallinity and low hygroscopicity, so it is very suitable for diabetics or obese people.
实施例3Example 3
本实例中的具有改善起霜问题的CBS巧克力配方为:The CBS chocolate formula with improved blooming problem in this example is:
油脂:350重量份(包含50重量份天然可可脂和300重量份月桂酸类代可可脂),可可粉:150重量份,白砂糖:200重量份,异麦芽糖醇:150重量份,脱脂奶粉:150份,香兰素:1重量份,卵磷脂:2重量份,吐温60:2重量份。Fat: 350 parts by weight (comprising 50 parts by weight of natural cocoa butter and 300 parts by weight of lauric cocoa butter substitute), cocoa powder: 150 parts by weight, white sugar: 200 parts by weight, isomalt: 150 parts by weight, skimmed milk powder: 150 parts, vanillin: 1 part by weight, lecithin: 2 parts by weight, Tween 60: 2 parts by weight.
利用本实例制做巧克力的方法同实施例1。本实施例中异麦芽糖醇的甜度低于蔗糖,热值为蔗糖的一半。The method that utilizes this example to make chocolate is with embodiment 1. In this embodiment, the sweetness of isomalt is lower than that of sucrose, and the caloric value is half of that of sucrose.
对比例1Comparative example 1
将实施例1中所述的木糖醇以等量的白砂糖替代,用于制备作为对比例的巧克力。制做巧克力的方法同实施例1。The xylitol described in Example 1 was replaced with an equal amount of white granulated sugar to prepare chocolate as a comparative example. The method for making chocolate is with embodiment 1.
巧克力抗起霜实验Chocolate anti-blooming test
取实施例1~3和对比例1中的CBS巧克力产品,于25℃保藏,定期检测巧克力的表面白色度、X-衍射晶型分析、结晶网络结构分析,试验期3个月。实施例巧克力产品在3个月的储藏期内保持β′晶型,未发生油脂迁移至表面引起起霜的现象,实验结束时巧克力仍具有良好的光泽度和宜人的香味。而对比例在储存四周之后即出现白霜,失去表面光泽The CBS chocolate products in Examples 1-3 and Comparative Example 1 were stored at 25°C, and the surface whiteness, X-diffraction crystal form analysis, and crystal network structure analysis of the chocolate were regularly tested, and the test period was 3 months. Example The chocolate product maintained the β′ crystal form during the storage period of 3 months, and the phenomenon of blooming caused by oil migration to the surface did not occur. At the end of the experiment, the chocolate still had good gloss and pleasant fragrance. However, after four weeks of storage, white frost appeared in the comparative example, and the surface luster was lost.
图1为未添加木糖醇的对照组CBS巧克力显微镜图片,图2为添加10%木糖醇的巧克力显微镜图片。Fig. 1 is a microscopic picture of CBS chocolate without adding xylitol, and Fig. 2 is a microscopic picture of chocolate with 10% xylitol added.
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| CN104244725A (en) * | 2012-04-25 | 2014-12-24 | 株式会社明治 | Baked composite confection and method for producing same |
| CN105076622A (en) * | 2015-08-08 | 2015-11-25 | 蚌埠市老顽童食品厂 | Edible mushroom chocolate |
| CN105230902A (en) * | 2015-09-25 | 2016-01-13 | 四川茂华食品有限公司 | High-temperature resistant chocolate and preparation method thereof |
| CN107455537A (en) * | 2017-10-07 | 2017-12-12 | 关华杏 | A kind of new substitute of cocoa fat chocolate |
| CN108200991A (en) * | 2016-12-16 | 2018-06-26 | 内蒙古蒙牛乳业(集团)股份有限公司 | Spray chocolate and its application in crispy cone |
| CN110150432A (en) * | 2019-06-21 | 2019-08-23 | 北京康贝尔食品有限责任公司 | A kind of chocolate and preparation method thereof |
| CN111374203A (en) * | 2018-12-29 | 2020-07-07 | 内蒙古蒙牛乳业(集团)股份有限公司 | Yoghourt-flavored chocolate coating composition and preparation method thereof |
| CN111713588A (en) * | 2020-06-30 | 2020-09-29 | 汕头市甜甜乐糖果食品有限公司 | Low-sugar chocolate paste and preparation method and application thereof |
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| CN104244725A (en) * | 2012-04-25 | 2014-12-24 | 株式会社明治 | Baked composite confection and method for producing same |
| CN104244725B (en) * | 2012-04-25 | 2017-05-17 | 株式会社明治 | Baked composite confection and method for producing same |
| CN102894159A (en) * | 2012-09-13 | 2013-01-30 | 河南梦想食品有限公司 | Marble chocolate and manufacturing method thereof |
| CN104126673A (en) * | 2013-05-03 | 2014-11-05 | 丰益(上海)生物技术研发中心有限公司 | Peanut oil body composition and application thereof |
| CN105076622A (en) * | 2015-08-08 | 2015-11-25 | 蚌埠市老顽童食品厂 | Edible mushroom chocolate |
| CN105230902A (en) * | 2015-09-25 | 2016-01-13 | 四川茂华食品有限公司 | High-temperature resistant chocolate and preparation method thereof |
| CN108200991A (en) * | 2016-12-16 | 2018-06-26 | 内蒙古蒙牛乳业(集团)股份有限公司 | Spray chocolate and its application in crispy cone |
| CN107455537A (en) * | 2017-10-07 | 2017-12-12 | 关华杏 | A kind of new substitute of cocoa fat chocolate |
| CN111374203A (en) * | 2018-12-29 | 2020-07-07 | 内蒙古蒙牛乳业(集团)股份有限公司 | Yoghourt-flavored chocolate coating composition and preparation method thereof |
| CN111374203B (en) * | 2018-12-29 | 2023-04-07 | 内蒙古蒙牛乳业(集团)股份有限公司 | Yoghourt-flavored chocolate coating composition and preparation method thereof |
| CN110150432A (en) * | 2019-06-21 | 2019-08-23 | 北京康贝尔食品有限责任公司 | A kind of chocolate and preparation method thereof |
| CN110150432B (en) * | 2019-06-21 | 2022-04-26 | 北京康贝尔食品有限责任公司 | Chocolate candy and preparation method thereof |
| CN111713588A (en) * | 2020-06-30 | 2020-09-29 | 汕头市甜甜乐糖果食品有限公司 | Low-sugar chocolate paste and preparation method and application thereof |
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