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CN101814574A - Light emitting diode base plate heat radiation structure and manufacture method thereof - Google Patents

Light emitting diode base plate heat radiation structure and manufacture method thereof Download PDF

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Publication number
CN101814574A
CN101814574A CN201010151292A CN201010151292A CN101814574A CN 101814574 A CN101814574 A CN 101814574A CN 201010151292 A CN201010151292 A CN 201010151292A CN 201010151292 A CN201010151292 A CN 201010151292A CN 101814574 A CN101814574 A CN 101814574A
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circuit board
light
emitting diode
base plate
heat dissipation
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贺能
陈建平
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Foryou Multimedia Electronics Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched

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Abstract

一种发光二极管线路板散热结构,包括线路板以及与线路板中导电线路层电路连接的发光二极管,在线路板下表面紧贴有一散热底板,在线路板安装发光二极管位置开有贯穿孔,发光二极管通过贯穿孔贴于底板内表面。本结构通过增设导热底板消除了现有技术中对线路板本身的破坏以及后续制作加工带来的负面影响,发光二极管可直接贴于散热底板上,使整个基板具有更高的导热系数,光线的发射效果以及散热效果极佳,并且不影响现有线路板的制作加工工艺,底板可以单独进行加工底板的平整度以及光洁度更易于保证,极大简化了加工步骤,降低了制作难度,从而也降低了生产成本。

Figure 201010151292

A light-emitting diode circuit board heat dissipation structure, including a circuit board and a light-emitting diode connected to a conductive circuit layer circuit in the circuit board, a heat-dissipating bottom plate is attached to the lower surface of the circuit board, and a through hole is opened at the position where the light-emitting diode is installed on the circuit board to emit light. The diode is pasted on the inner surface of the bottom plate through the through hole. This structure eliminates the damage to the circuit board itself and the negative impact of subsequent manufacturing and processing in the prior art by adding a heat-conducting bottom plate. The light-emitting diode can be directly attached to the heat-dissipating bottom plate, so that the entire substrate has a higher thermal conductivity. The emission effect and heat dissipation effect are excellent, and it does not affect the production and processing technology of the existing circuit board. The base plate can be processed separately. production cost.

Figure 201010151292

Description

一种发光二极管基板散热结构及其制作方法 A light-emitting diode substrate heat dissipation structure and manufacturing method thereof

技术领域technical field

本发明涉及一种基板散热结构的改进。The invention relates to an improvement of a heat dissipation structure of a substrate.

背景技术Background technique

过去,开发了把发光二极管安装在铝基板上作为照明光源,尤其近几年随着铝基板的导热系数逐渐提高,发光二极管的驱动电流可以使用更大的电流。再者,为了减小照明光源的体积,对安装在铝基板上的发光二极管的集成度原来越高。然而高集成的照明光源在更大的驱动电流下,发光二极管的将会相对产生更多的热量,使其因过热而影响其它的性能的表现,甚至造成发光二极管的损坏。请参考图1。In the past, light-emitting diodes were developed to be installed on aluminum substrates as lighting sources. Especially in recent years, as the thermal conductivity of aluminum substrates has gradually increased, the driving current of light-emitting diodes can use a larger current. Furthermore, in order to reduce the volume of the lighting source, the integration degree of the light emitting diodes mounted on the aluminum substrate is originally higher. However, under the higher driving current of the highly integrated lighting source, the light-emitting diode will relatively generate more heat, which will affect other performances due to overheating, and even cause damage to the light-emitting diode. Please refer to Figure 1.

为了再提高铝基板的导热系数,降低其热阻,通过锣铣的方法露出底部的铝板并直接把发光二极管安装在铝基板的铝板上。但由于铝板的发光二极管安装表面反射效果不好、不平整的缺点,在提高照明光源的亮度上仍然受到了限制。请参考图2。In order to further increase the thermal conductivity of the aluminum substrate and reduce its thermal resistance, the aluminum plate at the bottom is exposed by milling and the light-emitting diodes are directly mounted on the aluminum plate of the aluminum substrate. However, due to the poor reflection effect and unevenness of the light-emitting diode installation surface of the aluminum plate, it is still limited in improving the brightness of the lighting source. Please refer to Figure 2.

为了解决以上底部铝板反射效果不好、不平整的问题,提出了将铝基板上包含的导电线路层及铝板一起镀银的方案,但由于导电线路层上镀银后使发光二极管的所引出的金线在镀银导电线路层上的焊接存在焊接不牢固的问题。In order to solve the problem of poor reflection effect and unevenness of the aluminum plate at the bottom above, a scheme of silver-plating the conductive circuit layer contained on the aluminum substrate and the aluminum plate is proposed, but because the conductive circuit layer is silver-plated, the light-emitting diodes drawn out The welding of the gold wire on the silver-plated conductive circuit layer has the problem of weak welding.

为了解决以上焊接不牢固的问题,提出了铝板镀银以提高反射效果,而导电线路层镀金以解决焊接不牢固问题,但由于此工艺技术较难,这种结构的铝基板未能得到广泛的使用。In order to solve the above problem of weak welding, it is proposed to plate silver on the aluminum plate to improve the reflection effect, and to plate the conductive circuit layer with gold to solve the problem of weak welding. However, due to the difficulty of this process technology, the aluminum substrate with this structure has not been widely used. use.

因此,如何设计一种制作工艺简单、散热效果好的发光二极管基板散热结构是本领域工程技术人员需要解决的一大难题。Therefore, how to design a light-emitting diode substrate heat dissipation structure with simple manufacturing process and good heat dissipation effect is a major problem to be solved by engineers and technicians in the field.

发明内容Contents of the invention

本发明所要解决的技术问题之一是克服现有技术不足、提供一种具有良好散热效果的发光二极管基板散热结构。One of the technical problems to be solved by the present invention is to overcome the deficiencies of the prior art and provide a light emitting diode substrate heat dissipation structure with good heat dissipation effect.

为解决上述技术问题,本发明采用以下技术方案实现:In order to solve the above-mentioned technical problems, the present invention adopts the following technical solutions to realize:

一种发光二极管线路板散热结构,包括线路板以及与线路板中导电线路层电路连接的发光二极管,在线路板下表面紧贴有一散热底板,在线路板安装发光二极管位置开有贯穿孔,发光二极管通过贯穿孔贴于底板内表面。A light-emitting diode circuit board heat dissipation structure, including a circuit board and a light-emitting diode connected to a conductive circuit layer circuit in the circuit board, a heat-dissipating bottom plate is attached to the lower surface of the circuit board, and a through hole is opened at the position where the light-emitting diode is installed on the circuit board to emit light. The diode is pasted on the inner surface of the bottom plate through the through hole.

作为对上述方案的改进,所述的底板为散热良好的片材,在底板贴发光二极管表面加工为利于光线反射的光洁面。As an improvement to the above solution, the base plate is a sheet material with good heat dissipation, and the surface of the base plate on which the light-emitting diodes are attached is processed into a smooth surface that facilitates light reflection.

为了保证整个结构的稳定性以及良好的散热效果,线路板下表面与底板之间通过导热粘接剂紧密贴合。In order to ensure the stability of the entire structure and a good heat dissipation effect, the lower surface of the circuit board and the bottom plate are tightly bonded by a thermally conductive adhesive.

其中,所述的线路板为铝基板或玻璃纤维线路板。所述的铝基板由位于导线线路层上表面的白油层以及依次位于导线线路层下表面的绝缘层/铝制基板组成,底板紧贴于铝制基板下表面。所述的玻璃纤维线路板由位于导线线路层上表面的白油层以及位于导线线路层下表面的玻璃纤维材料制的绝缘层组成,底板紧贴于绝缘层下表面。Wherein, the circuit board is an aluminum substrate or a glass fiber circuit board. The aluminum substrate is composed of a white oil layer on the upper surface of the wire circuit layer and an insulating layer/aluminum substrate sequentially located on the lower surface of the wire circuit layer, and the bottom plate is closely attached to the lower surface of the aluminum substrate. The glass fiber circuit board is composed of a white oil layer on the upper surface of the wire circuit layer and an insulating layer made of glass fiber material on the lower surface of the wire circuit layer, and the bottom plate is closely attached to the lower surface of the insulating layer.

本结构通过增设导热底板消除了现有技术中对线路板本身的破坏以及后续制作加工带来的负面影响,发光二极管可直接贴于散热底板上,使整个基板具有更高的导热系数,光线的发射效果以及散热效果极佳。This structure eliminates the damage to the circuit board itself and the negative impact of subsequent manufacturing and processing in the prior art by adding a heat-conducting bottom plate. The light-emitting diode can be directly attached to the heat-dissipating bottom plate, so that the entire substrate has a higher thermal conductivity. The emission effect and heat dissipation effect are excellent.

本发明要解决的另一个技术问题是提供一种制作方法简单的发光二极管基板散热结构制作方法。Another technical problem to be solved by the present invention is to provide a method for manufacturing a light-emitting diode substrate heat dissipation structure with a simple manufacturing method.

该方法步骤为:The method steps are:

a、根据线路板尺寸、发光二极管分布情况加工底板,使底板与线路板贴合面加工至光洁面;a. Process the bottom plate according to the size of the circuit board and the distribution of light-emitting diodes, so that the bonding surface of the bottom plate and the circuit board is processed to a smooth surface;

b、根据发光二极管分布情况加工线路板,将线路板预安装发光二极管位置开设容纳发光二极管的贯穿孔;b. Process the circuit board according to the distribution of the light-emitting diodes, and open through holes for accommodating the light-emitting diodes at the position where the light-emitting diodes are pre-installed on the circuit board;

c、将发光二极管紧贴于底板光洁面且与贯穿孔对应的位置处,利用导热粘接剂将底板光洁面紧贴于线路板下表面;c. Attach the light-emitting diode to the smooth surface of the base plate at the position corresponding to the through hole, and use a heat-conducting adhesive to attach the smooth surface of the base plate to the lower surface of the circuit board;

d、将发光二极管电源线焊接于线路板导电线路层线路中。d. Solder the LED power line to the conductive circuit layer of the circuit board.

该方法与现有的具有高散热效果的线路板结构相比,不影响现有线路板的制作加工工艺,且其主要散热部件底板可以单独进行加工底板的平整度以及光洁度更易于保证,极大简化了加工步骤,降低了制作难度,从而也降低了生产成本。采用本方法制作的发光二极管线路板散热结构也使发光二极管的热量更易于传导至底板上散失,并且发光二极管的光线反射效果也更佳。Compared with the existing circuit board structure with high heat dissipation effect, this method does not affect the production and processing technology of the existing circuit board, and the bottom plate of the main heat dissipation component can be processed separately, and the flatness and smoothness of the bottom plate are easier to ensure, which greatly The processing steps are simplified, the manufacturing difficulty is reduced, and thus the production cost is also reduced. The heat dissipation structure of the light-emitting diode circuit board manufactured by the method also makes it easier for the heat of the light-emitting diode to be conducted to the base plate for dissipation, and the light reflection effect of the light-emitting diode is also better.

附图说明Description of drawings

附图1为现有一种发光二极管线路板散热结构示意图;Accompanying drawing 1 is a schematic diagram of the heat dissipation structure of an existing LED circuit board;

附图2为现有另一种发光二极管线路板散热结构示意图;Accompanying drawing 2 is the schematic diagram of heat dissipation structure of another existing light-emitting diode circuit board;

附图3为本发明实施例一结构示意图;Accompanying drawing 3 is a structural schematic diagram of Embodiment 1 of the present invention;

附图4为本发明实施例二结构示意图。Accompanying drawing 4 is the structural schematic diagram of embodiment 2 of the present invention.

具体实施方式Detailed ways

为了便于本领域技术人员的理解,下面将结合具体实施例及附图对本发明结构原理作进一步详细描叙:In order to facilitate the understanding of those skilled in the art, the structural principle of the present invention will be further described in detail below in conjunction with specific embodiments and accompanying drawings:

实施例一:如附图3所示,本实施例揭示的发光二极管线路板散热结构是针对常规发光二极管铝基板散热结构的改进,与常规铝基板一致,该铝基板1从上之下依次包括白油层12、导电线路层11、绝缘层13以及铝制基板14。Embodiment 1: As shown in Figure 3, the heat dissipation structure of the light-emitting diode circuit board disclosed in this embodiment is an improvement on the heat dissipation structure of the conventional light-emitting diode aluminum substrate, which is consistent with the conventional aluminum substrate. The aluminum substrate 1 consists of White oil layer 12 , conductive circuit layer 11 , insulating layer 13 and aluminum substrate 14 .

相对现有的铝基板而言,本实施例中铝基板最大改进之处为在铝制基板14底部通过导热粘接剂16紧密贴有一片状散热底板3,该底板3的材料可为散热良好的金属、也可以为硅或陶瓷等。在基板14安装发光二极管2位置开有贯穿孔15,发光二极管2通过贯穿孔15紧贴于底板3表面,发光二极管2的电源线则与导电线路层11内部电路连接。为了增加底板3的反光效果,在底板3粘贴发光二极管2位置加工至光洁面,当然为了加工的方便,也可以将整个底板与基板14贴合面加工至光洁面。Compared with the existing aluminum substrate, the biggest improvement of the aluminum substrate in this embodiment is that the bottom of the aluminum substrate 14 is closely pasted with a heat-dissipating base plate 3 through the heat-conducting adhesive 16, and the material of the base plate 3 can be good for heat dissipation The metal, silicon or ceramics can also be used. A through hole 15 is opened at the position where the light emitting diode 2 is installed on the substrate 14 , the light emitting diode 2 is closely attached to the surface of the bottom plate 3 through the through hole 15 , and the power line of the light emitting diode 2 is connected to the internal circuit of the conductive circuit layer 11 . In order to increase the reflective effect of the bottom plate 3, the position where the light-emitting diode 2 is pasted on the bottom plate 3 is processed to a smooth surface. Of course, for the convenience of processing, the bonding surface of the entire bottom plate and the substrate 14 can also be processed to a smooth surface.

很明显,在制作本实施例描述的发光二极管线路板散热结构时,可不用改变现有铝基板1结构,只需在铝基板1安装发光二极管位置开设贯穿孔15,再将发光二极管通过紧贴于底板3上,然后将预先加工完成的底板3紧贴于铝基板1下表面、将发光二极管的电源线与导电线路层中相应导线连接即可。Obviously, when making the heat dissipation structure of the light-emitting diode circuit board described in this embodiment, it is not necessary to change the structure of the existing aluminum substrate 1. It is only necessary to open a through-hole 15 at the position where the light-emitting diode is installed on the aluminum substrate 1, and then the light-emitting diode is passed through. On the bottom plate 3, then stick the pre-processed bottom plate 3 on the lower surface of the aluminum substrate 1, and connect the power line of the light emitting diode to the corresponding wire in the conductive circuit layer.

具体制作时,可采用如下步骤:For specific production, the following steps can be used:

a、根据线路板尺寸、发光二极管分布情况加工底板,使底板与线路板贴合面加工至光洁面;a. Process the bottom plate according to the size of the circuit board and the distribution of light-emitting diodes, so that the bonding surface of the bottom plate and the circuit board is processed to a smooth surface;

b、根据发光二极管分布情况加工线路板,将线路板预安装发光二极管位置开设容纳发光二极管的贯穿孔;b. Process the circuit board according to the distribution of the light-emitting diodes, and open through holes for accommodating the light-emitting diodes at the position where the light-emitting diodes are pre-installed on the circuit board;

c、将发光二极管紧贴于底板光洁面且与贯穿孔对应的位置处,利用导热粘接剂将底板光洁面紧贴于线路板下表面;c. Attach the light-emitting diode to the smooth surface of the base plate at the position corresponding to the through hole, and use a heat-conducting adhesive to attach the smooth surface of the base plate to the lower surface of the circuit board;

d、将发光二极管电源线焊接于线路板导电线路层线路中。d. Solder the LED power line to the conductive circuit layer of the circuit board.

可见,该结构在制作、安装时工艺非常方便、难度也低,散热效果好,成本也较低。It can be seen that the fabrication and installation of this structure are very convenient in process, low in difficulty, good in heat dissipation effect, and low in cost.

实施例二:如附图4所示,本实施例与实施例一中结构原理一致,其不同之处为针对线路板中的玻璃纤维线路板进行的改进,该玻璃纤维线路板1从上至下依次包括白油层12、导电线路层11和绝缘层13,与实施例中改进方案一致,在绝缘层13下方同样通过导热粘接剂16紧贴有一散热底板3,发光二极管2通过预设于玻璃纤维线路板1上的贯穿孔紧贴于底板3上,而发光二极管2的电源线同样与导线线路层11连接。Embodiment 2: As shown in accompanying drawing 4, the structural principle of this embodiment is consistent with that of Embodiment 1, the difference is that the glass fiber circuit board in the circuit board is improved, and the glass fiber circuit board 1 is from top to bottom The lower layer includes a white oil layer 12, a conductive circuit layer 11 and an insulating layer 13 in sequence, which is consistent with the improvement in the embodiment. A heat dissipation bottom plate 3 is also closely attached to the bottom of the insulating layer 13 through a heat-conducting adhesive 16. The light-emitting diode 2 is preset in the The through holes on the glass fiber circuit board 1 are closely attached to the base plate 3 , and the power lines of the LEDs 2 are also connected to the wiring layer 11 .

同样,具体制作时,可采用如下步骤:Similarly, the following steps can be used for specific production:

a、根据线路板尺寸、发光二极管分布情况加工底板,使底板与线路板贴合面加工至光洁面;a. Process the bottom plate according to the size of the circuit board and the distribution of light-emitting diodes, so that the bonding surface of the bottom plate and the circuit board is processed to a smooth surface;

b、根据发光二极管分布情况加工线路板,将线路板预安装发光二极管位置开设容纳发光二极管的贯穿孔;b. Process the circuit board according to the distribution of the light-emitting diodes, and open through holes for accommodating the light-emitting diodes at the position where the light-emitting diodes are pre-installed on the circuit board;

c、将发光二极管紧贴于底板光洁面且与贯穿孔对应的位置处,利用导热粘接剂将底板光洁面紧贴于线路板下表面;c. Attach the light-emitting diode to the smooth surface of the base plate at the position corresponding to the through hole, and use a heat-conducting adhesive to attach the smooth surface of the base plate to the lower surface of the circuit board;

d、将发光二极管电源线焊接于线路板导电线路层线路中。d. Solder the LED power line to the conductive circuit layer of the circuit board.

可见,该结构在制作、安装时工艺非常方便、难度也低,散热效果好,成本也较低。It can be seen that the fabrication and installation of this structure are very convenient in process, low in difficulty, good in heat dissipation effect, and low in cost.

上述实施例仅为本发明的较佳的实施方式,除此之外,本发明还可以有其他实现方式。也就是说,在没有脱离本发明构思的前提下,任何显而易见的替换均应落入本发明的保护范围之内。The above-mentioned embodiments are only preferred implementation manners of the present invention, and besides this, the present invention may also have other implementation manners. That is to say, on the premise of not departing from the concept of the present invention, any obvious replacement shall fall within the protection scope of the present invention.

Claims (7)

1.一种发光二极管线路板散热结构,包括线路板(1)以及与线路板中导电线路层(11)电路连接的发光二极管(2),其特征在于:在线路板下表面紧贴有一散热底板(3),在线路板安装发光二极管位置开有贯穿孔(15),发光二极管通过贯穿孔贴于底板内表面。1. A light-emitting diode circuit board heat dissipation structure, comprising a circuit board (1) and a light-emitting diode (2) connected to a circuit of a conductive circuit layer (11) in the circuit board, characterized in that: a heat dissipation device is closely attached to the circuit board lower surface The base plate (3) is provided with a through hole (15) at the position where the light emitting diode is installed on the circuit board, and the light emitting diode is pasted on the inner surface of the base plate through the through hole. 2.根据权利要求1所述的发光二极管基板散热结构,其特征在于:所述的底板为散热良好的片材,在底板贴发光二极管表面加工为利于光线反射的光洁面。2 . The heat dissipation structure of the LED substrate according to claim 1 , wherein the base plate is a sheet material with good heat dissipation, and the surface of the base plate pasted with the LEDs is processed into a smooth surface that facilitates light reflection. 3 . 3.根据权利要求2所述的发光二极管基板散热结构,其特征在于:线路板下表面与底板之间通过导热粘接剂紧密贴合。3 . The LED substrate heat dissipation structure according to claim 2 , wherein the lower surface of the circuit board and the base plate are closely bonded by a heat-conducting adhesive. 4 . 4.根据权利要求1~3中任一一项所述的发光二极管基板散热结构,其特征在于:所述的线路板为铝基板或玻璃纤维线路板。4 . The light emitting diode substrate heat dissipation structure according to claim 1 , wherein the circuit board is an aluminum substrate or a glass fiber circuit board. 5.根据权利要求4所述的发光二极管基板散热结构,其特征在于:所述的铝基板由位于导线线路层上表面的白油层(12)以及依次位于导线线路层下表面的绝缘层(13)、铝制基板(14)组成,底板紧贴于铝制基板下表面。5. The light-emitting diode substrate heat dissipation structure according to claim 4, characterized in that: the aluminum substrate is composed of a white oil layer (12) positioned on the upper surface of the wire circuit layer and an insulating layer (13) sequentially positioned on the lower surface of the wire circuit layer ), an aluminum base plate (14), the base plate is closely attached to the lower surface of the aluminum base plate. 6.根据根据权利要求4所述的发光二极管基板散热结构,其特征在于:所述的玻璃纤维线路板由位于导线线路层上表面的白油层(12)以及位于导线线路层下表面的玻璃纤维材料制的绝缘层(13)组成,底板紧贴于绝缘层下表面。6. The light-emitting diode substrate heat dissipation structure according to claim 4, characterized in that: the glass fiber circuit board is composed of a white oil layer (12) located on the upper surface of the wire circuit layer and a glass fiber layer located on the lower surface of the wire circuit layer. The insulating layer (13) made of material is composed, and the bottom plate is closely attached to the lower surface of the insulating layer. 7.一种根据权利要求1所述发光二极管线路板散热结构制作方法,其特征在于,所述步骤为:7. A method for manufacturing a heat dissipation structure for a light-emitting diode circuit board according to claim 1, wherein the steps are: a、根据线路板尺寸、发光二极管分布情况加工底板,使底板与线路板贴合面加工至光洁面;a. Process the bottom plate according to the size of the circuit board and the distribution of light-emitting diodes, so that the bonding surface of the bottom plate and the circuit board is processed to a smooth surface; b、根据发光二极管分布情况加工线路板,将线路板预安装发光二极管位置开设容纳发光二极管的贯穿孔;b. Process the circuit board according to the distribution of the light-emitting diodes, and open through holes for accommodating the light-emitting diodes at the position where the light-emitting diodes are pre-installed on the circuit board; c、将发光二极管紧贴于底板光洁面且与贯穿孔对应的位置处,利用导热粘接剂将底板光洁面紧贴于线路板下表面;c. Attach the light-emitting diode to the smooth surface of the base plate at the position corresponding to the through hole, and use a heat-conducting adhesive to attach the smooth surface of the base plate to the lower surface of the circuit board; d、将发光二极管导线焊接于线路板导电线路层线路中。d. Solder the light-emitting diode wires in the conductive circuit layer circuit of the circuit board.
CN201010151292A 2010-04-16 2010-04-16 Light emitting diode base plate heat radiation structure and manufacture method thereof Pending CN101814574A (en)

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CN102427656A (en) * 2011-09-04 2012-04-25 东莞市万丰纳米材料有限公司 Composite circuit board
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CN104654247A (en) * 2013-11-25 2015-05-27 海洋王(东莞)照明科技有限公司 Heat dissipation structure of LED lamp, manufacturing method thereof, and LED lamp
CN106793707A (en) * 2017-01-17 2017-05-31 扬州扬杰电子科技股份有限公司 The framework and its processing method of a kind of diode (led) module

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CN102403436A (en) * 2010-09-07 2012-04-04 昆山科技大学 Manufacturing method of heat sink for semiconductor light emitting element
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CN102427656A (en) * 2011-09-04 2012-04-25 东莞市万丰纳米材料有限公司 Composite circuit board
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Application publication date: 20100825